Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains...Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.展开更多
The exploration of advanced materials through rational structure/phase design is the key to develop highperformance lithium-ion capacitors(LICs).However,high complexity of material preparation and difficulty in quanti...The exploration of advanced materials through rational structure/phase design is the key to develop highperformance lithium-ion capacitors(LICs).However,high complexity of material preparation and difficulty in quantity production largely hinder the further development.Herein,Cu_(5)FeS_(4-x)/C(CFS@C)heterojunction with rich sulfur vacancies has successfully achieved from natural bornite,presenting low costeffective and bulk-production prospect.Density functional theory(DFT)calculations indicate that rich vacancies in bulk phase can decrease band gap of bornite and thus improve its intrinsic electron conductivity,as well as the heterojunction spontaneously evokes a built-in electric field between its interfacial region,largely reducing the migration barrier from 1.27 e V to 0.75 e V.Benefited from these merits,the CFS@C electrodes deliver outperformed lithium storage performance,e.g.,high reversible capacity(822.4m Ah/g at 0.1 A/g),excellent cycling stability(up to 820 cycles at 2 A/g and 540 cycles at 5 A/g with respective capacity retention of over or nearly 100%).With CFS@C as anode and porous carbon nanosheets(PCS)as cathode,the assembled CFS@C//PCS LIC full cells exhibit high energy/power density characteristics of 139.2 Wh/kg at 2500 W/kg.This work is expected to offer significant insights into structure modifications/devising toward natural minerals for advanced energy-storage systems.展开更多
Here,we report a mixed GAI and MAI(MGM)treatment method by forming a 2D alternating-cation-interlayer(ACI)phase(n=2)perovskite layer on the 3D perovskite,modulating the bulk and interfacial defects in the perovskite f...Here,we report a mixed GAI and MAI(MGM)treatment method by forming a 2D alternating-cation-interlayer(ACI)phase(n=2)perovskite layer on the 3D perovskite,modulating the bulk and interfacial defects in the perovskite films simultaneously,leading to the suppressed nonradiative recombination,longer lifetime,higher mobility,and reduced trap density.Consequently,the devices’performance is enhanced to 24.5%and 18.7%for 0.12 and 64 cm^(2),respectively.In addition,the MGM treatment can be applied to a wide range of perovskite compositions,including MA-,FA-,MAFA-,and CsFAMA-based lead halide perovskites,making it a general method for preparing efficient perovskite solar cells.Without encapsulation,the treated devices show improved stabilities.展开更多
The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the p...The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the performance of solar energy evaporation and minimizing material degradation during application can be achieved through the design of novel photothermal materials.In solar interfacial evaporation,photothermal materials exhibit a wide range of additional characteristics,but a systematic overview is lacking.This paper encompasses an examination of various categories and principles pertaining to photothermal materials,as well as the structural design considerations for salt-resistant materials.Additionally,we discuss the versatile uses of this appealing technology in different sectors related to energy and the environment.Furthermore,potential solutions to enhance the durability of photothermal materials are also highlighted,such as the rational design of micro/nano-structures,the use of adhesives,the addition of anti-corrosion coatings,and the preparation of self-healing surfaces.The objective of this review is to offer a viable resolution for the logical creation of high-performance photothermal substances,presenting a guide for the forthcoming advancement of solar evaporation technology.展开更多
Revealing the structure evolution of interfacial active species during a dynamic catalytic process is a challenging but pivotal issue for the rational design of high-performance catalysts.Here,we successfully prepare ...Revealing the structure evolution of interfacial active species during a dynamic catalytic process is a challenging but pivotal issue for the rational design of high-performance catalysts.Here,we successfully prepare sub-nanometric Pt clusters(~0.8 nm)encapsulated within the defects of CeO_(2)nanorods via an in-situ defect engineering methodology.The as-prepared Pt@d-CeO_(2)catalyst significantly boosts the activity and stability in the water-gas shift(WGS)reaction compared to other analogs.Based on controlled experiments and complementary(in-situ)spectroscopic studies,a reversible encapsulation induced by active site transformation between the Pt^(2+)-terminal hydroxyl and Pt^(δ+)-O vacancy species at the interface is revealed,which enables to evoke the enhanced performance.Our findings not only offer practical guidance for the design of high-efficiency catalysts but also bring a new understanding of the exceptional performance of WGS in a holistic view,which shows a great application potential in materials and catalysis.展开更多
Interfacial ferroelectricity is a recently established mechanism for generating spontaneous reversible electric polarization,arising from the charge transfer between stacked van der Waals layered atomic crystals.It ha...Interfacial ferroelectricity is a recently established mechanism for generating spontaneous reversible electric polarization,arising from the charge transfer between stacked van der Waals layered atomic crystals.It has been realized in both naturally formed multilayer crystals and moirésuperlattices.Owing to the large number of material choices and combinations,this approach is highly versatile,greatly expanding the scope of ultrathin ferroelectrics.A key advantage of interfacial ferroelectricity is its potential to couple with preexisting properties of the constituent layers,enabling their electrical manipulation through ferroelectric switching and paving the way for advanced device functionalities.This review article summarizes recent experimental progress in interfacial ferroelectricity,with an emphasis on its coupling with a variety of electronic properties.After introducing the underlying mechanism of interfacial ferroelectricity and the range of material systems discovered to date,we highlight selected examples showcasing ferroelectric control of excitonic optical properties,Berry curvature effects,and superconductivity.We also discuss the challenges and opportunities that await further studies in this field.展开更多
Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In ...Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In order to obtain high-quality HMX@PDA-based PBX explosives with high sphericity and a narrow particle size distribution,composite microspheres were prepared using co-axial droplet microfluidic technology.The formation mechanism,thermal behavior,mechanical sensitivity,electrostatic spark sensitivity,compressive strength,and combustion performance of the microspheres were investigated.The results show that PDA can effectively enhance the interfacial interaction between the explosive particles and the binder under the synergistic effect of chemical bonds and the physical"mechanical interlocking"structure.Interface reinforcement causes the thermal decomposition temperature of the sample microspheres to move to a higher temperature,with the sensitivity to impact,friction,and electrostatic sparks(for S-1)increasing by 12.5%,31.3%,and 81.5%respectively,and the compressive strength also increased by 30.7%,effectively enhancing the safety performance of the microspheres.Therefore,this study provides an effective and universal strategy for preparing high-quality functional explosives,and also provides some reference for the safe use of energetic materials in practical applications.展开更多
The unique structure and formation mechanism of medium-entropy alloys(MEAs)generally result in bet-ter comprehensive properties than traditional alloys.However,the strength-ductility trade-offremains a bottleneck,whic...The unique structure and formation mechanism of medium-entropy alloys(MEAs)generally result in bet-ter comprehensive properties than traditional alloys.However,the strength-ductility trade-offremains a bottleneck,which limits their applications.In this study,we designed novel high-performance CrNiCu x MEAs with a heterophase composition by incorporating a Cu-rich phase,and they were fabricated using laser-directed energy deposition(LDED).The results show that synergistic strengthening from multiple phases significantly improved the mechanical properties of the alloys,resulting in a tensile strength of 675 MPa and a ductility of 34.4%,demonstrating an excellent combination of high tensile strength and ductility.The improved mechanical properties of the CrNiCu x medium-entropy alloys are primarily due to the heterophase interfacial strengthening mechanism.In the alloy,numerous semi-coherent and coher-ent interfaces formed between the Cr-rich phase,Cu-rich phase,and the matrix,creating extensive lattice distortions at the interfaces.An increase in the Cu-rich phase content promoted the interaction between phases,enhancing the strain energy of the alloy and the barrier strength of the interfaces.The calcu-latedτint values,ranging from approximately 5.92-6.69 GPa,are significantly higher than those found in traditional alloys,providing a benchmark for designing new high-performance medium-entropy alloys.展开更多
The tungsten particles reinforced Zr41.2Ti13.8Cu12.5Ni10Be22.5 (Vit 1 alloy) bulk metallic glass composites (BMGCs) were prepared by the melt infiltrating casting method with the infiltrating time of 1, 5 and 10 min, ...The tungsten particles reinforced Zr41.2Ti13.8Cu12.5Ni10Be22.5 (Vit 1 alloy) bulk metallic glass composites (BMGCs) were prepared by the melt infiltrating casting method with the infiltrating time of 1, 5 and 10 min, respectively. The changes of interfacial reaction and compression properties of the bulk metallic glass composites with different infiltrating times were studied. Results show that with the increase of infiltrating time, tiny nanocrystals are generated at the interfacial boundary of tungsten particles and the amorphous matrix, and the size of tiny crystals increases with the infiltrating time. When the infiltrating time is 10 min, polygonal crystals with a larger size are also generated within the amorphous matrix. The compressive strength of the composites also increases with the infiltrating time. When the infiltrating time is 10 min, the compressive strength of the composite reaches 2,030 MPa and the compression strain is 44%. The fracture morphology of the composite materials is in a vein-like pattern and the melting phenomenon is found on the fracture surface. In addition, the density of the shear bands during the compressive tests of the composite materials increases with the infiltrating time.展开更多
Glass fiber reinforced polypropylene(GF-PP)composites have high flammability on account of wick effect which leads to accelerated flow of the polymer melt along the glass fibers(GF)surface to the flame zone.In this st...Glass fiber reinforced polypropylene(GF-PP)composites have high flammability on account of wick effect which leads to accelerated flow of the polymer melt along the glass fibers(GF)surface to the flame zone.In this study,dipentaerythritol(DPER),a charring agent,was adsorbed on the GF surface through the hydrogen bond between silane coupling agent and DPER.DPER has a synergistic effect with the intumescent flame retardants(IFR)added in the composites,which can induce interfacial carbonization on the surface of GF,thus transforming the intrinsic smooth GF surface into roughness one.In this way,the negative effect of the wick effect in flame retardancy is weakened.Moreover,the char residues remained on the surface of GF can bring an improved adhesion between GF and char residues formed in the resin so that a more stable barrier char layer is formed.The PP composites with 20 wt%modified glass fiber(M-GF)and 30 wt%IFR can achieve the UL-94 V-0,and its limiting oxygen index(LOI)value increased from 16.5%to 29.5%.Simultaneously,the heat release rate(HRR),total heat release(THR)and total smoke release(TSR)decreased significantly,and the peak of heat release rate(PHRR)reduced60.6%compared with GF-PP.展开更多
Through strategies such as process optimization,solvent selection,and component tuning,the crystallization of perovskite materials has been effectively controlled,enabling perovskite solar cells(PSCs)to achieve over 2...Through strategies such as process optimization,solvent selection,and component tuning,the crystallization of perovskite materials has been effectively controlled,enabling perovskite solar cells(PSCs)to achieve over 25%power conversion efficiency(PCE).However,as PCE continues to improve,interfacial issues within the devices have emerged as critical bottlenecks,hindering further performance enhancements.Recently,interfacial engineering has driven transformative progress,pushing PCEs to nearly 27%.Building upon these developments,this review first summarizes the pivotal role of interfacial modifications in elevating device performance and then,as a starting point,provides a comprehensive overview of recent advancements in normal,inverted,and tandem structure devices.Finally,based on the current progress of PSCs,preliminary perspectives on future directions are presented.展开更多
