The electrical conductivity and piezoresistivity of carbon fiber graphite cement-matrix composites（CFGCC） with carbon fiber content（1% by the weight of cement）,graphite powder contents （0%-50% by the weight of ce...The electrical conductivity and piezoresistivity of carbon fiber graphite cement-matrix composites（CFGCC） with carbon fiber content（1% by the weight of cement）,graphite powder contents （0%-50% by the weight of cement） and CCCW（cementitious capillary crystalline waterproofing materials,4% by the weight of cement） were studied.The experimental results showed that the relationship between the resistivity of CFGCC and the concentration of graphite powders had typical features of percolation phenomena.The percolation threshold was about 20%.A clear piezoresistive effect was observed in CFGCC with 1wt% of carbon fibers,20wt% or 30wt% of graphite powders under uniaxial compressive tests,indicating that this type of smart composites was a promising candidate for strain sensing.The measured gage factor （defined as the fractional change in resistance per unit strain） of CFGCC with graphite content of 20wt% and 30wt% were 37 and 22,respectively.With the addition of CCCW,the mechanical properties of CFGCC were improved,which benefited CFGCC piezoresistivity of stability.展开更多
A kind of piezoresistive response extraction method for smart cement-based composites/sensors was proposed.Two kinds of typical piezoresistive cement-based composites/sensors were fabricated by respectively adding car...A kind of piezoresistive response extraction method for smart cement-based composites/sensors was proposed.Two kinds of typical piezoresistive cement-based composites/sensors were fabricated by respectively adding carbon nanotubes and nickel powders as conductive fillers into cement paste or cement mortar.The variation in measured electrical resistance of such cement-based composites/sensors was explored without loading and under repeated compressive loading and impulsive loading.The experimental results indicate that the measured electrical resistance of piezoresistive cement-based composites/sensors exhibits a two-stage variation trend of fast increase and steady increase with measurement time without loading,and an irreversible increase after loading.This results from polarization caused by ionic conduction in these composites/sensors.After reaching a plateau,the measured electrical resistance can be divided into an electrical resistance part and an electrical capacity part.The piezoresistive responses of electrical resistance part in measured electrical resistance to loading can be extracted by eliminating the linear electrical capacity part in measured electrical resistance.展开更多
Directionally distributed steel fiber cement-based composites(SFCCs)were prepared by magnetic field(MF)induction technology.The orientation factor of steel fibers in the as-obtained SFCCs was determined.Besides,the el...Directionally distributed steel fiber cement-based composites(SFCCs)were prepared by magnetic field(MF)induction technology.The orientation factor of steel fibers in the as-obtained SFCCs was determined.Besides,the electrical resistivity and piezoresistive responses in two directions of aligned steel fiber cement-based composites,i e,parallel and perpendicular to MF,were measured.The effects of several variables,eg,steel fiber content,curing age,humidity,and temperature,on anisotropic electrical property were studied.The cyclic and failure piezoresistive responses in different directions were tested.It is found that the aligned steel fibers in the as-obtained SFCCs have a high orientation factor more than 0.88.Besides,SFCCs with aligned steel fibers exhibit an obvious anisotropic conductivity and piezoelectric sensitivity.The electrical conductivity of SFCCs with aligned steel fibers is less affected by temperature and humidity.At the steel fiber content of 2.5wt%,the piezoelectric sensitivity coefficient of SFCCs in the direction parallel to MF has the highest value of 324.14.In addition,the piezoresistive properties of SFCCs with aligned steel fibers in the direction parallel to MF indicate excellent sensitivity and stability under cyclic loading and monotonic loading.展开更多
In this paper,a split Hopkinson pressure bar(SHPB)was used to investigate the dynamic impact mechanical behavior of sisal fiber-reinforced cement-based composites(SFRCCs),and the microscopic damage evolution of the co...In this paper,a split Hopkinson pressure bar(SHPB)was used to investigate the dynamic impact mechanical behavior of sisal fiber-reinforced cement-based composites(SFRCCs),and the microscopic damage evolution of the composites was analyzed by scanning electron microscopy(SEM)and energy-dispersive X-ray spectrome-try(EDS).The results show that the addition of sisal fibers improves the impact resistance of cement-based composite materials.Compared with ordinary cement-based composites(OCCs),the SFRCCs demonstrate higher post-peak strength,ductility,and energy absorption capacity with higher fiber content.Moreover,the SFRCCs are strain rate sensitive materials,and their peak stress,ultimate strain,and energy integrals all increase with increasing strain rate.From the perspective of fracture failure characteristics,the failure of OCCs is dominated by the brittle failure of crystal cleavage.In contrast,the failure mode of the SFRCCs changes to microscale matrix cracks,multi-scale pull-out interface debonding of fibers(fine filaments and bundles),and mechanical interlock.This research provides an experimental basis for the engineering application of high-performance and green cement-based composites.展开更多
