The Jurassic coal-measure source rocks in the Junggar Basin have drawn considerable attention in recent years. In our hydrocarbon thermal simulation experiments of these rocks, we found that the dark mudstone evaluate...The Jurassic coal-measure source rocks in the Junggar Basin have drawn considerable attention in recent years. In our hydrocarbon thermal simulation experiments of these rocks, we found that the dark mudstone evaluated as good source rock, had a much lower hydrocarbon generation capacity than the coal and carbonaceous mudstone, evaluated as poor source rock. Based on this background, we performed Fourier transform infrared spectroscopy(FTIR) and combined the results of semi-open thermal simulation experiments to explore the association between the molecular structure and hydrocarbon production capacity, with the aim of obtaining a new understanding of hydrocarbon potential of Jurassic coal-measure source rocks from the perspective of molecular structure. The results indicate that coals exhibit lower condensation of aromatic structures and higher relative abundance of aliphatic structures with a higher degree of branched chaining than mudstones and carbonaceous mudstones. Apparent aromaticity(f_a), aromatic abundance parameter I, and degree of condensation(DOC) are negatively correlated with organic matter abundance. The aliphatic structural parameter H demonstrates a substantial positive correlation with organic matter abundance. Furthermore, aliphatic relative abundance factor A is associated with the type of organic matter;the better is the type of the organic matter, the larger is the A value. The combination of the molecular structures with the thermal simulation results shows that the aliphatic hydrogen enrichment of selected carbonaceous mudstone is similar to that of coal. However, the relative abundance of the aliphatic group of it is high, and the DOC of the aromatic structure is low, making the hydrocarbon generation base stronger and easier to crack. Thus, the hydrocarbon generation capacity of carbonaceous mudstone is slightly higher than that of coal. Mudstone has low H and I values, and the DOC is high, indicating that its hydrocarbon base is low, so it has low hydrocarbon generation capacity. Therefore, the molecular structure is closely associated with the hydrocarbon potential of coal-measure source rocks. When evaluating the qualities of coal-measure source rocks, the influence of molecular structure on these rocks should be considered.展开更多
There are known to be enormous Cenozoic coal-type oil and gas resources located in the basins of the South China Sea,among which the Paleogene coal-measure source rock are one of the main source rock.In order to more ...There are known to be enormous Cenozoic coal-type oil and gas resources located in the basins of the South China Sea,among which the Paleogene coal-measure source rock are one of the main source rock.In order to more effectively analyze the distribution laws of coal-measure source rock in marginal sea basins and guide coal-type oil and gas explorations,the Oligocene coal-measure source rock in the Qiongdongnan Basin were selected as examples in order to systematically analyze the types,development characteristics,control factors,and distribution prediction methods of coalmeasure source rock in marginal sea basins.The Qiongdongnan Basin is located in the northern region of the South China Sea.Previous explorations of the area have determined that the Oligocene coal-measure source rock in the Qiongdongnan Basin have typical"binary structures",which include coal seams and terrigenous marine mudstone.Among those,the terrigenous marine mudstone has been found to greatly expand the scope of the coal-measure source rock.In addition,the coal seams which have been exposed by drilling have been observed to have the characteristics of thin single layer thickness,many layers,and poor stability.Meanwhile,the terrigenous marine mudstone has the characteristics of large thickness and wide distribution.The development of coal-measure source rock is known to be controlled by many factors,such as paleoclimate and paleobotany condition,paleo-structure and topography,paleo-geography,rise and fall of base level,and so on.In accordance with the comprehensive analyses of various control factors of coal-measure source rock,and the changes in water body energy in sedimentary environments,a genetic model of the"energy belt"for the development and distribution of coal-measure source rock was proposed.Also,the development and distribution characteristics of coalmeasure source rock in different types of energy belts were clarified.Then,based on the development and distribution characteristics of coal-measure source rock and their controlling factors,prediction methods of the distribution ranges of coal-measure source rock were proposed from both qualitative and(semi-)quantitative aspects.That is to say,a method for(semi-)quantitative predictions of the distribution ranges of coal-bearing intervals based on model wave impedance inversion and neural network wave impedance inversion,along with a method for(semi-)quantitative predictions of the distribution ranges of terrigenous marine mudstone based on topographical slopes,were introduced in this study.展开更多
Coal-measure gas is the natural gas generated by coal, carbonaceous shale, and dark shale in coal-measure strata. It includes resources of continuous-type coalbed methane (CBM), shale gas and tight gas reservoirs, and...Coal-measure gas is the natural gas generated by coal, carbonaceous shale, and dark shale in coal-measure strata. It includes resources of continuous-type coalbed methane (CBM), shale gas and tight gas reservoirs, and trap-type coal-bearing gas reservoirs. Huge in resources, it is an important gas source in the natural gas industry. The formation and distribution characteristics of coal-measure gas in San Juan, Surat, West Siberia and Ordos basins are introduced in this paper. By reviewing the progress of exploration and development of coal-measure gas around the world, the coal-measure gas is confirmed as an important strategic option for gas supply. This understanding is mainly manifested in three aspects. First, globally, the Eurasian east-west coal-accumulation belt and North American north-south coal-accumulation belt are two major coal-accumulation areas in the world, and the Late Carboniferous–Permian, Jurassic and end of Late Cretaceous–Neogene are 3 main coal-accumulation periods. Second, continuous-type and trap-type are two main accumulation modes of coal-measure gas;it is proposed that the area with gas generation intensity of greater than 10×10^8 m^3/km^2 is essential for the formation of large coal-measure gas field, and the CBM generated by medium- to high-rank coal is usually enriched in syncline, while CBM generated by low-rank coal is likely to accumulate when the source rock and caprock are in good configuration. Third, it is predicted that coal-measure gas around the world has huge remaining resources, coal-measure gas outside source is concentrated in Central Asia-Russia, the United States, Canada and other countries/regions, while CBM inside source is largely concentrated in 12 countries. The production of coal-measure gas in China is expected to exceed 1000×10^8 m^3 by 2030, including (500–550)×10^8 m^3 conventional coal-measure gas,(400–450)×10^8 m^3 coal-measure tight gas, and (150–200)×10^8 m^3 CBM.展开更多
This paper discusses the enviromental characteristics of carbonaceous mudstone and mudstone (coal-measure mudstone in short) of the Early and Middle Jurassic in the Turpan-Hami basin, which were formed in swamps. Thro...This paper discusses the enviromental characteristics of carbonaceous mudstone and mudstone (coal-measure mudstone in short) of the Early and Middle Jurassic in the Turpan-Hami basin, which were formed in swamps. Through the organic facies study of the coal-measure mudstone in this area, the authors clarify that the flowing-water swamp is the most advanced organic facies belt. Furthermore, according to the practical materials of coal-measure mudstone in the area and with the evaluation criteria of lacustrine mudstone in the past, the authors have established the integrated symbol systems from the abundance of organic matter and the type of organic matter, which can be used in the source rock evaluation of the coal-measure mudstone.展开更多
