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Influential Factors of Suicidal Ideation among University Students——The Moderating Role of Family Closeness and Peer Support
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作者 Jun Qiu Jinling Wang 《International Journal of Mental Health Promotion》 2025年第4期484-504,共21页
Objectives:Suicidal ideation(SI)among university students is a growing concern,influenced by anxiety,depression,and bullying.However,family closeness and peer support may act as protective factors,reducing the risk of... Objectives:Suicidal ideation(SI)among university students is a growing concern,influenced by anxiety,depression,and bullying.However,family closeness and peer support may act as protective factors,reducing the risk of SI.Therefore,this study aims to investigate the key factors influencing SI among university students,focusing on the effects of anxiety,depression,and bullying,along with the roles of family closeness and peer support.The research also explores the interactions and mechanisms between these variables.Methods:A sample of 318 university students was surveyed,evaluating six main factors:anxiety,depression,bullying,family closeness,peer support,and SI.Using the Structural Equation Modeling(SEM)and Artificial Neural Networks(ANN)approach,both compensatory and non-compensatory relationships were examined.Results:Anxiety,depression,and bullying significantly contribute to SI,with depression mediating the link between anxiety,bullying,and SI.Additionally,family closeness moderates the effects of anxiety and bullying on SI,while peer supportmoderates the effects of depression and bullying.Themultilayer perceptron analysis identifies peer support as the most influential predictor,followed by bullying,family closeness,depression,and anxiety.Conclusion:The study identifies anxiety,depression,and bullying as key factors influencing suicidal ideation(SI)among university students.Family closeness and peer support act as protective factors,moderating the effects of these variables on SI. 展开更多
关键词 ANXIETY DEPRESSION bullying experience family closeness peer support suicidal ideation
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Synthetical condition assessment of long span suspension bridge based on closeness degree and FAHP 被引量:1
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作者 郭彤 李爱群 +1 位作者 赵大亮 王浩 《Journal of Southeast University(English Edition)》 EI CAS 2007年第2期261-265,共5页
Based on the theory of pattern recognition, the concept of closeness degree between fuzzy sets is brought into the condition assessment of long span bridges. Using the fuzzy analytic hierarchy process (FAHP), a math... Based on the theory of pattern recognition, the concept of closeness degree between fuzzy sets is brought into the condition assessment of long span bridges. Using the fuzzy analytic hierarchy process (FAHP), a mathematical model of a multi-objective assessment of a long span suspension bridge is set up. An example is given to show the procedure in the synthetical condition assessment of the Runyang Suspension Bridge, which includes the hierarchical division, the definition of factor weights and fuzzy membership functions, and the calculation of closeness degrees, etc. The assessment combines both the data from the health monitoring system and the manual tests. The classification of evaluation items as well as the calculation of deterministic and nondeterministic items is presented. Compared with the traditional method of point rating, this method can better describe the discreteness of monitoring data and the fuzziness in the condition assessment. 展开更多
关键词 pattern recognition fuzzy analytic hierarchy process closeness degree synthetical condition assessment suspension bridge
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模糊t-closeness隐私保护方法研究 被引量:4
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作者 陈晓宇 韩斌 +1 位作者 黄树成 朱文正 《计算机应用与软件》 北大核心 2018年第9期317-322,333,共7页
针对t-closeness隐私保护方法中数据泛化机制带来的信息损失量较大的不足,基于模糊理论提出一种模糊t-closeness隐私保护方法。该方法给出数据模糊化的定义,设计并实现替代泛化机制的数据模糊化过程。该过程在模糊聚类的基础上划分出符... 针对t-closeness隐私保护方法中数据泛化机制带来的信息损失量较大的不足,基于模糊理论提出一种模糊t-closeness隐私保护方法。该方法给出数据模糊化的定义,设计并实现替代泛化机制的数据模糊化过程。该过程在模糊聚类的基础上划分出符合t-closeness隐私保护要求的模糊等价类,对元素隶属度限幅求取平均值以获取元素模糊化的替代值。同时针对元素中分类属性给出模糊化语义结构树的构造方法。进行理论证明并通过实验验证模糊t-closeness隐私保护方法降低信息损失量的同时,提高了数据的隐私保护强度。 展开更多
关键词 t—closeness 隐私保护 模糊理论 模糊化
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Evaluation Indexes of Degree of Closeness between Strategy and Project Portfolio Allocation
