Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important eval...Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important evaluation parameter.In this study,the concept of whole-process carbon sequestration using coal-based solid waste and CO_(2),including sequential stirring and curing stages,was proposed to evaluate the performance evolution of CS.The results showed that CO_(2) pressure and ambient temperature positively correlated with the CS amount from coal-based SWB.In particular,CO_(2) pressure prevailed in the stirring stage,while the ambient temperature effect was more significant in the curing stage.The CS amounts obtained during the stirring stage alone,the curing stage alone,and two sequential stages ranged from 0.66%–3.10%,3.53%–5.09%,and 5.12%–6.02%,respectively.The functional group and micromorphology analyses revealed that the prevailing mechanism at the CS stirring stage was the stirringdriven gas dissolution-leaching-mineralization reaction,while that at the curing stage was the hydration-driven gas permeation-dissociation-CS reaction.Both were essentially solid-liquid-gas multiphase chemical reactions.The results are instrumental in substantiating the coal-based SWB carbon sequestration evolution patterns and mechanisms and providing data support for waste disposal and carbon emission reduction in the coal industry.展开更多
On July 2^(nd),2025,32 scientists representing 15 countries gathered at Tartu,Estonia to make on-site endorsements for the Global ONCE(Ocean Negative Carbon Emissions)Program at the 12th INTECOL Wetlands Conference.Th...On July 2^(nd),2025,32 scientists representing 15 countries gathered at Tartu,Estonia to make on-site endorsements for the Global ONCE(Ocean Negative Carbon Emissions)Program at the 12th INTECOL Wetlands Conference.This marks a significant milestone for ONCE in establishing a systematic framework for coastal wetland carbon sequestration research and global collaboration(Figs.1,2).Coastal wetlands are critical transition zones linking terrestrial and marine ecosystems,yet they face severe degradation from anthropogenic land-based activities and sea level rise that propagate impacts to the ocean.As a UN Ocean Decade Program,the Global ONCE Program champions interdisciplinary and cross-regional collaboration to enhance carbon sequestration in the ocean and coastal wetlands through science and innovation.Aligned with the Tartu Declaration on Wetlands that includes resolutions to promote the rights of global wetlands(especially peatlands)and advance the discipline of wetland science based on facts,this initiative addresses key knowledge gaps in land-ocean interactions.The goal is to harness the full potential of coastal wetlands and ocean systems for climate mitigation,thereby laying a scientific foundation for international policy formulation and implementation.展开更多
Peri-urban plantations in the Mediterranean are often degraded due to human inactivity and climate change,leading to a loss of ecosystem services and biodiversity.This study investigates the impact of different thinni...Peri-urban plantations in the Mediterranean are often degraded due to human inactivity and climate change,leading to a loss of ecosystem services and biodiversity.This study investigates the impact of different thinning practices on carbon sequestration and tree stability in a degraded periurban plantation in the Italian Apennines,six years after thinning.Three treatments were compared:(a)moderate thinning from below(-25%biomass),representing the typical practice;(b)intense selective thinning(-35%biomass),representing an innovative approach;and(c)no management as the control.Growth projections were used to estimate carbon recovery for these treatments,based on site-specific models calibrated with real data.The results show that both thinning approaches increased carbon sequestration over time,with the innovative thinning achieving a 7%higher annual carbon sequestration rate than traditional thinning and 8%more than the control.Estimated payback times were9 years for recovering the harvested volume in both thinning approaches,10 years for innovative thinning to surpass traditional thinning,17 years for innovative thinning to surpass the control,and 24 years for traditional thinning to surpass the control.Additionally,tree mechanical stability improved significantly in both thinning treatments after two years,with further increases observed in the innovative thinning group after six years.These results suggest that selective thinning can accelerate forest recovery and carbon sequestration,especially in areas with high stem density,where it can reduce the negative impacts of tree mortality and deadwood accumulation.However,careful planning is required to mitigate potential short-term stability is sues,particularly in challenging environments(e.g.,windy conditions,steep slopes).Forest management strategies should therefore aim to balance growth,carbon storage,and tree stability,considering both long-term sustainability and local environmental conditions.The findings are particularly relevant for current climate change mitigation strategies,emphasizing that thinning should be carefully tailored to forest type and conditions to maximize benefits in carbon credit generation and sustainable forest management practices.展开更多
Understanding the dynamics of vegetation carbon sequestration(VCS)is essential for regional carbon neutrality strategies.This study revealed the spatiotemporal patterns of VCS and its relationship with anthropogenic c...Understanding the dynamics of vegetation carbon sequestration(VCS)is essential for regional carbon neutrality strategies.This study revealed the spatiotemporal patterns of VCS and its relationship with anthropogenic carbon emissions(ACEs)in Shandong Province,China during 2000-2020,and identified the sensitivity factors affecting VCS.The results show that:1)VCS increased consistently from 193.45 million t to 256.41 million t,with high values areas concentrated in the central,northeastern,and southeastern mountainous and hilly regions,while low values were found in water bodies and urban built-up areas.At the city level,Linyi,Yantai,Binzhou,and Jinan experienced the most significant rises-reaching up to 243000 t/yr.At the county level,Pingdu,Qixia,and Yiyuan also showed substantial growth,each exceeding 30400 t/yr.2)Digital Elevation Molde(DEM)was identified as the dominant natural factor influencing VCS distribution,while land use optimization measures,especially afforestation and farmland conversion in sloped terrain,were the primary human drivers of VCS increase.3)Urbanization and carbon neutrality were not mutually exclusive.While urban expansion locally reduced VCS,rural emigration enhanced carbon sinks in surrounding areas,partially offsetting urban losses.This compensatory mechanism supported VCS increases in nearly all cities and 90% of counties.Nevertheless,with ACEs continuing to rise and the offset ratio by VCS declining,achieving carbon neutrality requires regional strategies that integrate with accelerated energy conservation,emission reduction technologies,and energy transition.These findings provide a scientific basis for decomposing carbon neutrality targets across cities and counties in Shandong and a reference for developing localized land use policies in similar regions.展开更多
Global warming caused by the emission of CO_(2) in industrial flue gas has attractedmore and more attention.Therefore,to fix CO_(2) with high efficiency and environmentally friendly had become the hot research field.C...Global warming caused by the emission of CO_(2) in industrial flue gas has attractedmore and more attention.Therefore,to fix CO_(2) with high efficiency and environmentally friendly had become the hot research field.Compared with the traditional coal-fired power plant flue gas emission reduction technology,carbon fixation and emission reduction by microalgae is considered as a promising technology due to the advantages of simple process equipment,convenient operation and environmental protection.When the flue gas is treated by microalgae carbon fixation and emission reduction technology,microalgae cells can fix CO_(2) in the flue gas through photosynthesis,and simultaneously absorb NO_(x) and SO_(x) as nitrogen and sulfur sources required for growth.Meanwhile,they can also absorb mercury,selenium,arsenic,cadmium,lead and other heavy metal ions in the flue gas to obtain microalgae biomass.The obtained microalgae biomass can be further transformed into high valueadded products,which has broad development prospects.This paper reviews the mechanisms and pathways of CO_(2) sequestration,the mechanism and impacts of microalgal emission reduction of flue gas pollutants,and the applications of carbon sequestration in industrial flue gas by microalgae.Finally,this paper provides some guidelines and prospects for the research and application of green emission reduction technology for industrial flue gas.展开更多
