This study intends to find out the correlation between the cover depth and the bond characteristics of UHPC through pull-out tests of UHPC specimens with different cover depths and bond tests of rebar using flexural m...This study intends to find out the correlation between the cover depth and the bond characteristics of UHPC through pull-out tests of UHPC specimens with different cover depths and bond tests of rebar using flexural members. In this experimental study, specimens are fabricated with the lap-splice length as test variable in relation with the calculation of the lap-splice length for 180- MPa UHPC. Moreover, specimens are also fabricated with the cover depth as test variable to evaluate the effect of the cover depth on the UHPC flexural members. The load-displacement curves are analyzed for each of these test variables to compute the lap-splice length proposed in the K-UHPC structural design guideline and to evaluate the influence of the cover depth on the flexural members. As a result, the stability of the structural behavior can be significantly enhanced by increasing slightly the cover depth specification of the current UHPC Structure Design Guideline from the maximum value between 1.5 times of rebar diameter and 20 mm to the maximum value between 1.5 times of rebar diameter and 25 mm.展开更多
The operation of reinforced concrete structures is directly associated with the adhesion between the steel bar and the concrete,which allows the internal forces to be transferred to the reinforcement during the ...The operation of reinforced concrete structures is directly associated with the adhesion between the steel bar and the concrete,which allows the internal forces to be transferred to the reinforcement during the process of loading the structural elements.The modification of the concrete composition,with the introduction of recycled aggregate from construction and demolition waste(CDW),affects the steel-concrete interface and can modify the bonding stress,which is also influenced by the type and diameter of the bar used.In this work,the influence of the recycled fine aggregate(RFA)and types of steel bar on the steel-concrete bond was experimentally evaluated using the pullout test.Conventional concrete and recycled concrete,with RFA replacement level of 25%,were produced.Two types of steel rebars(i.e.,plain and deformed)with diameters of 10.0 and 16.0 mm were considered in this paper.The results indicate a reduction in the adhesion stress with the introduction of recycled aggregate,but this trend is influenced by the diameter of the bar used.The use of ribbed bars modifies the stress bon-slip behavior,with an increase in the average bond strength,which is also observed with the reduction of the diameter of the bar.展开更多
The steel corrosion in concrete is widely reported over the last two to three decades. Much effort has been devoted to researching the causes and mechanisms of reinforcement corrosion and to the questions of durabilit...The steel corrosion in concrete is widely reported over the last two to three decades. Much effort has been devoted to researching the causes and mechanisms of reinforcement corrosion and to the questions of durability for concrete structures, but relatively little attention has been devoted to the problem of assessing the effect of bond loss due to corrosion on the structural behavior of corroded elements. From the test results on corroded specimens, the mechanism of degradation in bond behavior between corroded bars and concrete, and the effects of bond loss on structural performances are summarized. Results show that corrosion level, cover depth-W-bar diameter ratio, surface condition of re/nforcement, stirrups, etc. can influence the bond behavior of corroded bars. In addition, the deterioration in bond due to corrosion may induce reduction in bearing capacity, degradation of serviceability, and the loss in ductility for steel-corroded concrete members.展开更多
In this study,a new linear friction welding(LFW)process,embedded LFW process,was put forward,which was mainly applied to combination manufacturing of long or overlong loadcarrying titanium alloy structural components ...In this study,a new linear friction welding(LFW)process,embedded LFW process,was put forward,which was mainly applied to combination manufacturing of long or overlong loadcarrying titanium alloy structural components in aircraft.The interfacial plastic flow behavior and bonding mechanism of this process were investigated by a developed coupling EulerianLagrangian numerical model using software ABAQUS and a novel thermo-physical simulation method with designed embedded hot compression specimen.In addition,the formation mechanism and control method of welding defects caused by uneven plastic flow were discussed.The results reveal that the plastic flow along oscillating direction of this process is even and sufficient.In the direction perpendicular to oscillation,thermo-plastic metals mainly flow downward along welding interface under coupling of shear stress and interfacial pressure,resulting in the interfacial plastic zone shown as an inverted“V”shape.The upward plastic flow in this direction is relatively weak,and only a small amount of flash is extruded from top of joint.Moreover,the wedge block and welding components at top of joint are always in un-steady friction stage,leading to nonuniform temperature field distribution and un-welded defects.According to the results of numerical simulation,high oscillating frequency combined with low pressure and small amplitude is considered as appropriate parameter selection scheme to improve the upward interfacial plastic flow at top of joint and suppress the un-welded defects.The results of thermo-physical simulation illustrate that continuous dynamic recrystallization(CDRX)induces the bonding of interface,accompanying by intense dislocation movement and creation of many low-angle grain boundaries.In the interfacial bonding area,grain orientation is random with relatively low texture density(5.0 mud)owing to CDRX.展开更多
Sodium-ion batteries(SIBs) and potassium-ion batteries(PIBs) are the most promising alternatives to lithium-ion batteries, and thus have drawn intensive research attention. Porous carbon materials from different precu...Sodium-ion batteries(SIBs) and potassium-ion batteries(PIBs) are the most promising alternatives to lithium-ion batteries, and thus have drawn intensive research attention. Porous carbon materials from different precursors have been widely used as anode materials owing to their compatible storage effectiveness of both larger radii sodium and potassium ions. However, the differential bonding behaviors of Na and K ions with porous carbon-based anode are the significant one worth investigating, which could provide a clean picture of alkali ions storage mechanism. Therefore, in this work, we prepare a porous carbon network derived from sawdust(SDC) wastes, to further analyze the differences on sodium and potassium ions storage behaviors in terms of bond-forming process. It is found that, as-prepared SDC anodes could deliver stable sodium and potassium storage capacities, however, there are notable distinctions in terms of electrochemical behaviors and diffusion processes. By virtue of ex-situ XRD and Raman spectroscopy, the phase transition reaction of potassium ions could be well-observed, and the results shows that the multiple intercalated compounds was formed in SDC network during ions insertion, further resulting in slower diffusion kinetics and larger resistance compared to non-bonded process of sodium ions storage. This study provides more insights into the differences between sodium and potassium ions storage, as well as the energy storage mechanism of porous carbon as anodes for secondary batteries.展开更多
In this work, porous Ti6Al4V alloys with 30%-70% porosity for biomedical applications were fabricated by diffusion bonding of alloy meshes. Pore structure was characterized by Micro-CT and SEM. Compressive behavior in...In this work, porous Ti6Al4V alloys with 30%-70% porosity for biomedical applications were fabricated by diffusion bonding of alloy meshes. Pore structure was characterized by Micro-CT and SEM. Compressive behavior in the out-of-plane direction and biocompatibility with cortical bone were studied. The results reveal that the fabricated porous Ti6Al4V alloys possess anisotropic structure with square pores in the in-plane direction and elongated pores in the out-of-plane direction. The average pore size of porous Ti6Al4V alloys with 30%-70% porosity is in the range of 240-360 Bin. By tailoring diffusion bonding temperature, aspect ratio of alloy meshes and porosity, porous Ti6Al4V alloys with different compressive properties can be obtained, for instance, Young＇s modulus and yield stress in the ranges of 4-40 GPa and 70-500 MPa, respectively. Yield stress of porous Ti6Al4V alloys fabricated by diffusion bonding is close to that of alloys fabricated by rapid prototyping, hut higher than that of fabricated by powder sintering and space-holder method. Diffusion bonding temperature has some effects on the yield stress of porous Ti6Al4V alloys, but has a minor effect on the Young＇s modulus. The relationship between compressive properties and relative density conforms well to the Gibson-Ashby model. The Young＇s modulus is linear with the aspect ratio, while the yield stress is linear with the square of aspect ratio of alloy meshes. Porous Ti6Al4V alloys with 60%-70% porosity have potential for cortical bone implant applications.展开更多
The mechanical behavior of inherently anisotropic shale rocks under Brazilian test conditions are investigated in this study based on experimental studies and numerical simulations. The effects of the weak lamination ...The mechanical behavior of inherently anisotropic shale rocks under Brazilian test conditions are investigated in this study based on experimental studies and numerical simulations. The effects of the weak lamination planes and interlayer bonding force of these layers on the failure strength and fracture patterns are studied systematically. Numerical simulations using particle flow code in two dimensions based on the discrete element method showed a good agreement with the experimental results in the failure strength and fracture patterns. The shale revealed strong anisotropic behavior with the failure strength perpendicular to the lamination plane greater than failure strength parallel to lamination plane. The failure strength of the different interlayer bonding force against the layer orientations changed significantly. Four types of fracture patterns were observed: curved fracture, broken-linear fracture, layeractivated fracture, and central-linear fracture. The observed fracture patterns are either or a combination of tensile and/or shear fractures. Increase in interlayer bonding strength decreased the quantity of micro cracks and this directly led to reduction in the anisotropic behavior. Overall the layer orientation and interlayer bonding force of the shale thus play a very important role in the anisotropic behavior of the shale.展开更多
Repair and reinformcement of aged civil steel structures is one of the important issues for maintaining and using them for a long term. For repair and reinforcement of deteriorated civil steel structures due to fatigu...Repair and reinformcement of aged civil steel structures is one of the important issues for maintaining and using them for a long term. For repair and reinforcement of deteriorated civil steel structures due to fatigue and corrosion, patch plate reinforcement is widely applied. Bolting is generally used because of easy quality control and many construction achievements. However, bolting has downsides including holes made and weight increase. Welding is considered to overcome these demerits but in reality the application of welding is unsatisfactory due to the possibility of fatigue crack occurring from the welded part. In this study, a patch plate strengthening system of welded joint assisted with bonding has been proposed. The compressive behaviors of weld-bond jointed specimen were investigated by a series of experiments and FE analysis. It was confirmed that use of welding and bonding was effective to enhance compressive strength of specimen, due to better load-carrying capacity of patch plate compared with sole use of welding.展开更多
