The recovery of rare earths from industrial rare earth leaching solution is typically achieved through the ammonium carbonate precipitation method,which presents challenges in terms of prolonged production cycle and a...The recovery of rare earths from industrial rare earth leaching solution is typically achieved through the ammonium carbonate precipitation method,which presents challenges in terms of prolonged production cycle and ammonia nitrogen pollution.The present study explored the synthesis of crystalline yttrium carbonate in a sodium carbonate system,employing a conventional mother liquor derived from yttrium chloride.The growth of yttrium carbonate was explored through the lens of density functional theory(DFT)calculations,unveiling a novel perspective on its formation mechanism.The synthesized yttrium carbonate demonstrates enhanced crystallinity,with a D50value of 19.75μm achieved under reaction conditions comprising a temperature of 60℃,stirring rate of 200 r/min,feeding rate of 4 mL/min,and aging time of 30 h.The molar ratio for precipitation is set at 1.6:1.The morphology of yttrium carbonate undergoes a transition from needle-like structures to sheet-like formations,ultimately culminating in the formation of spherical aggregates.The variation in surface energy among distinct crystal planes and CO_(3)^(2-)configurations within crystal cells accounts for this phenomenon.The DFT calculations unveil a progression of growth and trans formation in yttrium carbonate,commencing from a one-dimensional configuration and culminating in a multidimensional morphology.展开更多
Estuaries are often a significant source of atmospheric CO_(2).However,studies of carbonate systems have predominantly focused on large estuaries,while smaller estuaries have scarcely been documented.In this study,we ...Estuaries are often a significant source of atmospheric CO_(2).However,studies of carbonate systems have predominantly focused on large estuaries,while smaller estuaries have scarcely been documented.In this study,we collected surface and bottom seawater carbonate samples in the subtropical Jiulong River Estuary across different tidal levels from 2019 to 2021.The results showed that estuarine mixing of freshwater from the river with seawater was the dominant factor influencing the estuarine carbonate system.Moreover,estuarine mixing is concomitantly impacted by the net metabolism of biological production and decomposition,groundwater input,release of CO_(2)from the estuary,and precipitation or dissolution of calcium carbonate.The estuarine partial pressure of CO_(2)(pCO_(2))varied from 530μatm to 7715μatm,which represents a strong source of atmospheric CO_(2).The mean annual air-sea CO_(2)flux estimated from three different parameterized equations was approximately(25.63±10.25)mol/(m2·a).Furthermore,the annual emission to the atmosphere was approximately(0.031±0.012)Tg C,which accounts for a mere 0.0077%−0.015%of global estuarine emissions.Dissolved inorganic carbon(DIC),total alkalinity(TA)and the pCO_(2)exhibited high variability throughout the tidal cycle across all cruises.Specifically,the disparities observed between DIC and TA during low and high tides at identical stations during all cruises ranged from approximately 15%to 30%.The variance in the pCO_(2)was even more pronounced,ranging from approximately 30%to 40%.Thus,tidal discrepancies may need to be taken into consideration to estimate the CO_(2)flux from estuarine systems more accurately.展开更多
The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, s...The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [CO^2-3 ] is the dominant control on the partition coefficient (KD) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei (300- 355 μm) and Pulleniatina obliquiloculata (355- 400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states (Δ[CO^2-3 ]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients (R2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters (e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between KD values of N. dutertrei and P. obliquiloculata and carbonate system parameters (e.g.,[CO^2-3 ], DIC, ALK, pH and [HCO^-3 ]) in the study area reflect chemical links between the KD denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the KD of N. dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei (300 -355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [CO^2-3 ] show an increase with time, and the record of subsurface seawater pCO2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO2 in the study area was promoted by enhanced upwelling in the Southern Ocean.展开更多
Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water withdrawals.In this study,the wa...Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water withdrawals.In this study,the water chemistry and the controls of carbonate system in an urbanized river(the Fenhe River)on the semi-arid Loess Plateau were analyzed.The water chemistry of the river water showed that the high dissolved inorganic carbon(DIC)concentration(about 37 mg L^(-1))in the upstream with a karst land type was mainly sourced from carbonate weathering involved by H_(2)CO_(3) and H_(2)SO_(4),resulting in an oversaturated partial pressure of CO_(2)(pCO_(2))(about 800μatm).In comparison,damming resulted in the widespread appearance of non-free flowing river segments,and aquatic photosynthesis dominated the DIC and pCO_(2) spatiality demonstrated by the enriched stable isotope of DIC(δ^(13)CDIC).Especially in the mid-downstream flowing through major cities in warm and low-runoff August,some river segments even acted as an atmospheric CO_(2) sink.The noteworthy is wastewater input leading to a sudden increase in DIC(>55 mg L^(-1))and pCO_(2)(>4500μatm)in the downstream of Taiyuan City,and in cold November the increased DIC even extended to the outlet of the river.Our results highlight the effects of aquatic production induced by damming and urban sewage input on riverine CO_(2) system in semi-arid areas,and reducing sewage discharge may mitigate CO_(2) emission from the rivers.展开更多
Tropical waters show different regional aspects due to specificities in their nutrient biogeochemical cycles, which can affect the carbon system and influence their regional role as sinks or sources of CO<sub>2&...Tropical waters show different regional aspects due to specificities in their nutrient biogeochemical cycles, which can affect the carbon system and influence their regional role as sinks or sources of CO<sub>2</sub>. This study was performed on particular tropical areas that present a different seasonal behaviour related to the carbon cycle observed in the late rainy season (July 2013). Understanding the CO<sub>2</sub> drawdown and outgassing potential in these areas is needed to call attention to more long-term monitoring efforts and protect understudied tropical coastal systems more efficiently. This study is focused on nutrient values, hydrological data, biogeochemical carbon behaviour linked to the carbonate system and includes estimates of CO<sub>2</sub> fluxes in three contrasting areas off the northeastern Brazilian shelf: 1) an urbanised estuary (Recife-REC), 2) a coastal Island (Itamaracá-ITA) and 3) an oceanic archipelago (Fernando de Noronha-FN). In general, REC acted as a source, while ITA and FN as carbon sinks. In ITA, despite the high DIC and Total Alkalinity observed (mean ~2360 μmol·kg<sup>-1</sup>), the sink is associated with an effective cascading of atmospheric CO<sub>2</sub> associated with turbulent shallow waters coupled with biogenic removal of and precipitation of CaCO<sub>3</sub> by coralline algae. FN acted as a sink, linked to minor decreases in Total Alkalinity (mean~2295 μmol·kg<sup>-1</sup>) influenced by ammonium-based primary production, nitrogen fixation and sporadic entrainment of nutrient rich waters in the upper thermocline. More studies in different western tropical Atlantic coastal systems can improve the knowledge of tropical shelf seas and their contribution to the ocean carbon budget under specific regional trophic regimes.展开更多
