From different reports, it （AZO） and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide （IZO） thin film...From different reports, it （AZO） and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide （IZO） thin films with their optical, luminescence and surface properties establish an assessment to carry out further information to summarize AZO and IZO impact of the layer number.展开更多
Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,viole...Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,violet LEDs are proposed as an alternative solution.Currently,phosphors that can be efficiently excited by violet light(with wavelengths from 400 to 420 nm)remain under development still.In this study,we utilize large language models to construct a comprehensive database of Eu^(2+)and Ce^(3+)doped phosphors for discovering novel violet-excited phosphors.A total of 822 phosphor data entries,including elemental compositions,crystal structures and excitation/emission wavelengths,have been extracted and validated from 9551 research papers.Compared with Ce^(3+)doped phosphors,the Eu^(2+)are in general more suited for violet-excited phosphors,as well as red-emitting phosphors.In particular,Eu^(2+)doped nitrides and sulfides are worth of exploration for violet-excited phosphors.This database is expected to be useful in the future development of phosphors for pc-WLEDs based on artificial intelligence methods.The datasets in this article are listed in Science Data Bank at http://doi.org/10.57760/sciencedb.34314.展开更多
In this study,sawdust served as a carbon source and urea as a nitrogen source to synthesize carbonsupported,nitrogen-doped TiO_(2)composites via a one-pot solvothermal method.The composites were characterized using FT...In this study,sawdust served as a carbon source and urea as a nitrogen source to synthesize carbonsupported,nitrogen-doped TiO_(2)composites via a one-pot solvothermal method.The composites were characterized using FTIR,powder X-ray diffraction,X-ray photoelectron spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,thermogravimetry-derivative thermogravimetry,scanning electron microscopy-energy dispersive spectroscopy,and transmission electron microscopy.Results indicated that all synthesized composites exhibit the anatase phase,with those calcined at 800℃ demonstrating enhanced crystallinity.Nitrogen is incorporated into the TiO_(2)lattice,while carbon is predominantly located on the surface.Photodegradation experiments showed that 20 mg of composite N-TiO_(2)/C-800 achieved degradation rates of 93.4% for methylene blue(20 mg·L^(-1),50 mL)and 99.4% for oxytetracycline(20 mg·L^(-1),50 mL)within 30 min.Free radical capture experiments indicated that h+was the primary active species in the photocatalytic degradation process.展开更多
Violet phosphorus,a recently explored layered elemental semiconductor,has attracted much attention due to its unique photoelectric,mechanical properties,and high hole mobility.Herein,violet arsenic phosphorus has for ...Violet phosphorus,a recently explored layered elemental semiconductor,has attracted much attention due to its unique photoelectric,mechanical properties,and high hole mobility.Herein,violet arsenic phosphorus has for the first time been synthesized by a molten lead method.The crystal structure of violet arsenic phosphorus(P^(83.4)As_(0.6),CSD-2408761)was determined by single crystal X-ray diffraction to have similar structure as that of violet phosphorus,where P12 is occupied by arsenic/phosphorus(As/P)atoms as mixed occupancy sites As1/P12.The arsenic substitution has been demonstrated to tune the band structure of violet phosphorus,switching p-type of violet phosphorus to high-performance n-type violet arsenic phosphorus.The effective electron mass along the<010>direction is significantly reduced from 1.792 to 0.515 m_(0)by arsenic substitution,resulting in an extremely high electron mobility of 2622.503 cm^(2)V^(-1)s^(-1).The field effect transistor built with P_(83.4)As_(0.6)nanosheets was measured to have a high electron mobility(137.06 cm^(2)V^(-1)s^(-1),61.2 nm),even under ambient conditions for 5 h,much higher than the hole mobility of violet phosphorene nanosheets(4.07 cm^(2)V^(-1)s^(-1),73.3 nm).This work provides a new idea for designing phosphorus-based materials for field effect transistors,giving significant potential in complementary metal-oxide-semiconductor applications.展开更多
A machine learning-based APP may quickly and non-destructively evaluate the quality of parameters,such as hardness and anthocyanin content in blue honeysuckle berries(Lonicera caerulea L.,BHB),based on changes in peri...A machine learning-based APP may quickly and non-destructively evaluate the quality of parameters,such as hardness and anthocyanin content in blue honeysuckle berries(Lonicera caerulea L.,BHB),based on changes in pericarp color characteristics.The color feature information of the BHB pericarp was extracted,and the corresponding hardness and anthocyanin content were determined at various growing stages.Correlation analysis of BHB quality indexes was conducted by single and combined components of BHB epidermal color features.The results showed that fruit hardness had a significantly negative correlation with color feature parameter R-G,and its anthocyanin content had a significantly positive correlation with color feature parameter R.Comparing the eight models,random forest(RF)was established to evaluate the hardness and anthocyanin content of BHB according to the correlation between pericarp color features and hardness and anthocyanin content on BHB quality evaluation APP on the WeChat platform.The credibility of APP embedding RF model for evaluating hardness and anthocyanin content in BHB was validated with the determination coefficient of 0.89 and 0.93 in practice.This approach could efficiently and conveniently evaluate the quality indexes of BHB in real time and serve as a technical reference for the detection of quality indicators of other berries using smartphones.展开更多
