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Creating super-tough and strong PA6/ABS blends using multi-phase compatibilizers 被引量:4
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作者 Xianwei Sui Xu-Ming Xie 《Chinese Chemical Letters》 SCIE CAS CSCD 2019年第1期149-152,共4页
Polyamide/acrylonitrile-butadiene-styrene copolymer(PA/ABS) blends have drawn considerable attention from both academia and industry for their important applications in automotive and electronic areas. Due to poor mis... Polyamide/acrylonitrile-butadiene-styrene copolymer(PA/ABS) blends have drawn considerable attention from both academia and industry for their important applications in automotive and electronic areas. Due to poor miscibility of PA and ABS, developing an effective compatibilization strategy has been an urgent challenge to achieve prominent mechanical properties. In this study, we create a set of mechanically enhanced PA6/ABS blends using two multi-monomer melt-grafted compatibilizers, SEBSg-(MAH-co-St) and ABS-g-(MAH-co-St). The dispersed domain size is significantly decreased and meanwhile the unique "soft shell-encapsulating-hard core" structures form in the presence of compatibilizers. The optimum mechanical performances manifest an increase of 36% in tensile strength and an increase of 1300% in impact strength, compared with the neat PA6/ABS binary blend. 展开更多
关键词 MELT BLENDING multi-phase COMPATIbiLIZER Morphology Tensile properties SUPER-TOUGH
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BiPAP联合抗生素降阶梯疗法对重症肺炎合并Ⅰ型呼吸衰竭患者的抢救效果
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作者 季红华 纪王斐 朱麒霖 《中国急救复苏与灾害医学杂志》 2026年第1期89-92,共4页
目的探究双水平无创正压通气(BiPAP)联合抗生素降阶梯疗法对重症肺炎合并Ⅰ型呼吸衰竭的抢救效果。方法选取2023年1月—2024年12月南通市第三人民医院收治的101例重症肺炎合并Ⅰ型呼吸衰竭患者资料,所有患者均接受抗生素降阶梯疗法,其... 目的探究双水平无创正压通气(BiPAP)联合抗生素降阶梯疗法对重症肺炎合并Ⅰ型呼吸衰竭的抢救效果。方法选取2023年1月—2024年12月南通市第三人民医院收治的101例重症肺炎合并Ⅰ型呼吸衰竭患者资料,所有患者均接受抗生素降阶梯疗法,其中57例接受常规经口气管插管机械通气,纳入对照组;拒绝插管的44例患者接受BiPAP机械通气,纳入研究组。比较两组通气前后血气分析指标、机械通气时间、恢复时间、撤机情况、机械通气相关并发症、近期预后。结果两组通气1 h后血气分析指标及院内病死率、出院28 d病死率差异无统计学意义(P>0.05);研究组机械通气时间、住ICU时间、总住院时间分别为(6.49±1.40)、(9.72±2.23)、(14.15±3.20)d,均短于对照组的(9.44±2.36)、(12.25±2.41)、(18.80±4.52)d,一次撤机成功率高于对照组(87.50%vs.68.63%),机械通气相关并发症总发生率低于对照组(20.00%vs.39.22%)(t=6.994、5.135、5.510,χ^(2)=4.498、3.886,均P<0.05)。结论在患者拒绝气管插管的前提下,BiPAP联合抗生素降阶梯疗法可使重症肺炎合并Ⅰ型呼吸衰竭患者获得与有创通气相当的通气改善效果,且安全性更高,帮助患者获得良好撤机结局,进而缩短住院时间。 展开更多
关键词 重症肺炎 Ⅰ型呼吸衰竭 双水平无创正压通气 抗生素降阶梯疗法
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Heavy metals in a typical city-river-reservoir system of East China:Multi-phase distribution,microbial response and ecological risk 被引量:4
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作者 Jun Yang Mingrui Zhou +3 位作者 Kaifeng Yu Karina Yew-Hoong Gin Muhammad Hassan Yiliang He 《Journal of Environmental Sciences》 SCIE EI CAS CSCD 2022年第2期343-354,共12页
The rapid construction of artificial reservoirs in metropolises has promoted the emergence of city-river-reservoir systems worldwide.This study investigated the environmental behaviors and risks of heavy metals in the... The rapid construction of artificial reservoirs in metropolises has promoted the emergence of city-river-reservoir systems worldwide.This study investigated the environmental behaviors and risks of heavy metals in the aquatic environment of a typical system composed of main watersheds in Suzhou and Jinze Reservoir in Shanghai.Results shown that Mn,Zn and Cu were the dominant metals detected in multiple phases.Cd,Mn and Zn were mainly presented in exchangeable fraction and exhibited high bioavailability.Great proportion and high mobility of metals were found in suspended particulate matter(SPM),suggesting that SPM can greatly affect metal multi-phase distribution process.Spatially,city system(Ci S)exhibited more serious metal pollution and higher ecological risk than river system(Ri S)and reservoir system(Re S)owing to the diverse emission sources.Ci S and Re S were regarded as critical pollution source and sink,respectively,while Ri S was a vital transportation aisle.Microbial community in sediments exhibited evident spatial variation and obviously modified by exchangeable metals and nutrients.In particular,Bacteroidetes and Firmicutes presented significant positive correlations with most exchangeable metals.Risk assessment implied that As,Sb and Ni in water may pose potential carcinogenic risk to human health.Nevertheless,Re S was in a fairly safe state.Hg was the main risk contributor in SPM,while Cu,Zn,Ni and Sb showed moderate risk in sediments.Overall,Hg,Sb and Ci S were screened out as priority metals and system,respectively.More attention should be paid to these priority issues to promote the sustainable development of the watershed. 展开更多
