In this study,sawdust served as a carbon source and urea as a nitrogen source to synthesize carbonsupported,nitrogen-doped TiO_(2)composites via a one-pot solvothermal method.The composites were characterized using FT...In this study,sawdust served as a carbon source and urea as a nitrogen source to synthesize carbonsupported,nitrogen-doped TiO_(2)composites via a one-pot solvothermal method.The composites were characterized using FTIR,powder X-ray diffraction,X-ray photoelectron spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,thermogravimetry-derivative thermogravimetry,scanning electron microscopy-energy dispersive spectroscopy,and transmission electron microscopy.Results indicated that all synthesized composites exhibit the anatase phase,with those calcined at 800℃ demonstrating enhanced crystallinity.Nitrogen is incorporated into the TiO_(2)lattice,while carbon is predominantly located on the surface.Photodegradation experiments showed that 20 mg of composite N-TiO_(2)/C-800 achieved degradation rates of 93.4% for methylene blue(20 mg·L^(-1),50 mL)and 99.4% for oxytetracycline(20 mg·L^(-1),50 mL)within 30 min.Free radical capture experiments indicated that h+was the primary active species in the photocatalytic degradation process.展开更多
A machine learning-based APP may quickly and non-destructively evaluate the quality of parameters,such as hardness and anthocyanin content in blue honeysuckle berries(Lonicera caerulea L.,BHB),based on changes in peri...A machine learning-based APP may quickly and non-destructively evaluate the quality of parameters,such as hardness and anthocyanin content in blue honeysuckle berries(Lonicera caerulea L.,BHB),based on changes in pericarp color characteristics.The color feature information of the BHB pericarp was extracted,and the corresponding hardness and anthocyanin content were determined at various growing stages.Correlation analysis of BHB quality indexes was conducted by single and combined components of BHB epidermal color features.The results showed that fruit hardness had a significantly negative correlation with color feature parameter R-G,and its anthocyanin content had a significantly positive correlation with color feature parameter R.Comparing the eight models,random forest(RF)was established to evaluate the hardness and anthocyanin content of BHB according to the correlation between pericarp color features and hardness and anthocyanin content on BHB quality evaluation APP on the WeChat platform.The credibility of APP embedding RF model for evaluating hardness and anthocyanin content in BHB was validated with the determination coefficient of 0.89 and 0.93 in practice.This approach could efficiently and conveniently evaluate the quality indexes of BHB in real time and serve as a technical reference for the detection of quality indicators of other berries using smartphones.展开更多
In this study,Palm kernel shell(PKS)is utilized as a raw material to produce activated biochar as adsorbent for dye removal from wastewater,specifically methylene blue(MB)dye,by utilizing a simplified and costeffectiv...In this study,Palm kernel shell(PKS)is utilized as a raw material to produce activated biochar as adsorbent for dye removal from wastewater,specifically methylene blue(MB)dye,by utilizing a simplified and costeffective approach.Production of activated biocharwas carried out using both a furnace and a domesticmicrowave oven without an inert atmosphere.Three samples of palm kernel shell(PKS)based activated biochar labeled as samples A,B and C were carbonized inside the furnace at 800℃ for 1 h and then activated using the microwave-heating technique with varying heating times(0,5,10,and 15 min).The heating was conducted in the absence of an inert gas.Fourier Transform Infrared Spectroscopy(FTIR)highlighted a significant Si-O stretching vibration between 1040.5 to 692.7 cm−1,indicating the presence of key components(Silica and Alumina)in all PKS-based activated biochar samples.For wastewater treatment,activated biochar samples were tested against a 20 mg/LMethylene Blue(MB)solution,and the MB percentage removal was calculated for each run using a standard curve.Central Composite Design(CCD)experiments were conducted for optimization,with activated biochar Sample C exhibiting the highest adsorption capacity at 88.14%MB removal under specific conditions.ANOVA analysis confirmed the significance of the quadratic model,with a p-value of 0.0222 and R^(2)=0.9438.In conclusion,the results demonstrated the efficiency of PKS-based activated biochar as an adsorbent for MB removal in comparison to other commercial adsorbents.展开更多
Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,th...Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,the underlying causes of the instability of monoclinic K^(+) -containing MnFePBA(KMnFePBA)cathodes in aqueous electrolytes were investigated.To prevent irreversible phase transitions,a lowconcentration,flame-retardant organic electrolyte operable under open-air conditions was developed.Utilizing triethyl phosphate(TEP)as the electrolyte solvent,the KMnFePBA cathode exhibited two distinct redox peaks at approximately 1.83 and 1.70 V,coupled with a high reversible capacity of -130 m A h g^(-1).The TEP electrolyte offers not only flame-retardant and anti-drying properties but also benefits from the inclusion of trace amounts of water,which enhances the redox kinetics.The optimized electrolyte enables Zn||KMnFePBA batteries to operate reversibly without structural degradation,function effectively across a wide temperature range,and suppress Zn dendrite formation by modulating the zinc-ion solvation structure and interfacial environment.This study presents a practical electrolyte engineering strategy for stabilizing monoclinic MnFePBA cathodes while simultaneously extending the lifespan of Zn anodes in ZIBs.展开更多
Hybrid local and charge-transfer(HLCT)states offer an effective pathway for developing efficient blue organic light-emitting diodes(OLEDs).In HLCT emitters,locally excited(LE)states enhance radiative transitions and p...Hybrid local and charge-transfer(HLCT)states offer an effective pathway for developing efficient blue organic light-emitting diodes(OLEDs).In HLCT emitters,locally excited(LE)states enhance radiative transitions and photoluminescence quantum yield,while charge-transfer(CT)states facilitate exciton harvesting via reverse intersystem crossing.Here,we propose an HLCT-oriented molecular design strategy to achieve efficient blue emission.Pyrene-imidazole(PyI)was employed as a weak donor and linked to benzoxazole(BO)acceptors through para-and meta-benzene π-bridges,affording two D-π-A molecules,p-PyI-PBO and m-PyI-PBO.The π-bridges strengthen conjugation and stabilize the HLCT state,while the para-to-meta linkage transforms a linear"I-shaped"geometry into a twisted"V-shaped"configuration,shortening conjugation and modulating donoracceptor coupling.This structural regulation produces a more balanced LE/CT distribution,suppressing excessive LE character while retaining sufficient CT contribution for efficient exciton utilization.As a result,m-PyI-PBO exhibits more favorable excited-state properties and delivers efficient blue emission with high color purity.Benefiting from its balanced HLCT characteristics and robust photophysical and thermal stability,the nondoped OLED based on m-PyI-PBO shows bright blue emission with CIE coordinates of(0.15,0.13),a maximum external quantum efficiency(EQE_(max))of 9.52%,and a low roll-off of 3.36%at 1000 cd^(-2).The doped device further emits deep blue with CIE coordinates of(0.16,0.06),close to the European Broadcasting Union standard,and achieves an EQE_(max)of 13.22%with an exciton utilization efficiency of 79.72%.This work demonstrates thatπ-bridge engineering combined with meta-linkage is an effective strategy for constructing efficient HLCT-type blue emitters.展开更多
Although manganese Prussian blue analogues(Mn-PBAs)offer advantages as cost-effective,high-energy-density cathode materials for sodium-ion batteries,their practical application is severely constrained by substantial c...Although manganese Prussian blue analogues(Mn-PBAs)offer advantages as cost-effective,high-energy-density cathode materials for sodium-ion batteries,their practical application is severely constrained by substantial capacity degradation during long-term cycling.This performance deterioration is closely associated with the structural instability of the material during the cycling process,which is mainly attributed to the gradual dissolution of the active material into the electrolyte and severe lattice distortion during Na+intercalation/deintercalation.Fortunately,the aforementioned challenges can be effectively addressed by fabricating an in situ engineered nickel cage(ISE-NC)on Mn-PBAs(denoted as Mn-PBAs-NC).Experimental characterization combined with theoretical calculations reveals that this spontaneously formed nickel cage not only suppresses the diffusion of Mn-PBAs into the electrolyte but also acts as a structural stabilizer,significantly alleviating lattice distortion during cycling.This dual stabilization mechanism ensures remarkable cycling stability,with Mn-PBAs-NC delivering a retained capacity of 96.4 mA h g^(−1)(80%capacity retention)over 2,300 cycles at 2 C,elevating the cycle life of Mn-PBAs to unprecedented levels.展开更多
Ischemic stroke represents a significant global health challenge,frequently associated with intricate pathophysiological alterations.During ischemic stroke,the generation of reactive oxygen species markedly increases,...Ischemic stroke represents a significant global health challenge,frequently associated with intricate pathophysiological alterations.During ischemic stroke,the generation of reactive oxygen species markedly increases,leading to direct neuronal damage as well as initiating a cascade of inflammatory responses.This oxidative stress can also disturb the equilibrium of the gut microbiota,resulting in dysbiosis.In turn,an imbalance in gut microbiota can further exacerbate the production of reactive oxygen species and contribute to a pro-inflammatory environment within the body.This creates a vicious cycle that not only promotes the progression of stroke but also leads to adverse functional outcomes.The neuroinflammation and intestinal microbiota dysbiosis that occur following ischemic stroke are critical contributors to stroke progression and adverse functional outcomes.We previously developed manganese-iron Prussian blue nanozymes,characterized by a multi-enzyme structure and a porous design,that exhibit strong antioxidant properties.However,the therapeutic effects of manganese-iron Prussian blue nanozymes on ischemic stroke and their mechanisms of action remain have not been fully elucidated.To investigate this,we constructed a mouse model of middle cerebral artery occlusion and administered manganese-iron Prussian blue nanozymes via gastric gavage.Our results demonstrated that these nanozymes substantially reduced infarct volume,improved neurological function,restored gut microbiota balance,and increased levels of short-chain fatty acids in the mouse model.Treatment of lipopolysaccharide-treated BV-2 cells with short-chain fatty acids markedly decreased the expression levels of components of the Toll-like receptor 4/nuclear factor kappa B signaling pathway,including Toll-like receptor 4,inhibitor of nuclear factor kappa-B kinase subunit alpha,and pp65.These findings suggest that manganese-iron Prussian blue nanozymes can correct gut microbiota dysbiosis and increase short-chain fatty acid production by modulating the Toll-like receptor 4/nuclear factor kappa B signaling pathway,thereby providing therapeutic benefits in the context of ischemic stroke.展开更多
英国作家立德夫人的民族志作品The Land of the Blue Gown有多个汉语无本回译译本。本文选取其中三个代表性译本,尝试从民族志翻译理论出发,通过对不同译本的语言风格传达和文化信息还原进行比较,总结各无本回译译本的翻译策略选择以及...英国作家立德夫人的民族志作品The Land of the Blue Gown有多个汉语无本回译译本。本文选取其中三个代表性译本,尝试从民族志翻译理论出发,通过对不同译本的语言风格传达和文化信息还原进行比较,总结各无本回译译本的翻译策略选择以及译者在各自翻译过程中扮演的不同角色,为民族志翻译相关研究作学理探讨。展开更多
In the heart of southern China,Nanning is set to host the 22nd China-ASEAN Expo(CAEXPO)from September 17 to 21,again turning the city into a global hub for trade,innovation,and economic cooperation.This year marks the...In the heart of southern China,Nanning is set to host the 22nd China-ASEAN Expo(CAEXPO)from September 17 to 21,again turning the city into a global hub for trade,innovation,and economic cooperation.This year marks the beginning of a new chapter in regional collaboration with the debut of the Blue Economy Pavilion—an exhibition space dedicated to the fast-growing and increasingly crucial marine economy.展开更多
