Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effecti...Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.展开更多
Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductiv...Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductivity and poor shape stability are the main drawbacks in realizing the large-scale application of PCMs.Promisingly,developing composite PCM(CPCM)based on porous supporting mate-rial provides a desirable solution to obtain performance-enhanced PCMs with improved effective thermal conductivity and shape stability.Among all the porous matrixes as supports for PCM,three-dimensional carbon-based porous supporting material has attracted considerable attention ascribing to its high ther-mal conductivity,desirable loading capacity of PCMs,and excellent chemical compatibility with various PCMs.Therefore,this work systemically reviews the CPCMs with three-dimensional carbon-based porous supporting materials.First,a concise rule for the fabrication of CPCMs is illustrated in detail.Next,the experimental and computational research of carbon nanotube-based support,graphene-based support,graphite-based support and amorphous carbon-based support are reviewed.Then,the applications of the shape-stabilized CPCMs including thermal management and thermal conversion are illustrated.Last but not least,the challenges and prospects of the CPCMs are discussed.To conclude,introducing carbon-based porous materials can solve the liquid leakage issue and essentially improve the thermal conductivity of PCMs.However,there is still a long way to further develop a desirable CPCM with higher latent heat capacity,higher thermal conductivity,and more excellent shape stability.展开更多
With the rapid development of industry,the environmental problems caused by heavy metal arsenic and antimony are becoming increasingly serious.Therefore,it is urgent to solve the problem of arsenic and antimony pollut...With the rapid development of industry,the environmental problems caused by heavy metal arsenic and antimony are becoming increasingly serious.Therefore,it is urgent to solve the problem of arsenic and antimony pollution in the water environment.Renewable carbon-based materials,as a kind of adsorbent widely used in wastewater treatment,have been the focus of scholars’research for many years.In this review,the preparation methods,characteristics,and applications of renewable carbon-based materials(biochar,activated carbon,carbon nanotubes,and graphene)for the removal of arsenic and antimony are described in detail.Based on adsorption kinetics,isothermal adsorption,temperature,pH,and coexisting ions,we discuss the process of adsorption of arsenic and antimony by renewable carbon-based materials,explore the mechanism of adsorption of anions in water by renewable carbon-basedmaterials,and comparatively analyze the differences in adsorption performance of arsenic and antimony by different renewable carbon-based materials.Compared with biochar,activated carbon,carbon nanotube,and graphene renewable materials loaded with iron-manganese oxides have better removal effects on arsenic and antimony wastewater.Extensive research data shows that biochar,as a renewable material,is recommended,followed by activated carbon.Both are recommended because of their excellent adsorption properties and low production costs.Finally,the prospects and challenges of the application of renewable carbon-based materials in wastewater treatment are discussed,and the directions and development trends of future research are pointed out,which provide references and insights for further promoting the application of renewable carbon-based materials in wastewater treatment.展开更多
Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based elect...Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based electrode exhibit multi-scale structural characteristics including macroscopic electrode morphologies,mesoscopic microcrystals and pores,and microscopic defects and dopants in the carbon basal plane.Therefore,the ordered combination of multi-scale structures of carbon electrode is crucial for achieving dense energy storage and high volumetric performance by leveraging the functions of various scale structu re.Considering that previous reviews have focused more on the discussion of specific scale structu re of carbon electrodes,this review takes a multi-scale perspective in which recent progresses regarding the structureperformance relationship,underlying mechanism and directional design of carbon-based multi-scale structures including carbon morphology,pore structure,carbon basal plane micro-environment and electrode technology on dense energy storage and volumetric property of supercapacitors are systematically discussed.We analyzed in detail the effects of the morphology,pore,and micro-environment of carbon electrode materials on ion dense storage,summarized the specific effects of different scale structures on volumetric property and recent research progress,and proposed the mutual influence and trade-off relationship between various scale structures.In addition,the challenges and outlooks for improving the dense storage and volumetric performance of carbon-based supercapacitors are analyzed,which can provide feasible technical reference and guidance for the design and manufacture of dense carbon-based electrode materials.展开更多
The rapid advancement of modern electronics has led to a surge in solid electronic waste,which poses significant environmental and health challenges.This review focuses on recent developments in paper-based electronic...The rapid advancement of modern electronics has led to a surge in solid electronic waste,which poses significant environmental and health challenges.This review focuses on recent developments in paper-based electronic devices fabricated through low-cost,hand-printing techniques,with particular emphasis on their applications in energy harvesting,storage,and sensing.Unlike conventional plastic-based substrates,cellulose paper offers several advantages,including biodegradability,recyclability,and low fabrication cost.By integrating functional nanomaterials such as two-dimensional chalcogenides,metal oxides,conductive polymers,and carbon-based structures onto paper,researchers have achieved high-performance devices such as broadband photodetectors(responsivity up to 52 mA/W),supercapacitors(energy density~15.1 mWh/cm^(2)),and pressure sensors(sensitivity~18.42 kPa^(-1)).The hand-printing approach,which eliminates the need for sophisticated equipment and toxic solvents,offers a promising route for scalable,sustainable,and disposable electronics.This review outlines fabrication methods and key performance metrics,and discusses the current challenges and future directions for realizing robust,flexible devices aligned with green technology and the United Nation’s Sustainable Development Goals.展开更多
Sodium ion batteries(SIBs)are one of the most prospective energy storage devices recently.Carbon materials have been commonly used as anode materials for SIBs because of their wide sources and low price.However,pure c...Sodium ion batteries(SIBs)are one of the most prospective energy storage devices recently.Carbon materials have been commonly used as anode materials for SIBs because of their wide sources and low price.However,pure carbon materials still have the disadvantage of low theoretical capacity.New design and preparation strategies for carbon-based composites can overcome the problems.Based on the analysis of Na^(+)storage mechanism of carbon-based composite materials,the factors influencing the performance of SIBs are discussed.Adjustment methods for improving the electrochemical performance of electrodes are evaluated in detail,including carbon skeleton design and composite material selection.Some advanced composite materials,i.e.,carbon-conversion composite and carbon-MXene composite,are also being explored.New advances in flexible electrodes based on carbon-based composite on flexible SIBs is investigated.The existing issues and future issues of carbon-based composite materials are discussed.展开更多