Long-term mulching has improved crop yields and farmland productivity in semiarid areas,but it has also increased greenhouse gas(GHG)emissions and depleted soil fertility.Biochar application has emerged as a promising...Long-term mulching has improved crop yields and farmland productivity in semiarid areas,but it has also increased greenhouse gas(GHG)emissions and depleted soil fertility.Biochar application has emerged as a promising solution for addressing these issues.In this study,we investigated the effects of four biochar application rates(no biochar(N)=0 t ha^(-1),low(L)=3 t ha^(-1),medium(M)=6 t ha^(-1),and high(H)=9 t ha^(-1))under film mulching and no mulching conditions over three growing seasons.We assessed the impacts on GHG emissions,soil organic carbon sequestration(SOCS),and maize yield to evaluate the productivity and sustainability of farmland ecosystems.Our results demonstrated that mulching increased maize yield(18.68-41.80%),total fixed C in straw(23.64%),grain(28.87%),and root(46.31%)biomass,and GHG emissions(CO_(2),10.78%;N_(2)O,3.41%),while reducing SOCS(6.57%)and GHG intensity(GHGI;13.61%).Under mulching,biochar application significantly increased maize yield(10.20%),total fixed C in straw(17.97%),grain(17.69%)and root(16.75%)biomass,and SOCS(4.78%).Moreover,it reduced the GHG emissions(CO_(2),3.09%;N_(2)O,6.36%)and GHGI(12.28%).These effects correlated with the biochar addition rate,with the optimal rate being 9.0 t ha^(-1).In conclusion,biochar application reduces CO_(2) and N_(2)O emissions,enhances CH_(4) absorption,and improves maize yield under film mulching.It also improves the soil carbon fixation capacity while mitigating the warming potential,making it a promising sustainable management method for mulched farmland in semiarid areas.展开更多
Blue carbon ecosystems,including mangroves,seagrasses,and salt marshes,play a crucial role in mitigating climate change by capturing and storing atmospheric CO_(2)at rates exceeding those of terrestrial forests.This s...Blue carbon ecosystems,including mangroves,seagrasses,and salt marshes,play a crucial role in mitigating climate change by capturing and storing atmospheric CO_(2)at rates exceeding those of terrestrial forests.This study explores the potential of HCWs(Human-Controlled Wetlands)in the Italian Venice Lagoon as an underappreciated component of the global blue carbon pool.Using GEE(Google Earth Engine),we conducted a large-scale assessment of carbon sequestration in these wetlands,demonstrating its advantages over traditional in situ methods in addressing spatial variability.Our findings highlight the significance of below-water mud sediments as primary carbon reservoirs,with a TC(Total Carbon)content of 3.81%±0.94%and a stable storage function akin to peat,reinforced by high CEC(Cation Exchange Capacity).GEE analysis identified a redoximorphic zone at a depth of 20-30 cm,where microbial respiration shifts to anaerobic pathways,preventing carbon release and maintaining long-term sequestration.The study also evaluates key factors affecting remote sensing accuracy,including tidal variations,water depth,and sky cover.The strong correlation between field-measured and satellite-derived carbon parameters(R^(2)>0.85)confirms the reliability of our approach.Furthermore,we developed a GEE-based script for monitoring sediment bioturbation,leveraging Sentinel-1 SAR(Synthetic Aperture Radar)and Sentinel-2 optical data to quantify biological disturbances affecting carbon fluxes.Our results underscore the value of HCWs for carbon sequestration,reinforcing the need for targeted conservation strategies.The scalability and efficiency of remote sensing methodologies,particularly GEE,make them essential for the long-term monitoring of blue carbon ecosystems and the development of effective climate mitigation policies.展开更多
Tree plantations in the tropical-subtropical transition zone(TSTZ)represent crucial ecological regions where diverse biomes converge.Investigating the carbon sequestration potential and dynamic changes within these pl...Tree plantations in the tropical-subtropical transition zone(TSTZ)represent crucial ecological regions where diverse biomes converge.Investigating the carbon sequestration potential and dynamic changes within these plantation ecosystems is of considerable ecological significance.However,the spatial distribution,driving factors,and underlying mechanisms of carbon sequestration in plantations in this region are poorly understood,thereby limiting accurate assessments of their carbon sequestration potential.This study examines four types of plantation forests located within the TSTZ on the Puwen forest farm of Xishuangbanna,China.Two slope gradients were established to quantify and compare the rate of carbon sequestration across these ecosystems.Using random forest modeling and structural equation modeling,the study identifies key environmental factors influencing the rate of carbon sequestration in the plantations.The results reveal substantial variation in DBH growth rates,biomass carbon sequestration,and soil organic carbon sequestration rates(R_(SOC))among the four forest types.Critical factors affecting R_(SOC)include leaf nitrogen and phosphorus concentrations(LP),total soil nitrogen(STN),total soil phosphorus(STP),soil available phosphorus,and nitrogen concentration in ground surface litter.Among these,STN and STP exerted positive effects on R_(SOC),while LP is exerted negative.Overall,the concentration of soil carbon,nitrogen and phosphorus,along with the nitrogen and phosphorus levels in leaves,under different species and topographic slopes,play decisive roles in regulating soil carbon sequestration rates in tropical and subtropical plantations.This research provides support for vegetation protection and restoration in ecologically sensitive areas and watersheds,contributing to the enhancement of regional forest carbon sequestration capacity.展开更多
Soil organic carbon(SOC)plays a crucial role in mangrove blue carbon formation,yet the differences in microbemediated underlying SOC sequestration between introduced and native mangroves remain unclear.Here,we compare...Soil organic carbon(SOC)plays a crucial role in mangrove blue carbon formation,yet the differences in microbemediated underlying SOC sequestration between introduced and native mangroves remain unclear.Here,we compared the SOC pool,including recalcitrant organic carbon(ROC)and labile carbon pools,as well as three residual carbon sources(amino sugars,lignin phenols,and lipids)in sediments between mangroves of introduced Sonneratia apetala and native Kandelia obovata,and further connected them with microbial life strategies and C metabolism capability.The results showed that SOC accumulation in S.apetala(SA)sediment was about 30%-50% of that in K.obovata(KO)sediment.ROC was the dominant form of SOC in long-term sequestration(76%-83%),while lignin phenols,amino sugars,and lipids were important sources of ROC.In S.apetala sediments,the ROC content was positively correlated with amino sugars,resulting from the more r-strategist microbes that can rapidly convert plant-derived carbon into microbial biomass,which is subsequently transformed into microbial necromass.In contrast,in K.obovata sediments,ROC content showed a stronger positive correlation with the concentrations of lignin phenols and lipids.More K-strategist fungi in the topsoil of K.obovata increased enzyme activities,while more K-strategist bacteria in the subsoil enhanced carbon utilization capacity,thereby increasing lignin phenols and lipids from plant residues in both soil layers.Meanwhile,higher Ca^(2+)concentrations in K.obovata sediments protected three residual carbons from further microbe decomposition.This study provides valuable insights into the molecular mechanisms of SOC sequestration mediated by microbial life strategies in mangrove ecosystems.展开更多
Growing concerns about greenhouse gas emissions from underground mining have intensified the need for carbon reduction strategies at every stage.Shotcrete used in tunnel support presents a promising opportunity for ca...Growing concerns about greenhouse gas emissions from underground mining have intensified the need for carbon reduction strategies at every stage.Shotcrete used in tunnel support presents a promising opportunity for carbon emission reduction.This study investigates the carbon absorption capacity,mechanical strength,and underlying mechanisms of shotcrete when exposed to varying CO_(2)concentrations during the mine support process.Findings reveal that higher CO_(2)concentrations during the initial stages of carbonation curing enhance early strength but may impede long-term strength development.Shotcrete samples exposed to 2vol%CO_(2)for 14 d exhibited a carbonation degree approximately three times higher than those exposed to 0.03vol%CO_(2).A carbonation layer formed in the shotcrete,sequestering CO_(2)as solid carbonates.In practical terms,shotcrete in an underground return-air tunnel absorbed 1.1 kg·m^(2)of CO_(2)over 14 d,equivalent to treating 33 m^(3)of contaminated air.Thus,using shotcrete for CO_(2)curing in return-air tunnels can significantly reduce carbon emissions,contributing to greener and more sustainable mining practices.展开更多
Dissolved organic carbon(DOC)and particulate organic carbon(POC)play essential roles in the carbon sequestration,with macroalgae being major producers of DOC and POC.The intertidal zone is the transition area between ...Dissolved organic carbon(DOC)and particulate organic carbon(POC)play essential roles in the carbon sequestration,with macroalgae being major producers of DOC and POC.The intertidal zone is the transition area between the ocean and the land,the main habitat of macroalgae.However,few studies have focused on the regulation of tidally induced desiccation-rewetting cycles on carbon sequestration by intertidal macroalgae.Therefore,we simulated the intertidal environments to investigate the effects of desiccation-rewetting cycles on the growth,DOC and POC release mechanisms of Ulva pertusa.After 14 days of experiments,the DOC release capacities of U.pertusa(per gram fresh weight)were 1.08,5.31,9.74 and 7.47 mg/g in the subtidal,low,middle and high tide zones,respectively.The corresponding POC release capacities were 0.04,1.00,3.90 and 1.38 mg/g.Combined biological carbon sequestration,the total carbon sequestration capacities of U.pertusa in the subtidal,low,middle and high tide zones were 24.73,32.84,27.83 and 16.97 mg/g,respectively.The results indicated that the highest carbon sequestration capacity of U.pertusa occurred in low tide zones.In conclusion,the results will provide support for the application of seaweed negative emissions.展开更多