Prussian blue/Prussian blue analogues(PB/PBAs)are widely used in electrochemistry and materials science fields,such as electrochemical energy storage,catalysis,water purification,and electromagnetic wave absorption,ow...Prussian blue/Prussian blue analogues(PB/PBAs)are widely used in electrochemistry and materials science fields,such as electrochemical energy storage,catalysis,water purification,and electromagnetic wave absorption,owing to their 3D open-framework structure,tunable composition,and large specific surface area.However,the co-precipitation method,which is most suitable for large-scale production of PB/PBAs,often leads to the formation of numerous crystal defects and severe lattice distortion,which significantly affects the structural stability of PB/PBAs.To obtain high-crystallinity PB/PBAs with targeted properties,precise synthesis considering various detailed conditions is especially needed.Herein,this review comprehensively summarizes the fundamental structure composition,key factors in synthesis,and applications in the electrochemistry of PB/PBAs.Unlike previous reports,this review elucidates the relationship between the physicochemical properties of PB/PBAs and their structural composition,with a particular focus on revealing the mechanisms and significance of specific preparation methods during the synthesis process,including reactant concentration,chelating agent,aging,atmosphere,temperature,and drying conditions,for achieving the precise fabrication of PB/PBAs nanomaterials.As PB/PBAs gradually become materials for multidimensional applications,we urge greater attention to the unique properties of PB/PBAs that are sustained by high crystallinity and stable crystal structures.This will effectively ensure the maximization of their advantages in practical applications.展开更多
With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Elec...With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Electrochemical energy storage,as the most popular and promising energy storage method,has received extensive attention.Currently,the most widely used energy storage method is metal-ion secondary batteries,whose performance mainly depends on the cathode material.Prussian blue analogues(PBAs)have a unique open framework structures that allow quick and reversible insertion/extraction of metal ions such as Na^(+),K^(+),Zn^(2+),Li^(+)etc.,thus attracting widespread attention.The advantages of simple synthesis process,abundant resources,and low cost also distinguish it from its counterparts.Unfortunately,the crystal water and structural defects in the PBAs lattice that is generated during the synthesis process,as well as the low Na content,significantly affect their electrochemical performance.This paper focuses on PBAs’synthesis methods,crystal structure,modification strategies,and their potential applications as cathode materials for various metal ion secondary batteries and looks forward to their future development direction.展开更多
Exploring modification methods for enhancing the adsorption performance of biochar-based adsorbents for effective removal of methylene blue(MB),biochar-loaded CeO_(2)nanoparticles(Ce/BC)were synthesized by pomelo peel...Exploring modification methods for enhancing the adsorption performance of biochar-based adsorbents for effective removal of methylene blue(MB),biochar-loaded CeO_(2)nanoparticles(Ce/BC)were synthesized by pomelo peels through co-precipitation combined with the pyrolysis method.Ce/BC showed a higher specific surface area and disorder degree than that of BC.The 0.5Ce/BC(mass ratio of Ce(NO_(3))_(3)·6H_(2)O/BC=0.5/1)showed the best performance to adsorption of MB solution at different reaction conditions(MB concentration,Ce/BC composites dosage,and initial pH).Adsorption kinetics and equilibrium isotherms were well-described with a pseudo-first-order equation and Langmuir model,respectively.In addition,the maximum adsorption capacity of 0.5Ce/BC for MB was 105.68 mg·g^(-1)at 328 K.The strong adsorption was attributed to multi-interactions including pore filling,π-πinteractions,electrostatic interaction,and hydrogen bonding between the composites and MB.This work demonstrated that the modified pomelo peels biochar,as a green promising material with cost-effectiveness,exhibited a great potential for broad application prospectively to dyeing-contaminated wastewater treatment.展开更多
By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimizatio...By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimization of multiple primary reactions for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Many catalysts developed through entropy engineering have been built in nearly equimolar ratios to pursue high entropy,hindering the identification of the active sites and potentially diluting the concentration of real active sites while weakening their electronic interactions with reaction intermediates.Herein,this work proposes an entropy-engineering strategy in metal nanoparticle-embedded nitrogen carbon electrocatalysts,implemented by entropy-engineered Prussian blue analogs(PBA)as precursors to enhance the catalytic activity of primary Cu-Fe active sites.Through the introduction of the micro-strains driven by entropy engineering,density functional theory(DFT)calculations and geometric phase analysis(GPA)using Lorentz electron microscopy further elucidate the optimization of the adsorption/desorption of intermediates.Furthermore,the multi-dimensional morphology and the size diminishment of the nanocrystals serve to expand the electrochemical area,maximizing the catalytic activity for both ORR and OER.Notably,the Zn-air battery assembled with CuFeCoNiZn-NC operated for over 1300 h with negligible decay.This work presents a paradigm for the design of low-cost electrocatalysts with entropy engineering for multi-step reactions.展开更多
The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are...The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays.展开更多