On the basis of GC–MS analysis, a suite of nine coal-measure source rocks(Ro 0.51%–0.63%) from the southern margin of Junggar basin was found to contain many biomarkers for bacterially-generated hydrocarbons:hopane,...On the basis of GC–MS analysis, a suite of nine coal-measure source rocks(Ro 0.51%–0.63%) from the southern margin of Junggar basin was found to contain many biomarkers for bacterially-generated hydrocarbons:hopane, sesquiterpene, C_(23)+ monomethyl alkanes(even carbon predominance), and C_(24)+ alkyl cyclohexane.Rock–eval and microscope analysis indicate that vitrinite(especially desmocollinite and homocollinite) plays a significant role in the generation of hydrocarbons in coalmeasure source rocks. Vitrinite performs this role by absorbing ultramicroscopic organic matter, generally in the form of resins or bacterial plastids. C_(23)+ monomethyl alkanes(even carbon predominance) and C_(24)+ alkyl cyclohexane series compounds are derived from bacterial metabolites of higher plants. The ultramicro organic matter adsorbed by vitrinite source rocks in the study area is probably ultramicro bacterial plastids. Because the organic matter of higher plants with low hydrogen content has been transformed into organic matter rich in hydrogen by bacteria, the hydrocarbon generation capacity of source rocks is greatly improved. In other words, in coal-measure source rocks, bacteria play an important role in hydrocarbon generation.展开更多
Natural gas is providing a larger proportion of primary energy, and will soon surpass oil to become the most important fossil fuel. There are various genetic types of natural gas of which the type that pyrolysed or cr...Natural gas is providing a larger proportion of primary energy, and will soon surpass oil to become the most important fossil fuel. There are various genetic types of natural gas of which the type that pyrolysed or cracked from humic kerogen accounts for 70% of presently discovered global natural gas reserves. The parent material of humic kerogen is higher multi-cellular plants. Investigations of offshore basins in China, Russia, Indonesia, Bangladesh, Australia, Egypt and Namibia show that river-delta systems contain the major sources of coal-type gas. Sand and mud carried by rivers form deltas at river mouths and fertile soil of these deltas encourages the long-term growth of higher plants. Autochthonous higher plants and allochthonous terrigenous phytoclasts contribute to the formation of coal, carbargilite and dark mudstone, which are potential parent materials of natural gas and the basis of coal-type gas generation.展开更多
Using X-ray diffraction (XRD) analysis and an electron-probe microanalyser (EPMA), this research found that the main independent mineral of titanium (Ti) in the kaoline of Songyi is anatase. The granularity of anatase...Using X-ray diffraction (XRD) analysis and an electron-probe microanalyser (EPMA), this research found that the main independent mineral of titanium (Ti) in the kaoline of Songyi is anatase. The granularity of anatase is from 0.5 μm to 1.5 μm, and some exceed 10 μm. This research provides important scientific evidence for the exploitation of the coal-measure kaoline in the South China.展开更多
TiO2/Al-MCM-41 composites with various titania content were prepared by loading titania into the mesopores of Al-MCM-41 mesoporous molecular sieve from coal-measure kaolin as silicon and aluminum source via general so...TiO2/Al-MCM-41 composites with various titania content were prepared by loading titania into the mesopores of Al-MCM-41 mesoporous molecular sieve from coal-measure kaolin as silicon and aluminum source via general sol-gel method and incipient wetness impregnation method. TiO2/Al-MCM-41 composites were characterized by XRD, FT-IR and SEM, and the photocatalytic degradation of methyl orange solution under visible light irradiation. The results showed that the titania crystalline phase was anatase, and the particles size of TiO2 increase with TiO2 content. The photocatalytic degradation rates of all samples prepared by sol-gel method and incipient wetness impregnation have been become stable by visible light irradiation for 150 min, and the highest degradation rate was 83.7% and 76% respectively.展开更多
Mesoporous materials with the highest surface area were synthesized by hydrothermal treatment from coal-measure kaolin using cetyltrimethylammonium bromide（CTAB）as template.The effect of several factors on surface a...Mesoporous materials with the highest surface area were synthesized by hydrothermal treatment from coal-measure kaolin using cetyltrimethylammonium bromide（CTAB）as template.The effect of several factors on surface area of products also had been discussed.The products were characterized by FT- IR,HRTEM and N 2 adsorption and desorption isotherm plot methods.There was typical structure as Si-O,Si- OH and Si-O-Si of mesoporous materials in the framework of synthesized materials;the pore size distributions of the products showed a sharp peak at 3.82 nm.The effect of hydrothermal treatment time and the amount of template on the specific surface area of mesoporous materials was important,when the Surf/Si=0.135,and hydrothermal time=12 h,and the surface area of the product reached up to 1 070 m2/g,which was higher than other products.展开更多
The Triassic and Jurassic tight sandstone gas in the western Sichuan depression,Sichuan Basin has attracted much attention in recent years,and the Upper Triassic coal-bearing Xujiahe Formation is believed to be the ma...The Triassic and Jurassic tight sandstone gas in the western Sichuan depression,Sichuan Basin has attracted much attention in recent years,and the Upper Triassic coal-bearing Xujiahe Formation is believed to be the major source rock.However,there are relatively few studies on the carbon isotopic heterogeneity of methane generated from coal-measure source rocks and the origin of the natural gases in Xinchang Gas Field is still controversial.In this study,one coal-measure mudstone sample and one coal sample of the Xujiahe Formation in western Sichuan Basin were selected for gold tube pyrolysis experiment to determine their gas generation characteristics.Geological extrapolation of gas generation and methane carbon isotope fractionation parameters reveals that the main gas generation stage of Xujiahe Formation ranges from Late Jurassic to Cretaceous in the Xinchang Gas Field.The natural gas in the 5th member of Xujiahe Formation in Xinchang Gas Field is mainly derived from the 5th member of Xujiahe Formation itself,i.e.,self-generation and self-reservoir,however,the gas in the Jurassic gas pools is mainly derived from the source rocks of the 3rd member of Xujiahe Formation rather than the 5th member of Xujiahe Formation.展开更多
The Paleogene coal accumulation basins of China are part of the global Tertiary coal-accumulated zone of the Pacific Rim located in the eastern coastal provinces and areas. Although the coal-bearing basins of the Chin...The Paleogene coal accumulation basins of China are part of the global Tertiary coal-accumulated zone of the Pacific Rim located in the eastern coastal provinces and areas. Although the coal-bearing basins of the China Sea area are faults and depressed basins, they come up in groups. The overall structures are suitable for the development of coal-bearing deposition. The continuity of basin groups are good, and the coal-bearing depositions are thick. For example, the coal-bearing deposi- tion is more than a kilometer thick at the Qiongdongnan Basin and Xihu Sag in the East China Sea, which the continental Pa- leogene coal basins cannot reach. Research shows that the coal accumulation basins in the sea area consist of many sags. There are two types of coal accumulation sags： half-graben sag and graben sag. In terms of water depth, coal accumulation sags can also be classified as deep-water half-graben sag and shallow-water half-graben sag; the graben sag is the deep-water sag. There are two distinct coal-accumulated zones in the basin： gentle slope and steep slope, with the gentle slope being the dominant one. The marshes of the supratidal zone and intertidal zone in a tidal flat system is favorable for the coal accumulation process widely taking place. There are two types of peat accumulation： autochthonous accumulation and allochthonous accumulation. Because of tectonic activities in the basins, allochthonous accumulations may be the more important form of coal-forming ac- tivities in the sea area. The very thick coal-bearing deposition in the sea area provides a rich material base for the assemblage of coal-related gas. Also, as a result of the deep burial depth, the degree of coal metamorphism is relatively high, so the coal-bearing strata become good hydrocarbon source rocks.展开更多