The combined application of organic manure and chemical fertilizers is an effective way to enhance soil organic carbon(SOC)sequestration through its influences on organic carbon(OC)input and the stability of SOC fract...The combined application of organic manure and chemical fertilizers is an effective way to enhance soil organic carbon(SOC)sequestration through its influences on organic carbon(OC)input and the stability of SOC fractions.However,there is limited information on the carbon sequestration efficiency(CSE)of chemically separated SOC fractions and its response to OC input under long-term fertilization regimes,especially at different sites.This study used three long-term fertilization experiments in Gongzhuling,Zhengzhou and Qiyang spanning 20 years to compare the stocks and CSE in four different OC fractions(very labile OC,labile OC,less labile OC,and non-labile OC)and their relationships with annual OC input.Three treatments of no fertilization(CK),chemical nitrogen,phosphorous,and potassium fertilizers(NPK),and chemical NPK combined with manure(NPKM)were employed.The results showed that compared with CK,NPKM resulted in enhanced SOC stocks and sequestration rates as well as CSE levels of all fractions irrespective of experimental site.Specifically for the very labile and non-labile OC fractions,NPKM significantly increased the SOC stocks by 43 and 83%,77 and 86%,and 73 and 82%in Gongzhuling,Qiyang,and Zhengzhou relative to CK,respectively.However,the greatest changes in SOC stock relative to the initial value were associated with non-labile OC fractions in Gongzhuling,Zhengzhou,and Qiyang,which reached 6.65,7.16,and 7.35 Mg ha^(-1) under NPKM.Similarly,the highest CSE was noted for non-labile OC fractions under NPKM followed sequentially by the very labile OC,labile OC,and less-labile OC fractions,however a CSE of 8.56%in the non-labile OC fraction for Gongzhuling was higher than the values of 6.10 and 4.61%in Zhengzhou and Qiyang,respectively.In addition,the CSE for the passive pool(very labile+labile OC fractions)was higher than the active pool(less-labile+non-labile OC fractions),with the highest value in Gongzhuling.The redundancy analysis revealed that the CSEs of fractions and pools were negatively influenced by annual OC input,mean annual precipitation and temperature,but positively influenced by the initial SOC and total nitrogen contents.This suggests that differential stability of sequestered OC is further governed by indigenous site characteristics and variable amounts of annual OC input.展开更多
Although supercritical carbon dioxide(SC-CO_(2))fracturing shows tremendous potential for maximizing injection efficiency and enhancing storage volumes,few investigations have been reported on the SC-CO_(2) fracturing...Although supercritical carbon dioxide(SC-CO_(2))fracturing shows tremendous potential for maximizing injection efficiency and enhancing storage volumes,few investigations have been reported on the SC-CO_(2) fracturing characteristics of tight basalts and the reactions between fractured basalt and SC-CO_(2).In this study,hydraulic fracturing experiments were conducted on cylindrical basalt specimens using water and SC-CO_(2) as fracturing fluids.Geometric parameters were proposed to characterize the fracture morphologies based on the three-dimensional(3D)reconstructions of fracture networks.The rock slices with induced fractures after SC-CO_(2) fracturing were then processed for fluid(deionized water/SC-CO_(2))-basalt reaction tests.The experimental results demonstrate that SC-CO_(2) fracturing can induce complex and tortuous fractures with spatially dispersed morphologies.Other fracturing behaviors accompanying the acoustic emission(AE)signals and pump pressure changes show that the AE activity responds almost simultaneously to variation in the pump pressure.The fractured basalt blocks exposed to both SC-CO_(2) and water exhibit rough and uneven surfaces,along with decreased intensities in the element peaks,indicating that solubility trapping predominantly occurs during the early injection stage.The above findings provide a laboratory research basis for understanding the fracturing and sequestration issues related to effective CO_(2) utilization.展开更多
Green roofs play a vital role in promoting sustainable urban development and achieving carbon neutrality by enhancing carbon sequestration, oxygen release, and efficiency of land use. Despite these benefits, living ro...Green roofs play a vital role in promoting sustainable urban development and achieving carbon neutrality by enhancing carbon sequestration, oxygen release, and efficiency of land use. Despite these benefits, living roof coverage in China remains limited. To address the challenges in policy formulation, operational monitoring, and the absence of multi-scale retrofit strategies supported by robust assessment methods, this study develops a comprehensive evaluation framework. The framework integrates vector data, building age information, and point-of-interest(POI) data, and applies an optimized Prophet model to classify six major climate zones. This approach facilitates the selection of appropriate plant species and substrates while quantifying the potential for carbon sequestration and oxygen release. An assessment of 90 cities reveals approximately 1.3861 billion square meters of rooftop area suitable for green roof implementation, with an estimated annual carbon sequestration potential of 67.30 million tons and oxygen release of 30.36 million tons. Commercial buildings contribute significantly, comprising 65% of the total suitable area. Climate zones 2 and 3 exhibit the most favorable outcomes. The current study provides a reliable quantitative reference for evaluating the carbon sequestration and oxygen release capacities of green roofs and supports the formulation of effective retrofit policies.展开更多
Mitigating climate change demands innovative solutions,and carbon sequestration technologies are at the forefront.Among these,basalt,a mafic volcanic rock packed with calcium,magnesium,and iron,emerges as a powerful c...Mitigating climate change demands innovative solutions,and carbon sequestration technologies are at the forefront.Among these,basalt,a mafic volcanic rock packed with calcium,magnesium,and iron,emerges as a powerful candidate for carbon dioxide(CO_(2))sequestration through mineral carbonation.This method transforms CO_(2)into stable carbonate minerals,ensuring a permanent and environmentally safe storage solution.While extensive research has explored into basalt’s potential under high hydration conditions,the untapped promise of low water content scenarios remains largely unexplored.Our ground-breaking study investigates the mineral carbonation of basalt powder under low water condi-tions using supercritical CO_(2)(sc-CO_(2)).Conducted at 50℃ and 15 MPa with a controlled moisture content of 30%,our experiment spans various time points(0,7,14,21,and 28 days).Utilising advanced X-ray diffraction(XRD)and scanning electron microscopy with energy-dispersive X-ray spectroscopy(SEM-EDS),we unveil the mineralogical and morphological transformations.The results are striking:even under low water conditions,basalt efficiently forms valuable carbonate minerals such as calcite,siderite,magnesite,and ankerite.The carbonation efficiency evolves over time,reflecting the dynamic transfor-mation of the basalt matrix.These findings offer pivotal insights into optimising CO_(2)sequestration in basalt under low hydration,marking a significant leap toward sustainable carbon capture and storage.展开更多
Coal is an essential component of global energy;however,the processes of coal mining and utilization produce significant amounts of coal mine goafs,accompanied by coal-based solid wastes and emitted CO_(2),resulting i...Coal is an essential component of global energy;however,the processes of coal mining and utilization produce significant amounts of coal mine goafs,accompanied by coal-based solid wastes and emitted CO_(2),resulting in severe ecological and environmental challenges.In response to this issue,this study pro-poses a novel approach for filling coal mine goafs using cementitious materials prepared by coal-based solid wastes mineralized with CO_(2)(15%in concentration).The CO_(2) sequestration capacities of individual solid wastes are ranked as follows:carbide slag(CS)>red mud(RM)>fly ash(FA).The performance of filling material prepared from composite solid waste(FA-CS-RM)mineralized with CO_(2) meets the filling requirements of goaf.The filling material(F60C20R20)obtained by CO_(2) mineralization was 14.9 MPa in maximum compressive strength,increasing by 32.2%compared to the non-mineralized material.The prepared filling material exhibits excellent CO_(2) sequestration capacity(i.e.,14.4 kg·t^(−1) in maximum amount of CO_(2) sequestration).According to the analysis of carbon sequestration potential,in China,the annual production of FA,CS,and RM is approximately 899,30,and 107 Mt,respectively in the year of 2023.The utilization of FA,CS,and RM individually can achieve carbon emission reductions of 3.42,10.78,and 0.61 Mt,respectively.The composite solid waste(FA-CS-RM)mineralized with CO_(2) can achieve 1.23 Mt in carbon emissions reduction.Additionally,taking Yellow River Basin of China as a case study,the total volume of underground space in coal mine goafs from 2016 to 2030 is estimated at 8.16 Gm3,indicating that this technology can sequester 0.18 Gt of CO_(2).This approach offers a promising solution for large-scale flue gas CO_(2) sequestration,recycling coal-based solid wastes,and remediating coal mine goafs,contributing to green utilization of coal and the emission reduction of carbon.展开更多
