China Standardization:Can you please briefly introduce ISO,its international standards as well as your scope of work?Rachel Miller Prada:ISO is an independent non-governmental organization dedicated to developing inte...China Standardization:Can you please briefly introduce ISO,its international standards as well as your scope of work?Rachel Miller Prada:ISO is an independent non-governmental organization dedicated to developing international standards.Currently,ISO has 175 member bodies,representing 175 countries that participate in its standard development work.We have a portfolio of over 24,000 international standards,with around 100 new standards issued or existing ones revised every month.The ultimate goal of our standardization work is to support the achievement of the United Nations Sustainable Development Goals(SDGs).Every standard we develop and every task I undertake in my role contributes to these global objectives.展开更多
To achieve the goals of sustainable development of the energy system and the construction of a lowcarbon society,this study proposes a multi-energy storage collaborative optimization strategy for industrial park that ...To achieve the goals of sustainable development of the energy system and the construction of a lowcarbon society,this study proposes a multi-energy storage collaborative optimization strategy for industrial park that integrates the laddered carbon trading mechanism with demand response.Firstly,a dual dimensional DR model is constructed based on the characteristics of load elasticity.The alternativeDRenables flexible substitution of energy loads through complementary conversion of electricity/heat/cold multi-energy sources,while the price DR relies on timeof-use electricity price signals to guide load spatiotemporal migration;Secondly,the LCT mechanism is introduced to achieve optimal carbon emission costs through a tiered carbon quota allocation mechanism.On this basis,an optimization decision model is established with the core objective of maximizing the annual net profit of the park.The objective function takes into account energy sales revenue,generator unit costs,and investment and operation costs of multiple types of energy storage facilities.Themodel constraint system covers three key dimensions:dynamic operation constraints of power generation units,including unit output limits,ramping capability,and minimum start-stop time;the physical boundary of an electric/hot/cold multi-energy storage system involves energy storage capacity and charge/discharge efficiency;The multi-energy network coupling balance equation ensures that the energy conversion and transmission process satisfies the law of conservation of energy.Using CPLEX mathematical programming solver for simulation verification,construct an energy storage capacity configuration decision process that includes LCT-DR synergistic effect.The research results show that compared with the traditional single energy storage configuration mode,this strategy effectively enhances the economic feasibility and engineering practicality of industrial park operation by coordinating demand side resource scheduling and finely controlling carbon costs,while maintaining stable system operation.Its methodological framework provides a technical path that combines theoretical rigor and practical operability for the low-carbon transformation of regional integrated energy systems.展开更多
THE mechanical response and deformation mechanisms of pure nickel under nanoindentation were systematically investigated using molecular dynamics(MD)simulations,with a particular focus on the novel interplay between c...THE mechanical response and deformation mechanisms of pure nickel under nanoindentation were systematically investigated using molecular dynamics(MD)simulations,with a particular focus on the novel interplay between crystallographic orientation,grain boundary(GB)proximity,and pore characteristics(size/location).This study compares single-crystal nickel models along[100],[110],and[111]orientations with equiaxed polycrystalline models containing 0,1,and 2.5 nm pores in surface and subsurface configurations.Our results reveal that crystallographic anisotropy manifests as a 24.4%higher elastic modulus and 22.2%greater hardness in[111]-oriented single crystals compared to[100].Pore-GB synergistic effects are found to dominate the deformation behavior:2.5 nm subsurface pores reduce hardness by 25.2%through stress concentration and dislocation annihilation at GBs,whereas surface pores enable mechanical recovery via accelerated dislocation generation post-collapse.Additionally,size-dependent deformation regimes were identified,with 1 nm pores inducing negligible perturbation due to rapid atomic rearrangement,in contrast with persistent softening in 2.5 nm pores.These findings establish atomic-scale design principles for defect engineering in nickel-based aerospace components,demonstrating how crystallographic orientation,pore configuration,and GB interactions collectively govern nanoindentation behavior.展开更多
Micro-sized anatase TiO_(2) displays inferior capacity as cathode material for magnesium ion batteries because of the higher diffusion energy barrier of Mg^(2+)in anatase TiO_(2) lattice.Herein,we report that nanosize...Micro-sized anatase TiO_(2) displays inferior capacity as cathode material for magnesium ion batteries because of the higher diffusion energy barrier of Mg^(2+)in anatase TiO_(2) lattice.Herein,we report that nanosized anatase TiO_(2) exposed(001)facet doubles the capacity compared to the micro-sized sample ascribed to the interfacial Mg^(2+)ion storage.First-principles calculations reveal that the diffusion energy barrier of Mg^(2+)on the(001)facet is significantly lower than those in the bulk phase and on(100)facet,and the adsorption energy of Mg^(2+)on the(001)facet is also considerably lower than that on(100)facet,which guarantees superior interfacial Mg^(2+)storage of(001)facet.Moreover,anatase TiO_(2) exposed(001)facet displays a significantly higher capacity of 312.9 mAh g^(−1) in Mg-Li dual-salt electrolyte compared to 234.3 mAh g^(−1) in Li salt electrolyte.The adsorption energies of Mg^(2+)on(001)facet are much lower than the adsorption energies of Li+on(001)facet,implying that the Mg^(2+)ion interfacial storage is more favorable.These results highlight that controlling the crystal facet of the nanocrystals effectively enhances the interfacial storage of multivalent ions.This work offers valuable guidance for the rational design of high-capacity storage systems.展开更多
Photo-assisted lithium–sulfur batteries(PALSBs)offer an eco-friendly solution to address the issue of sluggish reaction kinetics of conventional LSBs.However,designing an efficient photoelectrode for practical implem...Photo-assisted lithium–sulfur batteries(PALSBs)offer an eco-friendly solution to address the issue of sluggish reaction kinetics of conventional LSBs.However,designing an efficient photoelectrode for practical implementation remains a significant challenge.Herein,we construct a free-standing polymer–inorganic hybrid photoelectrode with a direct Z-scheme heterostructure to develop high-efficiency PALSBs.Specifically,polypyrrole(PPy)is in situ vapor-phase polymerized on the surface of N-doped TiO_(2) nanorods supported on carbon cloth(N-TiO_(2)/CC),thereby forming a well-defined p–n heterojunction.This architecture efficiently facilitates the carrier separation of photo-generated electron–hole pairs and significantly enhances carrier transport by creating a built-in electric field.Thus,the PPy@N-TiO_(2)/CC can simultaneously act as a photocatalyst and an electrocatalyst to accelerate the reduction and evolution of sulfur,enabling ultrafast sulfur redox dynamics,as convincingly validated by both theoretical simulations and experimental results.Consequently,the PPy@N-TiO_(2)/CC PALSB achieves a high discharge capacity of 1653 mAh g−1,reaching 98.7%of the theoretical value.Furthermore,5 h of photo-charging without external voltage enables the PALSB to deliver a discharge capacity of 333 mAh g−1,achieving dual-mode energy harvesting capabilities.This work successfully integrates solar energy conversion and storage within a rechargeable battery system,providing a promising strategy for sustainable energy storage technologies.展开更多
