In this paper, cold simulation experiments and numerical calculations are conducted to predict 3 D flow field aerodynamics for an oil furnace after being retrofitted due to its fuel variation. K ε model and SIMPLE ...In this paper, cold simulation experiments and numerical calculations are conducted to predict 3 D flow field aerodynamics for an oil furnace after being retrofitted due to its fuel variation. K ε model and SIMPLE program under body fit coordination (BFC) system, in which TTM non orthogonal method is used to control the irregular geometric boundary, are adopted to solve the control equations. Model tests are conducted to check the calculation results, showing that they are in agreement with each other. Three different alternatives with different side window locations are also calculated to optimize the designs. The field retrofitting results show that the combination of cold tests with numerical calculations has prosperous application in retrofitting or renewing medium and small boilers.展开更多
The addition of cold flow improvers(CFIs)is considered as the optimum strategy to improve the cold flow properties(CFPs)of diesel fuels,but this strategy is always limited by the required large dosage.To obtain low-do...The addition of cold flow improvers(CFIs)is considered as the optimum strategy to improve the cold flow properties(CFPs)of diesel fuels,but this strategy is always limited by the required large dosage.To obtain low-dosage and high-efficiency CFIs for diesel,1,2,3,6-tetrahydrophthalic anhydride(THPA)was introduced as a third and polar monomer to enhance the depressive effects of alkyl methacrylatetrans anethole copolymers(C_(14)MC-TA).The terpolymers of alkyl methacrylate-trans anethole-1,2,3,6-tetrahydrophthalic anhydride(C_(14)MC-TA-THPA)were synthesized and compared with the binary copolymers of C_(14)MC-TA and alkyl methacrylate-1,2,3,6-tetrahydrophthalic anhydride(C_(14)MC-THPA).Results showed that C_(14)MC-THPA achieved the best depressive effects on the cold filter plugging point(CFPP)and solid point(SP)by 11℃and 16℃at a dosage of 1250 mg/L and monomer ratio of 6:1,while 1500mg/L C_(14)MC-TA(1:1)reached the optimal depressive effects on the CFPP and SP by 12℃and 18℃.THPA introduction significantly improved the depressive effects of C_(14)MC-TA.Lower dosages of C_(14)MCTA-THPA in diesel exerted better improvement effects on the CFPP and SP than that of C_(14)MC-TA and C_(14)MC-THPA.When the monomer ratio and dosage were 6:0.6:0.4 and 1000 mg/L,the improvement effect of C_(14)MC-TA-THPA on diesel reached the optimum level,and the CFPP and SP were reduced by 13℃and 19℃,respectively.A 3D nonlinear surface diagram fitted by a mathematical model was also used for the first time to better understand the relationships of monomer ratios,dosages,and depressive effects of CFIs in diesel.Surface analysis results showed that C_(14)MC-TA-THPA achieved the optimum depressive effects at a monomer ratio of 6:0.66:0.34 and dosage of 1000 mg/L,and the CFPP and SP decreased by 14℃ and 19℃,respectively.The predicted results were consistent with the actual ones.Additionally,the improvement mechanism of these copolymers in diesel was also explored.展开更多
Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and p...Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and poor heat resistance limit their application scope.Recent advances have highlighted that the combination of extensional flow and thermal fields can achieve toughness–stiffness balance,high transparency,and good heat resistance.However,the effect of extensional flow on the post-non-isothermal crystallization of PLLA during heating and the resulting crystalline texture remains unclear.In this study,PLLA with a heterogeneous amorphous structure and oriented polymorph was prepared by extensional flow.The effect of heterogeneous amorphous structures on non-isothermal crystallization kinetics during the heating process was studied by thermal analysis,polarized optical microscopy,infrared spectroscopy,and ex situ/in situ X-ray characterization.These results clearly illustrate that extensional flow enhances the formation of oriented crystalline structures,accelerates non-isothermal crystallization,and modulates the polymorphic composition of PLLA.Moreover,an unexpected dual cold-crystallization behavior is identified in ordered PLLA samples upon extensional flow,which is from the extensional flow-induced heterogeneous amorphous phase into α' phase(low-temperature peak)and the pristine amorphous phase intoαphase(high-temperature peak).The extensional flow primarily promotes the formation of the more perfectαandα'phases,but has a negative effect on the final content ofαphase formed after cold crystallization andα'-to-αphase transformation.The findings of this work advance the understanding of PLLA non-isothermal crystallization after extensional flow and offer valuable guidance for high-performance PLLA upon heat treatment in practical processing.展开更多
Detecting biomarkers in body fluids by optical lateral flow immune assay(LFIA) technology provides rapid access to disease information for early diagnosis.LFIA is based on an antigen-antibody reaction and is rapidly b...Detecting biomarkers in body fluids by optical lateral flow immune assay(LFIA) technology provides rapid access to disease information for early diagnosis.LFIA is based on an antigen-antibody reaction and is rapidly becoming the preferred choice of physicians and patients for point-of-care testing due to its simplicity,cost-effectiveness,and rapid detection.Observing the optical signal change from the colloidal gold of the traditional LFIA strip has been widely applied for various biomarkers detection in body fluids.Despite the significant progress,rapid real-time detection of color changes in the colloidal gold by the naked eye still faces many limitations,such as large errors and the inability to quantify and accurately detect.New optical LFIA strip technology has emerged in recent years to extend its application scenarios for achieving quantitative detection such as fluorescence,afterglow,and chemiluminescence.Herein,we summarized the development of optical LFIA technology from single to hyphenated optical signals for biomarkers detection in body fluids from invasive and non-invasive sources.Moreover,the challenge and outlook of optical LFIA strip technology are highlighted to inspire the designing of next-generation diagnostic platforms.展开更多
