In this study, the solar thermochemical reactor performance for CO_2 utilization into synthesis gas(H_2+ CO) based on CH_4 reforming process was investigated in the context of carbon capture and utilization(CCU) techn...In this study, the solar thermochemical reactor performance for CO_2 utilization into synthesis gas(H_2+ CO) based on CH_4 reforming process was investigated in the context of carbon capture and utilization(CCU) technologies. The P1 radiation heat transfer model is adopted to establish the heat and mass transfer model coupled with thermochemical reaction kinetics. The reactor thermal behavior with direct heat transfer between gaseous reactant and products evolution and the effects of different structural parameters were evaluated. It was found that the reactor has the potential to utilize by ～60% of CO_2 captured with 40% of CH_4 co-fed into syngas(72.9% of H_2 and 27.1% of CO) at 741.31 k W/mof incident radiation heat flux. However, the solar irradiance heat flux and temperature distribution were found to significantly affect the reactant species conversion efficiency and syngas production. The chemical reaction is mainly driven by the thermal energy and higher species conversion into syngas was observed when the temperature distribution at the inner cavity of the reactor was more uniform. Designed a solar thermochemical reactor able to volumetric store concentrated irradiance could highly improve CCU technologies for producing energy-rich chemicals. Besides, the mixture gas inlet velocity, operating pressure and CO_2/CH_4 feeding ratio were crucial to determining the efficiency of CO_2 utilization to solar fuels. Catalytic CO_2-reforming of CH_4 to chemical energy is a promising strategy for an efficient utilization of CO_2 as a renewable carbon source.展开更多
Reducing the anthropogenic COemissions from fossil resource combustion and human activities has become one of the major challenges we are facing today.Beyond those practical applications for the utilization of CO,such...Reducing the anthropogenic COemissions from fossil resource combustion and human activities has become one of the major challenges we are facing today.Beyond those practical applications for the utilization of CO,such as the synthesis of salicylic acid,methanol,urea,NaHCO-NaCOchemicals and recently developed polycarbonate synthesis,scientists are still seeking new materials and technologies for efficient capture,展开更多
Cyclic injection holds great potential for CO_(2) emission reduction coupled with enhanced unconventional oil recovery.There is,however,a lack of a thorough understanding of carbon distribution,migration,and transform...Cyclic injection holds great potential for CO_(2) emission reduction coupled with enhanced unconventional oil recovery.There is,however,a lack of a thorough understanding of carbon distribution,migration,and transformation underground over time at the reservoir scale.To address this issue,we conducted a rig-orous numerical simulation integrating microseismic events,multi-geomechanics,and multi-geochemistry to represent the complex fracture geometry,rock stress sensitivity,and CO_(2)-oil-brine-rock interactions.The fluid model,reservoir model,and geochemical reaction kinetics were carefully validated and calibrated using experimental data.The performance of CO_(2) utilization and geological storage was comprehensively investigated in terms of changes in oil production,CO_(2) storage,carbon distribution,and petrophysical properties.The results indicate that 48.3%of the injected CO_(2) was stored stably under-ground after ten cycles(ten years),with a 3.4%increase in oil recovery.The presence of multiple CO_(2) stor-age forms,such as dissolved in water and mineralized carbonate,impeded CO_(2)-oil interaction,leading to a 25.9%reduction in the volume of the CO_(2)-oil mixing zone and a 2.2%decrease in cumulative oil pro-duction,albeit with a 7.7%increase in the storage rate.The cyclic injection mode had a significant impact on the migration and transformation of CO_(2) in the reservoir.While dissolved CO_(2) in oil accounted for over half of the total storage,it had the possibility of being released during production.After ten cycles,20%of the injected CO_(2)(approximately 12000 t)reached long-term storage in four forms:mineralized carbon-ate(6%),water-dissolved CO_(2)(6%),aqueous ions(4%),and trapped gas(4%).Notably,the non-fracture zone within the stimulated reservoir volume(SRV)served as the primary trapping area for residual gas.This work provides valuable insights into dynamic CO_(2) transport and transformation processes under cyclic injection and presents a more comprehensive and precise framework for assessing CO_(2) capture,utilization,and storage with enhanced oil recovery(CCUS-EOR)performance in unconventional reser-voirs after fracturing.展开更多
