This research aims to study the bio-adsorption process of two dyes,Cibacron Green H3G(CG-H3G)and Terasil Red(TR),in a single system and to bring them closer to the industrial textile discharge by a binary mixture of t...This research aims to study the bio-adsorption process of two dyes,Cibacron Green H3G(CG-H3G)and Terasil Red(TR),in a single system and to bring them closer to the industrial textile discharge by a binary mixture of two dyes(TR+CG-H3G).The Cockle Shell(CS)was used as a natural bio-adsorbent.The characterizations of CS were investigated by Fourier transform infrared(FTIR),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDX)and Brunauer–Emmett–Teller(BET).The adsorption potential of Cockle Shells was tested in two cases(single and binary system)and determined by:contact time(0–60 min),bio-adsorption dose(3–15 g/L),initial concentration(10–300 mg/L),temperature(22–61°C)and pH solution(2–12).The study of bio-adsorption(equilibrium and kinetics)was conducted at 22°C.The kinetic studies demon-strated that a pseudo-second-order adsorption mechanism had a good correlation coefficient(R2≥0.999).The Langmuir isotherm modeling provided a well-defined description of TR and CG-H3G bio-adsorption on cockle shells,exhibiting maximum capacities of 29.41 and 3.69 mg/g respectively at 22°C.The thermodynamic study shows that the reaction between the TR,CG-H3G dyes molecules and the bio-adsorbent is exothermic,spontaneous in the range of 22–31°C with the aleatory character decrease at the solid-liquid interface.The study of selectivity in single and binary systems has been performed under optimal operating conditions using the industrial textile rejection pH(pH=6.04).CG-H3G dye is found to have a higher selectivity than TR in single(0–60 min)and binary systems with a range of 6–45 min,as shown by the selectivity measurement.It was discovered that CS has the capability to remove both CG-H3G and TR dyes in both simple and binary systems,making it a superior bio-adsorbent.展开更多
Study on coastal processes in Kapar waters was conducted from 2008-2016.The aim of this study is to identify potential blood cockle(Anadara granosa)induce spawning ground based on physical intermittency.A total of 132...Study on coastal processes in Kapar waters was conducted from 2008-2016.The aim of this study is to identify potential blood cockle(Anadara granosa)induce spawning ground based on physical intermittency.A total of 132 sampling stations were recorded.A thermal power station situated 2 km away is discharging treated warm water(<40℃)on to the open sea causing the Sea Surface Temperature at near-by cockle culture to intermittent between 31-34℃ while the temperature at the bottom(at 6-8 m Mean Sea Level,MSL)is constant between 29.5℃ and 30.5℃.The results suggested that Kapar waters have two seasons of low waters annually(January-March and June-September,respectively)and the Lowest Astronomical Tide(LAT)occur in late January-February while Great Diurnal Tide is observed on the same period.The bathymetry suggested the present of deep water(6-8 m,MSL)towards the end of cockle culture lot which is closed to merchant shipping lane near Port Klang.Based on water elevation,an area of 255.4 ha within cockle culture lots were identified to have this bottom temperature intermittency(29.5-34.0℃)during its GT and it associated with cockle induce spawning condition.But this area was left out for cockle culture due to its typical depth(>3 m MSL)which prevents cockle farmers from harvesting due to their maximum of 3 m long hand dredge.Thus,this information could be useful for cockle sustainable management plan in near future.展开更多
基金supported by the University Salah Boubnider-Constantine 3 (Algeria).
文摘This research aims to study the bio-adsorption process of two dyes,Cibacron Green H3G(CG-H3G)and Terasil Red(TR),in a single system and to bring them closer to the industrial textile discharge by a binary mixture of two dyes(TR+CG-H3G).The Cockle Shell(CS)was used as a natural bio-adsorbent.The characterizations of CS were investigated by Fourier transform infrared(FTIR),X-ray diffraction(XRD),scanning electron microscopy(SEM),energy-dispersive X-ray spectroscopy(EDX)and Brunauer–Emmett–Teller(BET).The adsorption potential of Cockle Shells was tested in two cases(single and binary system)and determined by:contact time(0–60 min),bio-adsorption dose(3–15 g/L),initial concentration(10–300 mg/L),temperature(22–61°C)and pH solution(2–12).The study of bio-adsorption(equilibrium and kinetics)was conducted at 22°C.The kinetic studies demon-strated that a pseudo-second-order adsorption mechanism had a good correlation coefficient(R2≥0.999).The Langmuir isotherm modeling provided a well-defined description of TR and CG-H3G bio-adsorption on cockle shells,exhibiting maximum capacities of 29.41 and 3.69 mg/g respectively at 22°C.The thermodynamic study shows that the reaction between the TR,CG-H3G dyes molecules and the bio-adsorbent is exothermic,spontaneous in the range of 22–31°C with the aleatory character decrease at the solid-liquid interface.The study of selectivity in single and binary systems has been performed under optimal operating conditions using the industrial textile rejection pH(pH=6.04).CG-H3G dye is found to have a higher selectivity than TR in single(0–60 min)and binary systems with a range of 6–45 min,as shown by the selectivity measurement.It was discovered that CS has the capability to remove both CG-H3G and TR dyes in both simple and binary systems,making it a superior bio-adsorbent.
文摘Study on coastal processes in Kapar waters was conducted from 2008-2016.The aim of this study is to identify potential blood cockle(Anadara granosa)induce spawning ground based on physical intermittency.A total of 132 sampling stations were recorded.A thermal power station situated 2 km away is discharging treated warm water(<40℃)on to the open sea causing the Sea Surface Temperature at near-by cockle culture to intermittent between 31-34℃ while the temperature at the bottom(at 6-8 m Mean Sea Level,MSL)is constant between 29.5℃ and 30.5℃.The results suggested that Kapar waters have two seasons of low waters annually(January-March and June-September,respectively)and the Lowest Astronomical Tide(LAT)occur in late January-February while Great Diurnal Tide is observed on the same period.The bathymetry suggested the present of deep water(6-8 m,MSL)towards the end of cockle culture lot which is closed to merchant shipping lane near Port Klang.Based on water elevation,an area of 255.4 ha within cockle culture lots were identified to have this bottom temperature intermittency(29.5-34.0℃)during its GT and it associated with cockle induce spawning condition.But this area was left out for cockle culture due to its typical depth(>3 m MSL)which prevents cockle farmers from harvesting due to their maximum of 3 m long hand dredge.Thus,this information could be useful for cockle sustainable management plan in near future.
