The spread of pine nematode disease caused by epidemic wood poses a great challenge to the environment,and there is an urgent need to develop effective processing methods;however,Ca/Fe-rich sludge ash can improve the ...The spread of pine nematode disease caused by epidemic wood poses a great challenge to the environment,and there is an urgent need to develop effective processing methods;however,Ca/Fe-rich sludge ash can improve the pyrolysis properties of biomass.Therefore,this paper focuses on the pyrolysis mechanism of epidemic wood with the addition of Ca/Fe-rich sludge ash.The presence of Ca-rich sludge ash was found to extend the pyrolytic temperature window of epidemic wood,intensify the cracking of its volatile constituents,and extend its reaction duration.At the same time,the Ca-rich sludge reduces the pyrolysis activation energy to 152.39 kJ/mol.The Fe-rich sludge ash demonstrated the capacity to lower the energy barriers during the initial phase of pyrolysis.Concurrently,the Ca-rich sludge ash accelerated the dehydration reaction of the epidemic wood,leading to 21.02%and 30.69%increases in the contents of acids and ketones in the pyrolytic oil,respectively.The Fe-rich sludge ash contributed to a notable 14.52%increase in aromatic compounds in the oil and a 19.14%decrease in alcoholic compounds.Additionally,the Ca-rich sludge ash accelerated the decomposition of lipid organic matter at elevated temperatures,enriching the pyrolytic char with more unsaturated bonds.This research lays a theoretical foundation for the safe and efficacious thermal decomposition of epidemic wood,thereby enhancing its utilization within the forestry industry.展开更多
Trace amounts of Zr and V can increase the recrystallization temperature of Al-Mg-Si wrought aluminum alloys,which is expected to regulate the recrystallization grain.In this paper,trace amounts of V and Zr were added...Trace amounts of Zr and V can increase the recrystallization temperature of Al-Mg-Si wrought aluminum alloys,which is expected to regulate the recrystallization grain.In this paper,trace amounts of V and Zr were added to recycled Al-Mg-Si alloys,and their e ffects on the microstructure and mechanical properties of the cast alloys were studied by scanning electron microscopy(SEM)and synchrotron radiation X-ray tomography(SRXT).The results show that the addition of Zr significantly increases the grain sizes due to the“Zr poisoning”;V addition has no significant effect on the grain size.The morphology of Fe-rich phase gradually changes from the large Chinese-script shape to the fine short rod and curved long strip shape,and the distribution uniformity is improved with the combined addition of V and Zr.The three-dimensional(3 D)morphology of Fe-rich phase includes granular,short rod-like,simple branch and multi-branch structures.The individual addition of V and Zr has no significant effect on the morphology of Fe-rich phase;but the combined addition of V and Zr significantly increases the number and volume fraction of Fe-rich phase with small size(diameter£15μm),the number of branches in the largest Fe-rich phase is significantly reduced,resulting in the improvement of elongation.This work provides a theoretical basis for the development of new recycled Al-Mg-Si alloys in industrial application.展开更多