Microbial chain elongation(CE),utilizing anaerobic fermentation for the synthesis of high-value medium chain fatty acids(MCFAs),merges as a promising strategy in resource sustainability.Recently,it has pivoted that th...Microbial chain elongation(CE),utilizing anaerobic fermentation for the synthesis of high-value medium chain fatty acids(MCFAs),merges as a promising strategy in resource sustainability.Recently,it has pivoted that the use of different types of additives or accelerantstowards enhancing the products yield and fermentation quality has got much attention,with carbon-based materials emerging as vital facilitators.Based on bibliometrics insights,this paper firstly commences with a comprehensive review of the past two decades’progress in applying carbon-based materials within anaerobic fermentation contexts.Subsequently,the recent advancements made by different research groups in order to enhance the performance of CE systemperformance are reviewed,with particular focus on the application,impact,and underlying mechanisms of carbon-based materials in expediting MCFAs biosynthesis via CE.Finally,the future research direction is prospected,aiming to inform innovative material design and sophisticated technological applications,as well as provide a reference for improving the efficiency of anaerobic fermentation of MCFAs using carbon-based material,thereby contributing to the broader discourse on enhancing sustainability and efficiency in bio-based processes.展开更多
Carbon-based materials have been widely applied for pollutant removal relying on their rich pore structure,functional groups,chemical stability,and expandability.However,the traditional manufacturing process of carbon...Carbon-based materials have been widely applied for pollutant removal relying on their rich pore structure,functional groups,chemical stability,and expandability.However,the traditional manufacturing process of carbon materials based on organic compounds pyrolysis is high energy-consuming and high-emission,which is not conducive to addressing the climate crisis and achieving the goal of carbon neutrality.Molten salt electrolysis technology enables the direct capture and reduction of CO_(2)to produce solid carbon,resulting in significant environmental benefits while achieving carbon emissions reduction.The molten salt also has a purification function,enabling the production of high-purity carbon materials.The kinetics of the electrochemical reduction process can be easily controlled,and the co-reduction of multiple elements provides convenience for the in-situ optimization of carbon material structure and the expansion of its applications.Therefore,this review focuses on the thermodynamics&kinetics processes of molten salt capture and electrochemical reduction of CO_(2)to prepare carbon materials.It further reviews the recent research progress on the preparation of carbon materials for pollutant removal based on molten salt electrochemical processes for the first time.Finally,we analyze the advantages and challenges of the current molten salt electrochemical processes and offers prospects for future research directions.展开更多
Hydrogen peroxide(H_(2)O_(2))is an essential environmentally friendly oxidant with a wide range of applications.Compared with traditional anthraquinone processes,the electrochemical synthesis of H_(2)O_(2)via the two-...Hydrogen peroxide(H_(2)O_(2))is an essential environmentally friendly oxidant with a wide range of applications.Compared with traditional anthraquinone processes,the electrochemical synthesis of H_(2)O_(2)via the two-electron oxygen reduction reaction and two-electron water oxidation reaction offers a more promising and sustainable alternative.Carbon-based electrocatalysts playing a crucial role in these processes owing to their abundance and facile functionalization.This review focuses on the strategic design of carbon-based electrocatalysts to enhance H_(2)O_(2)production.We begin by highlighting the significance of H_(2)O_(2)and the fundamental mechanisms of electrochemical process.Subsequently,we present a detailed analysis of key factors affecting catalytic performance,concentrating electronic structure and geometric structure regulation as primary catalyst design approaches to improve H_(2)O_(2)production.Interface engineering and pH effects are also emphasized for their crucial roles.Finally,the major challenges and prospects for advancing H_(2)O_(2)production towards practical applications are discussed.展开更多
This special issue will include reviews,regular papers,and short communications,and reports in the fields for next generation electronics and photonics.The topics include but not restricted in advanced microelectronic...This special issue will include reviews,regular papers,and short communications,and reports in the fields for next generation electronics and photonics.The topics include but not restricted in advanced microelectronic devices and materials,low-dimensional materials and novel nanodevice applications,flexible/wearable/implantable electronics,wide bandgap semiconductor materials and devices,photoelectronics,photonics,advanced display technologies,nanophotonics,integrated quantum photonics,photovoltaics,energy harvesting and self-powered wireless sensing,sensors,micro-actuators,MEMS,microfluidics,and bioMEMS,etc.展开更多
Soft electronics,which are designed to function under mechanical deformation(such as bending,stretching,and folding),have become essential in applications like wearable electronics,artificial skin,and brain-machine in...Soft electronics,which are designed to function under mechanical deformation(such as bending,stretching,and folding),have become essential in applications like wearable electronics,artificial skin,and brain-machine interfaces.Crystalline silicon is one of the most mature and reliable materials for high-performance electronics;however,its intrinsic brittleness and rigidity pose challenges for integrating it into soft electronics.Recent research has focused on overcoming these limitations by utilizing structural design techniques to impart flexibility and stretchability to Si-based materials,such as transforming them into thin nanomembranes or nanowires.This review summarizes key strategies in geometry engineering for integrating crystalline silicon into soft electronics,from the use of hard silicon islands to creating out-of-plane foldable silicon nanofilms on flexible substrates,and ultimately to shaping silicon nanowires using vapor-liquid-solid or in-plane solid-liquid-solid techniques.We explore the latest developments in Si-based soft electronic devices,with applications in sensors,nanoprobes,robotics,and brain-machine interfaces.Finally,the paper discusses the current challenges in the field and outlines future research directions to enable the widespread adoption of silicon-based flexible electronics.展开更多
