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Coupled thermo-hydro-mechanical analysis of porous rocks:Candidate of surrounding rocks for deep geological repositories 被引量:1
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作者 Tao Meng Zaobao Liu +6 位作者 Fengbiao Wu Zhijiang Zhang Xufeng Liang Yi He Xiaomeng Wu Yizhang Yang Haoran Gao 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第5期3073-3092,共20页
Deep geological sequestration is widely recognized as a reliable method for nuclear waste management,with expanded applications in thermal energy storage and adiabatic compressed air energy storage systems.This study ... Deep geological sequestration is widely recognized as a reliable method for nuclear waste management,with expanded applications in thermal energy storage and adiabatic compressed air energy storage systems.This study evaluated the suitability of granite,basalt,and marble as reservoir rocks capable of withstanding extreme high-temperature and high-pressure conditions.Using a custom-designed triaxial testing apparatus for thermal-hydro-mechanical(THM)coupling,we subjected rock samples to temperatures ranging from 20℃to 800℃,triaxial stresses up to 25 MPa,and seepage pressures of 0.6 MPa.After THM treatment,the specimens were analyzed using a Real-Time Load-Synchronized Micro-Computed Tomography(MCT)Scanner under a triaxial stress of 25 MPa,allowing for high-resolution insights into pore and fissure responses.Our findings revealed distinct thermal stability profiles and microscopic parameter changes across three phasesdslow growth,slow decline,and rapid growthdwith critical temperature thresholds observed at 500℃for granite,600℃for basalt,and 300℃for marble.Basalt showed minimal porosity changes,increasing gradually from 3.83%at 20℃to 12.45%at 800℃,indicating high structural integrity and resilience under extreme THM conditions.Granite shows significant increases in porosity due to thermally induced microcracking,while marble rapidly deteriorated beyond 300℃due to carbonate decomposition.Consequently,basalt,with its minimal porosity variability,high thermal stability,and robust mechanical properties,emerges as an optimal candidate for nuclear waste repositories and other high-temperature geological engineering applications,offering enhanced reliability,structural stability,and long-term safety in such settings. 展开更多
关键词 Deep geological repository coupled thermal-hydro-mechanical environment Pore structure Microcomputer tomography 3D reconstruction
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Coupled Urban Risks:A Complex Systems Perspective with a People-Centric Focus 被引量:1
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作者 Min Ouyang Zekai Cheng +2 位作者 Jiaxin Ma Hongwei Wang Stergios Aristoteles Mitoulis 《Engineering》 2025年第1期44-50,共7页
The complexity of coupled risks,which refer to the compounded effects of interacting uncertainties across multiple interdependent objectives,is inherent to cities functioning as dynamic,interdependent systems.A disrup... The complexity of coupled risks,which refer to the compounded effects of interacting uncertainties across multiple interdependent objectives,is inherent to cities functioning as dynamic,interdependent systems.A disruption in one domain ripples across various urban systems,often with unforeseen consequences.Central to this complexity are people,whose behaviors,needs,and vulnerabilities shape risk evolution and response effectiveness.Realizing cities as complex systems centered on human needs and behaviors is essential to understanding the complexities of coupled urban risks.This paper adopts a complex systems perspective to examine the intricacies of coupled urban risks,emphasizing the critical role of human decisions and behavior in shaping these dynamics.We focus on two key dimensions:cascading hazards in urban environments and cascading failures across interdependent exposed systems in cities.Existing risk assessment models often fail to capture the complexity of these processes,particularly when factoring in human decision-making.To tackle these challenges,we advocate for a standardized taxonomy of cascading hazards,urban components,and their interactions.At its core is a people-centric perspective,emphasizing the bidirectional interactions between people and the systems that serve them.Building on this foundation,we argue the need for an integrated,people-centric risk assessment framework that evaluates event impacts in relation to the hierarchical needs of people and incorporates their preparedness and response capacities.By leveraging real-time data,advanced simulations,and innovative validation methods,this framework aims to enhance the accuracy of coupled urban risk modeling.To effectively manage coupled urban risks,cities can draw from proven strategies in real complex systems.However,given the escalating uncertainties and complexities associated with climate change,prioritizing people-centric strategies is crucial.This approach will empower cities to build resilience not only against known hazards but also against evolving and unforeseen challenges in an increasingly uncertain world. 展开更多