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作者 Libiao Bai Sijun Bai 《American Journal of Operations Research》 2015年第1期38-46,共9页
The main activities in project portfolio allocation management are selecting the right project components given a strategy. It is crucial to establish a scientific system of evaluation indexes to guarantee the closene... The main activities in project portfolio allocation management are selecting the right project components given a strategy. It is crucial to establish a scientific system of evaluation indexes to guarantee the closeness between strategy and project portfolio allocation optimally. With organizations growing in sizes, the functions and objectives of project components are becoming more and more different. It is necessary to set evaluation indexes of the degree of closeness from the perspectives of financial, market share, social effects, and so on according to the strategy-oriented process of project portfolio allocation. This paper proposes a project portfolio allocation process under strategic orientation and evaluation indexes of the degree of closeness between strategy and project portfolio allocation. This will help projects managers make portfolio allocation decisions. 展开更多
关键词 PROJECT PORTFOLIO ALLOCATION Evaluation Indexes DEGREE of closeness PPA Process
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Knowing one’s parents’ friends: association with parental closeness
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作者 何玲熹 《留学》 2019年第12期78-79,共2页
Is one knowing about their parents’social lives associated with how close they are to them?An obvious answer might be yes.We first found that in a sample of Chinese students,they are more aware of the number of frien... Is one knowing about their parents’social lives associated with how close they are to them?An obvious answer might be yes.We first found that in a sample of Chinese students,they are more aware of the number of friends their mother has tham the friends their dads have.We then found that,for girls,knowing their mom and dad's friends predicts closeness with dad.Closeness to mother is not associated with knowledge of either parents’social network.For boys,however,knowing mothers’friends(but not the father’s friends)predicts their closeness to the father.As with girls,knowing either parent’s network is not associated with maternal closeness.This research implies that there are different ways closeness emerges between mothers and fathers and their children. 展开更多
关键词 parents’social LIVES maternal closeness children
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Topology-aware virtual network embedding based on closeness centrality 被引量:5
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作者 Zihou WANG Yanni HAN +3 位作者 Tao LIN Yuemei XU Song CI Hui TANG 《Frontiers of Computer Science》 SCIE EI CSCD 2013年第3期446-457,共12页
Network virtualization aims to provide a way to overcome ossification of the Internet. However, making efficient use of substrate resources requires effective techniques for embedding virtual networks: mapping virtua... Network virtualization aims to provide a way to overcome ossification of the Internet. However, making efficient use of substrate resources requires effective techniques for embedding virtual networks: mapping virtual nodes and virtual edges onto substrate networks. Previous research has presented several heuristic algorithms, which fail to consider that the attributes of the substrate topology and virtual net- works affect the embedding process. In this paper, for the first time, we introduce complex network centrality analysis into the virtual network embedding, and propose virtual network embedding algorithms based on closeness centrality. Due to considering of the attributes of nodes and edges in the topology, our studies are more reasonable than existing work. In addition, with the guidance of topology quantitative evalua- tion, the proposed network embedding approach largely improves the network utilization efficiency and decreases the embedding complexity. We also investigate our algorithms on real network topologies (e.g., AT&T, DFN) and random network topologies. Experimental results demonstrate the usability and capability of the proposed approach. 展开更多
关键词 network virtualization virtual network embedding complex networks closeness centrality
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An international study on implementation and facilitators and barriers for parent-infant closeness in neonatal units 被引量:2