The interfacial transition zone (ITZ) between the aggregates and the bulk paste is the weakest zone of ordinary concrete, which largely determines its mechanical and transporting properties. However, a complete unders...The interfacial transition zone (ITZ) between the aggregates and the bulk paste is the weakest zone of ordinary concrete, which largely determines its mechanical and transporting properties. However, a complete understanding and a quantitative modeling of ITZ are still lacking. Consequently, an integrated modeling and experimental study were conducted. First, the theoretical calculation model of the ITZ volume fraction about the rotary ellipsoidal aggregate particles was established based on the nearest surface function formula. Its calculation programs were written based on Visual Basic 6.0 language and achieved visualization and functionalization. Then, the influencing factors of ITZ volume fraction of the ellipsoidal aggregate particles and the overlapping degree between the ITZ were systematically analyzed. Finally, the calculation models of ITZ volume fraction on actual ellipsoidal aggregate were given, based on cobblestones or pebbles particles with naturally ellipsoidal shape. The results indicate that the calculation model proposed is highly reliable.展开更多
Mercury intrusion porosimetry was used to measure the pore structure of steel fiber reinforced polymer-cement-based composite. The results indicate that the large pore volume decreases by 57. 8% - 51.2% and by 87. 1% ...Mercury intrusion porosimetry was used to measure the pore structure of steel fiber reinforced polymer-cement-based composite. The results indicate that the large pore volume decreases by 57. 8% - 51.2% and by 87. 1% - 88% with the addition of steel fibers and polymers respectively. When both steel fibers and polymers are simultaneously added, the large pore volume decreases by 88.3% - 90.1% . As a surface active material , polymer has a favorable water-reduced and forming-film effect, which is contributed to the decrease of the thickness of water film and the improvement of the conglutination between the fibers and the matrix. Polymers could form a microstructure network. This network structure and the bone structure of cement hydration products penetrate each other and thus the interpenetrating network with sticky aggregate and steel fiber inside forms.展开更多
The texture of interfacial zone between cement paste and quartz in the cement-based composites containing polyvinyl alcohol (PVA), methylcellulose (MC) and their potyblend in an amount of 10 wt % with respect to cemen...The texture of interfacial zone between cement paste and quartz in the cement-based composites containing polyvinyl alcohol (PVA), methylcellulose (MC) and their potyblend in an amount of 10 wt % with respect to cement, as well as the texture of dehydrated bodies of PVA, MC, and the potyblend solutions, were investigated with SEM. The network texture of the dehydrated polyblend is confirmed by comparing the texture of dehydrated bodies of PVA and MC. The network texture has restrained the movement of polyblend molecules in the cement mortar but is helpful to forming a coherent interface between cement paste and quartz. The key factor of forming the coherent interface is not the neutralization reaction between H + from hydrolysis of quarts: and OH- from hydration of cement, but the electrostatic attraction and the chemical reaction between polar groups on the polyblend molecule and cations and onions from hydrolysis of quartz and hydration of cement, respectively. The model of the coherent interface formation is that excessive [HSiO3]- and [SiO3]2- onions are bonded with the hydrated cations such as Ca2+ and Al3+ , which is confirmed by the gel containing Ca and Si on the quartz surface.展开更多
In view of the disadvantage that the mechanical properties of cement-based composites can be significantly reduced by incorporating waste rubber powder in situ, the surface modification methods of the original rubber ...In view of the disadvantage that the mechanical properties of cement-based composites can be significantly reduced by incorporating waste rubber powder in situ, the surface modification methods of the original rubber powder by coupling agent KH560, sodium hydroxide, polyvinyl alcohol (PVA), methyl hydroxyethyl cellulose ether (MHEC) and tetraethyl orthosilicate (TEOS) as precursors were adopted respectively. The modification of waste rubber powder was studied by Change rate of mortar strength of cement-based composite mortar mixed with waste rubber powder. The results show that the hybrid modification method using tetraethyl orthosilicate as precursor has better ef-fect. When 5 phr ethyl orthosilicate is added, the compressive strength and flexural strength of cement-based composite mortar can be increased by 31.7% and 28%. Scanning electron microscopy (SEM) results show that the surface of waste rubber powder with good modification effect has many pro-trusions and flake-like porous structures which are beneficial to its bonding with cement-based materials.展开更多
Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynam...Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynamic size and slower degradation.It is key to develop facile methods to large-scale synthesis of polymer rings with tunable compositions and microstructures.Recent progresses in large-scale synthesis of polymer rings against single-chain dynamic nanoparticles,and the example applications in synchronous enhancing toughness and strength of polymer nanocomposites are summarized.Once there is the breakthrough in rational design and effective large-scale synthesis of polymer rings and their functional derivatives,a family of cyclic functional hybrids would be available,thus providing a new paradigm in developing polymer science and engineering.展开更多
KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to eva...KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to evaluate the influence of varying hydrothermal synthesis temperatures on the physicochemical properties of both the KIT-5/Beta supports and the resulting catalysts.The catalytic performances of catalysts were evaluated under reaction conditions of 320℃,4 MPa H_(2)pressure,and a weight hourly space velocity(WHSV)of 4.8 h^(-1)for hydrodenitrogenation(HDN)of quinoline.The results indicated that the specific surface area and pore structure of the materials could be effectively regulated by adjusting the hydrothermal synthesis temperature,which in turn influenced the number of active sites on the catalyst.The NiW/KB-125 catalyst,synthesized at 125℃,presented the highest quinoline HDN efficiency(96.8%),which can be attributed to its favorable pore channel structure,greater Brønsted acid number,higher degree of metal sulfidation(80.12%)and appropriate metal-support interaction(MSI).展开更多