As global efforts to combat climate change intensify,offshore wind farms have emerged as scalable and sustainable solutions.However,their deployment depends heavily on the availability of specialized vessels with Dyna...As global efforts to combat climate change intensify,offshore wind farms have emerged as scalable and sustainable solutions.However,their deployment depends heavily on the availability of specialized vessels with Dynamic Positioning(DP)systems such as Wind Turbine Installation Vessels(WTIVs)and Service Operation Vessels(SOVs).Despite their importance,long-term demand forecasting for such vessels remains underexplored,especially in South Korea.This study presents the dDP-W model,a System Dynamics(SD)-based framework that simulates the evolving demand for DP vessels under varying technological,policy,and environmental conditions.Unlike conventional methods based on historical extrapolation,the model uses feedback-driven causality and scenario-based simulations aligned with South Korea’s offshore wind roadmap(2026-2036).Three WTIV demand scenarios—baseline,optimistic,and pessimistic—were constructed based on vessel productivity and weather-related downtime.SOV demand was estimated using cumulative turbine counts and fixed vessel coverage ratios.The simulations indicate that WTIV demand peaks in the early 2030s,requiring 6 to 7 vessels depending on conditions,while SOV demand increases steadily,reaching nearly 70 vessels by 2036.These findings highlight the need for early vessel procurement,infrastructure investment,and workforce preparation.By integrating technical,logistical,and policy factors into a dynamic model,this study provides a practical decision-support tool for stakeholders in shipbuilding and offshore energy.The results offer strategic insights to address potential vessel shortages and ensure alignment with national renewable energy goals.展开更多
The cyclic injection and production of fluids into and from underground gas storage(UGS)may lead to caprock failure,such as capillary sealing failure,hydraulic fracturing,shear failure,and fault slipping or dilation.T...The cyclic injection and production of fluids into and from underground gas storage(UGS)may lead to caprock failure,such as capillary sealing failure,hydraulic fracturing,shear failure,and fault slipping or dilation.The dynamic sealing capacity of a caprock-fault system is a critical constraint for safe operation,and is a key factor in determining the maximum operating pressure(MOP).This study proposed an efficient semi-analytical method for calculating changes in the in situ stress within the caprock.Next,the parameters of dynamic pore pressure,in situ stresses,and deformations obtained from reservoir simulations and geomechanical modeling were used for inputs for the analytical solution.Based on the calculated results,an experimental scheme for the coupled cyclic stress-permeability testing of caprock was designed.The stability analysis indicated that the caprock was not prone to fatigue shear failure under the current injection and production strategy,supported by the experimental results.The experimental results further reveal that the sealing capacity of caprock plugs may remain stable.This phenomenon is attributed to cyclic stress causing pore connectivity and microcrack initiation in certain plugs,while leading to pore compaction in others.A comparison between the dynamic pore pressure and the minimum principal stress suggests that the risk of tensile failure is extremely low.Furthermore,although the faults remain stable under the current injection and production strategies,the continuous increase in injection pressure may lead to an increased tendency for fault slip and dilation,which can cause fault slip ultimately.The MOPs corresponding to each failure mode were calculated.The minimum value of approximately 36.5 MPa at capillary sealing failure indicated that the gas breakthrough in the caprock occurred earlier than rock failure.Therefore,this minimumvalue can be used as the MOP for the target UGS.展开更多
A model of Suzhou water resources carrying capacity （WRCC） was set up using the method of system dynamics （SD）. In the model, three different water resources utilization programs were adopted： （1） continuity of...A model of Suzhou water resources carrying capacity （WRCC） was set up using the method of system dynamics （SD）. In the model, three different water resources utilization programs were adopted： （1） continuity of existing water utilization, （2） water conservation/saving, and （3） water exploitation. The dynamic variation of the Suzhou WRCC was simulated with the supply-decided principle for the time period of 2001 to 2030, and the results were characterized based on socio-economic factors. The corresponding Suzhou WRCC values for several target years were calculated by the model. Based on these results, proper ways to improve the Suzhou WRCC are proposed. The model also produced an optimized plan, which can provide a scientific basis for the sustainable utilization of Suzhou water resources and for the coordinated development of the society, economy, and water resources.展开更多
When estimating the capacity of lithium-ion batteries offline or online,it is essential to extract a health feature(HF)that can effectively characterize capacity degradation under both conventional ideal and complex d...When estimating the capacity of lithium-ion batteries offline or online,it is essential to extract a health feature(HF)that can effectively characterize capacity degradation under both conventional ideal and complex dynamic operating conditions.However,the extraction of most HFs relies on complete charge-discharge cycle data,making them less adaptable to complex dynamic operating conditions.Existing mechanism HFs,while capable of characterizing capacity degradation from a mechanism perspective,suffer from limitations such as insufficient physical model expressiveness,high dimension,and redundancy of the mechanism HF.These issues increase the complexity of subsequent modeling of the relationship between HFs and capacity,thereby restricting their promotion in engineering practice.To meet this gap,this paper proposes a novel mechanism-based HF.Firstly,a multi-physical fields coupling model is developed to describe the interactions between electrochemical,thermal,and aging behaviors of the battery.Secondly,based on the aging mechanism,the accumulated charge of lithium lost during the formation of the solid electrolyte interphase(SEI)film is extracted as HF to provide a more intuitive representation of capacity degradation.Then,to reduce estimation errors caused by considering only a single aging mechanism,multiple representative regression models are employed to establish the mapping relationship between the mechanism HF and capacity,further enhancing the accuracy of final results.Finally,the proposed method is implemented and validated using real battery data under three different types of operating conditions.Experimental results demonstrate that,compared to other commonly used HFs,the proposed HF exhibits significant competitive advantages in handling incomplete cycle data,unknown operating conditions,and capacity estimation models.The minimum estimation error under ideal conditions is 0.0074,and the minimum estimation error under complex dynamic conditions is 0.0268.展开更多
Compared to the well-studied two-dimensional(2D)ferroelectricity,the appearance of 2D antiferroelectricity is much rarer,where local dipoles from the nonequivalent sublattices within 2D monolayers are oppositely orien...Compared to the well-studied two-dimensional(2D)ferroelectricity,the appearance of 2D antiferroelectricity is much rarer,where local dipoles from the nonequivalent sublattices within 2D monolayers are oppositely oriented.Using NbOCl_(2) monolayer with competing ferroelectric(FE)and antiferroelectric(AFE)phases as a 2D material platform,we demonstrate the emergence of intrinsic antiferroelectricity in NbOCl_(2) monolayer under experimentally accessible shear strain,along with new functionality associated with electric field-induced AFE-to-FE phase transition.Specifically,the complex configuration space accommodating FE and AFE phases,polarization switching kinetics,and finite temperature thermodynamic properties of 2D NbOCl_(2) are all accurately predicted by large-scale molecular dynamics simulations based on deep learning interatomic potential model.Moreover,room temperature stable antiferroelectricity with low polarization switching barrier and one-dimensional collinear polarization arrangement is predicted in shear-deformed NbOCl_(2) monolayer.The transition from AFE to FE phase in 2D NbOCl_(2) can be triggered by a low critical electric field,leading to a double polarization–electric(P–E)loop with small hysteresis.A new type of optoelectronic device composed of AFE-NbOCl_(2) is proposed,enabling electric“writing”and nonlinear optical“reading”logical operation with fast operation speed and low power consumption.展开更多