In this study,Palm kernel shell(PKS)is utilized as a raw material to produce activated biochar as adsorbent for dye removal from wastewater,specifically methylene blue(MB)dye,by utilizing a simplified and costeffectiv...In this study,Palm kernel shell(PKS)is utilized as a raw material to produce activated biochar as adsorbent for dye removal from wastewater,specifically methylene blue(MB)dye,by utilizing a simplified and costeffective approach.Production of activated biocharwas carried out using both a furnace and a domesticmicrowave oven without an inert atmosphere.Three samples of palm kernel shell(PKS)based activated biochar labeled as samples A,B and C were carbonized inside the furnace at 800℃ for 1 h and then activated using the microwave-heating technique with varying heating times(0,5,10,and 15 min).The heating was conducted in the absence of an inert gas.Fourier Transform Infrared Spectroscopy(FTIR)highlighted a significant Si-O stretching vibration between 1040.5 to 692.7 cm−1,indicating the presence of key components(Silica and Alumina)in all PKS-based activated biochar samples.For wastewater treatment,activated biochar samples were tested against a 20 mg/LMethylene Blue(MB)solution,and the MB percentage removal was calculated for each run using a standard curve.Central Composite Design(CCD)experiments were conducted for optimization,with activated biochar Sample C exhibiting the highest adsorption capacity at 88.14%MB removal under specific conditions.ANOVA analysis confirmed the significance of the quadratic model,with a p-value of 0.0222 and R^(2)=0.9438.In conclusion,the results demonstrated the efficiency of PKS-based activated biochar as an adsorbent for MB removal in comparison to other commercial adsorbents.展开更多
Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,th...Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,the underlying causes of the instability of monoclinic K^(+) -containing MnFePBA(KMnFePBA)cathodes in aqueous electrolytes were investigated.To prevent irreversible phase transitions,a lowconcentration,flame-retardant organic electrolyte operable under open-air conditions was developed.Utilizing triethyl phosphate(TEP)as the electrolyte solvent,the KMnFePBA cathode exhibited two distinct redox peaks at approximately 1.83 and 1.70 V,coupled with a high reversible capacity of -130 m A h g^(-1).The TEP electrolyte offers not only flame-retardant and anti-drying properties but also benefits from the inclusion of trace amounts of water,which enhances the redox kinetics.The optimized electrolyte enables Zn||KMnFePBA batteries to operate reversibly without structural degradation,function effectively across a wide temperature range,and suppress Zn dendrite formation by modulating the zinc-ion solvation structure and interfacial environment.This study presents a practical electrolyte engineering strategy for stabilizing monoclinic MnFePBA cathodes while simultaneously extending the lifespan of Zn anodes in ZIBs.展开更多
Hybrid local and charge-transfer(HLCT)states offer an effective pathway for developing efficient blue organic light-emitting diodes(OLEDs).In HLCT emitters,locally excited(LE)states enhance radiative transitions and p...Hybrid local and charge-transfer(HLCT)states offer an effective pathway for developing efficient blue organic light-emitting diodes(OLEDs).In HLCT emitters,locally excited(LE)states enhance radiative transitions and photoluminescence quantum yield,while charge-transfer(CT)states facilitate exciton harvesting via reverse intersystem crossing.Here,we propose an HLCT-oriented molecular design strategy to achieve efficient blue emission.Pyrene-imidazole(PyI)was employed as a weak donor and linked to benzoxazole(BO)acceptors through para-and meta-benzene π-bridges,affording two D-π-A molecules,p-PyI-PBO and m-PyI-PBO.The π-bridges strengthen conjugation and stabilize the HLCT state,while the para-to-meta linkage transforms a linear"I-shaped"geometry into a twisted"V-shaped"configuration,shortening conjugation and modulating donoracceptor coupling.This structural regulation produces a more balanced LE/CT distribution,suppressing excessive LE character while retaining sufficient CT contribution for efficient exciton utilization.As a result,m-PyI-PBO exhibits more favorable excited-state properties and delivers efficient blue emission with high color purity.Benefiting from its balanced HLCT characteristics and robust photophysical and thermal stability,the nondoped OLED based on m-PyI-PBO shows bright blue emission with CIE coordinates of(0.15,0.13),a maximum external quantum efficiency(EQE_(max))of 9.52%,and a low roll-off of 3.36%at 1000 cd^(-2).The doped device further emits deep blue with CIE coordinates of(0.16,0.06),close to the European Broadcasting Union standard,and achieves an EQE_(max)of 13.22%with an exciton utilization efficiency of 79.72%.This work demonstrates thatπ-bridge engineering combined with meta-linkage is an effective strategy for constructing efficient HLCT-type blue emitters.展开更多
Although manganese Prussian blue analogues(Mn-PBAs)offer advantages as cost-effective,high-energy-density cathode materials for sodium-ion batteries,their practical application is severely constrained by substantial c...Although manganese Prussian blue analogues(Mn-PBAs)offer advantages as cost-effective,high-energy-density cathode materials for sodium-ion batteries,their practical application is severely constrained by substantial capacity degradation during long-term cycling.This performance deterioration is closely associated with the structural instability of the material during the cycling process,which is mainly attributed to the gradual dissolution of the active material into the electrolyte and severe lattice distortion during Na+intercalation/deintercalation.Fortunately,the aforementioned challenges can be effectively addressed by fabricating an in situ engineered nickel cage(ISE-NC)on Mn-PBAs(denoted as Mn-PBAs-NC).Experimental characterization combined with theoretical calculations reveals that this spontaneously formed nickel cage not only suppresses the diffusion of Mn-PBAs into the electrolyte but also acts as a structural stabilizer,significantly alleviating lattice distortion during cycling.This dual stabilization mechanism ensures remarkable cycling stability,with Mn-PBAs-NC delivering a retained capacity of 96.4 mA h g^(−1)(80%capacity retention)over 2,300 cycles at 2 C,elevating the cycle life of Mn-PBAs to unprecedented levels.展开更多
