Odor pollution in landfill area has attracted more social attention in China. It is very important to control the generation of odor pollutants in situ. Analyzing odorous materials production form buried waste, simula...Odor pollution in landfill area has attracted more social attention in China. It is very important to control the generation of odor pollutants in situ. Analyzing odorous materials production form buried waste, simulated columns of different volatile solid (VS) content and different buried period waste were designed. Gas compounds produced from the columns were collected and analyzed by comprehensive two-dimensional gas chromatography (GC × GC) method. It has remarkable relationship between VS content and concentrations of odorous material. When VS content more than 40%, the total amount of odorous compounds increases remarkably. It can be inferred that reduced VS content of original waste may effective decreasing odorous materials production in landfill area. The old rubbish produced more odorous compounds than that of fresh one in simulated columns.展开更多
Acorns of Quercus aliena var. acuteserrata Maxim. are often predated by small mammals and birds in natural forests. These animals not only eat the acorns during the acorn ripening season, but also cache and hoard most...Acorns of Quercus aliena var. acuteserrata Maxim. are often predated by small mammals and birds in natural forests. These animals not only eat the acorns during the acorn ripening season, but also cache and hoard most of the remaining acorns on the forest floor in the soil for their future use. These buried acorns form the main seed resource for regeneration. Burying depth is potentially important for germination and for seedling development. The effects of burying depth on germination and seedling development in relation to acorn size were studied in an experiment, in which acorns were planted at 6 cm-, 12 cm- and 18 cm-depth. The experimental results showed that fewer acorns germinated as burying depth increased. From the deeply buried acorns fewer seedlings emerged at later time than from those acorns buried less deeply. They appeared to have more difficulties to emerge above-ground than die seedlings from shallowly buried acorns. The deeply buried acorns and their seedlings also appeared to be more susceptible to rot. Acorn size did not significantly affect germination and emergence of the seedlings. As early emerged seedlings had longer developmental periods in their first growing season, and therefore grew better than die late emerged seedlings, seedlings from die shallowly buried acorns took the advantage.展开更多
In order to address the low soil breaking rate,poor soil covering performance,and low working efficiency of the existing 3MT-1.8 and PMT-75 grapevine burying machines,two types of improved burying machines,namely the ...In order to address the low soil breaking rate,poor soil covering performance,and low working efficiency of the existing 3MT-1.8 and PMT-75 grapevine burying machines,two types of improved burying machines,namely the 3MTLJ-1.8 and 3MTXP-1.8,were developed in consideration of the local Ningxia soil conditions.Field experimental results indicated that the soil breaking rate of the 3MTLJ-1.8 machine was 71.44%,and its soil sampling volume increased by approximately 30%compared to that of the 3MT-1.8 machine.It was verified that the self-developed 3MTLJ-1.8 machine can be used in the southern regions of Ningxia.Furthermore,the soil sampling volume of the 3MTXP-1.8 burying machine was 0.24 m^(3)/m,and its soil breaking rate increased by more than 41.42%compared to the standard required volume.The 3MTXP-1.8 machine can be used in the northern areas of Ningxia,where the soil hardness is higher.The results can provide a reference for the development and popularization of grapevine burying machines in Ningxia.展开更多
Burying beetles (Nicrophorus sp.) are necrophagous insects with developed parental care. Genome of Nicrophorus vespilloides has been recently sequenced, which makes them interesting model organism in behavioral ecolog...Burying beetles (Nicrophorus sp.) are necrophagous insects with developed parental care. Genome of Nicrophorus vespilloides has been recently sequenced, which makes them interesting model organism in behavioral ecology. However, we know very little about their physiology, including the functioning of their neuroendocrine system. In this study, one of the physiological activities of proctolin, myosuppressin (Nieve? MS), myoinhibitory peptide (Trica-MIP-5) and the short neuropeptide F (Nicve-sNPF) in N. vespilloides have been investigated. The tested neuropeptides were myoactive on N. vespilloides hindgut. After application of the proctolin increased hindgut contraction frequency was observed (EC50 value was 5.47 x 10-8 mol/L). The other tested neuropeptides led to inhibition of N. vespilloides hindgut contractions (Nicve-MS: IC50 = 5.20 x 10~5 mol/L;Trica-MIP-5: IC50 = 5.95 x 10-6 mol/L;Nicvc-sNPF: IC50 = 4.08 x 10-5 mol/L). Moreover, the tested neuropeptides were immunolocalized in the nervous system of N. vespilloides. Neurons containing sNPF and MIP in brain and ventral nerve cord (VNC) were identified. Proctolin-immunolabeled neurons only in VNC were observed. Moreover, MIP-immunolabeled varicosities and fibers in retrocerebral complex were observed. In addition, our results have been supplemented with alignments of amino acid sequences of these neuropeptides in beetle species. This alignment analysis clearly showed amino acid sequence similarities between neuropeptides. Moreover, this allowed to deduce amino acid sequence of N. vespilloides proctolin (RYLPTa), Nicve-MS (QDVDHVFLRFa) and six isoforms ofNicve-MIP (Nicve-MIP-1一 DWNRNLHSWa;Nicve-MIP-2—AWQNLQGGWa;Nicve-MIP-3—AWQNLQGGWa;Nicve-MlP-4—AWKNLNNAGWa;Nicve-MIP-5—SEWGNFRGSWa;Nicve-MIP-6— DPAWTNLKGIWa;and Nicve-sNPF—SGRSPSLRLRFa).展开更多
Insect overwintering is one of the most astonishing phases of the insect life cycle. Despite vast amounts of knowledge available about the physiological mechanisms of this phenomenon, the impact of stress factors on i...Insect overwintering is one of the most astonishing phases of the insect life cycle. Despite vast amounts of knowledge available about the physiological mechanisms of this phenomenon, the impact of stress factors on insect immune system functioning during the winter is still unknown. The aim of this study is to analyze how low temperatures influence the immune system of the beetle Nic＇rophorus vespilloides. The results show that the beetle＇s immune system is differently modulated by cold induced in laboratory settings than that which occurs in natural conditions, Among beetles cultured in conditions similar to summer, low temperatures, did not influence the number of circulating haemocytes, phenoloxidase activity, haemocytes morphology, and percentage ratio of haemocyte types. In these beetles, differences were noted only in the ability of haemocytes to perform phagocytosis. Individuals acclimated in natural conditions in autumn had a higher level of humoral response and a different percentage ratio of haemocyte types. During the winter period, the number of haemocytes in the beetles decreased, but the percentage ratio of phagocytic haemocytes increased. Furthermore, we noted an increase of phenoloxidase activity. Our study also showed mitotic divisions ofhaemocytes in haemolymph collected from burying beetles after cold exposure and from burying beetles collected from natural conditions during autumn and winter. Differences in response to low temperatures in laboratory conditions and the natural environment suggest that the simultaneous presence of other stress factors during winter such as desiccation and starvation have a significant influence on the activity of burying beetle＇s immune system.展开更多
