In-situ bending and stretching were conducted on hot-rolled and annealed Ti/Al/Mg/Al/Ti laminates,with a focus on crack initiation and propagation of intermetallics and component layers,which helps to clarify their de...In-situ bending and stretching were conducted on hot-rolled and annealed Ti/Al/Mg/Al/Ti laminates,with a focus on crack initiation and propagation of intermetallics and component layers,which helps to clarify their deformation behavior and fracture forms.The results show that delamination is the early fracture form of laminate with or without intermetallics at Al/Mg interface,so Al/Mg interfacial bonding strength determines the mechanical properties of laminate.Various and irregular intermetallics cracks lead to Al/Mg interface delamination in annealed laminate and help to release stress.Necking and fracture of component layers are observed at the late deformation stage,and the sequence is Al,Mg and Ti layers,resulting from their strength.Angle between crack propagation direction and stretching direction of Mg layer both in rolled and annealed laminates is around 45°due to the effect of shear deformation,and crack convergence leads to final complete fracture of Mg layer.展开更多
Plasma electrolytic oxidation(PEO)coatings were prepared on Al−Mg laminated macro composites(LMCs)using both unipolar and bipolar waveforms in an appropriate electrolyte for both aluminum and magnesium alloys.The tech...Plasma electrolytic oxidation(PEO)coatings were prepared on Al−Mg laminated macro composites(LMCs)using both unipolar and bipolar waveforms in an appropriate electrolyte for both aluminum and magnesium alloys.The techniques of FESEM/EDS,grazing incident beam X-ray diffraction(GIXRD),and electrochemical methods of potentiodynamic polarization and electrochemical impedance spectroscopy(EIS)were used to characterize the coatings.The results revealed that the coatings produced using the bipolar waveform exhibited lower porosity and higher thickness than those produced using the unipolar one.The corrosion performance of the specimens’cut edge was investigated using EIS after 1,8,and 12 h of immersion in a 3.5 wt.%NaCl solution.It was observed that the coating produced using the bipolar waveform demonstrated the highest corrosion resistance after 12 h of immersion,with an estimated corrosion resistance of 5.64 kΩ·cm^(2),which was approximately 3 times higher than that of the unipolar coating.Notably,no signs of galvanic corrosion were observed in the LMCs,and only minor corrosion attacks were observed on the magnesium layer in some areas.展开更多
Mg/Al laminate with ZK60Mg and TiB2/6061Al as constitute layers was fabricated through the porthole die co-extrusion and hot rolling.The effects of rolling and roll temperatures on the microstructure,interfacial struc...Mg/Al laminate with ZK60Mg and TiB2/6061Al as constitute layers was fabricated through the porthole die co-extrusion and hot rolling.The effects of rolling and roll temperatures on the microstructure,interfacial structure,mechanical properties,and crack propagation paths were studied.The results show that the intermetallic compounds layer shows an intermittent form.The strong strain/dislocation hardening ability of Mg/Al laminate is attributed to the coupled effects of interlocking Al/βinterface,strain gradient,andβlayer with nanotwins and stacking faults.The complex dislocation structures such as network,loop,and array are found in the Al layer.Dislocation slip is the main deformation mode of the Al layer,while dislocation slip and dynamic recrystallization are the main deformation modes of the Mg layer.As roll temperature increases,prismatic〈a〉slip replaces the basal〈a〉slip as the most important slip mode.At a rolling temperature of 400℃ and a roll temperature of 150℃,an optimal synergy of mechanical properties is achieved,with ultimate tensile strength,shear strength,and elongation of 262.1 MPa,36.4 MPa,and 18.1%,respectively.As the rolling temperature increases,the fracture mode of Mg/Al laminate changes from discontinuous plastic shrinkage to transverse and longitudinal cracks.With increasing the roll temperature,the through cracks tend to form,indicating the plasticity and bonding quality of Mg/Al laminate are effectively enhanced.展开更多
Al/Cu laminate composite was fabricated based on hot press sintering using Cu sheet and Al powders as raw materials.The effects of sintering parameters on interfacial structure and mechanical properties were investiga...Al/Cu laminate composite was fabricated based on hot press sintering using Cu sheet and Al powders as raw materials.The effects of sintering parameters on interfacial structure and mechanical properties were investigated.The results revealed that a uniform Al/Cu interface with excellent bonding quality was achieved.The thickness of intermetallic compounds(IMCs)reached 33.88μm after sintering at 620℃for 2 h,whereas it was only 14.88μm when sintered at 600℃for 1 h.AlCu phase was developed through the reaction between Al4Cu9 and Al2Cu with prolonging sintering time,and an amorphous oxide strip formed at AlCu/Al4Cu9 interface.Both the grain morphology and interfacial structure affected the tensile strength of Al/Cu laminate,whereas the mode of tensile fracture strongly relied on the interfacial bonding strength.The highest tensile strength of 151.1 MPa and bonding strength of 93.7 MPa were achieved after sintering at 600℃for 1 h.展开更多