The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecul...The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.展开更多
Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the...Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.展开更多
The electrical characteristics of cement-based material can be remarkably improved by the addition of short carbon fibers. Carbon fiber reinforced cement composite (CFRC) is an intrinsically smart material that can se...The electrical characteristics of cement-based material can be remarkably improved by the addition of short carbon fibers. Carbon fiber reinforced cement composite (CFRC) is an intrinsically smart material that can sense not only the stress and strain, but also the temperature. In this paper, variations of electrical resistivity with external applied load, and relation of thermoelectric force and temperature were investigated. Test results indicated that the electrical signal is related to the increase in the material volume resistivity during crack generation or propagation and the decrease in the resistivity during crack closure. Moreover, it was found that the fiber addition increased the linearity and reversibility of the Seebeck effect in the cement-based materials. The change of electrical characteristics reflects large amount of information of inner damage and temperature differential of composite, which can be used for stress-strain or thermal self-monitoring by embedding it in the concrete structures.展开更多
Concrete is a continuously evolving material, and even the definition of high-performance concrete has changed over time. In this paper, high-performance characteristics of concrete material are considered to be those...Concrete is a continuously evolving material, and even the definition of high-performance concrete has changed over time. In this paper, high-performance characteristics of concrete material are considered to be those that support the desirable durability, resilience, and sustainability of civil infrastructure that directly impact our quality of life. It is proposed that high-performance material characteristics include tensile ductility, autogenous crack-width control, and material “greenness.” Furthermore, smart functionalities should be aimed at enhancing infrastructure durability, resilience, and sustainability by responding to changes in the surrounding environment of the structure in order to perform desirable functions, thus causing the material to behave in a manner more akin to certain biological materials. Based on recent advances in engineered cementitious composites (ECCs), this paper suggests that concrete embodying such high-performance characteristics and smart multifunctionalities can be designed, and holds the potential to fulfill the expected civil infrastructure needs of the 21st century. Highlights of relevant properties of ECCs are provided, and directions for necessary future research are indicated.展开更多
Ultra-high performance cement-based composites (UHPCC) is promising in construction of concrete structures that suffer impact and explosive loads.In this study,a reference UHPCC mixture with no fiber reinforcement and...Ultra-high performance cement-based composites (UHPCC) is promising in construction of concrete structures that suffer impact and explosive loads.In this study,a reference UHPCC mixture with no fiber reinforcement and four mixtures with a single type of fiber reinforcement or hybrid fiber reinforcements of straight smooth and end hook type of steel fibers were prepared.Split Hopkinson pressure bar (SHPB) was performed to investigate the dynamic compression behavior of UHPCC and X-CT test and 3D reconstruction technology were used to indicate the failure process of UHPCC under impact loading.Results show that UHPCC with 1% straight smooth fiber and 2% end hook fiber reinforcements demonstrated the best static and dynamic mechanical properties.When the hybrid steel fiber reinforcements are added in the concrete,it may need more impact energy to break the matrix and to pull out the fiber reinforcements,thus,the mixture with hybrid steel fiber reinforcements demonstrates excellent dynamic compressive performance.展开更多
N-layered spherical inclusions model was used to calculate the effective diffusion coefficient of chloride ion in cement-based materials by using multi-scale method and then to investigate the relationship between the...N-layered spherical inclusions model was used to calculate the effective diffusion coefficient of chloride ion in cement-based materials by using multi-scale method and then to investigate the relationship between the diffusivity and the microstructure of cement-basted materials where the microstructure included the interfacial transition zone （ITZ） between the aggregates and the bulk cement pastes as well as the microstructure of the bulk cement paste itself. For the convenience of applications, the mortar and concrete were considered as a four-phase spherical model, consisting of cement continuous phase, dispersed aggregates phase, interface transition zone and their homogenized effective medium phase. A general effective medium equation was established to calculate the diffusion coefficient of the hardened cement paste by considering the microstructure. During calculation, the tortuosity （n） and constrictivity factors （Ds/Do） of pore in the hardened pastes are n^3.2, Ds/Do=l.Ox 10-4 respectively from the test data. The calculated results using the n-layered spherical inclusions model are in good agreement with the experimental results; The effective diffusion coefficient of ITZ is 12 times that of the bulk cement for mortar and 17 times for concrete due to the difference between particle size distribution and the volume fraction of aggregates in mortar and concrete.展开更多
