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Absorption mechanism of SO_(3)on various alkaline absorbents in the presence of SO_(2)
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作者 Junxiang Guo Jin Xiong +2 位作者 Yuran Li Jirigele Qinggele Tingyu Zhu 《Journal of Environmental Sciences》 2025年第3期268-277,共10页
Sulfur trioxide(SO_(3))as a condensable particle matter has a significant influence on atmospheric visibility,which easily arouses formation of haze.It is imperative to control the SO_(3)emission from the industrial f... Sulfur trioxide(SO_(3))as a condensable particle matter has a significant influence on atmospheric visibility,which easily arouses formation of haze.It is imperative to control the SO_(3)emission from the industrial flue gas.Three commonly used basic absorbents,including Ca(OH)_(2),MgO and NaHCO_(3)were selected to explore the effects of temperature,SO_(2)concentration on the SO_(3)absorption,and the reaction mechanism of SO_(3)absorption was further illustrated.The suitable reaction temperature for various absorbents were proposed,Ca(OH)_(2)at the high temperatures above 500°C,MgO at the low temperatures below 320°C,and NaHCO_(3)at the temperature range of 320–500°C.The competitive absorption between SO_(2)and SO_(3)was found that the addition of SO_(2)reduced the SO_(3)absorption on Ca(OH)_(2)and NaHCO_(3),while had no effect on MgO.The order of the absorption selectivity of SO_(3)follows MgO,NaHCO_(3)and Ca(OH)_(2)under the given conditions in this work.The absorption process of SO_(3)on NaHCO_(3)follows the shrinking core model,thus the absorption reaction continues until NaHCO_(3)was exhausted with the utilization rate of nearly 100%.The absorption process of SO_(3)on Ca(OH)_(2)and MgO follows the grain model,and the dense product layer hinders the further absorption reaction,resulting in low utilization of about 50%for Ca(OH)_(2)and MgO.The research provides a favorable support for the selection of alkaline absorbent for SO_(3)removal in application. 展开更多
关键词 Alkali absorbent Sulfur trioxide SELECTIVITY Shrinking core model Grain model
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Effect of sterically hindered amines on the cycling capacity of biphasic absorbents for industrial CO_(2) capture
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作者 Zanbu Geng Le Fu +5 位作者 Yang Yang YixiWang Wenqing Xu Runlong Hao Daoping Zhan Tingyu Zhu 《Journal of Environmental Sciences》 2025年第11期501-510,共10页
The biphasic solvent is a promising solution to reduce regeneration energy consumption in CO_(2) capture.However,most current biphasic solvents suffer from high viscosity and poor desorption of the rich phase.To the i... The biphasic solvent is a promising solution to reduce regeneration energy consumption in CO_(2) capture.However,most current biphasic solvents suffer from high viscosity and poor desorption of the rich phase.To the issues,a novel pentamethyldiethylenetriamine(PMDETA)-2-amino-2-methyl-1-propanol(AMP)/diethylenetriamine(DETA)-sulfolane biphasic solvent was developed.The mechanism of AMP affecting CO_(2) recycling capacity was analyzed.By adjusting the ratio of AMP and DETA,the absorption and desorption performance were balanced,and the recycling capacity and renewable energy consumption of the absorbent were improved.For the P_(2.4)A_(0.8)D_(0.8)S_(2) biphasic solvent,the CO_(2) loading of the rich phase was 5.87 mol/L,and the proportion of the rich phase volume ratio was 35%,which surpasses most reported biphasic solvents.The viscosity of the absorbent significantly decreased from 527.00 mPa·s to 92.26 mPa·s,attributed to the beneficial effect of AMP.Thermodynamic analysis showed that the biphasic solvent produced a lower regeneration energy consumption of 1.70 GJ/t CO_(2),which was 57%lower than that of monoethanolamine(MEA).Overall,the PMDETA-AMP/DETA-sulfolane biphasic solvent exhibited cycle capacity,which provided new insights for the designing of biphasic solvent. 展开更多
关键词 CO_(2)capture Biphasic absorbent Absorption AMINES Viscosity
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Preparation and performance analysis of non-aqueous absorbents based on alcohol ether organic compounds for CO_(2) capture
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作者 Yi Wang Yucong Ge +4 位作者 Li Yang Fang Liu Qingfang Li Yi Li Kunlei Liu 《Chinese Journal of Chemical Engineering》 2025年第12期284-295,共12页