Coal-measure gas is a primary target with significant potential for the exploration of unconventional hydrocarbon resources.However,the spatiotemporal distribution and combination patterns of multi-type coal-measure g...Coal-measure gas is a primary target with significant potential for the exploration of unconventional hydrocarbon resources.However,the spatiotemporal distribution and combination patterns of multi-type coal-measure gases are yet to be clarified,directly impeding the sweet spot evaluation and exploration deployment of coal-measure gas.This study discussed the characteristics and distribution patterns of coal-measure gases in the Daniudi gas field in northeastern Ordos Basin,China,with abundant drilling data.The results indicate that the coal seams variably thin upward and are mainly seen in the first and second members of the Taiyuan Formation(also referred to as the Tai 1 and Tai 2 members,respectively)and the first member of the Shanxi Formation(Shan 1 Member).Nos.8,5 and 3 coal seams are laterally continuous,and significantly thicker in its southern part compared to the northern part.Moreover,carbonaceous mudstones and shales are better developed in the southern part,where limestones are only observed in the Tai 1 Member.Based on the main lithological types,we identified three lithologic roofs of coal seams,that is,limestone,mudstone,and sandstone,which determine the spatiotemporal distribution of coal-measure gases.Besides bauxite gas in the Benxi Formation,the coal-measure gases include tight-sand gas,coalbed methane(CBM),coal-measure shale gas,and tight-limestone gas,with CBM typically associated with coal-measure shale gas.The combinations of different types of coal-measure gas vary across different layers and regions.Tight-sand gas is well-developed in areas where tight sandstones are in contact with coal-measures.From the Taiyuan to the Shanxi formations,CBM gradually transitions into a combination of CBM and coal-measure shale gas,and coal-measure shale gas.Nos.8 and 5 coal seams in low-lying areas exhibit favorable gas-bearing properties due to their large thickness and favorable roof lithologies,serving as prospective play fairways.Mudstone and limestone roofs are more conducive to achieving good gas-bearing properties.The direct contact between sandstones and coal seams tends to result in the formation of tight-sand gas and a reduced gas content of CBM.While focusing on single types of gas reservoirs such as CBM and tight-sand gas,it is essential to consider the concurrent exploration of various coal-measure gas combinations to discover more additional gas resources and guide exploration deployment.展开更多
In this study,a group of overmature coal-measure shale core samples was collected in situ from an exploration well located in the Wuxiang area of the Qinshui Basin,north China.The pore water contents(CPW)of the shales...In this study,a group of overmature coal-measure shale core samples was collected in situ from an exploration well located in the Wuxiang area of the Qinshui Basin,north China.The pore water contents(CPW)of the shales under as-received conditions,equilibrium water contents(CEW)of the shales under moisture equilibrium conditions(relative humidity:100%),and nanopore structures of the shales under both as-received and dried conditions were measured.The results indicate that the CPW values of these shales are much lower than their CEW values,which implies that the bulk pore systems of these shales have low water-bearing extents.In addition,approximately half of the total pore volumes and surface areas of the as-received shales are occupied by pore water,and the effects of pore water on shale nanopores with various pore types and widths are different.The average water-occupied percentages(PW)are 59.16%−81.99%and 42.53%−43.44%for the non-micropores and micropores,respectively,and are 83.54%−97.69%and 19.57%−26.42%for the inorganic-matter hosted(IM)and organic-matter hosted(OM)pores,respectively.The pore water in shales not only significantly reduces the storage of shale gas by occupying many pore spaces,but also causes the shale gas,especially the absorbed gas,to be mostly stored in the OM pores;meanwhile,the IM pores mainly store free gas.Therefore,the water-bearing characteristics and their effects on the pore structures and gas-bearing properties of coal-measure shales should be noted for the evaluation and exploration of shale gas in the Qinshui Basin.展开更多
The coal-measure source rock in the Chinese sea area plays a significant role as a hydrocarbon source rock,with its genetic environment,development and distribution,and hydrocarbon generation potential serving as esse...The coal-measure source rock in the Chinese sea area plays a significant role as a hydrocarbon source rock,with its genetic environment,development and distribution,and hydrocarbon generation potential serving as essential factors for the exploration of coal-type oil and gas fields.This study focuses on the coal-measure source rock of the Paleogene Enping Formation in the ZhuⅠDepression,located in the northern South China Sea.The main geological insights obtained are as follows.The coal measures of the Enping Formation are developed in a warm and wet tropical-subtropical climate.The development environment of the coal-measure source rock in the Enping Formation includes the braided river delta upper plain peat swamp,characterized by dry forest swamp coal facies with relatively thick coal seams and a small number of layers.The braided river delta lower plain swamp-interdistributary bay of braided river delta front represents a forest edge-wetland herbaceous swamp coal facies with numerous layers of thin coal seams and poor stability.The shore swamp corresponds to an open water swamp coal facies with multiple layers of thin coal seams and poor stability.The organic matter abundance in the braided river delta upper plain is the highest,followed by the braided river delta lower plain-braided river delta front,and the shore-shallow lake.The organic matter type is predominantly typeⅡ1.Thermal evolution analysis suggests that the organic matter has progressed into a substantial oil generation stage.The hydrocarbon generation potential of the coal-measure source rock in the Enping Formation is the highest in the braided river delta upper plain,followed by the braided river delta lower plain-braided river delta front and the shore-shallow lake.Overall,this study proposes three organic facies in the coal-measure source rock of the Enping Formation:upper-plain swamp-dry forest swamp facies,lower plain-interdistributary bay-forest-herbaceous swamp facies,and lake swamp-herbaceous swamp facies.展开更多