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作者 Nicole R.van Veenendaal Nanon H.M.Labrie +4 位作者 Silke Mader Anne A.M.W.van Kempen Sophie R.D.van der Schoor Johannes B.van Goudoever CROWN Study Group 《Pediatric Investigation》 CAS CSCD 2022年第3期179-188,共10页
Importance:Parent-infant closeness and active parent participation in neonatal care are important for parent and infant health.Objective:To give an overview of current neonatal settings and gain an in-depth understand... Importance:Parent-infant closeness and active parent participation in neonatal care are important for parent and infant health.Objective:To give an overview of current neonatal settings and gain an in-depth understanding of facilitators and barriers to parent-infant closeness,zero-separation,in 19 countries.Methods:Neonatal intensive care unit(NICU)professionals,representing 45 NICUs from a range of geographic regions in Europe and Canada,were purposefully selected and interviewed June–December 2018.Thematic analysis was conducted to identify,analyze and report patterns(themes)for parent-infant closeness across the entire series of interviews.Results:Parent-infant separation during infant and/or maternity care is very common(42/45 units,93%),despite the implementation of family integrated care(FICare)practices,including parent participation in medical rounds(17/45,38%),structured education sessions for parents(16/45,36%)and structured training for healthcare professionals(22/45,49%).NICU professionals encountered four main themes with facilitators and barriers for parent-infant closeness on and between the hospital,unit,staff,and family level:Culture(jointly held characteristics,values,thinking and behaviors about parental presence and participation in the unit),Collaboration(the act of working together between and within different levels),Capacities(resources and policies),andCoaching(education to acquire and transfer knowledge and skills).Interpretation:Implementing parent-infant closeness in the NICU is still challenging for healthcare professionals.Further optimization in neonatal care towards zero-separation and parent-infant closeness can be achieved by enforcing the’’four Cs for Closeness’:Culture,Collaboration,Capacities,andCoaching. 展开更多
关键词 Parent-infant closeness Family centered care Family integrated care Couplet-care Neonatalogy Parent-collaboration Zero-separation
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Why employees stay: the roles of psychological ownership, territoriality and work relationship closeness in affecting employee turnover intention 被引量:1
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作者 Lu Lu Jun Liu Na Zhao 《Frontiers of Business Research in China》 2017年第2期186-207,共22页
Drawing on a tripartite perspective on attitudes, this study examines the influence of psychological ownership and territoriality on turnover intention, as well as the moderating role of work relationship closeness on... Drawing on a tripartite perspective on attitudes, this study examines the influence of psychological ownership and territoriality on turnover intention, as well as the moderating role of work relationship closeness on the relationship between territoriality and turnover intention. Analyses of longitudinal data collected from 341 employees in three Chinese automobile manufacturing companies demonstrate that employees' psychological ownership is negatively related to their turnover intention. As well, territoriality is negatively related to turnover intention and mediates the relationship between psychological ownership and turnover intention. Additionally, work relationship closeness moderates the relationship between territoriality and turnover intention such that the negative relationship is stronger when employees experience a higher level of work relationship closeness. Theoretical and practical implications are discussed. 展开更多
关键词 TERRITORIALITY psychological ownership Turnoverintention Work relationship closeness
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A Note on Closeness between NP-Hard Sets and C=P
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作者 刘田 《Journal of Computer Science & Technology》 SCIE EI CSCD 2000年第2期194-195,共2页
Two sets are close if their symmetric difference is a sparse set. It is shown that NP-hard sets are not C=P-close unless NP C=C=P. This improves the previous result and has implication in quantum compulation.