In the present work, the blend of poly（butylene succinate） （PBS） and bisphenol A （BPA） was prepared by solution mixing, and the intermolecular interactions between the two components were characterized by a comb...In the present work, the blend of poly（butylene succinate） （PBS） and bisphenol A （BPA） was prepared by solution mixing, and the intermolecular interactions between the two components were characterized by a combination of nuclear magnetic resonance （NMR） and Fourier transform infrared spectroscopy （FTIR）. The results showed that intermolecular hydrogen-bonding forms between the carbonyl group of PBS and phenol hydroxyl of BPA. With the increase of BPA content, more hydrogen bonds were formed. The effect of hydrogen bonding on the crystallization behavior of PBS was investigated by differential scanning calorimetry （DSC） and polarized optical microscopy （POM）. The results showed that the overall isothermal crystallization kinetics and the spherulite growth rate of PBS decrease with the increase of BPA content, while the PBS spherulite size increases with BPA content.展开更多
The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 ...The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 and 20°C/min) and the bonding property was evaluated by the wet shear strength and wood failure of two-ply plywood panels after soaking in water (48 hours at room temperature and followed by 1-hour boiling). The test results indicated that the NCC content had little influence on the peak temperature, activation energy and the total heat of reaction of LPF resin at 5 and 10°C/min. But at 20°C/min, LPF0.00% (LPF resin without NCC) showed the highest total heat of reaction, while LPF0.25% (LPF resin containing 0.25% NCC content) and LPF0.50% (LPF resin containing 0.50% NCC content) gave the lowest value. The wet shear strength was affected by the NCC content to a certain extent. With regard to the results of one-way analysis of variance, the bonding quality could be improved by NCC and the optimum NCC content ranged from 0.25% to 0.50%. The wood failure was also affected by the NCC content, but the trend with respect to NCC content was not clear.展开更多
In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt＋2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic ...In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt＋2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.展开更多
The aim of the investigations presented here was to understand how the stiffness of the adhesive affects the failure of ceramic tiles adhered to metallic backings. The working hypothesis was that varying the adhesive ...The aim of the investigations presented here was to understand how the stiffness of the adhesive affects the failure of ceramic tiles adhered to metallic backings. The working hypothesis was that varying the adhesive stiffness could have the same effect on the ballistic performance as a variation of the adhesive thickness.Two different projectile/target combinations were utilized for ballistic tests in order to generate extremely different loading conditions. With targets consisting of 6 mm aluminum oxide ceramic and 6 mm aluminum backing, complete penetration occurred in each test with 7.62 mm tungsten carbide core AP ammunition at an impact velocity of 940 m/s. In contrast, with ceramic tiles of 20 mm thickness on 13 mm steel backing,no penetration of the ceramic occurred at the impact of a 7.62 mm ball round at 840 m/s.Four different types of adhesive(high-strength till high-flexible) were tested in both configurations. The elongation of the adhesive layer, the deformation of the metallic backing and the failure of the ceramics were observed by means of a high-speed camera during the projectile/target interaction.The results of the ballistic tests showed that a higher fracture strain caused a larger deformation of the backing compared to adhesives, which exhibit a high tensile strength and low fracture strains.The experimental results indicate that the damage behavior of the ceramic/metal composites depends on the absolute elongation of the adhesive layer. This can be controlled either by the thickness or the stiffness of the bonding layer.展开更多
A new Co（Ⅱ） coordination polymer, [Co（1,4-chdc）（L）（H2O）]n（1）, was synthesized under hydrothermal condition（1,4-H2chdc = 1,4-cyclohexanedicarboxylic acid, L = 2-（4-fluoro-phenyl）-1 H-imidazo[4,5-f][1,10]p...A new Co（Ⅱ） coordination polymer, [Co（1,4-chdc）（L）（H2O）]n（1）, was synthesized under hydrothermal condition（1,4-H2chdc = 1,4-cyclohexanedicarboxylic acid, L = 2-（4-fluoro-phenyl）-1 H-imidazo[4,5-f][1,10]phenanthroline）. Its crystal structure was determined by single-crystal X-ray diffraction. 1 crystallizes in triclinic, space group P1 with a = 8.790（5）, b = 10.486（5）, c = 13.305（5） ?, α = 87.391（5）, β = 82.925（5）, γ = 81.841（5）o, V = 1204.2（10） ?3, Z = 2, C27H23FN4O5Co, Mr = 561.42, Dc = 1.548 g/cm3, F（000） = 578, μ（Mo Ka） = 0.769 mm-1, R = 0.0415 and wR = 0.1043. In 1, each 1,4-chdc anion bridges two neighboring Co（Ⅱ） atoms to give a chain structure. The L ligands are attached on one side of the chain through chelating the Co（Ⅱ） atoms, and are stacked with those of an adjacent chain through π-π interactions, yielding a double-chain structure. The double-chain structures are linked into a supramolecular layer structure through N–H···O hydrogen-bonding interactions between the adjacent double-chain structures. Moreover, the thermal behavior of 1 was also studied.展开更多
