Carbon nanotubes(CNTs)supported CoB and CoBSn catalysts were synthesized for hydrogen production via NaBH4 hydrolysis.The roles of Sn-promoter and the effect of CNTs treatment on CoB catalysts were evaluated and discu...Carbon nanotubes(CNTs)supported CoB and CoBSn catalysts were synthesized for hydrogen production via NaBH4 hydrolysis.The roles of Sn-promoter and the effect of CNTs treatment on CoB catalysts were evaluated and discussed.It is found that after the addition of Sn promoter,the specific surface area and the generation of active CoB phase are increased,while the oxidation treatment of CNTs results in more loading amounts of active components and enrichment of electron at active sites as well as large surface area.Consequently,the Sn-doped CoB catalysts supported on CNTs with oxidation treatment exhibits a significantly improved activity with a high H_(2)generation rate of 2640 mL/(min·g).Meanwhile,this catalyst shows a low activation energy of 43.7 kJ/mol and relatively high reusability.展开更多
针对LED高光效、低功耗的要求,在分析LED光学性能的基础上,采用了COB（chip on board）即板上芯片封装技术。研究了不同电流下和点亮不同时间后,分析其LED光通量、光效和色温。研究分析影响LED光学性能的因素并进行测试。结果表明,用两...针对LED高光效、低功耗的要求,在分析LED光学性能的基础上,采用了COB（chip on board）即板上芯片封装技术。研究了不同电流下和点亮不同时间后,分析其LED光通量、光效和色温。研究分析影响LED光学性能的因素并进行测试。结果表明,用两种色温接近3 000 K的样品,电流由500 m A增大到900 m A,色温升高了1.685%、2.626%,光通量也随着电流的变大而升高68.532%、84.625%,但相反光效却降低了13.535%、9.971%;而在电流保持不变的情况下,点亮的时间由0~1 min、0~5 min、0~10 min,其色温分别上升了0.537%、1.209%、2.384%;0.369%、1.104%、2.943%,同时,光通量分别降低1.474%、4.855%、7.493%;2.073%、3.859%、7.793%,光效也分别降低2.527%、4.617%、6.671%;2.171%、4.903%、7.579%。实验发现,电流与点亮时间直接影响LED光学性能。展开更多
基金supported by National Natural Science Foundation of China(22276144).
文摘Carbon nanotubes(CNTs)supported CoB and CoBSn catalysts were synthesized for hydrogen production via NaBH4 hydrolysis.The roles of Sn-promoter and the effect of CNTs treatment on CoB catalysts were evaluated and discussed.It is found that after the addition of Sn promoter,the specific surface area and the generation of active CoB phase are increased,while the oxidation treatment of CNTs results in more loading amounts of active components and enrichment of electron at active sites as well as large surface area.Consequently,the Sn-doped CoB catalysts supported on CNTs with oxidation treatment exhibits a significantly improved activity with a high H_(2)generation rate of 2640 mL/(min·g).Meanwhile,this catalyst shows a low activation energy of 43.7 kJ/mol and relatively high reusability.
文摘针对LED高光效、低功耗的要求,在分析LED光学性能的基础上,采用了COB（chip on board）即板上芯片封装技术。研究了不同电流下和点亮不同时间后,分析其LED光通量、光效和色温。研究分析影响LED光学性能的因素并进行测试。结果表明,用两种色温接近3 000 K的样品,电流由500 m A增大到900 m A,色温升高了1.685%、2.626%,光通量也随着电流的变大而升高68.532%、84.625%,但相反光效却降低了13.535%、9.971%;而在电流保持不变的情况下,点亮的时间由0~1 min、0~5 min、0~10 min,其色温分别上升了0.537%、1.209%、2.384%;0.369%、1.104%、2.943%,同时,光通量分别降低1.474%、4.855%、7.493%;2.073%、3.859%、7.793%,光效也分别降低2.527%、4.617%、6.671%;2.171%、4.903%、7.579%。实验发现,电流与点亮时间直接影响LED光学性能。