Mitochondrial dysfunction has emerged as a critical factor in the etiology of various neurodevelopmental disorders, including autism spectrum disorders, attention-deficit/hyperactivity disorder, and Rett syndrome. Alt...Mitochondrial dysfunction has emerged as a critical factor in the etiology of various neurodevelopmental disorders, including autism spectrum disorders, attention-deficit/hyperactivity disorder, and Rett syndrome. Although these conditions differ in clinical presentation, they share fundamental pathological features that may stem from abnormal mitochondrial dynamics and impaired autophagic clearance, which contribute to redox imbalance and oxidative stress in neurons. This review aimed to elucidate the relationship between mitochondrial dynamics dysfunction and neurodevelopmental disorders. Mitochondria are highly dynamic organelles that undergo continuous fusion and fission to meet the substantial energy demands of neural cells. Dysregulation of these processes, as observed in certain neurodevelopmental disorders, causes accumulation of damaged mitochondria, exacerbating oxidative damage and impairing neuronal function. The phosphatase and tensin homolog-induced putative kinase 1/E3 ubiquitin-protein ligase pathway is crucial for mitophagy, the process of selectively removing malfunctioning mitochondria. Mutations in genes encoding mitochondrial fusion proteins have been identified in autism spectrum disorders, linking disruptions in the fusion-fission equilibrium to neurodevelopmental impairments. Additionally, animal models of Rett syndrome have shown pronounced defects in mitophagy, reinforcing the notion that mitochondrial quality control is indispensable for neuronal health. Clinical studies have highlighted the importance of mitochondrial disturbances in neurodevelopmental disorders. In autism spectrum disorders, elevated oxidative stress markers and mitochondrial DNA deletions indicate compromised mitochondrial function. Attention-deficit/hyperactivity disorder has also been associated with cognitive deficits linked to mitochondrial dysfunction and oxidative stress. Moreover, induced pluripotent stem cell models derived from patients with Rett syndrome have shown impaired mitochondrial dynamics and heightened vulnerability to oxidative injury, suggesting the role of defective mitochondrial homeostasis in these disorders. From a translational standpoint, multiple therapeutic approaches targeting mitochondrial pathways show promise. Interventions aimed at preserving normal fusion-fission cycles or enhancing mitophagy can reduce oxidative damage by limiting the accumulation of defective mitochondria. Pharmacological modulation of mitochondrial permeability and upregulation of peroxisome proliferator-activated receptor gamma coactivator 1-alpha, an essential regulator of mitochondrial biogenesis, may also ameliorate cellular energy deficits. Identifying early biomarkers of mitochondrial impairment is crucial for precision medicine, since it can help clinicians tailor interventions to individual patient profiles and improve prognoses. Furthermore, integrating mitochondria-focused strategies with established therapies, such as antioxidants or behavioral interventions, may enhance treatment efficacy and yield better clinical outcomes. Leveraging these pathways could open avenues for regenerative strategies, given the influence of mitochondria on neuronal repair and plasticity. In conclusion, this review indicates mitochondrial homeostasis as a unifying therapeutic axis within neurodevelopmental pathophysiology. Disruptions in mitochondrial dynamics and autophagic clearance converge on oxidative stress, and researchers should prioritize validating these interventions in clinical settings to advance precision medicine and enhance outcomes for individuals affected by neurodevelopmental disorders.展开更多
The absorption of CO_(2)is of importance in carbon capture,utilization,and storage technology for greenhouse gas control.In the present work,we clarified the mechanism of how metal-based ionic liquids (MBILs),Bmim[XCl...The absorption of CO_(2)is of importance in carbon capture,utilization,and storage technology for greenhouse gas control.In the present work,we clarified the mechanism of how metal-based ionic liquids (MBILs),Bmim[XCl_(n)]_(m)(X is the metal atom),enhance the CO_(2)absorption capacity of ILs via performing molecular dynamics simulations.The sparse hydrogen bond interaction network constructed by CO_(2)and MBILs was identified through the radial distribution function and interaction energy of CO_(2)-ion pairs,which increase the absorption capacity of CO_(2)in MBILs.Then,the dynamical properties including residence time and self-diffusion coefficient confirmed that MBILs could also promote the diffusion process of CO_(2)in ILs.That's to say,the MBILs can enhance the CO_(2)absorption capacity and the diffusive ability simultaneously.Based on the analysis of structural,energetic and dynamical properties,the CO_(2)absorption capacity of MBILs increases in the order Cl^-→[ZnCl_(4)]^(2-)→[CuCl_(4)]^(2-)→[CrCl_(4)]^-→[FeCl_(4)]^-,revealing the fact that the short metal–Cl bond length and small anion volume could facilitate the performance of CO_(2)absorbing process.These findings show that the metal–Cl bond length and effective volume of the anion can be the effective factors to regulate the CO_(2)absorption process,which can also shed light on the rational molecular design of MBILs for CO_(2)capture and other key chemical engineering processes,such as IL-based gas sensors,nano-electrical devices and so on.展开更多
The cultivated land-water resources carrying capacity （CL-WRCC） with the method of system dynamics （SD） were analyzed. Bijie prefecture of Guizhou province served as a case in this study. Bijie prefecture is one o...The cultivated land-water resources carrying capacity （CL-WRCC） with the method of system dynamics （SD） were analyzed. Bijie prefecture of Guizhou province served as a case in this study. Bijie prefecture is one of the least-developed areas in China. In Bijie, the physical and chemical characteristics of karst as well as the rapid economic development lead to the scarcities of cultivated land-water resources （CL-WR）. On the basis of analysis on the subsystems of Bijie CL.WRCC system, the fundamental feedback structure of CL-WRCC was presented by causal loop diagram. Considering the three alms （＂ poverty alleviation and development, ecological construction, and population control＂） of Bijie as the major goals, Bijie CL-WRCC SD model was developed. Three scenarios, resource-saving and environment-friendly development-oriented scenario （Scenario 1 ）, fast economic development-oriented scenario （ Scenario 2 ）, and coordinated development-oriented scenario （Scenario 3 ）, were investigated. Simulation results indicate that Scenario 3 which takes social economic development, environment protection, and cultivated land- water resources utilization into account, is the best alternative scenario. It can promote the coordination development of society, economy, cultivated land, water resources, and environment. In this study, the technological support and the decision-making for the rational use of CL-WR are provided not only in Bijie, but also in other similar regions of China.展开更多
Low performance of operational practices and wrong perceptions on demand forecast cause improper investments on new facilities for containers terminals, without taking into account the best use of their available reso...Low performance of operational practices and wrong perceptions on demand forecast cause improper investments on new facilities for containers terminals, without taking into account the best use of their available resources. Accordingly, it would be desirable to model dynamic behaviour among demand, capacity and productivity of container terminal services, like reception, storage and distribution, to forecast their performances faced to demand evolution with time. This paper presents a system dynamic model to evaluate impacts from demand variations on 18 container terminals associated to ABRATEC （Associa^do Brasileira dos Terminals de Cont^ineres de Uso P^blico （in English： Brazilian Association of Public Container Terminals）） and their response capability to compensate demand growth with increasing productivity. The behaviour of the developed dynamic models was demonstrated by means of simulations carried out with the Vensim Standard 5.6d system dynamics software.展开更多