Ischemic stroke represents a significant global health challenge,frequently associated with intricate pathophysiological alterations.During ischemic stroke,the generation of reactive oxygen species markedly increases,...Ischemic stroke represents a significant global health challenge,frequently associated with intricate pathophysiological alterations.During ischemic stroke,the generation of reactive oxygen species markedly increases,leading to direct neuronal damage as well as initiating a cascade of inflammatory responses.This oxidative stress can also disturb the equilibrium of the gut microbiota,resulting in dysbiosis.In turn,an imbalance in gut microbiota can further exacerbate the production of reactive oxygen species and contribute to a pro-inflammatory environment within the body.This creates a vicious cycle that not only promotes the progression of stroke but also leads to adverse functional outcomes.The neuroinflammation and intestinal microbiota dysbiosis that occur following ischemic stroke are critical contributors to stroke progression and adverse functional outcomes.We previously developed manganese-iron Prussian blue nanozymes,characterized by a multi-enzyme structure and a porous design,that exhibit strong antioxidant properties.However,the therapeutic effects of manganese-iron Prussian blue nanozymes on ischemic stroke and their mechanisms of action remain have not been fully elucidated.To investigate this,we constructed a mouse model of middle cerebral artery occlusion and administered manganese-iron Prussian blue nanozymes via gastric gavage.Our results demonstrated that these nanozymes substantially reduced infarct volume,improved neurological function,restored gut microbiota balance,and increased levels of short-chain fatty acids in the mouse model.Treatment of lipopolysaccharide-treated BV-2 cells with short-chain fatty acids markedly decreased the expression levels of components of the Toll-like receptor 4/nuclear factor kappa B signaling pathway,including Toll-like receptor 4,inhibitor of nuclear factor kappa-B kinase subunit alpha,and pp65.These findings suggest that manganese-iron Prussian blue nanozymes can correct gut microbiota dysbiosis and increase short-chain fatty acid production by modulating the Toll-like receptor 4/nuclear factor kappa B signaling pathway,thereby providing therapeutic benefits in the context of ischemic stroke.展开更多
GaN-based continuous-wave operated blue-violet laser diodes(LDs) with long lifetime are demonstrated, which are grown on a c-plane GaN substrate by metal organic chemical vapor deposition with a 10 × 600 μm^2 ri...GaN-based continuous-wave operated blue-violet laser diodes(LDs) with long lifetime are demonstrated, which are grown on a c-plane GaN substrate by metal organic chemical vapor deposition with a 10 × 600 μm^2 ridge waveguide structure.The electrical and optical characteristics of a blue-violet LD are investigated under direct-current injection at room temperature(25 °C). The stimulated emission wavelength and peak optical power of the LD are around 413 nm and over 600 mW, respectively.In addition, the threshold current density and voltage are as small as 1.46 kA/cm^2 and 4.1 V, respectively. Moreover, the lifetime is longer than 1000 hours under room-temperature continuous-wave operation.展开更多
Blue-violet light can not only enhance the total content of biomass and glucoside but also enrich the taste of the fruit.Thus,it is meaningful to study the blue-violet luminescent materials for plant cultivation.In th...Blue-violet light can not only enhance the total content of biomass and glucoside but also enrich the taste of the fruit.Thus,it is meaningful to study the blue-violet luminescent materials for plant cultivation.In this study,titanium(IV)-activated CaYAlO4(CYAO) phosphors were synthesized by conventional hightemperature solid-state reaction.X-ray powder diffraction was employed to analyze the crystalstructure of CYAO.It is found that the doped Ti^4+ ions do not change obviously the crystal structure of phosphors.Upon 246 nm excitation,CaYAl1-xO4:xTi^4+phosphors exhibit broad blue-violet emission band peaking at 395 nm,which can be attributed to the charge transfer of Ti^4+-O^2-.Moreover,this phosphor exhibits strong thermal stability.The luminescence emission intensity at 150℃maintained about 91 mol% of its initial value at room temperature.Additionally,the electron transition process and concentration quenching mechanism of CaYAl1-xO4:xTi^4+are discussed in detail.The excellent luminescent properties indicate that CaYAl1-xO4:xTi^4+phosphor may have promising application in indoor plant cultivation.展开更多
英国作家立德夫人的民族志作品The Land of the Blue Gown有多个汉语无本回译译本。本文选取其中三个代表性译本,尝试从民族志翻译理论出发,通过对不同译本的语言风格传达和文化信息还原进行比较,总结各无本回译译本的翻译策略选择以及...英国作家立德夫人的民族志作品The Land of the Blue Gown有多个汉语无本回译译本。本文选取其中三个代表性译本,尝试从民族志翻译理论出发,通过对不同译本的语言风格传达和文化信息还原进行比较,总结各无本回译译本的翻译策略选择以及译者在各自翻译过程中扮演的不同角色,为民族志翻译相关研究作学理探讨。展开更多
Using cesium lead halide perovskite nanocrystals, CsPb(Cl/Br)3, as a light absorber, we report a highly effective UV and blue light blocking film. The CsPb(Cl/Br)3 nanocrystals are well dispersed in the ethyl cellulos...Using cesium lead halide perovskite nanocrystals, CsPb(Cl/Br)3, as a light absorber, we report a highly effective UV and blue light blocking film. The CsPb(Cl/Br)3 nanocrystals are well dispersed in the ethyl cellulose(EC) matrix to compose a UV and blue light shielding film, and the absorption edge of the film is tunable by adjusting Cl to Br ratio using anion exchange. The CsPbCl2 Br-EC film exhibits a transmittance of 5% at 459 nm, 90% at 478 nm and 95% in the range of 500–800 nm, which makes it excellent for UV and blue light shielding. In addition, the as-prepared EC-CsPb(Cl/Br)3 film shows excellent photostability under UV irradiation. Results demonstrate that this EC-CsPb(Cl/Br)3 based materials with sharp absorbance edges, tunable blocking wavelength, and high photostability can be useful for the applications in UV and blue light blocking and optical filters.展开更多
Three types of blue-violet light-emitting devices based on an excito n- confined structure have been prepared, in which different materials were used as emitting layers and hole-transporting layers. They had structur...Three types of blue-violet light-emitting devices based on an excito n- confined structure have been prepared, in which different materials were used as emitting layers and hole-transporting layers. They had structures of ITO/CuPc/ NPB/CPB/TPBi/Alq 3/LiF/Al(D NC), ITO/CuPc/J03/CBP/TPBi/Alq 3/LiF/Al(D JC) and ITO /CuPc/J03/FNPD/TPBi/Alq 3/LiF/Al(D JF). Here copper phthaloc yan ine (CuPc) acted as hole-injecting layer(HIL), N,N-bis-(1-naphthyl)-N,N-di phenyl-1.1bipheny1-4-4-diamine(NPB) and J03 hole-transporting layers (HTLs) , 4,4'-dicarbazolyl-1,1'-biphenyl (CBP) and FNPD as emitting layers(EMLs), N, arylbenzimidazoles (TPBi) as hole-blocking layer(HBL), and tris(8-quinolinolat o) aluminium complex(Alq 3) as electron-transporting layer(ETL). TPBi applied her e is a good confinement to both charges and excitons, which make the devices emit blue-violet light or iginating from the emitter, CBP and FNPD. Their characteristics have also been i nvestigated. The result shows that the device D NC based on NPB/CBP has the best performance among the three devices. The excellence of D NC is attrib uted to the better hole-transporting ability of NPB as compared with J03, and t he better emitting ability of CBP as compared with FNPD, although the best match ing of energy levels is found in the hole-transporting layer and emitting layer of the device D JF.展开更多