Based on the design of the multi-row sprocket with a new tooth profile,a cold semi-precision forging process for manufacturing 5052 aluminum alloy multi-row sprocket was presented.Through simulating the forging proces...Based on the design of the multi-row sprocket with a new tooth profile,a cold semi-precision forging process for manufacturing 5052 aluminum alloy multi-row sprocket was presented.Through simulating the forging process of 5052 aluminum alloy sprocket billet with 3D rigid-viscoplastic FEM,both the distributions of flow velocity field in axial(U_Z),radial(U_R) and circumferential(U_θ) directions and the curves of velocity component in different deformation regions were respectively obtained.By comparison and analysis of the velocity varying curves,the velocity component relation conditions for filling the die cavity were clarified.It shows that when the die cavity is almost fully filled,the circumferential velocity U_θ increases sharply,implying that U_θplays a key role in fully filling the die cavity.展开更多
The current research about the flow ripple of axial piston pump mainly focuses on the effect of the structure of parts on the flow ripple. Therein, the structure of parts are usually designed and optimized at rated wo...The current research about the flow ripple of axial piston pump mainly focuses on the effect of the structure of parts on the flow ripple. Therein, the structure of parts are usually designed and optimized at rated working conditions. However, the pump usually has to work in large-scale and time-variant working conditions. Therefore, the flow ripple characteristics of pump and analysis for its test accuracy with respect to variant steady-state conditions and transient conditions in a wide range of operating parameters are focused in this paper. First, a simulation model has been constructed, which takes the kinematics of oil film within friction pairs into account for higher accuracy. Afterwards, a test bed which adopts Secondary Source Method is built to verify the model. The simulation and tests results show that the angular position of the piston, corresponding to the position where the peak flow ripple is produced, varies with the different pressure. The pulsating amplitude and pulsation rate of flow ripple increase with the rise of pressure and the variation rate of pressure. For the pump working at a constant speed, the flow pulsation rate decreases dramatically with the increasing speed when the speed is less than 27.78% of the maximum speed, subsequently presents a small decrease tendency with the speed further increasing. With the rise of the variation rate of speed, the pulsating amplitude and pulsation rate of flow ripple increase. As the swash plate angle augments, the pulsating amplitude of flow ripple increases, nevertheless the flow pulsation rate decreases. In contrast with the effect of the variation of pressure, the test accuracy of flow ripple is more sensitive to the variation of speed. It makes the test accuracy above 96.20% available for the pulsating amplitude of pressure deviating within a range of ~6% from the mean pressure. However, with a variation of speed deviating within a range of ±2% from the mean speed, the attainable test accuracy of flow ripple is above 93.07%. The model constructed in this research proposes a method to determine the flow ripple characteristics of pump and its attainable test accuracy under the large-scale and time-variant working conditions. Meanwhile, a discussion about the variation of flow ripple and its obtainable test accuracy with the conditions of the pump working in wide operating ranges is given as well.展开更多
Synthesis of a cold flow improver （MAVA-a） for diesel fuel and its effect on solidifying point （SP） and cold filter plugging point （CFPP） of diesel fuels were investigated, The cold flow improver was prepared by...Synthesis of a cold flow improver （MAVA-a） for diesel fuel and its effect on solidifying point （SP） and cold filter plugging point （CFPP） of diesel fuels were investigated, The cold flow improver was prepared by using maleic anhydride （MA） and vinyl acetate （VA） as raw materials, toluene as solvent, dibenzoyl peroxide （BPO） as initiator, through alternating polymerization under nitrogen to obtain a binary-polymer and then through aminolysis by using a higher carbon amine as aminating agent at a temperature of 80 ℃. A cold flow improver was designed and prepared for No. 0 diesel fuel from Zhang Jia-Gang Petrochemical Company according to the contents of n-paraffin and its carbon number distribution in the No. 0 diesel fuel. It was also used together with two kinds of ethene-vinyl acetate copolymer improvers （EVA） separately. The test result showed that the CFPP of the No. 0 diesel fuel could be lowered by 3-5 ℃ when the improver MAVA-a was used. The CFPP was lowered by 8℃ when the improver MAVA-a was used together with EVA-2.展开更多
Numerical investigations on the flow field in Ti-Al melt during rectangular cold crucible directional solidification were carried out. Combined with the experimental results, 3-D finite element models for calculating ...Numerical investigations on the flow field in Ti-Al melt during rectangular cold crucible directional solidification were carried out. Combined with the experimental results, 3-D finite element models for calculating flow field inside melting pool were established, the characteristics of the flow under different power parameters were further studied. Numerical calculation results show that there is a complex circular flow in the melt, a rapid horizontal flow exists on the solid/liquid interface and those flows confluence in the center of the melting pool. The flow velocity v increases with the increase of current intensity, but the flow patterns remain unchanged. When the current is 1000 A, the vmax reaches 4 mm/s and the flow on the interface achieves 3 mm/s. Flow patterns are quite different when the frequency changes from 10 kHz to 100 kHz, the mechanism of the frequency influence on the flow pattern is analyzed, and there is an optimum frequency for cold crucible directional solidification.展开更多