The highly selective catalytic hydrogenation of halogenated nitroaromatics was achieved by employing Pd‑based catalysts that were co‑modified with organic and inorganic ligands.It was demonstrated that the catalysts c...The highly selective catalytic hydrogenation of halogenated nitroaromatics was achieved by employing Pd‑based catalysts that were co‑modified with organic and inorganic ligands.It was demonstrated that the catalysts contained Pd species in mixed valence states,with high valence Pd at the metal‑support interface and zero valence Pd at the metal surface.While the strong coordination of triphenylphosphine(PPh3)to Pd0 on the Pd surface prevents the adsorption of halogenated nitroaromatics and thus dehalogenation,the coordination of sodium metavanadate(NaVO3)to high‑valence Pd sites at the interface helps to activate H2 in a heterolytic pathway for the selective hydrogenation of nitro‑groups.The excellent catalytic performance of the interfacial active sites enables the selective hydrogenation of a wide range of halogenated nitroaromatics.展开更多
Even though vacuum induction melting(VIM)is widely employed in the industrial production of bulk metallic glasses(BMGs),the effect and mechanism of the interfacial reaction between the melt and the oxide ceramic cruci...Even though vacuum induction melting(VIM)is widely employed in the industrial production of bulk metallic glasses(BMGs),the effect and mechanism of the interfacial reaction between the melt and the oxide ceramic crucible on BMG formations are not yet fully understood.Here,the influences and mechanisms of the interfacial reaction on a Zr-based BMG(Vit 105)subjected to various melting temperatures and holding times are revealed by employing experiments and theoretical calculations.We find that the degree of interfacial reaction is intriguingly correlated with the process parameters during VIM processing,leading to an increase in the oxygen content of the alloy and the reaction layer thickness.Besides,the increase of oxygen content also induces variations in the ordering and shear transformation zone(STZ)size of the BMGs,thus resulting in the precipitation of a nanoscale fcc phase and affecting the mechanical properties and reliability under deformation of the alloy.Furthermore,thermodynamic and kinetic parameters involved in the interfacial reaction,such as the molar Gibbs free energy of each element,the apparent activation energy,etc.,are obtained,providing a comprehensive understanding of the transport processes at play.Our findings provide new insights into the preparation of BMGs by VIM and may be expanded to other melting techniques to accelerate the commercial application of metallic glasses.展开更多
Large-area two-dimensional(2D)materials,such as graphene,MoS_(2),WS_(2),h-BN,black phosphorus,and MXenes,are a class of advanced materials with many possible applications.Different applications need different substrat...Large-area two-dimensional(2D)materials,such as graphene,MoS_(2),WS_(2),h-BN,black phosphorus,and MXenes,are a class of advanced materials with many possible applications.Different applications need different substrates,and each substrate may need a different way of transferring the 2D material onto it.Problems such as local stress concentrations,an uneven surface tension,inconsistent adhesion,mechanical damage and contamination during the transfer can adversely affect the quality and properties of the transferred material.Therefore,how to improve the integrity,flatness and cleanness of large area 2D materials is a challenge.In order to achieve high-quality transfer,the main concern is to control the interface adhesion between the substrate,the 2D material and the transfer medium.This review focuses on this topic,and finally,in order to promote the industrial use of large area 2D materials,provides a recipe for this transfer process based on the requirements of the application,and points out the current problems and directions for future development.展开更多
Achieving industrial-level electrochemical CO_(2)reduction to formate remains a significant challenge due to limitations in catalyst selectivity and interfacial proton management at high current densities.In a recent ...Achieving industrial-level electrochemical CO_(2)reduction to formate remains a significant challenge due to limitations in catalyst selectivity and interfacial proton management at high current densities.In a recent study,Prof.Guo and colleagues report the development of Turingstructured electrocatalysts,which incorporate reaction-diffusion-inspired topologies to engineer mesoscale surface patterns.This design enables precise modulation of the interfacial microenvironment,enhancing CO_(2)activation and suppressing competing hydrogen evolution.The resulting catalysts achieve efficient and stable CO_(2)-to-formate conversion under industrially relevant conditions,offering a promising strategy for scalable carbon-neutral chemical production.展开更多
Recent advances in van der Waals(vdW) ferroelectrics have sparked the development of related heterostructures with non-volatile and field-tunable functionalities. In vdW ferroelectric heterojunctions, the interfacial ...Recent advances in van der Waals(vdW) ferroelectrics have sparked the development of related heterostructures with non-volatile and field-tunable functionalities. In vdW ferroelectric heterojunctions, the interfacial electrical characteristics play a crucial role in determining their performance and functionality. In this study,we explore the interfacial polarization coupling in two-dimensional(2D) ferroelectric heterojunctions by fabricating a graphene/h-BN/CuInP_(2)S_(6)/α-In_(2)Se_(3)/Au ferroelectric field-effect transistor. By varying the gate electric field, the CuInP_(2)S_(6)/α-In_(2)Se_(3) heterojunction displays distinct interfacial polarization coupling states, resulting in significantly different electrical transport behaviors. Under strong gate electric fields, the migration of Cu ions further enhances the interfacial polarization effect, enabling continuous tuning of both the polarization state and carrier concentration in α-In_(2)Se_(3). Our findings offer valuable insights for the development of novel multifunctional devices based on 2D ferroelectric materials.展开更多
Rechargeable magnesium batteries(RMBs)have garnered significant attention in energy storage applications due to their high capacity,low cost,and high safety.However,the strong polarization effect and slow kinetic de-i...Rechargeable magnesium batteries(RMBs)have garnered significant attention in energy storage applications due to their high capacity,low cost,and high safety.However,the strong polarization effect and slow kinetic de-intercalation of Mg^(2+)in the cathode limit their commercial application.This study presents a novel interface-coupled V_(2)CT_(x)@VS_(4)heterostructure through a one-step hydrothermal process.In this architecture,V_(2)CT_(x)and VS_(4)can mutually support their structural framework,which effectively prevents the structural collapse of V_(2)CT_(x)MXene and the aggregation of VS_(4).Crucially,interfacial coupling between V_(2)CT_(x)and VS_(4)induces strong V-S bonds,substantially enhancing structural stability.Benefiting from these advantages,the heterostructure exhibits high specific capacity(226 mAh g^(-1)at 100 mA g^(-1))and excellent long-cycle stability(89% capacity retention after 1000 cycles at 500 mA g^(-1)).Furthermore,the Mg^(2+)storage mechanism in the V_(2)CT_(x)@VS_(4)composite was elucidated through a series of ex-situ characterizations.This work provides a feasible strategy for designing V_(2)CT_(x)MXene-based cathodes with high capacity and extended cyclability for RMBs.展开更多
