ZrC coatings were deposited on graphite substrates by low pressure chemical vapor deposition（LPCVD） with the Br2-Zr-C3H6-H2-Ar system. The effects of deposition time on the microstructures and growth behavior of ZrC...ZrC coatings were deposited on graphite substrates by low pressure chemical vapor deposition（LPCVD） with the Br2-Zr-C3H6-H2-Ar system. The effects of deposition time on the microstructures and growth behavior of ZrC coatings were investigated. ZrC coating grew in an island-layer mode. The formation of coating was dominated by the nucleation of ZrC in the initial 20 minutes, and the rapid nucleation generated a fine-grained structure of ZrC coating. When the deposition time was over 30 min, the growth of coating was dominated by that of crystals, giving a column-arranged structure. Energy dispersive X-ray spectroscopy showed that the molar ratio of carbon to zirconium was near 1：1 in ZrC coating, and X-ray photoelectron spectroscopy showed that ZrC was the main phase in coatings, accompanied by about 2.5mol% ZrO2 minor phase.展开更多
Self-catalytic reactions have consistently been implicated in the high-temperature corrosion mechanism of NiAl-phase coatings in NaCl-or Na_(2)SO_(4)-containing mediums,with little discussion concerning the adsorption...Self-catalytic reactions have consistently been implicated in the high-temperature corrosion mechanism of NiAl-phase coatings in NaCl-or Na_(2)SO_(4)-containing mediums,with little discussion concerning the adsorption and competitive behavior of complex environmental molecules.This study investigated the adsorption and dissociation behavior of a series of gas-phase molecules(O_(2),H_(2)O,SO_(3),S_(2),H_(2)S,Cl_(2)and HCl)on the NiAl(110)surface using first-principles calculations.The findings reveal a mechanism of competitive adsorption and dissociation,with two distinct adsorption dissociation behaviors observed upon the introduction of Pt or Hf elements.Pt-doping inhibits the surface adsorption behavior of self-catalytic molecules,while Hf significantly enhances the adsorption and dissociation of oxygen-carrying molecules.By preparing three types of NiAl-phase coatings(β-NiAl,(Ni,Pt)Al,and Hf-(Ni,Pt)Al)and conducting corrosion tests in the presence of NaCl or Na_(2)SO_(4),it is determined that the excellent corrosion resistance of Hf-(Ni,Pt)Al can be attributed to the combined effects of Pt in delaying corrosion reactions and Hf in promoting the formation of a protective oxide scale.A comprehensive analysis,combining first-principles calculations and experimental observations,was conducted to elucidate the corrosion mechanisms of three coatings in different corrosion mediums.展开更多
IN the process of forecasts, analyses and numerical treatments of the ground water resource, we often meet with various chemical reaction models. One type of them is three kinds of chemical substance M<sub>1<...IN the process of forecasts, analyses and numerical treatments of the ground water resource, we often meet with various chemical reaction models. One type of them is three kinds of chemical substance M<sub>1</sub>, M<sub>2</sub> and M<sub>3</sub> which can react with each other to produce two new kinds of other chemical compounds: （M<sub>2</sub>）<sub>n</sub> （M<sub>1</sub>）<sub>m</sub> and （M<sub>3</sub>）<sub>r</sub> （M<sub>1</sub>）<sub>κ</sub> at the same time. Usually, these reactions are irreversible and they have the following forms:展开更多
基金Founded by the National Natural Science Foundation of China(No.91216302)the National Program on Key Basic Research Project of the People's Republic of China(No.2015CB655200)
文摘ZrC coatings were deposited on graphite substrates by low pressure chemical vapor deposition（LPCVD） with the Br2-Zr-C3H6-H2-Ar system. The effects of deposition time on the microstructures and growth behavior of ZrC coatings were investigated. ZrC coating grew in an island-layer mode. The formation of coating was dominated by the nucleation of ZrC in the initial 20 minutes, and the rapid nucleation generated a fine-grained structure of ZrC coating. When the deposition time was over 30 min, the growth of coating was dominated by that of crystals, giving a column-arranged structure. Energy dispersive X-ray spectroscopy showed that the molar ratio of carbon to zirconium was near 1：1 in ZrC coating, and X-ray photoelectron spectroscopy showed that ZrC was the main phase in coatings, accompanied by about 2.5mol% ZrO2 minor phase.
基金the sponsorship by the National Natural Science Foundation of China(Nos.51671202 and 52301116)the Fundamental Science Center for Aviation and Gas Turbine Engines(No.P2021-A-IV-002-001)+1 种基金supported by the National Science and Technology Major Project(No.J2019-IV-0006-0074)the Key Research Program of the Chinese Academy of Sciences(No.ZDRW-CN-2021-2-2).
文摘Self-catalytic reactions have consistently been implicated in the high-temperature corrosion mechanism of NiAl-phase coatings in NaCl-or Na_(2)SO_(4)-containing mediums,with little discussion concerning the adsorption and competitive behavior of complex environmental molecules.This study investigated the adsorption and dissociation behavior of a series of gas-phase molecules(O_(2),H_(2)O,SO_(3),S_(2),H_(2)S,Cl_(2)and HCl)on the NiAl(110)surface using first-principles calculations.The findings reveal a mechanism of competitive adsorption and dissociation,with two distinct adsorption dissociation behaviors observed upon the introduction of Pt or Hf elements.Pt-doping inhibits the surface adsorption behavior of self-catalytic molecules,while Hf significantly enhances the adsorption and dissociation of oxygen-carrying molecules.By preparing three types of NiAl-phase coatings(β-NiAl,(Ni,Pt)Al,and Hf-(Ni,Pt)Al)and conducting corrosion tests in the presence of NaCl or Na_(2)SO_(4),it is determined that the excellent corrosion resistance of Hf-(Ni,Pt)Al can be attributed to the combined effects of Pt in delaying corrosion reactions and Hf in promoting the formation of a protective oxide scale.A comprehensive analysis,combining first-principles calculations and experimental observations,was conducted to elucidate the corrosion mechanisms of three coatings in different corrosion mediums.
文摘IN the process of forecasts, analyses and numerical treatments of the ground water resource, we often meet with various chemical reaction models. One type of them is three kinds of chemical substance M<sub>1</sub>, M<sub>2</sub> and M<sub>3</sub> which can react with each other to produce two new kinds of other chemical compounds: （M<sub>2</sub>）<sub>n</sub> （M<sub>1</sub>）<sub>m</sub> and （M<sub>3</sub>）<sub>r</sub> （M<sub>1</sub>）<sub>κ</sub> at the same time. Usually, these reactions are irreversible and they have the following forms:
