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Mathematical simulation of hot metal desulfurization during KR process coupled with an unreacted core model 被引量:12
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作者 Yanyu Zhao Wei Chen +1 位作者 Shusen Cheng Lifeng Zhang 《International Journal of Minerals,Metallurgy and Materials》 SCIE EI CAS CSCD 2022年第4期758-766,共9页
A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulen... A three-dimensional mathematical model was established to predict the multiphase flow,motion and dispersion of desulfurizer particles,and desulfurization of hot metal during the Kanbara reactor(KR)process.The turbulent kinetic energy-turbulent dissipation rate(k-ε)turbulence model,volume-of-fluid multiphase model,discrete-phase model,and unreacted core model for the reaction between the hot metal and particles were coupled.The measured sulfur content of the hot metal with time during the actual KR process was employed to validate the current mathematical model.The distance from the lowest point of the liquid level to the bottom of the ladle decreased from 3170 to2191 mm when the rotation speed increased from 30 to 110 r/min,which had a great effect on the dispersion of desulfurizer particles.The critical rotation speed for the vortex to reach the upper edge of the stirring impeller was 70 r/min when the immersion depth was 1500 mm.The desulfurization rate increased with the increase in the impeller rotation speed,whereas the influence of the immersion depth was relatively small.Formulas for different rotation parameters on the desulfurization rate constant and turbulent energy dissipation rate were proposed to evaluate the variation in sulfur content over time. 展开更多
关键词 DESULFURIZATION unreacted core model desulfurizer dispersion KR process fluid flow
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The Selection and Breeding of a Novel Microorganism Strain I and Investigation of Core Model Experiment for MEOR 被引量:4
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作者 ZhangZhongzhi WeiXiaofang LuoYijing LiQingzhong LeiGuanglun 《Petroleum Science》 SCIE CAS CSCD 2005年第2期95-102,共8页
This paper introduces the results of selecting and breeding a micro-organism, Strain I, and its core model experiment investigation for microbial enhanced oil recovery (MEOR). Strain I was separated from the formation... This paper introduces the results of selecting and breeding a micro-organism, Strain I, and its core model experiment investigation for microbial enhanced oil recovery (MEOR). Strain I was separated from the formation water of the Dagang oil field, with analytical results showing that Strain I is a gram-positive bacillus. A further study revealed that this strain has an excellent tolerance of environmental stresses: It can survive in conditions of 70℃, 30 wt% salinity and pH3.5-9.4. Strain I can metabolize biosurfactants that could increase the oil recovery ratio, use crude oil as the single carbon source, and decompose long-chain paraffin with a large molecular weight into short-chain paraffin with a small molecular weight. The core model experiment shows that Strain I enhances oil recovery well. Using 2 vol% of the fermentation solution of Strain I to displace the crude oil in the synthetic plastic bonding core could increase the recovery ratio by 21.6%. 展开更多
关键词 BIOSURFACTANT THERMOTOLERANCE salinity tolerance core model flooding experiment microbial enhanced oil recovery.