The fracture behavior of polymer-bonded explosive(PBX) seriously affects the safety and reliability of weapon system.The effects of interface debonding and initial meso-damage on the fracture behavior of PBX under qua...The fracture behavior of polymer-bonded explosive(PBX) seriously affects the safety and reliability of weapon system.The effects of interface debonding and initial meso-damage on the fracture behavior of PBX under quasi-static tension are studied using numerical method.A twodimensional representative volume element(RVE) is established based on Voronoi model in which the component contents could be regulated and the particles are randomly distributed.A nonlinear damage model of polymer matrix relative to matrix depth between particles is constructed.The results show that the simulated strain-stress relation is coincident with experiment data.It is found that interface debonding leads to the nucleation and propagation of meso-cracks,and a main crack approximately perpendicular to the loading direction is generated finally.The interface debonding tends to occur in the interface perpendicular to the loading direction.There seems to be a phenomenon that strain softening and hardening alternatively appear around peak stress of stress and strain curve.It is shown that the initial damages of intragranular and interfacial cracks both decrease the modulus and failure stress,and the main crack tends to propagate toward the initial meso-cracks.展开更多
Because frit bonding material is brittle, sudden impacts such as dropping may damage the bonding significantly. Strain-rate-controlled in-situ nano-indentation testing, which can determine localized material propertie...Because frit bonding material is brittle, sudden impacts such as dropping may damage the bonding significantly. Strain-rate-controlled in-situ nano-indentation testing, which can determine localized material properties, was carried out on the frit-bonded specimen, especially on the frit bonding matrix and the filler. The results were compared with the drop-impact fracture behavior to understand the fracture characteristics. Mechanical properties at static condition or low strain rate did not show proper relationship with the fracture tendency of the drop tested result of the frit bonding. From the relationship between fracture toughness and the ratio of modulus/hardness, fracture characteristics at the drop impact situation could be estimated by the values at the high strain rate nano-indentation. The ratio between modulus and hardness on frit matrix showed close relationship with drop impact fracture. Though crack propagation path deflected at filler interface, filler property gave less influence on fracture tendency of drop impact fracture due to its small volume fraction. The properties of frit matrix were crucial to the fracture characteristics of the frit bonding.展开更多
The microstructure, interface thickness, element distribution and interfacial mechanical behavior of Ti-6Al-4V/Al couples prepared by an insert moulding method were investigated in depth in this paper. Moreover, Ti/Al...The microstructure, interface thickness, element distribution and interfacial mechanical behavior of Ti-6Al-4V/Al couples prepared by an insert moulding method were investigated in depth in this paper. Moreover, Ti/Al bonding was also given as a comparison for understanding the interface bonding mechanism. It is shown that there is much thinner compact sub-layer for the interface of the Ti-6Al-4V/Al joint, whose morphology is obviously different from that of the Ti/Al joint. The Ti-6Al-4V/Al interface has been proven to contain a slight content of vanadium. Moreover, both the shear strength and the interface reaction rate of Ti-6Al-4V/Al compound materials are lower than those of the Ti/Al ones.展开更多
Bonded NdFeB magnets were prepared by compression molding. The effect of preparation technology on their magnetic and mechanical properties was studied through the analysis of density, Br, Hcj, （BH）max, bending stre...Bonded NdFeB magnets were prepared by compression molding. The effect of preparation technology on their magnetic and mechanical properties was studied through the analysis of density, Br, Hcj, （BH）max, bending strength, and compressive strength of the bonded magnets. The results showed that the magnetic properties decreased with increasing binder content, whereas the mechanical properties increased. Br and （BH）max increased with rising pressure, whereas Hcj decreased. For a fixed mass fraction of the binder, the optimal pressure was 620 MPa and the best thermosetting temperature was 160°C. These conditions made the bonded magnets have the optimal mechanical properties. Scanning electron microscopy （SEM） analyses of the fracture surfaces indicated that the epoxy resin bonded magnets exhibited brittle behavior.展开更多
We use the bond percolation model to study the multifragrnentation of<sup>197</sup>Au projectiles interact-ing with Cu target at a bombarding energy of 600 MeV/u.The charge observables and some of their di...We use the bond percolation model to study the multifragrnentation of<sup>197</sup>Au projectiles interact-ing with Cu target at a bombarding energy of 600 MeV/u.The charge observables and some of their dif-ferential distributions are analyzed.The theoretical results agree well with the experimental data ofALADIN collaboration.This indicates that the percolation model can describe reasonably the universal be-havior of nuclear fragmentation in nucleus-nucleus collisions.展开更多
文摘This study intends to find out the correlation between the cover depth and the bond characteristics of UHPC through pull-out tests of UHPC specimens with different cover depths and bond tests of rebar using flexural members. In this experimental study, specimens are fabricated with the lap-splice length as test variable in relation with the calculation of the lap-splice length for 180- MPa UHPC. Moreover, specimens are also fabricated with the cover depth as test variable to evaluate the effect of the cover depth on the UHPC flexural members. The load-displacement curves are analyzed for each of these test variables to compute the lap-splice length proposed in the K-UHPC structural design guideline and to evaluate the influence of the cover depth on the flexural members. As a result, the stability of the structural behavior can be significantly enhanced by increasing slightly the cover depth specification of the current UHPC Structure Design Guideline from the maximum value between 1.5 times of rebar diameter and 20 mm to the maximum value between 1.5 times of rebar diameter and 25 mm.