Urbanization radically alters the climatic environment and landscape patterns of urban areas,but its impact on the carbon sequestration capacity of vegetation remains uncertain.Given the limitations of current small-s...Urbanization radically alters the climatic environment and landscape patterns of urban areas,but its impact on the carbon sequestration capacity of vegetation remains uncertain.Given the limitations of current small-scale ground-based in situ experiments,the response of vegetation carbon sequestration capacity to urbanization and the factors influencing it remain unclear at the global scale.Using multisource remote sensing data,we quanti-fied and differentiated the direct and indirect impacts of urbanization on the carbon sequestration capacity of vegetation in 508 large urban areas globally from 2000 to 2020.The results revealed that the direct impacts of urbanization were generally negative.However,446 cities experienced an indirect enhancement in vegetation carbon sequestration capacity during urbanization,averaging 19.6%globally and offsetting 14.7%of the di-rect loss due to urbanization.These positive indirect effects were most pronounced in environments with limited hydrothermal conditions and increased most in densely populated temperate and cold regions.Furthermore,indi-rect impacts were closely related to urbanization intensity,human footprint,and level of urban development.Our study enhances the understanding of how the carbon sequestration capacity of vegetation dynamically responds to changes in the urban environment,which is crucial for improving future urban vegetation management and building sustainable cities.展开更多
Understanding the differences in CO_(2)adsorption in cementitious material is critical in mitigating the carbon footprint of the construction industry.This study chose the most common β-C_(2)S phase in the industry a...Understanding the differences in CO_(2)adsorption in cementitious material is critical in mitigating the carbon footprint of the construction industry.This study chose the most common β-C_(2)S phase in the industry as the cementitious material,selecting the β-C_(2)S(111)and β-C_(2)S(100)surfaces for CO_(2)adsorption.First-principles calculations were employed to systematically compare the CO_(2)ad-sorption behaviors on both surfaces focusing on adsorption energy,adsorption configurations,and surface reconstruction.The comparis-on of CO_(2)and H2O adsorption behaviors on the β-C_(2)S(111)surface was also conducted to shed light on the influence of CO_(2)on cement hydration.The adsorption energies of CO_(2)on the β-C_(2)S(111)and β-C_(2)S(100)surfaces were determined as-0.647 and-0.423 eV,respect-ively,suggesting that CO_(2)adsorption is more energetically favorable on the β-C_(2)S(111)surface than on the β-C_(2)S(100)surface.The ad-sorption energy of H2O on the β-C_(2)S(111)surface was-1.588 eV,which is 0.941 eV more negative than that of CO_(2),implying that β-C_(2)S tends to become hydrated before reacting with CO_(2).Bader charges,charge density differences,and the partial density of states were ap-plied to characterize the electronic properties of CO_(2)and H2O molecules and those of the surface atoms.The initial Ca/O sites on the β-C_(2)S(111)surface exhibited higher chemical reactivity due to the greater change in the average number of valence electrons in the CO_(2)ad-sorption.Specifically,after CO_(2)adsorption,the average number of valence electrons for both the Ca and O atoms increased by 0.002 on the β-C_(2)S(111)surface,while both decreased by 0.001 on the β-C_(2)S(100)surface.In addition,due to the lower valence electron number of O atoms,the chemical reactivity of O atoms on the β-C_(2)S(111)surface after H2O adsorption was higher than the case of CO_(2)adsorption,which favors the occurrence of further reactions.Overall,this work assessed the adsorption capacity of the β-C_(2)S surface for CO_(2)mo-lecules,offering a strong theoretical foundation for the design of novel cementitious materials for CO_(2)capture and storage.展开更多
This study investigates carbon dioxide(CO₂)sequestration and biomass distribution across various plant components and land use types in Ban Krang Subdistrict,Mueang District,Phitsanulok Province,with the goal of enhan...This study investigates carbon dioxide(CO₂)sequestration and biomass distribution across various plant components and land use types in Ban Krang Subdistrict,Mueang District,Phitsanulok Province,with the goal of enhancing carbon management strategies.Field surveys were conducted using 14 plots of 40×40 meters to quantify biomass and estimate CO₂sequestration across different vegetation types.The findings reveal an average CO₂sequestration of 122.81 ton ha⁻¹,with aboveground biomass,particularly stems,contributing the most to carbon storage.Notably,abandoned perennial crops and mixed perennial crops demonstrated the highest sequestration rates,at 657.94 ton ha⁻¹and 613.00 ton ha⁻¹,respectively.In contrast,agricultural lands such as rice paddies and cassava plantations exhibited the lowest sequestration rates,though rice paddies contributed the highest total CO₂sequestration,amounting to 61,119.71 tons,due to their extensive area.The study highlights the critical role of diverse and dense vegetation,particularly perennial crops,in maximizing carbon sequestration.It also underscores the potential for improving carbon storage in agricultural lands through better land management practices.The results suggest that targeted strategies should prioritize high-sequestration land use types while also enhancing carbon storage in low-sequestration areas.By optimizing land use and management practices,the region can significantly increase its carbon storage capacity,contributing to climate change mitigation and promoting long-term ecological sustainability.These insights are crucial for formulating effective carbon management strategies in Ban Krang Subdistrict,as well as in other comparable regions.展开更多
This study investigates the application of carbon dioxide (CO2) sequestration to address challenges in water-drive gas reservoirs, specifically focusing on improving gas recovery and mitigating water invasion. Traditi...This study investigates the application of carbon dioxide (CO2) sequestration to address challenges in water-drive gas reservoirs, specifically focusing on improving gas recovery and mitigating water invasion. Traditional methods like blow-down and co-production have limitations, including sand production, water coning, and inefficiency in strong aquifers. To overcome these issues, this research explores CO2 injection near the edge aquifer, aiming to reduce water influx and enhance gas recovery through the propagation of a CO2 plume in the gas-water contact zone. Both synthetic and real compositional reservoir models were studied, with CO2 injection performed while maintaining reservoir pressure below 90% of the initial level. Results show that CO2 sequestration significantly improved recovery, particularly in higher permeability reservoirs, where it reduced aquifer influx and increased gas production by 26% under challenging conditions. While CO2 dissolution in water decreased aquifer influx by 39%, its adverse effect on sweep efficiency led to a reduction in gas and water production by 4.2% and 10%, respectively. The method's effectiveness was not significantly impacted by aquifer permeability, but it was sensitive to vertical-to-horizontal permeability ratios. When applied to a real gas reservoir, the proposed method increased gas production by 14% compared to conventional techniques, with minimal CO2 production over a 112-year period. This study demonstrates the potential of CO2 sequestration as a comprehensive solution for enhancing gas recovery, reducing water production, and mitigating environmental impacts in water-drive gas reservoirs.展开更多
基金supported by the National Key R&D Program of China(No.2023YFC3904304)the National Natural Science Foundation of China(No.52304158)Jiangsu Key Laboratory for Clean Utilization of Carbon Resources Research Project(No.BM2024007)。
文摘Underground carbon sequestration(CS)by solid waste backfill(SWB)offers an effective pathway for collaborative disposal of coal-based solid waste and CO_(2),where the amount of carbon sequestration is an important evaluation parameter.In this study,the concept of whole-process carbon sequestration using coal-based solid waste and CO_(2),including sequential stirring and curing stages,was proposed to evaluate the performance evolution of CS.The results showed that CO_(2) pressure and ambient temperature positively correlated with the CS amount from coal-based SWB.In particular,CO_(2) pressure prevailed in the stirring stage,while the ambient temperature effect was more significant in the curing stage.The CS amounts obtained during the stirring stage alone,the curing stage alone,and two sequential stages ranged from 0.66%–3.10%,3.53%–5.09%,and 5.12%–6.02%,respectively.The functional group and micromorphology analyses revealed that the prevailing mechanism at the CS stirring stage was the stirringdriven gas dissolution-leaching-mineralization reaction,while that at the curing stage was the hydration-driven gas permeation-dissociation-CS reaction.Both were essentially solid-liquid-gas multiphase chemical reactions.The results are instrumental in substantiating the coal-based SWB carbon sequestration evolution patterns and mechanisms and providing data support for waste disposal and carbon emission reduction in the coal industry.