Tetrasodium iminodisuccinate(IDS)was used as an inhibitor in the separation of sphalerite and pyrite in the EX−Cu(II)(ethyl xanthate and Cu2+)system.The flotation test results demonstrated that IDS can effectively sep...Tetrasodium iminodisuccinate(IDS)was used as an inhibitor in the separation of sphalerite and pyrite in the EX−Cu(II)(ethyl xanthate and Cu2+)system.The flotation test results demonstrated that IDS can effectively separate sphalerite and pyrite under low alkaline conditions.Furthermore,high-quality zinc concentrates with a Zn grade of 58.48%and a recovery of 91.24%through mixed mineral flotation were obtained.The fundamental mechanisms were investigated through surface wettability tests,adsorption capacity tests,LEIS,FTIR,and XPS.The results confirmed that IDS prevents the adsorption of EX on the surface of pyrite,thereby reducing the response and reactivity of pyrite.The introduction of IDS causes the detachment of Cu2+from the Cu-activated pyrite surface.This process allowed IDS to chelate with the Fe sites on the surface of pyrite through the-COO-and N-centered active groups.By contrast,IDS exhibits weaker adhesion on the surface of Cu-activated sphalerite,making it easily displaced by EX through competitive adsorption.展开更多
In this study,a pair of dicarboxylic acids as cis-trans isomerism—citraconic acid(CA)and mesaconic acid(MA),was incorporated into polymeric networks of poly(N-isopropylacrylamide)(PNIPAM)-based core-shell microgels v...In this study,a pair of dicarboxylic acids as cis-trans isomerism—citraconic acid(CA)and mesaconic acid(MA),was incorporated into polymeric networks of poly(N-isopropylacrylamide)(PNIPAM)-based core-shell microgels via semi-batch precipitation polymerization.We demonstrated that the pH-temperature dual responsiveness of the core-shell microgels is highly correlated with the structure and position of the acid isomers.Both the cis-trans molecular structure and the crosslinking position of the dicarboxylic acids significantly influenced the hydration capacity and surface charge density of the core-shell microgels.These diverse properties first influenced the swelling behavior,further affecting the interfacial behavior of the microgels,including the oil-water dynamic interfacial tension and air-water compression isotherms.Furthermore,the rheological behavior of the microgel suspensions also displayed distinct dependences on the frequency and temperature,illustrating that the cis-trans molecular structure and crosslinked position of the dicarboxylic acids also significantly influenced the interparticle clustering in the bulk solution.Our results suggest that the pH sensitivity of the cis-trans dicarboxylic acid isomer affects the ionization and surface charge distribution of the core or shell layers of individual microgels,which further determines the interparticle interaction and cooperative rearrangement at interfaces and in the bulk.展开更多
As a natural oil-soluble emulsifier to replace Polyglycerol Polyricinoleate(PGPR),lecithin's application in double emulsions(DEs)remains constrained due to low encapsulation efficiency and stability,while incorpor...As a natural oil-soluble emulsifier to replace Polyglycerol Polyricinoleate(PGPR),lecithin's application in double emulsions(DEs)remains constrained due to low encapsulation efficiency and stability,while incorporating Pickering particles within the inner aqueous phase(W_(1))has emerged as an effective approach to enhance DEs stability.However,the interfacial interactions between Pickering particles in W_(1) and lecithin in oil phase and their effects on the physical,delivery and digestion properties of DEs remain to be explored.In this study,a natural Pickering DEs encapsulating blueberry anthocyanins(ANCs)was developed using lecithin and gliadinbased particles,with gliadin colloid particles(GCPs)introduced into W_(1).The effects of GCP concentration in W_(1) on emulsion droplet size,microstructure,W_(1)/O interfacial rheology,in vitro digestion,and ANCs delivery performance were systematically investigated.Results showed that GCPs in W_(1) accelerated the decreasing of W_(1)/O interfacial tension,indicating that,beyond competitive adsorption,combination between the two might also occur at the interface,which could accelerate the interfacial adsorption of lecithin.GCPs significantly improved the strength of the W_(1)/O interface,thus improving ANCs encapsulation efficiency from 49.66%to 70.60%.Moreover,the droplet size of DEs decreased from 38.94μm to 24.09μm as GCPs concentration increased,indicating that some GCPs might transfer to the outer aqueous phase through phase exchange,acting as hydrophilic emulsifiers.GCPs in W_(1) can modulate ANCs in vitro release,enhancing ANCs'bioaccessibility(31.10%)and antioxidant capacity.展开更多
基金financially supported by the National Natural Science Foundation of China(Nos.22272118,22172111,and 22309134)the Science and Technology Commission of Shanghai Municipality,China(Nos.22ZR1464100,20ZR1460300,and 19DZ2271500)+2 种基金the China Postdoctoral Science Foundation(2022M712402),the Shanghai Rising-Star Program(23YF1449200)the Zhejiang Provincial Science and Technology Project(2022C01182)the Fundamental Research Funds for the Central Universities(2023-3-YB-07)。
文摘Carbon superstructures with multiscale hierarchies and functional attributes represent an appealing cathode candidate for zinc hybrid capacitors,but their tailor-made design to optimize the capacitive activity remains a confusing topic.Here we develop a hydrogen-bond-oriented interfacial super-assembly strategy to custom-tailor nanosheet-intertwined spherical carbon superstructures(SCSs)for Zn-ion storage with double-high capacitive activity and durability.Tetrachlorobenzoquinone(H-bond acceptor)and dimethylbenzidine(H-bond donator)can interact to form organic nanosheet modules,which are sequentially assembled,orientally compacted and densified into well-orchestrated superstructures through multiple H-bonds(N-H···O).Featured with rich surface-active heterodiatomic motifs,more exposed nanoporous channels,and successive charge migration paths,SCSs cathode promises high accessibility of built-in zincophilic sites and rapid ion diffusion with low energy barriers(3.3Ωs-0.5).Consequently,the assembled Zn||SCSs capacitor harvests all-round improvement in Zn-ion storage metrics,including high energy density(166 Wh kg-1),high-rate performance(172 m Ah g^(-1)at 20 A g^(-1)),and long-lasting cycling lifespan(95.5%capacity retention after 500,000 cycles).An opposite chargecarrier storage mechanism is rationalized for SCSs cathode to maximize spatial capacitive charge storage,involving high-kinetics physical Zn^(2+)/CF_(3)SO_(3)-adsorption and chemical Zn^(2+)redox with carbonyl/pyridine groups.This work gives insights into H-bond-guided interfacial superassembly design of superstructural carbons toward advanced energy storage.