关键词 NP-HARD exact counting closeness quantum computation
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Residual Closeness of Graphs with Given Parameters
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作者 Mei-Qun Cheng Bo Zhou 《Journal of the Operations Research Society of China》 EI CSCD 2023年第4期839-856,共18页
Robustness of the network topology is a key aspect in the design of computer networks. Residual closeness is a new graph-theoretic concept defined as a measure of network robustness due to the failure of individual ve... Robustness of the network topology is a key aspect in the design of computer networks. Residual closeness is a new graph-theoretic concept defined as a measure of network robustness due to the failure of individual vertices. We identify those graphs with maximum residual closeness among connected graphs with fixed connectivity, edge connectivity and bipartiteness, respectively. 展开更多
关键词 Residual closeness CONNECTIVITY Edge connectivity Bipartiteness
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Impact of roadside water on sloped subgrade stability along the Qingzang Railway with two-phase closed thermosyphon and crushed rock revetment
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作者 LI Yasheng WEN Zhi +1 位作者 ZHANG Mingli MA Wei 《Journal of Mountain Science》 2026年第1期254-269,共16页
In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A wid... In permafrost regions of the QinghaiXizang Plateau,embankments of the Qinghai-Xizang Highway and Qinghai-Xizang Railway experiencing roadside water accumulation exhibit more pronounced engineering deteriorations.A widely accepted view is that the accumulated water adjacent to the embankment possesses substantial thermal energy,which accelerates the degradation-even disappearance-of the underlying permafrost.Moreover,the presence of roadside water keeps the embankment soil in a persistently high-moisture state,thereby making the frozen-soil embankment more susceptible to deformation under traffic loading.However,in the permafrost regions of the QinghaiXizang Plateau,deteriorations of embankments affected by roadside water are more commonly manifested as undulating pavement surfaces,and extensive crack networks appear on the embankment crest even where thermosyphons are installed.These manifestations are not fully consistent with the deterioration mechanisms proposed by existing viewpoints.We propose the hypothesis that temperature gradients,formed due to the freezing and thawing processes between the roadside wateraffected soil and the roadbed soil,lead to moisture migration under the influence of temperature gradients,resulting in frost heave and thaw settlement in the roadbed soil.To validate this hypothesis,we conducted the following investigations sequentially.Initially,we selected a roadbed with a thermosyphon(TPCT)system,which has a significant cooling effect,as the study object.By analyzing the temperature monitoring data of the roadbed section,the temperature variance was calculated to identify the time nodes where the temperature gradient of the roadbed soil was maximum and minimum.Subsequently,corresponding roadbed temperature distribution maps were drawn,illustrating the changes in the temperature and position of the lowtemperature core near the TPCT over time.Furthermore,using small-scale indoor model experiments,we qualitatively concluded that moisture in the soil migrates toward the TPCT due to the temperature gradient.Thereafter,combining borehole water content data and precipitation data from the sloped terrain construction site,the formation mechanisms and timing characteristics of roadside water accumulation were analyzed.Ultimately,by integrating the ground temperature data,air temperature data,roadside water formation mechanisms,and the operating characteristics of the TPCT,it was concluded that roadside water,while in a thawed state during TPCT operation,acts as a supplementary source for moisture migration in the roadbed soil.This migration leads to cracking in the TPCT roadbed.Therefore,this study reveals a novel damage mechanism:asynchronous freeze-thaw processes induce temperature gradients,which drive the migration of roadside water into the roadbed and are responsible for the cracking damage. 展开更多
关键词 Roadside water Low-temperature core Two-phase closed thermosyphon Temperature gradient Water migration Field test
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Singular closed orbits and chaotic behavior of a double-winged quasi-zero-stiffness system
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作者 Xinyi HUANG S.LENCI Qingjie CAO 《Applied Mathematics and Mechanics(English Edition)》 2026年第3期509-534,I0005-I0006,共28页
