<span style="font-family:Verdana;">Soil bulk density and moisture content are dynamic properties that vary with changes in soil and field conditions and have many agricultural, hydrological and environ...<span style="font-family:Verdana;">Soil bulk density and moisture content are dynamic properties that vary with changes in soil and field conditions and have many agricultural, hydrological and environmental implications. The main objective of this study was to compare between a soil core sampling method (core) and the CPN MC-3 Elite<span style="white-space:nowrap;"><sup>TM</sup></span> nuclear gauge method (radiation) for measuring bulk density (<span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"></span><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span>) and volumetric moisture content (<span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<span style="font-size:10.9091px;">v</span></i></span></span></i></span>) in a clay loam soil. Soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> and <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"></span><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<span style="font-size:10.9091px;">v</span></i></span></span></i></span> measurements were determined using the core and radiation methods at 0 - 10 and 10 - 20 cm soil depths. The mean values of soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> obtained using the core method (1.454, 1.492 g<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#f7f7f7;"="">·</span>cm<span style="white-space:nowrap;"><sup>−3</sup></span>) were greater than those obtained using the radiation method (1.343, 1.476 g<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#f7f7f7;"="">·</span>cm<span style="white-space:nowrap;"><sup>−3</sup></span>) at the 0 - 10 and 10 - 20 cm depths, respectively. Mean <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> and <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<span style="font-size:10.9091px;">v</span></i></span></span></i></span> values averaged across both depths (referred to as the 0 - 20 cm depth) measured by the core method were 4.47% and 22.74% greater, respectively, than those obtained by the radiation method. The coefficients of variation (CV) of soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"></span><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> values measured by the core method were lower than the CV values of those measured by the radiation method at both depths;however, the CV’s of <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> values for both methods were larger at the 0 - 10 cm depth than those measured at the 10 - 20 cm depth. Similarly, the CV values of soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<sub>v</sub></i></span></span></i></span> values measured by the core method were lower than the CV values of those measured by the radiation method at both depths. There were significant differences between two methods in terms of <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> and <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<sub>v</sub></i></span></span></i></span>, with the core method generating greater values than the radiation method at the 0 - 20 cm depth. These discrepancies between the two methods could have resulted from soil compaction and soil disturbance caused by the core and radiation techniques, respectively, as well as by other sources of error. Nevertheless, the core sampling method is considered the most common one for measuring <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> for many agricultural, hydrological and environmental studies in most soils.</span>展开更多
Pure MgB2 bulk samples are successfully synthesized by self-propagatlng hlgh-temperature synthesis （SHS） method. The experiments show that the best preheating temperature is 250℃, the highest Jc values of the prepa...Pure MgB2 bulk samples are successfully synthesized by self-propagatlng hlgh-temperature synthesis （SHS） method. The experiments show that the best preheating temperature is 250℃, the highest Jc values of the prepared MgB2 reach 1.5×10^6A/cm^2 （10K, 0.5T） and 1.7×10^6A/cm^2 （20K, 0T）, and the MgB2 particle sizes range from 2 to 5μm. The advantages of this method are that it is simple, economical and suitable for the manufacture of bulk MgB2 materials on industrial scale.展开更多
T3SiC2 bulks have been synthesized by infiltrating Si liquid into porous precursor pellets composed of solid Ti and C powders. Silicon pellets were placed at the bottom of the precursor pellets as the liquid source. T...T3SiC2 bulks have been synthesized by infiltrating Si liquid into porous precursor pellets composed of solid Ti and C powders. Silicon pellets were placed at the bottom of the precursor pellets as the liquid source. The starting compositions can be represented by the formula 3Ti + 2C + xSi, where x = 1.0, 1.2, 1.4 and 1.6, respectively. The phase formation and microstructure of the bulks were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results demonstrated that the Ti/C precursor pellet could only react with Si completely when the x value is 1.6. Large, a purity of above 95wt% Ti3SiC2 bulk of up to 50 mm in diameter was obtained by this method.展开更多