The double blade pump is widely used in sewage treatment industry,however,the research on the internal flow characteristics of the double blade pump with particle image velocimetry（PIV） technology is very little at ...The double blade pump is widely used in sewage treatment industry,however,the research on the internal flow characteristics of the double blade pump with particle image velocimetry（PIV） technology is very little at present.To reveal inner flow characteristics in double blade pump impeller under off-design and design conditions,inner flows in a double blade pump impeller,whose specific speed is 111,are measured under the five off-design conditions and design condition by using 3D PIV test technology.In order to ensure the accuracy of the 3D PIV test,the external trigger synchronization system which makes use of fiber optic and equivalent calibration method are applied.The 3D PIV relative velocity synthesis procedure is compiled by using Visual C＋＋ 2005.Then absolute velocity distribution and relative velocity distribution in the double blade pump impeller are obtained.Test results show that vortex exists in each condition,but the location,size and velocity of vortex core are different.Average absolute velocity value of impeller outlet increases at first,then decreases,and then increases again with increase of flow rate.Again average relative velocity values under 0.4,0.8,and 1.2 design condition are higher than that under 1.0 design condition,while under 0.6 and 1.4 design condition it is lower.Under low flow rate conditions,radial vectors of absolute velocities at impeller outlet and blade inlet near the pump shaft decrease with increase of flow rate,while that of relative velocities at the suction side near the pump shaft decreases.Radial vectors of absolute velocities and relative velocities change slightly under the two large flow rate conditions.The research results can be applied to instruct the hydraulic optimization design of double blade pumps.展开更多
An S-band high-gradient accelerating structure is designed for a proton therapy linear accelerator(linac)to accommodate the new development of compact,singleroom facilities and ultra-high dose rate(FLASH)radiotherapy....An S-band high-gradient accelerating structure is designed for a proton therapy linear accelerator(linac)to accommodate the new development of compact,singleroom facilities and ultra-high dose rate(FLASH)radiotherapy.To optimize the design,an efficient optimization scheme is applied to improve the simulation efficiency.An S-band accelerating structure with 2856 MHz is designed with a low beta of 0.38,which is a difficult structure to achieve for a linac accelerating proton particles from 70 to 250 MeV,as a high gradient up to 50 MV/m is required.A special design involving a dual-feed coupler eliminates the dipole field effect.This paper presents all the details pertaining to the design,fabrication,and cold test results of the S-band high-gradient accelerating structure.展开更多
On December 3-5,2008,a cold flow snowfall happened in Shandong Peninsula.The basic weather situation and environmental field were analyzed.The results showed that the terrain condition,water vapor's latent heat-ex...On December 3-5,2008,a cold flow snowfall happened in Shandong Peninsula.The basic weather situation and environmental field were analyzed.The results showed that the terrain condition,water vapor's latent heat-exchange in Bo Sea,temperature differences between sea and land were very important elements in this process.展开更多
The purpose of this study was to investigate the effects of a traditional Japanese medicine Goshajinkigan (TJ-107) and Tokishigyakukagoshuyushokyoto (TJ-38) on warm sense threshold, cold sense threshold and the periph...The purpose of this study was to investigate the effects of a traditional Japanese medicine Goshajinkigan (TJ-107) and Tokishigyakukagoshuyushokyoto (TJ-38) on warm sense threshold, cold sense threshold and the peripheral blood flow. 31 healthy volunteers (control group: 9people, TJ-107 group: 12 people, TJ-38group:10 people) were examined. Drugs administered 2.5 g a dose. Analysis was before and after 1 hour dosage. The warm and cold sense threshold in the thenar of the non-handedness site of these subjects was measured using a thermostimulator (Intercross-200, Intercross Co., Tokyo, Japan). The peripheral blood flow in the finger of the non-handedness site of these subjects was measured using a full-field laser perfusion imager (FLPI, Moor Instruments Ltd., England). Control: The vehicle had no significant effect on the warm sense threshold, cold sense threshold and the peripheral blood flow. TJ-107: The warm sense threshold and cold sense threshold were significantly decreased, and the reaction latency of cold sense was significantly shortening. The peripheral blood flow was significantly increased second and third finger at 115.6%, 119.3%, respectively. TJ-38: The cold sense threshold and the reaction latency of cold sense were significantly increased. The peripheral blood flow was significantly increased second and third finger with 114.3%, 112.8%, respectively. These results suggest that TJ-107 and TJ-38 have effects on the changed warm sense threshold, cold sense threshold and increased peripheral blood flow.展开更多
A novel vapor-liquid distributor was developed on the basis of sufficient study on the existing distributors applied in hydroprocessing reactors. The cold model test data showed that the fluid distribution performance...A novel vapor-liquid distributor was developed on the basis of sufficient study on the existing distributors applied in hydroprocessing reactors. The cold model test data showed that the fluid distribution performance of the novel vapor-liquid distributor was evidently better than the traditional one. Com- mercial tests of the new distributor were carded out in the 300 kt/a gas oil hydrotreating reactor at SINOPEC Changling Branch Company, showing that the new vapor-liquid distributor could improve the fluid distribution, promote the hydrotreating efficiency and lead to better performance than the traditional one.展开更多
To further improve the performance of acceler-ators,the first cryogenic normal-conducting RF gun in China was designed and manufactured.As a new and attractive trend,this optimized cryogenic RF gun can generate a low-...To further improve the performance of acceler-ators,the first cryogenic normal-conducting RF gun in China was designed and manufactured.As a new and attractive trend,this optimized cryogenic RF gun can generate a low-emittance beam with a short-driven laser pulse because of its promising high gradient on the cath-ode.In this paper,optimization of the RF design and beam dynamics,including suppression of the peak RF field and elimination of the multipole mode,is presented.In addi-tion,the emittance growth caused by the alignment devi-ation and RF jitter is discussed.After the gun was manufactured,a cold test was conducted at both room temperature and cryogenic conditions.At room tempera-ture,the field distribution was obtained by the bead pull method.Under cryogenic conditions,the RF properties,such as the coupling coefficient and quality factor,varied with temperature.The test results agreed with the design.In the cryogenic test,vibration measurements were performed.Without vibration isolation,a maximum vibration of 50 lm was observed.These cold test results are the basis of the following high-power test.展开更多