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Mathematical Model for Growth of Inclusion in Deoxidization on the Basis of Unreacted Core Model
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作者 WU Su zhou ZHANG Jiong-ming 《Journal of Iron and Steel Research International》 SCIE EI CAS CSCD 2008年第6期24-28,共5页
Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, ... Controlling inclusion composition, from the point of view of thermodynamics, only explains the probability and limit of reaction. However, kinetics makes the nucleation and the velocity of growth of inclusions clear, and these kinetic factors are very important to the quality of slab. The basic kinetic theory of unreacted core model was used to build the mathematical model for the growth of inclusions and the concerned software was developed through Visual Basic 6.0. The time that different radius inclusions attain saturation was calculated to determine the controlling step of reaction between steel and inclusions. The time for the growth of inclusion obtained from the model was in good agreement with the data measured by Japanese Okuyama G, which indicated that the model is reasonable. 展开更多
关键词 INCLUSION finite difference method kinetic theory unreacted core model
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APPLICATION OF THE SHRINKING CORE MODEL TO THE KINETICS OF ZINC OXIDE DESULFURIZATION 被引量:3
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作者 李彦旭 张栓兵 +1 位作者 郭汉贤 钟炳 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 1997年第4期14-21,共8页
The kinetics of H<sub>2</sub>S removal by zinc oxide desulfurizer was studied through thermogravimetricanalysis.The experimental results show that desulfurization rate was controlled,at high temperatureand... The kinetics of H<sub>2</sub>S removal by zinc oxide desulfurizer was studied through thermogravimetricanalysis.The experimental results show that desulfurization rate was controlled,at high temperatureand low conversion,by the chemical reaction rate,and at low temperature and high conversion by thegrain diffusion rate.The reaction is first order with respect to H<sub>2</sub>S concentration in the differentcontrolled stages.The kinetic behavior can be modeled through the employment of the shrinking coremodel.The values of the model parameters were determined.The variation tendencies with temperatureand concentration of H<sub>2</sub>S at the controlled stages were discussed. 展开更多
关键词 hydrogen SULFIDE DESULFURIZATION KINETICS SHRINKING core model
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The Physics of Rotational Flattening and the Point Core Model
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作者 Hanno Essén 《International Journal of Geosciences》 2014年第6期555-570,共16页
The effect of rotation on the shape (figure) and gravitational quadrupole of astronomical bodies is calculated by using an approximate point core model: A point mass at the center of an ellipsoidal homogeneous fluid. ... The effect of rotation on the shape (figure) and gravitational quadrupole of astronomical bodies is calculated by using an approximate point core model: A point mass at the center of an ellipsoidal homogeneous fluid. Maclaurin’s analytical result for homogenous bodies generalizes to this model and leads to very accurate analytical results connecting the three observables: oblateness (ò), gravitational quadrupole (J2), and angular velocity parameter (q). The analytical results are compared to observational data for the planets and a good agreement is found. Oscillations near equilibrium are studied within the model. 展开更多
关键词 Rotation Angular Velocity OBLATENESS FLATTENING Figure of Celestial Body GRAVITATIONAL QUADRUPOLE POINT core model Moment of INERTIA
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Calculation and experimental verification of equivalent distributed circuit model based on refined iron core modelling
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作者 Yunpeng Liu Guanyu Chen +4 位作者 Fuseng Xu Tao Zhao Hongliang Liu Lu Sun Jiayi Guo 《High Voltage》 2025年第4期1020-1031,共12页
This research introduces an equivalent circuitmodel and a computational method to address complex mechanical motion issues through electromechanical analogies.The study initially refines core vibration characteristics... This research introduces an equivalent circuitmodel and a computational method to address complex mechanical motion issues through electromechanical analogies.The study initially refines core vibration characteristics using single-and multi-degree-of-freedom models,subsequently establishing equivalent circuit models for these various degrees of freedom.However,employing high degree-of-freedom models for detailed modelling of the core proves overly cumbersome.The research advocates for a distributed equivalent circuit model to more accurately represent the core's layered structure,thus facilitating enhanced core modelling.Moreover,the study formulates a mechanical wave transmission equation pertinent to the vibration of the iron core,which constitutes the foundation of the distributed mechanical vibration model.This model comprehensively assesses the impact of three critical factors on core vibration:the non-linearity of winding resistance,the elec-tromechanical coupling coefficient,and the dynamic stiffness of the core.A case study elucidates the distinct influences of each factor on vibration characteristics.Furthermore,this study derives vibration calculations from a 60-day overload ageing test conducted on a 10 kV transformer under 135℃overloadconditions.The methodology involves integrating measured compression force values and the calculated dynamic stiffness of the core into an equivalent circuit model.Subsequent analysis compares the results from the equivalent circuit model with experimental measurements.These comparisons indicate an agreement between the calculated and measured values in the time-frequency domain,thereby con-firming the accuracy of the equivalent circuit model calculations. 展开更多