Precise measurements of the CO2 gas transfer across the air-sea interface provide a better under- standing of the global carbon cycle. The air-sea CO2 fluxes are obtained by the eddy covariance method and the bulk met...Precise measurements of the CO2 gas transfer across the air-sea interface provide a better under- standing of the global carbon cycle. The air-sea CO2 fluxes are obtained by the eddy covariance method and the bulk method from a buoy observation in the northern Huanghai sea. The effects of buoy motion on flux calculated by the eddy covariance method are demonstrated. The research shows that a motion correction can improve the correlation coefficient between the C02 fluxes esti- mated from two different levels. Without the CO2-H20 cross-correlation correction which is termed as PKT correction, the air-sea CO2 fluxes estimated by eddy covariance method using the motion corrected data are nearly an order of magnitude larger than those estimated by the bulk method. After the CO2-H20 cross-correlation correction, some eddy covariance CO2 fluxes indeed become closer to the bulk CO2 flux, whereas some are overcorrected which are in response to small water vapor flux.展开更多
A first principles study of the electronic properties and bulk modulus （B0） of the fcc and bcc transition metals, transition metal carbides and nitrides is presented. The calculations were performed by plane-wave ps...A first principles study of the electronic properties and bulk modulus （B0） of the fcc and bcc transition metals, transition metal carbides and nitrides is presented. The calculations were performed by plane-wave pseudopotential method in the framework of the density functional theory with local density approximation. The density of states and the valence charge densities of these solids are plotted. The results show that B0 does not vary monotonically when the number of the valence d electrons increases. B0 reaches a maximum and then decreases for each of the four sorts of solids. It is related to the occupation of the bonding and anti-bonding states in the solid. The value of the valence charge density at the midpoint between the two nearest metal atoms tends to be proportional to B0.展开更多
The bulk metal forming processes were simulated by using a one-step finite element(FE)approach based on deformation theory of plasticity,which enables rapid prediction of final workpiece configurations and stress/stra...The bulk metal forming processes were simulated by using a one-step finite element(FE)approach based on deformation theory of plasticity,which enables rapid prediction of final workpiece configurations and stress/strain distributions.This approach was implemented to minimize the approximated plastic potential energy derived from the total plastic work and the equivalent external work in static equilibrium,for incompressibly rigid-plastic materials,by FE calculation based on the extremum work principle.The one-step forward simulations of compression and rolling processes were presented as examples,and the results were compared with those obtained by classical incremental FE simulation to verify the feasibility and validity of the proposed method.展开更多
The blend morphology and vertical arrangement are critical to the performance of organic bulk-heterojunction photovoltaic devices.In the present paper,the authors proposed a new annealing method that controls the blen...The blend morphology and vertical arrangement are critical to the performance of organic bulk-heterojunction photovoltaic devices.In the present paper,the authors proposed a new annealing method that controls the blend morphology and vertical arrangement of two materials by means of simultaneously applying external electrical field and violet irradiation on the active layer of poly(3-hexylthiophene) (P3HT) and -phenyl C61-butyric acid methyl ester(PCBM) during annealing process.By using this annealing method,the power conversion efficiency increased by 36%,which was caused by vertical phased-separated blend of crystalline P3HT and PCBM and better charge extraction of electrodes.X-ray photoelectron spectroscopy(XPS) was measured to prove more fullerene derivatives at the organic/cathode interfaces by using this annealing method.The X-ray diffraction(XRD) analysis and UV-Vis absorption spectrum analysis also revealed more ordered polymer crystallization.展开更多
Various methods are available for calculating the TOC of shale reservoirs with logging data, and each method has its unique applicability andaccuracy. So it is especially important to establish a regional experimental...Various methods are available for calculating the TOC of shale reservoirs with logging data, and each method has its unique applicability andaccuracy. So it is especially important to establish a regional experimental calculation model based on a thorough analysis of their applicability.With the Upper Ordovician Wufeng Fm-Lower Silurian Longmaxi Fm shale reservoirs as an example, TOC calculation models were built by useof the improved DlgR, bulk density, natural gamma spectroscopy, multi-fitting and volume model methods respectively, considering the previousresearch results and the geologic features of the area. These models were compared based on the core data. Finally, the bulk density method wasselected as the regional experimental calculation model. Field practices demonstrated that the improved DlgR and natural gamma spectroscopymethods are poor in accuracy;although the multi-fitting method and bulk density method have relatively high accuracy, the bulk density methodis simpler and wider in application. For further verifying its applicability, the bulk density method was applied to calculate the TOC of shalereservoirs in several key wells in the Jiaoshiba shale gas field, Sichuan Basin, and the calculation accuracy was clarified with the measured dataof core samples, showing that the coincidence rate of logging-based TOC calculation is up to 90.5%-91.0%.展开更多
