Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(...Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(EBPVD). Thermal cyclic performance of the TBCs was evaluated by flame shock testing at 1300 ℃. For comparison, the TBCs with a undoped NiAl bond coat were also studied. The microstructural evolution and failure mechanisms of the above TBCs during thermal cycling were investigated. Spallation failure of the TBCs with the undoped bond coat occurs after around 500 cycles by cracking at the interface between YSZ ceramic layer and thermally grown oxides(TGO) layer. The TBCs with Pt/Dy modified bond coat reveal improved interface bonding even after 1200 thermal cycles, whereas some delamination cracks are presented in the LCO layer. On the other hand,the Pt/Dy modified bond coat effectively suppresses the formation of the needle-like topologically closed packed phases(TCP) in the single crystal superalloy.展开更多
In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt＋2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic ...In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt＋2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.展开更多
The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conve...The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conventional NiCoCrAlY coating deposited on the same substrate.The AlCoCrFeNiY bond coat exhibits lower oxide growth rates due to its large columnar grains and low Al activity at the oxide scale/bond coat interface.Meanwhile,AlCoCrFeNiY has higher resistance to oxide spallation than NiCoCrAlY,which is attributed to the formation of a clean and defect-free metal/oxide interface.Significant interdiffusion occurs across the AlCoCrFeNiY/superalloy substrate interface.Our experimental evidence and thermody-namic modelling suggest that Fe accelerates interdiffusion and destabilizes theγ’phase,thereby causing the formation of a thick andγ’-depleted interdiffusion zone.In addition,the AlCoCrFeNiY bond coat un-dergoes more Al depletion and subsequentβtoγtransformation compared with NiCoCrAlY.Based on the findings in this work,a novel AlCoCrFeNiY/NiCoCrAlY double-layer bond coat was designed,tested and validated to achieve optimal balance between oxidation and interdiffusion.展开更多
A comparative study was conducted on the oxidation behavior of four different bond coat structures:single-layer air plasma spraying(APS),single-layer high-velocity oxygen fuel(HVOF),double-layer APS+HVOF,and double-la...A comparative study was conducted on the oxidation behavior of four different bond coat structures:single-layer air plasma spraying(APS),single-layer high-velocity oxygen fuel(HVOF),double-layer APS+HVOF,and double-layer HVOF+HVOF in a high-temperature and high-water vapor environment.The oxidation resistance and surface mixed oxide(MO)growth behavior and formation mechanisms of different structures in this environment were analyzed.The results indicate that CoNiCrAlY bond coats with different structures exhibit distinct oxidation behaviors in a high-temperature,high-water vapor environment.The growth of the MO phase is significantly influenced by the bond coat structure,and the high-water vapor environment promotes the nucleation and growth of bulk MO phase,resulting in a multilayer internal structure.Among these,the double-layer HVOF bond coat structure demonstrates superior resistance to water vapor corrosion,with fewer surface MO formations.These findings suggest that proper structural design can enhance the water vapor corrosion resistance of MCrAlY bond coats,providing theoretical foundations and technical support for optimizing their applications in high-temperature,high-water vapor environments.展开更多
The surface properties of the air-plasma sprayed bond-coat have been modified by cathode plasma electrolysis（CPE）. After modification, a re-melted layer without obvious pores and oxide stringers is formed,the gain s...The surface properties of the air-plasma sprayed bond-coat have been modified by cathode plasma electrolysis（CPE）. After modification, a re-melted layer without obvious pores and oxide stringers is formed,the gain size of re-melted layer is approximately 80–120 nm. It is shown, from cyclic oxidation at 1100℃,that a thin oxide scale mainly composed of α-Al;O;has been formed on the modified bond-coat and the oxidation resistance of the modified bond-coat has been significantly improved. Such beneficial result can be attributed to following effects: during CPE process, the plasma discharges with high temperature take place on the bond-coat surface. With plasma discharge treatment, the surface is melted and quickly re-solidified, the grain size decreases, and the pores and oxide stringers disappear. During cyclic oxidation, owing to the above modification of surface properties, the critical content of Al for selective oxidation is significantly decreased. Therefore, a continuous Al;O;scale is formed.展开更多