Geological storage and utilization of CO_(2)involve complex interactions among Thermo-hydromechanical-chemical(THMC)coupling processes,which significantly affect storage integrity and efficiency.To address the challen...Geological storage and utilization of CO_(2)involve complex interactions among Thermo-hydromechanical-chemical(THMC)coupling processes,which significantly affect storage integrity and efficiency.To address the challenges in accurately simulating these coupled phenomena,this paper systematically reviews recent advances in the mathematical modeling and numerical solution of THMC coupling in CO_(2)geological storage.The study focuses on the derivation and structure of governing and constitutive equations,the classification and comparative performance of fully coupled,iteratively coupled,and explicitly coupled solution methods,and the modeling of dynamic changes in porosity,permeability,and fracture evolution induced by multi-field interactions.Furthermore,the paper evaluates the capabilities,application scenarios,and limitations of major simulation platforms,including TOUGH,CMG-GEM,and COMSOL.By establishing a comparative framework integrating model formulations and solver strategies,this work clarifies the strengths and gaps of current approaches and contributes to the development of robust,scalable,and mechanism-oriented numerical models for long-term prediction of CO_(2)behavior in geological formations.展开更多
Carbon capture,utilization,and storage(CCUS)represents a critical technological pathway for global car-bon emission reduction.CCUS-enhanced oil recovery(EOR)technology is the most feasible CCUS technol-ogy demonstrati...Carbon capture,utilization,and storage(CCUS)represents a critical technological pathway for global car-bon emission reduction.CCUS-enhanced oil recovery(EOR)technology is the most feasible CCUS technol-ogy demonstrating dual benefits of enhanced energy production and carbon reduction.This study comprehensively described the key influencing factors governing CO_(2)-EOR and geological storage and systematically analyzed reservoir properties,fluid characteristics,and operational parameters.The mech-anisms of these parameters on EOR versus CO_(2) storage performance were investigated throughout CCUS-EOR processes.This paper proposes a coupled two-stage CCUS-EOR process:CO_(2)-EOR storage stage and long-term CO_(2) storage stage after the CO_(2) injection phase is completed.In each stage,the main control factors impacting the CO_(2)-EOR and storage stages are screened and coupled with rigorous technical anal-ysis.The key factors here are reservoir properties,fluid characteristics,and operational parameter.A novel CCUS-EOR synergistic method was proposed to optimize the lifecycle performance of dual objective of EOR and storage.Furthermore,based on multi-objective optimization,considering the lifecycle,a multi-scale techno-economic evaluation method was proposed to fully assess the CCUS-EOR project per-formance.Finally,a set of recommendations for advancing CCUS-EOR technologies by deploying multi-factor/multi-field coupling methodologies,novel green intelligent injection materials,and artificial intel-ligence/machine learning technologies were visited.展开更多
The photocatalytic reduction of CO_(2)presents a promising avenue for carbon fuel conversion.However,the efficiency of charge utilization remains a critical barrier to industrial applications.In this study,we introduc...The photocatalytic reduction of CO_(2)presents a promising avenue for carbon fuel conversion.However,the efficiency of charge utilization remains a critical barrier to industrial applications.In this study,we introduce a tandem design of Bi_(2)WO_(6)-BiOCl with an atomically matched interface,achieving highly efficient photoreduction of CO_(2)to CO.By incorporating WO_(4)^(2-)ions and tuning coordination environment,the(110)facet of BiOCl was in-situ grown on the(200)facet of Bi_(2)WO_(6).Compared to single phases and ball-milling samples,Bi_(2)WO_(6)-BiOCl exhibits a remarkable CO yield of 68.03μmol g^(-1)h^(-1)with a selectivity of 98%.Atomic visualization and coordination analysis confirm the formation of a coherent interface that facilitates charge migration for efficient electron transport.Density functional theory(DFT)calculations and in-situ Fourier transform infrared(FTIR)spectroscopy provide insights into the intrinsic active sites and reaction mechanisms.The proposed lattice engineering strategies offer a new paradigm for the rational design of heterostructures beyond traditional band alignment at the atomic scale.展开更多