Gas Transmitting From West to East Project' is significant. It should ensure the welding quality and safety of pipeline. The task is very arduous to guarantee the quality of the project in the condition of long li...Gas Transmitting From West to East Project' is significant. It should ensure the welding quality and safety of pipeline. The task is very arduous to guarantee the quality of the project in the condition of long line, complex weather and geology features. In this paper, the welding cold cracking susceptibility of domestic X 70 pipeline steel adopted by the project, which is one of the most interesting questions of welding quality about petrol pipeline, was studied by means of oblique Y groove cracking test. The crack ratio of surface and section was tested under the conditions of different welding materials and preheat temperature .The thickness of plate steel was 14.7 mm and 10.3 mm . The results reveal that X 70 pipeline steel has good crack resistance. The research has important value for the construction of large scale pipeline engineering and the application of domestic X 70 pipeline steel.展开更多
[Objective] The research aimed to study the possible mechanism of terrain effect on cold-flow snowstorm.[Method] By using the meso-scale numerical model(WRF),a cold-flow snowstorm weather process in Shandong Peninsula...[Objective] The research aimed to study the possible mechanism of terrain effect on cold-flow snowstorm.[Method] By using the meso-scale numerical model(WRF),a cold-flow snowstorm weather process in Shandong Peninsula was carried out numerical simulation and terrain sensitivity contrast test.The possible reason of terrain effect on falling zone and strength of snowstorm was deeply analyzed from water vapor,thermodynamic field and so on.[Result] The mountain terrain in Shandong Peninsula had great influences on falling zone and strength of cold-flow snowstorm.The strength of snowstorm obviously increased,and the snowfall center obviously moved northward.The main reason was that terrain caused the low-level wind field convergence and vertical movement in the troposphere strengthened.Then,the spatial distribution of water vapor and snow water content in the cold-flow snowstorm process obviously changed.So,the whole snowstorm process was affected.[Conclusion] The mountain terrain in Shandong Peninsula was the important element which needed to be focused on considering in the forecast analysis of cold-flow snowstorm weather process.展开更多
An experimental setup for cold extrusion process with electric-hydraulic chattering was developed and its working principle was introduced. The finite element （FE） model for a kind of cup part （material： 20Cr） wa...An experimental setup for cold extrusion process with electric-hydraulic chattering was developed and its working principle was introduced. The finite element （FE） model for a kind of cup part （material： 20Cr） was built by using the software Deform-3D. FE simulation experiments with and without electric-hydraulic chattering were carried out to analyze the velocity fields and the metal grid flow lines. The extrusion ex- periments of the cup part were also performed under different conditions. The difference of metal flow lines with and without electric-hydraulic chattering was discussed via a scanning electron microscope （SEM） and the Keyence super-depth three-dimensional microscopic system. The results showed that with the electric-hydraulic chattering, the velocity of material flow increases, whereas deformation resistance decreases. Electric hydraulic chattering results in easy metal flow, small bending degree of metal flow lines, slender and dense metal grains, and thereby an improved quality of the deformed parts.展开更多
The high effective nano-hybrid pour point depressant(PPD)has attracted extensive attention for its po-tential application in improving the cold flow properties of diesel fuel.In this paper,the nano-hybrid PPD was prep...The high effective nano-hybrid pour point depressant(PPD)has attracted extensive attention for its po-tential application in improving the cold flow properties of diesel fuel.In this paper,the nano-hybrid PPD was prepared by melt-blending method using three different alkyl chain lengths(i.e.,tetradecyl,hexade-cyl,and octodecyl)of n-alkyl methacrylate-maleic anhydride copolymers(R 1 MC-MA,R 1=C_(14),C_(16),C_(18))and SiO_(2)nanoparticles.The effect of those nano-hybrid PPDs on the cold filter plugging point(CFPP)and solidifying point(SP)depressing of diesel fuel were studied.Results indicated that nano-hybrid PPD showed much better performance on diesel fuel.The diesel fuel treated with 0.2 wt%C_(14)MC-MA/SiO_(2)nano-hybrid PPD exhibited the best depression in CFPP and SP by 6℃ and 18℃,respectively,which higher than that of single C 14 MC-MA.Viscosity-temperature curves and polarized optical microscopy were conducted to explore the performance mechanism;and results presented that nano-hybrid PPD of C_(14)MC-MA/SiO_(2)could effectively lower the low-temperature viscosity,and modify the crystallization behavior and crystal morphology of diesel.Therefore,the cold flow properties of diesel were significantly improved.展开更多
In order to solve the problem of property test of large flow-rate safety, the property parameter of safety valve test system was analyzed, and a device for property oflarge flow-rate safety valve test was designed.The...In order to solve the problem of property test of large flow-rate safety, the property parameter of safety valve test system was analyzed, and a device for property oflarge flow-rate safety valve test was designed.The device used accumulators as power source and a united function cylinder, which can realized the large flow-rate output for the test system.Analyzed the test data and made a particular research on the test device by testing different flow-rate safety valves;it verifies that the test device can be used tode-sign larger flow-rate safety valve test system and can make the flow-rate test and analysis and dynamic characteristics for the large-flow safety valve.展开更多
文摘In this paper, cold simulation experiments and numerical calculations are conducted to predict 3 D flow field aerodynamics for an oil furnace after being retrofitted due to its fuel variation. K ε model and SIMPLE program under body fit coordination (BFC) system, in which TTM non orthogonal method is used to control the irregular geometric boundary, are adopted to solve the control equations. Model tests are conducted to check the calculation results, showing that they are in agreement with each other. Three different alternatives with different side window locations are also calculated to optimize the designs. The field retrofitting results show that the combination of cold tests with numerical calculations has prosperous application in retrofitting or renewing medium and small boilers.