Fe-based and Fe/Mo composite amorphous coatings were deposited on the surface of plain carbon steel substrates by atmospheric plasma spraying （APS）. With increasing the Mo alloy content, the microstructure of the co...Fe-based and Fe/Mo composite amorphous coatings were deposited on the surface of plain carbon steel substrates by atmospheric plasma spraying （APS）. With increasing the Mo alloy content, the microstructure of the coatings revealed more dense structure. The porosities of composite coating were all less than those of Fe-based coat- ing due to Mo alloy self-bonding performance. The ML10 friction and wear tester was employed to investigate the wear behaviors of the coatings under dry sliding conditions. It was found that the mass loss of the resultant coatings decreased with increasing Mo-based powders into the feedstock. This was attributed to the reduction of the delamina- tions resulting from improved intersplat bond with Mo addition.展开更多
The mechanical properties of thermally sprayed metallic coatings are limited by the bonding between splats.In this study,tungsten coatings were deposited at different deposition temperatures by controlling the substra...The mechanical properties of thermally sprayed metallic coatings are limited by the bonding between splats.In this study,tungsten coatings were deposited at different deposition temperatures by controlling the substrate temperature through shrouded plasma spraying.The dependence of the splat bonding and mechanical properties of W coatings on deposition temperature was investigated.The results showed that the apparent porosity of the coatings decreased from 3.2%to 0.3%with the increase of the deposition temperature.The Young's modulus of W coating was significantly increased from 128 to 307 GPa as the deposition temperature increased from room temperature to 800°C.The microhardness of the coatings was less influenced by the deposition temperature.It was found that splat bonding across lamellae was formed when the deposition temperature was higher than 600°C compared to the obvious lamellae interface in the coatings deposited at temperatures lower than 600°C.The results evidently revealed that the mechanical properties of plasma-sprayed W coatings could be controlled through the splat bonding by altering deposition temperature.展开更多
On the basis of the alloying theory of bonding assistant coat （BAC）, taking into account of the interaction of alloy elements, the regressive equation, which relates the wetting ability of bonding assistant coat wit...On the basis of the alloying theory of bonding assistant coat （BAC）, taking into account of the interaction of alloy elements, the regressive equation, which relates the wetting ability of bonding assistant coat with the contents of Mn, Ni, Si, Sn, and B, was es- tablished by using quadratic regression orthogonal design of five factors. The influence of elements and their interaction on the wetting ability was analyzed. The ranges of alloy elements were optimized. The melting point of bonding assistant coat was measured by using differential thermal analysis. The results show that the interactions of Ni and Mn, Ni, and Sn can increase the wetting ability obviously and the melting point of bonding assistant coat has been decreased.展开更多
The Zr coating was deposited on titanium surface using the magnetron sputtering technique. Effects of Zr coating on microstructure and mechanical properties of porcelain fired to titanium have been investigated. The r...The Zr coating was deposited on titanium surface using the magnetron sputtering technique. Effects of Zr coating on microstructure and mechanical properties of porcelain fired to titanium have been investigated. The results show that interdiffusion of elements occurs during porcelain firing, and the Zr coating can effectively protect titanium surface from excess oxidation. The strength of bond zone with Zr coating deposited for 1 hour reaches 29. 7 MPa, which has increased by 26.4% as compared with that of bond zone without coating （23.5 MPa）.展开更多