The effects of artificial aging(T6)on the creep resistance with tensile stresses in the range of 50−80 MPa at 175℃were investigated for an extruded Mg−1.22Al−0.31Ca−0.44Mn(wt.%)alloy.The Guinier-Preston(G.P.)zones pr...The effects of artificial aging(T6)on the creep resistance with tensile stresses in the range of 50−80 MPa at 175℃were investigated for an extruded Mg−1.22Al−0.31Ca−0.44Mn(wt.%)alloy.The Guinier-Preston(G.P.)zones primarily precipitate in the sample aged at 200℃for 1 h(T6-200℃/1h),while the Al_(2)Ca phases mainly precipitate in the sample aged at 275℃for 8 h(T6-275℃/8h).The T6-200℃/1h sample exhibits excellent creep resistance,with a steady-state creep rate one order of magnitude lower than that of the T6-275℃/8h sample.The abnormally high stress exponent(~8.2)observed in the T6-200℃/1h sample is associated with the power-law breakdown mechanism.TEM analysis illuminates that the creep mechanism for the T6-200℃/1h sample is cross-slip between basal and prismatic dislocations,while the T6-275℃/8h sample exhibits a mixed mechanism of dislocation cross-slip and climb.Compared with the Al_(2)Ca phase,the dense G.P.zones effectively impede dislocation climb and glide during the creep process,demonstrating superior creep resistance of the T6-200℃/1h sample.展开更多
We report the results of the experiment on synthesizing ^(287,288)Mc isotopes (Z=115) using the fusionevaporation reaction ^(243)Am(^(48)Ca,4n,3n)^(287,288)Mc at the Spectrometer for Heavy Atoms and Nuclear Structure-...We report the results of the experiment on synthesizing ^(287,288)Mc isotopes (Z=115) using the fusionevaporation reaction ^(243)Am(^(48)Ca,4n,3n)^(287,288)Mc at the Spectrometer for Heavy Atoms and Nuclear Structure-2(SHANS2),a gas-filled recoil separator located at the China Accelerator Facility for Superheavy Elements(CAFE2).In total,20 decay chains are attributed to ^(288)Mc and 1 decay chain is assigned to ^(287)Mc.The measured oa-decay properties of ^(287,288)Mc as well as its descendants are consistent with the known data.No additional decay chains originating from the 2n or 5n reaction channels were detected.The excitation function of the ^(243)Am(^(48)Ca,3n)^(288)Mc reaction was measured at the cross-section level of picobarn,which indicates the promising capability for the study of heavy and superheavy nuclei at the facility.展开更多
基金supported by the Projects of Intergovernmental Cooperation of Science and Technology/National Key Research and Development Program of China(No.2024YFE0100200)the National Natural Science Foundation of China(No.52236008)+1 种基金the Zhejiang Provincial Natural Science Foundation(No.LZ23E060004)the National Natural Science Foundation of China(No.52206178).
文摘The spread of pine nematode disease caused by epidemic wood poses a great challenge to the environment,and there is an urgent need to develop effective processing methods;however,Ca/Fe-rich sludge ash can improve the pyrolysis properties of biomass.Therefore,this paper focuses on the pyrolysis mechanism of epidemic wood with the addition of Ca/Fe-rich sludge ash.The presence of Ca-rich sludge ash was found to extend the pyrolytic temperature window of epidemic wood,intensify the cracking of its volatile constituents,and extend its reaction duration.At the same time,the Ca-rich sludge reduces the pyrolysis activation energy to 152.39 kJ/mol.The Fe-rich sludge ash demonstrated the capacity to lower the energy barriers during the initial phase of pyrolysis.Concurrently,the Ca-rich sludge ash accelerated the dehydration reaction of the epidemic wood,leading to 21.02%and 30.69%increases in the contents of acids and ketones in the pyrolytic oil,respectively.The Fe-rich sludge ash contributed to a notable 14.52%increase in aromatic compounds in the oil and a 19.14%decrease in alcoholic compounds.Additionally,the Ca-rich sludge ash accelerated the decomposition of lipid organic matter at elevated temperatures,enriching the pyrolytic char with more unsaturated bonds.This research lays a theoretical foundation for the safe and efficacious thermal decomposition of epidemic wood,thereby enhancing its utilization within the forestry industry.