Carbonates present complex pore systems that strongly influence the physical properties and their interrelationships.This study proposes a new approach to establish pore-type mixing-based permeability transforms by in...Carbonates present complex pore systems that strongly influence the physical properties and their interrelationships.This study proposes a new approach to establish pore-type mixing-based permeability transforms by integrating well-log and core data.We investigate the influence of pore-structure heterogeneity on permeability and velocity through the rock-frame flexibility factors(γ and γ_(μ)),derivable using standard sonic and density logs.We derive permeability transforms,with correlation coefficients,R of 0.8 to 0.9,from core measurements and pore-structure variations-dependent physical parameters,namely the porosity exponent(m),Poisson’s ratio(σ),velocity deviation log(VDL),and velocity ratio(VR).Through extrapolation using log-data,the m-and VDL-based correlations provide significantly better permeability estimates,with the highest accuracy attained with the m-based correlation,whereas the VR-andσ-based correlations lead to permeability overes-timation for high porosities.We plotted log-derived porosity vs.permeability,obtained applying the m-based correlation,to generate consistent porosity-permeability relationships,which account for pore-structure heterogeneity,by sorting the scattering points into distinct groups/trends by considering the variations of pore-structure types and abundance of a specific porosity.For the studied oilfield,three porosity-permeability relationships are identified,with correlation coefficients approaching 0.9,thus validating the approach and supporting its application in petrophysically similar reservoirs.展开更多
Enzyme-Induced Carbonate Precipitation(EICP)is an innovative technique to improve soil strength and reduce permeability.However,the use of EICP for reinforcing underwater sand beds remains largely unexplored.To advanc...Enzyme-Induced Carbonate Precipitation(EICP)is an innovative technique to improve soil strength and reduce permeability.However,the use of EICP for reinforcing underwater sand beds remains largely unexplored.To advance EICP implementation in various geotechnical applications,this paper develops a model box system to investigate the effectiveness of the EICP technique in reinforcing underwater sand beds.An"injection-extraction"system is designed to facilitate the flow of the EICP solution through underwater sand layers.Key parameters,including conductivity,pH,and Ca^(2+)concentration of the solution,are measured and analyzed.Electrical resistivity tomography(ERT)is utilized to evaluate the reinforcement effect in the underwater sand bed.The permeability of the model is tested to verify the feasibility of EICP technology for strengthening underwater sands.Furthermore,scanning electron microscope(SEM)is performed to investigate the growth mechanisms of calcium carbonate(CaCO_(3))crystals.The results show that the permeability of the model decreases from 1.28×10^(-2)m/s to 9.66×10^(-5)m/s,representing a reduction of approximately three orders of magnitude.This verifies that the EICP technology can greatly reduce the permeability of underwater sand beds.With increasing grouting cycles,the resistivity of the underwater sand initially decreases and then increases.This variation in sand resistivity is significantly influenced by the ion concentration in the solution,resulting in marked differences in resistivity at various depths and positions within the sand.The findings from this study offer a theoretical basis for the application of EICP technology in reinforcing seabed foundations and supporting marine infrastructure such as offshore pipelines,wind turbines,and oil platforms.展开更多
While oceanic and coastal acidification has gained increased attention,long-term pH trends and their drivers in large freshwater systems remain poorly understood.The Laurentian Great Lakes are the world’s largest fre...While oceanic and coastal acidification has gained increased attention,long-term pH trends and their drivers in large freshwater systems remain poorly understood.The Laurentian Great Lakes are the world’s largest freshwater system,and in many ways resemble marine ecosystems.However,unlike the open ocean and coastal waters where pH has declined due to rising atmospheric CO_(2),no significant pH trends have been observed in the Laurentian Great Lakes,despite significant ecosystem changes driven partly by the invasion of dreissenid mussels.This study examined 41 years of field observations from Lake Michigan to investigate the long-term carbonate chemistry dynamics.Observational results revealed substantial declines in both total alkalinity(TA)and dissolved inorganic carbon(DIC)over the four decades.Mussel shell calcification emerged as the primary mechanism behind these declines,accounting for 97%and 47%of the observed changes in TA and DIC,respectively,lowering water column pH by 0.24 units.Elevated carbon accumulation in soft mussel tissues,coupled with long-term changes in the air-water pCO_(2)gradient during summer,significantly contributed to long-term DIC variations,explaining 18%and 28%of the lake-wide DIC loss.These two mechanisms also resulted in an overall pH increase of 0.09 and 0.12 units,largely offsetting the calcification-driven pH decrease.These findings bridge a gap in acidification research for large freshwater systems and provide valuable insights for comprehensive lake-wide management strategies.展开更多
Microbially induced calcium carbonate precipitation(MICP)is an eco-friendly technology for soil improvement.Although numerous experiments have been conducted to solidify sand foundations using MICP,the mechanisms by w...Microbially induced calcium carbonate precipitation(MICP)is an eco-friendly technology for soil improvement.Although numerous experiments have been conducted to solidify sand foundations using MICP,the mechanisms by which grain interfacial morphologies influencethe MICP process remain unclear.This study utilized 3D-printed flowcells with different boundary morphologies to investigate the effects of interfacial morphologies on the MICP process.CaCO_(3)precipitation characteristics were investigated through microscopic observation and image quantificationanalysis.The results indicate that low flowvelocities near the interface promote bacterial accumulation due to reduced hydrodynamic shear forces.Rough interfaces,compared to smooth ones,enhance bacterial adsorption owing to the larger regions of low flowvelocity,increased surface area,and the formation of local eddies,which promote greater CaCO_(3)precipitation.Compared to the regions away from the interface,a higher abundance of small CaCO_(3)crystals is observed near the interface because of the high urease activity from bacteria and the reduced shear-induced entrainment due to the low flowvelocity.Besides,larger crystals also preferentially precipitate in proximity to interfaces as the low flowvelocity enhances crystal growth according to the particle attachment theory.The presence of rough interfaces further reduces flowvelocities,leading to the precipitation of larger and more densely packed CaCO_(3)crystals.Therefore,rough interfaces promote the microbially induced calcium carbonate precipitation.This work is expected to enhance the understanding of microbially induced calcium carbonate precipitation characteristics on solid surfaces such as soil grains and contribute to the optimization of MICP applications.展开更多
In recent years,the addition of probiotics into non-dairy beverages has gained popularity.Probiotics offer a wider range of options for individuals who are sensitive to dairy products.Incorporating probiotics into wid...In recent years,the addition of probiotics into non-dairy beverages has gained popularity.Probiotics offer a wider range of options for individuals who are sensitive to dairy products.Incorporating probiotics into widely consumed beverages like carbonated soft drinks poses a notable challenge due to the detrimental impact of acidic pH.Herein,results demonstrate that chitosan-coated alginate/gellan gum microcapsules can enhance the viability of probiotics within carbonated soft drinks.The probiotics,Lactobacillus casei,are encapsulated in microcapsules and exposed to Pepsi,Fanta Strawberry,Sprite,and A&W Root Beer under 4 and 25℃for 60 days and simulated gastrointestinal tract.Microcapsules greatly improve the viability of adding probiotics in different beverages under simulated gastrointestinal tract.The probiotics had a gradual release from microcapsules,reaching maximum release within initial 2 h of simulated intestinal phase.During 4℃storage compared to storage at 25℃,it was found that the number of surviving cells is more than the recommended minimum(10^(6)CFU/g)at the end of the storage.The pH and soluble solids content of beverages containing microcapsules also signify little change.This work shows that the chitosan-coated alginate/gellan microcapsules have the potential to be used as protective microcapsules for probiotics in carbonated soft drinks.展开更多
Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In ...Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.展开更多
To enhance the low-carbon economic efficiency and increase the utilization of renewable energy within integrated energy systems(IES),this paper proposes a low-carbon dispatch model integrating power-to-gas(P2G),carbon...To enhance the low-carbon economic efficiency and increase the utilization of renewable energy within integrated energy systems(IES),this paper proposes a low-carbon dispatch model integrating power-to-gas(P2G),carbon capture and storage(CCS),hydrogen fuel cell(HFC),and combined heat and power(CHP).The P2G process is refined into a two-stage structure,and HFC is introduced to enhance hydrogen utilization.Together with CCS and CHP,these devices form a multi-energy conversion system coupling electricity,heat,cooling,and gas.A laddertype carbon trading approach is adopted to flexibly manage carbon output by leveraging marginal cost adjustments.To evaluate the resilience of the proposed low-carbon scheduling strategy involving multiple energy units under the variability of renewable energy,a two-level robust optimization framework is developed.This model captures the most adverse scenarios of wind and solar generation.The dispatch strategy is validated against these extreme conditions to demonstrate its flexibility and effectiveness.The problem is solved using the GUROBI optimization tool.Results from simulations indicate that themodel increases renewable energy integration by 39.1%,and achieves reductions of 15.96%in carbon emissions and 16.29%in operational expenditures.The results demonstrate that the strategy ensures both economic efficiency and environmental performance under uncertain conditions.Compared with existing studies that separately model two-stage P2G or CCS devices,this paper integrates HFC,CHP,and CCS into a unified dispatchable system,enabling refined hydrogen utilization and flexible carbon circulation.Furthermore,the introduction of a laddertype carbon pricing mechanism,combined with multi-energy storage participation in implicit demand response,creates a dynamic and cost-sensitive dispatch framework.These modeling strategies go beyond conventional linear IES formulations and provide more realistic system representations.The proposed approach not only deepens the coupling among electric,thermal,and gas systems,but also offers a feasible pathway for high-penetration renewable integration in low-carbon energy systems.展开更多
The application of conventional manganese dioxide(MnO_(2))materials in sodium-ion supercapacitors(Na-SCs)is considerably limited by their low conductivity and structural instability.Biomimetic morphology engineering c...The application of conventional manganese dioxide(MnO_(2))materials in sodium-ion supercapacitors(Na-SCs)is considerably limited by their low conductivity and structural instability.Biomimetic morphology engineering can optimize the electrochemical performance of MnO_(2).Here,based on the metal-organic frameworks(MOFs)-derived method and electrochemical reconstruction,a coral-like MnO_(2)structure integrated with a functional nitrogen-doped carbon(NC)coating is designed for Na-SC application.The bioinspired coral-like structure captures numerous electrolyte ions and increases the Na+concentration on the electrode surface,which is beneficial for optimizing the Na+transport pathway and accelerating the electrode reaction kinetics.Moreover,the coral-like crosslinked structure effectively enhances the mechanical properties,enabling the maintenance of the structure of MnO_(2)-based electrodes during long-term operation.Furthermore,in/ex-situ characterizations are performed to elucidate the mechanism of lattice transformation during electrochemical phase reconstruction.Additionally,the theoretical calculation and simulation results reveal the ion/electron dynamics in the fabricated electrode.The prepared electrode demonstrates excellent capacitance storage ability(340.7 F g^(−1)at 0.5 A g^(−1))and cycling stability(85.1%capacitance retention after 10,000 cycles).The assembled hybrid device exhibits exceptional life-span(82.0%capacitance retention after 10,000 cycles)and exceptional energy density(36.5 Wh kg^(−1)).This study provides a reliable biomimetic morphology design strategy for MnO_(2)cathodes,paving the way for the fabrication of high-performance Na-SCs.展开更多
Vegetation in terrestrial ecosystems as a carbon sink is a crucial factor in mitigating global warming and reaching carbon neutrality targets,although the drivers of net ecosystem productivity(NEP)under combined human...Vegetation in terrestrial ecosystems as a carbon sink is a crucial factor in mitigating global warming and reaching carbon neutrality targets,although the drivers of net ecosystem productivity(NEP)under combined human and environmental pressures remain poorly understood.In this study,we analyzed the spatiotemporal evolution of NEP in the Horqin Sandy Land,China from 2000 to 2020,and observed the variation in NEP across different land use types.We further identified and quantified the effects of human activities,topographical features,climatic conditions,and soil properties on NEP through the application of structural equation modeling(SEM)and boosted regression trees(BRT).The results showed that the multi-year average NEP ranged from–137.79 to 461.96 g C/m^(2) in the Horqin Sandy Land,with 88.21%of the area showing a significant increasing trend.Among different land use types,forestland exhibited the highest NEP values,followed by cropland,grassland,impervious land,and unused land.The NEP in carbon sink areas was primarily regulated by potential evapotranspiration(negatively correlated)and precipitation(positively correlated).Slope was identified as the most significant positive determinant in carbon source areas.Forestland exhibited climate–topography interactions driving NEP,whereas cropland and grassland relied on temperature;unused land and impervious land were susceptible to land use/cover change and human footprint.This study has significant implications for maintaining the carbon sink function and promoting ecological engineering programs that aim to enhance the capacity of terrestrial carbon sinks in the semi-arid agro-pastoral ecotone.展开更多
The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs ar...The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs are diversified in scale, space configuration, and complex in filling. For this kind of reservoir, a suite of seismic prestack or poststack prediction techniques has been developed based on the separation of seismic wave fields. Through cross-verification of the estimated results,a detailed description of palaeogeomorphology and structural features such as pores, cavities, and fractures in unaka has been achieved, the understanding of the spatial distribution of reservoir improved.展开更多
An ionic liquid system of [Bmim]X/[Bmim]OH(X Cl,BF4,and PF6,) was developed for the hydroly-sis of ethylene carbonate to ethylene glycol. The important parameters,such as the variety of ionic liquids,molar ratio of [B...An ionic liquid system of [Bmim]X/[Bmim]OH(X Cl,BF4,and PF6,) was developed for the hydroly-sis of ethylene carbonate to ethylene glycol. The important parameters,such as the variety of ionic liquids,molar ratio of [Bmim]X to [Bmim]OH,amount of ionic liquid,molar ratio of water to ethylene carbonate,reaction tem-perature,pressure and reaction time,were investigated systematically. Excellent yield(>93%) and high selectivity(99.5%) of ethylene glycol were achieved. Under the optimum reaction conditions,the ionic liquid system could be reused at least five times and the selectivity of ethylene glycol remained higher than 99.5%.展开更多
In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, ...In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.展开更多