A novel technique combining electrophoretic deposition (EPD) and reaction bonding process (RBP) is developed to fabricate thick ZrO2/Al2O3 composite coatings. Mixed organic solvents are used here to make suspension co...A novel technique combining electrophoretic deposition (EPD) and reaction bonding process (RBP) is developed to fabricate thick ZrO2/Al2O3 composite coatings. Mixed organic solvents are used here to make suspension containing yttria stablised zirconia (YSZ) and aluminium (Al). The results show that densely packed green form coatings are deposited using a mixture of ethanol and acetylacetone as suspension medium and ball milling for 48 hours. On subsequent heat treatment, melting and oxidation of aluminium in the green forms promote densification during sintering. By these means, thick, uniform and crack-free ZrtVA^Oa composite coatings have been fabricated on metal substrate.展开更多
A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent short...A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent shortcoming and controversy. The interface bond strength obtained by the test method is completely the inherent property of the interface and depends only on coating material properties, spray conditions, and technique of depositing the coating. By extensive tests, it is shown that the test tesults are very tepeatable and reliable. Furthermore, from this test, the critical coating thickness under which the coating spall can not emerge is also obtained.展开更多
Self-propagating high-temperature synthesis (SHS) with reduction process was used to fabricate TiB2 powder from TiO2-B2O3-Mg system. The colloidal alumina-bonded TiB2 paste was prepared and coated on the cathode carbo...Self-propagating high-temperature synthesis (SHS) with reduction process was used to fabricate TiB2 powder from TiO2-B2O3-Mg system. The colloidal alumina-bonded TiB2 paste was prepared and coated on the cathode carbon blocks. Various properties of the baked paste such as the corrosive resistance, thermal expansion and wettability were tested. Experimental results showed that the colloidal alumina-bonded TiB2 coating could be well wetted by liquid aluminum; and the thermal expansion coefficient of the coated material was 5.8x10(-6) degreesC(-1) at 20-1000 degreesC, which was close to that of the traditional anthracite block cathode (4x10(-6) degreesC(-1)); the electrical resistivity was 8 mu Omega (.)m at 900 degreesC when the content of alumina in the coated material was about 9% in mass fraction. In addition, some other good results such as sodium resistance were also reported.展开更多
A WC-Co/NiCrBSi composite coating was made on 42CrMo steel through vacuum brazing technology. The effects of cobalt and WC-17Co content on the properties of the coating were analyzed. The abrasive wear resistance decr...A WC-Co/NiCrBSi composite coating was made on 42CrMo steel through vacuum brazing technology. The effects of cobalt and WC-17Co content on the properties of the coating were analyzed. The abrasive wear resistance decreased as the cobalt content increased. The tensile strength of the coating increased with the increase of the WC-17Co content and the maximum strength approaches to 184MPa. The abrusive property of the composite coating is better than that of the WC-17Co/NiCrBSi flame overlaying and CoCrW overlaying.展开更多
Fluororesin-based anti-corrosive coatings including graded FEP/PPS were prepared on carbon steel by melt powder coating, the bonding strength of all coating systems was determined by the pull-off test. It is found tha...Fluororesin-based anti-corrosive coatings including graded FEP/PPS were prepared on carbon steel by melt powder coating, the bonding strength of all coating systems was determined by the pull-off test. It is found that the poor adhesion of fluororesin coatings to metallic substrates is improved obviously by the graded coating structure of FEP/PPS, and the bonding strength reaches up to 11.8 MPa for the five-layer system. Examination by electron probe microanalysis （EPMA） verifies that the distribution of main components is graded in the five-layer system, which is responsible for the enhancement of the interfacial bonding.展开更多
