The world’s production of cocoa highly has grown since 1960.In West Africa,the production reached about 3,000,000 tons in 2012.More than 50%of the world’s production of cocoa comes nowadays from Côte d’Ivoire ...The world’s production of cocoa highly has grown since 1960.In West Africa,the production reached about 3,000,000 tons in 2012.More than 50%of the world’s production of cocoa comes nowadays from Côte d’Ivoire and Ghana and Côte d’Ivoire is the biggest producer.After harvesting,the empty shells,considered as non-useful wastes,are abandoned in the fields where they become a source of pollution.That yields millions of tons of biomass that can be converted into charcoal,instead of being sources of pollution.In the present work,the drying kinetics of the empty wet shells were studied.Then,charcoal production by pyrolysis of those empty shells of cocoa pods was performed,using a carbonisation stove fitted with a chimney.The study showed that the empty shells have a high moisture content.The different phases of the drying were observed.The study compared the drying rates and the diffusion coefficients of a small sample and a big sample.Two experiences of carbonisation of the empty shells were successfully carried out.For the first experiment,the pyrolysis temperatures were recorded and the charcoal mass efficiency calculated.For the second experiment,the temperatures were higher and the result was colored charcoals.The colorations disappeared after some hours.展开更多
The biodegradability of chars derived from pyrolysis and hydrothermal carbonisation(HTC) was studied in short-term dynamic incubation experiments under controlled conditions. Carbon dioxide C(CO2) emissions from soil-...The biodegradability of chars derived from pyrolysis and hydrothermal carbonisation(HTC) was studied in short-term dynamic incubation experiments under controlled conditions. Carbon dioxide C(CO2) emissions from soil-char mixtures in combination with solid digestate or mineral nitrogen(N) fertiliser were measured in dynamic chambers for 10 d. Compared to the original material(maize straw), pyrolysis and HTC chars showed significantly lower CO2 emissions and slower decay dynamics; and compared to the soil control, HTC char increased soil respiration to a significant extent, while pyrolysis char did not. The addition of mineral N resulted in a delayed respiration dynamics for HTC char, while the addition of digestate resulted in an increase in the respired CO2 for pyrolysis char and a decrease for HTC char. For the first time, a peculiar two-stage decay kinetics was observed for HTC char,indicating a highly inhomogeneous substrate consisting at least of two C pools.展开更多
We report the synthesis, characterisation and catalytic performance of two nature-inspired biomassderived electro-catalysts for the oxygen reduction reaction in fuel cells. The catalysts were prepared via pyrolysis of...We report the synthesis, characterisation and catalytic performance of two nature-inspired biomassderived electro-catalysts for the oxygen reduction reaction in fuel cells. The catalysts were prepared via pyrolysis of a real food waste（lobster shells） or by mimicking the composition of lobster shells using chitin and CaCO3 particles followed by acid washing. The simplified model of artificial lobster was prepared for better reproducibility. The calcium carbonate in both samples acts as a pore agent, creating increased surface area and pore volume, though considerably higher in artificial lobster samples due to the better homogeneity of the components. Various characterisation techniques revealed the presence of a considerable amount of hydroxyapatite left in the real lobster samples after acid washing and a low content of carbon（23%）, nitrogen and sulphur（〈1%）, limiting the surface area to 23 m^2/g, and consequently resulting in rather poor catalytic activity. However, artificial lobster samples, with a surface area of ≈200 m^2/g and a nitrogen doping of 2%, showed a promising onset potential, very similar to a commercially available platinum catalyst, with better methanol tolerance, though with lower stability in long time testing over 10,000 s.展开更多
The“biological pumpo”,which is based on the gravity-induced vertical sinking of organic carbon,is one of the primary mechanisms for carbon storage in the ocean[1].Via this mechanism,atmospheric CO_(2) fixed by phyto...The“biological pumpo”,which is based on the gravity-induced vertical sinking of organic carbon,is one of the primary mechanisms for carbon storage in the ocean[1].Via this mechanism,atmospheric CO_(2) fixed by phytoplankton as particulate organic carbon(POC)is transferred from the surface to the deep sea for longterm sequestration.The amount of carbon flux entering the ocean interior is estimated to be approximately 5–10 Gt per year in the form of POC,which represents a major carbon source for deepsea ecosystems and plays a crucial role in global marine biogeochemical cycles and climate change[1].展开更多
基金ASCAD(l’Académie des Sciences,des Cultures,des Arts d’Afrique et de ses Diasporas)for its support to his renewable energy program。
文摘The world’s production of cocoa highly has grown since 1960.In West Africa,the production reached about 3,000,000 tons in 2012.More than 50%of the world’s production of cocoa comes nowadays from Côte d’Ivoire and Ghana and Côte d’Ivoire is the biggest producer.After harvesting,the empty shells,considered as non-useful wastes,are abandoned in the fields where they become a source of pollution.That yields millions of tons of biomass that can be converted into charcoal,instead of being sources of pollution.In the present work,the drying kinetics of the empty wet shells were studied.Then,charcoal production by pyrolysis of those empty shells of cocoa pods was performed,using a carbonisation stove fitted with a chimney.The study showed that the empty shells have a high moisture content.The different phases of the drying were observed.The study compared the drying rates and the diffusion coefficients of a small sample and a big sample.Two experiences of carbonisation of the empty shells were successfully carried out.For the first experiment,the pyrolysis temperatures were recorded and the charcoal mass efficiency calculated.For the second experiment,the temperatures were higher and the result was colored charcoals.The colorations disappeared after some hours.
