Present industrial decarbonization technologies require an active CO_(2)-concentration system,often based on lime reaction or amine binding reactions,which is energy intensive and carries a high CO_(2)-footprint.Here ...Present industrial decarbonization technologies require an active CO_(2)-concentration system,often based on lime reaction or amine binding reactions,which is energy intensive and carries a high CO_(2)-footprint.Here instead,an effective process without active CO_(2)concentration is demonstrated in a new process-termed IC2CNT(Insulationdiffusion facilitated CO_(2) to Carbon Nanomaterial Technology)decarbonization process.Molten carbonates such as Li_(2)CO_(3)(mp 723℃)are highly insoluble to industrial feed gas principal components(N2,O_(2),and H2O).However,CO_(2) can readily dissolve and react in molten carbonates.We have recently characterized high CO_(2) diffusion rates through porous aluminosilicate and calcium-magnesium silicate thermal insulations.Here,the CO_(2) in ambient feed gas passes through these membranes into molten Li_(2)CO_(3).The membrane also concurrently insulates the feed gas from the hot molten carbonate chamber,obviating the need to heat the(non-CO_(2))majority of the feed gas to high temperature.In this insulation facilitated decarbonization process CO_(2)is split by electrolysis in the molten carbonate producing sequestered,high-purity carbon nanomaterials(such as CNTs)and O_(2).展开更多
Addressing global warming,a common change today,requires achieving peak carbon dioxide emissions and carbon neutrality(also referred to as the dual carbon goals).Enhancing research on the carbon cycle is urgently need...Addressing global warming,a common change today,requires achieving peak carbon dioxide emissions and carbon neutrality(also referred to as the dual carbon goals).Enhancing research on the carbon cycle is urgently needed as the foundation.Water,a key carrier in the carbon cycle,necessitates investigation into groundwater carbon pools’contribution to atmospheric carbon sinks.This study assessed carbon stocks in the Yinchuan Basin’s soil and groundwater carbon pools.Findings indicate the basin’s surface soils contain approximately 24.16 Tg of organic carbon and a total of 60.01 Tg of carbon.In contrast,the basin’s groundwater holds around 4.90 Tg of carbon,roughly one-fifth of the organic carbon in surface soils.Thus,groundwater and soil carbon pools possess comparable carbon stocks,underscoring the importance of the groundwater carbon pool.Studies on terrestrial carbon balance should incorporate groundwater carbon pools,which deserve increased focus.Evaluating groundwater carbon pools’contributions is vital for achieving the dual carbon goals.展开更多
The discovery,advances,and industrial-scale up of a unique electrochemical decarbonization chemistry,which sequesters carbon dioxide to mitigate the existential threat of planetary climate change,are presented.C2CNT■...The discovery,advances,and industrial-scale up of a unique electrochemical decarbonization chemistry,which sequesters carbon dioxide to mitigate the existential threat of planetary climate change,are presented.C2CNT■(CO_(2) to Carbon NanoTechnology)is the transition metal nucleated electrolytic splitting of CO_(2) by its trans-formation into a wide range of Graphene NanoCarbon allotropes,C_(GNC),CO_(2)→C_(GNC)+O_(2),such as carbon nanotubes and carbon nano-onions.The original 2015 C2CNT 0.0005 m2 electrode process has been scaled to larger than meter-square area electrodes and used in a series of 100 tonne annual CO_(2) removal industrial Genesis Device modules.The pathway to a further scale-up to a series of 1000 tonne decarbonization placed in series and forming a megaton annual C2CNT decarbonization plant is illustrated.展开更多
With global carbon emissions continuing to rise,carbon dioxide(CO_(2))capture and resource utilization have become central challenges in achieving the“dual carbon”goals(carbon peak and carbon neutrality).Traditional...With global carbon emissions continuing to rise,carbon dioxide(CO_(2))capture and resource utilization have become central challenges in achieving the“dual carbon”goals(carbon peak and carbon neutrality).Traditional carbon capture and storage(CCS)technology can only temporarily sequester CO_(2),whereas emerging green catalytic technologies(photo/electro/thermal catalysis)enable the conversion of CO_(2) into high-value chemicals(e.g.,fuels,pharmaceutical intermediates),advancing the closure of the artificial carbon cycle[1,2].展开更多
This study explores the mechanisms by which China’s pilot carbon emissions trading schemes(ETS)facilitate industrial low-carbon transitions.We construct a theoretical model and conduct an empirical analysis using pro...This study explores the mechanisms by which China’s pilot carbon emissions trading schemes(ETS)facilitate industrial low-carbon transitions.We construct a theoretical model and conduct an empirical analysis using provincial panel data from seven pilot provinces spanning 2006-2021.Applying a multi-period difference-in-differences(DID)approach,we evaluate the environmental and economic impacts of the pilot ETS policies.The findings yield three key insights:(1)The pilot ETS significantly reduces carbon emission intensity and improves low-carbon total factor productivity(TFP),thereby promoting China’s industrial low-carbon transition.(2)Mechanism analysis indicates that the ETS primarily operates through cost constraints and industrial structural upgrading,while the effect of technological progress has yet to fully materialize.(3)Heterogeneity analysis reveals that the policy’s effects are more significant in regions with higher levels of economic development and R&D investment,leading to greater carbon intensity reductions and productivity gains.In addition,regions with higher foreign direct investment(FDI)experience more substantial improvements in low-carbon TFP,possibly reflecting technology spillover effects.展开更多
Carbon dioxide is an important medium of the global carbon cycle,and has the dual properties of realizing the conversion of organic matter in the ecosystem and causing the greenhouse effect.The fixed or available carb...Carbon dioxide is an important medium of the global carbon cycle,and has the dual properties of realizing the conversion of organic matter in the ecosystem and causing the greenhouse effect.The fixed or available carbon dioxide in the atmosphere is defined as"gray carbon",while the carbon dioxide that cannot be fixed or used and remains in the atmosphere is called"black carbon".Carbon neutral is the consensus of human development,but its implementation still faces many challenges in politics,resources,technology,market,and energy structure,etc.It is proposed that carbon replacement,carbon emission reduction,carbon sequestration,and carbon cycle are the four main approaches to achieve carbon neutral,among which carbon replacement is the backbone.New energy has become the leading role of the third energy conversion and will dominate carbon neutral in the future.Nowadays,solar energy,wind energy,hydropower,nuclear energy and hydrogen energy are the main forces of new energy,helping the power sector to achieve low carbon emissions."Green hydrogen"is the reserve force of new energy,helping further reduce carbon emissions in industrial and transportation fields.Artificial carbon conversion technology is a bridge connecting new energy and fossil energy,effectively reducing the carbon emissions of fossil energy.It is predicted that the peak value of China’s carbon dioxide emissions will reach 110×10^(8) t in 2030.The study predicts that China’s carbon emissions will drop to 22×10^(8) t,33×10^(8) t and 44×10^(8) t,respectively,in 2060 according to three scenarios of high,medium,and low levels.To realize carbon neutral in China,seven implementation suggestions have been put forward to build a new"three small and one large"energy structure in China and promote the realization of China’s energy independence strategy.展开更多