Aqueous zinc-ion batteries(AZIBs)show great potential in the field of electrochemical energy storage with the advantages of high safety,low cost and environmental friendliness.Prussian blue analogues(PBAs)are consider...Aqueous zinc-ion batteries(AZIBs)show great potential in the field of electrochemical energy storage with the advantages of high safety,low cost and environmental friendliness.Prussian blue analogues(PBAs)are considered as the highly promising cathode materials for AZIBs because of their low cost and high voltage potential.Its excellent electrochemical performance and sustainable energy storage capability provide a new direction and opportunity for the development of AZIBs technology.The practical application of PBAs in AZIBs,however,is restrained by its unstable cycle life deriving from PBAs’inherent structure deficiencies and its dissolution in aqueous electrolyte.Based on the summary of series of literature,we will comprehensively introduce the PBAs as cathodes for AZIBs in this review.Firstly,some basic knowledge of PBAs is introduced,including structural characteristics,advantages and issues.Secondly,several commonly used modification methods to improve the properties of PBAs,as well as electrolytes to stabilize PBAs,are presented.Finally,the future research directions and commercial prospects of PBAs in AZIBs are proposed to encourage further exploration and promote technological innovation.展开更多
Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion...Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium storage.With enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal decomposition.This review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these materials.Based on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.展开更多
The objective of this study is to propose an optimal plant design for blue hydrogen production aboard a liquefiednatural gas(LNG)carrier.This investigation focuses on integrating two distinct processes—steam methaner...The objective of this study is to propose an optimal plant design for blue hydrogen production aboard a liquefiednatural gas(LNG)carrier.This investigation focuses on integrating two distinct processes—steam methanereforming(SMR)and ship-based carbon capture(SBCC).The first refers to the common practice used to obtainhydrogen from methane(often derived from natural gas),where steam reacts with methane to produce hydrogenand carbon dioxide(CO_(2)).The second refers to capturing the CO_(2) generated during the SMR process on boardships.By capturing and storing the carbon emissions,the process significantly reduces its environmental impact,making the hydrogen production“blue,”as opposed to“grey”(which involves CO_(2) emissions without capture).For the SMR process,the analysis reveals that increasing the reformer temperature enhances both the processperformance and CO_(2) emissions.Conversely,a higher steam-to-carbon(s/c)ratio reduces hydrogen yield,therebydecreasing thermal efficiency.The study also shows that preheating the air and boil-off gas(BOG)before theyenter the combustion chamber boosts overall efficiency and curtails CO_(2) emissions.In the SBCC process,puremonoethanolamine(MEA)is employed to capture the CO_(2) generated by the exhaust gases from the SMR process.The results indicate that with a 90%CO_(2) capture rate,the associated heat consumption amounts to 4.6 MJ perkilogram of CO_(2) captured.This combined approach offers a viable pathway to produce blue hydrogen on LNGcarriers while significantly reducing the carbon footprint.展开更多
The scientific community has reached firm consensus that humans know less about the ocean than they do about the moon.Even though we have developed submersibles capable of diving to depths of ten thousand meters,our u...The scientific community has reached firm consensus that humans know less about the ocean than they do about the moon.Even though we have developed submersibles capable of diving to depths of ten thousand meters,our understanding of the oceans covering approximately 71 percent of the Earth’s surface remains scarce.A paper published in Science Advances last May noted that only 0.001 percent of the deep seafloor(190 meters or more below Earth’s surface)has been visually observed by scientists,yet this tiny fraction accounts for 95 percent of the total surface area of the oceans around the globe.展开更多
文摘In this study,sawdust served as a carbon source and urea as a nitrogen source to synthesize carbonsupported,nitrogen-doped TiO_(2)composites via a one-pot solvothermal method.The composites were characterized using FTIR,powder X-ray diffraction,X-ray photoelectron spectroscopy,ultraviolet-visible diffuse reflectance spectroscopy,thermogravimetry-derivative thermogravimetry,scanning electron microscopy-energy dispersive spectroscopy,and transmission electron microscopy.Results indicated that all synthesized composites exhibit the anatase phase,with those calcined at 800℃ demonstrating enhanced crystallinity.Nitrogen is incorporated into the TiO_(2)lattice,while carbon is predominantly located on the surface.Photodegradation experiments showed that 20 mg of composite N-TiO_(2)/C-800 achieved degradation rates of 93.4% for methylene blue(20 mg·L^(-1),50 mL)and 99.4% for oxytetracycline(20 mg·L^(-1),50 mL)within 30 min.Free radical capture experiments indicated that h+was the primary active species in the photocatalytic degradation process.
基金Supported by the National Natural Science Foundation of China(32072352)the National Key Research and Development Program Project of China(2022YFD1600500)。
文摘A machine learning-based APP may quickly and non-destructively evaluate the quality of parameters,such as hardness and anthocyanin content in blue honeysuckle berries(Lonicera caerulea L.,BHB),based on changes in pericarp color characteristics.The color feature information of the BHB pericarp was extracted,and the corresponding hardness and anthocyanin content were determined at various growing stages.Correlation analysis of BHB quality indexes was conducted by single and combined components of BHB epidermal color features.The results showed that fruit hardness had a significantly negative correlation with color feature parameter R-G,and its anthocyanin content had a significantly positive correlation with color feature parameter R.Comparing the eight models,random forest(RF)was established to evaluate the hardness and anthocyanin content of BHB according to the correlation between pericarp color features and hardness and anthocyanin content on BHB quality evaluation APP on the WeChat platform.The credibility of APP embedding RF model for evaluating hardness and anthocyanin content in BHB was validated with the determination coefficient of 0.89 and 0.93 in practice.This approach could efficiently and conveniently evaluate the quality indexes of BHB in real time and serve as a technical reference for the detection of quality indicators of other berries using smartphones.