The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic ...The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic recoiling at 10 keV and 20 keV, the coating layers are of excellent bonding strengths. The bonding strength of CrN coating with 40 keV static recoiling is higher than that of low energy(20 keV). On the other hand, the bonding strength of coating with 40 keV dynamic recoiling is much lower than that of static recoiling at the same energy and even less than that of dynamic recoiling intermixings at 10 keV and 20 keV energy. The results of scratch and spherical rolling contact fatigue methods exhibit the same trend for each group of recoiling methods, yet the results of the scratch and fatigue tests for two groups do not agree with each other.展开更多
Quasi-columnar structure 7YSZ（yttria stabilized zirconia） thermal barrier coatings（TBCs） are prepared by plasma spray-physical vapor deposition（PS-PVD） onto pretreated and un-pretreated bond coating, respectivel...Quasi-columnar structure 7YSZ（yttria stabilized zirconia） thermal barrier coatings（TBCs） are prepared by plasma spray-physical vapor deposition（PS-PVD） onto pretreated and un-pretreated bond coating, respectively. An isothermal oxidation experiment of 7YSZ TBCs is carried out in the atmosphere of 950 °C in order to simulate the high-temperature oxidation process of engine blades. The isothermal oxidation process of 7YSZ thermal barrier coatings is investigated systematically by impedance spectroscopy. The electrochemical physical model and equivalent circuit of columnar 7YSZ coatings are established. Results show that the isothermal oxidation kinetic curve of columnar 7YSZ thermal barrier coatings appears to follow the parabolic law. A pretreatment of bond coating can reduce the growth rate of the thermally grown oxide（TGO） layer, restraining the initiation and propagation of microcracks between YSZ and TGO layers. The oxidation rate constants of 7YSZ coatings with pretreated and un-pretreated bond coating are 0.101×10^（-12） cm^2·s^（-1） and 0.115 × 10^（-13） cm^2 ·s^（-1）, respectively. Impedance analysis shows that the content of oxygen vacancies decreases and the density increases after the TGO layer is oxidized for 150 h. In addition, shrinkage microcracks formed by sintering during the oxidation process is the main reason for an increase of the capacitance and a decrease of the resistance in the grain boundary of YSZ.展开更多
目的:探讨通用型粘结剂(Single Bond Universal,SBU)对牙本质的粘结强度。方法:选取A组(SBU)、B组(S3bond)和C组(hybrid coat,Hy C)三组不同类型处理剂,分别比较A组与B、C两组的牙本质微拉伸粘结强度。各组样本数量相同(n=30),结果通过...目的:探讨通用型粘结剂(Single Bond Universal,SBU)对牙本质的粘结强度。方法:选取A组(SBU)、B组(S3bond)和C组(hybrid coat,Hy C)三组不同类型处理剂,分别比较A组与B、C两组的牙本质微拉伸粘结强度。各组样本数量相同(n=30),结果通过两独立样本t检验进行统计学分析(α=0.05),通过扫描电镜观察断裂模式。结果:A组拉伸强度约23.371MP,与B组间无统计学差异,显示了与B组同等的粘结强度;与C组(17.314MP)比较,A组显示了较高的粘结强度,两组间有显著的统计学差异。断裂模式显示,三组断裂都主要以界面断裂为主,A、B两组样本断面可见牙本质小管结构,C组可见极少量牙本质小管结构。结论:通用型粘结剂Single Bond Universal具备与传统自酸一步法粘结剂同等的粘结强度,可以满足临床粘结要求;Single Bond Universal作为牙本质保护膜用于即刻牙本质封闭时,对牙本质小管有一定的封闭作用,并且可以获得较hybrid coat牙本质保护膜更高的粘结力,但其对牙本质小管的封闭效果还有待进一步实验研究。展开更多
Indentation creep behavior with cylindrical flat indenters on the thermal barrier coating (TBC) was studied by finite element method (FEM). On ike constant applied indentation creep stress, there is a steady creep rat...Indentation creep behavior with cylindrical flat indenters on the thermal barrier coating (TBC) was studied by finite element method (FEM). On ike constant applied indentation creep stress, there is a steady creep rate for each case studied for different creep properties of the TBC system. The steady creep depth rate depends on the applied indentation creep stress and size of the indenters as well as the creep properties of the bond coat of the TBC and the substrate. The possibilities to determine the creep properties of a thermal barrier system from indention creep testing were discussed. As an example, with two different size indenters, the creep properties of bond coat of the TBC system can be derived by an inverse FEM method. This study not only provides a numerical method to obtain the creep properties of the TBC system, but also extends the application of indentation creep method with cylindrical flat indenters.展开更多
基金financially sponsored by the National Natural Science Foundations of China(Nos.51590894,51425102 and 51231001)。