关键词 coupled urban risks People-centric Risk management
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Regional Storm Surge Forecast Method Based on a Neural Network and the Coupled ADCIRC-SWAN Model 被引量:1
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作者 Yuan SUN Po HU +2 位作者 Shuiqing LI Dongxue MO Yijun HOU 《Advances in Atmospheric Sciences》 2025年第1期129-145,共17页
Timely and accurate forecasting of storm surges can effectively prevent typhoon storm surges from causing large economic losses and casualties in coastal areas.At present,numerical model forecasting consumes too many ... Timely and accurate forecasting of storm surges can effectively prevent typhoon storm surges from causing large economic losses and casualties in coastal areas.At present,numerical model forecasting consumes too many resources and takes too long to compute,while neural network forecasting lacks regional data to train regional forecasting models.In this study,we used the DUAL wind model to build typhoon wind fields,and constructed a typhoon database of 75 processes in the northern South China Sea using the coupled Advanced Circulation-Simulating Waves Nearshore(ADCIRC-SWAN)model.Then,a neural network with a Res-U-Net structure was trained using the typhoon database to forecast the typhoon processes in the validation dataset,and an excellent storm surge forecasting effect was achieved in the Pearl River Estuary region.The storm surge forecasting effect of stronger typhoons was improved by adding a branch structure and transfer learning. 展开更多
关键词 regional storm surge forecast coupled ADCIRC-SWAN model neural network Res-U-Net structure
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Soliton Solutions of a Coupled KdV System via Backlund Transformation
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作者 CAO Xifang WU Yiheng +2 位作者 LU Yi XU Wenjing XIA Yutong 《应用数学》 北大核心 2025年第1期211-216,共6页
In this paper we use Böcklund transformation to construct soliton solutions for a coupled KdV system.This system was first proposed by Wang in 2010.First we generalize the well-known Bäcklund transformation ... In this paper we use Böcklund transformation to construct soliton solutions for a coupled KdV system.This system was first proposed by Wang in 2010.First we generalize the well-known Bäcklund transformation for the KdV equation to such coupled KdV system.Then from a trivial seed solution,we construct soliton solutions.We also give a nonlinear superposition formula,which allows us to generate multi-soliton solutions. 展开更多
关键词 KdV equation coupled KdV system B¨acklund transformation SOLITON
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Experimental study on coupled caloric effect driven by dual fields in metamagnetic alloy ErCo_(2)
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作者 Liming Wu Bingjie Wang +11 位作者 Fengxia Hu Zhaojun Mo Houbo Zhou Zhengying Tian Yangyang Fan Zhuo Yin Zibing Yu Jing Wang Yunzhong Chen Jirong Sun Tongyun Zhao Baogen Shen 《Journal of Rare Earths》 2025年第4期752-757,I0005,共7页
This study presents an experimental investigation of the coupled caloric effect driven by dual-fields in metamagnetic alloy ErCo_(2) with strong magneto-structural coupling.Magnetic measurements were conducted under d... This study presents an experimental investigation of the coupled caloric effect driven by dual-fields in metamagnetic alloy ErCo_(2) with strong magneto-structural coupling.Magnetic measurements were conducted under different pressures,revealing that the application of hydrostatic pressure stabilizes a small volume of paramagnetism(PM) phase,resulting in a shift of the phase transition temperature towards the low-temperature region.This shift is opposite to the temperature associated with the magnetic field-driven phase transition.As pressure increases,the metamagnetic transition in ErCo_(2) is suppressed,and the hysteresis disappears.However,the produced cross-coupling caloric effect compensates the decrease in entropy change caused by the disappearance of the metamagnetic transition.As a result,a reversible giant magnetocaloric effect of 46.2 J/(kg·K) without hysteresis is achieved at a pressure of 0.910 GPa.Moreover,we propose that the temperature span of ErCo_(2) can be significantly widened by optimizing the thermodynamic pathway of the magnetic and pressure fields,overcoming the defect of a narrow temperature range. 展开更多