With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite h...With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.展开更多
The effects of the component gradient distribution at interface and the fiber gradient distribution on the strength of cement-based materials were studied. The results show that the flexural strength and compressive s...The effects of the component gradient distribution at interface and the fiber gradient distribution on the strength of cement-based materials were studied. The results show that the flexural strength and compressive strength of the mortar and concrete with interface component and fiber gradient distributions are obviously improved. The strengthes of the fiber gradient distributed mortar and concrete (FGDM/C) are higher than those of fiber homogeneously distributed mortar and concrete (FHDM/C). To obtain the same strength, therefore, a smaller fiber volume content in FGDM/C is needed than that in FHDM/C. The results also show that the component gradient distribution of the concrete can be obtained by means of multi-layer vibrating formation.展开更多
In order to realize the full resource utilization of ferronickel slag(FNS)in cement-based materials,this paper studied the influences of mechanical grinding activation on the physical and chemical properties and react...In order to realize the full resource utilization of ferronickel slag(FNS)in cement-based materials,this paper studied the influences of mechanical grinding activation on the physical and chemical properties and reactivity of ferrous extraction tailing of nickel slag(FETNS).Four grinding processes of 5,10,20 and 30 min were set up to evaluate the influence of grinding process on the physical and chemical properties of FETNS with the aid of BET,XRD,Rietveld analysis and particle size distribution.The cement-FETNS composite cementitious material was prepared by replacing cement with 0%,10%,15%,20%,25%and 30%FETNS.The influence of FETNS fineness and content on the properties of composite cementitious system were characterized by mechanical properties,reaction products,early hydration process and pore structure characteristics.The results show that the grinding process can effectively improve the pozzolanic activity of FETNS.The compressive strength of FETNS-M_(30)paste is higher than that of FETNS-M_(5) paste in the early and late stages,and the later strength is higher than that of the baseline group when the content of FETNS-M_(30)is 10%-25%.The pozzolanic activity of FETNS-M_(30)powder is significantly improved and higher than that of FETNS-M_(5) powder.Under the same content,the Ca/Si ratio of C-S-H gel in FETNS-M_(30)paste is small,and the degree of silicate polymerization is higher.When the FETNS-M_(30)content is 10%,the proportions of favorable pores d<50 nm(harmless pores and less-harmful pores)of FETNS-M_(5) paste and FETNS-M_(30)paste is 95.3%and 95.4%,respectively,indicating a denser pore structure of the FETNS-M_(30)paste.展开更多
The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic ...The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW absorbers.In this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis treatment.The results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ratio.Furthermore,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption capacity.Specifically,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was proposed.Therefore,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.展开更多
基金Funded by the National Natural Science Foundation of China(No.50878170 and No. 10672128)
文摘The electrical conductivity and piezoresistivity of carbon fiber graphite cement-matrix composites（CFGCC） with carbon fiber content（1% by the weight of cement）,graphite powder contents （0%-50% by the weight of cement） and CCCW（cementitious capillary crystalline waterproofing materials,4% by the weight of cement） were studied.The experimental results showed that the relationship between the resistivity of CFGCC and the concentration of graphite powders had typical features of percolation phenomena.The percolation threshold was about 20%.A clear piezoresistive effect was observed in CFGCC with 1wt% of carbon fibers,20wt% or 30wt% of graphite powders under uniaxial compressive tests,indicating that this type of smart composites was a promising candidate for strain sensing.The measured gage factor （defined as the fractional change in resistance per unit strain） of CFGCC with graphite content of 20wt% and 30wt% were 37 and 22,respectively.With the addition of CCCW,the mechanical properties of CFGCC were improved,which benefited CFGCC piezoresistivity of stability.
基金Funded by the National Natural Science Foundation of China(Nos. 51178148,50808055)the Natural Scientific Research Innovation Foundation in Harbin Institute of Technology(No.HIT.NSRIF.2009096)the Program for New Century Excellent Talents University of China(No.NCET-0798)
文摘A kind of piezoresistive response extraction method for smart cement-based composites/sensors was proposed.Two kinds of typical piezoresistive cement-based composites/sensors were fabricated by respectively adding carbon nanotubes and nickel powders as conductive fillers into cement paste or cement mortar.The variation in measured electrical resistance of such cement-based composites/sensors was explored without loading and under repeated compressive loading and impulsive loading.The experimental results indicate that the measured electrical resistance of piezoresistive cement-based composites/sensors exhibits a two-stage variation trend of fast increase and steady increase with measurement time without loading,and an irreversible increase after loading.This results from polarization caused by ionic conduction in these composites/sensors.After reaching a plateau,the measured electrical resistance can be divided into an electrical resistance part and an electrical capacity part.The piezoresistive responses of electrical resistance part in measured electrical resistance to loading can be extracted by eliminating the linear electrical capacity part in measured electrical resistance.