The park-level integrated energy system(PIES)is essential for achieving carbon neutrality by managing multi-energy supply and demand while enhancing renewable energy integration.However,current carbon trading mechanis...The park-level integrated energy system(PIES)is essential for achieving carbon neutrality by managing multi-energy supply and demand while enhancing renewable energy integration.However,current carbon trading mechanisms lack sufficient incentives for emission reductions,and traditional optimization algorithms often face challenges with convergence and local optima in complex PIES scheduling.To address these issues,this paper introduces a low-carbon dispatch strategy that combines a reward-penalty tiered carbon trading model with P2G-CCS integration,hydrogen utilization,and the Secretary Bird Optimization Algorithm(SBOA).Key innovations include:(1)A dynamic reward-penalty carbon trading mechanism with coefficients(μ=0.2,λ=0.15),which reduces carbon trading costs by 47.2%(from$694.06 to$366.32)compared to traditional tiered models,incentivizing voluntary emission reductions.(2)The integration of P2G-CCS coupling,which lowers natural gas consumption by 41.9%(from$4117.20 to$2389.23)and enhances CO_(2) recycling efficiency,addressing the limitations of standalone P2G or CCS technologies.(3)TheSBOA algorithm,which outperforms traditionalmethods(e.g.,PSO,GWO)in convergence speed and global search capability,avoiding local optima and achieving 24.39%faster convergence on CEC2005 benchmark functions.(4)A four-energy PIES framework incorporating electricity,heat,gas,and hydrogen,where hydrogen fuel cells and CHP systems improve demand response flexibility,reducing gas-related emissions by 42.1%and generating$13.14 in demand response revenue.Case studies across five scenarios demonstrate the strategy’s effectiveness:total operational costs decrease by 14.7%(from$7354.64 to$6272.59),carbon emissions drop by 49.9%(from 5294.94 to 2653.39kg),andrenewable energyutilizationincreases by24.39%(from4.82%to8.17%).These results affirmthemodel’s ability to reconcile economic and environmental goals,providing a scalable approach for low-carbon transitions in industrial parks.展开更多
The reduction of carbon emissions in the steel industry is a significant challenge,and utilizing CO_(2) from carbon intensive steel industry off-gases for methanol production is a promising strategy for decarbonizatio...The reduction of carbon emissions in the steel industry is a significant challenge,and utilizing CO_(2) from carbon intensive steel industry off-gases for methanol production is a promising strategy for decarbonization.However,steelwork off-gases typically contain various impurities,including H_(2)S,which can deactivate commercial methanol synthesis catalysts,Cu/ZnO/Al_(2)O_(3)(CZA).Reverse water-gas shift(RWGS)reaction is the predominant side reaction in CO_(2) hydrogenation to methanol which can occur at ambient pressure,enabling the decouple of RWGS from methanol production at high pressure.Then,a series of activated CZA catalysts has been in-situ pretreated in 400 ppm H_(2)S/Ar at 250℃and tested for both RWGS reaction at ambient pressure and CO_(2) hydrogenation to methanol at high pressure.An innovative decoupling strategy was employed to isolate the RWGS reaction from the methanol synthesis process,enabling the investigation of the evolution of active site structures and the poisoning mechanism through elemental analysis,X-ray Diffraction,X-ray Photoelectron Spectroscopy,Fourier Transform Infrared Spectroscopy,Temperature Programmed Reduction and CO_(2) Temperature Programmed Desorption.The results indicate that there are different dynamic migration behaviors of ZnO_(x) in the two reaction systems,leading to different poisoning mechanisms.These interesting findings are beneficial to develop sulfur resistant and durable highly efficient catalysts for CO_(2) hydrogenation to methanol,promoting the carbon emission reduction in steel industry.展开更多