文摘In this study,Palm kernel shell(PKS)is utilized as a raw material to produce activated biochar as adsorbent for dye removal from wastewater,specifically methylene blue(MB)dye,by utilizing a simplified and costeffective approach.Production of activated biocharwas carried out using both a furnace and a domesticmicrowave oven without an inert atmosphere.Three samples of palm kernel shell(PKS)based activated biochar labeled as samples A,B and C were carbonized inside the furnace at 800℃ for 1 h and then activated using the microwave-heating technique with varying heating times(0,5,10,and 15 min).The heating was conducted in the absence of an inert gas.Fourier Transform Infrared Spectroscopy(FTIR)highlighted a significant Si-O stretching vibration between 1040.5 to 692.7 cm−1,indicating the presence of key components(Silica and Alumina)in all PKS-based activated biochar samples.For wastewater treatment,activated biochar samples were tested against a 20 mg/LMethylene Blue(MB)solution,and the MB percentage removal was calculated for each run using a standard curve.Central Composite Design(CCD)experiments were conducted for optimization,with activated biochar Sample C exhibiting the highest adsorption capacity at 88.14%MB removal under specific conditions.ANOVA analysis confirmed the significance of the quadratic model,with a p-value of 0.0222 and R^(2)=0.9438.In conclusion,the results demonstrated the efficiency of PKS-based activated biochar as an adsorbent for MB removal in comparison to other commercial adsorbents.
基金supported by the National Natural Science Foundation of China(22409002,62371003)the Open Research Fund of Songshan Lake Materials Laboratory(2023SLABFN18)+1 种基金Anhui Provincial Natural Science Foundation(2308085QB46)Scientific Research Foundation of Education Department of Anhui Province of China(2023AH051109,2022AH010025)。
文摘Manganese-based Prussian blue analogues(MnFePBAs),renowned for their high redox potential and dual redox-active sites,often fail to fully realize their intrinsic performance in zinc-ion batteries(ZIBs).In this work,the underlying causes of the instability of monoclinic K^(+) -containing MnFePBA(KMnFePBA)cathodes in aqueous electrolytes were investigated.To prevent irreversible phase transitions,a lowconcentration,flame-retardant organic electrolyte operable under open-air conditions was developed.Utilizing triethyl phosphate(TEP)as the electrolyte solvent,the KMnFePBA cathode exhibited two distinct redox peaks at approximately 1.83 and 1.70 V,coupled with a high reversible capacity of -130 m A h g^(-1).The TEP electrolyte offers not only flame-retardant and anti-drying properties but also benefits from the inclusion of trace amounts of water,which enhances the redox kinetics.The optimized electrolyte enables Zn||KMnFePBA batteries to operate reversibly without structural degradation,function effectively across a wide temperature range,and suppress Zn dendrite formation by modulating the zinc-ion solvation structure and interfacial environment.This study presents a practical electrolyte engineering strategy for stabilizing monoclinic MnFePBA cathodes while simultaneously extending the lifespan of Zn anodes in ZIBs.
基金supported by the Natural Science Foundation of Hei-longjiang Province(No.YQ2023B001)the"Academic Backbone"Project of Northeast Agricultural University(No.20xG19).
文摘Hybrid local and charge-transfer(HLCT)states offer an effective pathway for developing efficient blue organic light-emitting diodes(OLEDs).In HLCT emitters,locally excited(LE)states enhance radiative transitions and photoluminescence quantum yield,while charge-transfer(CT)states facilitate exciton harvesting via reverse intersystem crossing.Here,we propose an HLCT-oriented molecular design strategy to achieve efficient blue emission.Pyrene-imidazole(PyI)was employed as a weak donor and linked to benzoxazole(BO)acceptors through para-and meta-benzene π-bridges,affording two D-π-A molecules,p-PyI-PBO and m-PyI-PBO.The π-bridges strengthen conjugation and stabilize the HLCT state,while the para-to-meta linkage transforms a linear"I-shaped"geometry into a twisted"V-shaped"configuration,shortening conjugation and modulating donoracceptor coupling.This structural regulation produces a more balanced LE/CT distribution,suppressing excessive LE character while retaining sufficient CT contribution for efficient exciton utilization.As a result,m-PyI-PBO exhibits more favorable excited-state properties and delivers efficient blue emission with high color purity.Benefiting from its balanced HLCT characteristics and robust photophysical and thermal stability,the nondoped OLED based on m-PyI-PBO shows bright blue emission with CIE coordinates of(0.15,0.13),a maximum external quantum efficiency(EQE_(max))of 9.52%,and a low roll-off of 3.36%at 1000 cd^(-2).The doped device further emits deep blue with CIE coordinates of(0.16,0.06),close to the European Broadcasting Union standard,and achieves an EQE_(max)of 13.22%with an exciton utilization efficiency of 79.72%.This work demonstrates thatπ-bridge engineering combined with meta-linkage is an effective strategy for constructing efficient HLCT-type blue emitters.