基金supported from the Natural Science Foundation Project of Shanghai(Nos.23ZR1425300 and 22ZR1426100)Experimental Technical Team Construction Project of Shanghai Education Commission(No.10110N230080)+1 种基金National Natural Science Foundation of China(No.22075183)Research and Innovation Project of Shanghai Municipal Education Commission(No.2023ZKZD54).
文摘The addition of cold flow improvers(CFIs)is considered as the optimum strategy to improve the cold flow properties(CFPs)of diesel fuels,but this strategy is always limited by the required large dosage.To obtain low-dosage and high-efficiency CFIs for diesel,1,2,3,6-tetrahydrophthalic anhydride(THPA)was introduced as a third and polar monomer to enhance the depressive effects of alkyl methacrylatetrans anethole copolymers(C_(14)MC-TA).The terpolymers of alkyl methacrylate-trans anethole-1,2,3,6-tetrahydrophthalic anhydride(C_(14)MC-TA-THPA)were synthesized and compared with the binary copolymers of C_(14)MC-TA and alkyl methacrylate-1,2,3,6-tetrahydrophthalic anhydride(C_(14)MC-THPA).Results showed that C_(14)MC-THPA achieved the best depressive effects on the cold filter plugging point(CFPP)and solid point(SP)by 11℃and 16℃at a dosage of 1250 mg/L and monomer ratio of 6:1,while 1500mg/L C_(14)MC-TA(1:1)reached the optimal depressive effects on the CFPP and SP by 12℃and 18℃.THPA introduction significantly improved the depressive effects of C_(14)MC-TA.Lower dosages of C_(14)MCTA-THPA in diesel exerted better improvement effects on the CFPP and SP than that of C_(14)MC-TA and C_(14)MC-THPA.When the monomer ratio and dosage were 6:0.6:0.4 and 1000 mg/L,the improvement effect of C_(14)MC-TA-THPA on diesel reached the optimum level,and the CFPP and SP were reduced by 13℃and 19℃,respectively.A 3D nonlinear surface diagram fitted by a mathematical model was also used for the first time to better understand the relationships of monomer ratios,dosages,and depressive effects of CFIs in diesel.Surface analysis results showed that C_(14)MC-TA-THPA achieved the optimum depressive effects at a monomer ratio of 6:0.66:0.34 and dosage of 1000 mg/L,and the CFPP and SP decreased by 14℃ and 19℃,respectively.The predicted results were consistent with the actual ones.Additionally,the improvement mechanism of these copolymers in diesel was also explored.
基金supported by the National Natural Science Foundation of China(Nos.U23A20583,52033005,U21A2090,and 52173040)Department of Science and Technology of Sichuan Province(No.2024NSFTD0003)。
文摘Poly(_(L)-lactide)(PLLA),a leading biodegradable polyester,has demonstrated potential as a sustainable alternative,owing to its excellent biodegradability and rigidity.However,their slow crystallization kinetics and poor heat resistance limit their application scope.Recent advances have highlighted that the combination of extensional flow and thermal fields can achieve toughness–stiffness balance,high transparency,and good heat resistance.However,the effect of extensional flow on the post-non-isothermal crystallization of PLLA during heating and the resulting crystalline texture remains unclear.In this study,PLLA with a heterogeneous amorphous structure and oriented polymorph was prepared by extensional flow.The effect of heterogeneous amorphous structures on non-isothermal crystallization kinetics during the heating process was studied by thermal analysis,polarized optical microscopy,infrared spectroscopy,and ex situ/in situ X-ray characterization.These results clearly illustrate that extensional flow enhances the formation of oriented crystalline structures,accelerates non-isothermal crystallization,and modulates the polymorphic composition of PLLA.Moreover,an unexpected dual cold-crystallization behavior is identified in ordered PLLA samples upon extensional flow,which is from the extensional flow-induced heterogeneous amorphous phase into α' phase(low-temperature peak)and the pristine amorphous phase intoαphase(high-temperature peak).The extensional flow primarily promotes the formation of the more perfectαandα'phases,but has a negative effect on the final content ofαphase formed after cold crystallization andα'-to-αphase transformation.The findings of this work advance the understanding of PLLA non-isothermal crystallization after extensional flow and offer valuable guidance for high-performance PLLA upon heat treatment in practical processing.