基金Project(2024YEE0109100) supported by the National Key R&D Program of ChinaProjects(52074131,52104373) supported by the National Natural Science Foundation of ChinaProjects(2022YFJH001,2024YFJH001) supported by the Science and Technology Plan Program of Qingyuan City,China。
文摘Trace amounts of Zr and V can increase the recrystallization temperature of Al-Mg-Si wrought aluminum alloys,which is expected to regulate the recrystallization grain.In this paper,trace amounts of V and Zr were added to recycled Al-Mg-Si alloys,and their e ffects on the microstructure and mechanical properties of the cast alloys were studied by scanning electron microscopy(SEM)and synchrotron radiation X-ray tomography(SRXT).The results show that the addition of Zr significantly increases the grain sizes due to the“Zr poisoning”;V addition has no significant effect on the grain size.The morphology of Fe-rich phase gradually changes from the large Chinese-script shape to the fine short rod and curved long strip shape,and the distribution uniformity is improved with the combined addition of V and Zr.The three-dimensional(3 D)morphology of Fe-rich phase includes granular,short rod-like,simple branch and multi-branch structures.The individual addition of V and Zr has no significant effect on the morphology of Fe-rich phase;but the combined addition of V and Zr significantly increases the number and volume fraction of Fe-rich phase with small size(diameter£15μm),the number of branches in the largest Fe-rich phase is significantly reduced,resulting in the improvement of elongation.This work provides a theoretical basis for the development of new recycled Al-Mg-Si alloys in industrial application.
基金supported by the National Natural Science Foundation of China (Nos. 52175322, 52271031)the Natural Science Foundation of Jilin Province, China (No. SKL202302015)。
文摘The effects of artificial aging(T6)on the creep resistance with tensile stresses in the range of 50−80 MPa at 175℃were investigated for an extruded Mg−1.22Al−0.31Ca−0.44Mn(wt.%)alloy.The Guinier-Preston(G.P.)zones primarily precipitate in the sample aged at 200℃for 1 h(T6-200℃/1h),while the Al_(2)Ca phases mainly precipitate in the sample aged at 275℃for 8 h(T6-275℃/8h).The T6-200℃/1h sample exhibits excellent creep resistance,with a steady-state creep rate one order of magnitude lower than that of the T6-275℃/8h sample.The abnormally high stress exponent(~8.2)observed in the T6-200℃/1h sample is associated with the power-law breakdown mechanism.TEM analysis illuminates that the creep mechanism for the T6-200℃/1h sample is cross-slip between basal and prismatic dislocations,while the T6-275℃/8h sample exhibits a mixed mechanism of dislocation cross-slip and climb.Compared with the Al_(2)Ca phase,the dense G.P.zones effectively impede dislocation climb and glide during the creep process,demonstrating superior creep resistance of the T6-200℃/1h sample.
基金supported in part by the National Key R&D Program of China (Contract Nos.2023YFA1606500,2024YFE0109800,and 2024YFE0110400)Strategic Priority Research Program of Chinese Academy of Sciences(Grant No.XDB34010000)+5 种基金the Gansu Key Project of Science and Technology (Grant No.23ZDGA014)the Guangdong Major Project of Basic and Applied Basic Research (Grant No.2021B0301030006)the National Natural Science Foundation of China (Grant Nos.12105328,W2412040,12475126,12422507,12035011,12375118,12435008,and W2412043)the Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-002)the Youth Innovation Promotion Association of the Chinese Academy of Sciences (Grant Nos.2020409 and 2023439)the Russian Science Foundation (Grant No.25-42-00003)。
文摘We report the results of the experiment on synthesizing ^(287,288)Mc isotopes (Z=115) using the fusionevaporation reaction ^(243)Am(^(48)Ca,4n,3n)^(287,288)Mc at the Spectrometer for Heavy Atoms and Nuclear Structure-2(SHANS2),a gas-filled recoil separator located at the China Accelerator Facility for Superheavy Elements(CAFE2).In total,20 decay chains are attributed to ^(288)Mc and 1 decay chain is assigned to ^(287)Mc.The measured oa-decay properties of ^(287,288)Mc as well as its descendants are consistent with the known data.No additional decay chains originating from the 2n or 5n reaction channels were detected.The excitation function of the ^(243)Am(^(48)Ca,3n)^(288)Mc reaction was measured at the cross-section level of picobarn,which indicates the promising capability for the study of heavy and superheavy nuclei at the facility.