The complex chaotic behavior of a quasi-zero-stiffness(QZS)double-winged system with symmetric impact boundaries is investigated with Melnikov functions and numerical simulations.The analysis reveals the coexistence o... The complex chaotic behavior of a quasi-zero-stiffness(QZS)double-winged system with symmetric impact boundaries is investigated with Melnikov functions and numerical simulations.The analysis reveals the coexistence of multiple attractors.As a key mass parameter varies,the mechanism underlying degenerate singular closed orbits is elucidated,based upon which five distinct types of singular closed orbits are discovered,exhibiting both smooth and discontinuous(SD)characteristics.The chaotic threshold of each singular orbit is obtained by Melnikov functions and verified by numerical simulations.The numerical results further demonstrate the coexistence of SD motions.For zero damping systems,the Kolmogorov-Arnold-Moser(KAM)structures are exhibited to present the complex quasi-periodic and resonant behavior coexisting with chaotic and periodic motions.These findings advance the understanding of chaotic dynamics in nonsmooth multi-well impact systems. 展开更多
关键词 chaotic behavior Melnikov function singular closed orbit Kolmogorov-Arnold-Moser(KAM)structure RESONANCE
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Relative Motion Based Predictive Adaptive Control:A Case Study of AUV 3D Trajectory Tracking
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作者 Daxiong Ji Xinwei Wang Yuanchang Liu 《IEEE/CAA Journal of Automatica Sinica》 2026年第2期492-494,共3页
Dear Editor,This letter deals with the autonomous underwater vehicle(AUV)three dimensional(3D)trajectory tracking control chronically suffering from poor accuracy and efficiency in complex hydrodynamics.A state-of-the... Dear Editor,This letter deals with the autonomous underwater vehicle(AUV)three dimensional(3D)trajectory tracking control chronically suffering from poor accuracy and efficiency in complex hydrodynamics.A state-of-the-art predictive adaptive controller(PAC)is proposed with a distinct dual closed-loop structure. 展开更多
关键词 adaptive controller pac autonomous underwater vehicle auv three predictive adaptive control relative motion D trajectory tracking HYDRODYNAMICS closed loop structure complex hydrodynamicsa
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Comparative Study on the Efficacy of Closed Reduction and Kirschner Wire Fixation versus Open Reduction and Plate Fixation in the Treatment of Hand Surgery Fractures
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作者 Weishun Wang 《Journal of Clinical and Nursing Research》 2026年第2期81-87,共7页
Objective: To investigate the therapeutic advantages of closed reduction and Kirschner wire fixation versus open reduction and plate fixation in patients with hand surgery fractures. Methods: The sample was collected ... Objective: To investigate the therapeutic advantages of closed reduction and Kirschner wire fixation versus open reduction and plate fixation in patients with hand surgery fractures. Methods: The sample was collected from May 2021 to May 2025, consisting of 80 patients with hand surgery fractures. These patients were randomly divided into two groups using the red and blue ball method: the plate fixation group (40 cases, treated with open reduction and plate fixation) and the Kirschner wire fixation group (40 cases, treated with closed reduction and Kirschner wire fixation). The therapeutic effects between the two groups were randomly compared. Results: The Kirschner wire fixation group outperformed the plate fixation group in all indicators except for hand function scores (p < 0.05). There was no statistically significant difference in hand function scores between the two groups (p > 0.05). Conclusion: Compared with open reduction and plate fixation, closed reduction and Kirschner wire fixation for patients with hand surgery fractures achieves a more pronounced therapeutic effect, with advantages such as less trauma, shorter operation time, less bleeding, and a lower incidence of complications. It is suitable for hand surgery fractures with good stability. Open reduction and plate internal fixation have greater advantages in complex fractures and cases requiring high stability, and are worthy of promotion and application. 展开更多
关键词 Closed reduction and Kirschner wire fixation Open reduction and plate fixation Hand surgery fractures
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Countries’ Contact & Peoples’ Closeness from Shenyang to Tokyo(Twin City Exhibition) Exhibition Opened in Shenyang
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《Voice of Friendship》 2017年第4期8-8,共1页
This year marks the 45th anniversary of the normalization of diplomatic relations between China and Japan,and next year will usher in the 40th anniversary of the forging of a peace and friendship treaty between the tw... This year marks the 45th anniversary of the normalization of diplomatic relations between China and Japan,and next year will usher in the 40th anniversary of the forging of a peace and friendship treaty between the two countries.To celebrate the anniversaries,the Shenyang People’s Association for Friendship with Foreign Countries and the Japanese consulate in 展开更多