文摘On July 2^(nd),2025,32 scientists representing 15 countries gathered at Tartu,Estonia to make on-site endorsements for the Global ONCE(Ocean Negative Carbon Emissions)Program at the 12th INTECOL Wetlands Conference.This marks a significant milestone for ONCE in establishing a systematic framework for coastal wetland carbon sequestration research and global collaboration(Figs.1,2).Coastal wetlands are critical transition zones linking terrestrial and marine ecosystems,yet they face severe degradation from anthropogenic land-based activities and sea level rise that propagate impacts to the ocean.As a UN Ocean Decade Program,the Global ONCE Program champions interdisciplinary and cross-regional collaboration to enhance carbon sequestration in the ocean and coastal wetlands through science and innovation.Aligned with the Tartu Declaration on Wetlands that includes resolutions to promote the rights of global wetlands(especially peatlands)and advance the discipline of wetland science based on facts,this initiative addresses key knowledge gaps in land-ocean interactions.The goal is to harness the full potential of coastal wetlands and ocean systems for climate mitigation,thereby laying a scientific foundation for international policy formulation and implementation.
基金supported initially by the LIFE FoResMit Project(LIFE14 CCM/IT/000905)。
文摘Peri-urban plantations in the Mediterranean are often degraded due to human inactivity and climate change,leading to a loss of ecosystem services and biodiversity.This study investigates the impact of different thinning practices on carbon sequestration and tree stability in a degraded periurban plantation in the Italian Apennines,six years after thinning.Three treatments were compared:(a)moderate thinning from below(-25%biomass),representing the typical practice;(b)intense selective thinning(-35%biomass),representing an innovative approach;and(c)no management as the control.Growth projections were used to estimate carbon recovery for these treatments,based on site-specific models calibrated with real data.The results show that both thinning approaches increased carbon sequestration over time,with the innovative thinning achieving a 7%higher annual carbon sequestration rate than traditional thinning and 8%more than the control.Estimated payback times were9 years for recovering the harvested volume in both thinning approaches,10 years for innovative thinning to surpass traditional thinning,17 years for innovative thinning to surpass the control,and 24 years for traditional thinning to surpass the control.Additionally,tree mechanical stability improved significantly in both thinning treatments after two years,with further increases observed in the innovative thinning group after six years.These results suggest that selective thinning can accelerate forest recovery and carbon sequestration,especially in areas with high stem density,where it can reduce the negative impacts of tree mortality and deadwood accumulation.However,careful planning is required to mitigate potential short-term stability is sues,particularly in challenging environments(e.g.,windy conditions,steep slopes).Forest management strategies should therefore aim to balance growth,carbon storage,and tree stability,considering both long-term sustainability and local environmental conditions.The findings are particularly relevant for current climate change mitigation strategies,emphasizing that thinning should be carefully tailored to forest type and conditions to maximize benefits in carbon credit generation and sustainable forest management practices.
基金Under the auspices of the National Natural Science Foundation of China(No.42476247,42461015)the Open Research Fund of Key Laboratory of Coastal Science and Integrated Management,Ministry of Natural Resources(No.2024COSIM01)Guangxi Science and Technology Base and Talent Special Project(No.GuikeAD23026194)。
文摘Understanding the dynamics of vegetation carbon sequestration(VCS)is essential for regional carbon neutrality strategies.This study revealed the spatiotemporal patterns of VCS and its relationship with anthropogenic carbon emissions(ACEs)in Shandong Province,China during 2000-2020,and identified the sensitivity factors affecting VCS.The results show that:1)VCS increased consistently from 193.45 million t to 256.41 million t,with high values areas concentrated in the central,northeastern,and southeastern mountainous and hilly regions,while low values were found in water bodies and urban built-up areas.At the city level,Linyi,Yantai,Binzhou,and Jinan experienced the most significant rises-reaching up to 243000 t/yr.At the county level,Pingdu,Qixia,and Yiyuan also showed substantial growth,each exceeding 30400 t/yr.2)Digital Elevation Molde(DEM)was identified as the dominant natural factor influencing VCS distribution,while land use optimization measures,especially afforestation and farmland conversion in sloped terrain,were the primary human drivers of VCS increase.3)Urbanization and carbon neutrality were not mutually exclusive.While urban expansion locally reduced VCS,rural emigration enhanced carbon sinks in surrounding areas,partially offsetting urban losses.This compensatory mechanism supported VCS increases in nearly all cities and 90% of counties.Nevertheless,with ACEs continuing to rise and the offset ratio by VCS declining,achieving carbon neutrality requires regional strategies that integrate with accelerated energy conservation,emission reduction technologies,and energy transition.These findings provide a scientific basis for decomposing carbon neutrality targets across cities and counties in Shandong and a reference for developing localized land use policies in similar regions.
基金supported by the National Key R&D Program of China(No.2023YFC3709500).
文摘Global warming caused by the emission of CO_(2) in industrial flue gas has attractedmore and more attention.Therefore,to fix CO_(2) with high efficiency and environmentally friendly had become the hot research field.Compared with the traditional coal-fired power plant flue gas emission reduction technology,carbon fixation and emission reduction by microalgae is considered as a promising technology due to the advantages of simple process equipment,convenient operation and environmental protection.When the flue gas is treated by microalgae carbon fixation and emission reduction technology,microalgae cells can fix CO_(2) in the flue gas through photosynthesis,and simultaneously absorb NO_(x) and SO_(x) as nitrogen and sulfur sources required for growth.Meanwhile,they can also absorb mercury,selenium,arsenic,cadmium,lead and other heavy metal ions in the flue gas to obtain microalgae biomass.The obtained microalgae biomass can be further transformed into high valueadded products,which has broad development prospects.This paper reviews the mechanisms and pathways of CO_(2) sequestration,the mechanism and impacts of microalgal emission reduction of flue gas pollutants,and the applications of carbon sequestration in industrial flue gas by microalgae.Finally,this paper provides some guidelines and prospects for the research and application of green emission reduction technology for industrial flue gas.
基金supported by the National Key Research and Development Program of China(2021YFE0101300 and 2021YFD1901102)the project supported by the Natural Science Basic Research Plan in Shaanxi Province,China(2023-JC-YB-185)the Ningxia Key Research and Development Program,China(2023BCF01018)。
文摘Long-term mulching has improved crop yields and farmland productivity in semiarid areas,but it has also increased greenhouse gas(GHG)emissions and depleted soil fertility.Biochar application has emerged as a promising solution for addressing these issues.In this study,we investigated the effects of four biochar application rates(no biochar(N)=0 t ha^(-1),low(L)=3 t ha^(-1),medium(M)=6 t ha^(-1),and high(H)=9 t ha^(-1))under film mulching and no mulching conditions over three growing seasons.We assessed the impacts on GHG emissions,soil organic carbon sequestration(SOCS),and maize yield to evaluate the productivity and sustainability of farmland ecosystems.Our results demonstrated that mulching increased maize yield(18.68-41.80%),total fixed C in straw(23.64%),grain(28.87%),and root(46.31%)biomass,and GHG emissions(CO_(2),10.78%;N_(2)O,3.41%),while reducing SOCS(6.57%)and GHG intensity(GHGI;13.61%).Under mulching,biochar application significantly increased maize yield(10.20%),total fixed C in straw(17.97%),grain(17.69%)and root(16.75%)biomass,and SOCS(4.78%).Moreover,it reduced the GHG emissions(CO_(2),3.09%;N_(2)O,6.36%)and GHGI(12.28%).These effects correlated with the biochar addition rate,with the optimal rate being 9.0 t ha^(-1).In conclusion,biochar application reduces CO_(2) and N_(2)O emissions,enhances CH_(4) absorption,and improves maize yield under film mulching.It also improves the soil carbon fixation capacity while mitigating the warming potential,making it a promising sustainable management method for mulched farmland in semiarid areas.