While the moisture content of soil affects significantly the blast impulse of shallow buried explosives,the role of surface-covering water(SCW)on soil in such blast impulse remains elusive.A combined experimental and ...While the moisture content of soil affects significantly the blast impulse of shallow buried explosives,the role of surface-covering water(SCW)on soil in such blast impulse remains elusive.A combined experimental and numerical study has been carried out to characterize the effect of SCW on transferred impulse and loading magnitude of shallow buried explosives.Firstly,blast tests of shallow buried explosives were conducted,with and without the SCW,to quantitatively assess the blast loading impulse.Subsequently,finite element(FE)simulations were performed and validated against experimental measurement,with good agreement achieved.The validated FE model was then employed to predict the dynamic response of a fully-clamped metallic circular target,subjected to the explosive impact of shallow buried explosives with SCW,and explore the corresponding physical mechanisms.It was demonstrated that shallow buried explosives in saturated soil generate a greater impulse transferred towards the target relative to those in dry soil.The deformation displacement of the target plate is doubled.Increasing the height of SCW results in enhanced center peak deflection of the loaded target,accompanied by subsequent fall,due to the variation of deformation pattern of the loaded target from concentrated load to uniform load.Meanwhile,the presence of SCW increases the blast impulse transferred towards the target by three times.In addition,there exists a threshold value of the burial depth that maximizes the impact impulse.This threshold exhibits a strong sensitivity to SCW height,decreasing with increasing SCW height.An empirical formula for predicting threshold has been provided.Similar conclusions can be drawn for different explosive masses.The results provide technical guidance on blast loading intensity and its spatial distribution considering shallow buried explosives in coast-land battlefields,which can ultimately contribute to better protective designs.展开更多
Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numeri...Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numerical parameter analysis is conducted on the key influencing factors of the vibration isolation hole(VIH),which include hole diameter,hole net spacing,hole depth,hole number,hole arrangement,and soil parameters.The results indicate that a smaller ratio of net spacing to hole diameter,the deeper the hole,the multi-row hole,the hole adoption of staggered arrangements,and better site soil conditions can enhance the efficiency of the VIH barrier.The average maximum vibration reduction efficiency within the vibration isolation area can reach 42.2%.The vibration safety of adjacent oil pipelines during a dynamic compaction projection was evaluated according to existing standards,and the measurement of the VIH was recommended to reduce excessive vibration.The single-row vibration isolation scheme and three-row staggered arrangement with the same hole parameters are suggested according to different cases.The research findings can serve as a reference for the vibration safety analysis,assessment,and control of adjacent underground facilities under the influence of strong surface impact loads.展开更多
Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization proces...Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization processes lead to different order of crystallization dynamics within the perovskite thin film,resulting in the differences of additive distribution.We then tailor-designed an additive molecule named 1,3-bis(4-methoxyphenyl)thiourea to obtain films with fewer defects and holes at the buried interface,and prepared perovskite solar cells with a certified efficiency of 23.75%.Furthermore,this work also demonstrates an efficiency of 20.18%for the large-area perovskite solar module(PSM)with an aperture area of 60.84 cm^(2).The PSM possesses remarkable continuous operation stability for maximum power point tracking of T_(90)>1000 h in ambient air.展开更多
As one of the important components of high-effi-ciency perovskite/silicon series devices,wide-bandgap(WBG)perovskite solar cells(PSCs)have been suffering from serious carrier transport barriers and huge open-circuit v...As one of the important components of high-effi-ciency perovskite/silicon series devices,wide-bandgap(WBG)perovskite solar cells(PSCs)have been suffering from serious carrier transport barriers and huge open-circuit voltage deficit de-rived from non-radiative recombination,especial-ly at the buried interface that are often overlooked.Herein,we combined cationic and anion passiva-tion strategies via ammonium tetra-n-butyl tetrafluoroborate(TBABF_(4))pre-treating the buried interface.Theoretical calculation predicts that the tetrabutylammonium(TBA^(+))organic cations and(tetrafluoroborate)BF_(4)^(−)anions can easily interact with charged interfacial defect.Characterizations further confirm the enhance-ment of carrier transport performance and decrease in defect density upon TBABF4 pre-treat-ment.Consequently,a power conversion efficiency of 21.35%with an ultrahigh filling factor of 84.12%is obtained for 1.68 eV-WBG inverted PSCs.In addition,the device with TBABF4 pre-treatment demonstrates excellent shelf,thermal,and operational stability.展开更多
Since the 1950's,212 earth fissures have been discovered in the Wei River Basin.During a field survey in 2016,an additional 48 earth fissures were discovered in Anren area,northeast of the Wei River Basin.The char...Since the 1950's,212 earth fissures have been discovered in the Wei River Basin.During a field survey in 2016,an additional 48 earth fissures were discovered in Anren area,northeast of the Wei River Basin.The characteristics and formation mechanisms of these fissures were studied through field investigations,measurements,trench excavation,and drilling.On-site investigations indicated that these earth fissures were distributed along a fault-controlled geomorphic boundary.Fissures trended at 60°-80°NE and were divided into five groups.Trenches revealed multiple secondary fissures,exposing severe soil ruptures in the shallow earth surfaces.Drilling profiles revealed that earth fissures dislocated several strata,and resembled synsedimentary faults.Seismic reflection profiles revealed buried faults beneath the earth fissures.The Anren area fissures formed in the following three stages:regional extension that initially generated multiple buried faults;seismic activity rupturing multiple strata,resulting in multiple buried fractures;and finally,erosion processes that propagated the buried fractures to the surface,forming the current earth fissures.展开更多
This pictorial review discusses the imaging approach to evaluate for proper placement or complications of pediatric gastrostomy tube(G-tube)placement and long-term use.G-tubes are crucial for long-term nutritional sup...This pictorial review discusses the imaging approach to evaluate for proper placement or complications of pediatric gastrostomy tube(G-tube)placement and long-term use.G-tubes are crucial for long-term nutritional support in patients facing challenges with oral intake.The article depicts the role of imaging such as contrast radiography,fluoroscopy,ultrasound,and computed tomography scans for confirming G-tube position and evaluating complications,in addition to basic anatomical considerations and placement techniques.Complications discussed include malposition,intraperitoneal placement,buried bumper syndrome,and tube malfunction.Specific imaging techniques and checklists are provided to guide clinicians in assessing G-tube placement accurately.The latter half of the review is a comprehensive exploration of pearls and pitfalls of imaging when employed to detect complications to avoid false positives and negatives.展开更多
Numerous defects at the buried interface of perovskite film and the exacerbated oxidation and degradation of tin-lead(Sn-Pb)perovskites induced by poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS),du...Numerous defects at the buried interface of perovskite film and the exacerbated oxidation and degradation of tin-lead(Sn-Pb)perovskites induced by poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS),due to its hygroscopic and acidic nature,limit performance improvement of SnPb perovskite solar cells(PSCs).To address these issues,1-Ethyl-3-Guanidinothiourea-Hydrochloride(EGH)was employed as a multifunctional modifier at the PEDOT:PSS/perovskite interface to regulate the buried interface behaviors of Sn-Pb PSCs.EGH can not only passivate the defects of the perovskite buried interface and regulate the work function of PEDOT:PSS for a more matched interface energy level,but also prevent the perovskite film from erosion damage by the acidic PEDOT:PSS for a more stable PEDOT:PSS/perovskite interface.Moreover,the interfacial charge transport dynamics were significantly improved by obviously suppressing interfacial non-radiative recombination losses.As a consequence,EGH-tailored 1.25 eV Sn-Pb PSCs yielded a champion PCE of 23.20%,featuring enhanced long-term stability.展开更多
The development of guidance technology has made it possible for the earth penetration weapons(EPWs)to impact the target repeatedly at a close range. To investigative the damage of single and sequential strike induced ...The development of guidance technology has made it possible for the earth penetration weapons(EPWs)to impact the target repeatedly at a close range. To investigative the damage of single and sequential strike induced by the EPWs, experimental and numerical investigations are carried out in this paper.Firstly, a series of sequential explosion tests are conducted to provide the basic data of the crater size.Then, a numerical model is established to simulate the damage effects of sequential explosions using the meshfree method of Smoothed particle Galerkin. The effectiveness of numerical model is verified by comparison with the experimental results. Finally, based on dimensional analysis, several empirical formulas for describing the crater size are presented, including the conical crater diameter and the conical crater depth of the single explosion, the conical crater area and the joint depth of the secondary explosion. The formula for the single explosion expresses the relationship between the aspect ratio of the charge ranging from 3 to 7, the dimensionless buried depth ranging from 2 to 14 and the crater size. The formula for the secondary explosion expresses the relationship between the relative position of the two explosions and the crater size. All of data can provide reference for the design of protective structures.展开更多
Interface modification has been demonstrated as an effective means to enhance the performance of perovskite solar cells.However,the effect depends on the anchoring mode and strength of the interfacial molecules,which ...Interface modification has been demonstrated as an effective means to enhance the performance of perovskite solar cells.However,the effect depends on the anchoring mode and strength of the interfacial molecules,which determines whether long-term robust interface for carrier viaduct can be achieved under operational light illumination.Herein,we select squaric acid(SA)as the interfacial molecule between the perovskite and SnO_(2)layer and propose a selfregulated bilateral anchoring strategy.The unique four-membered ring conjugated structure and dicarboxylic acid groups facilitate stable hydrogen bonds and coordination bonds at both SnO_(2)/SA and SA/PbI_(2)interfaces.The self-transforming property of SA enables the dynamic bilateral anchoring at the buried interface,ultimately releasing residual stress and constructing a stable interfacial molecular bridge.The results show that SA molecular bridge not only can effectively inhibit the generation of diverse charged defects but also serves as an effective electron transport pathway,resulting in improved power conversion efficiency(PCE)from 23.19 to 25.50%and excellent stability at the maximum power point.Additionally,the PCEs of the flexible and large-area(1 cm^(2))devices were increased to 24.92%and 24.01%,respectively,demonstrating the universal applicability of the bilateral anchoring to PSCs based on different substrates and larger area.展开更多
Based on drilling,mud logging,core,seismic and imaging logging data,this paper studies the identification and evolution process of negative inversion structures in the Carboniferous buried hills in the No.1 and No.2 f...Based on drilling,mud logging,core,seismic and imaging logging data,this paper studies the identification and evolution process of negative inversion structures in the Carboniferous buried hills in the No.1 and No.2 fault zones of Weixinan Sag,Beibu Gulf Basin,China,and reveals the controls of these structures on high-quality reservoirs.The No.2 fault zone develops significant negative inversion structures in the Carboniferous buried hills,as a result of multi-stage transformations of compressive-tensile stress fields in the period from the Late Hercynian to the Himalayan.The Hercynian carbonates laid the material basis for the formation of high-quality reservoirs.The negative inversion structures mainly control the development of high-quality reservoirs in buried hills through:(1)creating large-scale fractures to increase reservoir space and improve oil-gas flow pathways;(2)regulating stratigraphic differential denudation to highlight dominant lithology for later reservoir transformation;(3)shaping the paleogeomorphological highlands to provide favorable conditions for superficial karstification.The negative inversion structures form a high-quality,composite reservoir space with the synergistic existence of superficial dissolution fractures/cavities and burial-enhanced karst systems through the coupling of fracture network creation,formation denudation screening and multi-stage karst transformation.The research results have guided the breakthrough of the first exploratory well with a daily oil production over 1000 m^(3)in carbonate buried-hill reservoir in the Beibu Gulf Basin,and provide referential geological basis for finding more reserves and achieving higher production in the Carboniferous buried hills in the Weixinan Sag.展开更多
Weijia Guyot,located in the western Pacific Ocean,has become a research focus due to its abundant cobalt-rich ferromanganese(Fe-Mn)crusts.While most studies on Fe-Mn crusts on seamounts have focused on the exposed var...Weijia Guyot,located in the western Pacific Ocean,has become a research focus due to its abundant cobalt-rich ferromanganese(Fe-Mn)crusts.While most studies on Fe-Mn crusts on seamounts have focused on the exposed variety,less attention has been paid to potential buried crusts.This study presents a preliminary geochemical and chronological study of buried Fe-Mn crusts at Weijia Guyot.The findings suggest that these buried crusts began to form around 57.5 Ma and ceased growing at approximately 46.3 Ma.Following the formation of Weijia Guyot through volcanic eruption,it did not experience continuous and steady subsidence to its current depth.Instead,an exhumation process took place from deep to shallow depths between 46.3 and 11.6 Ma.This process brought the Fe-Mn crusts into shallow water environments,halting their growth.During this time,Weijia Guyot was located near the equatorial Pacific Ocean and was exposed to an extended period of phosphatization.This exposure led to a depletion of key metallogenic elements,such as Co,Ni and Cu,within the Fe-Mn crusts,while P2O5 and CaO levels increased significantly.Since the Middle Miocene,the crusts have been progressively buried by pelagic sediments.展开更多