基金The authors would like to thank the CAPES which sponsored the first author.
文摘The operation of reinforced concrete structures is directly associated with the adhesion between the steel bar and the concrete,which allows the internal forces to be transferred to the reinforcement during the process of loading the structural elements.The modification of the concrete composition,with the introduction of recycled aggregate from construction and demolition waste(CDW),affects the steel-concrete interface and can modify the bonding stress,which is also influenced by the type and diameter of the bar used.In this work,the influence of the recycled fine aggregate(RFA)and types of steel bar on the steel-concrete bond was experimentally evaluated using the pullout test.Conventional concrete and recycled concrete,with RFA replacement level of 25%,were produced.Two types of steel rebars(i.e.,plain and deformed)with diameters of 10.0 and 16.0 mm were considered in this paper.The results indicate a reduction in the adhesion stress with the introduction of recycled aggregate,but this trend is influenced by the diameter of the bar used.The use of ribbed bars modifies the stress bon-slip behavior,with an increase in the average bond strength,which is also observed with the reduction of the diameter of the bar.
基金The Liaoning Province CommunicationDepartment Key Science Foundation (No.0101)
文摘The steel corrosion in concrete is widely reported over the last two to three decades. Much effort has been devoted to researching the causes and mechanisms of reinforcement corrosion and to the questions of durability for concrete structures, but relatively little attention has been devoted to the problem of assessing the effect of bond loss due to corrosion on the structural behavior of corroded elements. From the test results on corroded specimens, the mechanism of degradation in bond behavior between corroded bars and concrete, and the effects of bond loss on structural performances are summarized. Results show that corrosion level, cover depth-W-bar diameter ratio, surface condition of re/nforcement, stirrups, etc. can influence the bond behavior of corroded bars. In addition, the deterioration in bond due to corrosion may induce reduction in bearing capacity, degradation of serviceability, and the loss in ductility for steel-corroded concrete members.
基金co-supported by the National Natural Science Foundation of China(Nos.52105411,52105400and 52305420)the China Postdoctoral Science Foundation(No.2023M742830)Innovation Foundation for Doctor Dissertation of Northwestern Polytechnical University(No.CX2023008).
文摘In this study,a new linear friction welding(LFW)process,embedded LFW process,was put forward,which was mainly applied to combination manufacturing of long or overlong loadcarrying titanium alloy structural components in aircraft.The interfacial plastic flow behavior and bonding mechanism of this process were investigated by a developed coupling EulerianLagrangian numerical model using software ABAQUS and a novel thermo-physical simulation method with designed embedded hot compression specimen.In addition,the formation mechanism and control method of welding defects caused by uneven plastic flow were discussed.The results reveal that the plastic flow along oscillating direction of this process is even and sufficient.In the direction perpendicular to oscillation,thermo-plastic metals mainly flow downward along welding interface under coupling of shear stress and interfacial pressure,resulting in the interfacial plastic zone shown as an inverted“V”shape.The upward plastic flow in this direction is relatively weak,and only a small amount of flash is extruded from top of joint.Moreover,the wedge block and welding components at top of joint are always in un-steady friction stage,leading to nonuniform temperature field distribution and un-welded defects.According to the results of numerical simulation,high oscillating frequency combined with low pressure and small amplitude is considered as appropriate parameter selection scheme to improve the upward interfacial plastic flow at top of joint and suppress the un-welded defects.The results of thermo-physical simulation illustrate that continuous dynamic recrystallization(CDRX)induces the bonding of interface,accompanying by intense dislocation movement and creation of many low-angle grain boundaries.In the interfacial bonding area,grain orientation is random with relatively low texture density(5.0 mud)owing to CDRX.