基金financially supported by the Ten-thousand Talents Programthe K. C. Wong Pioneer Talent Program+3 种基金China Three Gorges Corporation (WWKY-2021–0027)Inner Mongolia Science and Technology Plan (2021ZD0033)the National Natural Science Foundation of China (52202121)funded by China Petroleum&Chemical Corporation (123091)
文摘Although manganese Prussian blue analogues(Mn-PBAs)offer advantages as cost-effective,high-energy-density cathode materials for sodium-ion batteries,their practical application is severely constrained by substantial capacity degradation during long-term cycling.This performance deterioration is closely associated with the structural instability of the material during the cycling process,which is mainly attributed to the gradual dissolution of the active material into the electrolyte and severe lattice distortion during Na+intercalation/deintercalation.Fortunately,the aforementioned challenges can be effectively addressed by fabricating an in situ engineered nickel cage(ISE-NC)on Mn-PBAs(denoted as Mn-PBAs-NC).Experimental characterization combined with theoretical calculations reveals that this spontaneously formed nickel cage not only suppresses the diffusion of Mn-PBAs into the electrolyte but also acts as a structural stabilizer,significantly alleviating lattice distortion during cycling.This dual stabilization mechanism ensures remarkable cycling stability,with Mn-PBAs-NC delivering a retained capacity of 96.4 mA h g^(−1)(80%capacity retention)over 2,300 cycles at 2 C,elevating the cycle life of Mn-PBAs to unprecedented levels.
基金supported by the Natural Science Foundation of Anhui Province of China,No.2208085Y32Scientific Research Plan Project of Anhui Province of China,No.2022AH020076the Chen Xiao-Ping Foundation for the Development of Science and Technology of Hubei Province,No.CXPJJH12000005-07-115(all to CT).
文摘Ischemic stroke represents a significant global health challenge,frequently associated with intricate pathophysiological alterations.During ischemic stroke,the generation of reactive oxygen species markedly increases,leading to direct neuronal damage as well as initiating a cascade of inflammatory responses.This oxidative stress can also disturb the equilibrium of the gut microbiota,resulting in dysbiosis.In turn,an imbalance in gut microbiota can further exacerbate the production of reactive oxygen species and contribute to a pro-inflammatory environment within the body.This creates a vicious cycle that not only promotes the progression of stroke but also leads to adverse functional outcomes.The neuroinflammation and intestinal microbiota dysbiosis that occur following ischemic stroke are critical contributors to stroke progression and adverse functional outcomes.We previously developed manganese-iron Prussian blue nanozymes,characterized by a multi-enzyme structure and a porous design,that exhibit strong antioxidant properties.However,the therapeutic effects of manganese-iron Prussian blue nanozymes on ischemic stroke and their mechanisms of action remain have not been fully elucidated.To investigate this,we constructed a mouse model of middle cerebral artery occlusion and administered manganese-iron Prussian blue nanozymes via gastric gavage.Our results demonstrated that these nanozymes substantially reduced infarct volume,improved neurological function,restored gut microbiota balance,and increased levels of short-chain fatty acids in the mouse model.Treatment of lipopolysaccharide-treated BV-2 cells with short-chain fatty acids markedly decreased the expression levels of components of the Toll-like receptor 4/nuclear factor kappa B signaling pathway,including Toll-like receptor 4,inhibitor of nuclear factor kappa-B kinase subunit alpha,and pp65.These findings suggest that manganese-iron Prussian blue nanozymes can correct gut microbiota dysbiosis and increase short-chain fatty acid production by modulating the Toll-like receptor 4/nuclear factor kappa B signaling pathway,thereby providing therapeutic benefits in the context of ischemic stroke.
文摘英国作家立德夫人的民族志作品The Land of the Blue Gown有多个汉语无本回译译本。本文选取其中三个代表性译本,尝试从民族志翻译理论出发,通过对不同译本的语言风格传达和文化信息还原进行比较,总结各无本回译译本的翻译策略选择以及译者在各自翻译过程中扮演的不同角色,为民族志翻译相关研究作学理探讨。
文摘In the heart of southern China,Nanning is set to host the 22nd China-ASEAN Expo(CAEXPO)from September 17 to 21,again turning the city into a global hub for trade,innovation,and economic cooperation.This year marks the beginning of a new chapter in regional collaboration with the debut of the Blue Economy Pavilion—an exhibition space dedicated to the fast-growing and increasingly crucial marine economy.
基金financial support from the National Natural Science Foundation of China(NSFC,Grant No.52202253,52372193,and 22293041)Natural Science Foundation of Jiangsu Province(Grant No.BK20220914)Large Instrument and Equipment Sharing Fund of Nanjing University of Aeronautics and Astronautics。
文摘Prussian blue/Prussian blue analogues(PB/PBAs)are widely used in electrochemistry and materials science fields,such as electrochemical energy storage,catalysis,water purification,and electromagnetic wave absorption,owing to their 3D open-framework structure,tunable composition,and large specific surface area.However,the co-precipitation method,which is most suitable for large-scale production of PB/PBAs,often leads to the formation of numerous crystal defects and severe lattice distortion,which significantly affects the structural stability of PB/PBAs.To obtain high-crystallinity PB/PBAs with targeted properties,precise synthesis considering various detailed conditions is especially needed.Herein,this review comprehensively summarizes the fundamental structure composition,key factors in synthesis,and applications in the electrochemistry of PB/PBAs.Unlike previous reports,this review elucidates the relationship between the physicochemical properties of PB/PBAs and their structural composition,with a particular focus on revealing the mechanisms and significance of specific preparation methods during the synthesis process,including reactant concentration,chelating agent,aging,atmosphere,temperature,and drying conditions,for achieving the precise fabrication of PB/PBAs nanomaterials.As PB/PBAs gradually become materials for multidimensional applications,we urge greater attention to the unique properties of PB/PBAs that are sustained by high crystallinity and stable crystal structures.This will effectively ensure the maximization of their advantages in practical applications.