The BZ oilfield in the Bohai Sea is a rare,highly volatile reservoir with fractures in the metamorphic rocks of buried hills.Clarifying the mechanism of gas injection for improving oil recovery and determining the opt...The BZ oilfield in the Bohai Sea is a rare,highly volatile reservoir with fractures in the metamorphic rocks of buried hills.Clarifying the mechanism of gas injection for improving oil recovery and determining the optimal way to deploy injection-production well networks are critical issues that must be urgently addressed for efficient oilfield development.Experimental research on the mixed-phase displacement mechanism through gas injection into indoor formation fluids was conducted to guide the efficient development of gas injection in oil fields.We established a model of dual-medium reservoir composition and researched the deployment strategy for a three-dimensional well network for gas injection development.The coupling relationship between key influencing factors of the well network and fracture development was also quantitatively analyzed.The results show that the solubility of the associated gas and strong volatile oil system injected into the BZ oilfield is high.This high solubility demonstrates a mixed-phase displacement mechanism involving intermediate hydrocarbons,dissolution and condensation of medium components,and coexistence of extraction processes.Injecting gas and crude oil can achieve a favorable mixing effect when the local formation pressure is greater than 35.79 MPa.Associated gas reinjection is recommended to supplement energy for developing the highly volatile oil reservoirs in the fractured buried hills of the BZ oilfield.This recommendation involves fully utilizing the structural position and gravity-assisted oil displacement mechanism to deploy an injection-production well network.Gas injection points should be constructed at the top of high areas,and oil production points should be placed at the middle and lower parts of low areas.This approach forms a spatial threedimensional well network.By adopting high inclination well development,the oil production well forms a 45°angle with the fracture direction,which increases the drainage area and enhances single-well production capacity.The optimal injection-production well spacing along the fracture direction is approximately 1000 m,while the reasonable well spacing in the vertical fracture direction is approximately 800 m.The research results were applied to the development practice of the buried hills in the BZ oilfield,which achieved favorable development results.These outcomes provide a valuable reference for the formulation of development plans and efficient gas injection development in similar oil and gas fields in buried hills.展开更多
Deeply buried mountain tunnels are often exposed to the risk of rock bursts,which always cause serious damage to the supporting structures and threaten the safety of the engineers.Due to the limited data available,a s...Deeply buried mountain tunnels are often exposed to the risk of rock bursts,which always cause serious damage to the supporting structures and threaten the safety of the engineers.Due to the limited data available,a suitable approach to predict the rockburst tendency at the preliminary stage becomes very important.In this study,an integrated methodology combining 3D initial stress inversion and rockburst tendency prediction was developed and subsequently applied to a case study of the Sangzhuling Tunnel on the Sichuan–Tibet Railway.The numerical modelling involved inverting the initial stress field using a multiple linear regression method.The tunnel excavation was simulated separately by FDM and DEM,based on a stress boundary condition from the inverted stress field.The comparative analysis demonstrates that the rockburst ratio calculated using DEM(76.70%)exhibits a slight increase compared to FDM(75.38%),and the rockburst location is consistent with the actual situation.This suggests that DEM is more suitable for simulating the stress redistribution during excavation in a jointed rock mass.The numerical simulation combined with the deviatoric stress approach effectively predicts rockburst tendency,meeting the engineering requirements.Despite its limitations,numerical simulation remains a reliable method for predicting rock bursts.展开更多
Tin oxide has emerged as a promising electron transport material in perovskite solar cells due to its high conductivity and photostability.However,the inherent defects in SnO_(2)nanoparticles and their imperfect bondi...Tin oxide has emerged as a promising electron transport material in perovskite solar cells due to its high conductivity and photostability.However,the inherent defects in SnO_(2)nanoparticles and their imperfect bonding with perovskite at the interface lead to additional energy loss.To achieve bifacial passivation on the SnO_(2)electron transport layer and the SnO_(2)/perovskite interface synchronously,a multifunctional surface modulation strategy has been developed by incorporating O-phospho-L-serine monolithium salt(PSLi)to regulate the SnO_(2)nanoparticles.PS-Li coordinates with SnO_(2)through the phosphate/carboxyl groups,with the exposed amino group passivating the uncoordinated lead ions at the interface.The introduction of a lithium ion further regulates the energy band of SnO_(2),accelerating electron extraction and transport.This multifunctional modulation strategy reduces trap states from tin dangling bonds and oxygen vacancies,enhancing film conductivity.It also regulates the growth of the perovskite crystal and reduces nonradiative recombination at the interface.Consequently,the optimized perovskite solar cells achieve power conversion efficiencies(PCEs)of 24.91% for small-area devices and 23.14% for minimodules(aperture area of 30 cm^(2)).The unencapsulated device retains 91% and 89% of its initial PCE after enduring 1000 h under ambient conditions,and 500 h under 1 sun illumination in N2atmosphere,respectively.展开更多
Uneven terrain significantly increases the seismic risk of tunnels in loess deposits.To investigate the variations in optimal intensity measures(IMs)for shallowly buried loess tunnels considering biased terrain,nonlin...Uneven terrain significantly increases the seismic risk of tunnels in loess deposits.To investigate the variations in optimal intensity measures(IMs)for shallowly buried loess tunnels considering biased terrain,nonlinear dynamic analyses were conducted to obtain seismic responses validated by the actual damage pattern.Then IMs were evaluated based on the automatic calculation of the time history damage index fulfilled by a compiled Python program.Results showed that the plastic strain zone progressively developed and extended from the vault to the central slope surface with increasing seismic intensities,ultimately causing shear failure to the tunnel.For IMs at the slope top,peak ground velocity(PGV)(ζ=0.15),velocity spectrum intensity(VSI)(ζ=0.20),and peak spectrum velocity(PSv)(ζ=0.22)were all suitable for seismic fragility assessment.The VSI(ζ=0.17)was optimal,followed by PGV(ζ=0.19)and PSv(ζ=0.2)for those at the slope foot.Acceleration-related IMs were more sensitive to terrain variation.Comparative analyses demonstrated smaller damage probabilities for the IMs at the slope top than those at the slope foot under the same intensity level.The impact of unfavorable terrain on tunnels was accentuated as those located in uneven mountainous regions became more vulnerable to ground shaking.展开更多
文摘Odor pollution in landfill area has attracted more social attention in China. It is very important to control the generation of odor pollutants in situ. Analyzing odorous materials production form buried waste, simulated columns of different volatile solid (VS) content and different buried period waste were designed. Gas compounds produced from the columns were collected and analyzed by comprehensive two-dimensional gas chromatography (GC × GC) method. It has remarkable relationship between VS content and concentrations of odorous material. When VS content more than 40%, the total amount of odorous compounds increases remarkably. It can be inferred that reduced VS content of original waste may effective decreasing odorous materials production in landfill area. The old rubbish produced more odorous compounds than that of fresh one in simulated columns.