基金Funded by the National Natural Science Foundation of China(Nos.51478164 and 52079048)the Key Research&Development Plan of Jiangsu Province,China(No.BE2021704)。
文摘Directionally distributed steel fiber cement-based composites(SFCCs)were prepared by magnetic field(MF)induction technology.The orientation factor of steel fibers in the as-obtained SFCCs was determined.Besides,the electrical resistivity and piezoresistive responses in two directions of aligned steel fiber cement-based composites,i e,parallel and perpendicular to MF,were measured.The effects of several variables,eg,steel fiber content,curing age,humidity,and temperature,on anisotropic electrical property were studied.The cyclic and failure piezoresistive responses in different directions were tested.It is found that the aligned steel fibers in the as-obtained SFCCs have a high orientation factor more than 0.88.Besides,SFCCs with aligned steel fibers exhibit an obvious anisotropic conductivity and piezoelectric sensitivity.The electrical conductivity of SFCCs with aligned steel fibers is less affected by temperature and humidity.At the steel fiber content of 2.5wt%,the piezoelectric sensitivity coefficient of SFCCs in the direction parallel to MF has the highest value of 324.14.In addition,the piezoresistive properties of SFCCs with aligned steel fibers in the direction parallel to MF indicate excellent sensitivity and stability under cyclic loading and monotonic loading.
基金supported within the framework of the Basic Research Project of the Yunnan Province-Young Program(No.2019FD097)Agricultural Joint Special Project of the Yunnan Province-General Program(No.202101BD070001-118).
文摘In this paper,a split Hopkinson pressure bar(SHPB)was used to investigate the dynamic impact mechanical behavior of sisal fiber-reinforced cement-based composites(SFRCCs),and the microscopic damage evolution of the composites was analyzed by scanning electron microscopy(SEM)and energy-dispersive X-ray spectrome-try(EDS).The results show that the addition of sisal fibers improves the impact resistance of cement-based composite materials.Compared with ordinary cement-based composites(OCCs),the SFRCCs demonstrate higher post-peak strength,ductility,and energy absorption capacity with higher fiber content.Moreover,the SFRCCs are strain rate sensitive materials,and their peak stress,ultimate strain,and energy integrals all increase with increasing strain rate.From the perspective of fracture failure characteristics,the failure of OCCs is dominated by the brittle failure of crystal cleavage.In contrast,the failure mode of the SFRCCs changes to microscale matrix cracks,multi-scale pull-out interface debonding of fibers(fine filaments and bundles),and mechanical interlock.This research provides an experimental basis for the engineering application of high-performance and green cement-based composites.
基金Funded by the National Natural Science Foundations of China(Nos.51478278 and 51408380)the Natural Science Foundation of Hebei Province(No.E2014210149)Higher Education Science and Technology Research Project of Hebei Province(No.ZD2016065)
文摘The interfacial transition zone (ITZ) between the aggregates and the bulk paste is the weakest zone of ordinary concrete, which largely determines its mechanical and transporting properties. However, a complete understanding and a quantitative modeling of ITZ are still lacking. Consequently, an integrated modeling and experimental study were conducted. First, the theoretical calculation model of the ITZ volume fraction about the rotary ellipsoidal aggregate particles was established based on the nearest surface function formula. Its calculation programs were written based on Visual Basic 6.0 language and achieved visualization and functionalization. Then, the influencing factors of ITZ volume fraction of the ellipsoidal aggregate particles and the overlapping degree between the ITZ were systematically analyzed. Finally, the calculation models of ITZ volume fraction on actual ellipsoidal aggregate were given, based on cobblestones or pebbles particles with naturally ellipsoidal shape. The results indicate that the calculation model proposed is highly reliable.
文摘Mercury intrusion porosimetry was used to measure the pore structure of steel fiber reinforced polymer-cement-based composite. The results indicate that the large pore volume decreases by 57. 8% - 51.2% and by 87. 1% - 88% with the addition of steel fibers and polymers respectively. When both steel fibers and polymers are simultaneously added, the large pore volume decreases by 88.3% - 90.1% . As a surface active material , polymer has a favorable water-reduced and forming-film effect, which is contributed to the decrease of the thickness of water film and the improvement of the conglutination between the fibers and the matrix. Polymers could form a microstructure network. This network structure and the bone structure of cement hydration products penetrate each other and thus the interpenetrating network with sticky aggregate and steel fiber inside forms.
基金Funded by Natural Science Foundation of China (No. 49802004)
文摘The texture of interfacial zone between cement paste and quartz in the cement-based composites containing polyvinyl alcohol (PVA), methylcellulose (MC) and their potyblend in an amount of 10 wt % with respect to cement, as well as the texture of dehydrated bodies of PVA, MC, and the potyblend solutions, were investigated with SEM. The network texture of the dehydrated polyblend is confirmed by comparing the texture of dehydrated bodies of PVA and MC. The network texture has restrained the movement of polyblend molecules in the cement mortar but is helpful to forming a coherent interface between cement paste and quartz. The key factor of forming the coherent interface is not the neutralization reaction between H + from hydrolysis of quarts: and OH- from hydration of cement, but the electrostatic attraction and the chemical reaction between polar groups on the polyblend molecule and cations and onions from hydrolysis of quartz and hydration of cement, respectively. The model of the coherent interface formation is that excessive [HSiO3]- and [SiO3]2- onions are bonded with the hydrated cations such as Ca2+ and Al3+ , which is confirmed by the gel containing Ca and Si on the quartz surface.