基金performed within the framework of the SAW project "Biochar in Agriculture:Perspectives for Germany and Malaysia" funded by the Leibniz Association,Germany,within the context of the "Joint Initiative for Research and Innovation"
文摘The biodegradability of chars derived from pyrolysis and hydrothermal carbonisation(HTC) was studied in short-term dynamic incubation experiments under controlled conditions. Carbon dioxide C(CO2) emissions from soil-char mixtures in combination with solid digestate or mineral nitrogen(N) fertiliser were measured in dynamic chambers for 10 d. Compared to the original material(maize straw), pyrolysis and HTC chars showed significantly lower CO2 emissions and slower decay dynamics; and compared to the soil control, HTC char increased soil respiration to a significant extent, while pyrolysis char did not. The addition of mineral N resulted in a delayed respiration dynamics for HTC char, while the addition of digestate resulted in an increase in the respired CO2 for pyrolysis char and a decrease for HTC char. For the first time, a peculiar two-stage decay kinetics was observed for HTC char,indicating a highly inhomogeneous substrate consisting at least of two C pools.
基金the EU for the Intra European Marie Curie Research Fellowship (PIEFGA-2013-623227)
文摘We report the synthesis, characterisation and catalytic performance of two nature-inspired biomassderived electro-catalysts for the oxygen reduction reaction in fuel cells. The catalysts were prepared via pyrolysis of a real food waste（lobster shells） or by mimicking the composition of lobster shells using chitin and CaCO3 particles followed by acid washing. The simplified model of artificial lobster was prepared for better reproducibility. The calcium carbonate in both samples acts as a pore agent, creating increased surface area and pore volume, though considerably higher in artificial lobster samples due to the better homogeneity of the components. Various characterisation techniques revealed the presence of a considerable amount of hydroxyapatite left in the real lobster samples after acid washing and a low content of carbon（23%）, nitrogen and sulphur（〈1%）, limiting the surface area to 23 m^2/g, and consequently resulting in rather poor catalytic activity. However, artificial lobster samples, with a surface area of ≈200 m^2/g and a nitrogen doping of 2%, showed a promising onset potential, very similar to a commercially available platinum catalyst, with better methanol tolerance, though with lower stability in long time testing over 10,000 s.
基金supported by the National Natural Science Foundation of China(42188102 and 42376122)the Scientific Research Foundation of Wuhan Institute of Technology(K202263)+1 种基金the Guangdong Major Project of Basic and Applied Basic Research(2023B0303000017)the Innovation Team Project of Universities in Guangdong Province(2023KCXTD028)。
文摘The“biological pumpo”,which is based on the gravity-induced vertical sinking of organic carbon,is one of the primary mechanisms for carbon storage in the ocean[1].Via this mechanism,atmospheric CO_(2) fixed by phytoplankton as particulate organic carbon(POC)is transferred from the surface to the deep sea for longterm sequestration.The amount of carbon flux entering the ocean interior is estimated to be approximately 5–10 Gt per year in the form of POC,which represents a major carbon source for deepsea ecosystems and plays a crucial role in global marine biogeochemical cycles and climate change[1].