On the basis of hydrochemical observation and experimental calculation, the features of stable carbon isotope geochemistry in the karst dynamic systems of the Guilin Karst Experimental Site, Huanglong Ravine and Wujia...On the basis of hydrochemical observation and experimental calculation, the features of stable carbon isotope geochemistry in the karst dynamic systems of the Guilin Karst Experimental Site, Huanglong Ravine and Wujiangdu Dam Site are summarized in this study. Furthermore, an attempt has been made to solve several geochemical problems, such as the origin of CO2 in the system, kinetic fractionation of carbon isotopes during calcite deposition, hydrochemistry and formation of tufa, and carbon-14 dating of tufa of hydrothermal origin. The results show that three kinds of karst dynamic system can be distinguished: (1) the shallow system, such as the Guilin Karst Experimental Site, in which soil CO2 provides the an active agent for karst processes; (2) the geothermal system, such as the Huanglong Ravine, in which metamorphic or/ and juvenile CO, is the source of activity for karst; (3) the anthropogenic system, such as the Wujiangdu Dam Site, in which the stable carbon isotope geochemical and hydrochemical features have been greatly affected by human activity.展开更多
Based on the situation and progress of marine oil/gas exploration in the Sichuan Basin,SW China,the whole petroleum system is divided for marine carbonate rocks of the basin according to the combinations of hydrocarbo...Based on the situation and progress of marine oil/gas exploration in the Sichuan Basin,SW China,the whole petroleum system is divided for marine carbonate rocks of the basin according to the combinations of hydrocarbon accumulation elements,especially the source rock.The hydrocarbon accumulation characteristics of each whole petroleum system are analyzed,the patterns of integrated conventional and unconventional hydrocarbon accumulation are summarized,and the favorable exploration targets are proposed.Under the control of multiple extensional-convergent tectonic cycles,the marine carbonate rocks of the Sichuan Basin contain three sets of regional source rocks and three sets of regional cap rocks,and can be divided into the Cambrian,Silurian and Permian whole petroleum systems.These whole petroleum systems present mainly independent hydrocarbon accumulation,containing natural gas of affinity individually.Locally,large fault zones run through multiple whole petroleum systems,forming a fault-controlled complex whole petroleum system.The hydrocarbon accumulation sequence of continental shelf facies shale gas accumulation,marginal platform facies-controlled gas reservoirs,and intra-platform fault-and facies-controlled gas reservoirs is common in the whole petroleum system,with a stereoscopic accumulation and orderly distribution pattern.High-quality source rock is fundamental to the formation of large gas fields,and natural gas in a whole petroleum system is generally enriched near and within the source rocks.The development and maintenance of large-scale reservoirs are essential for natural gas enrichment,multiple sources,oil and gas transformation,and dynamic adjustment are the characteristics of marine petroleum accumulation,and good preservation conditions are critical to natural gas accumulation.Large-scale marginal-platform reef-bank facies zones,deep shale gas,and large-scale lithological complexes related to source-connected faults are future marine hydrocarbon exploration targets in the Sichuan Basin.展开更多
Utilization of carbon dioxide(CO_(2)) is of great significance in the development of CO_(2) absorption and the solution of greenhouse gas effect.Highly efficient conversion of CO_(2) into cyclic carbonate with green c...Utilization of carbon dioxide(CO_(2)) is of great significance in the development of CO_(2) absorption and the solution of greenhouse gas effect.Highly efficient conversion of CO_(2) into cyclic carbonate with green catalysts is essential for the more sustainable expansion of CO_(2) fixation.Traditional batch reactor is limited by low efficiency, high cost and low security. Meanwhile, continuous flow system showcased a myriad of virtues, including shortening the residence time from hours to seconds, and decreasing reaction temperature, and possessing the nature of easy industrial scale-up. In this paper, a continuous-flow microreaction system was developed to synthesis propylene carbonate(PC) from propylene oxide(PO) and CO_(2) using 1-butyl-3-methylimidazolium bromide([BMIM]Br) as catalyst. By observing the flow patterns inside microreaction system, the effects of reaction temperature, molar fraction of catalyst, operating pressure, residence time, molar ratio of CO_(2)/PO as well as recycling performance of catalyst on the overall performances were comprehensively evaluated into details. Under different reaction conditions,the flow patterns were set to vary between slug flow and annular flow. The results showed that the yield of propylene carbonate(PC) can reach99.7% at 140℃ and 3.0 MPa with the residence time of 166 s, while the recycling performance of the designed system greatly conforms the future trend of green chemistry.展开更多
基金Project supported by the National Natural Science Foundation of China(52174250,92062110)the Youth Jinggang Scholars Program in Jiangxi Province(QNJG2020048)。
文摘The recovery of rare earths from industrial rare earth leaching solution is typically achieved through the ammonium carbonate precipitation method,which presents challenges in terms of prolonged production cycle and ammonia nitrogen pollution.The present study explored the synthesis of crystalline yttrium carbonate in a sodium carbonate system,employing a conventional mother liquor derived from yttrium chloride.The growth of yttrium carbonate was explored through the lens of density functional theory(DFT)calculations,unveiling a novel perspective on its formation mechanism.The synthesized yttrium carbonate demonstrates enhanced crystallinity,with a D50value of 19.75μm achieved under reaction conditions comprising a temperature of 60℃,stirring rate of 200 r/min,feeding rate of 4 mL/min,and aging time of 30 h.The molar ratio for precipitation is set at 1.6:1.The morphology of yttrium carbonate undergoes a transition from needle-like structures to sheet-like formations,ultimately culminating in the formation of spherical aggregates.The variation in surface energy among distinct crystal planes and CO_(3)^(2-)configurations within crystal cells accounts for this phenomenon.The DFT calculations unveil a progression of growth and trans formation in yttrium carbonate,commencing from a one-dimensional configuration and culminating in a multidimensional morphology.
基金The Scientific Research Foundation of Third Institute of Oceanography,MNR under contract Nos.2022001,2020017,2023008 and 2019018the Natural Science Foundation of Fujian Province of China under contract No.2023J01209+1 种基金the National Natural Science Foundation of China under contract No.4237061213the Fujian Science and Technology Innovation Leader Project.
文摘Estuaries are often a significant source of atmospheric CO_(2).However,studies of carbonate systems have predominantly focused on large estuaries,while smaller estuaries have scarcely been documented.In this study,we collected surface and bottom seawater carbonate samples in the subtropical Jiulong River Estuary across different tidal levels from 2019 to 2021.The results showed that estuarine mixing of freshwater from the river with seawater was the dominant factor influencing the estuarine carbonate system.Moreover,estuarine mixing is concomitantly impacted by the net metabolism of biological production and decomposition,groundwater input,release of CO_(2)from the estuary,and precipitation or dissolution of calcium carbonate.The estuarine partial pressure of CO_(2)(pCO_(2))varied from 530μatm to 7715μatm,which represents a strong source of atmospheric CO_(2).The mean annual air-sea CO_(2)flux estimated from three different parameterized equations was approximately(25.63±10.25)mol/(m2·a).Furthermore,the annual emission to the atmosphere was approximately(0.031±0.012)Tg C,which accounts for a mere 0.0077%−0.015%of global estuarine emissions.Dissolved inorganic carbon(DIC),total alkalinity(TA)and the pCO_(2)exhibited high variability throughout the tidal cycle across all cruises.Specifically,the disparities observed between DIC and TA during low and high tides at identical stations during all cruises ranged from approximately 15%to 30%.The variance in the pCO_(2)was even more pronounced,ranging from approximately 30%to 40%.Thus,tidal discrepancies may need to be taken into consideration to estimate the CO_(2)flux from estuarine systems more accurately.