The present teaching content of the power electronics course is insufficient to cover the power electronics technology used in building electrical engineering.This paper analyzes the relationship between building elec...The present teaching content of the power electronics course is insufficient to cover the power electronics technology used in building electrical engineering.This paper analyzes the relationship between building electrical engineering and power electronics technology,investigates the main power electronics technology used in building electrical engineering,introduces the teaching content of current power electronics course,analyzes the insufficiency of current teaching content related to the practice of electrical engineering,and proposes the principles and directions for the reformation and innovation of the teaching content of the course of power electronics for the major of building electricity and intelligence.展开更多
Transient electronics is a versatile tool that finds applications in various fields,including medical biology,environmental protection,and data information security.In the context of data protection,the traditional pa...Transient electronics is a versatile tool that finds applications in various fields,including medical biology,environmental protection,and data information security.In the context of data protection,the traditional passive degradation transient mode is being replaced by the active destruction mode,which features a short self-destruction time and provides greater resistance to recovery.This article presents an overview of recent progress in transient electronics,assessing the benefits and suitability of varying transient mechanisms.The article also analyses the influence of transient electronics on military security while emphasizing the advantages of implementing energetic materials.Besides,the article introduces energetic transient devices and evaluates their ability to support the autonomous operation of transient electronic devices.展开更多
The Cooling Storage Ring(CSR)external-target experiment(CEE)will be the first large-scale nuclear physics experiment at the Heavy Ion Research Facility in Lanzhou(HIRFL).A beam monitor has been developed to monitor th...The Cooling Storage Ring(CSR)external-target experiment(CEE)will be the first large-scale nuclear physics experiment at the Heavy Ion Research Facility in Lanzhou(HIRFL).A beam monitor has been developed to monitor the beam status and to improve the reconstruction resolution of the primary vertex.Custom-designed pixel charge sensors,named TopmetalCEEv1,are employed in the detector to locate the position of each particle.Readout electronics for the beam monitor were designed,including front-end electronics utilizing the Topmetal-CEEv1 sensors,as well as a readout and control unit that communicates with the DAQ,trigger,and clock systems.A series of tests were performed to validate the functionality and performance of the system,including basic electronic verifications and responses toαparticles and heavy-ion beams.The results show that all designed functions of the readout electronics system work well,and this system could be used for beam monitoring in the CEE experiment.展开更多
A rapidly growing field is piezoresistive sensor for accurate respiration rate monitoring to suppress the worldwide respiratory illness.However,a large neglected issue is the sensing durability and accuracy without in...A rapidly growing field is piezoresistive sensor for accurate respiration rate monitoring to suppress the worldwide respiratory illness.However,a large neglected issue is the sensing durability and accuracy without interference since the expiratory pressure always coupled with external humidity and temperature variations,as well as mechanical motion artifacts.Herein,a robust and biodegradable piezoresistive sensor is reported that consists of heterogeneous MXene/cellulose-gelation sensing layer and Ag-based interdigital electrode,featuring customizable cylindrical interface arrangement and compact hierarchical laminated architecture for collectively regulating the piezoresistive response and mechanical robustness,thereby realizing the long-term breath-induced pressure detection.Notably,molecular dynamics simulations reveal the frequent angle inversion and reorientation of MXene/cellulose in vacuum filtration,driven by shear forces and interfacial interactions,which facilitate the establishment of hydrogen bonds and optimize the architecture design in sensing layer.The resultant sensor delivers unprecedented collection features of superior stability for off-axis deformation(0-120°,~2.8×10^(-3) A)and sensing accuracy without crosstalk(humidity 50%-100%and temperature 30-80).Besides,the sensor-embedded mask together with machine learning models is achieved to train and classify the respiration status for volunteers with different ages(average prediction accuracy~90%).It is envisioned that the customizable architecture design and sensor paradigm will shed light on the advanced stability of sustainable electronics and pave the way for the commercial application in respiratory monitory.展开更多
Conjugated polymers(CPs)have emerged as an interesting class of materials in modern electronics and photonics,characterized by their unique delocalizedπ-electron systems that confer high flexibility,tunable electroni...Conjugated polymers(CPs)have emerged as an interesting class of materials in modern electronics and photonics,characterized by their unique delocalizedπ-electron systems that confer high flexibility,tunable electronic properties,and solution processability.These organic polymers present a compelling alternative to traditional inorganic semiconductors,offering the potential for a new generation of optoelectronic devices.This review explores the evolving role of CPs,exploring the molecular design strategies and innovative approaches that enhance their optoelectronic properties.We highlight notable progress toward developing faster,more efficient,and environmentally friendly devices by analyzing recent advancements in CP-based devices,including organic photovoltaics,field-effect transistors,and nonvolatile memories.The integration of CPs in flexible sustainable technologies underscores their potential to revolutionize future electronic and photonic systems.As ongoing research pushes the frontiers of molecular engineering and device architecture,CPs are poised to play an essential role in shaping next-generation technologies that prioritize performance,sustainability,and adaptability.展开更多