In order to deal with the global change and to reduce emission of greenhouse gas, a number of countries have strengthened studies on carbon sequestration in cropland. Carbon sequestration in cropland is not only an im...In order to deal with the global change and to reduce emission of greenhouse gas, a number of countries have strengthened studies on carbon sequestration in cropland. Carbon sequestration in cropland is not only an important component for the global carbon stock, but also is the most active part to sequestrate the carbon in soil from atmosphere. In this sense, it is of necessity and significance to strengthen the study on management of carbon sequestration in cropland. Based on the main factors affecting carbon cycle in agro-ecosystems, this paper summarizes the relevant management measures to strengthen the capacity of reducing emission of carbon and increasing the carbon sequestration in cropland, and evaluates the effects of these measures after being implemented at a regional extent.展开更多
The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D i...The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.展开更多
To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content ...To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.展开更多
Heteroatom-doped carbon is considered a promising alternative to commercial Pt/C as an efficient catalyst for the oxygen reduction reaction(ORR).This study presents the synthesis of iron-loaded,sulfur and nitrogen co-...Heteroatom-doped carbon is considered a promising alternative to commercial Pt/C as an efficient catalyst for the oxygen reduction reaction(ORR).This study presents the synthesis of iron-loaded,sulfur and nitrogen co-doped carbon(Fe/SNC)via in situ incorporation of 2-aminothiazole molecules into zeolitic imidazolate framework-8(ZIF-8)through coordination between metal ions and organic ligands.Sulfur and nitrogen doping in carbon supports effectively modulates the electronic structure of the catalyst,increases the Brunauer-Emmett-Teller surface area,and exposes more Fe-N_(x)active centers.Fe-loaded,S and N co-doped carbon with Fe/S molar ratio of 1:10(Fe/SNC-10)exhibits a half-wave potential of 0.902 V vs.RHE.After 5000 cycles of cyclic voltammetry,its half-wave potential decreases by only 20 mV vs.RHE,indicating excellent stability.Due to sulfur s lower electronegativity,the electronic structure of the Fe-N_(x)active center is modulated.Additionally,the larger atomic radius of sulfur introduces defects into the carbon support.As a result,Fe/SNC-10 demonstrates superior ORR activity and stability in alkaline solution compared with Fe-loaded N-doped carbon(Fe/NC).Furthermore,the zinc-air battery assembled with the Fe/SNC-10 catalyst shows enhanced performance relative to those assembled with Fe/NC and Pt/C catalysts.This work offers a novel design strategy for advanced energy storage and conversion applications.展开更多
Electrocatalytic nitrate reduction reaction(NO3RR)represents a sustainable and environmentally benign route for ammonia(NH3)synthesis.However,NO3RR is still limited by the competition from hydrogen evolution reaction(...Electrocatalytic nitrate reduction reaction(NO3RR)represents a sustainable and environmentally benign route for ammonia(NH3)synthesis.However,NO3RR is still limited by the competition from hydrogen evolution reaction(HER)and the high energy barrier in the hydrogenation step of nitrogen-containing intermediates.Here,we report a selective etching strategy to construct Ru M nanoalloys(M=Fe,Co,Ni,Cu)uniformly dispersed on porous nitrogen-doped carbon substrates for efficient neutral NH3electrosynthesis.Density functional theory calculations confirm that the synergic effect between Ru and transition metal M modulates the electronic structure of the alloy,significantly lowering the energy barrier for the conversion of*NO_(2)to*HNO_(2).Experimentally,the optimized Ru Fe-NC catalyst achieves 100%Faraday efficiency with a high yield rate of 0.83 mg h^(-1)mg^(-1)catat a low potential of-0.1 V vs.RHE,outperforming most reported catalysts.In situ spectroscopic analyses further demonstrate that the Ru M-NC effectively promotes the hydrogenation of nitrogen intermediates while inhibiting the formation of hydrogen radicals,thereby reducing HER competition.The Ru FeNC assembled Zn-NO_(3)^(-)battery achieved a high open-circuit voltage and an outstanding power density and capacity,which drive selective NO_(3)^(-)conversion to NH3.This work provides a powerful synergistic design strategy for efficient NH3electrosynthesis and a general framework for the development of advanced multi-component catalysts for sustainable nitrogen conversion.展开更多
Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains...Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.展开更多
Global land monsoon precipitation(GLMP)is highly sensitive to changes in interhemispheric thermal contrast(ITC).Amplified interhemispheric asymmetries of GLMP due to enhanced ITC driven by high-level anthropogenic emi...Global land monsoon precipitation(GLMP)is highly sensitive to changes in interhemispheric thermal contrast(ITC).Amplified interhemispheric asymmetries of GLMP due to enhanced ITC driven by high-level anthropogenic emissions are expected to simultaneously increase the probability of regional floods and droughts,threatening ecosystems within global terrestrial monsoon regions and the freshwater supply for billions of residents in these areas.In this study,the responses of GLMP to the evolution of ITC toward the carbon neutrality goal are assessed using multimodel outputs from a new model intercomparison project(CovidMIP).The results show that the Northern Hemisphere-Southern Hemisphere(NH-SH)asymmetry of GLMP in boreal summer weakens during the 2040s,as a persistent reduction in well-mixed greenhouse gas(WMGHG)emissions leads to a downward trend in the ITC after 2040.At the same time,the reduction in WMGHG emissions dampens the Eastern Hemisphere-Western Hemisphere(EH-WH)asymmetry of GLMP by inducing La Niña-like cooling and enhancing moisture transport to Inner America.The resulting increases in land monsoon precipitation(LMP)may alleviate drought under the global warming scenario by about 19%-25%and 7%-9%in the WH and SH monsoon regions,respectively.However,a persistent reduction in aerosol emissions in Asia will dominate the increases in LMP in this region until the mid-21st century,and these increases may be approximately 23%-60%of the growth under the global warming scenario.Our results highlight the different rates of response of aerosol and WMGHG concentrations to the carbon neutrality goal,leading to various changes in LMP at global and regional scales.展开更多