Removal of Methylene Blue (MB) and Crystal Violet (CV) dyes from monocomponent and binary aqueous solutions by water hyacinth-E. Crassipes roots fixed on alginate (a low-cost adsorbent) has been investigated. The exte...Removal of Methylene Blue (MB) and Crystal Violet (CV) dyes from monocomponent and binary aqueous solutions by water hyacinth-E. Crassipes roots fixed on alginate (a low-cost adsorbent) has been investigated. The extent of adsorption was evaluated as a function of solution pH, initial dye concentration, and bead biomass loading. Kinetic sorption data were analysed by widely used models: pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion models. The results showed that pseudo-second-order model better described the biosorption experimental data than the pseudo-first-order kinetic model for both dyes, whilst the Elovich model fitted the biosorption experimental data at lower dye concentrations. The intraparticle diffusion model indicated that sorption of CV and MB was characterized by rapid surface adsorption coupled with slow film diffusion process at higher initial dye concentration and at all initial bead biomass loading. The range of mean free energy values confirmed physical adsorption as the mechanism for dye removal from solution.展开更多
Dyed poly(vinyl alcohol) (PVA) films, prepared by a simple technique of casting aqueous solutions of PVA containing a mixture of Ethyl violet and bromophenol blue (EV-BPB) on a horizontal glass plate, are useful as ro...Dyed poly(vinyl alcohol) (PVA) films, prepared by a simple technique of casting aqueous solutions of PVA containing a mixture of Ethyl violet and bromophenol blue (EV-BPB) on a horizontal glass plate, are useful as routine high-dose dosimeter in the 1 - 30 kGy range. The color of films changes from violet to yellow when exposed to gamma radiation. The response of this dosimeter depends up on the concentration of chloral hydrate (CH) in the polymer material. The radiation chemical yield (G-value) of PVA dyed film was calculated and found to increase by increasing concentration of chloral hydrate. Post-irradiation storage on the response of the films are discussed. The overall combined uncertainty (at 2σ) associated with measurement of response (ΔA mm-1) at 600 nm for dose range 1 - 15 kGy is 5.6%.展开更多
Using the Cerenkov second harmonic generation, 478 nm blue and 402nm violet light are generated by direct frequency doubling of 956 and 804 nm diode lasers in a same proton exchanged MgO:LiNbO3 waveguide. Under the lo...Using the Cerenkov second harmonic generation, 478 nm blue and 402nm violet light are generated by direct frequency doubling of 956 and 804 nm diode lasers in a same proton exchanged MgO:LiNbO3 waveguide. Under the low fundamental guide wave power of less than 1mW, the estimated value of the output blue and violet light power is in the order of 0.1-0.01μW.展开更多
This article presented a facile fabrication process for polydimethylsiloxane(PDMS)composite gold nanotris⁃octahedra(Au NTOH)for a flexible SERS sensor with high sensitivity.Specifically,Au NTOH with excellent SERS beh...This article presented a facile fabrication process for polydimethylsiloxane(PDMS)composite gold nanotris⁃octahedra(Au NTOH)for a flexible SERS sensor with high sensitivity.Specifically,Au NTOH with excellent SERS behaviors was synthesized using a seed-mediated growth method and the dimensions of the Au NTOH was easily tuned.In addition,the influence of size on the SERS performance of their monolayers was systematically investigated,and the Au NTOH with the size of 61 nm possessed the best SERS performance.Importantly,a hydrophilic-substrateassisted interfacial self-assembled monolayer transfer technique was proposed to transfer Au NTOH onto PDMS films,resulting in forming flexible and transparent Au NTOH@PDMS substrates.Furthermore,the excellent signal homoge⁃neity of this substrate was demonstrated and the sensitivity was verified by a measurement of crystal violet(CV)as low as 1×10^(-8) mol/L.As a result,this SERS sensor is progressing for applying in the identification of trace contaminants in broad fields.展开更多
With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Elec...With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Electrochemical energy storage,as the most popular and promising energy storage method,has received extensive attention.Currently,the most widely used energy storage method is metal-ion secondary batteries,whose performance mainly depends on the cathode material.Prussian blue analogues(PBAs)have a unique open framework structures that allow quick and reversible insertion/extraction of metal ions such as Na^(+),K^(+),Zn^(2+),Li^(+)etc.,thus attracting widespread attention.The advantages of simple synthesis process,abundant resources,and low cost also distinguish it from its counterparts.Unfortunately,the crystal water and structural defects in the PBAs lattice that is generated during the synthesis process,as well as the low Na content,significantly affect their electrochemical performance.This paper focuses on PBAs’synthesis methods,crystal structure,modification strategies,and their potential applications as cathode materials for various metal ion secondary batteries and looks forward to their future development direction.展开更多
文摘From different reports, it （AZO） and indium-doped including usage areas. We nanocrystalline films with is realized that there is a need to consider all sides of aluminum-doped zinc oxide zinc oxide （IZO） thin films with their optical, luminescence and surface properties establish an assessment to carry out further information to summarize AZO and IZO impact of the layer number.