文摘Blue carbon ecosystems,including mangroves,seagrasses,and salt marshes,play a crucial role in mitigating climate change by capturing and storing atmospheric CO_(2)at rates exceeding those of terrestrial forests.This study explores the potential of HCWs(Human-Controlled Wetlands)in the Italian Venice Lagoon as an underappreciated component of the global blue carbon pool.Using GEE(Google Earth Engine),we conducted a large-scale assessment of carbon sequestration in these wetlands,demonstrating its advantages over traditional in situ methods in addressing spatial variability.Our findings highlight the significance of below-water mud sediments as primary carbon reservoirs,with a TC(Total Carbon)content of 3.81%±0.94%and a stable storage function akin to peat,reinforced by high CEC(Cation Exchange Capacity).GEE analysis identified a redoximorphic zone at a depth of 20-30 cm,where microbial respiration shifts to anaerobic pathways,preventing carbon release and maintaining long-term sequestration.The study also evaluates key factors affecting remote sensing accuracy,including tidal variations,water depth,and sky cover.The strong correlation between field-measured and satellite-derived carbon parameters(R^(2)>0.85)confirms the reliability of our approach.Furthermore,we developed a GEE-based script for monitoring sediment bioturbation,leveraging Sentinel-1 SAR(Synthetic Aperture Radar)and Sentinel-2 optical data to quantify biological disturbances affecting carbon fluxes.Our results underscore the value of HCWs for carbon sequestration,reinforcing the need for targeted conservation strategies.The scalability and efficiency of remote sensing methodologies,particularly GEE,make them essential for the long-term monitoring of blue carbon ecosystems and the development of effective climate mitigation policies.
基金supported by the National Key Research and Development Program of China(Grant No.2023YFE0105100-5-2)the Fundamental Research Funds of CAFYBB2022SY034)+2 种基金the Guangxi Science and Technology Base and Talents Fund(Grant No.GUIKE AD22035117)the Scientific Research Foundation for Highlevel Talent of Sanming University(Grant No.20YG02)Natural Science Foundation of Fujian Province(Grant No.2023J011022)。
文摘Tree plantations in the tropical-subtropical transition zone(TSTZ)represent crucial ecological regions where diverse biomes converge.Investigating the carbon sequestration potential and dynamic changes within these plantation ecosystems is of considerable ecological significance.However,the spatial distribution,driving factors,and underlying mechanisms of carbon sequestration in plantations in this region are poorly understood,thereby limiting accurate assessments of their carbon sequestration potential.This study examines four types of plantation forests located within the TSTZ on the Puwen forest farm of Xishuangbanna,China.Two slope gradients were established to quantify and compare the rate of carbon sequestration across these ecosystems.Using random forest modeling and structural equation modeling,the study identifies key environmental factors influencing the rate of carbon sequestration in the plantations.The results reveal substantial variation in DBH growth rates,biomass carbon sequestration,and soil organic carbon sequestration rates(R_(SOC))among the four forest types.Critical factors affecting R_(SOC)include leaf nitrogen and phosphorus concentrations(LP),total soil nitrogen(STN),total soil phosphorus(STP),soil available phosphorus,and nitrogen concentration in ground surface litter.Among these,STN and STP exerted positive effects on R_(SOC),while LP is exerted negative.Overall,the concentration of soil carbon,nitrogen and phosphorus,along with the nitrogen and phosphorus levels in leaves,under different species and topographic slopes,play decisive roles in regulating soil carbon sequestration rates in tropical and subtropical plantations.This research provides support for vegetation protection and restoration in ecologically sensitive areas and watersheds,contributing to the enhancement of regional forest carbon sequestration capacity.
基金supported by grants from the National Natural Science Foundation of China(Nos.42076117 and 32160051)the Guangdong Basic and Applied Basic Research Foundation(Nos.2023A1515012772,2024A1515011721,and 2024A1515012249).
文摘Soil organic carbon(SOC)plays a crucial role in mangrove blue carbon formation,yet the differences in microbemediated underlying SOC sequestration between introduced and native mangroves remain unclear.Here,we compared the SOC pool,including recalcitrant organic carbon(ROC)and labile carbon pools,as well as three residual carbon sources(amino sugars,lignin phenols,and lipids)in sediments between mangroves of introduced Sonneratia apetala and native Kandelia obovata,and further connected them with microbial life strategies and C metabolism capability.The results showed that SOC accumulation in S.apetala(SA)sediment was about 30%-50% of that in K.obovata(KO)sediment.ROC was the dominant form of SOC in long-term sequestration(76%-83%),while lignin phenols,amino sugars,and lipids were important sources of ROC.In S.apetala sediments,the ROC content was positively correlated with amino sugars,resulting from the more r-strategist microbes that can rapidly convert plant-derived carbon into microbial biomass,which is subsequently transformed into microbial necromass.In contrast,in K.obovata sediments,ROC content showed a stronger positive correlation with the concentrations of lignin phenols and lipids.More K-strategist fungi in the topsoil of K.obovata increased enzyme activities,while more K-strategist bacteria in the subsoil enhanced carbon utilization capacity,thereby increasing lignin phenols and lipids from plant residues in both soil layers.Meanwhile,higher Ca^(2+)concentrations in K.obovata sediments protected three residual carbons from further microbe decomposition.This study provides valuable insights into the molecular mechanisms of SOC sequestration mediated by microbial life strategies in mangrove ecosystems.
基金financially funded by the 14th Five Years Key Programs for Science and Technology Development of China(No.2021YFC2900400)the National Natural Science Foundation of China(Nos.52274151,552104156,52074351,and 22376221)+2 种基金the Science and Technology Innovation Program of Hunan Province,China(No.2021 RC3125)the Natural Science Foundation of Hunan Province,China(No.2024JJ2074)the Young Elite Scientists Sponsorship Program by CAST(No.2023QNRC 001)。
文摘Growing concerns about greenhouse gas emissions from underground mining have intensified the need for carbon reduction strategies at every stage.Shotcrete used in tunnel support presents a promising opportunity for carbon emission reduction.This study investigates the carbon absorption capacity,mechanical strength,and underlying mechanisms of shotcrete when exposed to varying CO_(2)concentrations during the mine support process.Findings reveal that higher CO_(2)concentrations during the initial stages of carbonation curing enhance early strength but may impede long-term strength development.Shotcrete samples exposed to 2vol%CO_(2)for 14 d exhibited a carbonation degree approximately three times higher than those exposed to 0.03vol%CO_(2).A carbonation layer formed in the shotcrete,sequestering CO_(2)as solid carbonates.In practical terms,shotcrete in an underground return-air tunnel absorbed 1.1 kg·m^(2)of CO_(2)over 14 d,equivalent to treating 33 m^(3)of contaminated air.Thus,using shotcrete for CO_(2)curing in return-air tunnels can significantly reduce carbon emissions,contributing to greener and more sustainable mining practices.