基金supported by the National Natural Science Foundation of China (No. 51522601)Chang Jiang Young Scholars Program of China (Q2016186)the Fok Ying Tong Education Foundation of China (No. 141055)
文摘In this study, the solar thermochemical reactor performance for CO_2 utilization into synthesis gas(H_2+ CO) based on CH_4 reforming process was investigated in the context of carbon capture and utilization(CCU) technologies. The P1 radiation heat transfer model is adopted to establish the heat and mass transfer model coupled with thermochemical reaction kinetics. The reactor thermal behavior with direct heat transfer between gaseous reactant and products evolution and the effects of different structural parameters were evaluated. It was found that the reactor has the potential to utilize by ～60% of CO_2 captured with 40% of CH_4 co-fed into syngas(72.9% of H_2 and 27.1% of CO) at 741.31 k W/mof incident radiation heat flux. However, the solar irradiance heat flux and temperature distribution were found to significantly affect the reactant species conversion efficiency and syngas production. The chemical reaction is mainly driven by the thermal energy and higher species conversion into syngas was observed when the temperature distribution at the inner cavity of the reactor was more uniform. Designed a solar thermochemical reactor able to volumetric store concentrated irradiance could highly improve CCU technologies for producing energy-rich chemicals. Besides, the mixture gas inlet velocity, operating pressure and CO_2/CH_4 feeding ratio were crucial to determining the efficiency of CO_2 utilization to solar fuels. Catalytic CO_2-reforming of CH_4 to chemical energy is a promising strategy for an efficient utilization of CO_2 as a renewable carbon source.
文摘Reducing the anthropogenic COemissions from fossil resource combustion and human activities has become one of the major challenges we are facing today.Beyond those practical applications for the utilization of CO,such as the synthesis of salicylic acid,methanol,urea,NaHCO-NaCOchemicals and recently developed polycarbonate synthesis,scientists are still seeking new materials and technologies for efficient capture,
基金support from the National Key Research and Development Program of China(2023YFE0120700)National Natural Science Foundation of China(52274041)Distinguished Young Sichuan Science Scholars(2023NSFSC1954).
文摘Cyclic injection holds great potential for CO_(2) emission reduction coupled with enhanced unconventional oil recovery.There is,however,a lack of a thorough understanding of carbon distribution,migration,and transformation underground over time at the reservoir scale.To address this issue,we conducted a rig-orous numerical simulation integrating microseismic events,multi-geomechanics,and multi-geochemistry to represent the complex fracture geometry,rock stress sensitivity,and CO_(2)-oil-brine-rock interactions.The fluid model,reservoir model,and geochemical reaction kinetics were carefully validated and calibrated using experimental data.The performance of CO_(2) utilization and geological storage was comprehensively investigated in terms of changes in oil production,CO_(2) storage,carbon distribution,and petrophysical properties.The results indicate that 48.3%of the injected CO_(2) was stored stably under-ground after ten cycles(ten years),with a 3.4%increase in oil recovery.The presence of multiple CO_(2) stor-age forms,such as dissolved in water and mineralized carbonate,impeded CO_(2)-oil interaction,leading to a 25.9%reduction in the volume of the CO_(2)-oil mixing zone and a 2.2%decrease in cumulative oil pro-duction,albeit with a 7.7%increase in the storage rate.The cyclic injection mode had a significant impact on the migration and transformation of CO_(2) in the reservoir.While dissolved CO_(2) in oil accounted for over half of the total storage,it had the possibility of being released during production.After ten cycles,20%of the injected CO_(2)(approximately 12000 t)reached long-term storage in four forms:mineralized carbon-ate(6%),water-dissolved CO_(2)(6%),aqueous ions(4%),and trapped gas(4%).Notably,the non-fracture zone within the stimulated reservoir volume(SRV)served as the primary trapping area for residual gas.This work provides valuable insights into dynamic CO_(2) transport and transformation processes under cyclic injection and presents a more comprehensive and precise framework for assessing CO_(2) capture,utilization,and storage with enhanced oil recovery(CCUS-EOR)performance in unconventional reser-voirs after fracturing.