关键词 iron core modeling equivalent circuit models electromechanical analogiesthe mechanical wave transmission equation distributed circuit model computational method distributed equivalent equivalent circuit model
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Establishment and verification of a shrinking core model for dilute acid hydrolysis of lignocellulose
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作者 Cunwen WANG Xiaoling DUAN +2 位作者 Weiguo WANG Zihao LI Yuanhang QIN 《Frontiers in Energy》 CSCD 2012年第4期413-419,共7页
The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid (mass fraction 0.05%) was investigated in this paper. By studying the reducing sugar concentration versus reaction te... The kinetics oflignocellulose hydrolysis under the conditions of high temperature and dilute acid (mass fraction 0.05%) was investigated in this paper. By studying the reducing sugar concentration versus reaction tempera ture (170℃-220℃) and reaction time (150-1800 s) during the hydrolysis process of five kinds of crop straw (rice, wheat, cotton, rape and corn), the shrinking core model was established, and the differential equation of the model and its analytical solution were obtained. With a numerical calculation method, the kinetic equation was estimated, and the degradation of reducing sugar obeyed firstorder kinetics was obtained. The calculated results from the equations agreed well with the original experimental data. The calculation by the model showed that the reducing sugar concentration increases as the size of the particles decrease, and the uniform particles increase. 展开更多
关键词 LIGNOCELLULOSE dilute acid hydrolysis shrink-ing core model
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Overall Features of EAST Operation Space by Using Simple Core-SOL-Divertor Model 被引量:1
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作者 R.HIWATARI A.HATAYAMA +2 位作者 朱思铮 T.TAKIZUKA Y.TOMITA 《Plasma Science and Technology》 SCIE EI CAS CSCD 2006年第1期114-117,共4页
A simple Core-SOL-Divertor (C-S-D) model has been developed to investigate qualitatively the overall features of the operational space for the integrated core and edge plasma. To construct the simple C-S-D model, a ... A simple Core-SOL-Divertor (C-S-D) model has been developed to investigate qualitatively the overall features of the operational space for the integrated core and edge plasma. To construct the simple C-S-D model, a simple core plasma model of ITER physics guidelines and a two-point SOL-divertor model are used. The simple C-S-D model is applied to the study of the EAST operational space with lower hybrid current drive experiments under various kinds of trade-off for the basic plasma parameters. Effective methods for extending the operational space are also presented, From this study for the EAST operational space, it is evident that the C-S-D model is a useful tool for understanding qualitatively the overall features of the plasma operational space. 展开更多
关键词 divertor modeling particle balance core-edge interface EAST
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Shell and shrinking core kinetics model of Mg-based hydrogen storage alloys
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作者 于振兴 王尔德 +3 位作者 张文丛 房文斌 孙宏飞 梁吉 《中国有色金属学会会刊:英文版》 CSCD 2005年第S2期178-182,共5页
The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption... The kinetics equation of the Mg-based hydrogen storage alloys (Mg-Ni-MO) was established by the shell and shrinking core model. The total coefficients of the kinetics equation of the hydrogen absorption and desorption process with shell diffusion as the controlling step were determined by semi-empirical and semi-theoretical methods, and the apparent activation energy of the hydrogen absorption process was obtained. The calculation results can well accord with the experimental data, and can well forecast the hydrogen storage capacity and absorption rate at different times. By using the kinetics equation, the effects of temperature and pressure on the hydrogen storage process can also be well understood. The kinetics equation is helpful for the design of the hydrogen storage container. 展开更多
关键词 Mg-based ALLOYS hydrogen storage SHELL and core SHRINKING model KINETICS EQUATION
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Validation of the TASS/SMR-S Code for the Core Heat Transfer Model on the Steady Experimental Conditions
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作者 In Sub Jun Kyoo Hwan Bae Young Jong Chung Won Jae Lee 《Journal of Energy and Power Engineering》 2012年第3期338-345,共8页
The SMART (System-integrated Modular Advanced ReacTor) which is a 330 MWt advanced integral PWR was developed by the KAERI (Korea Atomic Energy Institute) for electricity generation and seawater desalination. To e... The SMART (System-integrated Modular Advanced ReacTor) which is a 330 MWt advanced integral PWR was developed by the KAERI (Korea Atomic Energy Institute) for electricity generation and seawater desalination. To enhance its safety, the various design concepts were adopted such as the most containing of the RCS (reactor coolant system) components and a PRHRS (passive residual heat removal system). To ensure the safety and performance of the SMART, a thermal hydraulic evaluation and safety analysis are performed by the TASS/SMR-S code. It uses a one dimensional node/path modeling and point kinetics for the core power simulation. The code also has specific models reflecting the design features of the SMART such as a helical tube and PRHRS heat transfer models. In this study, the validation of the core heat transfer model in the TASS/SMR-S code on the steady conditions was performed with the Bennett's heated tube tests and THTF (thermal hydraulic test facility) experiment. From the results of the TASS/SMR-S code calculation, the CHF (critical heat flux) point and the fuel rod surface temperature were predicted conservatively compared to the test results. 展开更多
关键词 SMART TASS/SMR-S code core heat transfer model Bennett tube test THTF experiment.