关键词 Rare earths Magnetocaloric materials coupled caloric effect Metamagnetic behavior Dual fields Magnetic-structure coupling
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A granular thermodynamic framework-based coupled multiphasesubstance flow model considering temperature driving effect
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作者 Bing Bai Haiyan Wu +2 位作者 Rui Zhou Nan Wu Bixia Zhang 《Journal of Rock Mechanics and Geotechnical Engineering》 2025年第9期5816-5828,共13页
Based on the energy dissipation caused by consolidation deformation of the porous media under external force and migration of the internal suspended substances,a coupled multiphase-substance flow(CMF)model was establi... Based on the energy dissipation caused by consolidation deformation of the porous media under external force and migration of the internal suspended substances,a coupled multiphase-substance flow(CMF)model was established.This model introduced the new concepts,such as particle temperature and particle entropy,to describe energy dissipation at meso-level.This model used a potential energy density function and migration coefficients to establish the corresponding connection between the dissipative force and dissipative flow.This viewpoint unifies the deformation,seepage,and suspended substance migration of geotechnical materials under the framework of granular thermodynamics.It can reflect the evolution of effective stress in the solid matrix of multi-components in a particle-reorganized state,and considers the temperature driving effect.The proposed CMF model is validated using the experimental results under coupled migration of heavy metal ions(HMs)and suspended particles(SPs).The calculation results demonstrated that the CMF model can describe the flow process under the conditions of arbitrary changes in different suspended substance types,injection concentrations,and injection velocities. 展开更多
关键词 GROUNDWATER Granular thermodynamics Multiphase substance coupled migration Consolidation deformation
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Turing instability-induced oscillations in coupled reaction-diffusion systems
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作者 Nan Wang Yuan Tong +3 位作者 Fucheng Liu Xiaoxuan Li Yafeng He Weili Fan 《Chinese Physics B》 2025年第3期541-548,共8页
A new type of localized oscillatory pattern is presented in a two-layer coupled reaction-diffusion system under conditions in which no Hopf instability can be discerned in either layer.The transitions from stationary ... A new type of localized oscillatory pattern is presented in a two-layer coupled reaction-diffusion system under conditions in which no Hopf instability can be discerned in either layer.The transitions from stationary patterns to asynchronous and synchronous oscillatory patterns are obtained.A novel method based on decomposing coupled systems into two associated subsystems has been proposed to elucidate the mechanism of formation of oscillating patterns.Linear stability analysis of the associated subsystems reveals that the Turing pattern in one layer induces the other layer locally,undergoes a supercritical Hopf bifurcation and gives rise to localized oscillations.It is found that the sizes and positions of oscillations are determined by the spatial distribution of the Turing patterns.When the size is large,localized traveling waves such as spirals and targets emerge.These results may be useful for deeper understanding of pattern formation in complex systems,particularly multilayered systems. 展开更多
关键词 OSCILLATIONS localized oscillatory pattern Turing instability coupled reaction-diffusion system
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O-band low loss and polarization insensitivity bilayer and double-tip edge coupler
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作者 Yuanjian Wan Yu Zhang Jian Wang 《Advanced Photonics Nexus》 2025年第2期31-38,共8页
Edge couplers,widely recognized for their efficiency and broad bandwidth,have gained significant attention as optical fiber-to-chip couplers.Silicon waveguides exhibit strong birefringence properties,resulting in subs... Edge couplers,widely recognized for their efficiency and broad bandwidth,have gained significant attention as optical fiber-to-chip couplers.Silicon waveguides exhibit strong birefringence properties,resulting in substantial polarization-dependent loss for edge couplers in the O-band.We introduce a bilayer and double-tip edge coupler designed to efficiently couple both transverse electric(TE)and transverse magnetic(TM)modes while maintaining compatibility with standard manufacturing processes used in commercial silicon photonics foundries.We have successfully designed and fabricated this edge coupler,achieving coupling losses of<1.52 dB∕facet for TE mode and 2 dB∕facet for TM mode when coupled with a lensed optical fiber[4-μmmode field diameter(MFD)]within the wavelength range of 1260 to 1360 nm. 展开更多