关键词 Twin City Exhibition closeness from Shenyang to Tokyo Contact COUNTRIES Exhibition Opened in Shenyang
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Soothsayers See Doom,Gloom in Closeness of Mars
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作者 Ed Cropley 郑松林 《当代外语研究》 2003年第10期5-6,共2页
It’s an historic event,one not to miss,but those who watch the sky forclues to the future of an uncertain(无常的)world say little good will come of(从…产生;由…引起)it. Soothsayers(预言者;占卜者)from India and Hong ... It’s an historic event,one not to miss,but those who watch the sky forclues to the future of an uncertain(无常的)world say little good will come of(从…产生;由…引起)it. Soothsayers(预言者;占卜者)from India and Hong Kong to a tent outsidea temple in the heart of Cambodia’s(柬埔寨的)capital say Wednesday’s closeencounter with Mars spells(导致;意味着)natural or man-made disaster 展开更多
关键词 In Soothsayers See Doom Gloom in closeness of Mars
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Induced neural stem cells regulate microglial activation through Akt-mediated upregulation of CXCR4 and Crry in a mouse model of closed head injury 被引量:1
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作者 Mou Gao Qin Dong +3 位作者 Dan Zou Zhijun Yang Lili Guo Ruxiang Xu 《Neural Regeneration Research》 SCIE CAS 2025年第5期1416-1430,共15页
Microglial activation that occurs rapidly after closed head injury may play important and complex roles in neuroinflammation-associated neuronal damage and repair.We previously reported that induced neural stem cells ... Microglial activation that occurs rapidly after closed head injury may play important and complex roles in neuroinflammation-associated neuronal damage and repair.We previously reported that induced neural stem cells can modulate the behavior of activated microglia via CXCL12/CXCR4 signaling,influencing their activation such that they can promote neurological recovery.However,the mechanism of CXCR4 upregulation in induced neural stem cells remains unclear.In this study,we found that nuclear factor-κB activation induced by closed head injury mouse serum in microglia promoted CXCL12 and tumor necrosis factor-αexpression but suppressed insulin-like growth factor-1 expression.However,recombinant complement receptor 2-conjugated Crry(CR2-Crry)reduced the effects of closed head injury mouse serum-induced nuclear factor-κB activation in microglia and the levels of activated microglia,CXCL12,and tumor necrosis factor-α.Additionally,we observed that,in response to stimulation(including stimulation by CXCL12 secreted by activated microglia),CXCR4 and Crry levels can be upregulated in induced neural stem cells via the interplay among CXCL12/CXCR4,Crry,and Akt signaling to modulate microglial activation.In agreement with these in vitro experimental results,we found that Akt activation enhanced the immunoregulatory effects of induced neural stem cell grafts on microglial activation,leading to the promotion of neurological recovery via insulin-like growth factor-1 secretion and the neuroprotective effects of induced neural stem cell grafts through CXCR4 and Crry upregulation in the injured cortices of closed head injury mice.Notably,these beneficial effects of Akt activation in induced neural stem cells were positively correlated with the therapeutic effects of induced neural stem cells on neuronal injury,cerebral edema,and neurological disorders post–closed head injury.In conclusion,our findings reveal that Akt activation may enhance the immunoregulatory effects of induced neural stem cells on microglial activation via upregulation of CXCR4 and Crry,thereby promoting induced neural stem cell–mediated improvement of neuronal injury,cerebral edema,and neurological disorders following closed head injury. 展开更多
关键词 Akt signaling cerebral edema closed head injury Crry CXCR4 induced neural stem cell MICROGLIA NEUROINFLAMMATION
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Microstructure-mechanism-performance relationships in hard carbon anode materials for sodium-ion batteries 被引量:1
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作者 LI Jin-ting Sawut Nurbiye +3 位作者 ZHAO Yi-chu LIU Ping WANG Yan-xia CAO Yu-liang 《新型炭材料(中英文)》 北大核心 2025年第4期860-869,共10页
The advantages of sodium-ion batteries(SIBs)for large-scale energy storage are well known.Among possible anode materials,hard carbon(HC)stands out as the most viable commercial option because of its superior performan... The advantages of sodium-ion batteries(SIBs)for large-scale energy storage are well known.Among possible anode materials,hard carbon(HC)stands out as the most viable commercial option because of its superior performance.However,there is still disagreement regarding the sodium storage mechanism in the low-voltage plateau region of HC anodes,and the structure-performance relationship between its complex multiscale micro/nanostructure and electrochemical behavior remains unclear.This paper summarizes current research progress and the major problems in understanding HC’s microstructure and sodium storage mechanism,and the relationship between them.Findings about a universal sodium storage mechanism in HC,including predictions about micropore-capacity relationships,and the opportunities and challenges for using HC anodes in commercial SIBs are presented. 展开更多
