Herein,we report a facile solution process for preparing multi-walled carbon nanotube(MWCNT)bucky paper for solar-driven interfacial water evaporation.This process involves vacuum filtrating a dispersion of MWCNTs tha...Herein,we report a facile solution process for preparing multi-walled carbon nanotube(MWCNT)bucky paper for solar-driven interfacial water evaporation.This process involves vacuum filtrating a dispersion of MWCNTs that was modified by polyvinyl alcohol(PVA)under c-ray irradiation on a cellulose acetate microporous membrane,followed by borate crosslinking.Fourier transform infrared spectroscopy,Raman spectroscopy,and thermogravimetry confirmed the success of PVA grafting onto MWCNTs and borate crosslinking between modified MWCNT nanoyarns.The as-prepared crosslinked MWCNT bucky papers(BBP membranes)were used as a solar absorber,by placing them on a paper-wrapped floating platform,for interfacial water evaporation under simulated solar irradiation.The BBP membranes showed good water tolerance and mechanical stability,with an evaporation rate of 0.79 kg m^(-2)h^(-1)and an evaporation efficiency of 56%under 1 sun illumination in deionized water.Additionally,the BBP membranes achieved an evaporation rate of 0.76 kg m^(-2)h^(-1)in both NaCl solution(3.5 wt%)and sulfuric acid solution(1 mol L-1),demonstrating their impressive applicability for water reclamation from brine and acidic conditions.An evaporation rate of 0.70 kg m-2 h-1(very close to that from deionized water)was obtained from the solar evaporation of saturated NaCl solution,and the BBP membrane exhibited unexpected stability without the inference of salt accumulation on the membrane surface during long-term continuous solar evaporation.展开更多
The conjugated polycycles show excellent optical and electrical properties that are suitable for application in various organic electronics.While most of attentions have been paid to polycycles having planar π-conjug...The conjugated polycycles show excellent optical and electrical properties that are suitable for application in various organic electronics.While most of attentions have been paid to polycycles having planar π-conjugated system,the curved polycycles seem amazing due to their unique physical and chemical features.The non-planar conjugated polycycles have been created with the geometries of bracelet,saddle,bowl,Mobius band,helicenes,etc.Among them,the bowl-shaped one is of growing interest owing to the multidiscipline applications such as synthetic intermediates for end-cap of carbon nanotube,coordination with metal ions,encapsulation of fullerenes,and fabrication of electronic devices.In this paper,we summarize the recent advances on the chemistry of the bowl-shaped conjugated polycycles,particularly on their synthesis and the further chemical modifications toward organic functional materials.展开更多
Bucky ball(Buc)is involved in germ plasm(GP)assembly during early zebrafish development by regulating GP mRNA expression via an unknown mechanism.The present study demonstrates that an m^(6)A reader Igf2bp3 interacts ...Bucky ball(Buc)is involved in germ plasm(GP)assembly during early zebrafish development by regulating GP mRNA expression via an unknown mechanism.The present study demonstrates that an m^(6)A reader Igf2bp3 interacts and colocalizes with Buc in the GP.Similar to the loss of Buc,the genetic deletion of maternal igf2bp3 in zebrafish leads to abnormal GP assembly and insufficient germ cell specification,which can be partially restored by the injection of igf2 bp3 mRNA.Igf2bp3 binds to m^(6)A-modified GPorganizer and GP mRNAs in an m^(6)A-dependent manner and prevents their degradation.These findings indicate that the functions of Igf2bp3,a direct effector protein of Buc,in GP mRNA expression and GP assembly involve m^(6)A-dependent regulation;these results emphasize a critical role of m^(6)A modification in the process of GP assembly.展开更多
基金the National Natural Science Foundation of China(Grants 11875313 and 12075153).
文摘Herein,we report a facile solution process for preparing multi-walled carbon nanotube(MWCNT)bucky paper for solar-driven interfacial water evaporation.This process involves vacuum filtrating a dispersion of MWCNTs that was modified by polyvinyl alcohol(PVA)under c-ray irradiation on a cellulose acetate microporous membrane,followed by borate crosslinking.Fourier transform infrared spectroscopy,Raman spectroscopy,and thermogravimetry confirmed the success of PVA grafting onto MWCNTs and borate crosslinking between modified MWCNT nanoyarns.The as-prepared crosslinked MWCNT bucky papers(BBP membranes)were used as a solar absorber,by placing them on a paper-wrapped floating platform,for interfacial water evaporation under simulated solar irradiation.The BBP membranes showed good water tolerance and mechanical stability,with an evaporation rate of 0.79 kg m^(-2)h^(-1)and an evaporation efficiency of 56%under 1 sun illumination in deionized water.Additionally,the BBP membranes achieved an evaporation rate of 0.76 kg m^(-2)h^(-1)in both NaCl solution(3.5 wt%)and sulfuric acid solution(1 mol L-1),demonstrating their impressive applicability for water reclamation from brine and acidic conditions.An evaporation rate of 0.70 kg m-2 h-1(very close to that from deionized water)was obtained from the solar evaporation of saturated NaCl solution,and the BBP membrane exhibited unexpected stability without the inference of salt accumulation on the membrane surface during long-term continuous solar evaporation.
基金the National Natural Science Foundation of China(Nos.21522203,21372111,and 21190034)State Key Laboratory of Applied Organic Chemistry for the financial support
文摘The conjugated polycycles show excellent optical and electrical properties that are suitable for application in various organic electronics.While most of attentions have been paid to polycycles having planar π-conjugated system,the curved polycycles seem amazing due to their unique physical and chemical features.The non-planar conjugated polycycles have been created with the geometries of bracelet,saddle,bowl,Mobius band,helicenes,etc.Among them,the bowl-shaped one is of growing interest owing to the multidiscipline applications such as synthetic intermediates for end-cap of carbon nanotube,coordination with metal ions,encapsulation of fullerenes,and fabrication of electronic devices.In this paper,we summarize the recent advances on the chemistry of the bowl-shaped conjugated polycycles,particularly on their synthesis and the further chemical modifications toward organic functional materials.
基金supported by the National Key R&D Program of China(2018YFD0901201 and 2019YFA0802801)China Agricultural Research System(CARS-46)+3 种基金the National Natural Science Foundation of China(31870820)the Innovative Research Group Program of Hubei Province(2020CFA017)the Medical Science Advancement Program of Wuhan University(TFJC2018004)the Fundamental Research Funds for the Central Universities(2042019kf0207)。
文摘Bucky ball(Buc)is involved in germ plasm(GP)assembly during early zebrafish development by regulating GP mRNA expression via an unknown mechanism.The present study demonstrates that an m^(6)A reader Igf2bp3 interacts and colocalizes with Buc in the GP.Similar to the loss of Buc,the genetic deletion of maternal igf2bp3 in zebrafish leads to abnormal GP assembly and insufficient germ cell specification,which can be partially restored by the injection of igf2 bp3 mRNA.Igf2bp3 binds to m^(6)A-modified GPorganizer and GP mRNAs in an m^(6)A-dependent manner and prevents their degradation.These findings indicate that the functions of Igf2bp3,a direct effector protein of Buc,in GP mRNA expression and GP assembly involve m^(6)A-dependent regulation;these results emphasize a critical role of m^(6)A modification in the process of GP assembly.