基金supported by the National Natural Science Foundation of China(Nos.52004338,22378431)Hunan Provincial Natural Science Foundation(Nos.2022JJ20075,2023JJ40210)+1 种基金Scientific Research Fund of Hunan Provincial Education Department(No.21B0017)Central South University Innovation-Driven Research Programme(No.2023CXQD008)。
文摘The exploration of advanced materials through rational structure/phase design is the key to develop highperformance lithium-ion capacitors(LICs).However,high complexity of material preparation and difficulty in quantity production largely hinder the further development.Herein,Cu_(5)FeS_(4-x)/C(CFS@C)heterojunction with rich sulfur vacancies has successfully achieved from natural bornite,presenting low costeffective and bulk-production prospect.Density functional theory(DFT)calculations indicate that rich vacancies in bulk phase can decrease band gap of bornite and thus improve its intrinsic electron conductivity,as well as the heterojunction spontaneously evokes a built-in electric field between its interfacial region,largely reducing the migration barrier from 1.27 e V to 0.75 e V.Benefited from these merits,the CFS@C electrodes deliver outperformed lithium storage performance,e.g.,high reversible capacity(822.4m Ah/g at 0.1 A/g),excellent cycling stability(up to 820 cycles at 2 A/g and 540 cycles at 5 A/g with respective capacity retention of over or nearly 100%).With CFS@C as anode and porous carbon nanosheets(PCS)as cathode,the assembled CFS@C//PCS LIC full cells exhibit high energy/power density characteristics of 139.2 Wh/kg at 2500 W/kg.This work is expected to offer significant insights into structure modifications/devising toward natural minerals for advanced energy-storage systems.
基金supported by the National Key Research and Development Program of China(2021YFB3800103)the Fundamental Research Funds for the Central Universities(000-0903069032)the National Natural Science Foundation of China(52203237).
文摘Here,we report a mixed GAI and MAI(MGM)treatment method by forming a 2D alternating-cation-interlayer(ACI)phase(n=2)perovskite layer on the 3D perovskite,modulating the bulk and interfacial defects in the perovskite films simultaneously,leading to the suppressed nonradiative recombination,longer lifetime,higher mobility,and reduced trap density.Consequently,the devices’performance is enhanced to 24.5%and 18.7%for 0.12 and 64 cm^(2),respectively.In addition,the MGM treatment can be applied to a wide range of perovskite compositions,including MA-,FA-,MAFA-,and CsFAMA-based lead halide perovskites,making it a general method for preparing efficient perovskite solar cells.Without encapsulation,the treated devices show improved stabilities.
基金supported by Zhejiang Provincial Natural Science Foundation of China(No.LR23C160001)Scientific Research Startup Foundation of Zhejiang Ocean University(No.11034150220006).
文摘The utilization of solar-driven interfacial evaporation technology is highly important in addressing the energy crisis and water scarcity,primarily because of its affordability and minimal energy usage.Enhancing the performance of solar energy evaporation and minimizing material degradation during application can be achieved through the design of novel photothermal materials.In solar interfacial evaporation,photothermal materials exhibit a wide range of additional characteristics,but a systematic overview is lacking.This paper encompasses an examination of various categories and principles pertaining to photothermal materials,as well as the structural design considerations for salt-resistant materials.Additionally,we discuss the versatile uses of this appealing technology in different sectors related to energy and the environment.Furthermore,potential solutions to enhance the durability of photothermal materials are also highlighted,such as the rational design of micro/nano-structures,the use of adhesives,the addition of anti-corrosion coatings,and the preparation of self-healing surfaces.The objective of this review is to offer a viable resolution for the logical creation of high-performance photothermal substances,presenting a guide for the forthcoming advancement of solar evaporation technology.
文摘Revealing the structure evolution of interfacial active species during a dynamic catalytic process is a challenging but pivotal issue for the rational design of high-performance catalysts.Here,we successfully prepare sub-nanometric Pt clusters(~0.8 nm)encapsulated within the defects of CeO_(2)nanorods via an in-situ defect engineering methodology.The as-prepared Pt@d-CeO_(2)catalyst significantly boosts the activity and stability in the water-gas shift(WGS)reaction compared to other analogs.Based on controlled experiments and complementary(in-situ)spectroscopic studies,a reversible encapsulation induced by active site transformation between the Pt^(2+)-terminal hydroxyl and Pt^(δ+)-O vacancy species at the interface is revealed,which enables to evoke the enhanced performance.Our findings not only offer practical guidance for the design of high-efficiency catalysts but also bring a new understanding of the exceptional performance of WGS in a holistic view,which shows a great application potential in materials and catalysis.
基金Project supported by the Natural Science Foundation of Jiangsu Province(Grant Nos.BK20231529 and BK20233001)the National Key Research and Development Program of China(Grant No.2024YFA1409100)+2 种基金the Fundamental Research Funds for the Central Universities(Grant No.0204-14380233)the National Natural Science Foundation of China(Grant Nos.12474170 and 123B2059)the National Postdoctoral Program for Innovative Talents(Grant No.BX20240160)。
文摘Interfacial ferroelectricity is a recently established mechanism for generating spontaneous reversible electric polarization,arising from the charge transfer between stacked van der Waals layered atomic crystals.It has been realized in both naturally formed multilayer crystals and moirésuperlattices.Owing to the large number of material choices and combinations,this approach is highly versatile,greatly expanding the scope of ultrathin ferroelectrics.A key advantage of interfacial ferroelectricity is its potential to couple with preexisting properties of the constituent layers,enabling their electrical manipulation through ferroelectric switching and paving the way for advanced device functionalities.This review article summarizes recent experimental progress in interfacial ferroelectricity,with an emphasis on its coupling with a variety of electronic properties.After introducing the underlying mechanism of interfacial ferroelectricity and the range of material systems discovered to date,we highlight selected examples showcasing ferroelectric control of excitonic optical properties,Berry curvature effects,and superconductivity.We also discuss the challenges and opportunities that await further studies in this field.