基金The Open Fund of Qingdao National Laboratory for Marine Science and Technology under contract No.QNLM2016ORP0205the Basic Scientific Fund for National Public Research Institutes of China under contract Nos 2017Y07 and 2019S04+3 种基金the National Natural Science Foundation of China under contract Nos 41230959,41830539,91858106 and 41576051the Taishan Scholars Project Fundingthe Shandong Provincial Natural Science Foundation under contract No.ZR2016DQ17the Scientific and Technological Innovation Project of Qingdao National Laboratory for Marine Science and Technology under contract No.2016ASKJ13
文摘The B/Ca ratio of planktonic foraminifer shells has been used as a proxy for reconstructing past ocean carbonate chemistry. However, recent studies have revealed significant uncertainties associated with this proxy, such as whether seawater temperature or [CO^2-3 ] is the dominant control on the partition coefficient (KD) of planktonic foraminiferal B/Ca. To address these uncertainties and thus improve our understanding of the planktonic foraminiferal B/Ca proxy, we analysed B/Ca ratios in the tests of Neogloboquadrina dutertrei (300- 355 μm) and Pulleniatina obliquiloculata (355- 400 μm) in surface sediment samples from the tropical western Pacific and South China Sea. The relationship between these B/Ca ratios and bottom water calcite saturation states (Δ[CO^2-3 ]) is weak, thus suggesting only a small dissolution effect on the B/Ca of the two species. The correlation coefficients (R2) between the B/Ca ratios of N. dutertrei and P. obliquiloculata and environmental parameters (e.g., temperature, salinity, phosphate, DIC and ALK) in the tropical western Pacific and South China Sea are not high enough to justify using B/Ca ratios as a palaeoenvironmental proxy in the study areas. The significant correlation between KD values of N. dutertrei and P. obliquiloculata and carbonate system parameters (e.g.,[CO^2-3 ], DIC, ALK, pH and [HCO^-3 ]) in the study area reflect chemical links between the KD denominator and these variables. Based on our surface sediment calibration, an empirical relationship between the KD of N. dutertrei and temperature is proposed in the tropical western Pacific. We also generated a record of B/Ca ratios in N. dutertrei (300 -355 μm) from Core MD06-3052 in the tropical western Pacific over the past 24 ka to evaluate the application of the revised B/Ca proxy method. Based on the reconstructed empirical relationship for B/Ca and subsurface seawater ALK, we estimated subsurface seawater carbonate system parameters in the tropical western Pacific since 24 ka. In general, the estimated subsurface seawater pH and [CO^2-3 ] show an increase with time, and the record of subsurface seawater pCO2 shows a decrease with time, in the tropical western Pacific over the past 24 ka. The consistent trends in subsurface seawater pCO2 and opal flux during deglaciation may imply that the reported increase in subsurface water pCO2 in the study area was promoted by enhanced upwelling in the Southern Ocean.
基金supported by the National Natural Science Foundation of China (NSFC) (No.41376123)the Youth Project of Shanxi Basic Research (Nos.20210302124317,201901D211383)+1 种基金the Research and Promotion Project of Water Conservancy Science and Technology in Shanxi Province (No.2023GM41)the Science and Technology Innovation Fund of Shanxi Agricultural University (No.2018YJ21)。
文摘Different from rivers in humid areas,the variability of riverine CO_(2) system in arid areas is heavily impacted by anthropogenic disturbance with the increasing urbanization and water withdrawals.In this study,the water chemistry and the controls of carbonate system in an urbanized river(the Fenhe River)on the semi-arid Loess Plateau were analyzed.The water chemistry of the river water showed that the high dissolved inorganic carbon(DIC)concentration(about 37 mg L^(-1))in the upstream with a karst land type was mainly sourced from carbonate weathering involved by H_(2)CO_(3) and H_(2)SO_(4),resulting in an oversaturated partial pressure of CO_(2)(pCO_(2))(about 800μatm).In comparison,damming resulted in the widespread appearance of non-free flowing river segments,and aquatic photosynthesis dominated the DIC and pCO_(2) spatiality demonstrated by the enriched stable isotope of DIC(δ^(13)CDIC).Especially in the mid-downstream flowing through major cities in warm and low-runoff August,some river segments even acted as an atmospheric CO_(2) sink.The noteworthy is wastewater input leading to a sudden increase in DIC(>55 mg L^(-1))and pCO_(2)(>4500μatm)in the downstream of Taiyuan City,and in cold November the increased DIC even extended to the outlet of the river.Our results highlight the effects of aquatic production induced by damming and urban sewage input on riverine CO_(2) system in semi-arid areas,and reducing sewage discharge may mitigate CO_(2) emission from the rivers.
文摘Tropical waters show different regional aspects due to specificities in their nutrient biogeochemical cycles, which can affect the carbon system and influence their regional role as sinks or sources of CO<sub>2</sub>. This study was performed on particular tropical areas that present a different seasonal behaviour related to the carbon cycle observed in the late rainy season (July 2013). Understanding the CO<sub>2</sub> drawdown and outgassing potential in these areas is needed to call attention to more long-term monitoring efforts and protect understudied tropical coastal systems more efficiently. This study is focused on nutrient values, hydrological data, biogeochemical carbon behaviour linked to the carbonate system and includes estimates of CO<sub>2</sub> fluxes in three contrasting areas off the northeastern Brazilian shelf: 1) an urbanised estuary (Recife-REC), 2) a coastal Island (Itamaracá-ITA) and 3) an oceanic archipelago (Fernando de Noronha-FN). In general, REC acted as a source, while ITA and FN as carbon sinks. In ITA, despite the high DIC and Total Alkalinity observed (mean ~2360 μmol·kg<sup>-1</sup>), the sink is associated with an effective cascading of atmospheric CO<sub>2</sub> associated with turbulent shallow waters coupled with biogenic removal of and precipitation of CaCO<sub>3</sub> by coralline algae. FN acted as a sink, linked to minor decreases in Total Alkalinity (mean~2295 μmol·kg<sup>-1</sup>) influenced by ammonium-based primary production, nitrogen fixation and sporadic entrainment of nutrient rich waters in the upper thermocline. More studies in different western tropical Atlantic coastal systems can improve the knowledge of tropical shelf seas and their contribution to the ocean carbon budget under specific regional trophic regimes.
基金supported by the Strategic Priority Research Program of the Chinese Academy of Sciences(No.XDA14010302)the National Key Research and Development Program of China(No.2017YFC0603104)the Ministère de l’Enseignement Supérieur et de la Recherche,Agence Nigérienne des Allocations et des Bourses,ANAB-Niger(No.2015563007).