基金the financial support from the National Natural Science Foundation of China (No.52302222)Natural Science Foundation of Jilin Province (No.20230508177RC)+1 种基金China Postdoctoral Science Foundation (Nos.2022M720704,2023T160094)Fundamental Research Funds for the Central Universities (No.2412022QD038)。
文摘Sodium-ion batteries(SIBs) and potassium-ion batteries(PIBs) are the most promising alternatives to lithium-ion batteries, and thus have drawn intensive research attention. Porous carbon materials from different precursors have been widely used as anode materials owing to their compatible storage effectiveness of both larger radii sodium and potassium ions. However, the differential bonding behaviors of Na and K ions with porous carbon-based anode are the significant one worth investigating, which could provide a clean picture of alkali ions storage mechanism. Therefore, in this work, we prepare a porous carbon network derived from sawdust(SDC) wastes, to further analyze the differences on sodium and potassium ions storage behaviors in terms of bond-forming process. It is found that, as-prepared SDC anodes could deliver stable sodium and potassium storage capacities, however, there are notable distinctions in terms of electrochemical behaviors and diffusion processes. By virtue of ex-situ XRD and Raman spectroscopy, the phase transition reaction of potassium ions could be well-observed, and the results shows that the multiple intercalated compounds was formed in SDC network during ions insertion, further resulting in slower diffusion kinetics and larger resistance compared to non-bonded process of sodium ions storage. This study provides more insights into the differences between sodium and potassium ions storage, as well as the energy storage mechanism of porous carbon as anodes for secondary batteries.
基金supported by the National Basic Research Program of China (No. 2012CB619101)
文摘In this work, porous Ti6Al4V alloys with 30%-70% porosity for biomedical applications were fabricated by diffusion bonding of alloy meshes. Pore structure was characterized by Micro-CT and SEM. Compressive behavior in the out-of-plane direction and biocompatibility with cortical bone were studied. The results reveal that the fabricated porous Ti6Al4V alloys possess anisotropic structure with square pores in the in-plane direction and elongated pores in the out-of-plane direction. The average pore size of porous Ti6Al4V alloys with 30%-70% porosity is in the range of 240-360 Bin. By tailoring diffusion bonding temperature, aspect ratio of alloy meshes and porosity, porous Ti6Al4V alloys with different compressive properties can be obtained, for instance, Young＇s modulus and yield stress in the ranges of 4-40 GPa and 70-500 MPa, respectively. Yield stress of porous Ti6Al4V alloys fabricated by diffusion bonding is close to that of alloys fabricated by rapid prototyping, hut higher than that of fabricated by powder sintering and space-holder method. Diffusion bonding temperature has some effects on the yield stress of porous Ti6Al4V alloys, but has a minor effect on the Young＇s modulus. The relationship between compressive properties and relative density conforms well to the Gibson-Ashby model. The Young＇s modulus is linear with the aspect ratio, while the yield stress is linear with the square of aspect ratio of alloy meshes. Porous Ti6Al4V alloys with 60%-70% porosity have potential for cortical bone implant applications.
基金supported by the National Natural Science Foundation of China(Grants 41572310,41272351,and 41227901)the Strategic Priority Research Program of the Chinese Academy of Sciences(Grants XDB10030301 and XDB10030304)
文摘The mechanical behavior of inherently anisotropic shale rocks under Brazilian test conditions are investigated in this study based on experimental studies and numerical simulations. The effects of the weak lamination planes and interlayer bonding force of these layers on the failure strength and fracture patterns are studied systematically. Numerical simulations using particle flow code in two dimensions based on the discrete element method showed a good agreement with the experimental results in the failure strength and fracture patterns. The shale revealed strong anisotropic behavior with the failure strength perpendicular to the lamination plane greater than failure strength parallel to lamination plane. The failure strength of the different interlayer bonding force against the layer orientations changed significantly. Four types of fracture patterns were observed: curved fracture, broken-linear fracture, layeractivated fracture, and central-linear fracture. The observed fracture patterns are either or a combination of tensile and/or shear fractures. Increase in interlayer bonding strength decreased the quantity of micro cracks and this directly led to reduction in the anisotropic behavior. Overall the layer orientation and interlayer bonding force of the shale thus play a very important role in the anisotropic behavior of the shale.
文摘Repair and reinformcement of aged civil steel structures is one of the important issues for maintaining and using them for a long term. For repair and reinforcement of deteriorated civil steel structures due to fatigue and corrosion, patch plate reinforcement is widely applied. Bolting is generally used because of easy quality control and many construction achievements. However, bolting has downsides including holes made and weight increase. Welding is considered to overcome these demerits but in reality the application of welding is unsatisfactory due to the possibility of fatigue crack occurring from the welded part. In this study, a patch plate strengthening system of welded joint assisted with bonding has been proposed. The compressive behaviors of weld-bond jointed specimen were investigated by a series of experiments and FE analysis. It was confirmed that use of welding and bonding was effective to enhance compressive strength of specimen, due to better load-carrying capacity of patch plate compared with sole use of welding.