It is challenging to diagnose isolated hyperbilirubinemia with rare and complex etiologies under the constraints of traditional testing conditions.Herein,we present a rare case of coexisting Gilbert syndrome(GS)and er...It is challenging to diagnose isolated hyperbilirubinemia with rare and complex etiologies under the constraints of traditional testing conditions.Herein,we present a rare case of coexisting Gilbert syndrome(GS)and erythropoietic protoporphyria(EPP),which has not been previously documented.CASE SUMMARY We present a rare case of coexisting GS and EPP in a 23-year-old Chinese male with a long history of jaundice and recently found splenomegaly.Serial nonspecific hemolysis screening tests yielded inconsistent results,and investigations for common hemolytic etiologies were negative.However,Levitt’s carbon monoxide breath test,which measures erythrocyte lifespan(the gold-standard marker of hemolysis),demonstrated significant hemolysis,revealing a markedly shortened erythrocyte lifespan of 11 days(normal average 120 days).Genetic testing subsequently confirmed EPP with a homozygous ferrochelatase gene mutation and GS with a heterozygous uridine diphosphate glucuronosyl trans-ferase 1A1 gene mutation.CONCLUSION The rapid,non-invasive Levitt’s carbon monoxide breath test resolved the diagnostic challenge posed by a rare and complex cause of hyperbilirubinemia.展开更多
Analysis of the environmental and economic performance of fishing vessels has received limited attention compared with other ship types despite their notable contribution to global greenhouse gas(GHG)emissions.This st...Analysis of the environmental and economic performance of fishing vessels has received limited attention compared with other ship types despite their notable contribution to global greenhouse gas(GHG)emissions.This study evaluates the carbon footprint(CF)and economic viability of a liquefied natural gas(LNG)-fueled fishing vessel,using real engine operation simulations to provide precise and dynamic evaluation of fuel consumption and GHG emissions.Operational profiles are obtained through the utilization of onboard monitoring systems,whereas engine performance is simulated using the 1D/0D AVL Boost^(TM)model.Life cycle assessment(LCA)is conducted to quantify the environmental impact,whereas life cycle cost assessment(LCCA)is performed to analyze the profitability of LNG as an alternative fuel.The potential impact of the future fuel price uncertainties is addressed using Monte Carlo simulations.The LCA findings indicate that LNG has the potential to reduce the CF of the vessel by 14%to 16%,in comparison to a diesel power system configuration that serves as the baseline scenario.The LCCA results further indicate that the total cost of an LNG-powered ship is lower by 9.5%-13.8%,depending on the share of LNG and pilot fuels.This finding highlights the potential of LNG to produce considerable environmental benefits while addressing economic challenges under diverse operational and fuel price conditions.展开更多
Carbon dioxide storage and utilization has become an inevitable trend and choice for sustainable development under the background of global climate change and carbon neutrality.Carbon industry which is dominated by CO...Carbon dioxide storage and utilization has become an inevitable trend and choice for sustainable development under the background of global climate change and carbon neutrality.Carbon industry which is dominated by CO_(2) capture,utilization and storage/CO_(2) capture and storage(CCUS/CCS)is becoming a new strategic industry under the goal of carbon neutrality.The sustainable development of carbon industry needs to learn from the experiences of global oil and gas industry development.There are three types of“carbon”in the earth system.Black carbon is the CO_(2) that has not been sequestered or used and remains in the atmosphere for a long time;grey carbon is the CO_(2) that has been fixed or permanently sequestered in the geological body,and blue carbon is the CO_(2) that could be converted into products for human use through biological,physical,chemical and other ways.The carbon industry system covers carbon generation,carbon capture,carbon transportation,carbon utilization,carbon sequestration,carbon products,carbon finance,and other businesses.It is a revolutionary industrial field to completely eliminate“black carbon”.The development of carbon industry technical system takes carbon emission reduction,zero carbon,negative carbon and carbon economy as the connotation,and the construction of a low-cost and energy-efficient carbon industry system based on CCUS/CCS are strategic measures to achieve the goal of carbon neutrality and clean energy utilization globally.This will promote the“four 80%s”transformation of China's energy supply,namely,to 2060,the percentage of zero-carbon new energy in the energy consumption will be over 80%and the CO_(2) emission will be decreased by 80%to ensure the carbon emission reduction of total 80×10^(8) t from the percentage of carbon-based fossil energy in the energy consumption of over 80%,and the percentage of CO_(2) emission from energy of over 80%in 2021.The carbon industry in China is facing three challenges,large CO_(2) emissions,high percentage of coal in energy consumption,and poor innovative system.Three strategic measures are proposed accordingly,including:(1)unswervingly develop carbon industrial system and ensure the achievement of carbon neutrality as scheduled by 2060;(2)vigorously develop new energy sources and promote a revolutionary transformation of China’s energy production and consumption structure;(3)accelerate the establishment of scientific and technological innovation system of the whole CO_(2) industry.It is of great significance for continuously optimization of ecological environment and construction of green earth and ecological earth to develop the carbon industry system,utilize clean energy,and achieve the strategic goal of global carbon neutrality.展开更多
With the in-depth advancement of China’s dual carbon goals,the national carbon emissions trading market has become a core policy tool for achieving emission reduction targets.However,the current carbon market remains...With the in-depth advancement of China’s dual carbon goals,the national carbon emissions trading market has become a core policy tool for achieving emission reduction targets.However,the current carbon market remains predominantly spot-based,facing challenges such as limited financial products,restricted market participants,immature carbon pricing mechanisms,and insufficient liquidity,which constrain its resource allocation and risk management functions.Based on the spirit of the“Opinions on Promoting Green Low-Carbon Transformation and Strengthening National Carbon Market Construction”issued by the General Office of the CPC Central Committee and the General Office of the State Council,this paper focuses on the challenges faced during the implementation of the dual control system for carbon emissions in the“Fifteenth Five-Year Plan”period,with emphasis on analyzing the development bottlenecks of the carbon market.It proposes accelerating the launch of carbon futures,carbon options and other derivatives,expanding the scope of financial institution participation,improving carbon market infrastructure,and establishing a cross-departmental coordinated policy framework.By drawing on international experience and combining domestic pilot practices,this aims to provide an operational and implementable pathway for the development of China’s carbon market,further enhancing the supporting role of the carbon market in green low-carbon transformation.展开更多