基金supported by the China Postdoctoral Science Foundation(No.2024M752803)the National Natural Science Foundation of China(No.52179112)the Open Fund of National Key Laboratory of Oil and Gas Reservoir Geology and Exploitation(Southwest Petroleum University)(No.PLN2023-02)。
文摘Geological storage and utilization of CO_(2)involve complex interactions among Thermo-hydromechanical-chemical(THMC)coupling processes,which significantly affect storage integrity and efficiency.To address the challenges in accurately simulating these coupled phenomena,this paper systematically reviews recent advances in the mathematical modeling and numerical solution of THMC coupling in CO_(2)geological storage.The study focuses on the derivation and structure of governing and constitutive equations,the classification and comparative performance of fully coupled,iteratively coupled,and explicitly coupled solution methods,and the modeling of dynamic changes in porosity,permeability,and fracture evolution induced by multi-field interactions.Furthermore,the paper evaluates the capabilities,application scenarios,and limitations of major simulation platforms,including TOUGH,CMG-GEM,and COMSOL.By establishing a comparative framework integrating model formulations and solver strategies,this work clarifies the strengths and gaps of current approaches and contributes to the development of robust,scalable,and mechanism-oriented numerical models for long-term prediction of CO_(2)behavior in geological formations.
基金the financial support from the National Key Research and Development Program of China(2022YFE0206700)the Science Foundation of China University of Petroleum,Beijing(2462021YJRC012).
文摘Carbon capture,utilization,and storage(CCUS)represents a critical technological pathway for global car-bon emission reduction.CCUS-enhanced oil recovery(EOR)technology is the most feasible CCUS technol-ogy demonstrating dual benefits of enhanced energy production and carbon reduction.This study comprehensively described the key influencing factors governing CO_(2)-EOR and geological storage and systematically analyzed reservoir properties,fluid characteristics,and operational parameters.The mech-anisms of these parameters on EOR versus CO_(2) storage performance were investigated throughout CCUS-EOR processes.This paper proposes a coupled two-stage CCUS-EOR process:CO_(2)-EOR storage stage and long-term CO_(2) storage stage after the CO_(2) injection phase is completed.In each stage,the main control factors impacting the CO_(2)-EOR and storage stages are screened and coupled with rigorous technical anal-ysis.The key factors here are reservoir properties,fluid characteristics,and operational parameter.A novel CCUS-EOR synergistic method was proposed to optimize the lifecycle performance of dual objective of EOR and storage.Furthermore,based on multi-objective optimization,considering the lifecycle,a multi-scale techno-economic evaluation method was proposed to fully assess the CCUS-EOR project per-formance.Finally,a set of recommendations for advancing CCUS-EOR technologies by deploying multi-factor/multi-field coupling methodologies,novel green intelligent injection materials,and artificial intel-ligence/machine learning technologies were visited.
基金supported by the National Key R&D Program of China(No.2021YFA1200201)the Beijing Outstanding Young Scientists Projects(No.BJJWZYJH01201910005018)+1 种基金The Basic Science Center Program for Multiphase Evolution in Hypergravity of the National Natural Science Foundation of China(No.51988101)the National Natural Science Foundation of China(Nos.52071003 and 91860202)。
文摘The photocatalytic reduction of CO_(2)presents a promising avenue for carbon fuel conversion.However,the efficiency of charge utilization remains a critical barrier to industrial applications.In this study,we introduce a tandem design of Bi_(2)WO_(6)-BiOCl with an atomically matched interface,achieving highly efficient photoreduction of CO_(2)to CO.By incorporating WO_(4)^(2-)ions and tuning coordination environment,the(110)facet of BiOCl was in-situ grown on the(200)facet of Bi_(2)WO_(6).Compared to single phases and ball-milling samples,Bi_(2)WO_(6)-BiOCl exhibits a remarkable CO yield of 68.03μmol g^(-1)h^(-1)with a selectivity of 98%.Atomic visualization and coordination analysis confirm the formation of a coherent interface that facilitates charge migration for efficient electron transport.Density functional theory(DFT)calculations and in-situ Fourier transform infrared(FTIR)spectroscopy provide insights into the intrinsic active sites and reaction mechanisms.The proposed lattice engineering strategies offer a new paradigm for the rational design of heterostructures beyond traditional band alignment at the atomic scale.