关键词 edge coupler integrated photonics optical fiber-to-chip coupling O-band optical communication
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Coupled Hydrodynamics and FEM Simulation of Catamaran Pontoon
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作者 Ocid Mursid Karno Malau +5 位作者 Hartono Yudo Tuswan Muhammad Luqman Hakim Ahmad Firdhaus Andi Trimulyono Muhammad Iqbal 《China Ocean Engineering》 2025年第1期179-189,共11页
Shallow water infrastructure needs to support increased activity on the shores of Semarang.This study chooses several pontoons because of their good stability,rolling motion,and more expansive space.A coupled simulati... Shallow water infrastructure needs to support increased activity on the shores of Semarang.This study chooses several pontoons because of their good stability,rolling motion,and more expansive space.A coupled simulation method consisting of hydrodynamic and structural calculations has been used to evaluate a catamaran pontoon’s motion and structural integrity.Four different space sizes are set for the pontoon system:5 m,5.5 m,6 m,and 6.5 m.The frequency domain shows that the pontoon space affects the RAO in wave periods ranging from 3 s to 5 s.At wave periods of 3 s,4 s,and 5 s,the pontoon space significantly affects the maximum motion and chain tension parameter values,which are evaluated via time domain simulation.The critical stress of the pontoon is shown at a wave period of 5 s for 5 m and 5.5 m of pontoon space,which shows that the stress can reach 248 MPa. 展开更多
关键词 coupled simulation working pontoon HYDRODYNAMICS finite element method
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Coupled aeroelastic analysis of a panel in supersonic flow with add-on acoustic black hole
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作者 Zhuogeng ZHANG Hongli JI +2 位作者 Jinhao QIU Kaihua YUAN Li CHENG 《Chinese Journal of Aeronautics》 2025年第5期121-133,共13页
This study introduces a novel approach for coupled aeroelastic analysis of panel subjected to supersonic airflow,utilizing Add-On Acoustic Black Hole(AABH)to mitigate panel flutter.Employing Galerkin's method to d... This study introduces a novel approach for coupled aeroelastic analysis of panel subjected to supersonic airflow,utilizing Add-On Acoustic Black Hole(AABH)to mitigate panel flutter.Employing Galerkin's method to discretize aeroelastic equation of panel and leveraging finite element method to derive a reduced discrete model of AABH,this study effectively couples two substructures via interface displacement.Investigation into the interactive force highlights the modal effective mass,frequency discrepancy between oscillation and AABH mode,and modal damping ratio as critical factors influencing individual AABH mode in flutter suppression.The selection of effective AABH modes,closely linked to these factors,directly influences the accuracy of simulations.The results reveal that AABH notably enhances the panel's critical flutter boundary by14.6%,a significant improvement over the 3.6%increase afforded by equivalent mass.Furthermore,AABH outperforms both the tuned mass damper and nonlinear energy sink in flutter suppression efficacy.By adjusting the AABH's geometrical parameters to increase the accumulative modal effective mass within the pertinent frequency range,or choosing a suitable installation position for AABH,its performance in flutter suppression is further optimized.These findings not only underscore the AABH's potential in enhancing aeroelastic stability but also provide a foundation for its optimal design. 展开更多
关键词 Panel flutter Acoustic black hole Flutter suppression coupled analysis Aeroelastic
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Multi-component decompositions,linear superpositions,and new nonlinear integrable coupled KdV-type systems
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作者 Xiazhi Hao S Y Lou 《Communications in Theoretical Physics》 2025年第2期1-12,共12页
In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrabilit... In the realm of nonlinear integrable systems,the presence of decompositions facilitates the establishment of linear superposition solutions and the derivation of novel coupled systems exhibiting nonlinear integrability.By focusing on single-component decompositions within the potential BKP hierarchy,it has been observed that specific linear superpositions of decomposition solutions remain consistent with the underlying equations.Moreover,through the implementation of multi-component decompositions within the potential BKP hierarchy,successful endeavors have been undertaken to formulate linear superposition solutions and novel coupled Kd V-type systems that resist decoupling via alterations in dependent variables. 展开更多
