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Ce-PbO_2/C电极的制备及其去除水中酸性红B 被引量:5
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作者 杨丽娟 魏杰 胡翔 《环境工程学报》 CAS CSCD 北大核心 2014年第3期941-947,共7页
采用电沉积法制备铈修饰的PbO2/C电极,通过SEM、XRD、XPS及循环伏安对PbO2/C、Ce-PbO2/C电极进行表征,结果表明,Ce-PbO2/C电极比PbO2/C颗粒细小,表面均匀致密,电化学氧化能力较强,修饰电极中Ce以CeO2的形态存在。以Ce-PbO2/C为工作电极... 采用电沉积法制备铈修饰的PbO2/C电极,通过SEM、XRD、XPS及循环伏安对PbO2/C、Ce-PbO2/C电极进行表征,结果表明,Ce-PbO2/C电极比PbO2/C颗粒细小,表面均匀致密,电化学氧化能力较强,修饰电极中Ce以CeO2的形态存在。以Ce-PbO2/C为工作电极,电解浓度为1 000 mg/L的高盐酸性红B模拟活性染料废水,考察了电压、pH、电解质浓度、极间距对脱色率、氨氮去除率及COD去除率的影响。确定适宜工艺条件为:初始酸性红B溶液浓度为1 000 mg/L,pH值为6,电压10 V,电解时间1 h,电极间距1.5 cm,该条件下脱色率、氨氮去除率和COD去除率分别为99.98%、97.23%和90.17%。通过UV-Vis及GC-MS初步分析了降解过程可能存在的中间产物及降解途径。 展开更多
关键词 ce-pbo2 c 电极表征 电化学氧化 酸性红B
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Studies on Degradation of Diquat Pesticide in Aqueous Solutions Using Electrochemical Method
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作者 Nasser Abu Ghalwa Hazem M. Abu-Shawish +2 位作者 Mazen Hamada Khaled Hartani Abed Al Hakem Basheer 《American Journal of Analytical Chemistry》 2012年第2期99-105,共7页
The C/PbO2 electrode assisted electrochemical removal of diquat dibromide herbicides solutions has been the subject of the present investigation under several operating conditions. The optimum conditions of the treatm... The C/PbO2 electrode assisted electrochemical removal of diquat dibromide herbicides solutions has been the subject of the present investigation under several operating conditions. The optimum conditions of the treatment process are: current density of 150 mA/cm2, pH 2.2, NaCl concentration 2 g/L, temperature of 10?C and initial diquat concentration of 50 mg/L. The time of electrolysis is 60 min for degradation rate of diquat and chemical oxygen demand (COD) removal is 210 min. The results were obtained by UV-Vis spectrophotometer and the present designed electrode was coincident. 展开更多
关键词 carbon Paste ELEcTRODE HERBIcIDE c/pbo2 ELEcTRODE ELEcTROOXIDATION DIQUAT Dibromide
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