1060/7050 Al/Al laminated metal composites(LMCs)with heterogeneous lamellar structures were prepared by accumulative roll bonding(ARB),cold rolling and subsequent annealing treatment.The strengthening mechanism was in...1060/7050 Al/Al laminated metal composites(LMCs)with heterogeneous lamellar structures were prepared by accumulative roll bonding(ARB),cold rolling and subsequent annealing treatment.The strengthening mechanism was investigated by microstructural characterization,mechanical property tests and in-situ fracture morphology observations.The results show that microstructural differences between the constituent layers are present in the Al/Al LMCs after various numbers of ARB cycles.Compared with rolled 2560-layered Al/Al LMCs with 37.5%and 50.0%rolling reductions,those with 62.5%rolling reductions allow for more effective improvements in the mechanical properties after annealing treatment due to their relatively high mechanical incompatibility across the interface.During tensile deformation,with the increased magnitude of incompatibility in the 2560-layered Al/Al LMC with a heterogeneous lamellar structure,the densities of the geometrically necessary dislocations(GNDs)increase to accommodate the relatively large strain gradient,resulting in considerable back stress strengthening and improved mechanical properties.展开更多
The methods for reducing interface aperture inconsistency are studied in NC orbital milling(NCOM)of CFRP/Ti6Al4V laminates with coarse pitch.Comparative experiments show burr,aperture inconsistency and error are typic...The methods for reducing interface aperture inconsistency are studied in NC orbital milling(NCOM)of CFRP/Ti6Al4V laminates with coarse pitch.Comparative experiments show burr,aperture inconsistency and error are typical interface defects.Meanwhile,aperture inconsistency and error are more serious than burr in NCOM with coarse pitch.As one of the major causes of interface defects,axial force and radial force are intensively studied.Based upon the machining principle of orbital milling(OM)and the actual hole-making condition in laminated structures,NCOM experiments with coarse pitch are conducted on CFRP/Ti6Al4V laminates under different cutting conditions.Then,the effects of interlayer clamping,minimal quantity lubrication(MQL),twice milling instead of reaming,and interlayer speed change on interface aperture are analyzed.Research shows that interlayer clamping,interlayer speed change and MQL can effectively reduce out-of-tolerance of interface aperture.When making holes of different diameters with one cutter,axial feed has a greater effect on interface aperture precision than tangential feed.When making holes of the same diameter with different cutters,small diameter cutter will reduce interface aperture precision in a single processing.But the method of“twice milling instead of reaming”can improve the aperture precision effectively.展开更多
The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted...The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted by transmission electron microscope（TEM）, scanning electron microscope（SEM）, peeling tests and tensile tests. It is found that the ultra-fine grained laminated composites with tight bonding interface are prepared by the roll bonding technique. The annealing prompts the atomic diffusion in the interface between dissimilar matrixes, and even causes the formation of intermetallic compounds. The interfacial bonding strength increases to the maximum value owing to the interfacial solution strengthening at 300 °C annealing, but sharply decreases by the damage effect of intermetallic compounds at elevated temperatures. The composites obtain high tensile strength due to the Al crystallization grains and Cu twins at 300 °C. At 350 °C annealing, however, the composites get high elongation by the interfacial interlayer with submicron thickness.展开更多
基金financially supported by Shanxi provincial Youth Fund(No.201801D221101)the National Natural Science Foundation of China(Nos.52005362,U1810208,U1710254)Scientific and Technological Innovation Programs of Higher Education Institutions in Shanxi,China(Nos.2019L0149,2019L0994)。
文摘In-situ bending and stretching were conducted on hot-rolled and annealed Ti/Al/Mg/Al/Ti laminates,with a focus on crack initiation and propagation of intermetallics and component layers,which helps to clarify their deformation behavior and fracture forms.The results show that delamination is the early fracture form of laminate with or without intermetallics at Al/Mg interface,so Al/Mg interfacial bonding strength determines the mechanical properties of laminate.Various and irregular intermetallics cracks lead to Al/Mg interface delamination in annealed laminate and help to release stress.Necking and fracture of component layers are observed at the late deformation stage,and the sequence is Al,Mg and Ti layers,resulting from their strength.Angle between crack propagation direction and stretching direction of Mg layer both in rolled and annealed laminates is around 45°due to the effect of shear deformation,and crack convergence leads to final complete fracture of Mg layer.