Cu nanoparticles exhibit excellent properties as high-temperature-resistant,conductive,heat-dissipating,and connecting materials.However,their susceptibility to oxidation poses a major challenge to the production of h...Cu nanoparticles exhibit excellent properties as high-temperature-resistant,conductive,heat-dissipating,and connecting materials.However,their susceptibility to oxidation poses a major challenge to the production of high-quality sintered bodies in the air,severely limiting their widespread adoption in power electronics packaging.This study presents a novel approach to the synthesis of Cu nanoparticles capped with oleylamine ligands.By employing a simple solvent-cleaning process,effective control of the density of oleylamine ligands on particle surfaces was achieved,resulting in high-performance Cu nanoparticles with both oxidation resistance and air-sintering susceptibility.Moreover,through our research,the solvent-cleaning mechanism was clarified,a model for the oleylamine ligand decomposition was developed,the air-sintering behavior of Cu nanoparticles was analyzed,and the impacts of both the sintered bodies and interfaces on the sintering performance were explained.Additionally,Cu nanoparticles subjected to 5 cleaning rounds followed by sintering at 280℃and 5 MPa in air were confirmed to be able to produce the highest shear strength(49.2±3.51 MPa)and lowest resistivity(6.15±0.32μΩ·cm).Based on these results,flexible capacitive pressure sensors with Cu sintered electrodes were fabricated and demonstrated a stable pressure-capacitance response over the temperature range of 25-250℃.These findings underscore the impressive robustness and durability of sintered structures and the potential for high-temperature applications of oleylamine-capped Cu nanoparticles.Our study provides reliable application demonstrations for the low-cost manufacture of high-performance power electronics packaging structures that can operate in high-current-density,high-heat-flow-density,high-temperature,and high-stress environments.展开更多
Flexible pressure sensors show great promise for applications in such fields as electronic skin,healthcare,and intelligent robotics.Traditional capacitive pressure sensors,however,face the problem of low sensitivity,w...Flexible pressure sensors show great promise for applications in such fields as electronic skin,healthcare,and intelligent robotics.Traditional capacitive pressure sensors,however,face the problem of low sensitivity,which limits their wider application.In this paper,a flexible capacitive pressure sensor with microstructured ionization layer is fabricated by a sandwich-type process,with a low-cost and simple process of inverted molding with sandpapers being used to form a thermoplastic polyurethane elastomer ionic film with double-sided microstructure as the dielectric layer of the sensor,with silver nanowires as electrodes.The operating mechanism of this iontronic pressure sensor is analyzed using a graphical method,and the sensor is tested on a pressure platform.The test results show that the sensor has ultrahigh pressure sensitivities of 3.744 and 1.689 kPa^(−1) at low(0-20 kPa)and high(20-800 kPa)pressures,respectively,as well as a rapid response time(100 ms),and it exhibits good stability and repeatability.The sensor can be used for sensitive monitoring of activities such as finger bending,and for facial expression(smile,frown)recognition,as well as speech recognition.展开更多
Textiles with electronic components offer a portable and personalized approach for health monitoring and therapy.However,there is a lack of reliable strategy to integrate layered circuits and high-density chips on or ...Textiles with electronic components offer a portable and personalized approach for health monitoring and therapy.However,there is a lack of reliable strategy to integrate layered circuits and high-density chips on or inside textiles,which hinders system-level functionality and untethered user experiences.Herein,we propose monolithically integrated textile hybrid electronics(THE)on a textile platform,with multimodal functions and reliable performances.The textile system encompasses flexible electrodes,laser-induced sensors,and surface-mount devices,along with double-layer circuits interconnecting all of them.Vertical conductive paths are rendered by liquid metal composites infiltrated into textiles,which allows resistances less than 0.1?while reserving intact textile structures.The assembled THE exhibits endurance to handwashing and crumpling,as well as bendability.We customize a wireless textile patch for synchronously tracking multiple physiological indicators during exercise.Furthermore,a textile band is elaborated for monitoring and alleviating muscular fatigue,demonstrating potential in closed-loop diagnosis and treatment.展开更多
Wearable electronics incorporating proteins for biocompatibility have garnered significant research attention,given their potential applications in biocompatible medical devices,artificial skin,humanoid robots,and oth...Wearable electronics incorporating proteins for biocompatibility have garnered significant research attention,given their potential applications in biocompatible medical devices,artificial skin,humanoid robots,and other fields.However,a notable challenge exists,as many wearable electronics currently lack those essential properties due to issues such as non-biological compatibility,as well as insufficient mechanical and conductive performance.Here,we have developed a hybrid keratin(KE)hydrogel by incorporating a liquid metal(LM,eutectic gallium-indium alloy)to design a wearable electronic device with excellent biocompatibility,enhanced conductivity,and good mechanical properties.The resulting keratin liquid metal(KELM)hydrogel demonstrates favorable mechanical characteristics,including good tensile strength(166 kPa),impressive stretchability(2600%),and long-term stability.Furthermore,it exhibits good conductivity(6.84 S·m^(-1))and sensitivity as a sensing material(gauge factor(GF)=7.03),rendering it suitable for constructing high-performance strain sensors.Notably,the KELM hydrogel-based wearable electronics extend their functionality to monitoring marine inhabitants'health.This innovative application provides new insights for designing the next generation of biomimetic electronic devices,with potential applications in human-machine interfaces,electronic skin,artificial intelligence,and health monitoring.展开更多
文摘Supercapacitors are gaining popularity due to their high cycling stability,power density,and fast charge and discharge rates.Researchers are ex-ploring electrode materials,electrolytes,and separat-ors for cost-effective energy storage systems.Ad-vances in materials science have led to the develop-ment of hybrid nanomaterials,such as combining fil-amentous carbon forms with inorganic nanoparticles,to create new charge and energy transfer processes.Notable materials for electrochemical energy-stor-age applications include MXenes,2D transition met-al carbides,and nitrides,carbon black,carbon aerogels,activated carbon,carbon nanotubes,conducting polymers,carbon fibers,and nanofibers,and graphene,because of their thermal,electrical,and mechanical properties.Carbon materials mixed with conducting polymers,ceramics,metal oxides,transition metal oxides,metal hydroxides,transition metal sulfides,trans-ition metal dichalcogenide,metal sulfides,carbides,nitrides,and biomass materials have received widespread attention due to their remarkable performance,eco-friendliness,cost-effectiveness,and renewability.This article explores the development of carbon-based hybrid materials for future supercapacitors,including electric double-layer capacitors,pseudocapacitors,and hy-brid supercapacitors.It investigates the difficulties that influence structural design,manufacturing(electrospinning,hydro-thermal/solvothermal,template-assisted synthesis,electrodeposition,electrospray,3D printing)techniques and the latest car-bon-based hybrid materials research offer practical solutions for producing high-performance,next-generation supercapacitors.
基金supported by the National Natural Science Foundation of China(No.52127816),the National Key Research and Development Program of China(No.2020YFA0715000)the National Natural Science and Hong Kong Research Grant Council Joint Research Funding Project of China(No.5181101182)the NSFC/RGC Joint Research Scheme sponsored by the Research Grants Council of Hong Kong and the National Natural Science Foundation of China(No.N_PolyU513/18).