基金National Key Research and Development Program of China(2021YFB3500501)。
文摘Commercial phosphor-converted white LEDs(pc-WLEDs)face two inherent limitations,namely blue light hazard and low color rendering index,due to the use of blue LEDs as excitation source.To address these challenges,violet LEDs are proposed as an alternative solution.Currently,phosphors that can be efficiently excited by violet light(with wavelengths from 400 to 420 nm)remain under development still.In this study,we utilize large language models to construct a comprehensive database of Eu^(2+)and Ce^(3+)doped phosphors for discovering novel violet-excited phosphors.A total of 822 phosphor data entries,including elemental compositions,crystal structures and excitation/emission wavelengths,have been extracted and validated from 9551 research papers.Compared with Ce^(3+)doped phosphors,the Eu^(2+)are in general more suited for violet-excited phosphors,as well as red-emitting phosphors.In particular,Eu^(2+)doped nitrides and sulfides are worth of exploration for violet-excited phosphors.This database is expected to be useful in the future development of phosphors for pc-WLEDs based on artificial intelligence methods.The datasets in this article are listed in Science Data Bank at http://doi.org/10.57760/sciencedb.34314.
文摘In this study,sawdust served as a carbon source and urea as a nitrogen source to synthesize carbonsupported,nitrogen-doped TiO_(2)composites via a one-pot solvothermal method.The composites were characterized using FTIR,powder X-ray diffraction,X-ray photoelectron spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,thermogravimetry-derivative thermogravimetry,scanning electron microscopy-energy dispersive spectroscopy,and transmission electron microscopy.Results indicated that all synthesized composites exhibit the anatase phase,with those calcined at 800℃ demonstrating enhanced crystallinity.Nitrogen is incorporated into the TiO_(2)lattice,while carbon is predominantly located on the surface.Photodegradation experiments showed that 20 mg of composite N-TiO_(2)/C-800 achieved degradation rates of 93.4% for methylene blue(20 mg·L^(-1),50 mL)and 99.4% for oxytetracycline(20 mg·L^(-1),50 mL)within 30 min.Free radical capture experiments indicated that h+was the primary active species in the photocatalytic degradation process.
基金supported by the National Natural Science Foundation of China(Grant No.22175136)the State Key Laboratory of Electrical Insulation and Power Equipment(Grant No.EIPE23127)the Fundamental Research Funds for the Central Universities(xtr052024009,xtr052025002).
文摘Violet phosphorus,a recently explored layered elemental semiconductor,has attracted much attention due to its unique photoelectric,mechanical properties,and high hole mobility.Herein,violet arsenic phosphorus has for the first time been synthesized by a molten lead method.The crystal structure of violet arsenic phosphorus(P^(83.4)As_(0.6),CSD-2408761)was determined by single crystal X-ray diffraction to have similar structure as that of violet phosphorus,where P12 is occupied by arsenic/phosphorus(As/P)atoms as mixed occupancy sites As1/P12.The arsenic substitution has been demonstrated to tune the band structure of violet phosphorus,switching p-type of violet phosphorus to high-performance n-type violet arsenic phosphorus.The effective electron mass along the<010>direction is significantly reduced from 1.792 to 0.515 m_(0)by arsenic substitution,resulting in an extremely high electron mobility of 2622.503 cm^(2)V^(-1)s^(-1).The field effect transistor built with P_(83.4)As_(0.6)nanosheets was measured to have a high electron mobility(137.06 cm^(2)V^(-1)s^(-1),61.2 nm),even under ambient conditions for 5 h,much higher than the hole mobility of violet phosphorene nanosheets(4.07 cm^(2)V^(-1)s^(-1),73.3 nm).This work provides a new idea for designing phosphorus-based materials for field effect transistors,giving significant potential in complementary metal-oxide-semiconductor applications.
基金Supported by the National Natural Science Foundation of China(32072352)the National Key Research and Development Program Project of China(2022YFD1600500)。
文摘A machine learning-based APP may quickly and non-destructively evaluate the quality of parameters,such as hardness and anthocyanin content in blue honeysuckle berries(Lonicera caerulea L.,BHB),based on changes in pericarp color characteristics.The color feature information of the BHB pericarp was extracted,and the corresponding hardness and anthocyanin content were determined at various growing stages.Correlation analysis of BHB quality indexes was conducted by single and combined components of BHB epidermal color features.The results showed that fruit hardness had a significantly negative correlation with color feature parameter R-G,and its anthocyanin content had a significantly positive correlation with color feature parameter R.Comparing the eight models,random forest(RF)was established to evaluate the hardness and anthocyanin content of BHB according to the correlation between pericarp color features and hardness and anthocyanin content on BHB quality evaluation APP on the WeChat platform.The credibility of APP embedding RF model for evaluating hardness and anthocyanin content in BHB was validated with the determination coefficient of 0.89 and 0.93 in practice.This approach could efficiently and conveniently evaluate the quality indexes of BHB in real time and serve as a technical reference for the detection of quality indicators of other berries using smartphones.