基金supported by the National Natural Science Foundation of China(No.52072217)the National Key Research and Development Program of China(No.2022YFB3807700)+2 种基金the Joint Funds of the Hubei Natural Science Foundation Innovation and Development(No.2022CFD034)Hubei Natural Science Foundation Innovation Group Project(No.2022CFA020)the Major Technological Innovation Project of Hubei Science and Technology Department(No.2019AAA164).
文摘With the rapid development of new energy and the high proportion of new energy connected to the grid,energy storage has become the leading technology driving significant adjustments in the global energy landscape.Electrochemical energy storage,as the most popular and promising energy storage method,has received extensive attention.Currently,the most widely used energy storage method is metal-ion secondary batteries,whose performance mainly depends on the cathode material.Prussian blue analogues(PBAs)have a unique open framework structures that allow quick and reversible insertion/extraction of metal ions such as Na^(+),K^(+),Zn^(2+),Li^(+)etc.,thus attracting widespread attention.The advantages of simple synthesis process,abundant resources,and low cost also distinguish it from its counterparts.Unfortunately,the crystal water and structural defects in the PBAs lattice that is generated during the synthesis process,as well as the low Na content,significantly affect their electrochemical performance.This paper focuses on PBAs’synthesis methods,crystal structure,modification strategies,and their potential applications as cathode materials for various metal ion secondary batteries and looks forward to their future development direction.
基金supported by Basic scientific research business expense project of colleges and universities directly under Inner Mongolia(2024QNJS127 and 2023QNJS131)Science and Technology Plan Program of Inner Mongolia Autonomous Region(2023YFDZ0031)the Inner Mongolia Natural Science Foundation(2024QN02011).
文摘Exploring modification methods for enhancing the adsorption performance of biochar-based adsorbents for effective removal of methylene blue(MB),biochar-loaded CeO_(2)nanoparticles(Ce/BC)were synthesized by pomelo peels through co-precipitation combined with the pyrolysis method.Ce/BC showed a higher specific surface area and disorder degree than that of BC.The 0.5Ce/BC(mass ratio of Ce(NO_(3))_(3)·6H_(2)O/BC=0.5/1)showed the best performance to adsorption of MB solution at different reaction conditions(MB concentration,Ce/BC composites dosage,and initial pH).Adsorption kinetics and equilibrium isotherms were well-described with a pseudo-first-order equation and Langmuir model,respectively.In addition,the maximum adsorption capacity of 0.5Ce/BC for MB was 105.68 mg·g^(-1)at 328 K.The strong adsorption was attributed to multi-interactions including pore filling,π-πinteractions,electrostatic interaction,and hydrogen bonding between the composites and MB.This work demonstrated that the modified pomelo peels biochar,as a green promising material with cost-effectiveness,exhibited a great potential for broad application prospectively to dyeing-contaminated wastewater treatment.
基金supported by the National Natural Science Foundation of China(52071083,52231007,12327804,52471224)Zhuhai Fudan Innovation Institute,and the Science and Technology Commission of Shanghai Municipality(23ZR1405000).
文摘By the random distribution of metals in a single phase,entropy engineering is applied to construct dense neighboring active centers with diverse electronic and geometric structures,realizing the continuous optimization of multiple primary reactions for oxygen reduction reaction(ORR)and oxygen evolution reaction(OER).Many catalysts developed through entropy engineering have been built in nearly equimolar ratios to pursue high entropy,hindering the identification of the active sites and potentially diluting the concentration of real active sites while weakening their electronic interactions with reaction intermediates.Herein,this work proposes an entropy-engineering strategy in metal nanoparticle-embedded nitrogen carbon electrocatalysts,implemented by entropy-engineered Prussian blue analogs(PBA)as precursors to enhance the catalytic activity of primary Cu-Fe active sites.Through the introduction of the micro-strains driven by entropy engineering,density functional theory(DFT)calculations and geometric phase analysis(GPA)using Lorentz electron microscopy further elucidate the optimization of the adsorption/desorption of intermediates.Furthermore,the multi-dimensional morphology and the size diminishment of the nanocrystals serve to expand the electrochemical area,maximizing the catalytic activity for both ORR and OER.Notably,the Zn-air battery assembled with CuFeCoNiZn-NC operated for over 1300 h with negligible decay.This work presents a paradigm for the design of low-cost electrocatalysts with entropy engineering for multi-step reactions.