基金the National Natural Science Foundation of China(Nos.51063004,21264012)China National Funds for Distinguished Young Scientists(No.50925313)
文摘In the present work, the blend of poly（butylene succinate） （PBS） and bisphenol A （BPA） was prepared by solution mixing, and the intermolecular interactions between the two components were characterized by a combination of nuclear magnetic resonance （NMR） and Fourier transform infrared spectroscopy （FTIR）. The results showed that intermolecular hydrogen-bonding forms between the carbonyl group of PBS and phenol hydroxyl of BPA. With the increase of BPA content, more hydrogen bonds were formed. The effect of hydrogen bonding on the crystallization behavior of PBS was investigated by differential scanning calorimetry （DSC） and polarized optical microscopy （POM）. The results showed that the overall isothermal crystallization kinetics and the spherulite growth rate of PBS decrease with the increase of BPA content, while the PBS spherulite size increases with BPA content.
文摘The curing behavior of lignin-based phenol-formaldehyde (LPF) resin with different contents of nano-crystalline cellulose (NCC) was studied by differential scanning calorimetry (DSC) at different heating rates (5, 10 and 20°C/min) and the bonding property was evaluated by the wet shear strength and wood failure of two-ply plywood panels after soaking in water (48 hours at room temperature and followed by 1-hour boiling). The test results indicated that the NCC content had little influence on the peak temperature, activation energy and the total heat of reaction of LPF resin at 5 and 10°C/min. But at 20°C/min, LPF0.00% (LPF resin without NCC) showed the highest total heat of reaction, while LPF0.25% (LPF resin containing 0.25% NCC content) and LPF0.50% (LPF resin containing 0.50% NCC content) gave the lowest value. The wet shear strength was affected by the NCC content to a certain extent. With regard to the results of one-way analysis of variance, the bonding quality could be improved by NCC and the optimum NCC content ranged from 0.25% to 0.50%. The wood failure was also affected by the NCC content, but the trend with respect to NCC content was not clear.
基金supported by the Program for Changjiang Scholars and Innovative Research Team in University(PCSIRT)(IRT0512)the Program for New Century Excellent Talents in University(NCET)+1 种基金the National Natural Science Foundation of China(Nos.50671002and50971013)the National Institute for Materials Science (NIMS) internship program
文摘In the present investigation,Pt/Ru-modified bond coating consisted of 2 μm Pt＋2 μm Ru was deposited on a nickel-based superalloy by electroplating method and followed by conventional Al pack cementation.The cyclic corrosion behavior of Pt/Ru-modified bond coating exposed to NaCl plus water vapor has been investigated under atmospheric pressure at 1050℃.The result shows that the cyclic corrosion life of Pt/Ru-modified bond coating is longer than that of the conventional Pt-modified aluminide coating in the presence of NaCl plus water vapor.The addition of Ru makes the coating possess the increased strength and suppress the rumpling behavior.The absence of rumpling may be responsible for the improved corrosion resistance of Pt/Ru-modified aluminide coating.
文摘The aim of the investigations presented here was to understand how the stiffness of the adhesive affects the failure of ceramic tiles adhered to metallic backings. The working hypothesis was that varying the adhesive stiffness could have the same effect on the ballistic performance as a variation of the adhesive thickness.Two different projectile/target combinations were utilized for ballistic tests in order to generate extremely different loading conditions. With targets consisting of 6 mm aluminum oxide ceramic and 6 mm aluminum backing, complete penetration occurred in each test with 7.62 mm tungsten carbide core AP ammunition at an impact velocity of 940 m/s. In contrast, with ceramic tiles of 20 mm thickness on 13 mm steel backing,no penetration of the ceramic occurred at the impact of a 7.62 mm ball round at 840 m/s.Four different types of adhesive(high-strength till high-flexible) were tested in both configurations. The elongation of the adhesive layer, the deformation of the metallic backing and the failure of the ceramics were observed by means of a high-speed camera during the projectile/target interaction.The results of the ballistic tests showed that a higher fracture strain caused a larger deformation of the backing compared to adhesives, which exhibit a high tensile strength and low fracture strains.The experimental results indicate that the damage behavior of the ceramic/metal composites depends on the absolute elongation of the adhesive layer. This can be controlled either by the thickness or the stiffness of the bonding layer.
基金Supported by the National Natural Science Foundation of China(No.21607051)
文摘A new Co（Ⅱ） coordination polymer, [Co（1,4-chdc）（L）（H2O）]n（1）, was synthesized under hydrothermal condition（1,4-H2chdc = 1,4-cyclohexanedicarboxylic acid, L = 2-（4-fluoro-phenyl）-1 H-imidazo[4,5-f][1,10]phenanthroline）. Its crystal structure was determined by single-crystal X-ray diffraction. 1 crystallizes in triclinic, space group P1 with a = 8.790（5）, b = 10.486（5）, c = 13.305（5） ?, α = 87.391（5）, β = 82.925（5）, γ = 81.841（5）o, V = 1204.2（10） ?3, Z = 2, C27H23FN4O5Co, Mr = 561.42, Dc = 1.548 g/cm3, F（000） = 578, μ（Mo Ka） = 0.769 mm-1, R = 0.0415 and wR = 0.1043. In 1, each 1,4-chdc anion bridges two neighboring Co（Ⅱ） atoms to give a chain structure. The L ligands are attached on one side of the chain through chelating the Co（Ⅱ） atoms, and are stacked with those of an adjacent chain through π-π interactions, yielding a double-chain structure. The double-chain structures are linked into a supramolecular layer structure through N–H···O hydrogen-bonding interactions between the adjacent double-chain structures. Moreover, the thermal behavior of 1 was also studied.