MEA aqueous solution is widely utilized as an absorbent in chemical absorption processes.However,it is challenged by many disadvantages,including low regeneration capacity and high energy consumption during regenerati... MEA aqueous solution is widely utilized as an absorbent in chemical absorption processes.However,it is challenged by many disadvantages,including low regeneration capacity and high energy consumption during regeneration.In this study,new no-aqueous MEA absorbents were prepared using alcohol ether organic solvents,including proprylene glycol monomethyl ether(PGME),ethylene glycol butyl ether(EGBE),poly(ethylene glycol)dimethyl ether(NHD)and diethylene glycol monoethyl Ether(DGME).Then the performance of the absorbents was assessed through a series of experiments and based on the results,a comparison was made between the non-aqueous absorbents to the conventional absorbent(30%(mass)MEA aqueous solution).It was found that the organic solvent system presented a higher CO_(2)removal efficiency than the MEA-H_(2)O system in the first 350 s,with the maximum enhancement ranging from 5.16%to 14.36%.While NHD improved the CO_(2)loading but reduced the regeneration efficiency.Except for the MEA-NHD system,all the other no-aqueous absorbents possessed a better regeneration efficiency than the MEA aqueous solution,which offers them the potential for industrial application.According to the data from NMR and FTIR analysis,after CO_(2)absorption,the products in the MEA-EGBE and MEA-DGME systems were mainly found in the lower phase,the other phase was mainly organic solvents.Therefore,only the lower phase needs to be treated during desorption,with the upper phase being recycled directly,thus reducing energy consumption.The use of alcohol ether organic solvents can improve the CO_(2)capture performance of absorbents to a certain extent and enhance their regeneration ability,providing a new direction for the subsequent research of non-aqueous absorbents. 展开更多
关键词 CO_(2)capture Regeneration efficiency MEA Non-aqueous absorbent Cyclic capacity
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Radar cross section reduction in target airspace based on ultra-wide-angle artificial electromagnetic absorbing surface
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作者 LI Liang GAO Hongwei +1 位作者 ZHANG Binchao JIN Cheng 《Journal of Systems Engineering and Electronics》 2026年第1期75-83,共9页
A methodology for the reduction of radar cross section(RCS)of cambered platforms within the target airspace is presented,which utilizes a dual-polarized ultra-wide-angle artificial electromagnetic absorbing surface.By... A methodology for the reduction of radar cross section(RCS)of cambered platforms within the target airspace is presented,which utilizes a dual-polarized ultra-wide-angle artificial electromagnetic absorbing surface.By applying the theory of generalized Brewster complex wave impedance matching,five distinct unit cell designs are developed to attain more than95%absorption rate for dual-polarized incident waves within five angular ranges:0°-30°,30°-50°,50°-60°,60°-70°,and 70°-80°.To optimally reduce the RCS of a cambered platform,the five types of units can be evenly distributed on the surface based on the local incident angles of plane waves originating from the target airspace.As an illustrative example,the leading edge of an airfoil is taken into account,and experimental measurements validate the efficiency of the proposed structure.Specifically,the absorbing surface achieves more than 10 dB of RCS reduction in the frequency ranges from 5-10 GHz(about66.7%relative bandwidth)for dual polarizations. 展开更多
关键词 artificial electromagnetic absorbing surface DUAL-POLARIZATION oblique incidence ultra-wide-angle
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A theory perspective of the polysulfide absorbing materials for room-temperature sodium-sulfur batteries
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作者 Chhail Bihari Soni Vipin Kumar 《Journal of Energy Chemistry》 2026年第1期584-604,I0013,共22页
Though the formation of polysulfide is desirable,as it contributes to the capacity build-up,it must not leak into the electrolyte.The loss of polysulfide causes capacity fade,a change in the local chemistry of the ele... Though the formation of polysulfide is desirable,as it contributes to the capacity build-up,it must not leak into the electrolyte.The loss of polysulfide causes capacity fade,a change in the local chemistry of the electrolyte,and anode poisoning.Constant efforts are in progress to find suitable polysulfide-absorbing materials;however,the magical polysulfide absorber is yet to be discovered or developed.Experimental methods alone often fall short in accelerating the investigations may be due to the complex Nature of the testing.This review focuses on the importance of computational methods,particularly density functional theory(DFT),in screening suitable polysulfide absorbers.It highlights the critical role of anchoring materials in improving Na-S battery performance,including pristine and doped graphene,metal–organic frameworks,carbon Nanofibers,vanadium disulfide,MXenes,and metal sulfides.By examining adsorption energies,charge transfer mechanisms,and catalytic properties,this review provides insights into the design of advanced materials that can effectively immobilize polysulfides and enhance battery stability.The review aims to guide future research efforts toward the development of high-performance RT Na-S batteries through a comprehensive understanding of the polysulfide-absorbing materials. 展开更多