Oligocene(fan)delta-associated coal measures and marine source rocks are the main gas-generating source rocks in the Qiongdongnan Basin,and(fan)delta sand bodies are the dominant types of reservoirs.By comprehensively...Oligocene(fan)delta-associated coal measures and marine source rocks are the main gas-generating source rocks in the Qiongdongnan Basin,and(fan)delta sand bodies are the dominant types of reservoirs.By comprehensively utilizing a large amount of 2D and 3D seismic data and new drilling data,the distribution of(fan)deltas and three types of Oligocene fault fan systems were systematically identified;these are thought to have had joint control over the development of hydrocarbon source rocks and reservoirs.The three types of Oligocene fault fan coupling relationships in the Qiongdongnan Basin were found to be fault bend,fault gully,and fault tip.The fault bend type of(fan)delta developed at the bend of the fault and was distributed in the downthrown block of Fault Nos.5 and 2.The fault tip type developed where the fault died out toward the source direction and was distributed near the eastewest faults on the north and south sides of Baodao and Changchang Sags.The fault gully type developed along the fault trend in the downthrown block and was mainly distributed in areas including the northern part of Ya'nan Sag and the Fault No.3 downthrown block.The fault bend(fan)delta is surrounded by a relatively closed bay environment,and the terrigenously dominated marine source rocks in the still water bay environment were developed with a high hydrocarbon generation index and high hydrocarbon generation potential.Fault tip and fault gully types of(fan)delta plain facies have a wide distribution of plain subfacies,which is conducive to the development of coal-measure source rocks that have excellent gas potential.During sedimentation of the fault gully and the fault tip delta,the terrain was relatively flat,with sand bodies strongly reworked by hydrodynamic force;the reservoir quality of the sand bodies in the underwater distributary channel and estuary dam are good,and the sand bodies have wide distribution.The sand bodies of the fault bend type of(fan)delta were deposited rapidly near the source kitchen,and the degree of sorting and rounding was poor,which resulted in the poor physical properties of the plain subfacies.In the southern and northern step-fault zones of Baodao Sag in the eastern part of this basin,the fault bend,fault tip,and fault trench(fan)deltas were inherited and further developed,and the source-reservoir configuration conditions were favorable.Exploration deployment was carried out in the Baodao 21 area in the northern step-fault zone and the Yongle 10 area in the southern step-fault zone,where new discoveries in natural gas exploration have been realized.In the eastern part of this basin,the fault bend,fault tip,and fault gully(fan)deltas in the southern and northern fault step zones of Baodao Sag were successively developed,which were beneficial for favorable sourceereservoir configuration conditions.The natural gas exploration successes in the Baodao-21 area in the northern fault step zone and the Yongle-10 area in the southern fault step zone are beneficial for new discoveries in natural gas exploration in the Qiongdongnan Basin.展开更多
Coal measure gas(CMG),referring to natural gas stored in coal measures,as well as its existence,exploration and production,has been highly concerned recently in natural gas sector in China,and pilot tests of which hav...Coal measure gas(CMG),referring to natural gas stored in coal measures,as well as its existence,exploration and production,has been highly concerned recently in natural gas sector in China,and pilot tests of which have been succeeded with some achievements.To provide new geological references,this paper discussed the research progress in CMG co-existence and pooling factors in the respects of the tightening mechanism of coal measure sandstone reservoirs,CMG co-existence and gas pooling assemblages,the superimposed CMG system,and so on.The following findings were obtained.(1)The particularities of CMG geological conditions are shown in three aspects:First,the occurrence and reservoir lithology of CMG are diverse,and the accumulation of sandstone gas in coal measures may be different from that of conventional sandstone gas.Second,the sedimentary environment of coal measures causes the frequent and thin interbedding with various lithologic reservoirs,strong cyclicity and complex gasewater relationship,and the Surat-type CMG is worthy of attention.And third,the sandstone reservoirs in coal measures are embedded in the wide overlying mudstones,the special sourceereservoir match and composite gas reservoirs need to develop adaptive co-exploration and co-production technology.(2)The coal measures are rich in organic matters,and a large number of the organic acids are formed during gas generation from the source rocks,which are important factors for the densification of the sandstone reservoirs in coal measures.And the sandstone reservoirs in coal measures may be characteristic of self-generating and self-storing gas and adsorption to a certain extent,and their physical properties can be improved by organic detritus in the reservoirs.(3)The sedimentology of coal measures defines four generalities for favorable CMG accumulation,but effect of the gas-generating intensity,gas migration system,formation fluid energy and effective regional caprock thickness to the accumulation are variable.The natural gas generated in source rocks is re-allocated with a special migration system in a complex sourceereservoir system,which is an important basis of CMG accumulation.(4)The superimposition of the gas-bearing system is one of the leading problems in CMG research.In recent years,the logging response identification technology of key strata and the superposition identification method of the gas-bearing system have been further developed.It is found that there are three typical types of fluid pressure curves in coal measures.At the same time,the CMG co-accumulation in the whole sense requires a certain threshold depth.Based on the progress above,the theory of CMG accumulation has been improved and deepened,which is helpful in providing more pertinent suggestions for the development of the joint CMG exploration and production technology.展开更多
It is of great significance to study the controlling effect of sealing systems on CBM enrichment in coalbed methane (CBM) exploration anddevelopment. In this paper, the relationships between CBM enrichment and geologi...It is of great significance to study the controlling effect of sealing systems on CBM enrichment in coalbed methane (CBM) exploration anddevelopment. In this paper, the relationships between CBM enrichment and geological elements were analyzed. The geological elements includesealing layers (e.g. regional cap rock, regional floor, and immediate roof and floor), later structural adjustment and strata production status. It isshown that CBM tends to enrich in the areas where regional mudstone cap rocks and floors are distributed stably, structures are uplifted andinversed slightly after the hydrocarbon accumulation period and the strata is gentle in a balanced state. Then, the concept of sealing system wasput forward based on the worldwide CBM exploration and development practices over the years. A sealing system refers to a geological unitcomposed of a lateral stable zone and cap rock which prevents gas from migrating upward and downward. In a sealing system, CBM can getenriched and coal-measure gas can also be accumulated. Finally, three gas reservoir types (i.e., sandwich-type CBM reservoir, associated CBM-sandstone gas reservoir and coal-derived sandstone gas reservoir) were identified based on the configuration relationships between elements ofthe CBM (or coal-measure gas) sealing system. It is recommended to change the exploration ideas from simple CBM exploration to 3D CBMand coal-measure gas exploration. In addition, an evaluation index system of CBM (or coal-measure gas) geological selection was established. Itis pointed out that good application effects may be realized if the stereoscopic CBM and coal-measure gas exploration is applied in the JunggarBasin and the eastern margin of the Ordos Basin.展开更多
Natural gases discovered up to now in Lishui Sag,the East China Sea Basin,differ greatly in gaseous compositions,of which hydrocarbon gases amount to 2%―94%while non-hydrocarbon gases are dominated by CO2.Their hydro...Natural gases discovered up to now in Lishui Sag,the East China Sea Basin,differ greatly in gaseous compositions,of which hydrocarbon gases amount to 2%―94%while non-hydrocarbon gases are dominated by CO2.Their hydrocarbon gases,without exception,contain less than 90%of methane and over 10%of C2 + heavier hydrocarbons,indicating a wet gas.Carbon isotopic analyses on these hydrocarbon gases showed thatδ13C 1 ,δ13C 2 andδ13C 3 are basically lighter than-44‰,-29‰and-26‰, respectively.The difference in carbon isotopic values between methane and ethane is great,suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation.δ13C CO2 values of nonhydrocarbon gases are all heavier than-10‰,indicating a typical abiogenic gas.The simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit,consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the latter.Moreover, δ13C 1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit whileδ13C 2 andδ13C 3 values of the former are over 9‰heavier than those of the latter.Currently the LS36-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag,where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter,therefore,natural gases in the LS36-1 oil-gas pool are mainly derived from the Yueguifeng Formation lacustrine source rock rather than the Lingfeng Formation marine or Mingyuefeng Formation coal-measures source rocks.展开更多