文摘Latent heat thermal energy storage(TES)effectively reduces the mismatch between energy supply and demand of renewable energy sources by the utilization of phase change materials(PCMs).However,the low thermal conductivity and poor shape stability are the main drawbacks in realizing the large-scale application of PCMs.Promisingly,developing composite PCM(CPCM)based on porous supporting mate-rial provides a desirable solution to obtain performance-enhanced PCMs with improved effective thermal conductivity and shape stability.Among all the porous matrixes as supports for PCM,three-dimensional carbon-based porous supporting material has attracted considerable attention ascribing to its high ther-mal conductivity,desirable loading capacity of PCMs,and excellent chemical compatibility with various PCMs.Therefore,this work systemically reviews the CPCMs with three-dimensional carbon-based porous supporting materials.First,a concise rule for the fabrication of CPCMs is illustrated in detail.Next,the experimental and computational research of carbon nanotube-based support,graphene-based support,graphite-based support and amorphous carbon-based support are reviewed.Then,the applications of the shape-stabilized CPCMs including thermal management and thermal conversion are illustrated.Last but not least,the challenges and prospects of the CPCMs are discussed.To conclude,introducing carbon-based porous materials can solve the liquid leakage issue and essentially improve the thermal conductivity of PCMs.However,there is still a long way to further develop a desirable CPCM with higher latent heat capacity,higher thermal conductivity,and more excellent shape stability.
基金funded by the following grants,including the Key Research and Development Programof Shaanxi Province(Nos.2023-LL-QY-42,2024NC-ZDCYL-02-05)the Xi’an University of Architecture and Technology Research Initiation Grant Program(No.1960323102)+1 种基金the Xi’an University of Architecture and Technology Special Program for Cultivation of Frontier Interdisciplinary Fields(No.X20230079)the Open Fund for the Key Laboratory of Soil and Plant Nutrition of Ningxia(No.ZHS202401).
文摘With the rapid development of industry,the environmental problems caused by heavy metal arsenic and antimony are becoming increasingly serious.Therefore,it is urgent to solve the problem of arsenic and antimony pollution in the water environment.Renewable carbon-based materials,as a kind of adsorbent widely used in wastewater treatment,have been the focus of scholars’research for many years.In this review,the preparation methods,characteristics,and applications of renewable carbon-based materials(biochar,activated carbon,carbon nanotubes,and graphene)for the removal of arsenic and antimony are described in detail.Based on adsorption kinetics,isothermal adsorption,temperature,pH,and coexisting ions,we discuss the process of adsorption of arsenic and antimony by renewable carbon-based materials,explore the mechanism of adsorption of anions in water by renewable carbon-basedmaterials,and comparatively analyze the differences in adsorption performance of arsenic and antimony by different renewable carbon-based materials.Compared with biochar,activated carbon,carbon nanotube,and graphene renewable materials loaded with iron-manganese oxides have better removal effects on arsenic and antimony wastewater.Extensive research data shows that biochar,as a renewable material,is recommended,followed by activated carbon.Both are recommended because of their excellent adsorption properties and low production costs.Finally,the prospects and challenges of the application of renewable carbon-based materials in wastewater treatment are discussed,and the directions and development trends of future research are pointed out,which provide references and insights for further promoting the application of renewable carbon-based materials in wastewater treatment.
基金funded by the Joint Fund for Regional Innovation and Development of National Natural Science Foundation of China(U21A20143)the National Science Fund for Excellent Young Scholars(52322607)the Excellent Youth Foundation of Heilongjiang Scientific Committee(YQ2022E028)。
文摘Improving the volumetric energy density of supercapacitors is essential for practical applications,which highly relies on the dense storage of ions in carbon-based electrodes.The functional units of carbon-based electrode exhibit multi-scale structural characteristics including macroscopic electrode morphologies,mesoscopic microcrystals and pores,and microscopic defects and dopants in the carbon basal plane.Therefore,the ordered combination of multi-scale structures of carbon electrode is crucial for achieving dense energy storage and high volumetric performance by leveraging the functions of various scale structu re.Considering that previous reviews have focused more on the discussion of specific scale structu re of carbon electrodes,this review takes a multi-scale perspective in which recent progresses regarding the structureperformance relationship,underlying mechanism and directional design of carbon-based multi-scale structures including carbon morphology,pore structure,carbon basal plane micro-environment and electrode technology on dense energy storage and volumetric property of supercapacitors are systematically discussed.We analyzed in detail the effects of the morphology,pore,and micro-environment of carbon electrode materials on ion dense storage,summarized the specific effects of different scale structures on volumetric property and recent research progress,and proposed the mutual influence and trade-off relationship between various scale structures.In addition,the challenges and outlooks for improving the dense storage and volumetric performance of carbon-based supercapacitors are analyzed,which can provide feasible technical reference and guidance for the design and manufacture of dense carbon-based electrode materials.
基金The Consortium for Scientific Research,Indore(CSR,Indore)(No.CRS/2021-22/01/426)is acknowledged by the authorsFor the research facilities,the authors are grateful to CHARUSAT University.
文摘The rapid advancement of modern electronics has led to a surge in solid electronic waste,which poses significant environmental and health challenges.This review focuses on recent developments in paper-based electronic devices fabricated through low-cost,hand-printing techniques,with particular emphasis on their applications in energy harvesting,storage,and sensing.Unlike conventional plastic-based substrates,cellulose paper offers several advantages,including biodegradability,recyclability,and low fabrication cost.By integrating functional nanomaterials such as two-dimensional chalcogenides,metal oxides,conductive polymers,and carbon-based structures onto paper,researchers have achieved high-performance devices such as broadband photodetectors(responsivity up to 52 mA/W),supercapacitors(energy density~15.1 mWh/cm^(2)),and pressure sensors(sensitivity~18.42 kPa^(-1)).The hand-printing approach,which eliminates the need for sophisticated equipment and toxic solvents,offers a promising route for scalable,sustainable,and disposable electronics.This review outlines fabrication methods and key performance metrics,and discusses the current challenges and future directions for realizing robust,flexible devices aligned with green technology and the United Nation’s Sustainable Development Goals.
基金support from the National Natural Science Foundation of China(52376216,52006194,52006191)the Key Research and Development Program of Shaanxi(2023-YBGY-054).