Chengdu City is in the period of rapid urbanization and industrialization, and the disturbance derived from human activities on environment is increasing remarkablely in recent 20 years. The pressure on environment, e...Chengdu City is in the period of rapid urbanization and industrialization, and the disturbance derived from human activities on environment is increasing remarkablely in recent 20 years. The pressure on environment, economy and population is also increasing and land use in Chengdu has changed enormously. As struc- ture and function of land ecological system change obviously, sustainable development of land productivity has been an important goal and strategic task from now on, and it is necessary to systematically research land ecological carrying capacity based on ecological footprint. The ecological footprint of Chengdu City in the past ten years was calculated and analyzed from the spatial and temporal aspects according to statistical data from 1998 to 2008, as per ecological footprint method, ecological carrying capacity and the GIS spatial analysis method, and regression analysis method. The ecological footprint and ecological carrying capacity values from 2009 to 2019 in Chengdu City were predicted through calculation results in the past ten years. The results show that the ecological footprint and ecological deficit of land use from 1998 to 2008 increased in Chengdu City. The ecological deficit of land use within the city center was in high levels in the past ten years, and the ecological footprint kept raising, especially in areas, such as Shuangliu, Chongzhou, Qingyang among 9 city areas, 4 counties and 6 districts in Chengdu City. There is fanlike distribution of ecological deficit of land use. Analysis shows that the social and natural ecological system is uneven distribution, which is not in sustainable de- velopment situation. The results of the study show that the economic, social and natural ecological system in Chengdu City is not sustainable, and the ecological foot- print is uneven distribution. The analysis of the dynamic change of land ecological carrying capacity in Chengdu City is very important for city government in the pro- cess of the vigorous development in new Tianfu Xinqu, and redevelopment in the northern part of this city.展开更多
The existing researches of stepless capacity regulation system by depressing the suction valve for reciprocation compressor always adopt hypothesis that the compressor valves are open or close instantaneously,the valv...The existing researches of stepless capacity regulation system by depressing the suction valve for reciprocation compressor always adopt hypothesis that the compressor valves are open or close instantaneously,the valve dynamic has not been taken account into thermal cycle computation,the influence of capacity regulation system on suction valves dynamic performance and cylinder thermal cycle operation has not been considered.This paper focuses on theoretical and experimental analysis of the valve dynamic and thermal cycle for reciprocating compressor in the situation of stepless capacity regulation.The valve dynamics equation,gas forces for normal and back flow,and the cylinder pressure varying with suction valve unloader moment during compression thermal cycle are discussed.A new valve dynamic model based on L-K real gas state equation for reciprocating compressor is first deduced to reduce the calculation errors induced by the ideal gas state equation.The variations of valve dynamic and cylinder pressure during part of compression stroke are calculated numerically.The calculation results reveal the non-normal thermal cycle and operation condition of compressor in stepless capacity regulation situation.The numerical simulation results of the valve dynamic and thermal cycle parameters are also verified by the stepless capacity regulation experiments in the type of 3L-10/8 reciprocating compressor.The experimental results agree with the numerical simulation results,which show that the theoretical models proposed are effective and high-precision.The proposed theoretical models build the theoretical foundation to design the real stepless capacity regulation system.展开更多
Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longe...Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.展开更多
Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships w...Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships with antioxidant activity and oxidative stability,gas chromatography-mass spectrometry was performed to characterize the associated fatty acid profiles.The antioxidant activity of vegetable oils,based on their DPPH-scavenging capacity(expressed as IC_(50) values),was used to assess their impact on human health,and their oxidative stability was characterized by performing lipid oxidation analysis to determine the oxidative induction time of fats and oils.In addition,correlation analyses were performed to examine associations between the fatty acid composition of the oils and DPPH-scavenging capacity and oxidative stability.The results revealed that among the assessed oils,coffee seed oil has the highest saturated fatty acid content(355.10 mg/g),whereas Garddenia jaminoides oil has the highest unsaturated fatty acid content(844.84 mg/g).Coffee seed oil was also found have the lowest DPPH IC_(50) value(2.30 mg/mL)and the longest oxidation induction time(17.09 h).Correlation analysis revealed a significant linear relationship(P<0.05)between oxidative stability and unsaturated fatty acid content,with lower contents tending to be associated with better oxidative stability.The findings of this study provide reference data for the screening of functional edible vegetable oils.展开更多
This paper presents a simplified dynamic method based on the definition of field capacity. Two soil hydraulic characteristics models, the Brooks-Corey （BC） model and the van Genuchten （vG） model, and four soil dat...This paper presents a simplified dynamic method based on the definition of field capacity. Two soil hydraulic characteristics models, the Brooks-Corey （BC） model and the van Genuchten （vG） model, and four soil data groups were used in this study. The relative drainage rate, which is a unique parameter and independent of the soil type in the simplified dynamic method, was analyzed using the pressure-based method with a matric potential of -1/3 bar and the flux-based method with a drainage flux of 0.005 cm/d. As a result, the relative drainage rate of the simplified dynamic method was determined to be 3% per day. This was verified by the similar field capacity results estimated with the three methods for most soils suitable for cultivating plants. In addition, the drainage time calculated with the simplified dynamic method was two to three days, which agrees with the classical definition of field capacity. We recommend the simplified dynamic method with a relative drainage rate of 3% per day due to its simple application and clearly physically-based concept.展开更多
Spiral pile foundations,as a promising type of foundation,are of significant importance for the development of offshore wind energy,particularly as it moves toward deeper waters.This study conducted a physical experim...Spiral pile foundations,as a promising type of foundation,are of significant importance for the development of offshore wind energy,particularly as it moves toward deeper waters.This study conducted a physical experiment on a three-spiral-pile jacket foundation under deep-buried sandy soil conditions.During the experiment,horizontal displacement was applied to the structure to thoroughly investigate the bearing characteristics of the three-spiral-pile jacket foundation.This study also focused on analyzing the bearing mechanisms of conventional piles compared with spiral piles with different numbers of blades.Three different working conditions were set up and compared,and key data,such as the horizontal bearing capacity,pile shaft axial force,and spiral blade soil pressure,were measured and analyzed.The results show the distinct impacts of the spiral blades on the compressed and tensioned sides of the foundation.Specifically,on the compressed side,the spiral blades effectively enhance the restraint of the soil on the pile foundation,whereas on the tensioned side,an excessive number of spiral blades can negatively affect the structural tensile performance to some extent.This study also emphasizes that the addition of blades to the side of a single pile is the most effective method for increasing the bearing capacity of the foundation.This research aims to provide design insights into improving the bearing capacity of the foundation.展开更多
文摘China Standardization:Can you please briefly introduce ISO,its international standards as well as your scope of work?Rachel Miller Prada:ISO is an independent non-governmental organization dedicated to developing international standards.Currently,ISO has 175 member bodies,representing 175 countries that participate in its standard development work.We have a portfolio of over 24,000 international standards,with around 100 new standards issued or existing ones revised every month.The ultimate goal of our standardization work is to support the achievement of the United Nations Sustainable Development Goals(SDGs).Every standard we develop and every task I undertake in my role contributes to these global objectives.
