Color conversion glass ceramics are prepared by cosintering borosilicate glass frits and green 0.06Ce：Y2.94（Al1-xGax）5O12 phosphors. The crystal structures, the influence of Ga concentration on the photoluminescen...Color conversion glass ceramics are prepared by cosintering borosilicate glass frits and green 0.06Ce：Y2.94（Al1-xGax）5O12 phosphors. The crystal structures, the influence of Ga concentration on the photoluminescence （PL）, and reliability properties of the color conversion glass ceramics are investigated. The PL emission wavelengths of 0.06Ce：Y2.94（Al1-xGax）5O12 glass ceramics show blue shift from 545 nm to 525 nm with increasing Ga content （x value） under excited at 460 nm. Reliability test results show that the quantum yield （QY） of 0.06Ce：Y2.94（Al1-xGax）5O12 glass ceramics decreases from 70.60% to 59.06% with x value increasing from 0.15 to 0.35 under the ambient condition of 85℃/RH85% for the exposure time of 168 h. And the quantum yield （QY） of 0.06Ce：Y2.94（Al1-xGax）5O12 glass ceramics decreases from 65.13% to 52.23% after being soaked into boiled water for 4 h. The finding reveals that the addition of Ga can deteriorate the reliability of the color conversion glass ceramics.展开更多
基金Project supported by the National Natural Science Foundation of China(Grant No.51302171)the Science and Technology Commission of Shanghai Municipality,China(Grant No.14500503300)the Natural Science Foundation of Shanghai,China(Grant No.12ZR1430900)
文摘Color conversion glass ceramics are prepared by cosintering borosilicate glass frits and green 0.06Ce：Y2.94（Al1-xGax）5O12 phosphors. The crystal structures, the influence of Ga concentration on the photoluminescence （PL）, and reliability properties of the color conversion glass ceramics are investigated. The PL emission wavelengths of 0.06Ce：Y2.94（Al1-xGax）5O12 glass ceramics show blue shift from 545 nm to 525 nm with increasing Ga content （x value） under excited at 460 nm. Reliability test results show that the quantum yield （QY） of 0.06Ce：Y2.94（Al1-xGax）5O12 glass ceramics decreases from 70.60% to 59.06% with x value increasing from 0.15 to 0.35 under the ambient condition of 85℃/RH85% for the exposure time of 168 h. And the quantum yield （QY） of 0.06Ce：Y2.94（Al1-xGax）5O12 glass ceramics decreases from 65.13% to 52.23% after being soaked into boiled water for 4 h. The finding reveals that the addition of Ga can deteriorate the reliability of the color conversion glass ceramics.