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Poroelastic finite-difference modeling for ultrasonic waves in digital porous cores 被引量:1
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作者 Li-Yun Fu Yan Zhang +2 位作者 Zhenglin Pei Wei Wei Luxin Zhang 《Earthquake Science》 2014年第3期285-299,共15页
Scattering attenuation in short wavelengths has long been interesting to geophysicists. Ultrasonic coda waves, observed as the tail portion of ultrasonic wavetrains in laboratory ultrasonic measurements, are important... Scattering attenuation in short wavelengths has long been interesting to geophysicists. Ultrasonic coda waves, observed as the tail portion of ultrasonic wavetrains in laboratory ultrasonic measurements, are important for such studies where ultrasonic waves interact with smallscale random heterogeneities on a scale of micrometers, but often ignored as noises because of the contamination of boundary reflections from the side ends of a sample core. Numerical simulations with accurate absorbing boundary can provide insight into the effect of boundary reflections on coda waves in laboratory experiments. The simulation of wave propagation in digital and heterogeneous porous cores really challenges numerical techniques by digital image of poroelastic properties, numerical dispersion at high frequency and strong heterogeneity, and accurate absorbing boundary schemes at grazing incidence. To overcome these difficulties, we present a staggered-grid high-order finite-difference (FD) method of Biot's poroelastic equations, with an arbitrary even-order (2L) accuracy to simulate ultrasonic wave propagation in digital porous cores with strong heterogeneity. An unsplit convolutional perfectly matched layer (CPML) absorbing boundary, which improves conventional PML methods at grazing incidence with less memory and better computational efficiency, is employed in the simulation to investigate the influence of boundary reflections on ultra- sonic coda waves. Numerical experiments with saturated poroelastic media demonstrate that the 2L FD scheme with the CPML for ultrasonic wave propagation significantly improves stability conditions at strong heterogeneity and absorbing performance at grazing incidence. The boundary reflections from the artificial boundary surrounding the digital core decay fast with the increase of CPML thick- nesses, almost disappearing at the CPML thickness of 15 grids. Comparisons of the resulting ultrasonic coda Qsc values between the numerical and experimental ultrasonic S waveforms for a cylindrical rock sample demonstrate that the boundary reflection may contribute around one-third of the ultrasonic coda attenuation observed in laboratory experiments. 展开更多
关键词 Digital porous cores Ultrasonic coda Poroelastic finite-difference modeling Unsplitconvolutional PML absorbing boundary
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Mathematical modeling for dynamic stability of sandwich beam with variable mechanical properties of core 被引量:3
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作者 M.GRYGOROWICZ E.MAGNUCKA-BLANDZI 《Applied Mathematics and Mechanics(English Edition)》 SCIE EI CSCD 2016年第10期1361-1374,共14页