文摘Thermal barrier coatings(TBCs) consisting ofLa_(2)Ce_(2)O_(7)(LCO) and Y_(2)O_(3)-stabilized-ZrO_(2)(YSZ) doubleceramic layer and Dy/Pt co-doped NiAl bond coat were produced by electron beam physical vapor deposition(EBPVD). Thermal cyclic performance of the TBCs was evaluated by flame shock testing at 1300 ℃. For comparison, the TBCs with a undoped NiAl bond coat were also studied. The microstructural evolution and failure mechanisms of the above TBCs during thermal cycling were investigated. Spallation failure of the TBCs with the undoped bond coat occurs after around 500 cycles by cracking at the interface between YSZ ceramic layer and thermally grown oxides(TGO) layer. The TBCs with Pt/Dy modified bond coat reveal improved interface bonding even after 1200 thermal cycles, whereas some delamination cracks are presented in the LCO layer. On the other hand,the Pt/Dy modified bond coat effectively suppresses the formation of the needle-like topologically closed packed phases(TCP) in the single crystal superalloy.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)(IRT0512)the Program for New Century Excellent Talents in University(NCET)+1 种基金the National Natural Science Foundation of China(Nos.50671002and50971013)the National Institute for Materials Science (NIMS) internship program
文摘In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt＋2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.
基金financially supported by the National Natural Science Foundation of China(Nos.52201082 and 51971139)the Science Center for Gas Turbine Project(No.P2022-A-I-002-001)+1 种基金the Shanghai Sailing Program(No.22YF1419200)sponsored by the Chenguang Program supported by Shanghai Education Development Foundation and Shanghai Municipal Education Commission(No.21CGA10).
文摘The oxidation and interdiffusion behavior of a novel AlCoCrFeNiY bond coat deposited on a directionally solidified Ni-based superalloy were systematically studied at 1050,1100 and 1150°C,and compared with a conventional NiCoCrAlY coating deposited on the same substrate.The AlCoCrFeNiY bond coat exhibits lower oxide growth rates due to its large columnar grains and low Al activity at the oxide scale/bond coat interface.Meanwhile,AlCoCrFeNiY has higher resistance to oxide spallation than NiCoCrAlY,which is attributed to the formation of a clean and defect-free metal/oxide interface.Significant interdiffusion occurs across the AlCoCrFeNiY/superalloy substrate interface.Our experimental evidence and thermody-namic modelling suggest that Fe accelerates interdiffusion and destabilizes theγ’phase,thereby causing the formation of a thick andγ’-depleted interdiffusion zone.In addition,the AlCoCrFeNiY bond coat un-dergoes more Al depletion and subsequentβtoγtransformation compared with NiCoCrAlY.Based on the findings in this work,a novel AlCoCrFeNiY/NiCoCrAlY double-layer bond coat was designed,tested and validated to achieve optimal balance between oxidation and interdiffusion.
基金financially supported by the Funds of Science Center for Gas Turbine Project(No.P2022–B-Ⅳ-009–001)Beijing Natural Science Foundation(No.22B20116),Zhejiang Provincial Natural Science Foundation of China(No.LZ23E020005)+1 种基金University-Industry Cooperation Projects(No.HFZL2021CXY016)the Key R&D Program of Zhejiang(No.2024SSYS0075).
文摘A comparative study was conducted on the oxidation behavior of four different bond coat structures:single-layer air plasma spraying(APS),single-layer high-velocity oxygen fuel(HVOF),double-layer APS+HVOF,and double-layer HVOF+HVOF in a high-temperature and high-water vapor environment.The oxidation resistance and surface mixed oxide(MO)growth behavior and formation mechanisms of different structures in this environment were analyzed.The results indicate that CoNiCrAlY bond coats with different structures exhibit distinct oxidation behaviors in a high-temperature,high-water vapor environment.The growth of the MO phase is significantly influenced by the bond coat structure,and the high-water vapor environment promotes the nucleation and growth of bulk MO phase,resulting in a multilayer internal structure.Among these,the double-layer HVOF bond coat structure demonstrates superior resistance to water vapor corrosion,with fewer surface MO formations.These findings suggest that proper structural design can enhance the water vapor corrosion resistance of MCrAlY bond coats,providing theoretical foundations and technical support for optimizing their applications in high-temperature,high-water vapor environments.