文摘Sodium ion batteries(SIBs)are one of the most prospective energy storage devices recently.Carbon materials have been commonly used as anode materials for SIBs because of their wide sources and low price.However,pure carbon materials still have the disadvantage of low theoretical capacity.New design and preparation strategies for carbon-based composites can overcome the problems.Based on the analysis of Na^(+)storage mechanism of carbon-based composite materials,the factors influencing the performance of SIBs are discussed.Adjustment methods for improving the electrochemical performance of electrodes are evaluated in detail,including carbon skeleton design and composite material selection.Some advanced composite materials,i.e.,carbon-conversion composite and carbon-MXene composite,are also being explored.New advances in flexible electrodes based on carbon-based composite on flexible SIBs is investigated.The existing issues and future issues of carbon-based composite materials are discussed.
基金financially supported by the National Key R&D Program of China(No.2019YFC1906600)the National Natural Science Foundation of China(No.52000132).
文摘Microbial chain elongation(CE),utilizing anaerobic fermentation for the synthesis of high-value medium chain fatty acids(MCFAs),merges as a promising strategy in resource sustainability.Recently,it has pivoted that the use of different types of additives or accelerantstowards enhancing the products yield and fermentation quality has got much attention,with carbon-based materials emerging as vital facilitators.Based on bibliometrics insights,this paper firstly commences with a comprehensive review of the past two decades’progress in applying carbon-based materials within anaerobic fermentation contexts.Subsequently,the recent advancements made by different research groups in order to enhance the performance of CE systemperformance are reviewed,with particular focus on the application,impact,and underlying mechanisms of carbon-based materials in expediting MCFAs biosynthesis via CE.Finally,the future research direction is prospected,aiming to inform innovative material design and sophisticated technological applications,as well as provide a reference for improving the efficiency of anaerobic fermentation of MCFAs using carbon-based material,thereby contributing to the broader discourse on enhancing sustainability and efficiency in bio-based processes.
基金supported by the National Natural Science Foundation of China(Nos.52200143,51979011 and 52276208)the Natural Science Foundation of Hubei Province(No.2024AFB546)the Fundamental Research Funds for Central Public Welfare Research Institutes(Nos.CKSF2023302/CL and CKSF2023314/CL).
文摘Carbon-based materials have been widely applied for pollutant removal relying on their rich pore structure,functional groups,chemical stability,and expandability.However,the traditional manufacturing process of carbon materials based on organic compounds pyrolysis is high energy-consuming and high-emission,which is not conducive to addressing the climate crisis and achieving the goal of carbon neutrality.Molten salt electrolysis technology enables the direct capture and reduction of CO_(2)to produce solid carbon,resulting in significant environmental benefits while achieving carbon emissions reduction.The molten salt also has a purification function,enabling the production of high-purity carbon materials.The kinetics of the electrochemical reduction process can be easily controlled,and the co-reduction of multiple elements provides convenience for the in-situ optimization of carbon material structure and the expansion of its applications.Therefore,this review focuses on the thermodynamics&kinetics processes of molten salt capture and electrochemical reduction of CO_(2)to prepare carbon materials.It further reviews the recent research progress on the preparation of carbon materials for pollutant removal based on molten salt electrochemical processes for the first time.Finally,we analyze the advantages and challenges of the current molten salt electrochemical processes and offers prospects for future research directions.
基金funding supporting from the National Natural Science Foundation of China(Grant No.22125903,22439003,22309176)National Key R@D Program of China(Grants 2022YFA1504100)+2 种基金DICP(DICP I202471)the State Key Laboratory of Catalysis(No:2024SKL-A-001)Energy Revolution S&T Program of Yulin Innovation Institute of Clean Energy(Grant E412010508,Grant E411070316)。
文摘Hydrogen peroxide(H_(2)O_(2))is an essential environmentally friendly oxidant with a wide range of applications.Compared with traditional anthraquinone processes,the electrochemical synthesis of H_(2)O_(2)via the two-electron oxygen reduction reaction and two-electron water oxidation reaction offers a more promising and sustainable alternative.Carbon-based electrocatalysts playing a crucial role in these processes owing to their abundance and facile functionalization.This review focuses on the strategic design of carbon-based electrocatalysts to enhance H_(2)O_(2)production.We begin by highlighting the significance of H_(2)O_(2)and the fundamental mechanisms of electrochemical process.Subsequently,we present a detailed analysis of key factors affecting catalytic performance,concentrating electronic structure and geometric structure regulation as primary catalyst design approaches to improve H_(2)O_(2)production.Interface engineering and pH effects are also emphasized for their crucial roles.Finally,the major challenges and prospects for advancing H_(2)O_(2)production towards practical applications are discussed.
文摘This special issue will include reviews,regular papers,and short communications,and reports in the fields for next generation electronics and photonics.The topics include but not restricted in advanced microelectronic devices and materials,low-dimensional materials and novel nanodevice applications,flexible/wearable/implantable electronics,wide bandgap semiconductor materials and devices,photoelectronics,photonics,advanced display technologies,nanophotonics,integrated quantum photonics,photovoltaics,energy harvesting and self-powered wireless sensing,sensors,micro-actuators,MEMS,microfluidics,and bioMEMS,etc.
基金the National Natural Science Foundation of China under granted No.62104100National Key Research Program of China under No.92164201+1 种基金National Natural Science Foundation of China for Distinguished Young Scholars under No.62325403National Natural Science Foundation of China under No.61934004.
文摘Soft electronics,which are designed to function under mechanical deformation(such as bending,stretching,and folding),have become essential in applications like wearable electronics,artificial skin,and brain-machine interfaces.Crystalline silicon is one of the most mature and reliable materials for high-performance electronics;however,its intrinsic brittleness and rigidity pose challenges for integrating it into soft electronics.Recent research has focused on overcoming these limitations by utilizing structural design techniques to impart flexibility and stretchability to Si-based materials,such as transforming them into thin nanomembranes or nanowires.This review summarizes key strategies in geometry engineering for integrating crystalline silicon into soft electronics,from the use of hard silicon islands to creating out-of-plane foldable silicon nanofilms on flexible substrates,and ultimately to shaping silicon nanowires using vapor-liquid-solid or in-plane solid-liquid-solid techniques.We explore the latest developments in Si-based soft electronic devices,with applications in sensors,nanoprobes,robotics,and brain-machine interfaces.Finally,the paper discusses the current challenges in the field and outlines future research directions to enable the widespread adoption of silicon-based flexible electronics.