文摘Acorns of Quercus aliena var. acuteserrata Maxim. are often predated by small mammals and birds in natural forests. These animals not only eat the acorns during the acorn ripening season, but also cache and hoard most of the remaining acorns on the forest floor in the soil for their future use. These buried acorns form the main seed resource for regeneration. Burying depth is potentially important for germination and for seedling development. The effects of burying depth on germination and seedling development in relation to acorn size were studied in an experiment, in which acorns were planted at 6 cm-, 12 cm- and 18 cm-depth. The experimental results showed that fewer acorns germinated as burying depth increased. From the deeply buried acorns fewer seedlings emerged at later time than from those acorns buried less deeply. They appeared to have more difficulties to emerge above-ground than die seedlings from shallowly buried acorns. The deeply buried acorns and their seedlings also appeared to be more susceptible to rot. Acorn size did not significantly affect germination and emergence of the seedlings. As early emerged seedlings had longer developmental periods in their first growing season, and therefore grew better than die late emerged seedlings, seedlings from die shallowly buried acorns took the advantage.
基金supported by the Ningxia Hui Autonomous Region Science and Technology Support Plan Project,2015BY11102.
文摘In order to address the low soil breaking rate,poor soil covering performance,and low working efficiency of the existing 3MT-1.8 and PMT-75 grapevine burying machines,two types of improved burying machines,namely the 3MTLJ-1.8 and 3MTXP-1.8,were developed in consideration of the local Ningxia soil conditions.Field experimental results indicated that the soil breaking rate of the 3MTLJ-1.8 machine was 71.44%,and its soil sampling volume increased by approximately 30%compared to that of the 3MT-1.8 machine.It was verified that the self-developed 3MTLJ-1.8 machine can be used in the southern regions of Ningxia.Furthermore,the soil sampling volume of the 3MTXP-1.8 burying machine was 0.24 m^(3)/m,and its soil breaking rate increased by more than 41.42%compared to the standard required volume.The 3MTXP-1.8 machine can be used in the northern areas of Ningxia,where the soil hardness is higher.The results can provide a reference for the development and popularization of grapevine burying machines in Ningxia.
文摘Burying beetles (Nicrophorus sp.) are necrophagous insects with developed parental care. Genome of Nicrophorus vespilloides has been recently sequenced, which makes them interesting model organism in behavioral ecology. However, we know very little about their physiology, including the functioning of their neuroendocrine system. In this study, one of the physiological activities of proctolin, myosuppressin (Nieve? MS), myoinhibitory peptide (Trica-MIP-5) and the short neuropeptide F (Nicve-sNPF) in N. vespilloides have been investigated. The tested neuropeptides were myoactive on N. vespilloides hindgut. After application of the proctolin increased hindgut contraction frequency was observed (EC50 value was 5.47 x 10-8 mol/L). The other tested neuropeptides led to inhibition of N. vespilloides hindgut contractions (Nicve-MS: IC50 = 5.20 x 10~5 mol/L;Trica-MIP-5: IC50 = 5.95 x 10-6 mol/L;Nicvc-sNPF: IC50 = 4.08 x 10-5 mol/L). Moreover, the tested neuropeptides were immunolocalized in the nervous system of N. vespilloides. Neurons containing sNPF and MIP in brain and ventral nerve cord (VNC) were identified. Proctolin-immunolabeled neurons only in VNC were observed. Moreover, MIP-immunolabeled varicosities and fibers in retrocerebral complex were observed. In addition, our results have been supplemented with alignments of amino acid sequences of these neuropeptides in beetle species. This alignment analysis clearly showed amino acid sequence similarities between neuropeptides. Moreover, this allowed to deduce amino acid sequence of N. vespilloides proctolin (RYLPTa), Nicve-MS (QDVDHVFLRFa) and six isoforms ofNicve-MIP (Nicve-MIP-1一 DWNRNLHSWa;Nicve-MIP-2—AWQNLQGGWa;Nicve-MIP-3—AWQNLQGGWa;Nicve-MlP-4—AWKNLNNAGWa;Nicve-MIP-5—SEWGNFRGSWa;Nicve-MIP-6— DPAWTNLKGIWa;and Nicve-sNPF—SGRSPSLRLRFa).
文摘Insect overwintering is one of the most astonishing phases of the insect life cycle. Despite vast amounts of knowledge available about the physiological mechanisms of this phenomenon, the impact of stress factors on insect immune system functioning during the winter is still unknown. The aim of this study is to analyze how low temperatures influence the immune system of the beetle Nic＇rophorus vespilloides. The results show that the beetle＇s immune system is differently modulated by cold induced in laboratory settings than that which occurs in natural conditions, Among beetles cultured in conditions similar to summer, low temperatures, did not influence the number of circulating haemocytes, phenoloxidase activity, haemocytes morphology, and percentage ratio of haemocyte types. In these beetles, differences were noted only in the ability of haemocytes to perform phagocytosis. Individuals acclimated in natural conditions in autumn had a higher level of humoral response and a different percentage ratio of haemocyte types. During the winter period, the number of haemocytes in the beetles decreased, but the percentage ratio of phagocytic haemocytes increased. Furthermore, we noted an increase of phenoloxidase activity. Our study also showed mitotic divisions ofhaemocytes in haemolymph collected from burying beetles after cold exposure and from burying beetles collected from natural conditions during autumn and winter. Differences in response to low temperatures in laboratory conditions and the natural environment suggest that the simultaneous presence of other stress factors during winter such as desiccation and starvation have a significant influence on the activity of burying beetle＇s immune system.