基金supported by the National Natural Science Foundation of China(Grant No.22005275).
文摘Surface engineering plays a crucial role in improving the performance of high energy materials,and polydopamine(PDA)is widely used in the field of energetic materials for surface modification and functionalization.In order to obtain high-quality HMX@PDA-based PBX explosives with high sphericity and a narrow particle size distribution,composite microspheres were prepared using co-axial droplet microfluidic technology.The formation mechanism,thermal behavior,mechanical sensitivity,electrostatic spark sensitivity,compressive strength,and combustion performance of the microspheres were investigated.The results show that PDA can effectively enhance the interfacial interaction between the explosive particles and the binder under the synergistic effect of chemical bonds and the physical"mechanical interlocking"structure.Interface reinforcement causes the thermal decomposition temperature of the sample microspheres to move to a higher temperature,with the sensitivity to impact,friction,and electrostatic sparks(for S-1)increasing by 12.5%,31.3%,and 81.5%respectively,and the compressive strength also increased by 30.7%,effectively enhancing the safety performance of the microspheres.Therefore,this study provides an effective and universal strategy for preparing high-quality functional explosives,and also provides some reference for the safe use of energetic materials in practical applications.
基金supported by the National Natural Science Foundation of China(Grant No.U2341254)the National Natural Science Foundation of China(Grant No.52071124),the Natural Science Foundation of Jiangsu Province(No.BK20230502)the Jiangsu Funding Program for Excellent Postdoctoral Talent(No.2022ZB547).
文摘The unique structure and formation mechanism of medium-entropy alloys(MEAs)generally result in bet-ter comprehensive properties than traditional alloys.However,the strength-ductility trade-offremains a bottleneck,which limits their applications.In this study,we designed novel high-performance CrNiCu x MEAs with a heterophase composition by incorporating a Cu-rich phase,and they were fabricated using laser-directed energy deposition(LDED).The results show that synergistic strengthening from multiple phases significantly improved the mechanical properties of the alloys,resulting in a tensile strength of 675 MPa and a ductility of 34.4%,demonstrating an excellent combination of high tensile strength and ductility.The improved mechanical properties of the CrNiCu x medium-entropy alloys are primarily due to the heterophase interfacial strengthening mechanism.In the alloy,numerous semi-coherent and coher-ent interfaces formed between the Cr-rich phase,Cu-rich phase,and the matrix,creating extensive lattice distortions at the interfaces.An increase in the Cu-rich phase content promoted the interaction between phases,enhancing the strain energy of the alloy and the barrier strength of the interfaces.The calcu-latedτint values,ranging from approximately 5.92-6.69 GPa,are significantly higher than those found in traditional alloys,providing a benchmark for designing new high-performance medium-entropy alloys.
基金This work was supported by the Liaoning Joint Fund of NSFC(No.U1908219).
文摘The tungsten particles reinforced Zr41.2Ti13.8Cu12.5Ni10Be22.5 (Vit 1 alloy) bulk metallic glass composites (BMGCs) were prepared by the melt infiltrating casting method with the infiltrating time of 1, 5 and 10 min, respectively. The changes of interfacial reaction and compression properties of the bulk metallic glass composites with different infiltrating times were studied. Results show that with the increase of infiltrating time, tiny nanocrystals are generated at the interfacial boundary of tungsten particles and the amorphous matrix, and the size of tiny crystals increases with the infiltrating time. When the infiltrating time is 10 min, polygonal crystals with a larger size are also generated within the amorphous matrix. The compressive strength of the composites also increases with the infiltrating time. When the infiltrating time is 10 min, the compressive strength of the composite reaches 2,030 MPa and the compression strain is 44%. The fracture morphology of the composite materials is in a vein-like pattern and the melting phenomenon is found on the fracture surface. In addition, the density of the shear bands during the compressive tests of the composite materials increases with the infiltrating time.
基金supported by the National Natural Science Foundation of China(21878092,21838003,91834301)the Shanghai Scientific and Technological Innovation Project(18JC1410500,19JC1410400)+1 种基金the Innovation Program of Shanghai Municipal Education Commissionthe Fundamental Research Funds for the Central Universities(222201718002)。
文摘Glass fiber reinforced polypropylene(GF-PP)composites have high flammability on account of wick effect which leads to accelerated flow of the polymer melt along the glass fibers(GF)surface to the flame zone.In this study,dipentaerythritol(DPER),a charring agent,was adsorbed on the GF surface through the hydrogen bond between silane coupling agent and DPER.DPER has a synergistic effect with the intumescent flame retardants(IFR)added in the composites,which can induce interfacial carbonization on the surface of GF,thus transforming the intrinsic smooth GF surface into roughness one.In this way,the negative effect of the wick effect in flame retardancy is weakened.Moreover,the char residues remained on the surface of GF can bring an improved adhesion between GF and char residues formed in the resin so that a more stable barrier char layer is formed.The PP composites with 20 wt%modified glass fiber(M-GF)and 30 wt%IFR can achieve the UL-94 V-0,and its limiting oxygen index(LOI)value increased from 16.5%to 29.5%.Simultaneously,the heat release rate(HRR),total heat release(THR)and total smoke release(TSR)decreased significantly,and the peak of heat release rate(PHRR)reduced60.6%compared with GF-PP.
