The surface and bulk properties of Ce-5% La were studied with X-ray photoelectron spectroscopy (XPS)and X-ray diffraction (XRD), respectively.The XRD analysis shows that cerium in bulk is in γ-phase, and its lattice ...The surface and bulk properties of Ce-5% La were studied with X-ray photoelectron spectroscopy (XPS)and X-ray diffraction (XRD), respectively.The XRD analysis shows that cerium in bulk is in γ-phase, and its lattice parameter is 0.516 nm.And we also find Ce2O3 in the bulk from the XRD figure but no existence of metal lanthanum because of its small quantity.The XPS analysis shows that there are always oxides existing in the surface.The O1s peak always exists at the binding energy of 530.3 eV, which may be attributed to Ce2O3 and La2O3, but no evidence was found for the existence of CeO2.It is concluded that there is a thick layer of Ce2O3 on the sample surface.And the Ce3d peak show multi-split in the figure, in which there are two peaks in each region, 3d5/2 and 3d3/2, and the binding energy of these peaks are 882.86, 887.70 eV for 3d5/2, and 901.44, 905.93 eV for 3d3/2.The special phenomena can be attributed to the changes of 4f electronic configuration, and the cerium in the sample exhibits properties similar to Ce2O3.But the influence of the addition of lanthanum to cerium is not visible, and further investigations are expected.展开更多
随着我国探月工程和深空探测工程的实施,传统的地基测轨手段联合最小二乘定轨预报的模式已难以满足定轨任务的实时性需求,为此需要发展飞行器的自主测轨手段和定轨方法.本文采用扩展卡尔曼滤波算法对探月飞行器进行实时定轨研究.对CE-5T...随着我国探月工程和深空探测工程的实施,传统的地基测轨手段联合最小二乘定轨预报的模式已难以满足定轨任务的实时性需求,为此需要发展飞行器的自主测轨手段和定轨方法.本文采用扩展卡尔曼滤波算法对探月飞行器进行实时定轨研究.对CE-5T1月地转移段约2.5?h弧长的星基GNSS伪距数据进行滤波处理,计算结果表明,以预报轨道为先验参考轨道,约1?h后滤波即可稳定收敛,且收敛后轨道精度与批处理统计定轨精度相当,位置偏差(Root Mean Square,RMS)约在30?m,速度偏差好于1?cm/s.对CE-5T1环月段地基测量数据进行滤波计算,计算结果表明,对于轨道周期为2h的月球探测器,位置偏差好于50m(RMS).由于之前的定轨信息通过协方差矩阵传递保留,月球遮挡探测器以及月球升落引起的地面测轨数据长弧段间断不会影响后续可视弧段的滤波精度,且只需一两个观测数据即可快速收敛至滤波稳定.展开更多
文摘The surface and bulk properties of Ce-5% La were studied with X-ray photoelectron spectroscopy (XPS)and X-ray diffraction (XRD), respectively.The XRD analysis shows that cerium in bulk is in γ-phase, and its lattice parameter is 0.516 nm.And we also find Ce2O3 in the bulk from the XRD figure but no existence of metal lanthanum because of its small quantity.The XPS analysis shows that there are always oxides existing in the surface.The O1s peak always exists at the binding energy of 530.3 eV, which may be attributed to Ce2O3 and La2O3, but no evidence was found for the existence of CeO2.It is concluded that there is a thick layer of Ce2O3 on the sample surface.And the Ce3d peak show multi-split in the figure, in which there are two peaks in each region, 3d5/2 and 3d3/2, and the binding energy of these peaks are 882.86, 887.70 eV for 3d5/2, and 901.44, 905.93 eV for 3d3/2.The special phenomena can be attributed to the changes of 4f electronic configuration, and the cerium in the sample exhibits properties similar to Ce2O3.But the influence of the addition of lanthanum to cerium is not visible, and further investigations are expected.
文摘随着我国探月工程和深空探测工程的实施,传统的地基测轨手段联合最小二乘定轨预报的模式已难以满足定轨任务的实时性需求,为此需要发展飞行器的自主测轨手段和定轨方法.本文采用扩展卡尔曼滤波算法对探月飞行器进行实时定轨研究.对CE-5T1月地转移段约2.5?h弧长的星基GNSS伪距数据进行滤波处理,计算结果表明,以预报轨道为先验参考轨道,约1?h后滤波即可稳定收敛,且收敛后轨道精度与批处理统计定轨精度相当,位置偏差(Root Mean Square,RMS)约在30?m,速度偏差好于1?cm/s.对CE-5T1环月段地基测量数据进行滤波计算,计算结果表明,对于轨道周期为2h的月球探测器,位置偏差好于50m(RMS).由于之前的定轨信息通过协方差矩阵传递保留,月球遮挡探测器以及月球升落引起的地面测轨数据长弧段间断不会影响后续可视弧段的滤波精度,且只需一两个观测数据即可快速收敛至滤波稳定.