基金supported by the National Natural Science Foundation of China(Grant Nos.12002156,11972185,12372136)Research Fund of State Key Laboratory of Mechanics and Control for Aerospace Structures(Grant No.MCMS-I-0222K01)。
文摘While the moisture content of soil affects significantly the blast impulse of shallow buried explosives,the role of surface-covering water(SCW)on soil in such blast impulse remains elusive.A combined experimental and numerical study has been carried out to characterize the effect of SCW on transferred impulse and loading magnitude of shallow buried explosives.Firstly,blast tests of shallow buried explosives were conducted,with and without the SCW,to quantitatively assess the blast loading impulse.Subsequently,finite element(FE)simulations were performed and validated against experimental measurement,with good agreement achieved.The validated FE model was then employed to predict the dynamic response of a fully-clamped metallic circular target,subjected to the explosive impact of shallow buried explosives with SCW,and explore the corresponding physical mechanisms.It was demonstrated that shallow buried explosives in saturated soil generate a greater impulse transferred towards the target relative to those in dry soil.The deformation displacement of the target plate is doubled.Increasing the height of SCW results in enhanced center peak deflection of the loaded target,accompanied by subsequent fall,due to the variation of deformation pattern of the loaded target from concentrated load to uniform load.Meanwhile,the presence of SCW increases the blast impulse transferred towards the target by three times.In addition,there exists a threshold value of the burial depth that maximizes the impact impulse.This threshold exhibits a strong sensitivity to SCW height,decreasing with increasing SCW height.An empirical formula for predicting threshold has been provided.Similar conclusions can be drawn for different explosive masses.The results provide technical guidance on blast loading intensity and its spatial distribution considering shallow buried explosives in coast-land battlefields,which can ultimately contribute to better protective designs.
基金National Natural Science Foundation of China under Grant Nos.52078386 and 52308496SINOMACH Youth Science and Technology Fund under Grant No.QNJJ-PY-2022-02+2 种基金Young Elite Scientists Sponsorship Program under Grant No.BYESS2023432Fund of State Key Laboratory of Precision Blasting and Hubei Key Laboratory of Blasting Engineering,Jianghan University under Grant No.PBSKL2023A9Fund of China Railway Construction Group Co.,Ltd.under Grant No.LX19-04b。
文摘Strong surface impact will produce strong vibration,which will pose a threat to the safety of nearby buried pipelines and other important lifeline projects.Based on the verified numerical method,a comprehensive numerical parameter analysis is conducted on the key influencing factors of the vibration isolation hole(VIH),which include hole diameter,hole net spacing,hole depth,hole number,hole arrangement,and soil parameters.The results indicate that a smaller ratio of net spacing to hole diameter,the deeper the hole,the multi-row hole,the hole adoption of staggered arrangements,and better site soil conditions can enhance the efficiency of the VIH barrier.The average maximum vibration reduction efficiency within the vibration isolation area can reach 42.2%.The vibration safety of adjacent oil pipelines during a dynamic compaction projection was evaluated according to existing standards,and the measurement of the VIH was recommended to reduce excessive vibration.The single-row vibration isolation scheme and three-row staggered arrangement with the same hole parameters are suggested according to different cases.The research findings can serve as a reference for the vibration safety analysis,assessment,and control of adjacent underground facilities under the influence of strong surface impact loads.
基金supported by National Natural Science Foundation of China(62104082)Guangdong Basic and Applied Basic Research Foundation(2022A1515010746,2022A1515011228,and 2022B1515120006)the Science and Technology Program of Guangzhou(202201010458).
文摘Gas quenching and vacuum quenching process are widely applied to accelerate solvent volatilization to induce nucleation of perovskites in blade-coating method.In this work,we found these two pre-crystallization processes lead to different order of crystallization dynamics within the perovskite thin film,resulting in the differences of additive distribution.We then tailor-designed an additive molecule named 1,3-bis(4-methoxyphenyl)thiourea to obtain films with fewer defects and holes at the buried interface,and prepared perovskite solar cells with a certified efficiency of 23.75%.Furthermore,this work also demonstrates an efficiency of 20.18%for the large-area perovskite solar module(PSM)with an aperture area of 60.84 cm^(2).The PSM possesses remarkable continuous operation stability for maximum power point tracking of T_(90)>1000 h in ambient air.
文摘As one of the important components of high-effi-ciency perovskite/silicon series devices,wide-bandgap(WBG)perovskite solar cells(PSCs)have been suffering from serious carrier transport barriers and huge open-circuit voltage deficit de-rived from non-radiative recombination,especial-ly at the buried interface that are often overlooked.Herein,we combined cationic and anion passiva-tion strategies via ammonium tetra-n-butyl tetrafluoroborate(TBABF_(4))pre-treating the buried interface.Theoretical calculation predicts that the tetrabutylammonium(TBA^(+))organic cations and(tetrafluoroborate)BF_(4)^(−)anions can easily interact with charged interfacial defect.Characterizations further confirm the enhance-ment of carrier transport performance and decrease in defect density upon TBABF4 pre-treat-ment.Consequently,a power conversion efficiency of 21.35%with an ultrahigh filling factor of 84.12%is obtained for 1.68 eV-WBG inverted PSCs.In addition,the device with TBABF4 pre-treatment demonstrates excellent shelf,thermal,and operational stability.
基金the CMEC Technology Incubation Project(No.CMEC-KJFH-2018-02)the National Science Foundation of China(No.41877250)+2 种基金the Fundamental Research Funds for the Central Universities,CHD(Nos.300102263512 and 300102260401)Shaanxi Science and Technology Coordination Innovation Project(No.2011KTZB03-02-02)the National Geological Survey of China(No.DD20160264)。
文摘Since the 1950's,212 earth fissures have been discovered in the Wei River Basin.During a field survey in 2016,an additional 48 earth fissures were discovered in Anren area,northeast of the Wei River Basin.The characteristics and formation mechanisms of these fissures were studied through field investigations,measurements,trench excavation,and drilling.On-site investigations indicated that these earth fissures were distributed along a fault-controlled geomorphic boundary.Fissures trended at 60°-80°NE and were divided into five groups.Trenches revealed multiple secondary fissures,exposing severe soil ruptures in the shallow earth surfaces.Drilling profiles revealed that earth fissures dislocated several strata,and resembled synsedimentary faults.Seismic reflection profiles revealed buried faults beneath the earth fissures.The Anren area fissures formed in the following three stages:regional extension that initially generated multiple buried faults;seismic activity rupturing multiple strata,resulting in multiple buried fractures;and finally,erosion processes that propagated the buried fractures to the surface,forming the current earth fissures.
文摘This pictorial review discusses the imaging approach to evaluate for proper placement or complications of pediatric gastrostomy tube(G-tube)placement and long-term use.G-tubes are crucial for long-term nutritional support in patients facing challenges with oral intake.The article depicts the role of imaging such as contrast radiography,fluoroscopy,ultrasound,and computed tomography scans for confirming G-tube position and evaluating complications,in addition to basic anatomical considerations and placement techniques.Complications discussed include malposition,intraperitoneal placement,buried bumper syndrome,and tube malfunction.Specific imaging techniques and checklists are provided to guide clinicians in assessing G-tube placement accurately.The latter half of the review is a comprehensive exploration of pearls and pitfalls of imaging when employed to detect complications to avoid false positives and negatives.