The paper is devoted to mathematical modelling of static and dynamic stability of a simply supported three-layered beam with a metal foam core. Mechanical properties of the core vary along the vertical direction. The ... The paper is devoted to mathematical modelling of static and dynamic stability of a simply supported three-layered beam with a metal foam core. Mechanical properties of the core vary along the vertical direction. The field of displacements is for- mulated using the classical broken line hypothesis and the proposed nonlinear hypothesis that generalizes the classical one. Using both hypotheses, the strains are determined as well as the stresses of each layer. The kinetic energy, the elastic strain energy, and the work of load are also determined. The system of equations of motion is derived using Hamilton's principle. Finally, the system of three equations is reduced to one equation of motion, in particular, the Mathieu equation. The Bubnov-Galerkin method is used to solve the system of equations of motion, and the Runge-Kutta method is used to solve the second-order differential equation. Numerical calculations are done for the chosen family of beams. The critical loads, unstable regions, angular frequencies of the beam, and the static and dynamic equilibrium paths are calculated analytically and verified numerically. The results of this study are presented in the forms of figures and tables. 展开更多
关键词 mathematical modelling dynamic stability metal foam core with variable mechanical property static and dynamic equilibrium path angular frequency
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Modeling of Few-Mode Multi-Core Optical Fiber Channel Based on Non-Uniform Mode Field Distribution
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作者 Hang Zhou Bo Liu +6 位作者 Fu Wang Dandan Song Li Li Xiangjun Xin Qinghua Tian Qi Zhang Feng Tian 《China Communications》 SCIE CSCD 2016年第8期184-191,共8页
In this paper, the influencing factors that affect few-mode and multi core optical fiber channel are analyzed in a comprehensive way. The theoretical modeling and computer simulation of the information channel are car... In this paper, the influencing factors that affect few-mode and multi core optical fiber channel are analyzed in a comprehensive way. The theoretical modeling and computer simulation of the information channel are carried out and then the modeling scheme of few-mode multicore optical fiber channel based on non-uniform mode field distribution is put forward. The proposed modeling scheme can not only exponentially increases the system capacity through fewmode multi-core optical fiber channel, but has better transmission performance compared to the channel of the same type to the uniform channel revealing from the simulation results. 展开更多
关键词 few-mode multi-core optical fiber channel non-uniform channel channel modeling
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物流管理现代产业学院人才培养模式研究
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作者 鲁丽丽 赵佳静 +1 位作者 张勇 姚依含 《唐山师范学院学报》 2026年第1期115-122,共8页
育人主体多元化、培养目标精准化、课程体系模块化、教学资源共建共享以及教学方法创新融合等是具有产业学院特色的人才培养模式的主要特征。针对多主体协同机制的长效化、课程内容与产业需求匹配等问题,应采取加强实体化管理机构建设... 育人主体多元化、培养目标精准化、课程体系模块化、教学资源共建共享以及教学方法创新融合等是具有产业学院特色的人才培养模式的主要特征。针对多主体协同机制的长效化、课程内容与产业需求匹配等问题,应采取加强实体化管理机构建设、校企共建课程和教学资源、联合建设工作坊和虚拟教研室、加强“双师双能型”教师队伍建设等对策,提高现代物流人才的培养质量。 展开更多
关键词 现代产业学院 物流管理 人才培养模式 人才核心能力
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计及磁心集肤效应的高频磁性元件电磁瞬态建模方法
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作者 刘任 黄浩然 +3 位作者 卢友好 陈昊 刘焱 唐波 《中国电机工程学报》 北大核心 2026年第3期1286-1298,I0035,共14页
磁导-电容类比法已广泛应用于高频磁性元件电磁瞬态建模中,但现有基于该方法的模型均假设磁心内部磁场均匀分布,即不考虑高频激励下的磁心集肤效应。文中利用余弦基函数对磁心叠片涡流场控制方程近似展开,并通过积分方法推导得到磁心内... 磁导-电容类比法已广泛应用于高频磁性元件电磁瞬态建模中,但现有基于该方法的模型均假设磁心内部磁场均匀分布,即不考虑高频激励下的磁心集肤效应。文中利用余弦基函数对磁心叠片涡流场控制方程近似展开,并通过积分方法推导得到磁心内部磁场强度的表达式;然后,为确定其系数和考虑材料磁滞本构关系,引入伽辽金法基本思想和Play磁滞模型,进而基于损耗统计理论推导考虑磁畴介观涡流的磁心叠片边界磁场强度解析计算模型;在此基础上,运用磁导-电容类比法,提出一种同时计及磁心集肤效应与复杂磁滞本构关系的高频磁性元件电磁瞬态计算模型;最后,使用电力电子仿真PLECS软件底层模块和语言程序搭建单相桥式脉宽调制逆变器内部高频电感器的两类电磁瞬态模型——传统不考虑磁心集肤效应的模型与所提考虑磁心集肤效应的模型,并将其在不同工况下的电磁瞬态、动态磁滞回线及磁心损耗的仿真结果与相应实验测量结果进行对比,发现所提模型各项模拟结果与实测值更加吻合,且磁心损耗最大误差比传统模型低17.03%,验证了所提模型的准确性。 展开更多
关键词 高频磁性元件 电磁瞬态 磁心集肤效应 Play磁滞模型
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优秀地理教师成长的核心要素与培养路径研究
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作者 李水 王玉瑾 《地理教学》 北大核心 2026年第3期20-26,共7页