关键词 integrable system single-component decomposition multi-component decomposition linear superposition integrable coupled KdV-type system
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Non-planar vibration characteristics and buckling behaviors of two fluid-conveying pipes coupled with an intermediate spring
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作者 Dali WANG Tianli JIANG +1 位作者 Huliang DAI Lin WANG 《Applied Mathematics and Mechanics(English Edition)》 2025年第10期1829-1850,共22页
This study investigates the dynamical behavior of two parallel fluid-conveying pipes by developing a non-planar dynamical model of the two pipes coupled with an intermediate spring. A systematic analysis is conducted ... This study investigates the dynamical behavior of two parallel fluid-conveying pipes by developing a non-planar dynamical model of the two pipes coupled with an intermediate spring. A systematic analysis is conducted to evaluate the effects of spring parameters on the non-planar vibration characteristics and buckling behaviors of the coupled system. The nonlinear governing equations are derived with Hamilton's principle,subsequently discretized through Galerkin's method, and finally numerically solved by the Runge-Kutta algorithm. Based on the linearized equations, an eigenvalue analysis is performed to obtain the coupled frequencies, modal shapes, and critical flow velocities for buckling instability. Quantitative assessments further elucidate the effects of the spring position and stiffness coefficient on the coupled frequencies and critical flow velocities.Nonlinear dynamic analyses reveal the evolution of buckling patterns and bifurcation behaviors between the lateral displacements of the two pipes and the flow velocity. Numerical results indicate that the intermediate spring increases the susceptibility to buckling instability in the out-of-plane direction compared with the in-plane direction. Furthermore, synchronized lateral displacements emerge in both pipes when the flow velocity of one pipe exceeds the critical threshold. This work is expected to provide a theoretical foundation for the stability assessment and vibration analysis in coupled fluid-conveying pipe systems. 展开更多
关键词 coupled fluid-conveying pipe system intermediate spring non-planar vibration buckling behavior
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Acidic-thermal coupled degradation of tylosin by using magnetic sulfonated resins under microwave irradiation
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作者 Caitiao Fang Wei Zhang +3 位作者 Chunmei Wang Shiling Li Xiaomin Dou Jun Liu 《Journal of Environmental Sciences》 2025年第9期127-138,共12页
Acidic-and alkalic-hydrolyses are selective in breaking functional bonds and falling off pharmacological moieties of antibiotics in production wastewater in comparison with advanced oxidation processes.Elevating tempe... Acidic-and alkalic-hydrolyses are selective in breaking functional bonds and falling off pharmacological moieties of antibiotics in production wastewater in comparison with advanced oxidation processes.Elevating temperature can accelerate hydrolytic kinetics and improve efficiency.In this work,magnetic sulfonated polypropylene resin(Fe_(3)O_(4)@PS-S)composites were reported for acidic-thermal hydrolysis of tylosin by employing the acidic feature of sulfonic group,the dielectric effect of resin,and the magnetic-loss effect of magnetite under microwave irradiation.As observed,a rapid and complete mitigation 100 mg/L of tylosin was achieved within 15 min by the catalysts.Acidic cleavage of tylosin was fulfilled by sulfonic groups in the composites,and microwave thermal accelerated the hydrolysis reactions due to the dielectric and magnetic-loss effects.Differentiating the dielectric and magnetic-loss effects through electromagnetic analyses indicated that the latter contributed more in converting microwave energy to heat.The interactions under multiple operational conditions were quantitatively fitted using the Behnajady model and visually demonstrated,which indicated that a synergic effect of microwave thermal-and acidichydrolyses contributed to the efficient mitigation of tylosin.The transformation products were identified and the pathways were supposed.Cleaving deoxyaminosugars groups and destructing lactone structures led to reduced antibacterial potential and toxicity reduction.The acute toxicity of tylosin and transformation products to fish,daphnia,and green algae were all classified as non-toxic.This work suggested that this synergistic acid-thermal hydrolytic method is attractive and promising in pretreating tylosin production wastewater in field. 展开更多