Copper-nickel nanoparticle was directly prepared by flow-levitation method （FL） and sintered by vacuum sintering of powder （VSP） method. Several characterizations, such as transmission electron microscopy （TEM）,...Copper-nickel nanoparticle was directly prepared by flow-levitation method （FL） and sintered by vacuum sintering of powder （VSP） method. Several characterizations, such as transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, X-ray diffraction （XRD）, differential thermal analysis （DTA）, and energy-dispersive X-ray spectroscopy （EDX） were used to investigate the prepared nanostructures. The results of the study show that FL method could prepare high purity Cu-Ni nanocrystals of uniform spheres with size distribution between 20 and 90 nm. After sintering the bulk nanocrystalline copper-nickel has obvious thermal stability and the surface Webster hardness increases with the rising sintering temperature. At the temperature of 900 ℃, the specimen shows higher surface Webster hardness, which is about two times of traditional materials. When the sintering temperature arrives at 1 000 ℃ the relative density of bulk nanocrystals can reach 97.86 percent. In this paper, the variation tendency of porosity, phase and particles size of bulk along with the changing of sintering temperature have been studied.展开更多
With the addition of Si to replace some P,Pd40.5Ni40.5SixP19-x（x=0,2.5,5,9.5,14,and 19 in atomic number fraction） bulk glassy samples with the diameter of about 5 mm were successfully prepared by use of flux treatme...With the addition of Si to replace some P,Pd40.5Ni40.5SixP19-x（x=0,2.5,5,9.5,14,and 19 in atomic number fraction） bulk glassy samples with the diameter of about 5 mm were successfully prepared by use of flux treatment and water quenching technology.With the increase of Si content,the glass forming ability of Pd40.5Ni40.5Si-xP19-x increases first for low Si content and then decreases for high Si content （Si≥9.5at%）.The Pd40.50Ni40.5Si5P14 glassy alloy possesses the largest supercooled liquid region△T of 119 K,the largest reduced glass transition temperature of 0.621,and the largestγparameter of 0.460,indicating that this glassy alloy possesses very large glass forming ability and very high thermal stability.展开更多
文摘<span style="font-family:Verdana;">Soil bulk density and moisture content are dynamic properties that vary with changes in soil and field conditions and have many agricultural, hydrological and environmental implications. The main objective of this study was to compare between a soil core sampling method (core) and the CPN MC-3 Elite<span style="white-space:nowrap;"><sup>TM</sup></span> nuclear gauge method (radiation) for measuring bulk density (<span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"></span><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span>) and volumetric moisture content (<span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<span style="font-size:10.9091px;">v</span></i></span></span></i></span>) in a clay loam soil. Soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> and <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"></span><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<span style="font-size:10.9091px;">v</span></i></span></span></i></span> measurements were determined using the core and radiation methods at 0 - 10 and 10 - 20 cm soil depths. The mean values of soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> obtained using the core method (1.454, 1.492 g<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#f7f7f7;"="">·</span>cm<span style="white-space:nowrap;"><sup>−3</sup></span>) were greater than those obtained using the radiation method (1.343, 1.476 g<span style="color:#4F4F4F;font-family:" font-size:14px;white-space:normal;background-color:#f7f7f7;"="">·</span>cm<span style="white-space:nowrap;"><sup>−3</sup></span>) at the 0 - 10 and 10 - 20 cm depths, respectively. Mean <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> and <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<span style="font-size:10.9091px;">v</span></i></span></span></i></span> values averaged across both depths (referred to as the 0 - 20 cm depth) measured by the core method were 4.47% and 22.74% greater, respectively, than those obtained by the radiation method. The coefficients of variation (CV) of soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"></span><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> values measured by the core method were lower than the CV values of those measured by the radiation method at both depths;however, the CV’s of <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> values for both methods were larger at the 0 - 10 cm depth than those measured at the 10 - 20 cm depth. Similarly, the CV values of soil <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<sub>v</sub></i></span></span></i></span> values measured by the core method were lower than the CV values of those measured by the radiation method at both depths. There were significant differences between two methods in terms of <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> and <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>θ<sub>v</sub></i></span></span></i></span>, with the core method generating greater values than the radiation method at the 0 - 20 cm depth. These discrepancies between the two methods could have resulted from soil compaction and soil disturbance caused by the core and radiation techniques, respectively, as well as by other sources of error. Nevertheless, the core sampling method is considered the most common one for measuring <span style="white-space:nowrap;"><i><span style="font-family:Verdana;white-space:normal;"><span style="white-space:nowrap;"><i>ρ<sub>B</sub></i></span></span></i></span> for many agricultural, hydrological and environmental studies in most soils.</span>
基金Project supported by the Natural Science Foundation of Gansu province of China （Grant No ZS032-B25-019）.