关键词 Na-S battery Computational theory Polysulfide absorbing materials DFT
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Annular Microfluidic Meta-Atom Fusion-Enabled Broadband Metamaterial Absorber
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作者 Jinpeng Peng Yi Zhang +7 位作者 Zihao Chen Qiye Wen Shaomeng Wang Yaoyao Li Aiwu Zhou Zhengnan Sun Xiaohui Mu Xiaosheng Zhang 《Nano-Micro Letters》 2026年第5期729-745,共17页
Electromagnetic(EM)metamaterial absorbers(MMAs)with broadband absorption are of growing interest for applications such as stealth and EM interference mitigation.In this work,we present a novel 3D-printed MMA based on ... Electromagnetic(EM)metamaterial absorbers(MMAs)with broadband absorption are of growing interest for applications such as stealth and EM interference mitigation.In this work,we present a novel 3D-printed MMA based on a fused annular microfluidic metaatom(FAMMA)architecture,designed for W-band absorption.The FAMMA structure features three kinds of orthogonally fused annual meta-atoms,forming a complex 3D microfluidic meta-atom with intricate architecture.Fabricated via high-precision micro 3D printing technology,the FAMMA-based MMA exploits the synergistic solid-liquid coupling effect of the unique three-dimensional orthogonal structure to achieve strong broadband absorption.Three representative FAMMAs with different geometric dimensions have achieved ultra-low reflection loss(RL of-42.1 dB),ultra-broadband effective absorption bandwidth(EAB of 31.3 GHz),and dual-band absorption(in 76.0-85.3 and 99.1-105.6 GHz),respectively.The underlying absorption mechanisms are elucidated by impedance matching theory and electromagnetic field distribution analyses.Application demonstrations show that the FAMMA-based MMA significantly suppresses radar echo power and renders metallic targets undetectable to both radar detector and radar imaging systems,highlighting its potential in stealth technology.Overall,this work establishes a new design concept for high-performance broadband millimeter wave MMAs,opening new avenue for future applications such as high-speed communication,through-wall sensing,and drone detection. 展开更多
关键词 Metamaterial absorber MMA 3D printing Additive manufacturing Radar stealth
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Influence of high-frequency vibration-absorbing fasteners on suppressing localized rail bending modal vibration
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作者 Zhecheng Tao Dadi Li +7 位作者 Lai Wei Chaozhi Ma Sheng Qu Caihong Huang Hao Gao Bin Zhu Huanyun Dai Yunguang Ye 《Railway Engineering Science》 2026年第1期159-183,共25页
Since the view that the localized rail third-order bending mode can cause high-order polygonization(mainly 18-23)of high-speed train wheels was put forward in 2017,many scholars have attempted to link a connection bet... Since the view that the localized rail third-order bending mode can cause high-order polygonization(mainly 18-23)of high-speed train wheels was put forward in 2017,many scholars have attempted to link a connection between the localized rail bending modes and wheel polygonization phenomenon and polygonal wheel passing frequency.This paper first establishes a flexible track model considering the structural and parametric characteristics of fasteners,verifies the model by using vehicle tracking test data,then investigates the influence of fastener parameter matching on the localized rail bending modes,and obtains the following conclusions:(1)There is nearly a 1:1 mapping relationship between the localized rail bending modal frequency and polygonal wheel passing(PWP)frequency,which supports that the localized rail bending mode is one of the causes of wheel polygonization.(2)The iron plate of the fastener system plays a role of dynamic vibration absorber in the vehicle-rail coupled system,and the fastener parameters significantly influence the localized rail bending modal vibration.Finally,this paper proposes a design principle of a high-frequency vibration-absorbing fastener,which provides a feasible solution to mitigate the localized rail bending modal vibration and high-order wheel polygonization.Meanwhile,it points out that this measure may induce other high-frequency vibration problems,e.g.,aggravating modal vibration above 800 Hz.Further,this paper proposes a concept of differentiated arrangement of fasteners,suggesting that different high-frequency vibration-absorbing fasteners be installed in different sections of the whole line to make the localized rail bending modal frequency of the whole line disordered,thus disrupting and further mitigating the development of the wheel polygonization. 展开更多