关键词 Acidic-thermal coupled hydrolysis Tylosin degradation Microwave irradiation Synergetic effects Sulfonated resins
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Iterative solution and numerical analysis of vehicle-track-bridge nonlinear coupled vibration considering viscoelasticity of rail pads
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作者 CUI Wei-tao GAO Liang +3 位作者 XIAO Hong MIAO Shuai-jie NIU Zhen-yu XIAO Yi-xiong 《Journal of Central South University》 2025年第7期2750-2765,共16页
To investigate the effect of rail pad viscoelasticity on vehicle-track-bridge coupled vibration,the fractional Voigt and Maxwell model in parallel(FVMP)was used to characterize the viscoelastic properties of the rail ... To investigate the effect of rail pad viscoelasticity on vehicle-track-bridge coupled vibration,the fractional Voigt and Maxwell model in parallel(FVMP)was used to characterize the viscoelastic properties of the rail pad based on dynamic performance test results.The FVMP model was then incorporated into the vehicle-track-bridge nonlinear coupled model,and its dynamic response was solved using a cross-iteration algorithm with a relaxation factor.Results indicate that the nonlinear coupled model achieves good convergence when the time step is less than 0.001 s,with the cross-iteration algorithm adjusting the wheel-rail force.In particular,the best convergence is achieved when the relaxation factor is within the range of 0.3-0.5.The FVMP model effectively characterizes the viscoelasticity of rail pads across a temperature range of±20℃and a frequency range of 1-1000 Hz.The viscoelasticity of rail pads significantly affects high-frequency vibrations in the coupled system,particularly around 50 Hz,corresponding to the wheel-rail coupled resonance range.Considering rail pad viscoelasticity is essential for accurately predicting track structure vibrations. 展开更多
关键词 high-speed railway rail pads fractional derivative vehicle-track-bridge coupled model iterative algorithm
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A deep residual intelligent model for ENSO prediction by incorporating coupled model forecast data
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作者 Chunyang Song Xuefeng Zhang +3 位作者 Xingrong Chen Hua Jiang Liang Zhang Yongyong Huang 《Acta Oceanologica Sinica》 2025年第8期133-142,共10页
The El Niño-Southern Oscillation(ENSO)is a naturally recurring interannual climate fluctuation that affects the global climate system.The advent of deep learning-based approaches has led to transformative changes... The El Niño-Southern Oscillation(ENSO)is a naturally recurring interannual climate fluctuation that affects the global climate system.The advent of deep learning-based approaches has led to transformative changes in ENSO forecasts,resulting in significant progress.Most deep learning-based ENSO prediction models which primarily rely solely on reanalysis data may lead to challenges in intensity underestimation in long-term forecasts,reducing the forecasting skills.To this end,we propose a deep residual-coupled model prediction(Res-CMP)model,which integrates historical reanalysis data and coupled model forecast data for multiyear ENSO prediction.The Res-CMP model is designed as a lightweight model that leverages only short-term reanalysis data and nudging assimilation prediction results of the Community Earth System Model(CESM)for effective prediction of the Niño 3.4 index.We also developed a transfer learning strategy for this model to overcome the limitations of inadequate forecast data.After determining the optimal configuration,which included selecting a suitable transfer learning rate during training,along with input variables and CESM forecast lengths,Res-CMP demonstrated a high correlation ability for 19-month lead time predictions(correlation coefficients exceeding 0.5).The Res-CMP model also alleviated the spring predictability barrier(SPB).When validated against actual ENSO events,Res-CMP successfully captured the temporal evolution of the Niño 3.4 index during La Niña events(1998/99 and 2020/21)and El Niño events(2009/10 and 2015/16).Our proposed model has the potential to further enhance ENSO prediction performance by using coupled models to assist deep learning methods. 展开更多
关键词 ENSO prediction deep learning dynamical coupled model data incorporating