As the national carbon emission trading system extends to high energy-consuming industries,the petroleum exploration&development and refining&chemical engineering sectors face the dual challenges of rigid carb...As the national carbon emission trading system extends to high energy-consuming industries,the petroleum exploration&development and refining&chemical engineering sectors face the dual challenges of rigid carbon constraints and energy structure restructuring.This study innovatively proposes the“dual inflection point theory”,which reveals that the transformation window requires the industry to overcome composite pressures including regional energy imbalances,international carbon tariff barriers,and technological substitution bottlenecks.This paper constructs a five-in-one governance framework encompassing“policy coordination,market circulation,intelligent regulation,energy substitution,energy efficiency innovation”.展开更多
Soil erosion is a critical process influencing the global carbon cycle.However,erosion-induced carbon changes remain inadequately understood,particularly for soil inorganic carbon(SIC).There is also limited knowledge ...Soil erosion is a critical process influencing the global carbon cycle.However,erosion-induced carbon changes remain inadequately understood,particularly for soil inorganic carbon(SIC).There is also limited knowledge about the factors influencing soil carbon dynamics during erosion processes.Here we quantify the global translocation of soil organic carbon(SOC)and SIC due to soil erosion using data-driven global soil carbon estimates combined with a soil erosion map derived from the Revised Universal Soil Loss Equation(RUSLE)model.Our analysis reveals that global SIC and SOC translocations from soil erosion are 107.1 Tg C yr^(−1)and 898.4 Tg C yr^(−1),respectively.These translocations exhibit distinct patterns across aridity gradients and different biomes and soil types,with SIC translocation increasing while SOC translocation decreasing with aridity.Croplands exhibit significantly higher soil carbon translocation compared to natural vegetation,with SIC translocation being 2.41 times higher and SOC translocation 0.65 times higher than in forests.Topographic features(slope length and steepness)predominantly determine soil carbon translocation during erosion,with steeper and longer slopes exacerbating erosion and subsequent SIC/SOC translocation.Land use change,particularly agricultural practices,is also a critical driver.Our findings provide valuable insights into the factors influencing SIC and SOC translocation,enhancing our understanding of the global patterns and determinants of erosion-induced soil carbon dynamics.展开更多
Mesozoic-Palaeozoic marine carbonate rocks are crucial hydrocarbon reservoirs in the Central Uplift area of the South Yellow Sea Basin(SYSB).Due to the scarcity of boreholes and the significant heterogeneity of carbon...Mesozoic-Palaeozoic marine carbonate rocks are crucial hydrocarbon reservoirs in the Central Uplift area of the South Yellow Sea Basin(SYSB).Due to the scarcity of boreholes and the significant heterogeneity of carbonate reservoirs,the distribution of porous carbonate reservoirs and their related key controlling factors remain unclear.In this study,factors affecting the distribution of porous Carboniferous-Early Permian carbonate reservoirs in the SYSB were investigated through seismic inversion and isotope analysis.The log-seismic characteristics of porous carbonate reservoirs,sensitive lithology parameters,and physical property parameters were extracted and analyzed.The pre-stack simultaneous inversion technique was applied to predict the lithology and physical properties of porous carbonate reservoirs.Moreover,the sedimentary of carbonate was analyzed using isotopes of carbon,oxygen,and strontium.The results show that porous carbonate reservoirs are mainly developed in the open platform sediments with porosities of 3%-5%and are mainly distributed in the paleo-highland(Huanglong Formation and Chuanshan Formation)and the slope of paleo-highland(Hezhou Formation).The porous carbonate reservoirs of the Qixia Formation are only locally developed.In addition,the negativeδ13C excursions indicate a warm and humid tropical climate with three sea-level fluctuations in the study area from the Carboniferous to Early Permian.The favorable conditions for developing porous carbonate rocks include the sedimentary environment and diagenetic process.The primary pore tends to form in high-energy environments of the paleo-highland,and the secondary pore is increased by dissolution during the syngenetic or quasi-syngenetic period.According to the hydrocarbon potential analysis,the Late Ordovician Wufeng Formation and Lower Silurian Gaojiabian Formation are the source rocks in the high-maturity-over-maturity stage,the Carboniferous-Lower Permian carbonate is the good reservoirs,and the Late Permian Longtan-Dalong Formation is the stable seal,ensuring a huge hydrocarbon accumulation potential in SYSB.The methods proposed in this study can be applied to other carbonate-dominated strata worldwide.展开更多
文摘Present industrial decarbonization technologies require an active CO_(2)-concentration system,often based on lime reaction or amine binding reactions,which is energy intensive and carries a high CO_(2)-footprint.Here instead,an effective process without active CO_(2)concentration is demonstrated in a new process-termed IC2CNT(Insulationdiffusion facilitated CO_(2) to Carbon Nanomaterial Technology)decarbonization process.Molten carbonates such as Li_(2)CO_(3)(mp 723℃)are highly insoluble to industrial feed gas principal components(N2,O_(2),and H2O).However,CO_(2) can readily dissolve and react in molten carbonates.We have recently characterized high CO_(2) diffusion rates through porous aluminosilicate and calcium-magnesium silicate thermal insulations.Here,the CO_(2) in ambient feed gas passes through these membranes into molten Li_(2)CO_(3).The membrane also concurrently insulates the feed gas from the hot molten carbonate chamber,obviating the need to heat the(non-CO_(2))majority of the feed gas to high temperature.In this insulation facilitated decarbonization process CO_(2)is split by electrolysis in the molten carbonate producing sequestered,high-purity carbon nanomaterials(such as CNTs)and O_(2).
基金supported by the third scientific survey project in Xinjiang(2022xjkk0300)the public welfare geological survey projects initiated by the China Geological Survey(DD20190296,DD20221731).