基金financially supported by the National Key R&D Program of China(2022YFB4200303 to D.Zhao)the National Natural Science Foundation of China(62174112,52461160298 to D.Zhao and E30853YM19 to C.Xiao)+2 种基金the Natural Science Foundation of Sichuan Province(2024NSFSC1011 to C.Chen)the Fundamental Research Funds for the Central Universities(YJ2021157 to C.Chen)the Engineering Featured Team Fund of Sichuan University(2020SCUNG102 to D.Zhao)。
文摘Numerous defects at the buried interface of perovskite film and the exacerbated oxidation and degradation of tin-lead(Sn-Pb)perovskites induced by poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate)(PEDOT:PSS),due to its hygroscopic and acidic nature,limit performance improvement of SnPb perovskite solar cells(PSCs).To address these issues,1-Ethyl-3-Guanidinothiourea-Hydrochloride(EGH)was employed as a multifunctional modifier at the PEDOT:PSS/perovskite interface to regulate the buried interface behaviors of Sn-Pb PSCs.EGH can not only passivate the defects of the perovskite buried interface and regulate the work function of PEDOT:PSS for a more matched interface energy level,but also prevent the perovskite film from erosion damage by the acidic PEDOT:PSS for a more stable PEDOT:PSS/perovskite interface.Moreover,the interfacial charge transport dynamics were significantly improved by obviously suppressing interfacial non-radiative recombination losses.As a consequence,EGH-tailored 1.25 eV Sn-Pb PSCs yielded a champion PCE of 23.20%,featuring enhanced long-term stability.
文摘The development of guidance technology has made it possible for the earth penetration weapons(EPWs)to impact the target repeatedly at a close range. To investigative the damage of single and sequential strike induced by the EPWs, experimental and numerical investigations are carried out in this paper.Firstly, a series of sequential explosion tests are conducted to provide the basic data of the crater size.Then, a numerical model is established to simulate the damage effects of sequential explosions using the meshfree method of Smoothed particle Galerkin. The effectiveness of numerical model is verified by comparison with the experimental results. Finally, based on dimensional analysis, several empirical formulas for describing the crater size are presented, including the conical crater diameter and the conical crater depth of the single explosion, the conical crater area and the joint depth of the secondary explosion. The formula for the single explosion expresses the relationship between the aspect ratio of the charge ranging from 3 to 7, the dimensionless buried depth ranging from 2 to 14 and the crater size. The formula for the secondary explosion expresses the relationship between the relative position of the two explosions and the crater size. All of data can provide reference for the design of protective structures.
基金supported by the National Natural Science Foundation of China(Grant 52102196 and 52402228)China Postdoctoral Science Foundation(Grant 2023M740474)Postdoctoral Fellowship Program of CPSF(GZB20230095)。
文摘Interface modification has been demonstrated as an effective means to enhance the performance of perovskite solar cells.However,the effect depends on the anchoring mode and strength of the interfacial molecules,which determines whether long-term robust interface for carrier viaduct can be achieved under operational light illumination.Herein,we select squaric acid(SA)as the interfacial molecule between the perovskite and SnO_(2)layer and propose a selfregulated bilateral anchoring strategy.The unique four-membered ring conjugated structure and dicarboxylic acid groups facilitate stable hydrogen bonds and coordination bonds at both SnO_(2)/SA and SA/PbI_(2)interfaces.The self-transforming property of SA enables the dynamic bilateral anchoring at the buried interface,ultimately releasing residual stress and constructing a stable interfacial molecular bridge.The results show that SA molecular bridge not only can effectively inhibit the generation of diverse charged defects but also serves as an effective electron transport pathway,resulting in improved power conversion efficiency(PCE)from 23.19 to 25.50%and excellent stability at the maximum power point.Additionally,the PCEs of the flexible and large-area(1 cm^(2))devices were increased to 24.92%and 24.01%,respectively,demonstrating the universal applicability of the bilateral anchoring to PSCs based on different substrates and larger area.
基金Supported by the Hainan Provincial Science and Technology Special Project(ZDYF2025GXJS013)CNOOC Zhanjiang Branch Project(CCL2023ZJFN0540).
文摘Based on drilling,mud logging,core,seismic and imaging logging data,this paper studies the identification and evolution process of negative inversion structures in the Carboniferous buried hills in the No.1 and No.2 fault zones of Weixinan Sag,Beibu Gulf Basin,China,and reveals the controls of these structures on high-quality reservoirs.The No.2 fault zone develops significant negative inversion structures in the Carboniferous buried hills,as a result of multi-stage transformations of compressive-tensile stress fields in the period from the Late Hercynian to the Himalayan.The Hercynian carbonates laid the material basis for the formation of high-quality reservoirs.The negative inversion structures mainly control the development of high-quality reservoirs in buried hills through:(1)creating large-scale fractures to increase reservoir space and improve oil-gas flow pathways;(2)regulating stratigraphic differential denudation to highlight dominant lithology for later reservoir transformation;(3)shaping the paleogeomorphological highlands to provide favorable conditions for superficial karstification.The negative inversion structures form a high-quality,composite reservoir space with the synergistic existence of superficial dissolution fractures/cavities and burial-enhanced karst systems through the coupling of fracture network creation,formation denudation screening and multi-stage karst transformation.The research results have guided the breakthrough of the first exploratory well with a daily oil production over 1000 m^(3)in carbonate buried-hill reservoir in the Beibu Gulf Basin,and provide referential geological basis for finding more reserves and achieving higher production in the Carboniferous buried hills in the Weixinan Sag.
基金financial support from the National Natural Science Foundation of China(Grant No.U2244222,42576244,42072324,42442603)the Guangzhou Basic and Applied Basic Research Foundation(Grant No.202201011367,202201011487).
文摘Weijia Guyot,located in the western Pacific Ocean,has become a research focus due to its abundant cobalt-rich ferromanganese(Fe-Mn)crusts.While most studies on Fe-Mn crusts on seamounts have focused on the exposed variety,less attention has been paid to potential buried crusts.This study presents a preliminary geochemical and chronological study of buried Fe-Mn crusts at Weijia Guyot.The findings suggest that these buried crusts began to form around 57.5 Ma and ceased growing at approximately 46.3 Ma.Following the formation of Weijia Guyot through volcanic eruption,it did not experience continuous and steady subsidence to its current depth.Instead,an exhumation process took place from deep to shallow depths between 46.3 and 11.6 Ma.This process brought the Fe-Mn crusts into shallow water environments,halting their growth.During this time,Weijia Guyot was located near the equatorial Pacific Ocean and was exposed to an extended period of phosphatization.This exposure led to a depletion of key metallogenic elements,such as Co,Ni and Cu,within the Fe-Mn crusts,while P2O5 and CaO levels increased significantly.Since the Middle Miocene,the crusts have been progressively buried by pelagic sediments.