基金funded by State Grid Beijing Electric Power Company Technology Project,grant number 520210230004.
文摘The park-level integrated energy system(PIES)is essential for achieving carbon neutrality by managing multi-energy supply and demand while enhancing renewable energy integration.However,current carbon trading mechanisms lack sufficient incentives for emission reductions,and traditional optimization algorithms often face challenges with convergence and local optima in complex PIES scheduling.To address these issues,this paper introduces a low-carbon dispatch strategy that combines a reward-penalty tiered carbon trading model with P2G-CCS integration,hydrogen utilization,and the Secretary Bird Optimization Algorithm(SBOA).Key innovations include:(1)A dynamic reward-penalty carbon trading mechanism with coefficients(μ=0.2,λ=0.15),which reduces carbon trading costs by 47.2%(from$694.06 to$366.32)compared to traditional tiered models,incentivizing voluntary emission reductions.(2)The integration of P2G-CCS coupling,which lowers natural gas consumption by 41.9%(from$4117.20 to$2389.23)and enhances CO_(2) recycling efficiency,addressing the limitations of standalone P2G or CCS technologies.(3)TheSBOA algorithm,which outperforms traditionalmethods(e.g.,PSO,GWO)in convergence speed and global search capability,avoiding local optima and achieving 24.39%faster convergence on CEC2005 benchmark functions.(4)A four-energy PIES framework incorporating electricity,heat,gas,and hydrogen,where hydrogen fuel cells and CHP systems improve demand response flexibility,reducing gas-related emissions by 42.1%and generating$13.14 in demand response revenue.Case studies across five scenarios demonstrate the strategy’s effectiveness:total operational costs decrease by 14.7%(from$7354.64 to$6272.59),carbon emissions drop by 49.9%(from 5294.94 to 2653.39kg),andrenewable energyutilizationincreases by24.39%(from4.82%to8.17%).These results affirmthemodel’s ability to reconcile economic and environmental goals,providing a scalable approach for low-carbon transitions in industrial parks.
基金supported by the National Natural Science Foundation of China(Nos.22276060 and 21976059)Guangdong Basic and Applied Basic Research Foundation(No.2024A1515012636)China Scholarship Council Scholarship(No.201906155006)。
文摘The reduction of carbon emissions in the steel industry is a significant challenge,and utilizing CO_(2) from carbon intensive steel industry off-gases for methanol production is a promising strategy for decarbonization.However,steelwork off-gases typically contain various impurities,including H_(2)S,which can deactivate commercial methanol synthesis catalysts,Cu/ZnO/Al_(2)O_(3)(CZA).Reverse water-gas shift(RWGS)reaction is the predominant side reaction in CO_(2) hydrogenation to methanol which can occur at ambient pressure,enabling the decouple of RWGS from methanol production at high pressure.Then,a series of activated CZA catalysts has been in-situ pretreated in 400 ppm H_(2)S/Ar at 250℃and tested for both RWGS reaction at ambient pressure and CO_(2) hydrogenation to methanol at high pressure.An innovative decoupling strategy was employed to isolate the RWGS reaction from the methanol synthesis process,enabling the investigation of the evolution of active site structures and the poisoning mechanism through elemental analysis,X-ray Diffraction,X-ray Photoelectron Spectroscopy,Fourier Transform Infrared Spectroscopy,Temperature Programmed Reduction and CO_(2) Temperature Programmed Desorption.The results indicate that there are different dynamic migration behaviors of ZnO_(x) in the two reaction systems,leading to different poisoning mechanisms.These interesting findings are beneficial to develop sulfur resistant and durable highly efficient catalysts for CO_(2) hydrogenation to methanol,promoting the carbon emission reduction in steel industry.