基金co-funded by the National Natural Science Foundation of China (Grant Nos. 42372160, 42072172)Shandong Province Natural Science Fund for Distinguished Young Scholars (Grant No. JQ201311)the Graduate Scientific and Technological Innovation Project financially supported by Shandong University of Science and Technology (Grant No. SDKDYC190313)。
文摘The Jurassic coal-measure source rocks in the Junggar Basin have drawn considerable attention in recent years. In our hydrocarbon thermal simulation experiments of these rocks, we found that the dark mudstone evaluated as good source rock, had a much lower hydrocarbon generation capacity than the coal and carbonaceous mudstone, evaluated as poor source rock. Based on this background, we performed Fourier transform infrared spectroscopy(FTIR) and combined the results of semi-open thermal simulation experiments to explore the association between the molecular structure and hydrocarbon production capacity, with the aim of obtaining a new understanding of hydrocarbon potential of Jurassic coal-measure source rocks from the perspective of molecular structure. The results indicate that coals exhibit lower condensation of aromatic structures and higher relative abundance of aliphatic structures with a higher degree of branched chaining than mudstones and carbonaceous mudstones. Apparent aromaticity(f_a), aromatic abundance parameter I, and degree of condensation(DOC) are negatively correlated with organic matter abundance. The aliphatic structural parameter H demonstrates a substantial positive correlation with organic matter abundance. Furthermore, aliphatic relative abundance factor A is associated with the type of organic matter;the better is the type of the organic matter, the larger is the A value. The combination of the molecular structures with the thermal simulation results shows that the aliphatic hydrogen enrichment of selected carbonaceous mudstone is similar to that of coal. However, the relative abundance of the aliphatic group of it is high, and the DOC of the aromatic structure is low, making the hydrocarbon generation base stronger and easier to crack. Thus, the hydrocarbon generation capacity of carbonaceous mudstone is slightly higher than that of coal. Mudstone has low H and I values, and the DOC is high, indicating that its hydrocarbon base is low, so it has low hydrocarbon generation capacity. Therefore, the molecular structure is closely associated with the hydrocarbon potential of coal-measure source rocks. When evaluating the qualities of coal-measure source rocks, the influence of molecular structure on these rocks should be considered.
基金granted by the National Natural Science Foudation of China(Grant No.4207218841872172)the SDUST Research Fund(2018TDJH101)。
文摘There are known to be enormous Cenozoic coal-type oil and gas resources located in the basins of the South China Sea,among which the Paleogene coal-measure source rock are one of the main source rock.In order to more effectively analyze the distribution laws of coal-measure source rock in marginal sea basins and guide coal-type oil and gas explorations,the Oligocene coal-measure source rock in the Qiongdongnan Basin were selected as examples in order to systematically analyze the types,development characteristics,control factors,and distribution prediction methods of coalmeasure source rock in marginal sea basins.The Qiongdongnan Basin is located in the northern region of the South China Sea.Previous explorations of the area have determined that the Oligocene coal-measure source rock in the Qiongdongnan Basin have typical"binary structures",which include coal seams and terrigenous marine mudstone.Among those,the terrigenous marine mudstone has been found to greatly expand the scope of the coal-measure source rock.In addition,the coal seams which have been exposed by drilling have been observed to have the characteristics of thin single layer thickness,many layers,and poor stability.Meanwhile,the terrigenous marine mudstone has the characteristics of large thickness and wide distribution.The development of coal-measure source rock is known to be controlled by many factors,such as paleoclimate and paleobotany condition,paleo-structure and topography,paleo-geography,rise and fall of base level,and so on.In accordance with the comprehensive analyses of various control factors of coal-measure source rock,and the changes in water body energy in sedimentary environments,a genetic model of the"energy belt"for the development and distribution of coal-measure source rock was proposed.Also,the development and distribution characteristics of coalmeasure source rock in different types of energy belts were clarified.Then,based on the development and distribution characteristics of coal-measure source rock and their controlling factors,prediction methods of the distribution ranges of coal-measure source rock were proposed from both qualitative and(semi-)quantitative aspects.That is to say,a method for(semi-)quantitative predictions of the distribution ranges of coal-bearing intervals based on model wave impedance inversion and neural network wave impedance inversion,along with a method for(semi-)quantitative predictions of the distribution ranges of terrigenous marine mudstone based on topographical slopes,were introduced in this study.
基金Supported by the National Key Basic Research and Development Program(973 Program),China
文摘Coal-measure gas is the natural gas generated by coal, carbonaceous shale, and dark shale in coal-measure strata. It includes resources of continuous-type coalbed methane (CBM), shale gas and tight gas reservoirs, and trap-type coal-bearing gas reservoirs. Huge in resources, it is an important gas source in the natural gas industry. The formation and distribution characteristics of coal-measure gas in San Juan, Surat, West Siberia and Ordos basins are introduced in this paper. By reviewing the progress of exploration and development of coal-measure gas around the world, the coal-measure gas is confirmed as an important strategic option for gas supply. This understanding is mainly manifested in three aspects. First, globally, the Eurasian east-west coal-accumulation belt and North American north-south coal-accumulation belt are two major coal-accumulation areas in the world, and the Late Carboniferous–Permian, Jurassic and end of Late Cretaceous–Neogene are 3 main coal-accumulation periods. Second, continuous-type and trap-type are two main accumulation modes of coal-measure gas;it is proposed that the area with gas generation intensity of greater than 10×10^8 m^3/km^2 is essential for the formation of large coal-measure gas field, and the CBM generated by medium- to high-rank coal is usually enriched in syncline, while CBM generated by low-rank coal is likely to accumulate when the source rock and caprock are in good configuration. Third, it is predicted that coal-measure gas around the world has huge remaining resources, coal-measure gas outside source is concentrated in Central Asia-Russia, the United States, Canada and other countries/regions, while CBM inside source is largely concentrated in 12 countries. The production of coal-measure gas in China is expected to exceed 1000×10^8 m^3 by 2030, including (500–550)×10^8 m^3 conventional coal-measure gas,(400–450)×10^8 m^3 coal-measure tight gas, and (150–200)×10^8 m^3 CBM.
文摘This paper discusses the enviromental characteristics of carbonaceous mudstone and mudstone (coal-measure mudstone in short) of the Early and Middle Jurassic in the Turpan-Hami basin, which were formed in swamps. Through the organic facies study of the coal-measure mudstone in this area, the authors clarify that the flowing-water swamp is the most advanced organic facies belt. Furthermore, according to the practical materials of coal-measure mudstone in the area and with the evaluation criteria of lacustrine mudstone in the past, the authors have established the integrated symbol systems from the abundance of organic matter and the type of organic matter, which can be used in the source rock evaluation of the coal-measure mudstone.