基金financially supported by the National Natural Science Foundation of China (Grant No. 51271030)
文摘The surface properties of the air-plasma sprayed bond-coat have been modified by cathode plasma electrolysis（CPE）. After modification, a re-melted layer without obvious pores and oxide stringers is formed,the gain size of re-melted layer is approximately 80–120 nm. It is shown, from cyclic oxidation at 1100℃,that a thin oxide scale mainly composed of α-Al;O;has been formed on the modified bond-coat and the oxidation resistance of the modified bond-coat has been significantly improved. Such beneficial result can be attributed to following effects: during CPE process, the plasma discharges with high temperature take place on the bond-coat surface. With plasma discharge treatment, the surface is melted and quickly re-solidified, the grain size decreases, and the pores and oxide stringers disappear. During cyclic oxidation, owing to the above modification of surface properties, the critical content of Al for selective oxidation is significantly decreased. Therefore, a continuous Al;O;scale is formed.
基金the Special Found for Basic Scientific Research of Central Colleges,Chang'an University (00092014G1311093)the Special Fund for Basic Research Support Plan of Chang'an Universitythe Open Fund of Engineering Research Center of Transportation Materials,Ministry of Education of China
文摘Fe-based and Fe/Mo composite amorphous coatings were deposited on the surface of plain carbon steel substrates by atmospheric plasma spraying （APS）. With increasing the Mo alloy content, the microstructure of the coatings revealed more dense structure. The porosities of composite coating were all less than those of Fe-based coat- ing due to Mo alloy self-bonding performance. The ML10 friction and wear tester was employed to investigate the wear behaviors of the coatings under dry sliding conditions. It was found that the mass loss of the resultant coatings decreased with increasing Mo-based powders into the feedstock. This was attributed to the reduction of the delamina- tions resulting from improved intersplat bond with Mo addition.
基金National Natural Science Foundations of China(50725101)
文摘The mechanical properties of thermally sprayed metallic coatings are limited by the bonding between splats.In this study,tungsten coatings were deposited at different deposition temperatures by controlling the substrate temperature through shrouded plasma spraying.The dependence of the splat bonding and mechanical properties of W coatings on deposition temperature was investigated.The results showed that the apparent porosity of the coatings decreased from 3.2%to 0.3%with the increase of the deposition temperature.The Young's modulus of W coating was significantly increased from 128 to 307 GPa as the deposition temperature increased from room temperature to 800°C.The microhardness of the coatings was less influenced by the deposition temperature.It was found that splat bonding across lamellae was formed when the deposition temperature was higher than 600°C compared to the obvious lamellae interface in the coatings deposited at temperatures lower than 600°C.The results evidently revealed that the mechanical properties of plasma-sprayed W coatings could be controlled through the splat bonding by altering deposition temperature.
基金This work was financially supported by the National High-Tech Research and Development Program of China (863 Program) (No.2002AA334070).
文摘On the basis of the alloying theory of bonding assistant coat （BAC）, taking into account of the interaction of alloy elements, the regressive equation, which relates the wetting ability of bonding assistant coat with the contents of Mn, Ni, Si, Sn, and B, was es- tablished by using quadratic regression orthogonal design of five factors. The influence of elements and their interaction on the wetting ability was analyzed. The ranges of alloy elements were optimized. The melting point of bonding assistant coat was measured by using differential thermal analysis. The results show that the interactions of Ni and Mn, Ni, and Sn can increase the wetting ability obviously and the melting point of bonding assistant coat has been decreased.