通过对连云港市12位优秀中学地理教师的深度访谈,提炼出其专业成长的四大核心要素,分别是:坚定的专业信念与持续的内在驱动力、扎实的学科素养与精湛的教学技艺、支持性的专业社群与关键外部机遇以及自觉的教学反思与主动的创新实践。... 通过对连云港市12位优秀中学地理教师的深度访谈,提炼出其专业成长的四大核心要素,分别是:坚定的专业信念与持续的内在驱动力、扎实的学科素养与精湛的教学技艺、支持性的专业社群与关键外部机遇以及自觉的教学反思与主动的创新实践。基于此,构建了优秀地理教师专业发展“四位一体”成长模型,形成了以强化教师内在驱动力、优化专业社群支持机制、鼓励教学反思与创新实践为要点的教师专业发展支持体系。作者在连云港市开展教师专业发展区域实践,在实践中应用并检验了优秀地理教师专业发展“四位一体”成长模型。 展开更多
关键词 优秀地理教师 专业成长 核心要素 “四位一体”模型 培养路径
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Kinetics of zinc sulfide concentrate direct leaching in pilot plant scale and development of semi-empirical model 被引量:7
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作者 Nima SADEGHI Javad MOGHADDAM Mehdi OJAGHI ILKHCHI 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第10期2272-2281,共10页
The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurr... The direct leaching kinetics of an iron-poor zinc sulfide concentrate in the tubular reactor was examined.All tests werecarried out in the pilot plant.To allow the execution of hydrostatic pressure condition,the slurry with ferrous sulfate and sulfuric acidsolution was filled into a vertical tube(9m in height)and air was blown from the bottom of the reactor.The effects of initial acidconcentration,temperature,particle size,initial zinc sulfate concentration,pulp density and the concentration of Fe on the leachingkinetics were investigated.Results of the kinetic analysis indicate that direct leaching of zinc sulfide concentrate follows shrinkingcore model(SCM).This process was controlled by a chemical reaction with the apparent activation energy of49.7kJ/mol.Furthermore,a semi-empirical equation is obtained,showing that the order of the iron,sulfuric acid and zinc sulfate concentrationsand particle radius are0.982,0.189,-0.097and-0.992,respectively.Analysis of the unreacted and reacted sulfide particles bySEM-EDS shows that insensitive agitation in the reactor causes detachment of the sulfur layer from the particles surface in lowerthan60%Zn conversion and lixiviant in the face with sphalerite particles. 展开更多
关键词 KINETICS direct leaching SPHALERITE shrinking core model (SCM) pilot plant
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Optimization of process parameters and kinetic modelling for leaching of copper from oxidized copper ore in nitric acid solutions 被引量:1
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作者 Mehmet Kayra TANAYDIN Zümra BakıcıTANAYDIN Nizamettin DEMIRKIRAN 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2022年第4期1301-1313,共13页
The leaching behavior of Tunceli malachite mineral was investigated in nitric acid solutions by two steps to evaluate the effect of various experimental parameters.In the first step,the optimal conditions for the leac... The leaching behavior of Tunceli malachite mineral was investigated in nitric acid solutions by two steps to evaluate the effect of various experimental parameters.In the first step,the optimal conditions for the leaching process were determined,while in the second step,a kinetic evaluation for the process was performed.In the optimization experiments,the concentration of nitric acid,temperature,stirring speed,and solid-to-liquid ratio were selected as the independent variables,and the central composite design method(CCD)was applied to the experimental data.At the end of the experiments,the optimal values for the concentration of nitric acid,temperature,solid-to-liquid ratio and stirring speed were determined to be 0.5 mol/L,50℃,0.004 g/m L and 500 r/min,respectively.Under the optimal conditions,the leaching rate was found to be 99%for 120 min of reaction time.In the kinetic evaluation tests,the effects of the concentration of nitric acid,temperature,stirring speed,solid-to-liquid ratio and particle size on the leaching rate of copper from malachite were investigated.In these tests,it was determined that the leaching rate increased with the increase in the temperature,acid concentration and stirring speed,and with the decrease in the particle size and solid-to-liquid ratio.In consequence of the kinetic analysis,it was observed that the leaching kinetics followed the mixed kinetic model,and a mathematical model for the leaching process was introduced.The activation energy for this process was calculated to be 36.23 k J/mol. 展开更多