基金the National Key Research and Development Program of China(No.2022YFC 3106001)the National Natural Science Foundation of China(No.42206131)+2 种基金the Projects of Science&Technology Plan in Yantai City(No.2023ZDCX039)the Ocean Negative Carbon Emissions(ONCE)Programthe Key Technology Research and Application of Ecological and Efficient Comprehensive Utilization in‘Fishery-Photovoltaic Integration’Seawater Ponds in the Yellow River Delta(No.DYYG2024-10)。
文摘Dissolved organic carbon(DOC)and particulate organic carbon(POC)play essential roles in the carbon sequestration,with macroalgae being major producers of DOC and POC.The intertidal zone is the transition area between the ocean and the land,the main habitat of macroalgae.However,few studies have focused on the regulation of tidally induced desiccation-rewetting cycles on carbon sequestration by intertidal macroalgae.Therefore,we simulated the intertidal environments to investigate the effects of desiccation-rewetting cycles on the growth,DOC and POC release mechanisms of Ulva pertusa.After 14 days of experiments,the DOC release capacities of U.pertusa(per gram fresh weight)were 1.08,5.31,9.74 and 7.47 mg/g in the subtidal,low,middle and high tide zones,respectively.The corresponding POC release capacities were 0.04,1.00,3.90 and 1.38 mg/g.Combined biological carbon sequestration,the total carbon sequestration capacities of U.pertusa in the subtidal,low,middle and high tide zones were 24.73,32.84,27.83 and 16.97 mg/g,respectively.The results indicated that the highest carbon sequestration capacity of U.pertusa occurred in low tide zones.In conclusion,the results will provide support for the application of seaweed negative emissions.
基金support from the National Natural Science Foundation of China(42177341)is highly acknowledged。
文摘The combined application of organic manure and chemical fertilizers is an effective way to enhance soil organic carbon(SOC)sequestration through its influences on organic carbon(OC)input and the stability of SOC fractions.However,there is limited information on the carbon sequestration efficiency(CSE)of chemically separated SOC fractions and its response to OC input under long-term fertilization regimes,especially at different sites.This study used three long-term fertilization experiments in Gongzhuling,Zhengzhou and Qiyang spanning 20 years to compare the stocks and CSE in four different OC fractions(very labile OC,labile OC,less labile OC,and non-labile OC)and their relationships with annual OC input.Three treatments of no fertilization(CK),chemical nitrogen,phosphorous,and potassium fertilizers(NPK),and chemical NPK combined with manure(NPKM)were employed.The results showed that compared with CK,NPKM resulted in enhanced SOC stocks and sequestration rates as well as CSE levels of all fractions irrespective of experimental site.Specifically for the very labile and non-labile OC fractions,NPKM significantly increased the SOC stocks by 43 and 83%,77 and 86%,and 73 and 82%in Gongzhuling,Qiyang,and Zhengzhou relative to CK,respectively.However,the greatest changes in SOC stock relative to the initial value were associated with non-labile OC fractions in Gongzhuling,Zhengzhou,and Qiyang,which reached 6.65,7.16,and 7.35 Mg ha^(-1) under NPKM.Similarly,the highest CSE was noted for non-labile OC fractions under NPKM followed sequentially by the very labile OC,labile OC,and less-labile OC fractions,however a CSE of 8.56%in the non-labile OC fraction for Gongzhuling was higher than the values of 6.10 and 4.61%in Zhengzhou and Qiyang,respectively.In addition,the CSE for the passive pool(very labile+labile OC fractions)was higher than the active pool(less-labile+non-labile OC fractions),with the highest value in Gongzhuling.The redundancy analysis revealed that the CSEs of fractions and pools were negatively influenced by annual OC input,mean annual precipitation and temperature,but positively influenced by the initial SOC and total nitrogen contents.This suggests that differential stability of sequestered OC is further governed by indigenous site characteristics and variable amounts of annual OC input.
基金supported by the National Key Research and Development Project(Grant No.2023YFE0110900)the National Natural Science Foundation of China(Grant No.42320104003)the Shanghai Pujiang Programme(Grant No.23PJD105).
文摘Although supercritical carbon dioxide(SC-CO_(2))fracturing shows tremendous potential for maximizing injection efficiency and enhancing storage volumes,few investigations have been reported on the SC-CO_(2) fracturing characteristics of tight basalts and the reactions between fractured basalt and SC-CO_(2).In this study,hydraulic fracturing experiments were conducted on cylindrical basalt specimens using water and SC-CO_(2) as fracturing fluids.Geometric parameters were proposed to characterize the fracture morphologies based on the three-dimensional(3D)reconstructions of fracture networks.The rock slices with induced fractures after SC-CO_(2) fracturing were then processed for fluid(deionized water/SC-CO_(2))-basalt reaction tests.The experimental results demonstrate that SC-CO_(2) fracturing can induce complex and tortuous fractures with spatially dispersed morphologies.Other fracturing behaviors accompanying the acoustic emission(AE)signals and pump pressure changes show that the AE activity responds almost simultaneously to variation in the pump pressure.The fractured basalt blocks exposed to both SC-CO_(2) and water exhibit rough and uneven surfaces,along with decreased intensities in the element peaks,indicating that solubility trapping predominantly occurs during the early injection stage.The above findings provide a laboratory research basis for understanding the fracturing and sequestration issues related to effective CO_(2) utilization.
文摘Green roofs play a vital role in promoting sustainable urban development and achieving carbon neutrality by enhancing carbon sequestration, oxygen release, and efficiency of land use. Despite these benefits, living roof coverage in China remains limited. To address the challenges in policy formulation, operational monitoring, and the absence of multi-scale retrofit strategies supported by robust assessment methods, this study develops a comprehensive evaluation framework. The framework integrates vector data, building age information, and point-of-interest(POI) data, and applies an optimized Prophet model to classify six major climate zones. This approach facilitates the selection of appropriate plant species and substrates while quantifying the potential for carbon sequestration and oxygen release. An assessment of 90 cities reveals approximately 1.3861 billion square meters of rooftop area suitable for green roof implementation, with an estimated annual carbon sequestration potential of 67.30 million tons and oxygen release of 30.36 million tons. Commercial buildings contribute significantly, comprising 65% of the total suitable area. Climate zones 2 and 3 exhibit the most favorable outcomes. The current study provides a reliable quantitative reference for evaluating the carbon sequestration and oxygen release capacities of green roofs and supports the formulation of effective retrofit policies.
基金supported by the National Natural Science Foundation of China(Grant No.52374192)the Henan Province Funds for Distinguished Young Youths(Grant No.242300421013)the Innovative Scientific Research Team Project of Henan Polytechnic University(Grant No.T2024-1).
文摘Mitigating climate change demands innovative solutions,and carbon sequestration technologies are at the forefront.Among these,basalt,a mafic volcanic rock packed with calcium,magnesium,and iron,emerges as a powerful candidate for carbon dioxide(CO_(2))sequestration through mineral carbonation.This method transforms CO_(2)into stable carbonate minerals,ensuring a permanent and environmentally safe storage solution.While extensive research has explored into basalt’s potential under high hydration conditions,the untapped promise of low water content scenarios remains largely unexplored.Our ground-breaking study investigates the mineral carbonation of basalt powder under low water condi-tions using supercritical CO_(2)(sc-CO_(2)).Conducted at 50℃ and 15 MPa with a controlled moisture content of 30%,our experiment spans various time points(0,7,14,21,and 28 days).Utilising advanced X-ray diffraction(XRD)and scanning electron microscopy with energy-dispersive X-ray spectroscopy(SEM-EDS),we unveil the mineralogical and morphological transformations.The results are striking:even under low water conditions,basalt efficiently forms valuable carbonate minerals such as calcite,siderite,magnesite,and ankerite.The carbonation efficiency evolves over time,reflecting the dynamic transfor-mation of the basalt matrix.These findings offer pivotal insights into optimising CO_(2)sequestration in basalt under low hydration,marking a significant leap toward sustainable carbon capture and storage.
基金supported by the National Natural Science Foundation of China(U21A20321 and 22378241)Research Project Supported by Shanxi Scholarship Council of China(2024-015).
