Soil sulfur fractions, including monocalcium phosphate-extractable S, slowly soluble inorganic S, C- O-S ,C-bonded S and unidentified organic S, were analyzed for 48 soils, as representatives of 6 major groups ofupl...Soil sulfur fractions, including monocalcium phosphate-extractable S, slowly soluble inorganic S, C- O-S ,C-bonded S and unidentified organic S, were analyzed for 48 soils, as representatives of 6 major groups ofupland soils, fiuvisol, cinnamon soil, loessial soil, chestnut soil, black soil and brown soil, in North China.The contemns of total S and monocalcium phosphate-extractable S in the above 48 soils ranged from 234 to860 and 5.1 to 220.3 mg kg--1 , respectively, and each of 6 soil groups contained the samples with a low level ofphosph ate-extractable S. Great differences in the average contents of each fraction of S were observed amongthe above 6 soil groups. Expressed as average percentage of the total S in soils, fiuvisols, cinnamon soils,loessial soils, chestnut soils, black soils and brown soils contained 6.1%, 9.5%, 5.7%, 13.2%, 3.5% and 6.8%monocalcium phosphate-extractable S, 5. 7%, 3. 0%, 9. 3%, 1 0. 4%, 3. 2% and 3. 1 % slowly soluble inorganic S ,51.6%, 26.7%, 17.4%, 31.2%, 28.9% and 22.7% C-O-S, 11.0%, 9.1%, 6.6%, 6.8%, 9.7% and 9.4% in C-bondedS, and 25.6%, 51.7%, 60.8%, 38.4%, 54.7% and 53.0% unidentified organic S, respectively. For the above 6groups of soils, the mean C/N ratios were remarkably similar, ranging from 9.7 to 10.7, while the mean N/Sratios ranged from 1.16 to 3.12. The highest ratios of C/N, C/C-O-S and C/C-bonded S were found in blacksoils, averaging 30.4, 104.9 and 314.7, respectively, while the lowest ratios arose in chestnut soil, averaging12.4, 39.7 and 183.3, respectively.展开更多
1 Results Free radical reactions have become increasingly important,as well as a very attractive tool,in organic synthesis within the last two decades,due to their powerful,selective,specific,and mild reaction abiliti...1 Results Free radical reactions have become increasingly important,as well as a very attractive tool,in organic synthesis within the last two decades,due to their powerful,selective,specific,and mild reaction abilities.Mn(OAc)3 mediated oxidative free radical reactions have been extensively developed in the last twenty years[1,6].Numerous regio-,chemo-,and stereoselective synthetic methods have been developed in both inter-and intramolecular reactions,and have detailed the progress of Mn(OAc)3 mediated...展开更多
文摘Soil sulfur fractions, including monocalcium phosphate-extractable S, slowly soluble inorganic S, C- O-S ,C-bonded S and unidentified organic S, were analyzed for 48 soils, as representatives of 6 major groups ofupland soils, fiuvisol, cinnamon soil, loessial soil, chestnut soil, black soil and brown soil, in North China.The contemns of total S and monocalcium phosphate-extractable S in the above 48 soils ranged from 234 to860 and 5.1 to 220.3 mg kg--1 , respectively, and each of 6 soil groups contained the samples with a low level ofphosph ate-extractable S. Great differences in the average contents of each fraction of S were observed amongthe above 6 soil groups. Expressed as average percentage of the total S in soils, fiuvisols, cinnamon soils,loessial soils, chestnut soils, black soils and brown soils contained 6.1%, 9.5%, 5.7%, 13.2%, 3.5% and 6.8%monocalcium phosphate-extractable S, 5. 7%, 3. 0%, 9. 3%, 1 0. 4%, 3. 2% and 3. 1 % slowly soluble inorganic S ,51.6%, 26.7%, 17.4%, 31.2%, 28.9% and 22.7% C-O-S, 11.0%, 9.1%, 6.6%, 6.8%, 9.7% and 9.4% in C-bondedS, and 25.6%, 51.7%, 60.8%, 38.4%, 54.7% and 53.0% unidentified organic S, respectively. For the above 6groups of soils, the mean C/N ratios were remarkably similar, ranging from 9.7 to 10.7, while the mean N/Sratios ranged from 1.16 to 3.12. The highest ratios of C/N, C/C-O-S and C/C-bonded S were found in blacksoils, averaging 30.4, 104.9 and 314.7, respectively, while the lowest ratios arose in chestnut soil, averaging12.4, 39.7 and 183.3, respectively.
文摘1 Results Free radical reactions have become increasingly important,as well as a very attractive tool,in organic synthesis within the last two decades,due to their powerful,selective,specific,and mild reaction abilities.Mn(OAc)3 mediated oxidative free radical reactions have been extensively developed in the last twenty years[1,6].Numerous regio-,chemo-,and stereoselective synthetic methods have been developed in both inter-and intramolecular reactions,and have detailed the progress of Mn(OAc)3 mediated...