关键词 LEACHING COPPER RECOVERY central composite design shrinking core model
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空间电荷效应对低能超导直线加速器束流品质的影响
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作者 万鑫淼 任志强 +5 位作者 廖文龙 骆小宝 常轩恺 朱彦东 陶德强 李智慧 《强激光与粒子束》 北大核心 2026年第2期178-190,共13页
通过理论建模与数值模拟相结合,系统探究了在低能超导质子直线加速器内,加速过程中聚焦参数动态演化对空间电荷主导型包络不稳定性的影响机制,揭示了低能段双周期聚焦结构与束晕产生的内在关联。基于Vlasov-Poisson方程二阶偶模展开,构... 通过理论建模与数值模拟相结合,系统探究了在低能超导质子直线加速器内,加速过程中聚焦参数动态演化对空间电荷主导型包络不稳定性的影响机制,揭示了低能段双周期聚焦结构与束晕产生的内在关联。基于Vlasov-Poisson方程二阶偶模展开,构建了理论模型,设计零流强周期相移(σ_(0))局部突破90°的多种演化方案,全面探究了不同聚焦方案下,局部突破90°对束流品质的影响,并用多粒子模拟软件对低能、归一化均方根发射度0.2~0.4π·mm·mrad的质子束进行了多粒子模拟验证;针对双周期聚焦结构特征,设计了相应的聚焦结构与束流匹配方案,通过粒子-束核模型对比分析了准周期与双周期结构的束晕形成机制差异,定量分析了纵向包络对横向束晕的耦合作用。研究结果表明,当空间电荷效应较弱(对应于较高的调谐因子η,η=带电流周期相移σ/零流强周期相移σ_(0))时,σ_(0)可突破90°而不导致束流品质恶化;反之,当空间电荷效应较强(低η值)时,σ_(0)的突破会激发共振并导致束流发射度显著增长,且这一效应在双组合四极透镜聚焦结构中尤为显著。二维/三维模型均证实,即便每个聚焦单元的σ_(0)<90°,双周期结构仍会引发束流包络的不稳定性。二维模型研究结果显示,相较于准周期结构,双周期结构更易产生束晕现象,其中2∶1共振仍是束晕形成的主要原因。采用三维模型进一步研究纵向因素的影响时发现,三维束团纵向尺寸的变化会显著改变束核电荷密度分布,这一现象成为束晕形成的新机制。此外,高阶共振也在很大程度上促进了束晕的形成。研究还揭示了小周期结构数(N)与共振概率呈负相关关系。 展开更多
关键词 低能超导直线加速器 空间电荷效应 双周期结构 束流品质 包络稳定性 粒子-束核模型 束晕
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Modelling and numerical simulation of isothermal oxidation of an individual magnetite pellet based on computational fluid dynamics 被引量:1
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作者 Zhou Pu Feng Zhou +2 位作者 Yue Sun Ming Zhang Bo-quan Li 《Journal of Iron and Steel Research International》 SCIE EI CSCD 2021年第7期799-808,共10页
A mathematical model based on the computational fluid dynamics method,heat and mass transfer in porous media and the unreacted shrinking core model for the oxidation reaction of an individual magnetite pellet during p... A mathematical model based on the computational fluid dynamics method,heat and mass transfer in porous media and the unreacted shrinking core model for the oxidation reaction of an individual magnetite pellet during preheating was established.The commercial software COMSOL Multiphysics was used to simulate the change in the oxidation degree of the pellet at different temperatures and oxygen concentrations,and the simulated results were compared with the exper-imental results.The model considered the influence of the exothermic heat of the reaction,and the enthalpy change was added to calculate the heat released by the oxidation.The results show that the oxidation rate on the surface of the pellet is much faster than that of the inside of the pellet.Temperature and oxygen concentration have great influence on the pellet oxidation model.Meanwhile,the exothermic calculation results show that there is a non-isothermal phenomenon inside the pellet,which leads to an increase in temperature inside the single pellet.Under the preheating condition of 873-1273 K(20%oxygen content),the heat released by the pellet oxidation reaction in a chain grate is 7.8×10^(6)-10.8×10^(6) kJ/h,which is very large and needs to be considered in the magnetite pellet oxidation modelling. 展开更多
关键词 Magnetite pellet OXIDATION Numerical simulation Unreacted shrinking core model Computational fluid dynamics
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