基金supported by the National Natural Science Foundation of China (Nos.22234005,22494632,22404081)the Natural Science Foundation of Jiangsu Province (Nos.BK20222015,BK20240534)。
文摘Detecting biomarkers in body fluids by optical lateral flow immune assay(LFIA) technology provides rapid access to disease information for early diagnosis.LFIA is based on an antigen-antibody reaction and is rapidly becoming the preferred choice of physicians and patients for point-of-care testing due to its simplicity,cost-effectiveness,and rapid detection.Observing the optical signal change from the colloidal gold of the traditional LFIA strip has been widely applied for various biomarkers detection in body fluids.Despite the significant progress,rapid real-time detection of color changes in the colloidal gold by the naked eye still faces many limitations,such as large errors and the inability to quantify and accurately detect.New optical LFIA strip technology has emerged in recent years to extend its application scenarios for achieving quantitative detection such as fluorescence,afterglow,and chemiluminescence.Herein,we summarized the development of optical LFIA technology from single to hyphenated optical signals for biomarkers detection in body fluids from invasive and non-invasive sources.Moreover,the challenge and outlook of optical LFIA strip technology are highlighted to inspire the designing of next-generation diagnostic platforms.
基金Projects(51175363,51274149)supported by the National Natural Science Foundation of China
文摘Based on the design of the multi-row sprocket with a new tooth profile,a cold semi-precision forging process for manufacturing 5052 aluminum alloy multi-row sprocket was presented.Through simulating the forging process of 5052 aluminum alloy sprocket billet with 3D rigid-viscoplastic FEM,both the distributions of flow velocity field in axial(U_Z),radial(U_R) and circumferential(U_θ) directions and the curves of velocity component in different deformation regions were respectively obtained.By comparison and analysis of the velocity varying curves,the velocity component relation conditions for filling the die cavity were clarified.It shows that when the die cavity is almost fully filled,the circumferential velocity U_θ increases sharply,implying that U_θplays a key role in fully filling the die cavity.
基金Supported by National Basic Research Program of China(973 Program,Grant No.2014CB046403)National Key Technology R&D Program of the Twelfth Five-year Plan of China(Grant No.2013BAF07B01)
文摘The current research about the flow ripple of axial piston pump mainly focuses on the effect of the structure of parts on the flow ripple. Therein, the structure of parts are usually designed and optimized at rated working conditions. However, the pump usually has to work in large-scale and time-variant working conditions. Therefore, the flow ripple characteristics of pump and analysis for its test accuracy with respect to variant steady-state conditions and transient conditions in a wide range of operating parameters are focused in this paper. First, a simulation model has been constructed, which takes the kinematics of oil film within friction pairs into account for higher accuracy. Afterwards, a test bed which adopts Secondary Source Method is built to verify the model. The simulation and tests results show that the angular position of the piston, corresponding to the position where the peak flow ripple is produced, varies with the different pressure. The pulsating amplitude and pulsation rate of flow ripple increase with the rise of pressure and the variation rate of pressure. For the pump working at a constant speed, the flow pulsation rate decreases dramatically with the increasing speed when the speed is less than 27.78% of the maximum speed, subsequently presents a small decrease tendency with the speed further increasing. With the rise of the variation rate of speed, the pulsating amplitude and pulsation rate of flow ripple increase. As the swash plate angle augments, the pulsating amplitude of flow ripple increases, nevertheless the flow pulsation rate decreases. In contrast with the effect of the variation of pressure, the test accuracy of flow ripple is more sensitive to the variation of speed. It makes the test accuracy above 96.20% available for the pulsating amplitude of pressure deviating within a range of ~6% from the mean pressure. However, with a variation of speed deviating within a range of ±2% from the mean speed, the attainable test accuracy of flow ripple is above 93.07%. The model constructed in this research proposes a method to determine the flow ripple characteristics of pump and its attainable test accuracy under the large-scale and time-variant working conditions. Meanwhile, a discussion about the variation of flow ripple and its obtainable test accuracy with the conditions of the pump working in wide operating ranges is given as well.
基金Supported by the Basic Research Program of the State Key Laboratory of Heavy Oil Processing (200310) China University of Petroleum,Beijing,China
文摘Synthesis of a cold flow improver （MAVA-a） for diesel fuel and its effect on solidifying point （SP） and cold filter plugging point （CFPP） of diesel fuels were investigated, The cold flow improver was prepared by using maleic anhydride （MA） and vinyl acetate （VA） as raw materials, toluene as solvent, dibenzoyl peroxide （BPO） as initiator, through alternating polymerization under nitrogen to obtain a binary-polymer and then through aminolysis by using a higher carbon amine as aminating agent at a temperature of 80 ℃. A cold flow improver was designed and prepared for No. 0 diesel fuel from Zhang Jia-Gang Petrochemical Company according to the contents of n-paraffin and its carbon number distribution in the No. 0 diesel fuel. It was also used together with two kinds of ethene-vinyl acetate copolymer improvers （EVA） separately. The test result showed that the CFPP of the No. 0 diesel fuel could be lowered by 3-5 ℃ when the improver MAVA-a was used. The CFPP was lowered by 8℃ when the improver MAVA-a was used together with EVA-2.
基金Project (2011CB605504) supported by the National Basic Research Program of China
文摘Numerical investigations on the flow field in Ti-Al melt during rectangular cold crucible directional solidification were carried out. Combined with the experimental results, 3-D finite element models for calculating flow field inside melting pool were established, the characteristics of the flow under different power parameters were further studied. Numerical calculation results show that there is a complex circular flow in the melt, a rapid horizontal flow exists on the solid/liquid interface and those flows confluence in the center of the melting pool. The flow velocity v increases with the increase of current intensity, but the flow patterns remain unchanged. When the current is 1000 A, the vmax reaches 4 mm/s and the flow on the interface achieves 3 mm/s. Flow patterns are quite different when the frequency changes from 10 kHz to 100 kHz, the mechanism of the frequency influence on the flow pattern is analyzed, and there is an optimum frequency for cold crucible directional solidification.