文摘Carbonates present complex pore systems that strongly influence the physical properties and their interrelationships.This study proposes a new approach to establish pore-type mixing-based permeability transforms by integrating well-log and core data.We investigate the influence of pore-structure heterogeneity on permeability and velocity through the rock-frame flexibility factors(γ and γ_(μ)),derivable using standard sonic and density logs.We derive permeability transforms,with correlation coefficients,R of 0.8 to 0.9,from core measurements and pore-structure variations-dependent physical parameters,namely the porosity exponent(m),Poisson’s ratio(σ),velocity deviation log(VDL),and velocity ratio(VR).Through extrapolation using log-data,the m-and VDL-based correlations provide significantly better permeability estimates,with the highest accuracy attained with the m-based correlation,whereas the VR-andσ-based correlations lead to permeability overes-timation for high porosities.We plotted log-derived porosity vs.permeability,obtained applying the m-based correlation,to generate consistent porosity-permeability relationships,which account for pore-structure heterogeneity,by sorting the scattering points into distinct groups/trends by considering the variations of pore-structure types and abundance of a specific porosity.For the studied oilfield,three porosity-permeability relationships are identified,with correlation coefficients approaching 0.9,thus validating the approach and supporting its application in petrophysically similar reservoirs.
基金supported by the National Youth Top-notch Talent Support Program of China(Grant No.00389335)the National Natural Science Foundation of China(Grant No.52378392)+1 种基金the“Foal Eagle Program”Youth Top-notch Talent Project of Fujian Province(Grant No.00387088)supports are gratefully acknowledged.
文摘Enzyme-Induced Carbonate Precipitation(EICP)is an innovative technique to improve soil strength and reduce permeability.However,the use of EICP for reinforcing underwater sand beds remains largely unexplored.To advance EICP implementation in various geotechnical applications,this paper develops a model box system to investigate the effectiveness of the EICP technique in reinforcing underwater sand beds.An"injection-extraction"system is designed to facilitate the flow of the EICP solution through underwater sand layers.Key parameters,including conductivity,pH,and Ca^(2+)concentration of the solution,are measured and analyzed.Electrical resistivity tomography(ERT)is utilized to evaluate the reinforcement effect in the underwater sand bed.The permeability of the model is tested to verify the feasibility of EICP technology for strengthening underwater sands.Furthermore,scanning electron microscope(SEM)is performed to investigate the growth mechanisms of calcium carbonate(CaCO_(3))crystals.The results show that the permeability of the model decreases from 1.28×10^(-2)m/s to 9.66×10^(-5)m/s,representing a reduction of approximately three orders of magnitude.This verifies that the EICP technology can greatly reduce the permeability of underwater sand beds.With increasing grouting cycles,the resistivity of the underwater sand initially decreases and then increases.This variation in sand resistivity is significantly influenced by the ion concentration in the solution,resulting in marked differences in resistivity at various depths and positions within the sand.The findings from this study offer a theoretical basis for the application of EICP technology in reinforcing seabed foundations and supporting marine infrastructure such as offshore pipelines,wind turbines,and oil platforms.
基金Supported by the National Natural Science Foundation of China(No.43277051)the Key Laboratory of Integrated Regulation and Resources Development of Shallow Lakes of Ministry of Education(No.B230203006).
文摘While oceanic and coastal acidification has gained increased attention,long-term pH trends and their drivers in large freshwater systems remain poorly understood.The Laurentian Great Lakes are the world’s largest freshwater system,and in many ways resemble marine ecosystems.However,unlike the open ocean and coastal waters where pH has declined due to rising atmospheric CO_(2),no significant pH trends have been observed in the Laurentian Great Lakes,despite significant ecosystem changes driven partly by the invasion of dreissenid mussels.This study examined 41 years of field observations from Lake Michigan to investigate the long-term carbonate chemistry dynamics.Observational results revealed substantial declines in both total alkalinity(TA)and dissolved inorganic carbon(DIC)over the four decades.Mussel shell calcification emerged as the primary mechanism behind these declines,accounting for 97%and 47%of the observed changes in TA and DIC,respectively,lowering water column pH by 0.24 units.Elevated carbon accumulation in soft mussel tissues,coupled with long-term changes in the air-water pCO_(2)gradient during summer,significantly contributed to long-term DIC variations,explaining 18%and 28%of the lake-wide DIC loss.These two mechanisms also resulted in an overall pH increase of 0.09 and 0.12 units,largely offsetting the calcification-driven pH decrease.These findings bridge a gap in acidification research for large freshwater systems and provide valuable insights for comprehensive lake-wide management strategies.
基金supported by the National Key Research and Development Program of China(Grant No.2023YFC3707900)National Natural Science Foundation of China(Grant No.42230710,42525201)Key task project for joint research and development of the Yangtze River Delta Science and Technology Innovation Community(Grant No.2022CSJGG1200).
文摘Microbially induced calcium carbonate precipitation(MICP)is an eco-friendly technology for soil improvement.Although numerous experiments have been conducted to solidify sand foundations using MICP,the mechanisms by which grain interfacial morphologies influencethe MICP process remain unclear.This study utilized 3D-printed flowcells with different boundary morphologies to investigate the effects of interfacial morphologies on the MICP process.CaCO_(3)precipitation characteristics were investigated through microscopic observation and image quantificationanalysis.The results indicate that low flowvelocities near the interface promote bacterial accumulation due to reduced hydrodynamic shear forces.Rough interfaces,compared to smooth ones,enhance bacterial adsorption owing to the larger regions of low flowvelocity,increased surface area,and the formation of local eddies,which promote greater CaCO_(3)precipitation.Compared to the regions away from the interface,a higher abundance of small CaCO_(3)crystals is observed near the interface because of the high urease activity from bacteria and the reduced shear-induced entrainment due to the low flowvelocity.Besides,larger crystals also preferentially precipitate in proximity to interfaces as the low flowvelocity enhances crystal growth according to the particle attachment theory.The presence of rough interfaces further reduces flowvelocities,leading to the precipitation of larger and more densely packed CaCO_(3)crystals.Therefore,rough interfaces promote the microbially induced calcium carbonate precipitation.This work is expected to enhance the understanding of microbially induced calcium carbonate precipitation characteristics on solid surfaces such as soil grains and contribute to the optimization of MICP applications.
基金Chulalongkorn University and the National Science and Technology Development Agency(NSTDA)for providing the Chulalongkorn University-NSTDA Doctoral Scholarship,which funded this articlesupport from the 90~(th)Anniversary of Chulalongkorn University Scholarship under the Ratchadaphisek Somphot Endowment Fund。
文摘In recent years,the addition of probiotics into non-dairy beverages has gained popularity.Probiotics offer a wider range of options for individuals who are sensitive to dairy products.Incorporating probiotics into widely consumed beverages like carbonated soft drinks poses a notable challenge due to the detrimental impact of acidic pH.Herein,results demonstrate that chitosan-coated alginate/gellan gum microcapsules can enhance the viability of probiotics within carbonated soft drinks.The probiotics,Lactobacillus casei,are encapsulated in microcapsules and exposed to Pepsi,Fanta Strawberry,Sprite,and A&W Root Beer under 4 and 25℃for 60 days and simulated gastrointestinal tract.Microcapsules greatly improve the viability of adding probiotics in different beverages under simulated gastrointestinal tract.The probiotics had a gradual release from microcapsules,reaching maximum release within initial 2 h of simulated intestinal phase.During 4℃storage compared to storage at 25℃,it was found that the number of surviving cells is more than the recommended minimum(10^(6)CFU/g)at the end of the storage.The pH and soluble solids content of beverages containing microcapsules also signify little change.This work shows that the chitosan-coated alginate/gellan microcapsules have the potential to be used as protective microcapsules for probiotics in carbonated soft drinks.