基金Cloud Course of Beijing University of Civil Engineering and Architecture at Super Star Learning(YC240109)。
文摘The present teaching content of the power electronics course is insufficient to cover the power electronics technology used in building electrical engineering.This paper analyzes the relationship between building electrical engineering and power electronics technology,investigates the main power electronics technology used in building electrical engineering,introduces the teaching content of current power electronics course,analyzes the insufficiency of current teaching content related to the practice of electrical engineering,and proposes the principles and directions for the reformation and innovation of the teaching content of the course of power electronics for the major of building electricity and intelligence.
基金supported by the National Natural Science Foun-dation of China(Grant No.52206165)Key R&D Projects in Sichuan Province(Grant No.2022YFG0219)。
文摘Transient electronics is a versatile tool that finds applications in various fields,including medical biology,environmental protection,and data information security.In the context of data protection,the traditional passive degradation transient mode is being replaced by the active destruction mode,which features a short self-destruction time and provides greater resistance to recovery.This article presents an overview of recent progress in transient electronics,assessing the benefits and suitability of varying transient mechanisms.The article also analyses the influence of transient electronics on military security while emphasizing the advantages of implementing energetic materials.Besides,the article introduces energetic transient devices and evaluates their ability to support the autonomous operation of transient electronic devices.
基金supported by the National Natural Science Foundation of China(Nos.11927901,12105110,U2032209,12275105)the National Key Research and Development Program of China(Nos.2020YFE0202002,2022YFA1602103)the Fundamental Research Funds for the Central Universities(No.CCNU22QN005)。
文摘The Cooling Storage Ring(CSR)external-target experiment(CEE)will be the first large-scale nuclear physics experiment at the Heavy Ion Research Facility in Lanzhou(HIRFL).A beam monitor has been developed to monitor the beam status and to improve the reconstruction resolution of the primary vertex.Custom-designed pixel charge sensors,named TopmetalCEEv1,are employed in the detector to locate the position of each particle.Readout electronics for the beam monitor were designed,including front-end electronics utilizing the Topmetal-CEEv1 sensors,as well as a readout and control unit that communicates with the DAQ,trigger,and clock systems.A series of tests were performed to validate the functionality and performance of the system,including basic electronic verifications and responses toαparticles and heavy-ion beams.The results show that all designed functions of the readout electronics system work well,and this system could be used for beam monitoring in the CEE experiment.
基金supported by the National Natural Science Foundation of China(22074072,22274083,52376199)the Shandong Provincial Natural Science Foundation(ZR2023LZY005)+1 种基金the Exploration Project of the State Key Laboratory of BioFibers and EcoTextiles of Qingdao University(TSKT202101)the Fundamental Research Funds for the Central Universities(2022BLRD13,2023BLRD01).
文摘A rapidly growing field is piezoresistive sensor for accurate respiration rate monitoring to suppress the worldwide respiratory illness.However,a large neglected issue is the sensing durability and accuracy without interference since the expiratory pressure always coupled with external humidity and temperature variations,as well as mechanical motion artifacts.Herein,a robust and biodegradable piezoresistive sensor is reported that consists of heterogeneous MXene/cellulose-gelation sensing layer and Ag-based interdigital electrode,featuring customizable cylindrical interface arrangement and compact hierarchical laminated architecture for collectively regulating the piezoresistive response and mechanical robustness,thereby realizing the long-term breath-induced pressure detection.Notably,molecular dynamics simulations reveal the frequent angle inversion and reorientation of MXene/cellulose in vacuum filtration,driven by shear forces and interfacial interactions,which facilitate the establishment of hydrogen bonds and optimize the architecture design in sensing layer.The resultant sensor delivers unprecedented collection features of superior stability for off-axis deformation(0-120°,~2.8×10^(-3) A)and sensing accuracy without crosstalk(humidity 50%-100%and temperature 30-80).Besides,the sensor-embedded mask together with machine learning models is achieved to train and classify the respiration status for volunteers with different ages(average prediction accuracy~90%).It is envisioned that the customizable architecture design and sensor paradigm will shed light on the advanced stability of sustainable electronics and pave the way for the commercial application in respiratory monitory.
基金Khalifa University,Abu Dhabi,for the generous support of this researchthe financial support from the Khalifa University Research&Innovation Grant(RIG-2023-005)。
文摘Conjugated polymers(CPs)have emerged as an interesting class of materials in modern electronics and photonics,characterized by their unique delocalizedπ-electron systems that confer high flexibility,tunable electronic properties,and solution processability.These organic polymers present a compelling alternative to traditional inorganic semiconductors,offering the potential for a new generation of optoelectronic devices.This review explores the evolving role of CPs,exploring the molecular design strategies and innovative approaches that enhance their optoelectronic properties.We highlight notable progress toward developing faster,more efficient,and environmentally friendly devices by analyzing recent advancements in CP-based devices,including organic photovoltaics,field-effect transistors,and nonvolatile memories.The integration of CPs in flexible sustainable technologies underscores their potential to revolutionize future electronic and photonic systems.As ongoing research pushes the frontiers of molecular engineering and device architecture,CPs are poised to play an essential role in shaping next-generation technologies that prioritize performance,sustainability,and adaptability.
基金supported by the Natural Science Foundation of Fujian Province(No.2022J01044)the Digital Twin and Intelligent Transportation Maintenance Engineering Research Centre of Genting Applied Technology R&D Platform at Xiamen City University.