文摘In view of the disadvantage that the mechanical properties of cement-based composites can be significantly reduced by incorporating waste rubber powder in situ, the surface modification methods of the original rubber powder by coupling agent KH560, sodium hydroxide, polyvinyl alcohol (PVA), methyl hydroxyethyl cellulose ether (MHEC) and tetraethyl orthosilicate (TEOS) as precursors were adopted respectively. The modification of waste rubber powder was studied by Change rate of mortar strength of cement-based composite mortar mixed with waste rubber powder. The results show that the hybrid modification method using tetraethyl orthosilicate as precursor has better ef-fect. When 5 phr ethyl orthosilicate is added, the compressive strength and flexural strength of cement-based composite mortar can be increased by 31.7% and 28%. Scanning electron microscopy (SEM) results show that the surface of waste rubber powder with good modification effect has many pro-trusions and flake-like porous structures which are beneficial to its bonding with cement-based materials.
基金Supported by the National Natural Science Foundation of China(Nos.52293472,22473096 and 22471164)。
文摘Among various architectures of polymers,end-group-free rings have attracted growing interests due to their distinct physicochemical performances over the linear counterparts which are exemplified by reduced hydrodynamic size and slower degradation.It is key to develop facile methods to large-scale synthesis of polymer rings with tunable compositions and microstructures.Recent progresses in large-scale synthesis of polymer rings against single-chain dynamic nanoparticles,and the example applications in synchronous enhancing toughness and strength of polymer nanocomposites are summarized.Once there is the breakthrough in rational design and effective large-scale synthesis of polymer rings and their functional derivatives,a family of cyclic functional hybrids would be available,thus providing a new paradigm in developing polymer science and engineering.
基金Supported by the Autonomous Research Project of SKLCC(2024BWZ003)Strategic Priority Research Program of the Chinese Academy of Sciences(XDA0390401)the Doctoral Research Start-up Funding of Shanxi Institute of Technology(026012).
文摘KIT-5/Beta composite supports were synthesized using an in situ self-assembly hydrothermal method,and NiW/KIT-5/Beta catalysts were prepared by impregnation.A series of characterization techniques were utilized to evaluate the influence of varying hydrothermal synthesis temperatures on the physicochemical properties of both the KIT-5/Beta supports and the resulting catalysts.The catalytic performances of catalysts were evaluated under reaction conditions of 320℃,4 MPa H_(2)pressure,and a weight hourly space velocity(WHSV)of 4.8 h^(-1)for hydrodenitrogenation(HDN)of quinoline.The results indicated that the specific surface area and pore structure of the materials could be effectively regulated by adjusting the hydrothermal synthesis temperature,which in turn influenced the number of active sites on the catalyst.The NiW/KB-125 catalyst,synthesized at 125℃,presented the highest quinoline HDN efficiency(96.8%),which can be attributed to its favorable pore channel structure,greater Brønsted acid number,higher degree of metal sulfidation(80.12%)and appropriate metal-support interaction(MSI).
文摘The poor electrical conductivity of metal-organic frameworks(MOFs)limits their electrocatalytic performance in the oxygen evolution reaction(OER).In this study,a Py@Co-MOF composite material based on pyrene(Py)molecules and{[Co2(BINDI)(DMA)_(2)]·DMA}_(n)(Co-MOF,H4BINDI=N,N'-bis(5-isophthalic acid)naphthalenediimide,DMA=N,N-dimethylacetamide)was synthesized via a one-pot method,leveragingπ-πinteractions between pyrene and Co-MOF to modulate electrical conductivity.Results demonstrate that the Py@Co-MOF catalyst exhibited significantly enhanced OER performance compared to pure Co-MOF or pyrene-based electrodes,achieving an overpotential of 246 mV at a current density of 10 mA·cm^(-2) along with excellent stability.Density functional theory(DFT)calculations reveal that the formation of O*in the second step is the rate-determining step(RDS)during the OER process on Co-MOF,with an energy barrier of 0.85 eV due to the weak adsorption affinity of the OH*intermediate for Co sites.CCDC:2419276.
基金support provided by the Center for Fabrication and Application of Electronic Materials at Dokuz Eylül University,Türkiye。
文摘Biochar and biochar composites are versatile materials that can be used in many applications.In this study,biochar was prepared from sawdust and combined with the yttrium iron garnet(YIG)nanocrystal to investigate the shielding effectiveness of the composite structure.Firstly,the effect of the pyrolysis temperature on the shielding effectiveness of biochar was investigated.Secondly,biochars combined with YIG nanocrystals with different contents and shielding effectiveness of the composites were investigated.The electromagnetic effectiveness of the samples was investigated within the X band(8-12 GHz).The findings indicate that biochar demonstrates enhanced absorption properties with elevated pyrolysis temperatures.Biochars demonstrated an approximate 40 d B shielding effectiveness,while YIG exhibited approximately 7 d B,corresponding to absorption at 8 GHz.However,the combination of biochar and YIG exhibited exceptional absorption,reaching 67.12 d B at 8 GHz.