基金financially supported by the National Natural Science Foundation of China (42477044,32171648 and U23A2017)the Hubei Provincial Science and Technology Program,China (2025AFD451 and 2022CFB030)。
文摘Insight into the carbon turnover in soil aggregates and density fractions is essential for reducing the uncertainty in estimating carbon pools on the Tibetan Plateau,and how they vary with land use type is unclear.In this study,the effect of land use type on carbon storage and fractionation was quantified based on organic carbon and its ^(13)C abundance at the microscale of soil aggregates and density fractions in Tibetan alpine ecosystems.The sequence of soil aggregate destruction in the land use types of plantation(13.1%)<shrubland(32.7%)<grassland(47.9%)<farmland(61.8%)shows that plantations strengthen the soil structure.Plantation land had a greater contribution of light fraction organic carbon(28.3%)but a lower contribution of mineral-associated organic carbon(40.6%)to the carbon stock compared to farmland(13.5 and 70.3%).Interestingly,plantation land enhanced the aggregational differentiation of organic carbon and ^(13)C in each density fraction,whereas no such phenomenon existed in the soil organic carbon.Carbon isotope analyses revealed that carbon transfer in the plantation land occurred from the light fraction in macroaggregates(–24.9‰)to the mineral-associated fraction in microaggregates(–19.9‰).When compared to the other three land use types,the low transferability of carbon in aggregates and density fractions in plantation land provides a stable carbon pool for the Tibetan Plateau.This study shows that plantations can mitigate global climate change by slowing carbon transfer and increasing carbon storage at the microscale of aggregates and density fractions in alpine regions.
基金supported by the Key Project of Shanghai(Project Number A1-0224-25-002-02-040,Municipal Key Course—Heat Transfer)funded by the National Natural Science Foundation of China(Grant No.52077137).
文摘To enhance the low-carbon economic efficiency and increase the utilization of renewable energy within integrated energy systems(IES),this paper proposes a low-carbon dispatch model integrating power-to-gas(P2G),carbon capture and storage(CCS),hydrogen fuel cell(HFC),and combined heat and power(CHP).The P2G process is refined into a two-stage structure,and HFC is introduced to enhance hydrogen utilization.Together with CCS and CHP,these devices form a multi-energy conversion system coupling electricity,heat,cooling,and gas.A laddertype carbon trading approach is adopted to flexibly manage carbon output by leveraging marginal cost adjustments.To evaluate the resilience of the proposed low-carbon scheduling strategy involving multiple energy units under the variability of renewable energy,a two-level robust optimization framework is developed.This model captures the most adverse scenarios of wind and solar generation.The dispatch strategy is validated against these extreme conditions to demonstrate its flexibility and effectiveness.The problem is solved using the GUROBI optimization tool.Results from simulations indicate that themodel increases renewable energy integration by 39.1%,and achieves reductions of 15.96%in carbon emissions and 16.29%in operational expenditures.The results demonstrate that the strategy ensures both economic efficiency and environmental performance under uncertain conditions.Compared with existing studies that separately model two-stage P2G or CCS devices,this paper integrates HFC,CHP,and CCS into a unified dispatchable system,enabling refined hydrogen utilization and flexible carbon circulation.Furthermore,the introduction of a laddertype carbon pricing mechanism,combined with multi-energy storage participation in implicit demand response,creates a dynamic and cost-sensitive dispatch framework.These modeling strategies go beyond conventional linear IES formulations and provide more realistic system representations.The proposed approach not only deepens the coupling among electric,thermal,and gas systems,but also offers a feasible pathway for high-penetration renewable integration in low-carbon energy systems.
基金supported by the National Natural Science Foundation of China(22409065)the Guangdong Basic and Applied Basic Research Foundation(2022A1515011906)+2 种基金the China Postdoctoral Science Foundation(2023M731153)the Research Fund Program of Guangdong Provincial Key Laboratory of Fuel Cell Technologythe Postdoctoral Fellowship Program of CPSF(GZC20230868).
文摘The application of conventional manganese dioxide(MnO_(2))materials in sodium-ion supercapacitors(Na-SCs)is considerably limited by their low conductivity and structural instability.Biomimetic morphology engineering can optimize the electrochemical performance of MnO_(2).Here,based on the metal-organic frameworks(MOFs)-derived method and electrochemical reconstruction,a coral-like MnO_(2)structure integrated with a functional nitrogen-doped carbon(NC)coating is designed for Na-SC application.The bioinspired coral-like structure captures numerous electrolyte ions and increases the Na+concentration on the electrode surface,which is beneficial for optimizing the Na+transport pathway and accelerating the electrode reaction kinetics.Moreover,the coral-like crosslinked structure effectively enhances the mechanical properties,enabling the maintenance of the structure of MnO_(2)-based electrodes during long-term operation.Furthermore,in/ex-situ characterizations are performed to elucidate the mechanism of lattice transformation during electrochemical phase reconstruction.Additionally,the theoretical calculation and simulation results reveal the ion/electron dynamics in the fabricated electrode.The prepared electrode demonstrates excellent capacitance storage ability(340.7 F g^(−1)at 0.5 A g^(−1))and cycling stability(85.1%capacitance retention after 10,000 cycles).The assembled hybrid device exhibits exceptional life-span(82.0%capacitance retention after 10,000 cycles)and exceptional energy density(36.5 Wh kg^(−1)).This study provides a reliable biomimetic morphology design strategy for MnO_(2)cathodes,paving the way for the fabrication of high-performance Na-SCs.
基金funded by the National Major Science and Technology Program for Water Pollution Control and Treatment(2017ZX07101-002)the Discipline Construction Program of ZHANG Huayong,Distinguished Professor of School of Life Sciences,Shandong University(61200082363001).
文摘Vegetation in terrestrial ecosystems as a carbon sink is a crucial factor in mitigating global warming and reaching carbon neutrality targets,although the drivers of net ecosystem productivity(NEP)under combined human and environmental pressures remain poorly understood.In this study,we analyzed the spatiotemporal evolution of NEP in the Horqin Sandy Land,China from 2000 to 2020,and observed the variation in NEP across different land use types.We further identified and quantified the effects of human activities,topographical features,climatic conditions,and soil properties on NEP through the application of structural equation modeling(SEM)and boosted regression trees(BRT).The results showed that the multi-year average NEP ranged from–137.79 to 461.96 g C/m^(2) in the Horqin Sandy Land,with 88.21%of the area showing a significant increasing trend.Among different land use types,forestland exhibited the highest NEP values,followed by cropland,grassland,impervious land,and unused land.The NEP in carbon sink areas was primarily regulated by potential evapotranspiration(negatively correlated)and precipitation(positively correlated).Slope was identified as the most significant positive determinant in carbon source areas.Forestland exhibited climate–topography interactions driving NEP,whereas cropland and grassland relied on temperature;unused land and impervious land were susceptible to land use/cover change and human footprint.This study has significant implications for maintaining the carbon sink function and promoting ecological engineering programs that aim to enhance the capacity of terrestrial carbon sinks in the semi-arid agro-pastoral ecotone.