文摘The BZ oilfield in the Bohai Sea is a rare,highly volatile reservoir with fractures in the metamorphic rocks of buried hills.Clarifying the mechanism of gas injection for improving oil recovery and determining the optimal way to deploy injection-production well networks are critical issues that must be urgently addressed for efficient oilfield development.Experimental research on the mixed-phase displacement mechanism through gas injection into indoor formation fluids was conducted to guide the efficient development of gas injection in oil fields.We established a model of dual-medium reservoir composition and researched the deployment strategy for a three-dimensional well network for gas injection development.The coupling relationship between key influencing factors of the well network and fracture development was also quantitatively analyzed.The results show that the solubility of the associated gas and strong volatile oil system injected into the BZ oilfield is high.This high solubility demonstrates a mixed-phase displacement mechanism involving intermediate hydrocarbons,dissolution and condensation of medium components,and coexistence of extraction processes.Injecting gas and crude oil can achieve a favorable mixing effect when the local formation pressure is greater than 35.79 MPa.Associated gas reinjection is recommended to supplement energy for developing the highly volatile oil reservoirs in the fractured buried hills of the BZ oilfield.This recommendation involves fully utilizing the structural position and gravity-assisted oil displacement mechanism to deploy an injection-production well network.Gas injection points should be constructed at the top of high areas,and oil production points should be placed at the middle and lower parts of low areas.This approach forms a spatial threedimensional well network.By adopting high inclination well development,the oil production well forms a 45°angle with the fracture direction,which increases the drainage area and enhances single-well production capacity.The optimal injection-production well spacing along the fracture direction is approximately 1000 m,while the reasonable well spacing in the vertical fracture direction is approximately 800 m.The research results were applied to the development practice of the buried hills in the BZ oilfield,which achieved favorable development results.These outcomes provide a valuable reference for the formulation of development plans and efficient gas injection development in similar oil and gas fields in buried hills.
基金financially supported by the State Key Laboratory of Geohazard Prevention and Geoenvironment Protection(Chengdu University of Technology)(Grant No.SKLGP2020Z007)。
文摘Deeply buried mountain tunnels are often exposed to the risk of rock bursts,which always cause serious damage to the supporting structures and threaten the safety of the engineers.Due to the limited data available,a suitable approach to predict the rockburst tendency at the preliminary stage becomes very important.In this study,an integrated methodology combining 3D initial stress inversion and rockburst tendency prediction was developed and subsequently applied to a case study of the Sangzhuling Tunnel on the Sichuan–Tibet Railway.The numerical modelling involved inverting the initial stress field using a multiple linear regression method.The tunnel excavation was simulated separately by FDM and DEM,based on a stress boundary condition from the inverted stress field.The comparative analysis demonstrates that the rockburst ratio calculated using DEM(76.70%)exhibits a slight increase compared to FDM(75.38%),and the rockburst location is consistent with the actual situation.This suggests that DEM is more suitable for simulating the stress redistribution during excavation in a jointed rock mass.The numerical simulation combined with the deviatoric stress approach effectively predicts rockburst tendency,meeting the engineering requirements.Despite its limitations,numerical simulation remains a reliable method for predicting rock bursts.
基金financially supported by the Science Foundation of the Chinese Academy of Sciences。
文摘Tin oxide has emerged as a promising electron transport material in perovskite solar cells due to its high conductivity and photostability.However,the inherent defects in SnO_(2)nanoparticles and their imperfect bonding with perovskite at the interface lead to additional energy loss.To achieve bifacial passivation on the SnO_(2)electron transport layer and the SnO_(2)/perovskite interface synchronously,a multifunctional surface modulation strategy has been developed by incorporating O-phospho-L-serine monolithium salt(PSLi)to regulate the SnO_(2)nanoparticles.PS-Li coordinates with SnO_(2)through the phosphate/carboxyl groups,with the exposed amino group passivating the uncoordinated lead ions at the interface.The introduction of a lithium ion further regulates the energy band of SnO_(2),accelerating electron extraction and transport.This multifunctional modulation strategy reduces trap states from tin dangling bonds and oxygen vacancies,enhancing film conductivity.It also regulates the growth of the perovskite crystal and reduces nonradiative recombination at the interface.Consequently,the optimized perovskite solar cells achieve power conversion efficiencies(PCEs)of 24.91% for small-area devices and 23.14% for minimodules(aperture area of 30 cm^(2)).The unencapsulated device retains 91% and 89% of its initial PCE after enduring 1000 h under ambient conditions,and 500 h under 1 sun illumination in N2atmosphere,respectively.
基金supported by the National Natural Science Foundation of China(Grant numbers 52208392,52068044,and 52168058)China Post-doctoral Science Foundation(Grant number 2021M693843)+1 种基金Tianyou Youth Talent Lift Program of Lanzhou Jiaotong University(Grant number 1520260306)Key Laboratory of Road and Bridge and Underground Engineering of Gansu Province(Grant number GSDQ-KF2020-5).
文摘Uneven terrain significantly increases the seismic risk of tunnels in loess deposits.To investigate the variations in optimal intensity measures(IMs)for shallowly buried loess tunnels considering biased terrain,nonlinear dynamic analyses were conducted to obtain seismic responses validated by the actual damage pattern.Then IMs were evaluated based on the automatic calculation of the time history damage index fulfilled by a compiled Python program.Results showed that the plastic strain zone progressively developed and extended from the vault to the central slope surface with increasing seismic intensities,ultimately causing shear failure to the tunnel.For IMs at the slope top,peak ground velocity(PGV)(ζ=0.15),velocity spectrum intensity(VSI)(ζ=0.20),and peak spectrum velocity(PSv)(ζ=0.22)were all suitable for seismic fragility assessment.The VSI(ζ=0.17)was optimal,followed by PGV(ζ=0.19)and PSv(ζ=0.2)for those at the slope foot.Acceleration-related IMs were more sensitive to terrain variation.Comparative analyses demonstrated smaller damage probabilities for the IMs at the slope top than those at the slope foot under the same intensity level.The impact of unfavorable terrain on tunnels was accentuated as those located in uneven mountainous regions became more vulnerable to ground shaking.
