For a better understanding of the feasibility of supercritieal fluid dyeing （SFD） and more available information for the process development, the experiments of dyeing PET textile with C.I. disperse red 60 （anthraq...For a better understanding of the feasibility of supercritieal fluid dyeing （SFD） and more available information for the process development, the experiments of dyeing PET textile with C.I. disperse red 60 （anthraquinone type） and C. I. disperse orange 25 （azo type） in supercritieal CO2 were carried out with a high-pressure dyeing apparatus at temperatures from 80 to 130℃ and pressure up to 31 MPa. The effect of operating conditions on color yield （K/S） was investigated in SFD experiment, and the optimum operating conditions for the above two disperse dyes were obtained as follows： the temperature 120℃, the pressure 25 MPa and the dyeing time 100 min. As compared with SFD, the conventional water dyeing （CWD） was carried out with the same dyes and textile. The results show that the better fastness, levelness and apparent color can be achieved in SFD and the SFD process has many significant advantages over the CWD process.展开更多
等离子体处理作为一种高效的表面改性技术,在二维纳米材料/碳基复合结构的形貌调控中具有独特优势。本文通过调控等离子体处理参数(例如气体氛围),研究其对二硫化钨/碳(WS2/C)复合结构表面形貌和缺陷分布的影响。结合扫描电子显微镜(Sca...等离子体处理作为一种高效的表面改性技术,在二维纳米材料/碳基复合结构的形貌调控中具有独特优势。本文通过调控等离子体处理参数(例如气体氛围),研究其对二硫化钨/碳(WS2/C)复合结构表面形貌和缺陷分布的影响。结合扫描电子显微镜(Scanning Electron Microscope,SEM)和基于拉曼光谱的表征,揭示了等离子体处理诱导的WS2边缘选择性和碳纳米纤维骨架的协同效应,提高了复合材料的比表面积和边缘活性位点暴露程度。试验结果表明,参数优化后,等离子体处理可以有效调控WS2纳米晶片在碳纤维骨架中的分散性,并抑制晶片层间堆叠和层片团聚,从而增加边缘位置的暴露程度。该研究为高性能WS2/C复合材料的可控制备提供了新思路,推动其在能源存储与转换领域的实际应用。展开更多
基金Supported by National Natural Science Foundation of China(No.20277004)
文摘For a better understanding of the feasibility of supercritieal fluid dyeing （SFD） and more available information for the process development, the experiments of dyeing PET textile with C.I. disperse red 60 （anthraquinone type） and C. I. disperse orange 25 （azo type） in supercritieal CO2 were carried out with a high-pressure dyeing apparatus at temperatures from 80 to 130℃ and pressure up to 31 MPa. The effect of operating conditions on color yield （K/S） was investigated in SFD experiment, and the optimum operating conditions for the above two disperse dyes were obtained as follows： the temperature 120℃, the pressure 25 MPa and the dyeing time 100 min. As compared with SFD, the conventional water dyeing （CWD） was carried out with the same dyes and textile. The results show that the better fastness, levelness and apparent color can be achieved in SFD and the SFD process has many significant advantages over the CWD process.
文摘等离子体处理作为一种高效的表面改性技术,在二维纳米材料/碳基复合结构的形貌调控中具有独特优势。本文通过调控等离子体处理参数(例如气体氛围),研究其对二硫化钨/碳(WS2/C)复合结构表面形貌和缺陷分布的影响。结合扫描电子显微镜(Scanning Electron Microscope,SEM)和基于拉曼光谱的表征,揭示了等离子体处理诱导的WS2边缘选择性和碳纳米纤维骨架的协同效应,提高了复合材料的比表面积和边缘活性位点暴露程度。试验结果表明,参数优化后,等离子体处理可以有效调控WS2纳米晶片在碳纤维骨架中的分散性,并抑制晶片层间堆叠和层片团聚,从而增加边缘位置的暴露程度。该研究为高性能WS2/C复合材料的可控制备提供了新思路,推动其在能源存储与转换领域的实际应用。