关键词 Localized rail bending mode High-speed train Fastener system Dynamic vibration absorber Parameter investigation
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Design of dual-network structure based on coordination bonds and hydrogen bonds for high-performance multifunctional flexible gel absorbers
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作者 Xinyue Xie Zijing Li +3 位作者 Shusheng Wang Geng Chen Limin Zhang Hongjing Wu 《International Journal of Minerals,Metallurgy and Materials》 2026年第2期693-703,共11页
The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various... The emergence of precision electronic devices and wearable electronic products urgently requires high-performance multifunctional electromagnetic wave(EMW)absorbers to meet the applicability and versatility in various applications.Herein,a dual-network(DN)gel was successfully prepared using acrylamide and sodium lignosulphonate as the basic units by simple chemical cross-linking and physical cross-linking methods.Specifically,the hydrogel forms two types of cross-linking networks through metal coordination and hydrogen bonding.Benefiting from the combined effects of dipole polarization and conductivity loss,the gel achieves an effective absorption bandwidth(EAB)of 6.74 GHz at a thickness of only 1.89 mm,demonstrating excellent EMW absorption performance.In addition,this unique structural configuration endows the EMW absorber with multifunctional features,such as remarkable tensile strength,good environmental compatibility,ultraviolet(UV)resistance,and excellent adhesion.Integrating multiple functional features into the EMW gels displays a broad application prospect in a variety of application scenarios.This research reveals the significance of DN structure design in the electromagnetic wave absorption(EWA)performance of gel-based materials,providing a substantial foundation for the multifunctional design of gel-based absorbers. 展开更多
关键词 electromagnetic wave absorbers dual-network structure polarization loss hydrogen bonds coordination bonds multifunc-tional characteristics
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Effect of the presence of trace sulfur dioxide on piperazine-based amine absorbents for carbon dioxide capture 被引量:2
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作者 Songtao Zheng Yao Jiang +2 位作者 Shaojun Jia Yan Wu Peng Cui 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2024年第9期34-41,共8页
The effect of the presence of trace SO_(2)in industrial flue gas on the amine-scrubbing-based absorption process for CO_(2)capture has been a matter of concern.This study aimed to investigate the effect of trace SO_(2... The effect of the presence of trace SO_(2)in industrial flue gas on the amine-scrubbing-based absorption process for CO_(2)capture has been a matter of concern.This study aimed to investigate the effect of trace SO_(2)on the CO_(2)capture process using piperazine-based amine absorbents,focusing on SO_(2)-resistance capability,SO_(2)/CO_(2)absorption selectivity,and cyclic stability.The presence of trace SO_(2)not only restrains CO_(2)absorption,but also promotes the formation of carbamate within the piperazine-based amine absorbents.Remarkably,the incorporation of aminoethyl group in piperazine-based amine absorbents can enhance the SO_(2)-resistance capability by promoting the formation of carbamate,while piperazine-based amine absorbents with hydroxyethyl group can promote the formation of bicarbonate to reduce the SO_(2)-resistance capability.The work offers valuable insights into the efficient application of novel amine absorbents for CO_(2)capture from practical industrial flue gas. 展开更多
关键词 CO_(2)capture PIPERAZINE Amine absorbent Trace SO_(2) Absorption
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The effect of membrane pores wettability on CO_2 removal from CO_2/CH_4 gaseous mixture using NaOH, MEA and TEA liquid absorbents in hollow fiber membrane contactor 被引量:5
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作者 Ali Taghvaie Nakhjiri Amir Heydarinasab +1 位作者 Omid Bakhtiari Toraj Mohammadi 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2018年第9期1845-1861,共17页