关键词 Sodium-ion battery Hard carbon ANODE Closed pore
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Regulating the“core-shell”microstructure of hard carbon through sodium hydroxide activation for achieving high-capacity SIBs anode 被引量:5
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作者 Haihua Wang Huizhu Niu +6 位作者 Kewei Shu Liyu Sun Yu Wang Yifan Du Yun Han Cunguo Yang Yong-Mook Kang 《Journal of Materials Science & Technology》 2025年第6期161-170,共10页
Pore structure engineering has been acknowledged as suitable approach to creating active sites and en-hancing ion transport capabilities of hard carbon anodes.However,conventional porous carbon materials exhibit high ... Pore structure engineering has been acknowledged as suitable approach to creating active sites and en-hancing ion transport capabilities of hard carbon anodes.However,conventional porous carbon materials exhibit high BET and surface defects.Additionally,the sodium storage mechanism predominantly occurs in the slope region.This contradicts practical application requirements because the capacity of the plateau region is crucial for determining the actual capacity of batteries.In our work,we prepared a novel“core-shell”carbon framework(CNA1200).Introducingclosedporesand carboxylgroupsinto coal-basedcarbon materials to enhance its sodium storage performance.The closed pore structure dominates in the“core”structure,which is attributed to the timely removal of sodium hydroxide(NaOH)to prevent further for-mation of active carbon structure.The presence of closed pores is beneficial for increasing sodium ion storage in the low-voltage plateau region.And the“shell”structure originates from coal tar pitch,it not only uniformly connects hard carbon particles together to improve cycling stability,but is also rich in carboxyl groups to enhance the reversible sodium storage performance in slope region.CNA1200 has ex-cellent electrochemical performance,it exhibits a specific capacity of 335.2 mAh g^(−1)at a current density of 20 mA g^(−1)with ICE=51.53%.In addition,CNA1200 has outstanding cycling stability with a capac-ity retention of 91.8%even when cycling over 200 times.When CNA1200 is used as anode paired with Na_(3)V_(2)(PO_(4))_(3)cathode,it demonstrates a capacity of 109.54 mAh g^(−1)at 0.1 C and capacity retention of 94.64%at 0.5 C.This work provides valuable methods for regulating the structure of sodium-ion battery(SIBs)anode and enhances the potential for commercialization. 展开更多
关键词 Hard carbon plateau region NaOH controlled etching-thermal annealing Closed pore structure Carboxyl groups Coal-based carbon materials
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Construction of hard carbon with abundant closed ultra-micropores via a pre-oxidation strategy for high-efficiency sodium storage in the low potential plateau 被引量:2
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作者 Wenbo Hou Lili Ma +6 位作者 Zhiyuan Liu Yiming Hu Wenxing Miao Bo Tao Kanjun Sun Hui Peng Guofu Ma 《Journal of Energy Chemistry》 2025年第6期65-75,I0003,共12页
Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improv... Rationally regulating the porosity of hard carbon(HC),especially the closed pores matching the low potential plateau and the ultra-microporous structure suitable for Na+embedding,has been shown to be the key to improving the sodium storage performance and initial coulombic efficiency(ICE).However,the preparation of such HC materials with specific pore structures still faces great challenges.Herein,a simple pre-oxidation strategy is employed to construct abundant closed ultra-microporous structures in soy protein powder-derived HC material,achieving a significant improvement in its ICE and platform capacity.The pre-oxidation process promotes the cross-linking degree of the soy protein,thereby hindering the directional growth of graphite domains during the carbonization process.The optimized HC exhibits ultra-high platform capacity(329 mAh g^(-1))and considerable energy density(148.5 Wh kg^(-1)).Based on the ex-situ Raman and X-ray photoelectron spectroscopy characterization results,the excellent sodium storage capacity of the HC material is attributed to the synergistic effect of adsorption-intercalation/filling.The presented work provides novel insights into the synthesis of other biomass-derived HC materials with abundant closed ultra-micro pores. 展开更多
关键词 Pre-oxidation strategy Closed ultra-micropores Low potential plateau Sodium-ion storage
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