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Coupled Dissolution-Precipitation Mineralized Process in Bailongshan Li Deposit,West Kunlun(NW China),Evidenced by the Mineralogy of Cassiterite,Columbite-Group Minerals and Elbaite
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作者 Tao Hong ZhangZhang +2 位作者 Zeli Jiang Mingxi Hu Pengli Jiao 《Journal of Earth Science》 2025年第3期1033-1050,共18页
Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases a... Coupled dissolution-precipitation is one of the critical processes influencing the mineralogical and geochemical evolution of pegmatites.This mechanism involves the simultaneous dissolution of primary mineral phases and the precipitation of secondary phases,driven by changes in the chemical environment,often mediated by hydrothermal fluids.The Bailongshan Li deposit,located in the West Kunlun region of northwest China,is a significant geological formation known for its rich lithium content and associated rare metals such as tantalum,niobium,and tin.This study investigates the coupled dissolution-precipitation processes that have played a crucial role in the mineralization of this deposit,focusing on key minerals,including cassiterite(Cst),columbite-group minerals(CGM),and elbaite(Elb).Using a combination of petrographic analysis,back-scattered electron(BSE)imaging,cathodoluminescence(CL)imaging,and micro X-ray fluorescence(XRF)mapping,we examined the textural and chemical characteristics of these minerals.Our findings reveal intricate patchy zoning patterns and element distributions(indicated by the Nb,Ta,W,Mn,Fe,Hf,Ti for CGM;Hf,Ti Rb,W,Nb,Ta for Cst;Ti,Zn,Fe,W,Hf,Mn,K for Elb)that indicate multiple stages of mineral alteration driven by fluid-mediated processes.The coupled dissolution-precipitation mechanisms observed in the Bailongshan deposit have resulted in significant redistribution and enrichment of economically valuable elements.The study highlights the importance of hydrothermal fluids in altering primary mineral phases and precipitating secondary phases with distinct compositions.These processes not only modified the mineralogical makeup of the pegmatite but also enhanced its economic potential by concentrating rare metals.Signatures of coupled dissolutionprecipitation processes can serve as an essential tool for mineral exploration,guiding the search for high-grade zones within similar pegmatitic formations. 展开更多
关键词 coupled dissolution-precipitation mineralized process West Kunlun MINERALOGY pegmatite Li deposit ore deposits
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Mechanical properties and failure mechanisms of coarse carbonaceous mudstone particles as highway embankment filler under coupled temperature-moisture conditions
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作者 ZENG Ling LUO Jintao +7 位作者 ZHANG Hongri GAO Qianfeng BIAN Hanbing LI Junyan ZHANG Guangming YU Huicong SONG Jianping LI Youjun 《Journal of Mountain Science》 2025年第10期3818-3834,共17页
Carbonaceous mudstone is a potential embankment filler in mountainous regions with limited high-quality materials;however,its engineering performance in highway embankments under complex environmental conditions remai... Carbonaceous mudstone is a potential embankment filler in mountainous regions with limited high-quality materials;however,its engineering performance in highway embankments under complex environmental conditions remains poorly understood.This study aimed to investigate the mechanical properties and failure mechanisms of carbonaceous mudstone filler under different temperature-moisture coupled conditions.Triaxial shear tests were conducted under four temperaturemoisture coupled conditions:dry-heat to dry-cold(DHDC),wet-cold to wet-heat(WCWH),dry-cold to wet-heat(DCWH),and dry-heat to wet-cold(DHWC).The effects of these conditions on the strength characteristics,relative breakage ratio,failure mode,and microscopic morphology were examined.A segmented prediction model based on the DuncanChang model was applied to validate the experimental results under the DHWC condition.The failure mechanisms under different conditions were also analyzed.The results indicate that the degradation of carbonaceous mudstone increases in the following order:DHDC,WCWH,DCWH,and DHWC.Under the DHDC condition,the stress-strain curves exhibit strain-softening behavior,while other conditions show strain-hardening behavior,with peak deviatoric stress occurring at 2%and 4%axial strains,respectively.The shear strength decreases by up to 40%under the DHWC condition but remains nearly unchanged under the DHDC condition,showing a positive correlation with particle breakage.As the number of cycles increases,the failure surfaces gradually move downward.Higher confining pressure shifts failure mode from shear failure to shear slip or localized compression,and eventually to overall compression or expansion failure.The modified Duncan-Chang model accurately predicts the experimental results.These findings provide important guidance for the application of carbonaceous mudstone filler in highway embankment construction in humid mountainous regions. 展开更多