The present paper renders a modeling and a 2D numerical simulation for the removal of CO_2from CO_2/CH_4gaseous stream utilizing sodium hydroxide(NaOH),monoethanolamine(MEA)and triethanolamine(TEA)liquid absorbents in... The present paper renders a modeling and a 2D numerical simulation for the removal of CO_2from CO_2/CH_4gaseous stream utilizing sodium hydroxide(NaOH),monoethanolamine(MEA)and triethanolamine(TEA)liquid absorbents inside the hollow fiber membrane contactor.Counter-current arrangement of absorbing agents and CO_2/CH_4gaseous mixture flows are implemented in the modeling and numerical simulation.Non-wetting and partial wetting modes of operation are considered where in the partial wetting mode,CO_2/CH_4gaseous mixture and liquid absorbents fill the membrane pores.The deteriorated removal of CO_2in the partial wetting mode of operation is mainly due to the mass transfer resistance imposed by the liquid in the pores of membrane.The validation of numerical simulation is done based on the comparison of simulation results of CO_2removal using Na OH and experimental data under non-wetting mode of operation.The comparison illustrates a desirable agreement with an average deviation of less than 5%.According to the results,MEA provides higher efficiency for CO_2removal in comparison with the other liquid absorbents.The order for CO_2removal performance is MEAN Na OHN TEA.The influence of non-wetting and partial wetting modes of operation on CO_2removal are evaluated in this article as one of the novelties.Besides,the percentage of CO_2sequestration as a function of gas velocity for various percentages of membrane pores wetting ranging from 0(non-wetting mode of operation)to 100%(complete wetting mode of operation)is studied in this research paper,which can be proposed as the other novelty.The results indicate that increase in some operational parameters such as module length,membrane porosity and absorbents concentration encourage the removal percentage of CO_2from CO_2/CH_4gaseous mixture while increasing in membrane tortuosity,gas velocity and initial CO_2concentration has unfavorable influence on the separation efficiency of CO_2. 展开更多
关键词 CO2 removal Membrane wettability Numerical simulation CO2/CH4 gaseous mixture NAOH MEA and TEA liquid absorbents
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Influence of Reaction Parameters on Water Absorbency of Starch Grafted Superabsorbents
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作者 李明达 周永元 《Journal of Donghua University(English Edition)》 EI CAS 2002年第2期91-94,共4页
Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters,... Superabsorbents starch grafted sodium polyacrylate was synthesized by inverse suspension polymerization, using toluene as the continuous phase, potassium persulfate as the initiator. The effect of reaction parameters, such as starch pretreatment temperature, neutralization degree of monomer, reaction time and temperature, concentration of initiator, molar ratio of monomer and starch, on water absorbency of the starch grafted polymer was studied. The effects of the last two parameters were investigated by uniform design method, and the prediction equation was obtained. 展开更多
关键词 STARCH grafted sodium polyacrylate SUPERabsorbENT polymer water absorbency UNIFORM design method
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Industrial Progress:New Energy-Efficient Absorbents for the CO_(2) Separation from Natural Gas,Syngas and Flue Gas 被引量:1
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作者 Jorn Rolker Matthias Seiler 《Advances in Chemical Engineering and Science》 2011年第4期280-288,共9页
The CO2 separation from natural gas, syngas or flue gas represents an important industrial field of applications. An economic and energy-efficient CO2 separation from these gas streams is a prerequisite for sustainabl... The CO2 separation from natural gas, syngas or flue gas represents an important industrial field of applications. An economic and energy-efficient CO2 separation from these gas streams is a prerequisite for sustainable industry contributions to the megatrends resource efficiency and globalization of technologies. One way of reducing operational expenditure for these separation processes is the development of better performing CO2 absorbents. Although a number of absorbents for the separation of CO2 from process gas streams exist, the need for the development of CO2 absorbents with an improved absorption performance, less corrosion and foaming, no nitrosamine formation, lower energy requirement and therefore less operational expenditure remains. Recent industrial activities have led to the development of novel high-performance CO2 scrubbing agents that can be employed in numerous industrial processes such as natural gas treatment, purification of syngas and the scrubbing of flue gas. The objective of this paper is to introduce these new