基金financially supported by the National Natural Science Foundation of China (No. 41772124)National Science and Technology Major Project (No. 2016ZX05007001-002)
文摘On the basis of GC–MS analysis, a suite of nine coal-measure source rocks(Ro 0.51%–0.63%) from the southern margin of Junggar basin was found to contain many biomarkers for bacterially-generated hydrocarbons:hopane, sesquiterpene, C_(23)+ monomethyl alkanes(even carbon predominance), and C_(24)+ alkyl cyclohexane.Rock–eval and microscope analysis indicate that vitrinite(especially desmocollinite and homocollinite) plays a significant role in the generation of hydrocarbons in coalmeasure source rocks. Vitrinite performs this role by absorbing ultramicroscopic organic matter, generally in the form of resins or bacterial plastids. C_(23)+ monomethyl alkanes(even carbon predominance) and C_(24)+ alkyl cyclohexane series compounds are derived from bacterial metabolites of higher plants. The ultramicro organic matter adsorbed by vitrinite source rocks in the study area is probably ultramicro bacterial plastids. Because the organic matter of higher plants with low hydrogen content has been transformed into organic matter rich in hydrogen by bacteria, the hydrocarbon generation capacity of source rocks is greatly improved. In other words, in coal-measure source rocks, bacteria play an important role in hydrocarbon generation.
基金funded by the National Science&Technology Specific Project of China(No.2011ZX05030)
文摘Natural gas is providing a larger proportion of primary energy, and will soon surpass oil to become the most important fossil fuel. There are various genetic types of natural gas of which the type that pyrolysed or cracked from humic kerogen accounts for 70% of presently discovered global natural gas reserves. The parent material of humic kerogen is higher multi-cellular plants. Investigations of offshore basins in China, Russia, Indonesia, Bangladesh, Australia, Egypt and Namibia show that river-delta systems contain the major sources of coal-type gas. Sand and mud carried by rivers form deltas at river mouths and fertile soil of these deltas encourages the long-term growth of higher plants. Autochthonous higher plants and allochthonous terrigenous phytoclasts contribute to the formation of coal, carbargilite and dark mudstone, which are potential parent materials of natural gas and the basis of coal-type gas generation.
文摘Using X-ray diffraction (XRD) analysis and an electron-probe microanalyser (EPMA), this research found that the main independent mineral of titanium (Ti) in the kaoline of Songyi is anatase. The granularity of anatase is from 0.5 μm to 1.5 μm, and some exceed 10 μm. This research provides important scientific evidence for the exploitation of the coal-measure kaoline in the South China.
文摘TiO2/Al-MCM-41 composites with various titania content were prepared by loading titania into the mesopores of Al-MCM-41 mesoporous molecular sieve from coal-measure kaolin as silicon and aluminum source via general sol-gel method and incipient wetness impregnation method. TiO2/Al-MCM-41 composites were characterized by XRD, FT-IR and SEM, and the photocatalytic degradation of methyl orange solution under visible light irradiation. The results showed that the titania crystalline phase was anatase, and the particles size of TiO2 increase with TiO2 content. The photocatalytic degradation rates of all samples prepared by sol-gel method and incipient wetness impregnation have been become stable by visible light irradiation for 150 min, and the highest degradation rate was 83.7% and 76% respectively.
基金Funded by Social Development Plan of Jiangsu Department of the Science and Technology,Jiangsu,China(No.BS2007038)
文摘Mesoporous materials with the highest surface area were synthesized by hydrothermal treatment from coal-measure kaolin using cetyltrimethylammonium bromide（CTAB）as template.The effect of several factors on surface area of products also had been discussed.The products were characterized by FT- IR,HRTEM and N 2 adsorption and desorption isotherm plot methods.There was typical structure as Si-O,Si- OH and Si-O-Si of mesoporous materials in the framework of synthesized materials;the pore size distributions of the products showed a sharp peak at 3.82 nm.The effect of hydrothermal treatment time and the amount of template on the specific surface area of mesoporous materials was important,when the Surf/Si=0.135,and hydrothermal time=12 h,and the surface area of the product reached up to 1 070 m2/g,which was higher than other products.
基金supported by the XDA special program of Chinese Academy of Science (No.XDA14010104)the Natural Science Foundation of China (No.41925014)。
文摘The Triassic and Jurassic tight sandstone gas in the western Sichuan depression,Sichuan Basin has attracted much attention in recent years,and the Upper Triassic coal-bearing Xujiahe Formation is believed to be the major source rock.However,there are relatively few studies on the carbon isotopic heterogeneity of methane generated from coal-measure source rocks and the origin of the natural gases in Xinchang Gas Field is still controversial.In this study,one coal-measure mudstone sample and one coal sample of the Xujiahe Formation in western Sichuan Basin were selected for gold tube pyrolysis experiment to determine their gas generation characteristics.Geological extrapolation of gas generation and methane carbon isotope fractionation parameters reveals that the main gas generation stage of Xujiahe Formation ranges from Late Jurassic to Cretaceous in the Xinchang Gas Field.The natural gas in the 5th member of Xujiahe Formation in Xinchang Gas Field is mainly derived from the 5th member of Xujiahe Formation itself,i.e.,self-generation and self-reservoir,however,the gas in the Jurassic gas pools is mainly derived from the source rocks of the 3rd member of Xujiahe Formation rather than the 5th member of Xujiahe Formation.
基金Supported by the Major Research Project of the National Natural Science Foundation （40872100）
文摘The Paleogene coal accumulation basins of China are part of the global Tertiary coal-accumulated zone of the Pacific Rim located in the eastern coastal provinces and areas. Although the coal-bearing basins of the China Sea area are faults and depressed basins, they come up in groups. The overall structures are suitable for the development of coal-bearing deposition. The continuity of basin groups are good, and the coal-bearing depositions are thick. For example, the coal-bearing deposi- tion is more than a kilometer thick at the Qiongdongnan Basin and Xihu Sag in the East China Sea, which the continental Pa- leogene coal basins cannot reach. Research shows that the coal accumulation basins in the sea area consist of many sags. There are two types of coal accumulation sags： half-graben sag and graben sag. In terms of water depth, coal accumulation sags can also be classified as deep-water half-graben sag and shallow-water half-graben sag; the graben sag is the deep-water sag. There are two distinct coal-accumulated zones in the basin： gentle slope and steep slope, with the gentle slope being the dominant one. The marshes of the supratidal zone and intertidal zone in a tidal flat system is favorable for the coal accumulation process widely taking place. There are two types of peat accumulation： autochthonous accumulation and allochthonous accumulation. Because of tectonic activities in the basins, allochthonous accumulations may be the more important form of coal-forming ac- tivities in the sea area. The very thick coal-bearing deposition in the sea area provides a rich material base for the assemblage of coal-related gas. Also, as a result of the deep burial depth, the degree of coal metamorphism is relatively high, so the coal-bearing strata become good hydrocarbon source rocks.
基金funded by SINOPEC Science and Technology Research Program(No.P23206No.P23230).