文摘Coal is an essential component of global energy;however,the processes of coal mining and utilization produce significant amounts of coal mine goafs,accompanied by coal-based solid wastes and emitted CO_(2),resulting in severe ecological and environmental challenges.In response to this issue,this study pro-poses a novel approach for filling coal mine goafs using cementitious materials prepared by coal-based solid wastes mineralized with CO_(2)(15%in concentration).The CO_(2) sequestration capacities of individual solid wastes are ranked as follows:carbide slag(CS)>red mud(RM)>fly ash(FA).The performance of filling material prepared from composite solid waste(FA-CS-RM)mineralized with CO_(2) meets the filling requirements of goaf.The filling material(F60C20R20)obtained by CO_(2) mineralization was 14.9 MPa in maximum compressive strength,increasing by 32.2%compared to the non-mineralized material.The prepared filling material exhibits excellent CO_(2) sequestration capacity(i.e.,14.4 kg·t^(−1) in maximum amount of CO_(2) sequestration).According to the analysis of carbon sequestration potential,in China,the annual production of FA,CS,and RM is approximately 899,30,and 107 Mt,respectively in the year of 2023.The utilization of FA,CS,and RM individually can achieve carbon emission reductions of 3.42,10.78,and 0.61 Mt,respectively.The composite solid waste(FA-CS-RM)mineralized with CO_(2) can achieve 1.23 Mt in carbon emissions reduction.Additionally,taking Yellow River Basin of China as a case study,the total volume of underground space in coal mine goafs from 2016 to 2030 is estimated at 8.16 Gm3,indicating that this technology can sequester 0.18 Gt of CO_(2).This approach offers a promising solution for large-scale flue gas CO_(2) sequestration,recycling coal-based solid wastes,and remediating coal mine goafs,contributing to green utilization of coal and the emission reduction of carbon.
基金supported by the National Natural Science Foun-dation of China(Grants No.42471118 and 52078440)the Youth Innovation Promotion Association of CAS(Grant No.2021194).
文摘Urbanization radically alters the climatic environment and landscape patterns of urban areas,but its impact on the carbon sequestration capacity of vegetation remains uncertain.Given the limitations of current small-scale ground-based in situ experiments,the response of vegetation carbon sequestration capacity to urbanization and the factors influencing it remain unclear at the global scale.Using multisource remote sensing data,we quanti-fied and differentiated the direct and indirect impacts of urbanization on the carbon sequestration capacity of vegetation in 508 large urban areas globally from 2000 to 2020.The results revealed that the direct impacts of urbanization were generally negative.However,446 cities experienced an indirect enhancement in vegetation carbon sequestration capacity during urbanization,averaging 19.6%globally and offsetting 14.7%of the di-rect loss due to urbanization.These positive indirect effects were most pronounced in environments with limited hydrothermal conditions and increased most in densely populated temperate and cold regions.Furthermore,indi-rect impacts were closely related to urbanization intensity,human footprint,and level of urban development.Our study enhances the understanding of how the carbon sequestration capacity of vegetation dynamically responds to changes in the urban environment,which is crucial for improving future urban vegetation management and building sustainable cities.
基金financially supported by the Natural Sci-ence Foundation of Hunan Province,China(No.2024JJ2074)National Natural Science Foundation of China(No.22376221)+2 种基金Young Elite Scientists Sponsorship Pro-gram by the China Association for Science and Technology(CAST)(No.2023QNRC001)partly supported by the High Performance Computing Center of Central South University,Chinasupported by resources provided by the Pawsey Supercomputing Centre with funding from the Australian Government and the Government of Western Australia.
文摘Understanding the differences in CO_(2)adsorption in cementitious material is critical in mitigating the carbon footprint of the construction industry.This study chose the most common β-C_(2)S phase in the industry as the cementitious material,selecting the β-C_(2)S(111)and β-C_(2)S(100)surfaces for CO_(2)adsorption.First-principles calculations were employed to systematically compare the CO_(2)ad-sorption behaviors on both surfaces focusing on adsorption energy,adsorption configurations,and surface reconstruction.The comparis-on of CO_(2)and H2O adsorption behaviors on the β-C_(2)S(111)surface was also conducted to shed light on the influence of CO_(2)on cement hydration.The adsorption energies of CO_(2)on the β-C_(2)S(111)and β-C_(2)S(100)surfaces were determined as-0.647 and-0.423 eV,respect-ively,suggesting that CO_(2)adsorption is more energetically favorable on the β-C_(2)S(111)surface than on the β-C_(2)S(100)surface.The ad-sorption energy of H2O on the β-C_(2)S(111)surface was-1.588 eV,which is 0.941 eV more negative than that of CO_(2),implying that β-C_(2)S tends to become hydrated before reacting with CO_(2).Bader charges,charge density differences,and the partial density of states were ap-plied to characterize the electronic properties of CO_(2)and H2O molecules and those of the surface atoms.The initial Ca/O sites on the β-C_(2)S(111)surface exhibited higher chemical reactivity due to the greater change in the average number of valence electrons in the CO_(2)ad-sorption.Specifically,after CO_(2)adsorption,the average number of valence electrons for both the Ca and O atoms increased by 0.002 on the β-C_(2)S(111)surface,while both decreased by 0.001 on the β-C_(2)S(100)surface.In addition,due to the lower valence electron number of O atoms,the chemical reactivity of O atoms on the β-C_(2)S(111)surface after H2O adsorption was higher than the case of CO_(2)adsorption,which favors the occurrence of further reactions.Overall,this work assessed the adsorption capacity of the β-C_(2)S surface for CO_(2)mo-lecules,offering a strong theoretical foundation for the design of novel cementitious materials for CO_(2)capture and storage.
基金financially supported by the 2023 Fundamental Fund of Thailand Science Research and Innovation(TSRI)under the project titled“The Carbon Dioxide Storage in Local Administration Organization Phitsanulok province Database Partner Plant Genetic Conservation Project Under the Royal Initiation of Her Highness Princess Maha Chakri Siridhorn”(Grant No.4366604).
文摘This study investigates carbon dioxide(CO₂)sequestration and biomass distribution across various plant components and land use types in Ban Krang Subdistrict,Mueang District,Phitsanulok Province,with the goal of enhancing carbon management strategies.Field surveys were conducted using 14 plots of 40×40 meters to quantify biomass and estimate CO₂sequestration across different vegetation types.The findings reveal an average CO₂sequestration of 122.81 ton ha⁻¹,with aboveground biomass,particularly stems,contributing the most to carbon storage.Notably,abandoned perennial crops and mixed perennial crops demonstrated the highest sequestration rates,at 657.94 ton ha⁻¹and 613.00 ton ha⁻¹,respectively.In contrast,agricultural lands such as rice paddies and cassava plantations exhibited the lowest sequestration rates,though rice paddies contributed the highest total CO₂sequestration,amounting to 61,119.71 tons,due to their extensive area.The study highlights the critical role of diverse and dense vegetation,particularly perennial crops,in maximizing carbon sequestration.It also underscores the potential for improving carbon storage in agricultural lands through better land management practices.The results suggest that targeted strategies should prioritize high-sequestration land use types while also enhancing carbon storage in low-sequestration areas.By optimizing land use and management practices,the region can significantly increase its carbon storage capacity,contributing to climate change mitigation and promoting long-term ecological sustainability.These insights are crucial for formulating effective carbon management strategies in Ban Krang Subdistrict,as well as in other comparable regions.
文摘This study investigates the application of carbon dioxide (CO2) sequestration to address challenges in water-drive gas reservoirs, specifically focusing on improving gas recovery and mitigating water invasion. Traditional methods like blow-down and co-production have limitations, including sand production, water coning, and inefficiency in strong aquifers. To overcome these issues, this research explores CO2 injection near the edge aquifer, aiming to reduce water influx and enhance gas recovery through the propagation of a CO2 plume in the gas-water contact zone. Both synthetic and real compositional reservoir models were studied, with CO2 injection performed while maintaining reservoir pressure below 90% of the initial level. Results show that CO2 sequestration significantly improved recovery, particularly in higher permeability reservoirs, where it reduced aquifer influx and increased gas production by 26% under challenging conditions. While CO2 dissolution in water decreased aquifer influx by 39%, its adverse effect on sweep efficiency led to a reduction in gas and water production by 4.2% and 10%, respectively. The method's effectiveness was not significantly impacted by aquifer permeability, but it was sensitive to vertical-to-horizontal permeability ratios. When applied to a real gas reservoir, the proposed method increased gas production by 14% compared to conventional techniques, with minimal CO2 production over a 112-year period. This study demonstrates the potential of CO2 sequestration as a comprehensive solution for enhancing gas recovery, reducing water production, and mitigating environmental impacts in water-drive gas reservoirs.