基金funded by Science and Technology Projects from State Grid Corporation of China,(Research on Adaptive Balance Optimization and Simulation Technology of Industrial community Energy System with High Proportion of Distributed Energy,No.:5100-202355752A-3-4-SY).
文摘To achieve the goals of sustainable development of the energy system and the construction of a lowcarbon society,this study proposes a multi-energy storage collaborative optimization strategy for industrial park that integrates the laddered carbon trading mechanism with demand response.Firstly,a dual dimensional DR model is constructed based on the characteristics of load elasticity.The alternativeDRenables flexible substitution of energy loads through complementary conversion of electricity/heat/cold multi-energy sources,while the price DR relies on timeof-use electricity price signals to guide load spatiotemporal migration;Secondly,the LCT mechanism is introduced to achieve optimal carbon emission costs through a tiered carbon quota allocation mechanism.On this basis,an optimization decision model is established with the core objective of maximizing the annual net profit of the park.The objective function takes into account energy sales revenue,generator unit costs,and investment and operation costs of multiple types of energy storage facilities.Themodel constraint system covers three key dimensions:dynamic operation constraints of power generation units,including unit output limits,ramping capability,and minimum start-stop time;the physical boundary of an electric/hot/cold multi-energy storage system involves energy storage capacity and charge/discharge efficiency;The multi-energy network coupling balance equation ensures that the energy conversion and transmission process satisfies the law of conservation of energy.Using CPLEX mathematical programming solver for simulation verification,construct an energy storage capacity configuration decision process that includes LCT-DR synergistic effect.The research results show that compared with the traditional single energy storage configuration mode,this strategy effectively enhances the economic feasibility and engineering practicality of industrial park operation by coordinating demand side resource scheduling and finely controlling carbon costs,while maintaining stable system operation.Its methodological framework provides a technical path that combines theoretical rigor and practical operability for the low-carbon transformation of regional integrated energy systems.
基金The National Natural Science Foundation of China(Grant No.12462006)Beijing Institute of Structure and Environment Engineering Joint Innovation Fund(No.BQJJ202414).
文摘THE mechanical response and deformation mechanisms of pure nickel under nanoindentation were systematically investigated using molecular dynamics(MD)simulations,with a particular focus on the novel interplay between crystallographic orientation,grain boundary(GB)proximity,and pore characteristics(size/location).This study compares single-crystal nickel models along[100],[110],and[111]orientations with equiaxed polycrystalline models containing 0,1,and 2.5 nm pores in surface and subsurface configurations.Our results reveal that crystallographic anisotropy manifests as a 24.4%higher elastic modulus and 22.2%greater hardness in[111]-oriented single crystals compared to[100].Pore-GB synergistic effects are found to dominate the deformation behavior:2.5 nm subsurface pores reduce hardness by 25.2%through stress concentration and dislocation annihilation at GBs,whereas surface pores enable mechanical recovery via accelerated dislocation generation post-collapse.Additionally,size-dependent deformation regimes were identified,with 1 nm pores inducing negligible perturbation due to rapid atomic rearrangement,in contrast with persistent softening in 2.5 nm pores.These findings establish atomic-scale design principles for defect engineering in nickel-based aerospace components,demonstrating how crystallographic orientation,pore configuration,and GB interactions collectively govern nanoindentation behavior.
基金supported by the National Key R&D Program of China(No.2023YFB3809500)the Fundamental Research Funds for the Central Universities(No.2024CDJXY003)+1 种基金the Venture&Innovation Support Program for Chongqing Overseas Returnees(cx2023087)The Chongqing Technology Innovation and Application Development Project(No.2024TIAD-KPX0003).
文摘Micro-sized anatase TiO_(2) displays inferior capacity as cathode material for magnesium ion batteries because of the higher diffusion energy barrier of Mg^(2+)in anatase TiO_(2) lattice.Herein,we report that nanosized anatase TiO_(2) exposed(001)facet doubles the capacity compared to the micro-sized sample ascribed to the interfacial Mg^(2+)ion storage.First-principles calculations reveal that the diffusion energy barrier of Mg^(2+)on the(001)facet is significantly lower than those in the bulk phase and on(100)facet,and the adsorption energy of Mg^(2+)on the(001)facet is also considerably lower than that on(100)facet,which guarantees superior interfacial Mg^(2+)storage of(001)facet.Moreover,anatase TiO_(2) exposed(001)facet displays a significantly higher capacity of 312.9 mAh g^(−1) in Mg-Li dual-salt electrolyte compared to 234.3 mAh g^(−1) in Li salt electrolyte.The adsorption energies of Mg^(2+)on(001)facet are much lower than the adsorption energies of Li+on(001)facet,implying that the Mg^(2+)ion interfacial storage is more favorable.These results highlight that controlling the crystal facet of the nanocrystals effectively enhances the interfacial storage of multivalent ions.This work offers valuable guidance for the rational design of high-capacity storage systems.
基金financial support from the National Natural Science Foundation of China(22109127)the Chinese Postdoctoral Science Foundation(2021M702666),+1 种基金he Research Fund of the State Key Laboratory of Solidification Processing(NPU),China(Grant No.2023-TS-02)financial support from the Youth Project of"Shaanxi High-level Talents Introduction Plan"and the Key Laboratory of Advanced Energy Materials Chemistry(Ministry of Education)are also sincerely appreciated.
文摘Photo-assisted lithium–sulfur batteries(PALSBs)offer an eco-friendly solution to address the issue of sluggish reaction kinetics of conventional LSBs.However,designing an efficient photoelectrode for practical implementation remains a significant challenge.Herein,we construct a free-standing polymer–inorganic hybrid photoelectrode with a direct Z-scheme heterostructure to develop high-efficiency PALSBs.Specifically,polypyrrole(PPy)is in situ vapor-phase polymerized on the surface of N-doped TiO_(2) nanorods supported on carbon cloth(N-TiO_(2)/CC),thereby forming a well-defined p–n heterojunction.This architecture efficiently facilitates the carrier separation of photo-generated electron–hole pairs and significantly enhances carrier transport by creating a built-in electric field.Thus,the PPy@N-TiO_(2)/CC can simultaneously act as a photocatalyst and an electrocatalyst to accelerate the reduction and evolution of sulfur,enabling ultrafast sulfur redox dynamics,as convincingly validated by both theoretical simulations and experimental results.Consequently,the PPy@N-TiO_(2)/CC PALSB achieves a high discharge capacity of 1653 mAh g−1,reaching 98.7%of the theoretical value.Furthermore,5 h of photo-charging without external voltage enables the PALSB to deliver a discharge capacity of 333 mAh g−1,achieving dual-mode energy harvesting capabilities.This work successfully integrates solar energy conversion and storage within a rechargeable battery system,providing a promising strategy for sustainable energy storage technologies.