文摘The fracture behavior of polymer-bonded explosive(PBX) seriously affects the safety and reliability of weapon system.The effects of interface debonding and initial meso-damage on the fracture behavior of PBX under quasi-static tension are studied using numerical method.A twodimensional representative volume element(RVE) is established based on Voronoi model in which the component contents could be regulated and the particles are randomly distributed.A nonlinear damage model of polymer matrix relative to matrix depth between particles is constructed.The results show that the simulated strain-stress relation is coincident with experiment data.It is found that interface debonding leads to the nucleation and propagation of meso-cracks,and a main crack approximately perpendicular to the loading direction is generated finally.The interface debonding tends to occur in the interface perpendicular to the loading direction.There seems to be a phenomenon that strain softening and hardening alternatively appear around peak stress of stress and strain curve.It is shown that the initial damages of intragranular and interfacial cracks both decrease the modulus and failure stress,and the main crack tends to propagate toward the initial meso-cracks.
文摘Because frit bonding material is brittle, sudden impacts such as dropping may damage the bonding significantly. Strain-rate-controlled in-situ nano-indentation testing, which can determine localized material properties, was carried out on the frit-bonded specimen, especially on the frit bonding matrix and the filler. The results were compared with the drop-impact fracture behavior to understand the fracture characteristics. Mechanical properties at static condition or low strain rate did not show proper relationship with the fracture tendency of the drop tested result of the frit bonding. From the relationship between fracture toughness and the ratio of modulus/hardness, fracture characteristics at the drop impact situation could be estimated by the values at the high strain rate nano-indentation. The ratio between modulus and hardness on frit matrix showed close relationship with drop impact fracture. Though crack propagation path deflected at filler interface, filler property gave less influence on fracture tendency of drop impact fracture due to its small volume fraction. The properties of frit matrix were crucial to the fracture characteristics of the frit bonding.
基金supported by The Fundamental Research Funds for the Central Universities(No.FRF-TD-12-001)Constructed Project for the Key Laboratory of Beijing(No.FRF-SD-B-378 005B)+1 种基金the Specialized Research Fund for the Doctoral Program of Higher Education(No.20120006110019)the Opening Research Fund of State Key Laboratory for Advanced Metals and Materials(No.2012Z-13)
文摘The microstructure, interface thickness, element distribution and interfacial mechanical behavior of Ti-6Al-4V/Al couples prepared by an insert moulding method were investigated in depth in this paper. Moreover, Ti/Al bonding was also given as a comparison for understanding the interface bonding mechanism. It is shown that there is much thinner compact sub-layer for the interface of the Ti-6Al-4V/Al joint, whose morphology is obviously different from that of the Ti/Al joint. The Ti-6Al-4V/Al interface has been proven to contain a slight content of vanadium. Moreover, both the shear strength and the interface reaction rate of Ti-6Al-4V/Al compound materials are lower than those of the Ti/Al ones.
基金supported by the National Natural Science Foundation of China (No. 50074014)the Science Foundation of Hubei Province,China (No. 2003ABA092)
文摘Bonded NdFeB magnets were prepared by compression molding. The effect of preparation technology on their magnetic and mechanical properties was studied through the analysis of density, Br, Hcj, （BH）max, bending strength, and compressive strength of the bonded magnets. The results showed that the magnetic properties decreased with increasing binder content, whereas the mechanical properties increased. Br and （BH）max increased with rising pressure, whereas Hcj decreased. For a fixed mass fraction of the binder, the optimal pressure was 620 MPa and the best thermosetting temperature was 160°C. These conditions made the bonded magnets have the optimal mechanical properties. Scanning electron microscopy （SEM） analyses of the fracture surfaces indicated that the epoxy resin bonded magnets exhibited brittle behavior.
基金①The project supported in part by the National Natural Science Foundation of Chinathe Science Foundation of Chinese Nuclear Industry
文摘We use the bond percolation model to study the multifragrnentation of<sup>197</sup>Au projectiles interact-ing with Cu target at a bombarding energy of 600 MeV/u.The charge observables and some of their dif-ferential distributions are analyzed.The theoretical results agree well with the experimental data ofALADIN collaboration.This indicates that the percolation model can describe reasonably the universal be-havior of nuclear fragmentation in nucleus-nucleus collisions.