基金supported by National Natural Science Foundation of China(52302229,62404072)the Key Lab of Modern Optical Technologies of Education Ministry of China,Soochow University(KJS2425)+1 种基金Doctoral Foundation of Henan Polytech-nic University(B2024-72)Science and Technology Research Project of Jiangxi Provincial Department of Education(Grant No.GJJ2400702).
文摘Through strategies such as process optimization,solvent selection,and component tuning,the crystallization of perovskite materials has been effectively controlled,enabling perovskite solar cells(PSCs)to achieve over 25%power conversion efficiency(PCE).However,as PCE continues to improve,interfacial issues within the devices have emerged as critical bottlenecks,hindering further performance enhancements.Recently,interfacial engineering has driven transformative progress,pushing PCEs to nearly 27%.Building upon these developments,this review first summarizes the pivotal role of interfacial modifications in elevating device performance and then,as a starting point,provides a comprehensive overview of recent advancements in normal,inverted,and tandem structure devices.Finally,based on the current progress of PSCs,preliminary perspectives on future directions are presented.
文摘The highly selective catalytic hydrogenation of halogenated nitroaromatics was achieved by employing Pd‑based catalysts that were co‑modified with organic and inorganic ligands.It was demonstrated that the catalysts contained Pd species in mixed valence states,with high valence Pd at the metal‑support interface and zero valence Pd at the metal surface.While the strong coordination of triphenylphosphine(PPh3)to Pd0 on the Pd surface prevents the adsorption of halogenated nitroaromatics and thus dehalogenation,the coordination of sodium metavanadate(NaVO3)to high‑valence Pd sites at the interface helps to activate H2 in a heterolytic pathway for the selective hydrogenation of nitro‑groups.The excellent catalytic performance of the interfacial active sites enables the selective hydrogenation of a wide range of halogenated nitroaromatics.
基金financially supported by the National Natural Science Foundation of China(Nos.51827801 and 52371152)the National Key Research and Development Program of China(Nos.2023YFB3710801,2023YFB3710802,and 2021YFB3704002)+1 种基金the Fundamental Research Funds for the Central Universities(No.FRFCU5710001320)the fellowship from the China Scholarship Council(CSC,No.202406120125)for the Visiting PhD Student Program.
文摘Even though vacuum induction melting(VIM)is widely employed in the industrial production of bulk metallic glasses(BMGs),the effect and mechanism of the interfacial reaction between the melt and the oxide ceramic crucible on BMG formations are not yet fully understood.Here,the influences and mechanisms of the interfacial reaction on a Zr-based BMG(Vit 105)subjected to various melting temperatures and holding times are revealed by employing experiments and theoretical calculations.We find that the degree of interfacial reaction is intriguingly correlated with the process parameters during VIM processing,leading to an increase in the oxygen content of the alloy and the reaction layer thickness.Besides,the increase of oxygen content also induces variations in the ordering and shear transformation zone(STZ)size of the BMGs,thus resulting in the precipitation of a nanoscale fcc phase and affecting the mechanical properties and reliability under deformation of the alloy.Furthermore,thermodynamic and kinetic parameters involved in the interfacial reaction,such as the molar Gibbs free energy of each element,the apparent activation energy,etc.,are obtained,providing a comprehensive understanding of the transport processes at play.Our findings provide new insights into the preparation of BMGs by VIM and may be expanded to other melting techniques to accelerate the commercial application of metallic glasses.
基金the National Key R&D Program of China(2022YFA1505200)the National Natural Science Foundation of China(22472140,22021001)the Fundamental Research Funds for the Central Universities(20720210017 and 20720210009)。
文摘Large-area two-dimensional(2D)materials,such as graphene,MoS_(2),WS_(2),h-BN,black phosphorus,and MXenes,are a class of advanced materials with many possible applications.Different applications need different substrates,and each substrate may need a different way of transferring the 2D material onto it.Problems such as local stress concentrations,an uneven surface tension,inconsistent adhesion,mechanical damage and contamination during the transfer can adversely affect the quality and properties of the transferred material.Therefore,how to improve the integrity,flatness and cleanness of large area 2D materials is a challenge.In order to achieve high-quality transfer,the main concern is to control the interface adhesion between the substrate,the 2D material and the transfer medium.This review focuses on this topic,and finally,in order to promote the industrial use of large area 2D materials,provides a recipe for this transfer process based on the requirements of the application,and points out the current problems and directions for future development.
基金financially supported by the National Natural Science Foundation of China(No.22209024)Tongcheng R&D Foundation(No.CPCIF-RA-0102)the State Key Laboratory of Advanced Fiber Materials,Donghua University
文摘Achieving industrial-level electrochemical CO_(2)reduction to formate remains a significant challenge due to limitations in catalyst selectivity and interfacial proton management at high current densities.In a recent study,Prof.Guo and colleagues report the development of Turingstructured electrocatalysts,which incorporate reaction-diffusion-inspired topologies to engineer mesoscale surface patterns.This design enables precise modulation of the interfacial microenvironment,enhancing CO_(2)activation and suppressing competing hydrogen evolution.The resulting catalysts achieve efficient and stable CO_(2)-to-formate conversion under industrially relevant conditions,offering a promising strategy for scalable carbon-neutral chemical production.
基金supported by the Chinese Academy of Sciences Project for Young Scientists in Basic Research(Grant No.YSBR-049)the Innovation Program for Quantum Science and Technology(Grant No.2021ZD0302800)the Fundamental Research Funds for the Central Universities(Grant No.WK3510000013)。
文摘Recent advances in van der Waals(vdW) ferroelectrics have sparked the development of related heterostructures with non-volatile and field-tunable functionalities. In vdW ferroelectric heterojunctions, the interfacial electrical characteristics play a crucial role in determining their performance and functionality. In this study,we explore the interfacial polarization coupling in two-dimensional(2D) ferroelectric heterojunctions by fabricating a graphene/h-BN/CuInP_(2)S_(6)/α-In_(2)Se_(3)/Au ferroelectric field-effect transistor. By varying the gate electric field, the CuInP_(2)S_(6)/α-In_(2)Se_(3) heterojunction displays distinct interfacial polarization coupling states, resulting in significantly different electrical transport behaviors. Under strong gate electric fields, the migration of Cu ions further enhances the interfacial polarization effect, enabling continuous tuning of both the polarization state and carrier concentration in α-In_(2)Se_(3). Our findings offer valuable insights for the development of novel multifunctional devices based on 2D ferroelectric materials.