high-performance scrubbing agents and to compare their performance with other state-of-the-art absorbents. It turned out, that the evaluated absorbents offer high cyclic capacities in the range of 2.4 to 2.6 mol CO2/kg absorbent and low absorption enthalpies (–30 kJ/mol) allowing for distinctive savings in the regeneration energy of the absorbent. Calculations with the modified Kremser model resulted in a reduction of the specific reboiler heat duty of 55%. Furthermore, the absorbents are less corrosive than standard amines as indicated by the measured corrosion rates of 0.21 mm/y versus 1.18 mm/y for a piperazine/methyldiethanolamine mixture. Based on new experimental results it is shown how substantial savings in operational and capital expenditure can be realized due to favorable absorbent properties. The novel high-performance CO2 system solutions meet recent industrial absorbent requirements and allow for more efficient or new CO2 separation processes. 展开更多
关键词 absorbENT CO_(2) Energy Efficiency Sustainability Operational Expenditure SEPARATION Capture
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Experimental study on removal nitrogen oxide of flue gas by using solid absorbents
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作者 YANG Jia-mo GAO Feng LIU Hua-yang 《Journal of Environmental Science and Engineering》 2008年第1期46-48,66,共4页
With the rapid development of modem industry and increase of consumption of the coal, petroleum and natural gas etc., emission of nitrogen oxide (NOx) from flue gas has air environment quality worsen day by day. Thi... With the rapid development of modem industry and increase of consumption of the coal, petroleum and natural gas etc., emission of nitrogen oxide (NOx) from flue gas has air environment quality worsen day by day. This research work is experimental study on removal low concentration NOx of flue gas by using solid absorbents. The experiment result shown that denification rate by modified activated carbon is higher than that of modified zeolite and rectorite. Average denitrification rate is 65.47% and maximum denitrification rate is 95.82% for activated carbon; average denitrification rate is respectively as 43.29% and 36.18%, maximum denitrification rate is respectively as 87.51% and 79.47% for modified zeolite and rectorite. Experiment results indicated that NO adsorption process of activated carbon can be described by Freudlich adsorption mode, K=0.143 and n=2.842 and Freudlich adsorption isotherm equation is: q = 0.143MO^0.3519. 展开更多
关键词 nitrogen oxide denitrification rate adsorption kinetics solid absorbents
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Generation and dynamics of special mode-locked pulses in an ultrafast Er-doped fiber laser with SMF-GIMF-SMF saturable absorber 被引量:1
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作者 LIN Yingjie ZENG Qiong +3 位作者 JI Yubo SONG Yufeng WANG Ke WANG Zhenhong 《Optoelectronics Letters》 2025年第5期265-270,共6页
In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not ... In this paper, we have demonstrated an Er-doped ultrafast laser with a single mode fiber-gradient index multimode fiber-single mode fiber(SMF-GIMF-SMF, SMS) structure as saturable absorber(SA), which can generate not only stable single-pulse state, but also special mode-locked pulses with the characteristics of high energy and noisy behaviors at proper pump power and cavity polarization state. In addition, we have deeply investigated the real-time spectral evolutions of the mode-locked pulses through the dispersive Fourier transformation(DFT) technique. It can be found that the pulse regime can actually consist of a lot of small noise pulses with randomly varying intensities. We believe that these results will further enrich the nonlinear dynamical processes in the ultrafast lasers. 展开更多
关键词 ultrafast laser ER doped fiber SMF GIMF SMF dispersive Fourier transformation saturable absorber sa mode locked pulses nonlinear dynamics saturable absorber
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Hydrogen bond-induced conduction loss for enhanced electromagnetic attenuation in deep eutectic gel absorbers 被引量:1
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作者 Yuntong Wang Shengchong Hui +6 位作者 Zhaoxiaohan Shi Zijing Li Geng Chen Tao Zhang Xinyue Xie Limin Zhang Hongjing Wu 《International Journal of Minerals,Metallurgy and Materials》 2025年第3期738-746,共9页