文摘Pure MgB2 bulk samples are successfully synthesized by self-propagatlng hlgh-temperature synthesis （SHS） method. The experiments show that the best preheating temperature is 250℃, the highest Jc values of the prepared MgB2 reach 1.5×10^6A/cm^2 （10K, 0.5T） and 1.7×10^6A/cm^2 （20K, 0T）, and the MgB2 particle sizes range from 2 to 5μm. The advantages of this method are that it is simple, economical and suitable for the manufacture of bulk MgB2 materials on industrial scale.
基金National Basic Research Program of China (2011CBA00102)National Natural Science Foundation of China (50672077)
文摘T3SiC2 bulks have been synthesized by infiltrating Si liquid into porous precursor pellets composed of solid Ti and C powders. Silicon pellets were placed at the bottom of the precursor pellets as the liquid source. The starting compositions can be represented by the formula 3Ti + 2C + xSi, where x = 1.0, 1.2, 1.4 and 1.6, respectively. The phase formation and microstructure of the bulks were investigated by X-ray diffraction (XRD) and scanning electron microscopy (SEM). The results demonstrated that the Ti/C precursor pellet could only react with Si completely when the x value is 1.6. Large, a purity of above 95wt% Ti3SiC2 bulk of up to 50 mm in diameter was obtained by this method.
基金The National Basic Research Program of China under contract No. 2011CB403501the Public Science and Technology Research Funds Projects of Ocean of the State oceanic Administration of China under contract No. 200905012-9+1 种基金the Fund for Creative Research Groups by the National Natural Science Foundation of China under contract No. 41121064the Open Research Foundation for the key Laboratory of Ocean Circulation and Waves.Institute of Oceanology,Chinese Academy of Sciences of China under contract No.KLOCAW1207
文摘Precise measurements of the CO2 gas transfer across the air-sea interface provide a better under- standing of the global carbon cycle. The air-sea CO2 fluxes are obtained by the eddy covariance method and the bulk method from a buoy observation in the northern Huanghai sea. The effects of buoy motion on flux calculated by the eddy covariance method are demonstrated. The research shows that a motion correction can improve the correlation coefficient between the C02 fluxes esti- mated from two different levels. Without the CO2-H20 cross-correlation correction which is termed as PKT correction, the air-sea CO2 fluxes estimated by eddy covariance method using the motion corrected data are nearly an order of magnitude larger than those estimated by the bulk method. After the CO2-H20 cross-correlation correction, some eddy covariance CO2 fluxes indeed become closer to the bulk CO2 flux, whereas some are overcorrected which are in response to small water vapor flux.
基金Project supported by the National Natural Science Foundation of China （Grant Nos 50175082 and 10275049）, and the Fund for the Doctoral Program of Higher Education （Grant No 2002486016）.
文摘A first principles study of the electronic properties and bulk modulus （B0） of the fcc and bcc transition metals, transition metal carbides and nitrides is presented. The calculations were performed by plane-wave pseudopotential method in the framework of the density functional theory with local density approximation. The density of states and the valence charge densities of these solids are plotted. The results show that B0 does not vary monotonically when the number of the valence d electrons increases. B0 reaches a maximum and then decreases for each of the four sorts of solids. It is related to the occupation of the bonding and anti-bonding states in the solid. The value of the valence charge density at the midpoint between the two nearest metal atoms tends to be proportional to B0.
基金Project(50575143)supported by the National Natural Science Foundation of ChinaProject(20040248005)supported by the Specialized Research Fund for the Doctoral Program of Higher Education of China
文摘The bulk metal forming processes were simulated by using a one-step finite element(FE)approach based on deformation theory of plasticity,which enables rapid prediction of final workpiece configurations and stress/strain distributions.This approach was implemented to minimize the approximated plastic potential energy derived from the total plastic work and the equivalent external work in static equilibrium,for incompressibly rigid-plastic materials,by FE calculation based on the extremum work principle.The one-step forward simulations of compression and rolling processes were presented as examples,and the results were compared with those obtained by classical incremental FE simulation to verify the feasibility and validity of the proposed method.