文摘Addressing global warming,a common change today,requires achieving peak carbon dioxide emissions and carbon neutrality(also referred to as the dual carbon goals).Enhancing research on the carbon cycle is urgently needed as the foundation.Water,a key carrier in the carbon cycle,necessitates investigation into groundwater carbon pools’contribution to atmospheric carbon sinks.This study assessed carbon stocks in the Yinchuan Basin’s soil and groundwater carbon pools.Findings indicate the basin’s surface soils contain approximately 24.16 Tg of organic carbon and a total of 60.01 Tg of carbon.In contrast,the basin’s groundwater holds around 4.90 Tg of carbon,roughly one-fifth of the organic carbon in surface soils.Thus,groundwater and soil carbon pools possess comparable carbon stocks,underscoring the importance of the groundwater carbon pool.Studies on terrestrial carbon balance should incorporate groundwater carbon pools,which deserve increased focus.Evaluating groundwater carbon pools’contributions is vital for achieving the dual carbon goals.
文摘The discovery,advances,and industrial-scale up of a unique electrochemical decarbonization chemistry,which sequesters carbon dioxide to mitigate the existential threat of planetary climate change,are presented.C2CNT■(CO_(2) to Carbon NanoTechnology)is the transition metal nucleated electrolytic splitting of CO_(2) by its trans-formation into a wide range of Graphene NanoCarbon allotropes,C_(GNC),CO_(2)→C_(GNC)+O_(2),such as carbon nanotubes and carbon nano-onions.The original 2015 C2CNT 0.0005 m2 electrode process has been scaled to larger than meter-square area electrodes and used in a series of 100 tonne annual CO_(2) removal industrial Genesis Device modules.The pathway to a further scale-up to a series of 1000 tonne decarbonization placed in series and forming a megaton annual C2CNT decarbonization plant is illustrated.
基金supported by the National Natural Science Foundation of China(22472069,22102064,and 22302080)China Postdoctoral Science Foundation(2024M760028).
文摘With global carbon emissions continuing to rise,carbon dioxide(CO_(2))capture and resource utilization have become central challenges in achieving the“dual carbon”goals(carbon peak and carbon neutrality).Traditional carbon capture and storage(CCS)technology can only temporarily sequester CO_(2),whereas emerging green catalytic technologies(photo/electro/thermal catalysis)enable the conversion of CO_(2) into high-value chemicals(e.g.,fuels,pharmaceutical intermediates),advancing the closure of the artificial carbon cycle[1,2].
基金Major Project of the National Social Science Foundation of China(NSSFC)-“Study on the Construction of China’s Unified Carbon Market and the Realization Mechanism of the‘Dual Carbon’Goal”(Grant No.24VRC003).
文摘This study explores the mechanisms by which China’s pilot carbon emissions trading schemes(ETS)facilitate industrial low-carbon transitions.We construct a theoretical model and conduct an empirical analysis using provincial panel data from seven pilot provinces spanning 2006-2021.Applying a multi-period difference-in-differences(DID)approach,we evaluate the environmental and economic impacts of the pilot ETS policies.The findings yield three key insights:(1)The pilot ETS significantly reduces carbon emission intensity and improves low-carbon total factor productivity(TFP),thereby promoting China’s industrial low-carbon transition.(2)Mechanism analysis indicates that the ETS primarily operates through cost constraints and industrial structural upgrading,while the effect of technological progress has yet to fully materialize.(3)Heterogeneity analysis reveals that the policy’s effects are more significant in regions with higher levels of economic development and R&D investment,leading to greater carbon intensity reductions and productivity gains.In addition,regions with higher foreign direct investment(FDI)experience more substantial improvements in low-carbon TFP,possibly reflecting technology spillover effects.
文摘Carbon dioxide is an important medium of the global carbon cycle,and has the dual properties of realizing the conversion of organic matter in the ecosystem and causing the greenhouse effect.The fixed or available carbon dioxide in the atmosphere is defined as"gray carbon",while the carbon dioxide that cannot be fixed or used and remains in the atmosphere is called"black carbon".Carbon neutral is the consensus of human development,but its implementation still faces many challenges in politics,resources,technology,market,and energy structure,etc.It is proposed that carbon replacement,carbon emission reduction,carbon sequestration,and carbon cycle are the four main approaches to achieve carbon neutral,among which carbon replacement is the backbone.New energy has become the leading role of the third energy conversion and will dominate carbon neutral in the future.Nowadays,solar energy,wind energy,hydropower,nuclear energy and hydrogen energy are the main forces of new energy,helping the power sector to achieve low carbon emissions."Green hydrogen"is the reserve force of new energy,helping further reduce carbon emissions in industrial and transportation fields.Artificial carbon conversion technology is a bridge connecting new energy and fossil energy,effectively reducing the carbon emissions of fossil energy.It is predicted that the peak value of China’s carbon dioxide emissions will reach 110×10^(8) t in 2030.The study predicts that China’s carbon emissions will drop to 22×10^(8) t,33×10^(8) t and 44×10^(8) t,respectively,in 2060 according to three scenarios of high,medium,and low levels.To realize carbon neutral in China,seven implementation suggestions have been put forward to build a new"three small and one large"energy structure in China and promote the realization of China’s energy independence strategy.
基金Supported by National Natural Science Foundation of China(70873118)the Chinese Academy of Sciences (kzcx2-yw-305-2)the national key scientific and technological project(2006BAC08B03,2006BAC08B06,2008BAC43B01)~~
文摘In order to deal with the global change and to reduce emission of greenhouse gas, a number of countries have strengthened studies on carbon sequestration in cropland. Carbon sequestration in cropland is not only an important component for the global carbon stock, but also is the most active part to sequestrate the carbon in soil from atmosphere. In this sense, it is of necessity and significance to strengthen the study on management of carbon sequestration in cropland. Based on the main factors affecting carbon cycle in agro-ecosystems, this paper summarizes the relevant management measures to strengthen the capacity of reducing emission of carbon and increasing the carbon sequestration in cropland, and evaluates the effects of these measures after being implemented at a regional extent.
基金Supported by the National Natural Science Foundation of China(22378181).
文摘The development of materials with excellent microwave absorption(MWA)and electromagnetic interference(EMI)shielding performances has currently received attention.Herein,mesophase pitch-based carbon foam(MPCF)with 3D interconnected pore structure was prepared through the high pressure pyrolysis of mesophase coal tar pitch.It is found that the 3D interconnected cellular pores of MPCF facilitate multiple reflections of electromagnetic waves,which results in the minimum reflection loss(RLmin)value of MPCF reaches-37.84 dB with the effective absorption bandwidth(EAB)of 5.44 GHz at a thickness of 2.70 mm,and the total average electromagnetic shielding effectiveness(SE_(T))under 3.00 mm thickness achieves 26.52 dB in X-band.Subsequently,MPCF is activated by KOH to obtain activated carbon foam(A-MPCF).The average SE_(T)of A-MPCF achieves 103.00 dB for abundant nanopores on the pore cell walls,which leads to a transition from the multiple reflections of electromagnetic waves on the walls to diffuse reflection.Unfortunately,the reflection coefficient(R)of A-MPCF increases from 0.78 to 0.90.To reduce the R value,Fe_(3)O_(4)/A-MPCF was fabricated via the in situ growth of nano Fe_(3)O_(4)on A-MPCF.Consequently,the R value of Fe_(3)O_(4)/A-MPCF was reduced from 0.90 to 0.74,whereas the MWA performance was only slightly decreased.This work proposes a simple strategy for simultaneously adjusting MWA and EMI shielding performances of materials.