基金Project supported by the Key R&D Projects in Hunan Province(2021SK2047,2022NK2044)Science and Technology Innovation Program of Hunan Province(2022WZ1022)Superior Youth Project of the Science Research Project of Hunan Provincial Department of Education(22B0211)。
文摘The technology of solid-state lighting has developed for decades in various industries.Phosphor,as an element part,determines the application domain of lighting products.For instance,blue and redemitting phosphors are required in the process of plant supplementing light,arrow-band emitting phosphors are applied to backlight displays,etc.In this work,a Bi^(3+)-activated blue phosphor was obtained in a symmetrical and co mpact crystal structure of Gd3Sb07(GSO).Then,the co-doping strategy of alkali metal ions(Li^(+),Na^(+),and K^(+))was used to optimize the performance.The result shows that the photoluminescence intensity is increased by 2.1 times and 1.3 times respectively by introducing Li~+and K^(+)ions.Not only that,it also achieves narrow-band emitting with the full width of half-maximum(FWHM)reaching 42 nm through Na^(+)doping,and its excitation peak position also shifts from 322 to 375 nm,which can be well excited by near-ultraviolet(NUV)light emitting diode(LED)chips(365 nm).Meanwhile,the electroluminescence spectrum of GSO:0.6 mol%Bi^(3+),3 wt%Na^(+)matches up to 93.39%of the blue part of the absorption spectrum of chlorophyll a.In summary,the Bi^(3+)-activated blue phosphor reported in this work can synchronously meet the requirements of plant light replenishment and field emission displays.
基金financially supported by the National Natural Science Foundation of China(Youth Program,Nos.52204378 and No.22309209)the Natural Science Foundation of Hunan Province in China(No.2023JJ40709).
文摘Aqueous zinc-ion batteries(AZIBs)show great potential in the field of electrochemical energy storage with the advantages of high safety,low cost and environmental friendliness.Prussian blue analogues(PBAs)are considered as the highly promising cathode materials for AZIBs because of their low cost and high voltage potential.Its excellent electrochemical performance and sustainable energy storage capability provide a new direction and opportunity for the development of AZIBs technology.The practical application of PBAs in AZIBs,however,is restrained by its unstable cycle life deriving from PBAs’inherent structure deficiencies and its dissolution in aqueous electrolyte.Based on the summary of series of literature,we will comprehensively introduce the PBAs as cathodes for AZIBs in this review.Firstly,some basic knowledge of PBAs is introduced,including structural characteristics,advantages and issues.Secondly,several commonly used modification methods to improve the properties of PBAs,as well as electrolytes to stabilize PBAs,are presented.Finally,the future research directions and commercial prospects of PBAs in AZIBs are proposed to encourage further exploration and promote technological innovation.
基金financial support from the Special Funds for the Cultivation of Guangdong College Students’Scientific and Technological Innovation(“Climbing Program”Special Funds,pdjh2023b0145)the Scientific Research Innovation Project of Graduate School of South China Normal University(2024KYLX047)financial support from the Australian Research Council,Centre for Materials Science,Queensland University of Technology.
文摘Lithium-ion batteries(LIBs)have dominated the portable electronic and electrochemical energy markets since their commercialisation,whose high cost and lithium scarcity have prompted the development of other alkali-ion batteries(AIBs)including sodium-ion batteries(SIBs)and potassium-ion batteries(PIBs).Owing to larger ion sizes of Na^(+)and K^(+)compared with Li^(+),nanocomposites with excellent crystallinity orientation and well-developed porosity show unprecedented potential for advanced lithium/sodium/potassium storage.With enticing open rigid framework structures,Prussian blue analogues(PBAs)remain promising self-sacrificial templates for the preparation of various nanocomposites,whose appeal originates from the well-retained porous structures and exceptional electrochemical activities after thermal decomposition.This review focuses on the recent progress of PBA-derived nanocomposites from their fabrication,lithium/sodium/potassium storage mechanism,and applications in AIBs(LIBs,SIBs,and PIBs).To distinguish various PBA derivatives,the working mechanism and applications of PBA-templated metal oxides,metal chalcogenides,metal phosphides,and other nanocomposites are systematically evaluated,facilitating the establishment of a structure–activity correlation for these materials.Based on the fruitful achievements of PBA-derived nanocomposites,perspectives for their future development are envisioned,aiming to narrow down the gap between laboratory study and industrial reality.
文摘The objective of this study is to propose an optimal plant design for blue hydrogen production aboard a liquefiednatural gas(LNG)carrier.This investigation focuses on integrating two distinct processes—steam methanereforming(SMR)and ship-based carbon capture(SBCC).The first refers to the common practice used to obtainhydrogen from methane(often derived from natural gas),where steam reacts with methane to produce hydrogenand carbon dioxide(CO_(2)).The second refers to capturing the CO_(2) generated during the SMR process on boardships.By capturing and storing the carbon emissions,the process significantly reduces its environmental impact,making the hydrogen production“blue,”as opposed to“grey”(which involves CO_(2) emissions without capture).For the SMR process,the analysis reveals that increasing the reformer temperature enhances both the processperformance and CO_(2) emissions.Conversely,a higher steam-to-carbon(s/c)ratio reduces hydrogen yield,therebydecreasing thermal efficiency.The study also shows that preheating the air and boil-off gas(BOG)before theyenter the combustion chamber boosts overall efficiency and curtails CO_(2) emissions.In the SBCC process,puremonoethanolamine(MEA)is employed to capture the CO_(2) generated by the exhaust gases from the SMR process.The results indicate that with a 90%CO_(2) capture rate,the associated heat consumption amounts to 4.6 MJ perkilogram of CO_(2) captured.This combined approach offers a viable pathway to produce blue hydrogen on LNGcarriers while significantly reducing the carbon footprint.
文摘The scientific community has reached firm consensus that humans know less about the ocean than they do about the moon.Even though we have developed submersibles capable of diving to depths of ten thousand meters,our understanding of the oceans covering approximately 71 percent of the Earth’s surface remains scarce.A paper published in Science Advances last May noted that only 0.001 percent of the deep seafloor(190 meters or more below Earth’s surface)has been visually observed by scientists,yet this tiny fraction accounts for 95 percent of the total surface area of the oceans around the globe.