基金This work was supported by NSFC(No.59908007)a foundation for phosphor plan from the Science and Technology Committee of Shanghai Municipality(No.01QE14052)The financial support from the Foundation for the University Key Studies of Shanghai was also gratefully acknowledged.
文摘The electrical characteristics of cement-based material can be remarkably improved by the addition of short carbon fibers. Carbon fiber reinforced cement composite (CFRC) is an intrinsically smart material that can sense not only the stress and strain, but also the temperature. In this paper, variations of electrical resistivity with external applied load, and relation of thermoelectric force and temperature were investigated. Test results indicated that the electrical signal is related to the increase in the material volume resistivity during crack generation or propagation and the decrease in the resistivity during crack closure. Moreover, it was found that the fiber addition increased the linearity and reversibility of the Seebeck effect in the cement-based materials. The change of electrical characteristics reflects large amount of information of inner damage and temperature differential of composite, which can be used for stress-strain or thermal self-monitoring by embedding it in the concrete structures.
基金supported by a grant from the CMMI program at the United States National Science Foundation(1634694).
文摘Concrete is a continuously evolving material, and even the definition of high-performance concrete has changed over time. In this paper, high-performance characteristics of concrete material are considered to be those that support the desirable durability, resilience, and sustainability of civil infrastructure that directly impact our quality of life. It is proposed that high-performance material characteristics include tensile ductility, autogenous crack-width control, and material “greenness.” Furthermore, smart functionalities should be aimed at enhancing infrastructure durability, resilience, and sustainability by responding to changes in the surrounding environment of the structure in order to perform desirable functions, thus causing the material to behave in a manner more akin to certain biological materials. Based on recent advances in engineered cementitious composites (ECCs), this paper suggests that concrete embodying such high-performance characteristics and smart multifunctionalities can be designed, and holds the potential to fulfill the expected civil infrastructure needs of the 21st century. Highlights of relevant properties of ECCs are provided, and directions for necessary future research are indicated.
基金Funded by the National Key Research and Development Program of China(No.2018YFC0705400)National Natural Science Foundation of China(No.51678142)the Fundamental Research Funds for the Central Universities。
文摘Ultra-high performance cement-based composites (UHPCC) is promising in construction of concrete structures that suffer impact and explosive loads.In this study,a reference UHPCC mixture with no fiber reinforcement and four mixtures with a single type of fiber reinforcement or hybrid fiber reinforcements of straight smooth and end hook type of steel fibers were prepared.Split Hopkinson pressure bar (SHPB) was performed to investigate the dynamic compression behavior of UHPCC and X-CT test and 3D reconstruction technology were used to indicate the failure process of UHPCC under impact loading.Results show that UHPCC with 1% straight smooth fiber and 2% end hook fiber reinforcements demonstrated the best static and dynamic mechanical properties.When the hybrid steel fiber reinforcements are added in the concrete,it may need more impact energy to break the matrix and to pull out the fiber reinforcements,thus,the mixture with hybrid steel fiber reinforcements demonstrates excellent dynamic compressive performance.
基金Funded by the National Basic Research Program of China (No.2009CB623203)the National High-Tech R&D Program of China (No.2008AA030794)the Postgraduates Research Innovation in University of Jiangsu Province in China (No.CX10B-064Z)
文摘N-layered spherical inclusions model was used to calculate the effective diffusion coefficient of chloride ion in cement-based materials by using multi-scale method and then to investigate the relationship between the diffusivity and the microstructure of cement-basted materials where the microstructure included the interfacial transition zone （ITZ） between the aggregates and the bulk cement pastes as well as the microstructure of the bulk cement paste itself. For the convenience of applications, the mortar and concrete were considered as a four-phase spherical model, consisting of cement continuous phase, dispersed aggregates phase, interface transition zone and their homogenized effective medium phase. A general effective medium equation was established to calculate the diffusion coefficient of the hardened cement paste by considering the microstructure. During calculation, the tortuosity （n） and constrictivity factors （Ds/Do） of pore in the hardened pastes are n^3.2, Ds/Do=l.Ox 10-4 respectively from the test data. The calculated results using the n-layered spherical inclusions model are in good agreement with the experimental results; The effective diffusion coefficient of ITZ is 12 times that of the bulk cement for mortar and 17 times for concrete due to the difference between particle size distribution and the volume fraction of aggregates in mortar and concrete.
基金sponsored by National Natural Science Foundation of China(No.52302121,No.52203386)Shanghai Sailing Program(No.23YF1454700)+1 种基金Shanghai Natural Science Foundation(No.23ZR1472700)Shanghai Post-doctoral Excellent Program(No.2022664).