基金Supported by the Science and Technology Cooperation and Exchange special project of Cooperation of Shanxi Province(202404041101014)the Fundamental Research Program of Shanxi Province(202403021212333)+3 种基金the Joint Funds of the National Natural Science Foundation of China(U24A20555)the Lvliang Key R&D of University-Local Cooperation(2023XDHZ10)the Initiation Fund for Doctoral Research of Taiyuan University of Science and Technology(20242026)the Outstanding Doctor Funding Award of Shanxi Province(20242080).
文摘To elucidate the effect of calcite-regulated activated carbon(AC)structure on low-temperature denitrification performance of SCR catalysts,this work prepared a series of Mn-Ce/De-AC-xCaCO_(3)(x is the calcite content in coal)catalysts were prepared by the incipient wetness impregnation method,followed by acid washing to remove calcium-containing minerals.Comprehensive characterization and low-temperature denitrification tests revealed that calcite-induced structural modulation of coal-derived AC significantly enhances catalytic activity.Specifically,NO conversion increased from 88.3%of Mn-Ce/De-AC to 91.7%of Mn-Ce/De-AC-1CaCO_(3)(210℃).The improved SCR denitrification activity results from the enhancement of physicochemical properties including higher Mn^(4+)content and Ce^(4+)/Ce^(3+)ratio,an abundance of chemisorbed oxygen and acidic sites,which could strengthen the SCR reaction pathways(richer NH_(3)activated species and bidentate nitrate active species).Therefore,NO removal is enhanced.
基金financial support of the National Natural Science Foundation of China(No.52472271)the National Key Research and Development Program of China(No.2023YFE0115800)。
文摘Heteroatom-doped carbon is considered a promising alternative to commercial Pt/C as an efficient catalyst for the oxygen reduction reaction(ORR).This study presents the synthesis of iron-loaded,sulfur and nitrogen co-doped carbon(Fe/SNC)via in situ incorporation of 2-aminothiazole molecules into zeolitic imidazolate framework-8(ZIF-8)through coordination between metal ions and organic ligands.Sulfur and nitrogen doping in carbon supports effectively modulates the electronic structure of the catalyst,increases the Brunauer-Emmett-Teller surface area,and exposes more Fe-N_(x)active centers.Fe-loaded,S and N co-doped carbon with Fe/S molar ratio of 1:10(Fe/SNC-10)exhibits a half-wave potential of 0.902 V vs.RHE.After 5000 cycles of cyclic voltammetry,its half-wave potential decreases by only 20 mV vs.RHE,indicating excellent stability.Due to sulfur s lower electronegativity,the electronic structure of the Fe-N_(x)active center is modulated.Additionally,the larger atomic radius of sulfur introduces defects into the carbon support.As a result,Fe/SNC-10 demonstrates superior ORR activity and stability in alkaline solution compared with Fe-loaded N-doped carbon(Fe/NC).Furthermore,the zinc-air battery assembled with the Fe/SNC-10 catalyst shows enhanced performance relative to those assembled with Fe/NC and Pt/C catalysts.This work offers a novel design strategy for advanced energy storage and conversion applications.
基金financially supported by National Natural Science Foundation of China(22466010)Guizhou Provincial Basic Research Program(Natural Science)ZK[2023]47 and key program ZD[2025]075+6 种基金Innovation and Entrepreneurship Project for overseas Talents in Guizhou Province[2022]02Specific Natural Science Foundation of Guizhou University(X202207)the national undergraduate innovation and entrepreneurship training program(gzugc2023006gzusc2024012)SRT project of Guizhou university(2023SRT0292023SRT024)supported by Shanghai Technical Service Center of Science and Engineering Computing,Shanghai University。
文摘Electrocatalytic nitrate reduction reaction(NO3RR)represents a sustainable and environmentally benign route for ammonia(NH3)synthesis.However,NO3RR is still limited by the competition from hydrogen evolution reaction(HER)and the high energy barrier in the hydrogenation step of nitrogen-containing intermediates.Here,we report a selective etching strategy to construct Ru M nanoalloys(M=Fe,Co,Ni,Cu)uniformly dispersed on porous nitrogen-doped carbon substrates for efficient neutral NH3electrosynthesis.Density functional theory calculations confirm that the synergic effect between Ru and transition metal M modulates the electronic structure of the alloy,significantly lowering the energy barrier for the conversion of*NO_(2)to*HNO_(2).Experimentally,the optimized Ru Fe-NC catalyst achieves 100%Faraday efficiency with a high yield rate of 0.83 mg h^(-1)mg^(-1)catat a low potential of-0.1 V vs.RHE,outperforming most reported catalysts.In situ spectroscopic analyses further demonstrate that the Ru M-NC effectively promotes the hydrogenation of nitrogen intermediates while inhibiting the formation of hydrogen radicals,thereby reducing HER competition.The Ru FeNC assembled Zn-NO_(3)^(-)battery achieved a high open-circuit voltage and an outstanding power density and capacity,which drive selective NO_(3)^(-)conversion to NH3.This work provides a powerful synergistic design strategy for efficient NH3electrosynthesis and a general framework for the development of advanced multi-component catalysts for sustainable nitrogen conversion.
基金financially supported by the National Natural Science Foundation of China(Nos.22272118,22172111,and 22309134)the Science and Technology Commission of Shanghai Municipality,China(Nos.22ZR1464100,20ZR1460300,and 19DZ2271500)+2 种基金the China Postdoctoral Science Foundation(2022M712402),the Shanghai Rising-Star Program(23YF1449200)the Zhejiang Provincial Science and Technology Project(2022C01182)the Fundamental Research Funds for the Central Universities(2023-3-YB-07)。
文摘Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.