文摘Coal-measure gas is a primary target with significant potential for the exploration of unconventional hydrocarbon resources.However,the spatiotemporal distribution and combination patterns of multi-type coal-measure gases are yet to be clarified,directly impeding the sweet spot evaluation and exploration deployment of coal-measure gas.This study discussed the characteristics and distribution patterns of coal-measure gases in the Daniudi gas field in northeastern Ordos Basin,China,with abundant drilling data.The results indicate that the coal seams variably thin upward and are mainly seen in the first and second members of the Taiyuan Formation(also referred to as the Tai 1 and Tai 2 members,respectively)and the first member of the Shanxi Formation(Shan 1 Member).Nos.8,5 and 3 coal seams are laterally continuous,and significantly thicker in its southern part compared to the northern part.Moreover,carbonaceous mudstones and shales are better developed in the southern part,where limestones are only observed in the Tai 1 Member.Based on the main lithological types,we identified three lithologic roofs of coal seams,that is,limestone,mudstone,and sandstone,which determine the spatiotemporal distribution of coal-measure gases.Besides bauxite gas in the Benxi Formation,the coal-measure gases include tight-sand gas,coalbed methane(CBM),coal-measure shale gas,and tight-limestone gas,with CBM typically associated with coal-measure shale gas.The combinations of different types of coal-measure gas vary across different layers and regions.Tight-sand gas is well-developed in areas where tight sandstones are in contact with coal-measures.From the Taiyuan to the Shanxi formations,CBM gradually transitions into a combination of CBM and coal-measure shale gas,and coal-measure shale gas.Nos.8 and 5 coal seams in low-lying areas exhibit favorable gas-bearing properties due to their large thickness and favorable roof lithologies,serving as prospective play fairways.Mudstone and limestone roofs are more conducive to achieving good gas-bearing properties.The direct contact between sandstones and coal seams tends to result in the formation of tight-sand gas and a reduced gas content of CBM.While focusing on single types of gas reservoirs such as CBM and tight-sand gas,it is essential to consider the concurrent exploration of various coal-measure gas combinations to discover more additional gas resources and guide exploration deployment.
基金This study was supported by the National Natural Science Foundation of China(Grant Nos.U1810201 and 41925014)the Natural Science Foundation of Guangdong Province(No.2021A1515011381).
文摘In this study,a group of overmature coal-measure shale core samples was collected in situ from an exploration well located in the Wuxiang area of the Qinshui Basin,north China.The pore water contents(CPW)of the shales under as-received conditions,equilibrium water contents(CEW)of the shales under moisture equilibrium conditions(relative humidity:100%),and nanopore structures of the shales under both as-received and dried conditions were measured.The results indicate that the CPW values of these shales are much lower than their CEW values,which implies that the bulk pore systems of these shales have low water-bearing extents.In addition,approximately half of the total pore volumes and surface areas of the as-received shales are occupied by pore water,and the effects of pore water on shale nanopores with various pore types and widths are different.The average water-occupied percentages(PW)are 59.16%−81.99%and 42.53%−43.44%for the non-micropores and micropores,respectively,and are 83.54%−97.69%and 19.57%−26.42%for the inorganic-matter hosted(IM)and organic-matter hosted(OM)pores,respectively.The pore water in shales not only significantly reduces the storage of shale gas by occupying many pore spaces,but also causes the shale gas,especially the absorbed gas,to be mostly stored in the OM pores;meanwhile,the IM pores mainly store free gas.Therefore,the water-bearing characteristics and their effects on the pore structures and gas-bearing properties of coal-measure shales should be noted for the evaluation and exploration of shale gas in the Qinshui Basin.
基金The Scientific research project under contract under contract No.CCL2021RCPS172KQNFormation mechanism and distribution prediction of Cenozoic marine source rocks in Qiongdongnan and Pearl River Mouth Basin under contract No.2021KT-YXKY-01+2 种基金the resource potential,accumulation mechanism and breakthrough direction of potential oil-rich sags in offshore basins of China under contract No.2021-KT-YXKY-03the Open Foundation of Hebei Provincial Key Laboratory of Resource Survey and Researchthe National Natural Science Foundation of China(NSFC)under contract Nos 42072188,42272205。
文摘The coal-measure source rock in the Chinese sea area plays a significant role as a hydrocarbon source rock,with its genetic environment,development and distribution,and hydrocarbon generation potential serving as essential factors for the exploration of coal-type oil and gas fields.This study focuses on the coal-measure source rock of the Paleogene Enping Formation in the ZhuⅠDepression,located in the northern South China Sea.The main geological insights obtained are as follows.The coal measures of the Enping Formation are developed in a warm and wet tropical-subtropical climate.The development environment of the coal-measure source rock in the Enping Formation includes the braided river delta upper plain peat swamp,characterized by dry forest swamp coal facies with relatively thick coal seams and a small number of layers.The braided river delta lower plain swamp-interdistributary bay of braided river delta front represents a forest edge-wetland herbaceous swamp coal facies with numerous layers of thin coal seams and poor stability.The shore swamp corresponds to an open water swamp coal facies with multiple layers of thin coal seams and poor stability.The organic matter abundance in the braided river delta upper plain is the highest,followed by the braided river delta lower plain-braided river delta front,and the shore-shallow lake.The organic matter type is predominantly typeⅡ1.Thermal evolution analysis suggests that the organic matter has progressed into a substantial oil generation stage.The hydrocarbon generation potential of the coal-measure source rock in the Enping Formation is the highest in the braided river delta upper plain,followed by the braided river delta lower plain-braided river delta front and the shore-shallow lake.Overall,this study proposes three organic facies in the coal-measure source rock of the Enping Formation:upper-plain swamp-dry forest swamp facies,lower plain-interdistributary bay-forest-herbaceous swamp facies,and lake swamp-herbaceous swamp facies.
基金funded by the National Natural Science Foundation of China under contract number 91528303the National Science and Technology Major Project under contract numbers 2016ZX05026,2011ZX05025,and 2008ZX05025+1 种基金the National Basic Research Program(973 Program)of China under contract number 2009CB219400the Science and Technology Project of China National Offshore Oil Corporation under contract number KJGG2022-0101.
文摘Oligocene(fan)delta-associated coal measures and marine source rocks are the main gas-generating source rocks in the Qiongdongnan Basin,and(fan)delta sand bodies are the dominant types of reservoirs.By comprehensively utilizing a large amount of 2D and 3D seismic data and new drilling data,the distribution of(fan)deltas and three types of Oligocene fault fan systems were systematically identified;these are thought to have had joint control over the development of hydrocarbon source rocks and reservoirs.The three types of Oligocene fault fan coupling relationships in the Qiongdongnan Basin were found to be fault bend,fault gully,and fault tip.The fault bend type of(fan)delta developed at the bend of the fault and was distributed in the downthrown block of Fault Nos.5 and 2.The fault tip type developed where the fault died out toward the source direction and was distributed near the eastewest faults on the north and south sides of Baodao and Changchang Sags.The fault gully type developed along the fault trend in the downthrown block and was mainly distributed in areas including the northern part of Ya'nan Sag and the Fault No.3 downthrown block.The fault bend(fan)delta is surrounded by a relatively closed bay environment,and the terrigenously dominated marine source rocks in the still water bay environment were developed with a high hydrocarbon generation index and high hydrocarbon generation potential.Fault tip and fault gully types of(fan)delta plain facies have a wide distribution of plain subfacies,which is conducive to the development of coal-measure source rocks that have excellent gas potential.During sedimentation of the fault gully and the fault tip delta,the terrain was relatively flat,with sand bodies strongly reworked by hydrodynamic force;the reservoir quality of the sand bodies in the underwater distributary channel and estuary dam are good,and the sand bodies have wide distribution.The sand bodies of the fault bend type of(fan)delta were deposited rapidly near the source kitchen,and the degree of sorting and rounding was poor,which resulted in the poor physical properties of the plain subfacies.In the southern and northern step-fault zones of Baodao Sag in the eastern part of this basin,the fault bend,fault tip,and fault trench(fan)deltas were inherited and further developed,and the source-reservoir configuration conditions were favorable.Exploration deployment was carried out in the Baodao 21 area in the northern step-fault zone and the Yongle 10 area in the southern step-fault zone,where new discoveries in natural gas exploration have been realized.In the eastern part of this basin,the fault bend,fault tip,and fault gully(fan)deltas in the southern and northern fault step zones of Baodao Sag were successively developed,which were beneficial for favorable sourceereservoir configuration conditions.The natural gas exploration successes in the Baodao-21 area in the northern fault step zone and the Yongle-10 area in the southern fault step zone are beneficial for new discoveries in natural gas exploration in the Qiongdongnan Basin.