Gels and conductive polymer composites,including hydrogen bonds(HBs),have emerged as promising materials for electro-magnetic wave(EMW)absorption across various applications.However,the relationship between conduction... Gels and conductive polymer composites,including hydrogen bonds(HBs),have emerged as promising materials for electro-magnetic wave(EMW)absorption across various applications.However,the relationship between conduction loss in EMW-absorbing materials and charge transfer in HB remains to be fully understood.In this study,we developed a series of deep eutectic gels to fine-tune the quantity of HB by adjusting the molar ratio of choline chloride(ChCl)and ethylene glycol(EG).Owing to the unique properties of deep eutectic gels,the effects of magnetic loss and polarization loss on EMW attenuation can be disregarded.Our results indicate that the quantity of HB initially increases and then decreases with the introduction of EG,with HB-induced conductive loss following similar pat-terns.At a ChCl and EG molar ratio of 2.4,the gel labeled G22-CE2.4 exhibited the best EMW absorption performance,characterized by an effective absorption bandwidth of 8.50 GHz and a thickness of 2.54 mm.This superior performance is attributed to the synergistic ef-fects of excellent conductive loss and impedance matching generated by the optimal number of HB.This work elucidates the role of HB in dielectric loss for the first time and provides valuable insights into the optimal design of supramolecular polymer absorbers. 展开更多
关键词 absorbERS hydrogen bonds deep eutectic gels dielectric properties conduction loss
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Absorption frequency band switchable intelligent electromagnetic wave absorbing carbon composite by cobalt confined catalysis 被引量:1
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作者 Luo Kong Haodong Cui +3 位作者 Shuyu Zhang Guiqin Zhang Jun Yang Xiaomeng Fan 《Journal of Materials Science & Technology》 2025年第8期203-211,共9页
The dielectric loss of carbon materials is closely related to the microstructure and the degree of crystallization,and the microstructure modulation of electromagnetic wave absorbing carbon materials is the key to enh... The dielectric loss of carbon materials is closely related to the microstructure and the degree of crystallization,and the microstructure modulation of electromagnetic wave absorbing carbon materials is the key to enhancing absorption properties.In this work,a porous elastic Co@CNF-PDMS composite was prepared by freeze-drying and confined catalysis.The graphitization degree and conductivity loss of carbon nanofibers(CNFs)were regulated by heat treatment temperature and Co catalyst content.The construction of a heterointerface between Co and C enhances the interfacial polarization loss.The Co@CNF-PDMS composite with 4.5 mm achieves the minimum reflection loss(RLmin)of-81.0 dB at 9.9 GHz and RL no higher than-12.1 dB in the whole of the X-band.After applying a load of up to 40% strain and 100 cycles to Co@CNF-PDMS,the dielectric properties of the composite remain stable.With the increase of compression strain,the distribution density of the absorbent increases,and the CNF sheet layer extrusion contact forms a conductive path,which leads to the conductive loss increase,finally,the absorption band moves to a high frequency.The absorption band can be bi-directionally regulated by loading and strain with good stability,which provides a new strategy for the development of intelligent electromagnetic wave absorbing materials. 展开更多
关键词 Carbon nanofiber Confined catalysis Electromagnetic wave absorbing material
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Fabrication of flake-like NiCo_(2)O_(4)/reduced graphene oxide/melamine-derived carbon foam as an excellent microwave absorber 被引量:1
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作者 Konghu Tian Hang Yang +4 位作者 Chao Zhang Ruiwen Shu Qun Shao Xiaowei Liu Kaipeng Gao 《International Journal of Minerals,Metallurgy and Materials》 2025年第3期556-565,共10页
Carbon-based foams with a three-dimensional structure can serve as a lightweight template for the rational design and control-lable preparation of metal oxide/carbon-based composite microwave absorption materials.In t... Carbon-based foams with a three-dimensional structure can serve as a lightweight template for the rational design and control-lable preparation of metal oxide/carbon-based composite microwave absorption materials.In this study,a flake-like nickel cobaltate/re-duced graphene oxide/melamine-derived carbon foam(FNC/RGO/MDCF)was successfully fabricated through a combination of solvo-thermal treatment and high-temperature pyrolysis.Results indicated that RGO was evenly distributed in the MDCF skeleton,providing ef-fective support for the load growth of FNC on its surface.Sample S3,the FNC/RGO/MDCF composite prepared by solvothermal method for 16 h,exhibited a minimum reflection loss(RL_(min))of-66.44 dB at a thickness of 2.29 mm.When the thickness was reduced to 1.50 mm,the optimal effective absorption bandwidth was 3.84 GHz.Analysis of the absorption mechanism of FNC/RGO/MDCF revealed that its excellent absorption performance was primarily attributed to the combined effects of conduction loss,multiple reflection,scattering,in-terface polarization,and dipole polarization. 展开更多