关键词 Carbonaceous mudstone Temperature-moisture coupled conditions Mechanical properties Particle breakage Modified Duncan-Chang model
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Visible-light-induced ring-opening cross-coupling of cycloalcohols with vinylazaarenes and enones viaβ-C-C scission enabled by proton-coupled electron transfer
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作者 Qinghong Zhang Qiao Zhao +7 位作者 Xiaodi Wu Li Wang Kairui Shen Yuchen Hua Cheng Gao Yu Zhang Mei Peng Kai Zhao 《Chinese Chemical Letters》 2025年第2期372-377,共6页
Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,p... Pyridyl-based ketones and 1,6-diketones are both attractive and invaluable scaffolds which play pivotal roles in the construction and structural modification of a plethora of synthetically paramount natural products,pharmaceuticals,organic materials and fine chemicals.In this context,we herein demonstrate an unprecedented,robust and generally applicable synthetically strategy to deliver these two crucial ketone frameworks via visible-light-induced ring-opening coupling reactions of cycloalcohols with vinylazaarenes and enones,respectively.A plausible mechanism involves the selectiveβ-C-C bond cleavage of cycloalcohols enabled by proton-coupled electron transfer and ensuing Giese-type addition followed by single electron reduction and protonation.The synthetic methodology exhibits broad substrate scope,excellent functional group compatibility as well as operational simplicity and environmental friendliness. 展开更多
关键词 Pyridyl-based ketone 1 6-Diketone Proton-coupled electron transfer C-C Bond cleavage Ring-opening coupling
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The N-soliton solutions of the three-component coupled nonlinear Hirota equations based on Riemann-Hilbert method
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作者 Xin Wang Zhi-Hui Zhang 《Chinese Physics B》 2025年第9期10-20,共11页
In order to more accurately and effectively consider the propagation process of solitons in electromagnetic pulse waves and make full use of wavelength division multiplexing,we study a class of high-order three-compon... In order to more accurately and effectively consider the propagation process of solitons in electromagnetic pulse waves and make full use of wavelength division multiplexing,we study a class of high-order three-component Hirota equations by the Riemann-Hilbert method.Under zero boundary conditions and given initial conditions q_(j)(x,0),the N-soliton solutions of the equations are obtained by constructing and solving Riemann-Hilbert problems based on matrix spectral problem.Specifically,we discuss the cases of N=1,2,analyze the dynamical properties of 1-soliton and 2-soliton solutions through numerical simulations,and summarize the effect of integrable perturbations and spectral parameters on soliton motion. 展开更多
关键词 coupled Hirota equation soliton solutions Riemann-Hilbert problem matrix spectral problem
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Four-wave mixing Bragg scattering for small frequency shift from silicon coupled microrings
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作者 Chang Zhao Chao Wu +5 位作者 Pingyu Zhu Yuxing Du Yan Wang Miaomiao Yu Kaikai Zhang Ping Xu 《Chinese Physics B》 2025年第1期351-355,共5页
Frequency conversion is pivotal in nonlinear optics and quantum optics for manipulating and translating light signals across different wavelength regimes.Achieving frequency conversion between two light beams with a s... Frequency conversion is pivotal in nonlinear optics and quantum optics for manipulating and translating light signals across different wavelength regimes.Achieving frequency conversion between two light beams with a small frequency interval is a central challenge.In this work,we design a pair of coupled silicon microrings wherein coupled-induced modesplitting exists to achieve a small frequency shift by the process of four-wave mixing Bragg scattering.As an example,the signal can be up or down converted to the idler which is 15.5 GHz spaced when two pumps align with another pair of split resonances.The results unveil the potential of coupled microring resonators for small interval frequency conversion in a high-fidelity,all-optical,and signal processing quantum frequency interface. 展开更多
关键词 four-wave mixing Bragg scattering silicon coupled microrings
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