The effects of peptides,amino acids and organic bases as an axial ligand on reaction ac- tivities in the electrocarboxylation of benzyl chloride with CO_2 catalyzed by CoTPP are reported. The imidazole organic base,pe...The effects of peptides,amino acids and organic bases as an axial ligand on reaction ac- tivities in the electrocarboxylation of benzyl chloride with CO_2 catalyzed by CoTPP are reported. The imidazole organic base,peptide containing —SH and amino acid containing imidazolyl en- hance the catalytic activity.The effect of imidazole amounts on the catalytic activity of CoTPP is studied.展开更多
A novel electrochromic display composed of polymeric solid electrolyte and ferroin electroactive species has been assembled, which presents a reversible variation of the color between light blue and red when a potenti...A novel electrochromic display composed of polymeric solid electrolyte and ferroin electroactive species has been assembled, which presents a reversible variation of the color between light blue and red when a potential of 0.98 and 0.75 V is applied respectively. The results indicate that the response speed is increased by lowering the concentration of ferroin without decreasing color contrast.展开更多
文摘The effects of peptides,amino acids and organic bases as an axial ligand on reaction ac- tivities in the electrocarboxylation of benzyl chloride with CO_2 catalyzed by CoTPP are reported. The imidazole organic base,peptide containing —SH and amino acid containing imidazolyl en- hance the catalytic activity.The effect of imidazole amounts on the catalytic activity of CoTPP is studied.
文摘A novel electrochromic display composed of polymeric solid electrolyte and ferroin electroactive species has been assembled, which presents a reversible variation of the color between light blue and red when a potential of 0.98 and 0.75 V is applied respectively. The results indicate that the response speed is increased by lowering the concentration of ferroin without decreasing color contrast.