文摘The carbonate rocks in Tahe oilfield, which suffered from multi-period polycycle karstification and structure deformation, are heterogeneous reservoirs that are rich in pores, cavities,and fractures. The reservoirs are diversified in scale, space configuration, and complex in filling. For this kind of reservoir, a suite of seismic prestack or poststack prediction techniques has been developed based on the separation of seismic wave fields. Through cross-verification of the estimated results,a detailed description of palaeogeomorphology and structural features such as pores, cavities, and fractures in unaka has been achieved, the understanding of the spatial distribution of reservoir improved.
基金Supported by the National High Technology Research and Development Program of China（2006AA06Z317） National Natural Science Foundation of China（20876162）+3 种基金 National Basic Research Program of China（2009CB219901） National Key Technology Research and Development Program（2008BAF33B04） National Science Fund of China（21006117） Science and Technology Project of Beijing（Y090081135）
文摘An ionic liquid system of [Bmim]X/[Bmim]OH(X Cl,BF4,and PF6,) was developed for the hydroly-sis of ethylene carbonate to ethylene glycol. The important parameters,such as the variety of ionic liquids,molar ratio of [Bmim]X to [Bmim]OH,amount of ionic liquid,molar ratio of water to ethylene carbonate,reaction tem-perature,pressure and reaction time,were investigated systematically. Excellent yield(>93%) and high selectivity(99.5%) of ethylene glycol were achieved. Under the optimum reaction conditions,the ionic liquid system could be reused at least five times and the selectivity of ethylene glycol remained higher than 99.5%.
基金supported by the Foundation for Development of Geological Science and Technology of the former Ministry of Geology and Mineral Resources of China grant HY979830
文摘In the early Proterozoic the Li'eryu Formation and Dashiqiao Formation of eastern Liaoning province, China, there are distributed Mg-rich carbonate rock formations, in which large to superlarge deposits of boron, magnesite, talc, Xiuyan jade etc. occur. The formation of these magnesian nonmetallic deposits was related to early Proterozoic evaporates; then these deposits underwent reworking of regional metamorphism and hydrothermal metasomatism during the Lüliang orogeny and tectono-magmatism during the Indosinian-Yanshanian. Among other things, the Mg-rich carbonates formations, minerogenetic structures and ore-forming fluids played a controlling role in the formation of the mineral deposits. Therefore, it can be concluded that the mineral deposits are products of combined processes of the coupling of ore source field, fluid field, thermal field (energy field) and stress field under certain time-space conditions in the early Proterozoic and the late-stage superimposed reworking of tectono-magmatism.
基金This research was supproted by IGCP Project 379, National Natural Science Foundation of China (No. 49632100) and the Ministry of Geology and Mineral Resources of China (No. 9501104, Karst Dynamics Laboratory)
文摘On the basis of hydrochemical observation and experimental calculation, the features of stable carbon isotope geochemistry in the karst dynamic systems of the Guilin Karst Experimental Site, Huanglong Ravine and Wujiangdu Dam Site are summarized in this study. Furthermore, an attempt has been made to solve several geochemical problems, such as the origin of CO2 in the system, kinetic fractionation of carbon isotopes during calcite deposition, hydrochemistry and formation of tufa, and carbon-14 dating of tufa of hydrothermal origin. The results show that three kinds of karst dynamic system can be distinguished: (1) the shallow system, such as the Guilin Karst Experimental Site, in which soil CO2 provides the an active agent for karst processes; (2) the geothermal system, such as the Huanglong Ravine, in which metamorphic or/ and juvenile CO, is the source of activity for karst; (3) the anthropogenic system, such as the Wujiangdu Dam Site, in which the stable carbon isotope geochemical and hydrochemical features have been greatly affected by human activity.
基金Supported by the National Natural Science Foundation of China(42090022)。
文摘Based on the situation and progress of marine oil/gas exploration in the Sichuan Basin,SW China,the whole petroleum system is divided for marine carbonate rocks of the basin according to the combinations of hydrocarbon accumulation elements,especially the source rock.The hydrocarbon accumulation characteristics of each whole petroleum system are analyzed,the patterns of integrated conventional and unconventional hydrocarbon accumulation are summarized,and the favorable exploration targets are proposed.Under the control of multiple extensional-convergent tectonic cycles,the marine carbonate rocks of the Sichuan Basin contain three sets of regional source rocks and three sets of regional cap rocks,and can be divided into the Cambrian,Silurian and Permian whole petroleum systems.These whole petroleum systems present mainly independent hydrocarbon accumulation,containing natural gas of affinity individually.Locally,large fault zones run through multiple whole petroleum systems,forming a fault-controlled complex whole petroleum system.The hydrocarbon accumulation sequence of continental shelf facies shale gas accumulation,marginal platform facies-controlled gas reservoirs,and intra-platform fault-and facies-controlled gas reservoirs is common in the whole petroleum system,with a stereoscopic accumulation and orderly distribution pattern.High-quality source rock is fundamental to the formation of large gas fields,and natural gas in a whole petroleum system is generally enriched near and within the source rocks.The development and maintenance of large-scale reservoirs are essential for natural gas enrichment,multiple sources,oil and gas transformation,and dynamic adjustment are the characteristics of marine petroleum accumulation,and good preservation conditions are critical to natural gas accumulation.Large-scale marginal-platform reef-bank facies zones,deep shale gas,and large-scale lithological complexes related to source-connected faults are future marine hydrocarbon exploration targets in the Sichuan Basin.
基金the supports of the National Natural Science Foundation of China(21991101,21991100)。
文摘Utilization of carbon dioxide(CO_(2)) is of great significance in the development of CO_(2) absorption and the solution of greenhouse gas effect.Highly efficient conversion of CO_(2) into cyclic carbonate with green catalysts is essential for the more sustainable expansion of CO_(2) fixation.Traditional batch reactor is limited by low efficiency, high cost and low security. Meanwhile, continuous flow system showcased a myriad of virtues, including shortening the residence time from hours to seconds, and decreasing reaction temperature, and possessing the nature of easy industrial scale-up. In this paper, a continuous-flow microreaction system was developed to synthesis propylene carbonate(PC) from propylene oxide(PO) and CO_(2) using 1-butyl-3-methylimidazolium bromide([BMIM]Br) as catalyst. By observing the flow patterns inside microreaction system, the effects of reaction temperature, molar fraction of catalyst, operating pressure, residence time, molar ratio of CO_(2)/PO as well as recycling performance of catalyst on the overall performances were comprehensively evaluated into details. Under different reaction conditions,the flow patterns were set to vary between slug flow and annular flow. The results showed that the yield of propylene carbonate(PC) can reach99.7% at 140℃ and 3.0 MPa with the residence time of 166 s, while the recycling performance of the designed system greatly conforms the future trend of green chemistry.