文摘Plasma electrolytic oxidation(PEO)coatings were prepared on Al−Mg laminated macro composites(LMCs)using both unipolar and bipolar waveforms in an appropriate electrolyte for both aluminum and magnesium alloys.The techniques of FESEM/EDS,grazing incident beam X-ray diffraction(GIXRD),and electrochemical methods of potentiodynamic polarization and electrochemical impedance spectroscopy(EIS)were used to characterize the coatings.The results revealed that the coatings produced using the bipolar waveform exhibited lower porosity and higher thickness than those produced using the unipolar one.The corrosion performance of the specimens’cut edge was investigated using EIS after 1,8,and 12 h of immersion in a 3.5 wt.%NaCl solution.It was observed that the coating produced using the bipolar waveform demonstrated the highest corrosion resistance after 12 h of immersion,with an estimated corrosion resistance of 5.64 kΩ·cm^(2),which was approximately 3 times higher than that of the unipolar coating.Notably,no signs of galvanic corrosion were observed in the LMCs,and only minor corrosion attacks were observed on the magnesium layer in some areas.
基金supported by the National Natural Science Foundation of China(Nos.52175338 and 52222510)Science Fund for Distinguished Young Scholars of Shandong Province(No.ZR2021JQ21)+1 种基金Key Research and Development Program of Shandong Province(No.2021ZLGX01)The Excellent Young Team Project of Central Universities(No.2023QNTD002).
文摘Mg/Al laminate with ZK60Mg and TiB2/6061Al as constitute layers was fabricated through the porthole die co-extrusion and hot rolling.The effects of rolling and roll temperatures on the microstructure,interfacial structure,mechanical properties,and crack propagation paths were studied.The results show that the intermetallic compounds layer shows an intermittent form.The strong strain/dislocation hardening ability of Mg/Al laminate is attributed to the coupled effects of interlocking Al/βinterface,strain gradient,andβlayer with nanotwins and stacking faults.The complex dislocation structures such as network,loop,and array are found in the Al layer.Dislocation slip is the main deformation mode of the Al layer,while dislocation slip and dynamic recrystallization are the main deformation modes of the Mg layer.As roll temperature increases,prismatic〈a〉slip replaces the basal〈a〉slip as the most important slip mode.At a rolling temperature of 400℃ and a roll temperature of 150℃,an optimal synergy of mechanical properties is achieved,with ultimate tensile strength,shear strength,and elongation of 262.1 MPa,36.4 MPa,and 18.1%,respectively.As the rolling temperature increases,the fracture mode of Mg/Al laminate changes from discontinuous plastic shrinkage to transverse and longitudinal cracks.With increasing the roll temperature,the through cracks tend to form,indicating the plasticity and bonding quality of Mg/Al laminate are effectively enhanced.