基金Financial support from the National Natural Science Foundation of China(52302317)is gratefully acknowledged。
文摘Rechargeable magnesium batteries(RMBs)have garnered significant attention in energy storage applications due to their high capacity,low cost,and high safety.However,the strong polarization effect and slow kinetic de-intercalation of Mg^(2+)in the cathode limit their commercial application.This study presents a novel interface-coupled V_(2)CT_(x)@VS_(4)heterostructure through a one-step hydrothermal process.In this architecture,V_(2)CT_(x)and VS_(4)can mutually support their structural framework,which effectively prevents the structural collapse of V_(2)CT_(x)MXene and the aggregation of VS_(4).Crucially,interfacial coupling between V_(2)CT_(x)and VS_(4)induces strong V-S bonds,substantially enhancing structural stability.Benefiting from these advantages,the heterostructure exhibits high specific capacity(226 mAh g^(-1)at 100 mA g^(-1))and excellent long-cycle stability(89% capacity retention after 1000 cycles at 500 mA g^(-1)).Furthermore,the Mg^(2+)storage mechanism in the V_(2)CT_(x)@VS_(4)composite was elucidated through a series of ex-situ characterizations.This work provides a feasible strategy for designing V_(2)CT_(x)MXene-based cathodes with high capacity and extended cyclability for RMBs.
基金supports from the National Natural Science Foundation of China(No.52174272)the Fundamental Research Funds for the Central Universities of Central South University,China(No.2021zzts0306)the Hunan Provincial Natural Science Foundation of China(No.2020JJ5736).
文摘Tetrasodium iminodisuccinate(IDS)was used as an inhibitor in the separation of sphalerite and pyrite in the EX−Cu(II)(ethyl xanthate and Cu2+)system.The flotation test results demonstrated that IDS can effectively separate sphalerite and pyrite under low alkaline conditions.Furthermore,high-quality zinc concentrates with a Zn grade of 58.48%and a recovery of 91.24%through mixed mineral flotation were obtained.The fundamental mechanisms were investigated through surface wettability tests,adsorption capacity tests,LEIS,FTIR,and XPS.The results confirmed that IDS prevents the adsorption of EX on the surface of pyrite,thereby reducing the response and reactivity of pyrite.The introduction of IDS causes the detachment of Cu2+from the Cu-activated pyrite surface.This process allowed IDS to chelate with the Fe sites on the surface of pyrite through the-COO-and N-centered active groups.By contrast,IDS exhibits weaker adhesion on the surface of Cu-activated sphalerite,making it easily displaced by EX through competitive adsorption.
基金financially supported by the National Natural Science Foundation of China(No.22303033)the Fundamental Research Funds for the Central Universities,China(No.JUSRP123017)+1 种基金Wuxi“Taihu Light”Science and Technology Project-Basic Research(No.K20231063)the Research Matching Grant Scheme at CUHK(No.8601309)。
文摘In this study,a pair of dicarboxylic acids as cis-trans isomerism—citraconic acid(CA)and mesaconic acid(MA),was incorporated into polymeric networks of poly(N-isopropylacrylamide)(PNIPAM)-based core-shell microgels via semi-batch precipitation polymerization.We demonstrated that the pH-temperature dual responsiveness of the core-shell microgels is highly correlated with the structure and position of the acid isomers.Both the cis-trans molecular structure and the crosslinking position of the dicarboxylic acids significantly influenced the hydration capacity and surface charge density of the core-shell microgels.These diverse properties first influenced the swelling behavior,further affecting the interfacial behavior of the microgels,including the oil-water dynamic interfacial tension and air-water compression isotherms.Furthermore,the rheological behavior of the microgel suspensions also displayed distinct dependences on the frequency and temperature,illustrating that the cis-trans molecular structure and crosslinked position of the dicarboxylic acids also significantly influenced the interparticle clustering in the bulk solution.Our results suggest that the pH sensitivity of the cis-trans dicarboxylic acid isomer affects the ionization and surface charge distribution of the core or shell layers of individual microgels,which further determines the interparticle interaction and cooperative rearrangement at interfaces and in the bulk.
基金supported by National Natural Science Foundation of China(32202235)。
文摘As a natural oil-soluble emulsifier to replace Polyglycerol Polyricinoleate(PGPR),lecithin's application in double emulsions(DEs)remains constrained due to low encapsulation efficiency and stability,while incorporating Pickering particles within the inner aqueous phase(W_(1))has emerged as an effective approach to enhance DEs stability.However,the interfacial interactions between Pickering particles in W_(1) and lecithin in oil phase and their effects on the physical,delivery and digestion properties of DEs remain to be explored.In this study,a natural Pickering DEs encapsulating blueberry anthocyanins(ANCs)was developed using lecithin and gliadinbased particles,with gliadin colloid particles(GCPs)introduced into W_(1).The effects of GCP concentration in W_(1) on emulsion droplet size,microstructure,W_(1)/O interfacial rheology,in vitro digestion,and ANCs delivery performance were systematically investigated.Results showed that GCPs in W_(1) accelerated the decreasing of W_(1)/O interfacial tension,indicating that,beyond competitive adsorption,combination between the two might also occur at the interface,which could accelerate the interfacial adsorption of lecithin.GCPs significantly improved the strength of the W_(1)/O interface,thus improving ANCs encapsulation efficiency from 49.66%to 70.60%.Moreover,the droplet size of DEs decreased from 38.94μm to 24.09μm as GCPs concentration increased,indicating that some GCPs might transfer to the outer aqueous phase through phase exchange,acting as hydrophilic emulsifiers.GCPs in W_(1) can modulate ANCs in vitro release,enhancing ANCs'bioaccessibility(31.10%)and antioxidant capacity.