基金supported by the Key Project of Natural Science Foundation of China"Study on Dynamic Balance Mechanism of Deep Coal Measure Gas System"(No.41530314)the Special and Significant Project of National Science and Technology(Nos.2016ZX05066-01,2016ZX05044-02).
文摘Coal measure gas(CMG),referring to natural gas stored in coal measures,as well as its existence,exploration and production,has been highly concerned recently in natural gas sector in China,and pilot tests of which have been succeeded with some achievements.To provide new geological references,this paper discussed the research progress in CMG co-existence and pooling factors in the respects of the tightening mechanism of coal measure sandstone reservoirs,CMG co-existence and gas pooling assemblages,the superimposed CMG system,and so on.The following findings were obtained.(1)The particularities of CMG geological conditions are shown in three aspects:First,the occurrence and reservoir lithology of CMG are diverse,and the accumulation of sandstone gas in coal measures may be different from that of conventional sandstone gas.Second,the sedimentary environment of coal measures causes the frequent and thin interbedding with various lithologic reservoirs,strong cyclicity and complex gasewater relationship,and the Surat-type CMG is worthy of attention.And third,the sandstone reservoirs in coal measures are embedded in the wide overlying mudstones,the special sourceereservoir match and composite gas reservoirs need to develop adaptive co-exploration and co-production technology.(2)The coal measures are rich in organic matters,and a large number of the organic acids are formed during gas generation from the source rocks,which are important factors for the densification of the sandstone reservoirs in coal measures.And the sandstone reservoirs in coal measures may be characteristic of self-generating and self-storing gas and adsorption to a certain extent,and their physical properties can be improved by organic detritus in the reservoirs.(3)The sedimentology of coal measures defines four generalities for favorable CMG accumulation,but effect of the gas-generating intensity,gas migration system,formation fluid energy and effective regional caprock thickness to the accumulation are variable.The natural gas generated in source rocks is re-allocated with a special migration system in a complex sourceereservoir system,which is an important basis of CMG accumulation.(4)The superimposition of the gas-bearing system is one of the leading problems in CMG research.In recent years,the logging response identification technology of key strata and the superposition identification method of the gas-bearing system have been further developed.It is found that there are three typical types of fluid pressure curves in coal measures.At the same time,the CMG co-accumulation in the whole sense requires a certain threshold depth.Based on the progress above,the theory of CMG accumulation has been improved and deepened,which is helpful in providing more pertinent suggestions for the development of the joint CMG exploration and production technology.
文摘It is of great significance to study the controlling effect of sealing systems on CBM enrichment in coalbed methane (CBM) exploration anddevelopment. In this paper, the relationships between CBM enrichment and geological elements were analyzed. The geological elements includesealing layers (e.g. regional cap rock, regional floor, and immediate roof and floor), later structural adjustment and strata production status. It isshown that CBM tends to enrich in the areas where regional mudstone cap rocks and floors are distributed stably, structures are uplifted andinversed slightly after the hydrocarbon accumulation period and the strata is gentle in a balanced state. Then, the concept of sealing system wasput forward based on the worldwide CBM exploration and development practices over the years. A sealing system refers to a geological unitcomposed of a lateral stable zone and cap rock which prevents gas from migrating upward and downward. In a sealing system, CBM can getenriched and coal-measure gas can also be accumulated. Finally, three gas reservoir types (i.e., sandwich-type CBM reservoir, associated CBM-sandstone gas reservoir and coal-derived sandstone gas reservoir) were identified based on the configuration relationships between elements ofthe CBM (or coal-measure gas) sealing system. It is recommended to change the exploration ideas from simple CBM exploration to 3D CBMand coal-measure gas exploration. In addition, an evaluation index system of CBM (or coal-measure gas) geological selection was established. Itis pointed out that good application effects may be realized if the stereoscopic CBM and coal-measure gas exploration is applied in the JunggarBasin and the eastern margin of the Ordos Basin.
基金the Research Project of CNOOC(Grant No.CT/04-EXP-009)
文摘Natural gases discovered up to now in Lishui Sag,the East China Sea Basin,differ greatly in gaseous compositions,of which hydrocarbon gases amount to 2%―94%while non-hydrocarbon gases are dominated by CO2.Their hydrocarbon gases,without exception,contain less than 90%of methane and over 10%of C2 + heavier hydrocarbons,indicating a wet gas.Carbon isotopic analyses on these hydrocarbon gases showed thatδ13C 1 ,δ13C 2 andδ13C 3 are basically lighter than-44‰,-29‰and-26‰, respectively.The difference in carbon isotopic values between methane and ethane is great,suggesting a biogenic oil-type gas produced by the mixed organic matter at peak generation.δ13C CO2 values of nonhydrocarbon gases are all heavier than-10‰,indicating a typical abiogenic gas.The simulation experiment on hydrocarbon generation of organic matter in a closed gold-tube system showed that the proportion of methane in natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit is obviously higher than that in natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit,consequently the proportion of heavier hydrocarbons of the former is remarkably lower than that of the latter.Moreover, δ13C 1 values of natural gases produced by terrigenous organic matter in the Lingfeng Formation marine deposit are about 5‰heavier than those of natural gases derived from the aquatic and terrigenous mixed organic matter in the Yueguifeng Formation lacustrine deposit whileδ13C 2 andδ13C 3 values of the former are over 9‰heavier than those of the latter.Currently the LS36-1 oil-gas pool is the only commercial oil-gas reservoir in Lishui Sag,where carbon isotopic compositions of various hydrocarbon components differ greatly from those of natural gases produced by the Lingfeng Formation organic matter but are very similar to those of natural gases derived from the Yueguifeng Formation organic matter,therefore,natural gases in the LS36-1 oil-gas pool are mainly derived from the Yueguifeng Formation lacustrine source rock rather than the Lingfeng Formation marine or Mingyuefeng Formation coal-measures source rocks.