基金the financial support from the National Natural Science Foundation of China(Nos.51875317,52222510)Key Research and Development Program of Shandong Province,China(No.2021ZLGX01)。
文摘Al/Cu laminate composite was fabricated based on hot press sintering using Cu sheet and Al powders as raw materials.The effects of sintering parameters on interfacial structure and mechanical properties were investigated.The results revealed that a uniform Al/Cu interface with excellent bonding quality was achieved.The thickness of intermetallic compounds(IMCs)reached 33.88μm after sintering at 620℃for 2 h,whereas it was only 14.88μm when sintered at 600℃for 1 h.AlCu phase was developed through the reaction between Al4Cu9 and Al2Cu with prolonging sintering time,and an amorphous oxide strip formed at AlCu/Al4Cu9 interface.Both the grain morphology and interfacial structure affected the tensile strength of Al/Cu laminate,whereas the mode of tensile fracture strongly relied on the interfacial bonding strength.The highest tensile strength of 151.1 MPa and bonding strength of 93.7 MPa were achieved after sintering at 600℃for 1 h.
基金financial support from the Special Fund for Special Posts of Guizhou University,China(No.[2022]06)the Guizhou Provincial Basic Research Program(Natural Science),China(No.ZK[2023]78)+1 种基金the National Natural Science Foundation of China(No.52365020)the Open Fund Project of Key Laboratory of Advanced Manufacturing Technology,China(No.GZUAMT2022KF[04]).
文摘1060/7050 Al/Al laminated metal composites(LMCs)with heterogeneous lamellar structures were prepared by accumulative roll bonding(ARB),cold rolling and subsequent annealing treatment.The strengthening mechanism was investigated by microstructural characterization,mechanical property tests and in-situ fracture morphology observations.The results show that microstructural differences between the constituent layers are present in the Al/Al LMCs after various numbers of ARB cycles.Compared with rolled 2560-layered Al/Al LMCs with 37.5%and 50.0%rolling reductions,those with 62.5%rolling reductions allow for more effective improvements in the mechanical properties after annealing treatment due to their relatively high mechanical incompatibility across the interface.During tensile deformation,with the increased magnitude of incompatibility in the 2560-layered Al/Al LMC with a heterogeneous lamellar structure,the densities of the geometrically necessary dislocations(GNDs)increase to accommodate the relatively large strain gradient,resulting in considerable back stress strengthening and improved mechanical properties.
基金Natural Science Research in Jiangsu Province(No.17KJB460008)the 333 Project Research Funding Project in Jiangsu Province(No.BRA2018310)the Innovation Project of Jiangsu Province.
文摘The methods for reducing interface aperture inconsistency are studied in NC orbital milling(NCOM)of CFRP/Ti6Al4V laminates with coarse pitch.Comparative experiments show burr,aperture inconsistency and error are typical interface defects.Meanwhile,aperture inconsistency and error are more serious than burr in NCOM with coarse pitch.As one of the major causes of interface defects,axial force and radial force are intensively studied.Based upon the machining principle of orbital milling(OM)and the actual hole-making condition in laminated structures,NCOM experiments with coarse pitch are conducted on CFRP/Ti6Al4V laminates under different cutting conditions.Then,the effects of interlayer clamping,minimal quantity lubrication(MQL),twice milling instead of reaming,and interlayer speed change on interface aperture are analyzed.Research shows that interlayer clamping,interlayer speed change and MQL can effectively reduce out-of-tolerance of interface aperture.When making holes of different diameters with one cutter,axial feed has a greater effect on interface aperture precision than tangential feed.When making holes of the same diameter with different cutters,small diameter cutter will reduce interface aperture precision in a single processing.But the method of“twice milling instead of reaming”can improve the aperture precision effectively.
基金Projects(50971038,51174058)supported by the National Natural Science Foundation of China
文摘The microstructural development and its effect on the mechanical properties of Al/Cu laminated composite produced by asymmetrical roll bonding and annealing were studied. The composite characterizations were conducted by transmission electron microscope（TEM）, scanning electron microscope（SEM）, peeling tests and tensile tests. It is found that the ultra-fine grained laminated composites with tight bonding interface are prepared by the roll bonding technique. The annealing prompts the atomic diffusion in the interface between dissimilar matrixes, and even causes the formation of intermetallic compounds. The interfacial bonding strength increases to the maximum value owing to the interfacial solution strengthening at 300 °C annealing, but sharply decreases by the damage effect of intermetallic compounds at elevated temperatures. The composites obtain high tensile strength due to the Al crystallization grains and Cu twins at 300 °C. At 350 °C annealing, however, the composites get high elongation by the interfacial interlayer with submicron thickness.