文摘The Zr coating was deposited on titanium surface using the magnetron sputtering technique. Effects of Zr coating on microstructure and mechanical properties of porcelain fired to titanium have been investigated. The results show that interdiffusion of elements occurs during porcelain firing, and the Zr coating can effectively protect titanium surface from excess oxidation. The strength of bond zone with Zr coating deposited for 1 hour reaches 29. 7 MPa, which has increased by 26.4% as compared with that of bond zone without coating （23.5 MPa）.
文摘A novel technique combining electrophoretic deposition (EPD) and reaction bonding process (RBP) is developed to fabricate thick ZrO2/Al2O3 composite coatings. Mixed organic solvents are used here to make suspension containing yttria stablised zirconia (YSZ) and aluminium (Al). The results show that densely packed green form coatings are deposited using a mixture of ethanol and acetylacetone as suspension medium and ball milling for 48 hours. On subsequent heat treatment, melting and oxidation of aluminium in the green forms promote densification during sintering. By these means, thick, uniform and crack-free ZrtVA^Oa composite coatings have been fabricated on metal substrate.
文摘A novel test method of measuring the interface bond strength between a thermal sprayed coating and substrate is put forward first in this paper. The test method is simple and reliable, and exists no any inherent shortcoming and controversy. The interface bond strength obtained by the test method is completely the inherent property of the interface and depends only on coating material properties, spray conditions, and technique of depositing the coating. By extensive tests, it is shown that the test tesults are very tepeatable and reliable. Furthermore, from this test, the critical coating thickness under which the coating spall can not emerge is also obtained.
文摘Self-propagating high-temperature synthesis (SHS) with reduction process was used to fabricate TiB2 powder from TiO2-B2O3-Mg system. The colloidal alumina-bonded TiB2 paste was prepared and coated on the cathode carbon blocks. Various properties of the baked paste such as the corrosive resistance, thermal expansion and wettability were tested. Experimental results showed that the colloidal alumina-bonded TiB2 coating could be well wetted by liquid aluminum; and the thermal expansion coefficient of the coated material was 5.8x10(-6) degreesC(-1) at 20-1000 degreesC, which was close to that of the traditional anthracite block cathode (4x10(-6) degreesC(-1)); the electrical resistivity was 8 mu Omega (.)m at 900 degreesC when the content of alumina in the coated material was about 9% in mass fraction. In addition, some other good results such as sodium resistance were also reported.
文摘A WC-Co/NiCrBSi composite coating was made on 42CrMo steel through vacuum brazing technology. The effects of cobalt and WC-17Co content on the properties of the coating were analyzed. The abrasive wear resistance decreased as the cobalt content increased. The tensile strength of the coating increased with the increase of the WC-17Co content and the maximum strength approaches to 184MPa. The abrusive property of the composite coating is better than that of the WC-17Co/NiCrBSi flame overlaying and CoCrW overlaying.
文摘Fluororesin-based anti-corrosive coatings including graded FEP/PPS were prepared on carbon steel by melt powder coating, the bonding strength of all coating systems was determined by the pull-off test. It is found that the poor adhesion of fluororesin coatings to metallic substrates is improved obviously by the graded coating structure of FEP/PPS, and the bonding strength reaches up to 11.8 MPa for the five-layer system. Examination by electron probe microanalysis （EPMA） verifies that the distribution of main components is graded in the five-layer system, which is responsible for the enhancement of the interfacial bonding.
文摘The coating substrate bonding strengths under different intermixing processes were evaluated by scratch and spherical rolling contact fatigue methods. The results show that for low bombarding energy of N ions dynamic recoiling at 10 keV and 20 keV, the coating layers are of excellent bonding strengths. The bonding strength of CrN coating with 40 keV static recoiling is higher than that of low energy(20 keV). On the other hand, the bonding strength of coating with 40 keV dynamic recoiling is much lower than that of static recoiling at the same energy and even less than that of dynamic recoiling intermixings at 10 keV and 20 keV energy. The results of scratch and spherical rolling contact fatigue methods exhibit the same trend for each group of recoiling methods, yet the results of the scratch and fatigue tests for two groups do not agree with each other.