基金funded by the National Natural Science Foundation of China(Grant No.42275039)the Meteorological Joint Fund by NSF and CMA(Grant No.U2342224)+1 种基金the National Key R&D Program of China(Grant No.2022YFC3701202)the S&T Development Fund of CAMS(Grant No.2024KJ019)。
文摘Global land monsoon precipitation(GLMP)is highly sensitive to changes in interhemispheric thermal contrast(ITC).Amplified interhemispheric asymmetries of GLMP due to enhanced ITC driven by high-level anthropogenic emissions are expected to simultaneously increase the probability of regional floods and droughts,threatening ecosystems within global terrestrial monsoon regions and the freshwater supply for billions of residents in these areas.In this study,the responses of GLMP to the evolution of ITC toward the carbon neutrality goal are assessed using multimodel outputs from a new model intercomparison project(CovidMIP).The results show that the Northern Hemisphere-Southern Hemisphere(NH-SH)asymmetry of GLMP in boreal summer weakens during the 2040s,as a persistent reduction in well-mixed greenhouse gas(WMGHG)emissions leads to a downward trend in the ITC after 2040.At the same time,the reduction in WMGHG emissions dampens the Eastern Hemisphere-Western Hemisphere(EH-WH)asymmetry of GLMP by inducing La Niña-like cooling and enhancing moisture transport to Inner America.The resulting increases in land monsoon precipitation(LMP)may alleviate drought under the global warming scenario by about 19%-25%and 7%-9%in the WH and SH monsoon regions,respectively.However,a persistent reduction in aerosol emissions in Asia will dominate the increases in LMP in this region until the mid-21st century,and these increases may be approximately 23%-60%of the growth under the global warming scenario.Our results highlight the different rates of response of aerosol and WMGHG concentrations to the carbon neutrality goal,leading to various changes in LMP at global and regional scales.
文摘It is challenging to diagnose isolated hyperbilirubinemia with rare and complex etiologies under the constraints of traditional testing conditions.Herein,we present a rare case of coexisting Gilbert syndrome(GS)and erythropoietic protoporphyria(EPP),which has not been previously documented.CASE SUMMARY We present a rare case of coexisting GS and EPP in a 23-year-old Chinese male with a long history of jaundice and recently found splenomegaly.Serial nonspecific hemolysis screening tests yielded inconsistent results,and investigations for common hemolytic etiologies were negative.However,Levitt’s carbon monoxide breath test,which measures erythrocyte lifespan(the gold-standard marker of hemolysis),demonstrated significant hemolysis,revealing a markedly shortened erythrocyte lifespan of 11 days(normal average 120 days).Genetic testing subsequently confirmed EPP with a homozygous ferrochelatase gene mutation and GS with a heterozygous uridine diphosphate glucuronosyl trans-ferase 1A1 gene mutation.CONCLUSION The rapid,non-invasive Levitt’s carbon monoxide breath test resolved the diagnostic challenge posed by a rare and complex cause of hyperbilirubinemia.
文摘Analysis of the environmental and economic performance of fishing vessels has received limited attention compared with other ship types despite their notable contribution to global greenhouse gas(GHG)emissions.This study evaluates the carbon footprint(CF)and economic viability of a liquefied natural gas(LNG)-fueled fishing vessel,using real engine operation simulations to provide precise and dynamic evaluation of fuel consumption and GHG emissions.Operational profiles are obtained through the utilization of onboard monitoring systems,whereas engine performance is simulated using the 1D/0D AVL Boost^(TM)model.Life cycle assessment(LCA)is conducted to quantify the environmental impact,whereas life cycle cost assessment(LCCA)is performed to analyze the profitability of LNG as an alternative fuel.The potential impact of the future fuel price uncertainties is addressed using Monte Carlo simulations.The LCA findings indicate that LNG has the potential to reduce the CF of the vessel by 14%to 16%,in comparison to a diesel power system configuration that serves as the baseline scenario.The LCCA results further indicate that the total cost of an LNG-powered ship is lower by 9.5%-13.8%,depending on the share of LNG and pilot fuels.This finding highlights the potential of LNG to produce considerable environmental benefits while addressing economic challenges under diverse operational and fuel price conditions.
基金Supported by the National Natural Science Foundation of China(42072187)PetroChina Science and Technology Major Project(2021ZZ01-05,2021DJ18).
文摘Carbon dioxide storage and utilization has become an inevitable trend and choice for sustainable development under the background of global climate change and carbon neutrality.Carbon industry which is dominated by CO_(2) capture,utilization and storage/CO_(2) capture and storage(CCUS/CCS)is becoming a new strategic industry under the goal of carbon neutrality.The sustainable development of carbon industry needs to learn from the experiences of global oil and gas industry development.There are three types of“carbon”in the earth system.Black carbon is the CO_(2) that has not been sequestered or used and remains in the atmosphere for a long time;grey carbon is the CO_(2) that has been fixed or permanently sequestered in the geological body,and blue carbon is the CO_(2) that could be converted into products for human use through biological,physical,chemical and other ways.The carbon industry system covers carbon generation,carbon capture,carbon transportation,carbon utilization,carbon sequestration,carbon products,carbon finance,and other businesses.It is a revolutionary industrial field to completely eliminate“black carbon”.The development of carbon industry technical system takes carbon emission reduction,zero carbon,negative carbon and carbon economy as the connotation,and the construction of a low-cost and energy-efficient carbon industry system based on CCUS/CCS are strategic measures to achieve the goal of carbon neutrality and clean energy utilization globally.This will promote the“four 80%s”transformation of China's energy supply,namely,to 2060,the percentage of zero-carbon new energy in the energy consumption will be over 80%and the CO_(2) emission will be decreased by 80%to ensure the carbon emission reduction of total 80×10^(8) t from the percentage of carbon-based fossil energy in the energy consumption of over 80%,and the percentage of CO_(2) emission from energy of over 80%in 2021.The carbon industry in China is facing three challenges,large CO_(2) emissions,high percentage of coal in energy consumption,and poor innovative system.Three strategic measures are proposed accordingly,including:(1)unswervingly develop carbon industrial system and ensure the achievement of carbon neutrality as scheduled by 2060;(2)vigorously develop new energy sources and promote a revolutionary transformation of China’s energy production and consumption structure;(3)accelerate the establishment of scientific and technological innovation system of the whole CO_(2) industry.It is of great significance for continuously optimization of ecological environment and construction of green earth and ecological earth to develop the carbon industry system,utilize clean energy,and achieve the strategic goal of global carbon neutrality.