文摘As global efforts to combat climate change intensify,offshore wind farms have emerged as scalable and sustainable solutions.However,their deployment depends heavily on the availability of specialized vessels with Dynamic Positioning(DP)systems such as Wind Turbine Installation Vessels(WTIVs)and Service Operation Vessels(SOVs).Despite their importance,long-term demand forecasting for such vessels remains underexplored,especially in South Korea.This study presents the dDP-W model,a System Dynamics(SD)-based framework that simulates the evolving demand for DP vessels under varying technological,policy,and environmental conditions.Unlike conventional methods based on historical extrapolation,the model uses feedback-driven causality and scenario-based simulations aligned with South Korea’s offshore wind roadmap(2026-2036).Three WTIV demand scenarios—baseline,optimistic,and pessimistic—were constructed based on vessel productivity and weather-related downtime.SOV demand was estimated using cumulative turbine counts and fixed vessel coverage ratios.The simulations indicate that WTIV demand peaks in the early 2030s,requiring 6 to 7 vessels depending on conditions,while SOV demand increases steadily,reaching nearly 70 vessels by 2036.These findings highlight the need for early vessel procurement,infrastructure investment,and workforce preparation.By integrating technical,logistical,and policy factors into a dynamic model,this study provides a practical decision-support tool for stakeholders in shipbuilding and offshore energy.The results offer strategic insights to address potential vessel shortages and ensure alignment with national renewable energy goals.
基金supported by the National Natural Science Foundation of China(Grant No.42072166)Natural Science Foundation of Heilongjiang Province of China(Grant No.LH2020D004)Key R&D Program of Heilongjiang Province of China(Grant No.JD2023SJ26)。
文摘The cyclic injection and production of fluids into and from underground gas storage(UGS)may lead to caprock failure,such as capillary sealing failure,hydraulic fracturing,shear failure,and fault slipping or dilation.The dynamic sealing capacity of a caprock-fault system is a critical constraint for safe operation,and is a key factor in determining the maximum operating pressure(MOP).This study proposed an efficient semi-analytical method for calculating changes in the in situ stress within the caprock.Next,the parameters of dynamic pore pressure,in situ stresses,and deformations obtained from reservoir simulations and geomechanical modeling were used for inputs for the analytical solution.Based on the calculated results,an experimental scheme for the coupled cyclic stress-permeability testing of caprock was designed.The stability analysis indicated that the caprock was not prone to fatigue shear failure under the current injection and production strategy,supported by the experimental results.The experimental results further reveal that the sealing capacity of caprock plugs may remain stable.This phenomenon is attributed to cyclic stress causing pore connectivity and microcrack initiation in certain plugs,while leading to pore compaction in others.A comparison between the dynamic pore pressure and the minimum principal stress suggests that the risk of tensile failure is extremely low.Furthermore,although the faults remain stable under the current injection and production strategies,the continuous increase in injection pressure may lead to an increased tendency for fault slip and dilation,which can cause fault slip ultimately.The MOPs corresponding to each failure mode were calculated.The minimum value of approximately 36.5 MPa at capillary sealing failure indicated that the gas breakthrough in the caprock occurred earlier than rock failure.Therefore,this minimumvalue can be used as the MOP for the target UGS.
基金supported by the National Natural Science Foundation of China (Grant No.50638020)
文摘A model of Suzhou water resources carrying capacity （WRCC） was set up using the method of system dynamics （SD）. In the model, three different water resources utilization programs were adopted： （1） continuity of existing water utilization, （2） water conservation/saving, and （3） water exploitation. The dynamic variation of the Suzhou WRCC was simulated with the supply-decided principle for the time period of 2001 to 2030, and the results were characterized based on socio-economic factors. The corresponding Suzhou WRCC values for several target years were calculated by the model. Based on these results, proper ways to improve the Suzhou WRCC are proposed. The model also produced an optimized plan, which can provide a scientific basis for the sustainable utilization of Suzhou water resources and for the coordinated development of the society, economy, and water resources.
基金supported by the National Natural Science Foundation of China(NSFC,No.62303031)the Fundamental Research Funds for the Central Universities。
文摘When estimating the capacity of lithium-ion batteries offline or online,it is essential to extract a health feature(HF)that can effectively characterize capacity degradation under both conventional ideal and complex dynamic operating conditions.However,the extraction of most HFs relies on complete charge-discharge cycle data,making them less adaptable to complex dynamic operating conditions.Existing mechanism HFs,while capable of characterizing capacity degradation from a mechanism perspective,suffer from limitations such as insufficient physical model expressiveness,high dimension,and redundancy of the mechanism HF.These issues increase the complexity of subsequent modeling of the relationship between HFs and capacity,thereby restricting their promotion in engineering practice.To meet this gap,this paper proposes a novel mechanism-based HF.Firstly,a multi-physical fields coupling model is developed to describe the interactions between electrochemical,thermal,and aging behaviors of the battery.Secondly,based on the aging mechanism,the accumulated charge of lithium lost during the formation of the solid electrolyte interphase(SEI)film is extracted as HF to provide a more intuitive representation of capacity degradation.Then,to reduce estimation errors caused by considering only a single aging mechanism,multiple representative regression models are employed to establish the mapping relationship between the mechanism HF and capacity,further enhancing the accuracy of final results.Finally,the proposed method is implemented and validated using real battery data under three different types of operating conditions.Experimental results demonstrate that,compared to other commonly used HFs,the proposed HF exhibits significant competitive advantages in handling incomplete cycle data,unknown operating conditions,and capacity estimation models.The minimum estimation error under ideal conditions is 0.0074,and the minimum estimation error under complex dynamic conditions is 0.0268.
基金supported by the National Natural Science Foundation of China (Grant No.11574244 for G.Y.G.)the XJTU Research Fund for AI Science (Grant No.2025YXYC011 for G.Y.G.)the Hong Kong Global STEM Professorship Scheme (for X.C.Z.)。
文摘Compared to the well-studied two-dimensional(2D)ferroelectricity,the appearance of 2D antiferroelectricity is much rarer,where local dipoles from the nonequivalent sublattices within 2D monolayers are oppositely oriented.Using NbOCl_(2) monolayer with competing ferroelectric(FE)and antiferroelectric(AFE)phases as a 2D material platform,we demonstrate the emergence of intrinsic antiferroelectricity in NbOCl_(2) monolayer under experimentally accessible shear strain,along with new functionality associated with electric field-induced AFE-to-FE phase transition.Specifically,the complex configuration space accommodating FE and AFE phases,polarization switching kinetics,and finite temperature thermodynamic properties of 2D NbOCl_(2) are all accurately predicted by large-scale molecular dynamics simulations based on deep learning interatomic potential model.Moreover,room temperature stable antiferroelectricity with low polarization switching barrier and one-dimensional collinear polarization arrangement is predicted in shear-deformed NbOCl_(2) monolayer.The transition from AFE to FE phase in 2D NbOCl_(2) can be triggered by a low critical electric field,leading to a double polarization–electric(P–E)loop with small hysteresis.A new type of optoelectronic device composed of AFE-NbOCl_(2) is proposed,enabling electric“writing”and nonlinear optical“reading”logical operation with fast operation speed and low power consumption.