文摘With vigorous developments in nanotechnology,the elaborate regulation of microstructure shows attractive potential in the design of electromagnetic wave absorbers.Herein,a hierarchical porous structure and composite heterogeneous interface are constructed successfully to optimize the electromagnetic loss capacity.The macro–micro-synergistic graphene aerogel formed by the ice template‑assisted 3D printing strategy is cut by silicon carbide nanowires(SiC_(nws))grown in situ,while boron nitride(BN)interfacial structure is introduced on graphene nanoplates.The unique composite structure forces multiple scattering of incident EMWs,ensuring the combined effects of interfacial polarization,conduction networks,and magnetic-dielectric synergy.Therefore,the as-prepared composites present a minimum reflection loss value of−37.8 dB and a wide effective absorption bandwidth(EAB)of 9.2 GHz(from 8.8 to 18.0 GHz)at 2.5 mm.Besides,relying on the intrinsic high-temperature resistance of SiC_(nws) and BN,the EAB also remains above 5.0 GHz after annealing in air environment at 600℃ for 10 h.
文摘The effects of the component gradient distribution at interface and the fiber gradient distribution on the strength of cement-based materials were studied. The results show that the flexural strength and compressive strength of the mortar and concrete with interface component and fiber gradient distributions are obviously improved. The strengthes of the fiber gradient distributed mortar and concrete (FGDM/C) are higher than those of fiber homogeneously distributed mortar and concrete (FHDM/C). To obtain the same strength, therefore, a smaller fiber volume content in FGDM/C is needed than that in FHDM/C. The results also show that the component gradient distribution of the concrete can be obtained by means of multi-layer vibrating formation.
基金Funded by the Science and Technology Program of Gansu Province(Nos.25CXGA070,24JRRA213)the National Natural Science Foundation of China(Nos.52468036,52178216,U21A20150)。
文摘In order to realize the full resource utilization of ferronickel slag(FNS)in cement-based materials,this paper studied the influences of mechanical grinding activation on the physical and chemical properties and reactivity of ferrous extraction tailing of nickel slag(FETNS).Four grinding processes of 5,10,20 and 30 min were set up to evaluate the influence of grinding process on the physical and chemical properties of FETNS with the aid of BET,XRD,Rietveld analysis and particle size distribution.The cement-FETNS composite cementitious material was prepared by replacing cement with 0%,10%,15%,20%,25%and 30%FETNS.The influence of FETNS fineness and content on the properties of composite cementitious system were characterized by mechanical properties,reaction products,early hydration process and pore structure characteristics.The results show that the grinding process can effectively improve the pozzolanic activity of FETNS.The compressive strength of FETNS-M_(30)paste is higher than that of FETNS-M_(5) paste in the early and late stages,and the later strength is higher than that of the baseline group when the content of FETNS-M_(30)is 10%-25%.The pozzolanic activity of FETNS-M_(30)powder is significantly improved and higher than that of FETNS-M_(5) powder.Under the same content,the Ca/Si ratio of C-S-H gel in FETNS-M_(30)paste is small,and the degree of silicate polymerization is higher.When the FETNS-M_(30)content is 10%,the proportions of favorable pores d<50 nm(harmless pores and less-harmful pores)of FETNS-M_(5) paste and FETNS-M_(30)paste is 95.3%and 95.4%,respectively,indicating a denser pore structure of the FETNS-M_(30)paste.
基金supported by the Natural Science Research Project of the Anhui Educational Committee,China(No.2022AH050827)the Open Research Fund Program of Anhui Province Key Laboratory of Specialty Polymers,Anhui University of Science and Technology,China(No.AHKLSP23-12)the Joint National-Local Engineering Research Center for Safe and Precise Coal Mining Fund,China(No.EC2022020)。
文摘The preparation of carbon-based electromagnetic wave(EMW)absorbers possessing thin matching thickness,wide absorption bandwidth,strong absorption intensity,and low filling ratio remains a huge challenge.Metal-organic frameworks(MOFs)are ideal self-sacrificing templates for the construction of carbon-based EMW absorbers.In this work,bimetallic FeMn-MOF-derived MnFe_(2)O_(4)/C/graphene composites were fabricated via a two-step route of solvothermal reaction and the following pyrolysis treatment.The results re-veal the evolution of the microscopic morphology of carbon skeletons from loofah-like to octahedral and then to polyhedron and pomegran-ate after the adjustment of the Fe^(3+)to Mn^(2+)molar ratio.Furthermore,at the Fe^(3+)to Mn^(2+)molar ratio of 2:1,the obtained MnFe_(2)O_(4)/C/graphene composite exhibited the highest EMW absorption capacity.Specifically,a minimum reflection loss of-72.7 dB and a max-imum effective absorption bandwidth of 5.1 GHz were achieved at a low filling ratio of 10wt%.In addition,the possible EMW absorp-tion mechanism of MnFe_(2)O_(4)/C/graphene composites was proposed.Therefore,the results of this work will contribute to the construction of broadband and efficient carbon-based EMW absorbers derived from MOFs.