文摘In this study,Palm kernel shell(PKS)is utilized as a raw material to produce activated biochar as adsorbent for dye removal from wastewater,specifically methylene blue(MB)dye,by utilizing a simplified and costeffective approach.Production of activated biocharwas carried out using both a furnace and a domesticmicrowave oven without an inert atmosphere.Three samples of palm kernel shell(PKS)based activated biochar labeled as samples A,B and C were carbonized inside the furnace at 800℃ for 1 h and then activated using the microwave-heating technique with varying heating times(0,5,10,and 15 min).The heating was conducted in the absence of an inert gas.Fourier Transform Infrared Spectroscopy(FTIR)highlighted a significant Si-O stretching vibration between 1040.5 to 692.7 cm−1,indicating the presence of key components(Silica and Alumina)in all PKS-based activated biochar samples.For wastewater treatment,activated biochar samples were tested against a 20 mg/LMethylene Blue(MB)solution,and the MB percentage removal was calculated for each run using a standard curve.Central Composite Design(CCD)experiments were conducted for optimization,with activated biochar Sample C exhibiting the highest adsorption capacity at 88.14%MB removal under specific conditions.ANOVA analysis confirmed the significance of the quadratic model,with a p-value of 0.0222 and R^(2)=0.9438.In conclusion,the results demonstrated the efficiency of PKS-based activated biochar as an adsorbent for MB removal in comparison to other commercial adsorbents.
基金supported by the National Natural Science Foundation of China(22409002,62371003)the Open Research Fund of Songshan Lake Materials Laboratory(2023SLABFN18)+1 种基金Anhui Provincial Natural Science Foundation(2308085QB46)Scientific Research Foundation of Education Department of Anhui Province of China(2023AH051109,2022AH010025)。
文摘Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,the underlying causes of the instability of monoclinic K^(+) -containing MnFePBA(KMnFePBA)cathodes in aqueous electrolytes were investigated.To prevent irreversible phase transitions,a lowconcentration,flame-retardant organic electrolyte operable under open-air conditions was developed.Utilizing triethyl phosphate(TEP)as the electrolyte solvent,the KMnFePBA cathode exhibited two distinct redox peaks at approximately 1.83 and 1.70 V,coupled with a high reversible capacity of -130 m A h g^(-1).The TEP electrolyte offers not only flame-retardant and anti-drying properties but also benefits from the inclusion of trace amounts of water,which enhances the redox kinetics.The optimized electrolyte enables Zn||KMnFePBA batteries to operate reversibly without structural degradation,function effectively across a wide temperature range,and suppress Zn dendrite formation by modulating the zinc-ion solvation structure and interfacial environment.This study presents a practical electrolyte engineering strategy for stabilizing monoclinic MnFePBA cathodes while simultaneously extending the lifespan of Zn anodes in ZIBs.
基金supported by the Natural Science Foundation of Hei-longjiang Province(No.YQ2023B001)the"Academic Backbone"Project of Northeast Agricultural University(No.20xG19).
文摘Hybrid local and charge-transfer(HLCT)states offer an effective pathway for developing efficient blue organic light-emitting diodes(OLEDs).In HLCT emitters,locally excited(LE)states enhance radiative transitions and photoluminescence quantum yield,while charge-transfer(CT)states facilitate exciton harvesting via reverse intersystem crossing.Here,we propose an HLCT-oriented molecular design strategy to achieve efficient blue emission.Pyrene-imidazole(PyI)was employed as a weak donor and linked to benzoxazole(BO)acceptors through para-and meta-benzene π-bridges,affording two D-π-A molecules,p-PyI-PBO and m-PyI-PBO.The π-bridges strengthen conjugation and stabilize the HLCT state,while the para-to-meta linkage transforms a linear"I-shaped"geometry into a twisted"V-shaped"configuration,shortening conjugation and modulating donoracceptor coupling.This structural regulation produces a more balanced LE/CT distribution,suppressing excessive LE character while retaining sufficient CT contribution for efficient exciton utilization.As a result,m-PyI-PBO exhibits more favorable excited-state properties and delivers efficient blue emission with high color purity.Benefiting from its balanced HLCT characteristics and robust photophysical and thermal stability,the nondoped OLED based on m-PyI-PBO shows bright blue emission with CIE coordinates of(0.15,0.13),a maximum external quantum efficiency(EQE_(max))of 9.52%,and a low roll-off of 3.36%at 1000 cd^(-2).The doped device further emits deep blue with CIE coordinates of(0.16,0.06),close to the European Broadcasting Union standard,and achieves an EQE_(max)of 13.22%with an exciton utilization efficiency of 79.72%.This work demonstrates thatπ-bridge engineering combined with meta-linkage is an effective strategy for constructing efficient HLCT-type blue emitters.
基金financially supported by the Ten-thousand Talents Programthe K. C. Wong Pioneer Talent Program+3 种基金China Three Gorges Corporation (WWKY-2021–0027)Inner Mongolia Science and Technology Plan (2021ZD0033)the National Natural Science Foundation of China (52202121)funded by China Petroleum&Chemical Corporation (123091)
文摘Although manganese Prussian blue analogues(Mn-PBAs)offer advantages as cost-effective,high-energy-density cathode materials for sodium-ion batteries,their practical application is severely constrained by substantial capacity degradation during long-term cycling.This performance deterioration is closely associated with the structural instability of the material during the cycling process,which is mainly attributed to the gradual dissolution of the active material into the electrolyte and severe lattice distortion during Na+intercalation/deintercalation.Fortunately,the aforementioned challenges can be effectively addressed by fabricating an in situ engineered nickel cage(ISE-NC)on Mn-PBAs(denoted as Mn-PBAs-NC).Experimental characterization combined with theoretical calculations reveals that this spontaneously formed nickel cage not only suppresses the diffusion of Mn-PBAs into the electrolyte but also acts as a structural stabilizer,significantly alleviating lattice distortion during cycling.This dual stabilization mechanism ensures remarkable cycling stability,with Mn-PBAs-NC delivering a retained capacity of 96.4 mA h g^(−1)(80%capacity retention)over 2,300 cycles at 2 C,elevating the cycle life of Mn-PBAs to unprecedented levels.
基金supported by the Natural Science Foundation of Anhui Province of China,No.2208085Y32Scientific Research Plan Project of Anhui Province of China,No.2022AH020076the Chen Xiao-Ping Foundation for the Development of Science and Technology of Hubei Province,No.CXPJJH12000005-07-115(all to CT).