文摘Mitochondrial dysfunction has emerged as a critical factor in the etiology of various neurodevelopmental disorders, including autism spectrum disorders, attention-deficit/hyperactivity disorder, and Rett syndrome. Although these conditions differ in clinical presentation, they share fundamental pathological features that may stem from abnormal mitochondrial dynamics and impaired autophagic clearance, which contribute to redox imbalance and oxidative stress in neurons. This review aimed to elucidate the relationship between mitochondrial dynamics dysfunction and neurodevelopmental disorders. Mitochondria are highly dynamic organelles that undergo continuous fusion and fission to meet the substantial energy demands of neural cells. Dysregulation of these processes, as observed in certain neurodevelopmental disorders, causes accumulation of damaged mitochondria, exacerbating oxidative damage and impairing neuronal function. The phosphatase and tensin homolog-induced putative kinase 1/E3 ubiquitin-protein ligase pathway is crucial for mitophagy, the process of selectively removing malfunctioning mitochondria. Mutations in genes encoding mitochondrial fusion proteins have been identified in autism spectrum disorders, linking disruptions in the fusion-fission equilibrium to neurodevelopmental impairments. Additionally, animal models of Rett syndrome have shown pronounced defects in mitophagy, reinforcing the notion that mitochondrial quality control is indispensable for neuronal health. Clinical studies have highlighted the importance of mitochondrial disturbances in neurodevelopmental disorders. In autism spectrum disorders, elevated oxidative stress markers and mitochondrial DNA deletions indicate compromised mitochondrial function. Attention-deficit/hyperactivity disorder has also been associated with cognitive deficits linked to mitochondrial dysfunction and oxidative stress. Moreover, induced pluripotent stem cell models derived from patients with Rett syndrome have shown impaired mitochondrial dynamics and heightened vulnerability to oxidative injury, suggesting the role of defective mitochondrial homeostasis in these disorders. From a translational standpoint, multiple therapeutic approaches targeting mitochondrial pathways show promise. Interventions aimed at preserving normal fusion-fission cycles or enhancing mitophagy can reduce oxidative damage by limiting the accumulation of defective mitochondria. Pharmacological modulation of mitochondrial permeability and upregulation of peroxisome proliferator-activated receptor gamma coactivator 1-alpha, an essential regulator of mitochondrial biogenesis, may also ameliorate cellular energy deficits. Identifying early biomarkers of mitochondrial impairment is crucial for precision medicine, since it can help clinicians tailor interventions to individual patient profiles and improve prognoses. Furthermore, integrating mitochondria-focused strategies with established therapies, such as antioxidants or behavioral interventions, may enhance treatment efficacy and yield better clinical outcomes. Leveraging these pathways could open avenues for regenerative strategies, given the influence of mitochondria on neuronal repair and plasticity. In conclusion, this review indicates mitochondrial homeostasis as a unifying therapeutic axis within neurodevelopmental pathophysiology. Disruptions in mitochondrial dynamics and autophagic clearance converge on oxidative stress, and researchers should prioritize validating these interventions in clinical settings to advance precision medicine and enhance outcomes for individuals affected by neurodevelopmental disorders.
基金financial support of the National Science Foundation of China(No.21808220)。
文摘The absorption of CO_(2)is of importance in carbon capture,utilization,and storage technology for greenhouse gas control.In the present work,we clarified the mechanism of how metal-based ionic liquids (MBILs),Bmim[XCl_(n)]_(m)(X is the metal atom),enhance the CO_(2)absorption capacity of ILs via performing molecular dynamics simulations.The sparse hydrogen bond interaction network constructed by CO_(2)and MBILs was identified through the radial distribution function and interaction energy of CO_(2)-ion pairs,which increase the absorption capacity of CO_(2)in MBILs.Then,the dynamical properties including residence time and self-diffusion coefficient confirmed that MBILs could also promote the diffusion process of CO_(2)in ILs.That's to say,the MBILs can enhance the CO_(2)absorption capacity and the diffusive ability simultaneously.Based on the analysis of structural,energetic and dynamical properties,the CO_(2)absorption capacity of MBILs increases in the order Cl^-→[ZnCl_(4)]^(2-)→[CuCl_(4)]^(2-)→[CrCl_(4)]^-→[FeCl_(4)]^-,revealing the fact that the short metal–Cl bond length and small anion volume could facilitate the performance of CO_(2)absorbing process.These findings show that the metal–Cl bond length and effective volume of the anion can be the effective factors to regulate the CO_(2)absorption process,which can also shed light on the rational molecular design of MBILs for CO_(2)capture and other key chemical engineering processes,such as IL-based gas sensors,nano-electrical devices and so on.
基金Knowledge Innovation Project of Chinese Academy of Sciences(CAS),China(No.KZCX2-YW-333)
文摘The cultivated land-water resources carrying capacity （CL-WRCC） with the method of system dynamics （SD） were analyzed. Bijie prefecture of Guizhou province served as a case in this study. Bijie prefecture is one of the least-developed areas in China. In Bijie, the physical and chemical characteristics of karst as well as the rapid economic development lead to the scarcities of cultivated land-water resources （CL-WR）. On the basis of analysis on the subsystems of Bijie CL.WRCC system, the fundamental feedback structure of CL-WRCC was presented by causal loop diagram. Considering the three alms （＂ poverty alleviation and development, ecological construction, and population control＂） of Bijie as the major goals, Bijie CL-WRCC SD model was developed. Three scenarios, resource-saving and environment-friendly development-oriented scenario （Scenario 1 ）, fast economic development-oriented scenario （ Scenario 2 ）, and coordinated development-oriented scenario （Scenario 3 ）, were investigated. Simulation results indicate that Scenario 3 which takes social economic development, environment protection, and cultivated land- water resources utilization into account, is the best alternative scenario. It can promote the coordination development of society, economy, cultivated land, water resources, and environment. In this study, the technological support and the decision-making for the rational use of CL-WR are provided not only in Bijie, but also in other similar regions of China.
文摘Low performance of operational practices and wrong perceptions on demand forecast cause improper investments on new facilities for containers terminals, without taking into account the best use of their available resources. Accordingly, it would be desirable to model dynamic behaviour among demand, capacity and productivity of container terminal services, like reception, storage and distribution, to forecast their performances faced to demand evolution with time. This paper presents a system dynamic model to evaluate impacts from demand variations on 18 container terminals associated to ABRATEC （Associa^do Brasileira dos Terminals de Cont^ineres de Uso P^blico （in English： Brazilian Association of Public Container Terminals）） and their response capability to compensate demand growth with increasing productivity. The behaviour of the developed dynamic models was demonstrated by means of simulations carried out with the Vensim Standard 5.6d system dynamics software.