关键词 carbon foam reduced graphene oxide flake-like nickel cobaltate microwave absorbing materials
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Research on conduction band offset of CZTSSe solar cell with double absorber layers 被引量:1
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作者 HU Xiaofeng XUE Yuming +3 位作者 DAI Hongli WANG Luoxin NI Meng BAI Xin 《Optoelectronics Letters》 2025年第7期391-396,共6页
Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIG... Cu_(2)ZnSn(S,Se)_(4)(CZTSSe)is considered to be the most potential light-absorbing material to replace CuInGaSe_(2)(CIGS),but the actual photoelectric conversion efficiency of such cells is much lower than that of CIGS.One of the reasons is the high recombination rate of carriers at the interface.In this paper,in order to reduce the carrier recombination,a new solar cell structure with double absorber layers of Al-doped ZnO(AZO)/intrinsic(i)-ZnO/CdS/CZTS_(x1)Se_(1−x1)(CZTSSe_(1))/CZTS_(x2)Se_(1−x2)(CZTSSe_(2))/Mo was proposed,and the optimal conduction band offsets(CBOs)of CdS/CZTSSe_(1) interface and CZTSSe_(1)/CZTSSe_(2) interface were determined by changing the S ratio in CZTSSe_(1) and CZTSSe_(2),and the effect of thickness of CZTSSe_(1) on the performance of the cell was studied.The efficiencies of the optimized single and double absorber layers reached 17.97%and 23.4%,respectively.Compared with the single absorber layer structure,the proposed structure with double absorber layers has better cell performance. 展开更多
关键词 EFFICIENCY carrier recombination double absorber layers conduction band offset solar cell CZTSSe solar cell
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Super absorbent fiber: 200:1 water absorption ratio
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作者 Zhao Xinhua 《China Textile》 2025年第3期19-19,共1页
In today's era of continuous advancement in materials science,the properties of materials are constantly being enhanced,and their application fields are also expanding continuously.SAF(Super Absorbent Fiber),one s... In today's era of continuous advancement in materials science,the properties of materials are constantly being enhanced,and their application fields are also expanding continuously.SAF(Super Absorbent Fiber),one such material,stands out.Compared to traditional SAP(Super Absorbent Polymer),SAF boasts a unique fibrous form and exceptional performance,presenting broad application prospects. 展开更多
关键词 materials science fibrous form super absorbent fiber sap super absorbent polymer saf super absorbent polymer performance absorbent fiber one water absorption ratio
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Broadband Optically Transparent Absorber and Multi-Band Stealth Based on Organic Metasurface
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作者 Chuwen Lan Yutong Gao +4 位作者 Zehua Gao Hongye Wang Ke Bi Ming Lei Guoan Zhao 《Chinese Physics Letters》 2025年第5期93-99,共7页
Optically transparent microwave absorbers and multi-band stealth have extensive potential applications in military defense and wireless communication fields, and thus have attracted considerable attention. So far,most... Optically transparent microwave absorbers and multi-band stealth have extensive potential applications in military defense and wireless communication fields, and thus have attracted considerable attention. So far,most related work is based on inorganic transparent conductive metasurfaces. In this paper, we proposed and experimentally demonstrated a flexible, broadband and optically transparent microwave absorber using an organic metasurface. The metasurface absorber is composed of a sandwich structure, in which electric resonances and magnetic resonances are induced resulting in broadband absorption. A spraying process was developed to prepare this metasurface absorber. Both simulations and experiment show that this metasurface has broadband microwave absorption and good optical transparency. We further found that by using a multi-layer structure, visible, radar,and infrared stealth(multi-band stealth) can be achieved simultaneously. With the advantages of excellent foldability and low cost, the proposed metasurfaces may have applications in military and wireless communication fields. 展开更多
关键词 microwave absorber broadband microwave absorption organic metasurface metasurface absorber microwave absorbers inorganic transparent conductive metasurfaces military defense sandwich structure
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