基金supported by the National Natural Science Foundation of China under grant No.10934001the National Basic Research Program of China under grant No.2009CB930504
文摘The blend morphology and vertical arrangement are critical to the performance of organic bulk-heterojunction photovoltaic devices.In the present paper,the authors proposed a new annealing method that controls the blend morphology and vertical arrangement of two materials by means of simultaneously applying external electrical field and violet irradiation on the active layer of poly(3-hexylthiophene) (P3HT) and -phenyl C61-butyric acid methyl ester(PCBM) during annealing process.By using this annealing method,the power conversion efficiency increased by 36%,which was caused by vertical phased-separated blend of crystalline P3HT and PCBM and better charge extraction of electrodes.X-ray photoelectron spectroscopy(XPS) was measured to prove more fullerene derivatives at the organic/cathode interfaces by using this annealing method.The X-ray diffraction(XRD) analysis and UV-Vis absorption spectrum analysis also revealed more ordered polymer crystallization.
基金National Key Science&Technology Project“Shale Gas Resource Evaluation and Regional Selection in Upper Yangtze and Dian(Yunnan)-Qian(Guizhou)-Gui(Guangxi)”(No.14B12XQ151001).
文摘Various methods are available for calculating the TOC of shale reservoirs with logging data, and each method has its unique applicability andaccuracy. So it is especially important to establish a regional experimental calculation model based on a thorough analysis of their applicability.With the Upper Ordovician Wufeng Fm-Lower Silurian Longmaxi Fm shale reservoirs as an example, TOC calculation models were built by useof the improved DlgR, bulk density, natural gamma spectroscopy, multi-fitting and volume model methods respectively, considering the previousresearch results and the geologic features of the area. These models were compared based on the core data. Finally, the bulk density method wasselected as the regional experimental calculation model. Field practices demonstrated that the improved DlgR and natural gamma spectroscopymethods are poor in accuracy;although the multi-fitting method and bulk density method have relatively high accuracy, the bulk density methodis simpler and wider in application. For further verifying its applicability, the bulk density method was applied to calculate the TOC of shalereservoirs in several key wells in the Jiaoshiba shale gas field, Sichuan Basin, and the calculation accuracy was clarified with the measured dataof core samples, showing that the coincidence rate of logging-based TOC calculation is up to 90.5%-91.0%.
基金Supported by the National Natural Science Foundation of China(No.10804101)
文摘Copper-nickel nanoparticle was directly prepared by flow-levitation method （FL） and sintered by vacuum sintering of powder （VSP） method. Several characterizations, such as transmission electron microscopy （TEM）, scanning electron microscopy （SEM）, X-ray diffraction （XRD）, differential thermal analysis （DTA）, and energy-dispersive X-ray spectroscopy （EDX） were used to investigate the prepared nanostructures. The results of the study show that FL method could prepare high purity Cu-Ni nanocrystals of uniform spheres with size distribution between 20 and 90 nm. After sintering the bulk nanocrystalline copper-nickel has obvious thermal stability and the surface Webster hardness increases with the rising sintering temperature. At the temperature of 900 ℃, the specimen shows higher surface Webster hardness, which is about two times of traditional materials. When the sintering temperature arrives at 1 000 ℃ the relative density of bulk nanocrystals can reach 97.86 percent. In this paper, the variation tendency of porosity, phase and particles size of bulk along with the changing of sintering temperature have been studied.
基金supported by the National Basic Research Priorities Program of China(No.2007CB613905)the National Natural Science Foundation of China(Nos.50671050 and 50971073)
文摘With the addition of Si to replace some P,Pd40.5Ni40.5SixP19-x（x=0,2.5,5,9.5,14,and 19 in atomic number fraction） bulk glassy samples with the diameter of about 5 mm were successfully prepared by use of flux treatment and water quenching technology.With the increase of Si content,the glass forming ability of Pd40.5Ni40.5Si-xP19-x increases first for low Si content and then decreases for high Si content （Si≥9.5at%）.The Pd40.50Ni40.5Si5P14 glassy alloy possesses the largest supercooled liquid region△T of 119 K,the largest reduced glass transition temperature of 0.621,and the largestγparameter of 0.460,indicating that this glassy alloy possesses very large glass forming ability and very high thermal stability.