文摘Ischemic stroke represents a significant global health challenge,frequently associated with intricate pathophysiological alterations.During ischemic stroke,the generation of reactive oxygen species markedly increases,leading to direct neuronal damage as well as initiating a cascade of inflammatory responses.This oxidative stress can also disturb the equilibrium of the gut microbiota,resulting in dysbiosis.In turn,an imbalance in gut microbiota can further exacerbate the production of reactive oxygen species and contribute to a pro-inflammatory environment within the body.This creates a vicious cycle that not only promotes the progression of stroke but also leads to adverse functional outcomes.The neuroinflammation and intestinal microbiota dysbiosis that occur following ischemic stroke are critical contributors to stroke progression and adverse functional outcomes.We previously developed manganese-iron Prussian blue nanozymes,characterized by a multi-enzyme structure and a porous design,that exhibit strong antioxidant properties.However,the therapeutic effects of manganese-iron Prussian blue nanozymes on ischemic stroke and their mechanisms of action remain have not been fully elucidated.To investigate this,we constructed a mouse model of middle cerebral artery occlusion and administered manganese-iron Prussian blue nanozymes via gastric gavage.Our results demonstrated that these nanozymes substantially reduced infarct volume,improved neurological function,restored gut microbiota balance,and increased levels of short-chain fatty acids in the mouse model.Treatment of lipopolysaccharide-treated BV-2 cells with short-chain fatty acids markedly decreased the expression levels of components of the Toll-like receptor 4/nuclear factor kappa B signaling pathway,including Toll-like receptor 4,inhibitor of nuclear factor kappa-B kinase subunit alpha,and pp65.These findings suggest that manganese-iron Prussian blue nanozymes can correct gut microbiota dysbiosis and increase short-chain fatty acid production by modulating the Toll-like receptor 4/nuclear factor kappa B signaling pathway,thereby providing therapeutic benefits in the context of ischemic stroke.
基金supported by the National Key R&D Program of China (Nos. 2016YFB0401801, 2016YFB0400803)the Science Challenge Project (No. TZ2016003)+1 种基金the National Natural Science Foundation of China (Nos. 61674138, 61674139, 61604145, 61574135, 61574134, 61474142, 61474110)the Beijing Municipal Science and Technology Project (No. Z161100002116037)
文摘GaN-based continuous-wave operated blue-violet laser diodes(LDs) with long lifetime are demonstrated, which are grown on a c-plane GaN substrate by metal organic chemical vapor deposition with a 10 × 600 μm^2 ridge waveguide structure.The electrical and optical characteristics of a blue-violet LD are investigated under direct-current injection at room temperature(25 °C). The stimulated emission wavelength and peak optical power of the LD are around 413 nm and over 600 mW, respectively.In addition, the threshold current density and voltage are as small as 1.46 kA/cm^2 and 4.1 V, respectively. Moreover, the lifetime is longer than 1000 hours under room-temperature continuous-wave operation.
基金supported by the National Natural Science Foundation of China(21706060,51703061)Natural Science Foundation of Hunan Province(2017JJ3103)+1 种基金Youth Project of Hunan Education Department(17B1118)Hunan Provincial Engineering Technology Research Center for Optical Agriculture(2018TP2003).
文摘Blue-violet light can not only enhance the total content of biomass and glucoside but also enrich the taste of the fruit.Thus,it is meaningful to study the blue-violet luminescent materials for plant cultivation.In this study,titanium(IV)-activated CaYAlO4(CYAO) phosphors were synthesized by conventional hightemperature solid-state reaction.X-ray powder diffraction was employed to analyze the crystalstructure of CYAO.It is found that the doped Ti^4+ ions do not change obviously the crystal structure of phosphors.Upon 246 nm excitation,CaYAl1-xO4:xTi^4+phosphors exhibit broad blue-violet emission band peaking at 395 nm,which can be attributed to the charge transfer of Ti^4+-O^2-.Moreover,this phosphor exhibits strong thermal stability.The luminescence emission intensity at 150℃maintained about 91 mol% of its initial value at room temperature.Additionally,the electron transition process and concentration quenching mechanism of CaYAl1-xO4:xTi^4+are discussed in detail.The excellent luminescent properties indicate that CaYAl1-xO4:xTi^4+phosphor may have promising application in indoor plant cultivation.
文摘英国作家立德夫人的民族志作品The Land of the Blue Gown有多个汉语无本回译译本。本文选取其中三个代表性译本,尝试从民族志翻译理论出发,通过对不同译本的语言风格传达和文化信息还原进行比较,总结各无本回译译本的翻译策略选择以及译者在各自翻译过程中扮演的不同角色,为民族志翻译相关研究作学理探讨。
基金financially supported by the National Nature Scientific Foundation of China(No.21675133)and OESACLS201902
文摘Using cesium lead halide perovskite nanocrystals, CsPb(Cl/Br)3, as a light absorber, we report a highly effective UV and blue light blocking film. The CsPb(Cl/Br)3 nanocrystals are well dispersed in the ethyl cellulose(EC) matrix to compose a UV and blue light shielding film, and the absorption edge of the film is tunable by adjusting Cl to Br ratio using anion exchange. The CsPbCl2 Br-EC film exhibits a transmittance of 5% at 459 nm, 90% at 478 nm and 95% in the range of 500–800 nm, which makes it excellent for UV and blue light shielding. In addition, the as-prepared EC-CsPb(Cl/Br)3 film shows excellent photostability under UV irradiation. Results demonstrate that this EC-CsPb(Cl/Br)3 based materials with sharp absorbance edges, tunable blocking wavelength, and high photostability can be useful for the applications in UV and blue light blocking and optical filters.
