采用含Si的BNi-5非晶箔片作为中间层合金对CMSX-4镍基单晶合金棒在放电等离子体烧结炉中进行TLP连接,采用SEM观测了TLP接头在不组织形貌特征,借助于EDS分析了TLP接头界面处的物相组成及其对接头力学性能的影响。采用常温和高温拉伸试验...采用含Si的BNi-5非晶箔片作为中间层合金对CMSX-4镍基单晶合金棒在放电等离子体烧结炉中进行TLP连接,采用SEM观测了TLP接头在不组织形貌特征,借助于EDS分析了TLP接头界面处的物相组成及其对接头力学性能的影响。采用常温和高温拉伸试验验证了不同焊接工艺条件对TLP接头性能的影响。结果表明,在1 200℃/5 k N/20 min工艺参数下可得到满意的TLP接头,此时组织分布较为均匀,常温抗拉强度达到了母材的95%,760℃高温抗拉强度达到母材的99%。展开更多
Compressive and tensile pre-strains at room temperature were induced in the second generation single crystal superalloy CMSX-4 fully heat treated.Both compressive and tensile pre-strain generated shear bands in the si...Compressive and tensile pre-strains at room temperature were induced in the second generation single crystal superalloy CMSX-4 fully heat treated.Both compressive and tensile pre-strain generated shear bands in the single crystal CMSX-4.Thermal exposure for 10 h at 950 ℃ on the pre-strained single crystal CMSX-4 developed preferential coarsening of γ＇ particles along the shear bands.γ＇ particles on the shear band gradually invaded γ channel.Finally,the γ channels along the shear band disappeared.TCP-like particles appeared at the expense of γ channel disappearance.However,thermal exposure for 10 h of the normal single crystal CMSX-4 did not develop TCP precipitation or preferential coarsening of γ＇ particles.Thermal exposure for 100 h of pre-strained CMSX-4 developed preferential coarsening of γ＇ and TCP phase particles along the shear bands as well as coarsening of γ＇ particles in the matrix.展开更多
基金Ministry of Major Science&Technology of Shanghai(19DZ1100703)National Natural Science Foundation of China(51472263)+1 种基金Shanghai Institute of Ceramics,Chinese Academy of Sciences Launched the Fund in Advance(Y82ZC8180G)Key Laboratory of Space Manufacturing,Chinese Academy of Sciences(SMT-2019-004)。
文摘采用含Si的BNi-5非晶箔片作为中间层合金对CMSX-4镍基单晶合金棒在放电等离子体烧结炉中进行TLP连接,采用SEM观测了TLP接头在不组织形貌特征,借助于EDS分析了TLP接头界面处的物相组成及其对接头力学性能的影响。采用常温和高温拉伸试验验证了不同焊接工艺条件对TLP接头性能的影响。结果表明,在1 200℃/5 k N/20 min工艺参数下可得到满意的TLP接头,此时组织分布较为均匀,常温抗拉强度达到了母材的95%,760℃高温抗拉强度达到母材的99%。
文摘CMSX-4是目前世界上应用最广泛的第二代镍基单晶高温合金,在CMSX-4中添加微量的镧(La),铈(Ce)等稀土元素可以显著提高合金的抗氧化性和耐腐蚀性。本文建立了湿法消解-电感耦合等离子体质谱法(ICP-MS)同时测定CMSX-4镍基高温合金中La, Ce元素含量的方法。样品经王水-HF常压加热溶解,利用HClO4冒烟消除F-的干扰,优化了溶样用酸的量和消解条件。在优化条件下,方法的检出限为La 0.23μg/g, Ce 0.85μg/g,加标回收率为95.0%~98.9%,相对标准偏差(RSD)为1.3%~3.9%,能够用于对CMSX-4镍基高温合金中微量La和Ce元素的准确、快速测定。
文摘Compressive and tensile pre-strains at room temperature were induced in the second generation single crystal superalloy CMSX-4 fully heat treated.Both compressive and tensile pre-strain generated shear bands in the single crystal CMSX-4.Thermal exposure for 10 h at 950 ℃ on the pre-strained single crystal CMSX-4 developed preferential coarsening of γ＇ particles along the shear bands.γ＇ particles on the shear band gradually invaded γ channel.Finally,the γ channels along the shear band disappeared.TCP-like particles appeared at the expense of γ channel disappearance.However,thermal exposure for 10 h of the normal single crystal CMSX-4 did not develop TCP precipitation or preferential coarsening of γ＇ particles.Thermal exposure for 100 h of pre-strained CMSX-4 developed preferential coarsening of γ＇ and TCP phase particles along the shear bands as well as coarsening of γ＇ particles in the matrix.