基金supported by National Outstanding Young Scientists Founds of China (Grant No. 50825902)National Key Technology R&D Program of China (Grant No. 2008BAF34B15)+2 种基金National Natural Science Foundation of China (Grant No. 51079062)Jiangsu Provincial 333 High-level Personal Training Project of ChinaJiangsu Provincial Six Talent Peak of China
文摘The double blade pump is widely used in sewage treatment industry,however,the research on the internal flow characteristics of the double blade pump with particle image velocimetry（PIV） technology is very little at present.To reveal inner flow characteristics in double blade pump impeller under off-design and design conditions,inner flows in a double blade pump impeller,whose specific speed is 111,are measured under the five off-design conditions and design condition by using 3D PIV test technology.In order to ensure the accuracy of the 3D PIV test,the external trigger synchronization system which makes use of fiber optic and equivalent calibration method are applied.The 3D PIV relative velocity synthesis procedure is compiled by using Visual C＋＋ 2005.Then absolute velocity distribution and relative velocity distribution in the double blade pump impeller are obtained.Test results show that vortex exists in each condition,but the location,size and velocity of vortex core are different.Average absolute velocity value of impeller outlet increases at first,then decreases,and then increases again with increase of flow rate.Again average relative velocity values under 0.4,0.8,and 1.2 design condition are higher than that under 1.0 design condition,while under 0.6 and 1.4 design condition it is lower.Under low flow rate conditions,radial vectors of absolute velocities at impeller outlet and blade inlet near the pump shaft decrease with increase of flow rate,while that of relative velocities at the suction side near the pump shaft decreases.Radial vectors of absolute velocities and relative velocities change slightly under the two large flow rate conditions.The research results can be applied to instruct the hydraulic optimization design of double blade pumps.
基金This work was supported by the Alliance of International Science Organizations(No.ANSO-CR-KP-2020-16).
文摘An S-band high-gradient accelerating structure is designed for a proton therapy linear accelerator(linac)to accommodate the new development of compact,singleroom facilities and ultra-high dose rate(FLASH)radiotherapy.To optimize the design,an efficient optimization scheme is applied to improve the simulation efficiency.An S-band accelerating structure with 2856 MHz is designed with a low beta of 0.38,which is a difficult structure to achieve for a linac accelerating proton particles from 70 to 250 MeV,as a high gradient up to 50 MV/m is required.A special design involving a dual-feed coupler eliminates the dipole field effect.This paper presents all the details pertaining to the design,fabrication,and cold test results of the S-band high-gradient accelerating structure.
文摘On December 3-5,2008,a cold flow snowfall happened in Shandong Peninsula.The basic weather situation and environmental field were analyzed.The results showed that the terrain condition,water vapor's latent heat-exchange in Bo Sea,temperature differences between sea and land were very important elements in this process.
文摘The purpose of this study was to investigate the effects of a traditional Japanese medicine Goshajinkigan (TJ-107) and Tokishigyakukagoshuyushokyoto (TJ-38) on warm sense threshold, cold sense threshold and the peripheral blood flow. 31 healthy volunteers (control group: 9people, TJ-107 group: 12 people, TJ-38group:10 people) were examined. Drugs administered 2.5 g a dose. Analysis was before and after 1 hour dosage. The warm and cold sense threshold in the thenar of the non-handedness site of these subjects was measured using a thermostimulator (Intercross-200, Intercross Co., Tokyo, Japan). The peripheral blood flow in the finger of the non-handedness site of these subjects was measured using a full-field laser perfusion imager (FLPI, Moor Instruments Ltd., England). Control: The vehicle had no significant effect on the warm sense threshold, cold sense threshold and the peripheral blood flow. TJ-107: The warm sense threshold and cold sense threshold were significantly decreased, and the reaction latency of cold sense was significantly shortening. The peripheral blood flow was significantly increased second and third finger at 115.6%, 119.3%, respectively. TJ-38: The cold sense threshold and the reaction latency of cold sense were significantly increased. The peripheral blood flow was significantly increased second and third finger with 114.3%, 112.8%, respectively. These results suggest that TJ-107 and TJ-38 have effects on the changed warm sense threshold, cold sense threshold and increased peripheral blood flow.
文摘A novel vapor-liquid distributor was developed on the basis of sufficient study on the existing distributors applied in hydroprocessing reactors. The cold model test data showed that the fluid distribution performance of the novel vapor-liquid distributor was evidently better than the traditional one. Com- mercial tests of the new distributor were carded out in the 300 kt/a gas oil hydrotreating reactor at SINOPEC Changling Branch Company, showing that the new vapor-liquid distributor could improve the fluid distribution, promote the hydrotreating efficiency and lead to better performance than the traditional one.
基金supported by the National Key R&D Program of China(No.2018YFF0109203)ANSO(ANSO-CR-KP-2020-16).