基金Project supported by the National Natural Science Foundation of China ( Grant Nos. 60077020 90201034) and the Foundation of National High Technology Research and Development Program (Grant No.2001AA313070)
文摘Three types of blue-violet light-emitting devices based on an excito n- confined structure have been prepared, in which different materials were used as emitting layers and hole-transporting layers. They had structures of ITO/CuPc/ NPB/CPB/TPBi/Alq 3/LiF/Al(D NC), ITO/CuPc/J03/CBP/TPBi/Alq 3/LiF/Al(D JC) and ITO /CuPc/J03/FNPD/TPBi/Alq 3/LiF/Al(D JF). Here copper phthaloc yan ine (CuPc) acted as hole-injecting layer(HIL), N,N-bis-(1-naphthyl)-N,N-di phenyl-1.1bipheny1-4-4-diamine(NPB) and J03 hole-transporting layers (HTLs) , 4,4'-dicarbazolyl-1,1'-biphenyl (CBP) and FNPD as emitting layers(EMLs), N, arylbenzimidazoles (TPBi) as hole-blocking layer(HBL), and tris(8-quinolinolat o) aluminium complex(Alq 3) as electron-transporting layer(ETL). TPBi applied her e is a good confinement to both charges and excitons, which make the devices emit blue-violet light or iginating from the emitter, CBP and FNPD. Their characteristics have also been i nvestigated. The result shows that the device D NC based on NPB/CBP has the best performance among the three devices. The excellence of D NC is attrib uted to the better hole-transporting ability of NPB as compared with J03, and t he better emitting ability of CBP as compared with FNPD, although the best match ing of energy levels is found in the hole-transporting layer and emitting layer of the device D JF.
文摘Removal of Methylene Blue (MB) and Crystal Violet (CV) dyes from monocomponent and binary aqueous solutions by water hyacinth-E. Crassipes roots fixed on alginate (a low-cost adsorbent) has been investigated. The extent of adsorption was evaluated as a function of solution pH, initial dye concentration, and bead biomass loading. Kinetic sorption data were analysed by widely used models: pseudo-first-order, pseudo-second-order, Elovich, and intraparticle diffusion models. The results showed that pseudo-second-order model better described the biosorption experimental data than the pseudo-first-order kinetic model for both dyes, whilst the Elovich model fitted the biosorption experimental data at lower dye concentrations. The intraparticle diffusion model indicated that sorption of CV and MB was characterized by rapid surface adsorption coupled with slow film diffusion process at higher initial dye concentration and at all initial bead biomass loading. The range of mean free energy values confirmed physical adsorption as the mechanism for dye removal from solution.
文摘Dyed poly(vinyl alcohol) (PVA) films, prepared by a simple technique of casting aqueous solutions of PVA containing a mixture of Ethyl violet and bromophenol blue (EV-BPB) on a horizontal glass plate, are useful as routine high-dose dosimeter in the 1 - 30 kGy range. The color of films changes from violet to yellow when exposed to gamma radiation. The response of this dosimeter depends up on the concentration of chloral hydrate (CH) in the polymer material. The radiation chemical yield (G-value) of PVA dyed film was calculated and found to increase by increasing concentration of chloral hydrate. Post-irradiation storage on the response of the films are discussed. The overall combined uncertainty (at 2σ) associated with measurement of response (ΔA mm-1) at 600 nm for dose range 1 - 15 kGy is 5.6%.
文摘Using the Cerenkov second harmonic generation, 478 nm blue and 402nm violet light are generated by direct frequency doubling of 956 and 804 nm diode lasers in a same proton exchanged MgO:LiNbO3 waveguide. Under the low fundamental guide wave power of less than 1mW, the estimated value of the output blue and violet light power is in the order of 0.1-0.01μW.
基金The National Natural Science Foundation of China(12274055)the Fundamental Research Funds for the Central Universities(04442024072)the Training Program of Innovation and Entrepreneurship for Undergraduates in Dalian Minzu University(202312026063)。
文摘This article presented a facile fabrication process for polydimethylsiloxane(PDMS)composite gold nanotris⁃octahedra(Au NTOH)for a flexible SERS sensor with high sensitivity.Specifically,Au NTOH with excellent SERS behaviors was synthesized using a seed-mediated growth method and the dimensions of the Au NTOH was easily tuned.In addition,the influence of size on the SERS performance of their monolayers was systematically investigated,and the Au NTOH with the size of 61 nm possessed the best SERS performance.Importantly,a hydrophilic-substrateassisted interfacial self-assembled monolayer transfer technique was proposed to transfer Au NTOH onto PDMS films,resulting in forming flexible and transparent Au NTOH@PDMS substrates.Furthermore,the excellent signal homoge⁃neity of this substrate was demonstrated and the sensitivity was verified by a measurement of crystal violet(CV)as low as 1×10^(-8) mol/L.As a result,this SERS sensor is progressing for applying in the identification of trace contaminants in broad fields.
基金supported by the National Natural Science Foundation of China(No.52072217)the National Key Research and Development Program of China(No.2022YFB3807700)+2 种基金the Joint Funds of the Hubei Natural Science Foundation Innovation and Development(No.2022CFD034)Hubei Natural Science Foundation Innovation Group Project(No.2022CFA020)the Major Technological Innovation Project of Hubei Science and Technology Department(No.2019AAA164).
文摘With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Electrochemical energy storage,as the most popular and promising energy storage method,has received extensive attention.Currently,the most widely used energy storage method is metal-ion secondary batteries,whose performance mainly depends on the cathode material.Prussian blue analogues(PBAs)have a unique open framework structures that allow quick and reversible insertion/extraction of metal ions such as Na^(+),K^(+),Zn^(2+),Li^(+)etc.,thus attracting widespread attention.The advantages of simple synthesis process,abundant resources,and low cost also distinguish it from its counterparts.Unfortunately,the crystal water and structural defects in the PBAs lattice that is generated during the synthesis process,as well as the low Na content,significantly affect their electrochemical performance.This paper focuses on PBAs’synthesis methods,crystal structure,modification strategies,and their potential applications as cathode materials for various metal ion secondary batteries and looks forward to their future development direction.