基金financial supports from National Key Research Program (No. 2017YFB0306100)Guangdong Academy of Sciences (No. 2017GDASCX-0843)+3 种基金Guang-dong Technical Research Program (No’s. 201707010385, 2014B070706026, and 2013B061800053)Guangdong Natural Science Foundation (No. 2016A030312015)National Natural Science Foundation of China (No. 51501044)Guangzhou Technical Research Program (No. 201707010385)
文摘Quasi-columnar structure 7YSZ（yttria stabilized zirconia） thermal barrier coatings（TBCs） are prepared by plasma spray-physical vapor deposition（PS-PVD） onto pretreated and un-pretreated bond coating, respectively. An isothermal oxidation experiment of 7YSZ TBCs is carried out in the atmosphere of 950 °C in order to simulate the high-temperature oxidation process of engine blades. The isothermal oxidation process of 7YSZ thermal barrier coatings is investigated systematically by impedance spectroscopy. The electrochemical physical model and equivalent circuit of columnar 7YSZ coatings are established. Results show that the isothermal oxidation kinetic curve of columnar 7YSZ thermal barrier coatings appears to follow the parabolic law. A pretreatment of bond coating can reduce the growth rate of the thermally grown oxide（TGO） layer, restraining the initiation and propagation of microcracks between YSZ and TGO layers. The oxidation rate constants of 7YSZ coatings with pretreated and un-pretreated bond coating are 0.101×10^（-12） cm^2·s^（-1） and 0.115 × 10^（-13） cm^2 ·s^（-1）, respectively. Impedance analysis shows that the content of oxygen vacancies decreases and the density increases after the TGO layer is oxidized for 150 h. In addition, shrinkage microcracks formed by sintering during the oxidation process is the main reason for an increase of the capacitance and a decrease of the resistance in the grain boundary of YSZ.
文摘目的:探讨通用型粘结剂(Single Bond Universal,SBU)对牙本质的粘结强度。方法:选取A组(SBU)、B组(S3bond)和C组(hybrid coat,Hy C)三组不同类型处理剂,分别比较A组与B、C两组的牙本质微拉伸粘结强度。各组样本数量相同(n=30),结果通过两独立样本t检验进行统计学分析(α=0.05),通过扫描电镜观察断裂模式。结果:A组拉伸强度约23.371MP,与B组间无统计学差异,显示了与B组同等的粘结强度;与C组(17.314MP)比较,A组显示了较高的粘结强度,两组间有显著的统计学差异。断裂模式显示,三组断裂都主要以界面断裂为主,A、B两组样本断面可见牙本质小管结构,C组可见极少量牙本质小管结构。结论:通用型粘结剂Single Bond Universal具备与传统自酸一步法粘结剂同等的粘结强度,可以满足临床粘结要求;Single Bond Universal作为牙本质保护膜用于即刻牙本质封闭时,对牙本质小管有一定的封闭作用,并且可以获得较hybrid coat牙本质保护膜更高的粘结力,但其对牙本质小管的封闭效果还有待进一步实验研究。
基金supported by the National Natural Science Foundation of China(50005016,50375124)China Aviation Foundation(02c53011,03B53003)as well as the Yangtze River Foundation.
文摘Indentation creep behavior with cylindrical flat indenters on the thermal barrier coating (TBC) was studied by finite element method (FEM). On ike constant applied indentation creep stress, there is a steady creep rate for each case studied for different creep properties of the TBC system. The steady creep depth rate depends on the applied indentation creep stress and size of the indenters as well as the creep properties of the bond coat of the TBC and the substrate. The possibilities to determine the creep properties of a thermal barrier system from indention creep testing were discussed. As an example, with two different size indenters, the creep properties of bond coat of the TBC system can be derived by an inverse FEM method. This study not only provides a numerical method to obtain the creep properties of the TBC system, but also extends the application of indentation creep method with cylindrical flat indenters.