文摘Cu nanoparticles exhibit excellent properties as high-temperature-resistant,conductive,heat-dissipating,and connecting materials.However,their susceptibility to oxidation poses a major challenge to the production of high-quality sintered bodies in the air,severely limiting their widespread adoption in power electronics packaging.This study presents a novel approach to the synthesis of Cu nanoparticles capped with oleylamine ligands.By employing a simple solvent-cleaning process,effective control of the density of oleylamine ligands on particle surfaces was achieved,resulting in high-performance Cu nanoparticles with both oxidation resistance and air-sintering susceptibility.Moreover,through our research,the solvent-cleaning mechanism was clarified,a model for the oleylamine ligand decomposition was developed,the air-sintering behavior of Cu nanoparticles was analyzed,and the impacts of both the sintered bodies and interfaces on the sintering performance were explained.Additionally,Cu nanoparticles subjected to 5 cleaning rounds followed by sintering at 280℃and 5 MPa in air were confirmed to be able to produce the highest shear strength(49.2±3.51 MPa)and lowest resistivity(6.15±0.32μΩ·cm).Based on these results,flexible capacitive pressure sensors with Cu sintered electrodes were fabricated and demonstrated a stable pressure-capacitance response over the temperature range of 25-250℃.These findings underscore the impressive robustness and durability of sintered structures and the potential for high-temperature applications of oleylamine-capped Cu nanoparticles.Our study provides reliable application demonstrations for the low-cost manufacture of high-performance power electronics packaging structures that can operate in high-current-density,high-heat-flow-density,high-temperature,and high-stress environments.
基金supported by the Youth Project of the National Natural Science Foundation of China(Grant No.52105594)the Youth Project of the Applied Basic Research Program of Shanxi Province(Grant No.20210302124274)+4 种基金the Key Research and Development Program of Shanxi Province(Grant No.202102030201005)the Natural Youth Science Foundation of Shanxi Province(Grant Nos.202103021223005 and 202203021212015)the Fund for Shanxi 1331 Project,the Science and Technology Innovation Plan for Colleges and Universities in Shanxi Province(Grant No.2022L575)the Science and Technology Innovation Project in Higher Schools in Shanxi(Grant No.J2020383)Teaching Reform and Innovation Project of the Education Department of Shanxi Province(Grant No.J20221195).
文摘Flexible pressure sensors show great promise for applications in such fields as electronic skin,healthcare,and intelligent robotics.Traditional capacitive pressure sensors,however,face the problem of low sensitivity,which limits their wider application.In this paper,a flexible capacitive pressure sensor with microstructured ionization layer is fabricated by a sandwich-type process,with a low-cost and simple process of inverted molding with sandpapers being used to form a thermoplastic polyurethane elastomer ionic film with double-sided microstructure as the dielectric layer of the sensor,with silver nanowires as electrodes.The operating mechanism of this iontronic pressure sensor is analyzed using a graphical method,and the sensor is tested on a pressure platform.The test results show that the sensor has ultrahigh pressure sensitivities of 3.744 and 1.689 kPa^(−1) at low(0-20 kPa)and high(20-800 kPa)pressures,respectively,as well as a rapid response time(100 ms),and it exhibits good stability and repeatability.The sensor can be used for sensitive monitoring of activities such as finger bending,and for facial expression(smile,frown)recognition,as well as speech recognition.
基金support from the National Natural Science Foundation of China(Grant Nos.52475610 and 52105593)the Zhejiang Provincial Natural Science Foundation of China(Grant No.LDQ24E050001)+2 种基金the‘Pioneer’and‘Leading Goose’R&D Program of Zhejiang(Grant No.2023C01051)the Leading Innovation and Entrepreneurship Team Project in Zhejiang(Grant No.2022R01001)the Fundamental Research Funds for the Central Universities(Grant No.226-2024-00085)。
文摘Textiles with electronic components offer a portable and personalized approach for health monitoring and therapy.However,there is a lack of reliable strategy to integrate layered circuits and high-density chips on or inside textiles,which hinders system-level functionality and untethered user experiences.Herein,we propose monolithically integrated textile hybrid electronics(THE)on a textile platform,with multimodal functions and reliable performances.The textile system encompasses flexible electrodes,laser-induced sensors,and surface-mount devices,along with double-layer circuits interconnecting all of them.Vertical conductive paths are rendered by liquid metal composites infiltrated into textiles,which allows resistances less than 0.1?while reserving intact textile structures.The assembled THE exhibits endurance to handwashing and crumpling,as well as bendability.We customize a wireless textile patch for synchronously tracking multiple physiological indicators during exercise.Furthermore,a textile band is elaborated for monitoring and alleviating muscular fatigue,demonstrating potential in closed-loop diagnosis and treatment.
基金supported by the National Natural Science Foundation of China(22176221 and 22273045)the Central Public-interest Scientific Institution Basal Research Fund,Chinese Academy of Fishery Sciences(2024XT09)+1 种基金the Tsinghua University Independent Scientific Research Plan for Young Investigatorthe Tsinghua University Initiative Scientific Research Program。
文摘Wearable electronics incorporating proteins for biocompatibility have garnered significant research attention,given their potential applications in biocompatible medical devices,artificial skin,humanoid robots,and other fields.However,a notable challenge exists,as many wearable electronics currently lack those essential properties due to issues such as non-biological compatibility,as well as insufficient mechanical and conductive performance.Here,we have developed a hybrid keratin(KE)hydrogel by incorporating a liquid metal(LM,eutectic gallium-indium alloy)to design a wearable electronic device with excellent biocompatibility,enhanced conductivity,and good mechanical properties.The resulting keratin liquid metal(KELM)hydrogel demonstrates favorable mechanical characteristics,including good tensile strength(166 kPa),impressive stretchability(2600%),and long-term stability.Furthermore,it exhibits good conductivity(6.84 S·m^(-1))and sensitivity as a sensing material(gauge factor(GF)=7.03),rendering it suitable for constructing high-performance strain sensors.Notably,the KELM hydrogel-based wearable electronics extend their functionality to monitoring marine inhabitants'health.This innovative application provides new insights for designing the next generation of biomimetic electronic devices,with potential applications in human-machine interfaces,electronic skin,artificial intelligence,and health monitoring.