基金Supported by National High-tech R&D Program of China(863Program)(2009AA12Z-140)National Natural Science Foundation of China(40771144,40575035)Scientific Research Foundation of Sichuan Normal University(SXK11002)~~
文摘Chengdu City is in the period of rapid urbanization and industrialization, and the disturbance derived from human activities on environment is increasing remarkablely in recent 20 years. The pressure on environment, economy and population is also increasing and land use in Chengdu has changed enormously. As struc- ture and function of land ecological system change obviously, sustainable development of land productivity has been an important goal and strategic task from now on, and it is necessary to systematically research land ecological carrying capacity based on ecological footprint. The ecological footprint of Chengdu City in the past ten years was calculated and analyzed from the spatial and temporal aspects according to statistical data from 1998 to 2008, as per ecological footprint method, ecological carrying capacity and the GIS spatial analysis method, and regression analysis method. The ecological footprint and ecological carrying capacity values from 2009 to 2019 in Chengdu City were predicted through calculation results in the past ten years. The results show that the ecological footprint and ecological deficit of land use from 1998 to 2008 increased in Chengdu City. The ecological deficit of land use within the city center was in high levels in the past ten years, and the ecological footprint kept raising, especially in areas, such as Shuangliu, Chongzhou, Qingyang among 9 city areas, 4 counties and 6 districts in Chengdu City. There is fanlike distribution of ecological deficit of land use. Analysis shows that the social and natural ecological system is uneven distribution, which is not in sustainable de- velopment situation. The results of the study show that the economic, social and natural ecological system in Chengdu City is not sustainable, and the ecological foot- print is uneven distribution. The analysis of the dynamic change of land ecological carrying capacity in Chengdu City is very important for city government in the pro- cess of the vigorous development in new Tianfu Xinqu, and redevelopment in the northern part of this city.
基金supported by China National Key Technology R&D Program(Grant No.2008BAF34B13)China Postdoctoral Science Foundation Funded Project(Grant No.2011M501363)
文摘The existing researches of stepless capacity regulation system by depressing the suction valve for reciprocation compressor always adopt hypothesis that the compressor valves are open or close instantaneously,the valve dynamic has not been taken account into thermal cycle computation,the influence of capacity regulation system on suction valves dynamic performance and cylinder thermal cycle operation has not been considered.This paper focuses on theoretical and experimental analysis of the valve dynamic and thermal cycle for reciprocating compressor in the situation of stepless capacity regulation.The valve dynamics equation,gas forces for normal and back flow,and the cylinder pressure varying with suction valve unloader moment during compression thermal cycle are discussed.A new valve dynamic model based on L-K real gas state equation for reciprocating compressor is first deduced to reduce the calculation errors induced by the ideal gas state equation.The variations of valve dynamic and cylinder pressure during part of compression stroke are calculated numerically.The calculation results reveal the non-normal thermal cycle and operation condition of compressor in stepless capacity regulation situation.The numerical simulation results of the valve dynamic and thermal cycle parameters are also verified by the stepless capacity regulation experiments in the type of 3L-10/8 reciprocating compressor.The experimental results agree with the numerical simulation results,which show that the theoretical models proposed are effective and high-precision.The proposed theoretical models build the theoretical foundation to design the real stepless capacity regulation system.
基金supported by a Horizontal Project on the Development of a Hybrid Energy Storage Simulation Model for Wind Power Based on an RT-LAB Simulation System(PH2023000190)the Inner Mongolia Natural Science Foundation Project and the Optimization of Exergy Efficiency of a Hybrid Energy Storage System with Crossover Control for Wind Power(2023JQ04).
文摘Present of wind power is sporadically and cannot be utilized as the only fundamental load of energy sources.This paper proposes a wind-solar hybrid energy storage system(HESS)to ensure a stable supply grid for a longer period.A multi-objective genetic algorithm(MOGA)and state of charge(SOC)region division for the batteries are introduced to solve the objective function and configuration of the system capacity,respectively.MATLAB/Simulink was used for simulation test.The optimization results show that for a 0.5 MW wind power and 0.5 MW photovoltaic system,with a combination of a 300 Ah lithium battery,a 200 Ah lead-acid battery,and a water storage tank,the proposed strategy reduces the system construction cost by approximately 18,000 yuan.Additionally,the cycle count of the electrochemical energy storage systemincreases from4515 to 4660,while the depth of discharge decreases from 55.37%to 53.65%,achieving shallow charging and discharging,thereby extending battery life and reducing grid voltage fluctuations significantly.The proposed strategy is a guide for stabilizing the grid connection of wind and solar power generation,capability allocation,and energy management of energy conservation systems.
文摘Fatty acids are the main constituents of vegetable oils.To determine the fatty acid compositions of small trade vegetable oils and some less well studied beneficial vegetable oils,and investigate their relationships with antioxidant activity and oxidative stability,gas chromatography-mass spectrometry was performed to characterize the associated fatty acid profiles.The antioxidant activity of vegetable oils,based on their DPPH-scavenging capacity(expressed as IC_(50) values),was used to assess their impact on human health,and their oxidative stability was characterized by performing lipid oxidation analysis to determine the oxidative induction time of fats and oils.In addition,correlation analyses were performed to examine associations between the fatty acid composition of the oils and DPPH-scavenging capacity and oxidative stability.The results revealed that among the assessed oils,coffee seed oil has the highest saturated fatty acid content(355.10 mg/g),whereas Garddenia jaminoides oil has the highest unsaturated fatty acid content(844.84 mg/g).Coffee seed oil was also found have the lowest DPPH IC_(50) value(2.30 mg/mL)and the longest oxidation induction time(17.09 h).Correlation analysis revealed a significant linear relationship(P<0.05)between oxidative stability and unsaturated fatty acid content,with lower contents tending to be associated with better oxidative stability.The findings of this study provide reference data for the screening of functional edible vegetable oils.
基金supported by the National Natural Science Foundation of China(Grants No.51179083 and 91225302)
文摘This paper presents a simplified dynamic method based on the definition of field capacity. Two soil hydraulic characteristics models, the Brooks-Corey （BC） model and the van Genuchten （vG） model, and four soil data groups were used in this study. The relative drainage rate, which is a unique parameter and independent of the soil type in the simplified dynamic method, was analyzed using the pressure-based method with a matric potential of -1/3 bar and the flux-based method with a drainage flux of 0.005 cm/d. As a result, the relative drainage rate of the simplified dynamic method was determined to be 3% per day. This was verified by the similar field capacity results estimated with the three methods for most soils suitable for cultivating plants. In addition, the drainage time calculated with the simplified dynamic method was two to three days, which agrees with the classical definition of field capacity. We recommend the simplified dynamic method with a relative drainage rate of 3% per day due to its simple application and clearly physically-based concept.
基金The National Natural Science Foundation of China(No.52171274).
文摘Spiral pile foundations,as a promising type of foundation,are of significant importance for the development of offshore wind energy,particularly as it moves toward deeper waters.This study conducted a physical experiment on a three-spiral-pile jacket foundation under deep-buried sandy soil conditions.During the experiment,horizontal displacement was applied to the structure to thoroughly investigate the bearing characteristics of the three-spiral-pile jacket foundation.This study also focused on analyzing the bearing mechanisms of conventional piles compared with spiral piles with different numbers of blades.Three different working conditions were set up and compared,and key data,such as the horizontal bearing capacity,pile shaft axial force,and spiral blade soil pressure,were measured and analyzed.The results show the distinct impacts of the spiral blades on the compressed and tensioned sides of the foundation.Specifically,on the compressed side,the spiral blades effectively enhance the restraint of the soil on the pile foundation,whereas on the tensioned side,an excessive number of spiral blades can negatively affect the structural tensile performance to some extent.This study also emphasizes that the addition of blades to the side of a single pile is the most effective method for increasing the bearing capacity of the foundation.This research aims to provide design insights into improving the bearing capacity of the foundation.