文摘To further improve the performance of acceler-ators,the first cryogenic normal-conducting RF gun in China was designed and manufactured.As a new and attractive trend,this optimized cryogenic RF gun can generate a low-emittance beam with a short-driven laser pulse because of its promising high gradient on the cath-ode.In this paper,optimization of the RF design and beam dynamics,including suppression of the peak RF field and elimination of the multipole mode,is presented.In addi-tion,the emittance growth caused by the alignment devi-ation and RF jitter is discussed.After the gun was manufactured,a cold test was conducted at both room temperature and cryogenic conditions.At room tempera-ture,the field distribution was obtained by the bead pull method.Under cryogenic conditions,the RF properties,such as the coupling coefficient and quality factor,varied with temperature.The test results agreed with the design.In the cryogenic test,vibration measurements were performed.Without vibration isolation,a maximum vibration of 50 lm was observed.These cold test results are the basis of the following high-power test.
文摘Gas Transmitting From West to East Project' is significant. It should ensure the welding quality and safety of pipeline. The task is very arduous to guarantee the quality of the project in the condition of long line, complex weather and geology features. In this paper, the welding cold cracking susceptibility of domestic X 70 pipeline steel adopted by the project, which is one of the most interesting questions of welding quality about petrol pipeline, was studied by means of oblique Y groove cracking test. The crack ratio of surface and section was tested under the conditions of different welding materials and preheat temperature .The thickness of plate steel was 14.7 mm and 10.3 mm . The results reveal that X 70 pipeline steel has good crack resistance. The research has important value for the construction of large scale pipeline engineering and the application of domestic X 70 pipeline steel.
基金Supported by Special Item of Public Welfare Industry (Meteorology)Science Research (GYHY201106006)Special Item of Forecaster of China Meteorological Administration (CMATG2007Y08)Key Topics of Shandong Meteorological Bureau (2010sdqxz10)
文摘[Objective] The research aimed to study the possible mechanism of terrain effect on cold-flow snowstorm.[Method] By using the meso-scale numerical model(WRF),a cold-flow snowstorm weather process in Shandong Peninsula was carried out numerical simulation and terrain sensitivity contrast test.The possible reason of terrain effect on falling zone and strength of snowstorm was deeply analyzed from water vapor,thermodynamic field and so on.[Result] The mountain terrain in Shandong Peninsula had great influences on falling zone and strength of cold-flow snowstorm.The strength of snowstorm obviously increased,and the snowfall center obviously moved northward.The main reason was that terrain caused the low-level wind field convergence and vertical movement in the troposphere strengthened.Then,the spatial distribution of water vapor and snow water content in the cold-flow snowstorm process obviously changed.So,the whole snowstorm process was affected.[Conclusion] The mountain terrain in Shandong Peninsula was the important element which needed to be focused on considering in the forecast analysis of cold-flow snowstorm weather process.
文摘An experimental setup for cold extrusion process with electric-hydraulic chattering was developed and its working principle was introduced. The finite element （FE） model for a kind of cup part （material： 20Cr） was built by using the software Deform-3D. FE simulation experiments with and without electric-hydraulic chattering were carried out to analyze the velocity fields and the metal grid flow lines. The extrusion ex- periments of the cup part were also performed under different conditions. The difference of metal flow lines with and without electric-hydraulic chattering was discussed via a scanning electron microscope （SEM） and the Keyence super-depth three-dimensional microscopic system. The results showed that with the electric-hydraulic chattering, the velocity of material flow increases, whereas deformation resistance decreases. Electric hydraulic chattering results in easy metal flow, small bending degree of metal flow lines, slender and dense metal grains, and thereby an improved quality of the deformed parts.
基金supported by the National Natural Science Foundation of China(Nos.22008155,22075183,21878188 and 21975161)Chenguang Program of Shanghai Education Devel-opment Foundation and Shanghai Municipal Education Commis-sion(No.19CG69).
文摘The high effective nano-hybrid pour point depressant(PPD)has attracted extensive attention for its po-tential application in improving the cold flow properties of diesel fuel.In this paper,the nano-hybrid PPD was prepared by melt-blending method using three different alkyl chain lengths(i.e.,tetradecyl,hexade-cyl,and octodecyl)of n-alkyl methacrylate-maleic anhydride copolymers(R 1 MC-MA,R 1=C_(14),C_(16),C_(18))and SiO_(2)nanoparticles.The effect of those nano-hybrid PPDs on the cold filter plugging point(CFPP)and solidifying point(SP)depressing of diesel fuel were studied.Results indicated that nano-hybrid PPD showed much better performance on diesel fuel.The diesel fuel treated with 0.2 wt%C_(14)MC-MA/SiO_(2)nano-hybrid PPD exhibited the best depression in CFPP and SP by 6℃ and 18℃,respectively,which higher than that of single C 14 MC-MA.Viscosity-temperature curves and polarized optical microscopy were conducted to explore the performance mechanism;and results presented that nano-hybrid PPD of C_(14)MC-MA/SiO_(2)could effectively lower the low-temperature viscosity,and modify the crystallization behavior and crystal morphology of diesel.Therefore,the cold flow properties of diesel were significantly improved.
基金Supported by China Coal Research Institute Innovation Item(2007CX06)
文摘In order to solve the problem of property test of large flow-rate safety, the property parameter of safety valve test system was analyzed, and a device for property oflarge flow-rate safety valve test was designed.The device used accumulators as power source and a united function cylinder, which can realized the large flow-rate output for the test system.Analyzed the test data and made a particular research on the test device by testing different flow-rate safety valves;it verifies that the test device can be used tode-sign larger flow-rate safety valve test system and can make the flow-rate test and analysis and dynamic characteristics for the large-flow safety valve.