文摘With the in-depth advancement of China’s dual carbon goals,the national carbon emissions trading market has become a core policy tool for achieving emission reduction targets.However,the current carbon market remains predominantly spot-based,facing challenges such as limited financial products,restricted market participants,immature carbon pricing mechanisms,and insufficient liquidity,which constrain its resource allocation and risk management functions.Based on the spirit of the“Opinions on Promoting Green Low-Carbon Transformation and Strengthening National Carbon Market Construction”issued by the General Office of the CPC Central Committee and the General Office of the State Council,this paper focuses on the challenges faced during the implementation of the dual control system for carbon emissions in the“Fifteenth Five-Year Plan”period,with emphasis on analyzing the development bottlenecks of the carbon market.It proposes accelerating the launch of carbon futures,carbon options and other derivatives,expanding the scope of financial institution participation,improving carbon market infrastructure,and establishing a cross-departmental coordinated policy framework.By drawing on international experience and combining domestic pilot practices,this aims to provide an operational and implementable pathway for the development of China’s carbon market,further enhancing the supporting role of the carbon market in green low-carbon transformation.
文摘As the national carbon emission trading system extends to high energy-consuming industries,the petroleum exploration&development and refining&chemical engineering sectors face the dual challenges of rigid carbon constraints and energy structure restructuring.This study innovatively proposes the“dual inflection point theory”,which reveals that the transformation window requires the industry to overcome composite pressures including regional energy imbalances,international carbon tariff barriers,and technological substitution bottlenecks.This paper constructs a five-in-one governance framework encompassing“policy coordination,market circulation,intelligent regulation,energy substitution,energy efficiency innovation”.
基金funded by the National Natural Science Foundation of China Project(Grants No.42494823 and 42301108)the Young Elite Scientists Sponsorship Program by CAST(Grant No.07M715BOAM)L.W.considers this work a contribution to his Carlsberg Foundation Internationalisation Fellowship project(Grant No.CF21–0157).
文摘Soil erosion is a critical process influencing the global carbon cycle.However,erosion-induced carbon changes remain inadequately understood,particularly for soil inorganic carbon(SIC).There is also limited knowledge about the factors influencing soil carbon dynamics during erosion processes.Here we quantify the global translocation of soil organic carbon(SOC)and SIC due to soil erosion using data-driven global soil carbon estimates combined with a soil erosion map derived from the Revised Universal Soil Loss Equation(RUSLE)model.Our analysis reveals that global SIC and SOC translocations from soil erosion are 107.1 Tg C yr^(−1)and 898.4 Tg C yr^(−1),respectively.These translocations exhibit distinct patterns across aridity gradients and different biomes and soil types,with SIC translocation increasing while SOC translocation decreasing with aridity.Croplands exhibit significantly higher soil carbon translocation compared to natural vegetation,with SIC translocation being 2.41 times higher and SOC translocation 0.65 times higher than in forests.Topographic features(slope length and steepness)predominantly determine soil carbon translocation during erosion,with steeper and longer slopes exacerbating erosion and subsequent SIC/SOC translocation.Land use change,particularly agricultural practices,is also a critical driver.Our findings provide valuable insights into the factors influencing SIC and SOC translocation,enhancing our understanding of the global patterns and determinants of erosion-induced soil carbon dynamics.
基金This study was supported by the project ofthe Science and Technology Innovation Fund of Command Center of Natural Resources Intergrated Survey entitled“Temporal and spatial distribution of paleochannel and origin of organic carbon burial in the Western Bohai Sea since 2.28Ma”(KC20220011)the project entitled“Characterization of Carboniferous-Early Permian heterogeneous porous carbonate reservoirs and hydrocarbon potential analysis in the central uplift of the South Yellow Sea Basin”(KLSG2304)+3 种基金by the Key laboratory of Submarine Science,Ministry of Natural Resources,the project entitled“1∶50000 Marine regional Geological survey in Caofeidian Sea Area,Bohai Sea”(ZD20220602)“1∶250000 Marine regional Geological survey in Weihai Sea Area,North Yellow Sea”(DD20230412)“Geological survey on tectonic and sedimentary conditions of Laoshan uplift”(DD2016015)by the China Geological Survey,and the project entitled“Study on Hydrocarbon Accumulation Failure and Fluid Evolution Reduction of the Permian Reservoir in the Laoshan Uplift,South Yellow Sea”(42076220)organized by the National Natural Science Foundation of China.
文摘Mesozoic-Palaeozoic marine carbonate rocks are crucial hydrocarbon reservoirs in the Central Uplift area of the South Yellow Sea Basin(SYSB).Due to the scarcity of boreholes and the significant heterogeneity of carbonate reservoirs,the distribution of porous carbonate reservoirs and their related key controlling factors remain unclear.In this study,factors affecting the distribution of porous Carboniferous-Early Permian carbonate reservoirs in the SYSB were investigated through seismic inversion and isotope analysis.The log-seismic characteristics of porous carbonate reservoirs,sensitive lithology parameters,and physical property parameters were extracted and analyzed.The pre-stack simultaneous inversion technique was applied to predict the lithology and physical properties of porous carbonate reservoirs.Moreover,the sedimentary of carbonate was analyzed using isotopes of carbon,oxygen,and strontium.The results show that porous carbonate reservoirs are mainly developed in the open platform sediments with porosities of 3%-5%and are mainly distributed in the paleo-highland(Huanglong Formation and Chuanshan Formation)and the slope of paleo-highland(Hezhou Formation).The porous carbonate reservoirs of the Qixia Formation are only locally developed.In addition,the negativeδ13C excursions indicate a warm and humid tropical climate with three sea-level fluctuations in the study area from the Carboniferous to Early Permian.The favorable conditions for developing porous carbonate rocks include the sedimentary environment and diagenetic process.The primary pore tends to form in high-energy environments of the paleo-highland,and the secondary pore is increased by dissolution during the syngenetic or quasi-syngenetic period.According to the hydrocarbon potential analysis,the Late Ordovician Wufeng Formation and Lower Silurian Gaojiabian Formation are the source rocks in the high-maturity-over-maturity stage,the Carboniferous-Lower Permian carbonate is the good reservoirs,and the Late Permian Longtan-Dalong Formation is the stable seal,ensuring a huge hydrocarbon accumulation potential in SYSB.The methods proposed in this study can be applied to other carbonate-dominated strata worldwide.