关键词 Heavy metal multi-phase Chemical fraction City-river-reservoir system Microbial community
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Bi/nZVI在柠檬酸缓冲溶液中电催化降解磺胺二甲基嘧啶
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作者 唐紫依 刘杰 龚建宇 《环境化学》 北大核心 2026年第1期436-444,共9页
随着医药和畜牧业的快速发展,大量磺胺类药物残余物进入水体,引起一系列环境和健康问题.改性纳米零价铁(nZVI)通过激活分子氧产H_(2)O_(2),发生类芬顿反应快速高效降解SAs,引起广泛关注.本文利用铋改性纳米零价铁(Bi/nZVI)在柠檬酸(CA)... 随着医药和畜牧业的快速发展,大量磺胺类药物残余物进入水体,引起一系列环境和健康问题.改性纳米零价铁(nZVI)通过激活分子氧产H_(2)O_(2),发生类芬顿反应快速高效降解SAs,引起广泛关注.本文利用铋改性纳米零价铁(Bi/nZVI)在柠檬酸(CA)-柠檬酸钠(NaCA)缓冲溶液中电催化氧化降解磺胺二甲基嘧啶(SMZ).结果表明,Bi的掺杂有利于降低分子氧活化生成H_(2)O_(2)的反应活化能,柠檬酸根与铁络合生成的柠檬酸亚铁络合物与体系自发生成的H_(2)O_(2)发生类芬顿反应,Fe^(2+)/Fe^(3+)氧化还原电位降低,利于铁循环过程,从而强化对SMZ的降解效果.在该体系中存在·OH、·O_(2)^(-)、^(1)O_(2)等3种活性氧物种(ROS),其贡献大小依次为:·OH>·O_(2)^(-)>^(1)O_(2).质谱分析推测,在该体系下,SMZ可能的降解路径主要包括4方面:羟基化加成、磺酰胺基SO_(2)脱除、S—N键断裂和含氮杂环C—N/C=N键断裂.这种新型体系的构建不仅为水体中磺胺类药物的去除提供了新的技术方法,也为其他有机污染物的处理提供了一定的理论支撑. 展开更多
关键词 电催化 bi/nZVI 柠檬酸缓冲液 磺胺二甲基嘧啶 络合
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Sn-Bi基焊料界面可靠性关键问题与改性策略研究进展
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作者 赏敏 马海涛 +2 位作者 马浩然 王加俊 王云鹏 《表面技术》 北大核心 2026年第3期219-243,共25页
系统综述了旨在提升Sn-Bi焊点界面可靠性的多层次改性策略。首先,评述了通过焊料合金化调控其本征性能的方法,系统分析了添加Ag、Cu、Ni、In、Sb、Zn、Co等元素对焊料微观结构、力学性能及界面反应动力学的影响。其次,探讨了以石墨烯为... 系统综述了旨在提升Sn-Bi焊点界面可靠性的多层次改性策略。首先,评述了通过焊料合金化调控其本征性能的方法,系统分析了添加Ag、Cu、Ni、In、Sb、Zn、Co等元素对焊料微观结构、力学性能及界面反应动力学的影响。其次,探讨了以石墨烯为代表的纳米颗粒强化机制,阐明其在细化晶粒和抑制IMC生长方面的作用。随后,重点阐述了以基板改性为核心的界面工程策略,深入剖析了Ni基金属镀层和Ni-P、Ni-W-P等先进复合镀层作为扩散阻挡层的核心机理,即通过改变界面反应热力学路径来抑制原子互扩散。同时,也关注了复合改性方法,如焊料合金化与基板表面处理,如ENEPIG的协同作用。最后,对未来研究方向进行了展望,指出开发高熵/非晶合金等新型阻挡层,并结合计算材料学与先进原位表征技术,将是实现下一代高可靠性Sn-Bi焊点界面“按需设计”的关键。 展开更多
关键词 Sn-bi焊料 界面可靠性 金属间化合物 bi相偏析 合金化 扩散阻挡层 纳米增强
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Multi-phase field simulation of grain growth in multiple phase transformations of a binary alloy 被引量:1
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作者 冯力 贾北北 +3 位作者 朱昶胜 安国升 肖荣振 冯小静 《Chinese Physics B》 SCIE EI CAS CSCD 2017年第8期87-95,共9页
This work establishes a temperature-controlled sequence function, and a new multi-phase-field model, for liquid- solid-solid multi-phase transformation by coupling the liquid-solid phase transformation model with the ... This work establishes a temperature-controlled sequence function, and a new multi-phase-field model, for liquid- solid-solid multi-phase transformation by coupling the liquid-solid phase transformation model with the solid-solid phase transformation model. Taking an Fe-C alloy as an example, the continuous evolution of a multi-phase transformation is simulated by using this new model. In addition, the growth of grains affected by the grain orientation of the parent phase (generated in liquid-solid phase transformation) in the solid-solid phase transformation is studied. The results show that the morphology of ferrite grains which nucleate at the boundaries of the austenite grains is influenced by the orientation of the parent austenite grains. The growth rate of ferrite grains which nucleate at small-angle austenite grain boundaries is faster than those that nucleate at large-angle austenite grain boundaries. The difference of the growth rate of ferrites grains in different parent phase that nucleate at large-angle austenite grain boundaries, on both sides of the boundaries, is greater than that of ferrites nucleating at small-angle austenite grain boundaries. 展开更多
关键词 multi-phase transformation MICROSTRUCTURE multi-phase-field method grain orientation
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Bi基催化剂CO_(2)还原反应生成甲酸的研究进展
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作者 宫智超 莫瑞 +2 位作者 辛雯 王文飞 聂春红 《化工科技》 2026年第1期59-64,共6页
可持续地将CO_(2)转化为高附加值的化学品和燃料是解决CO_(2)过量排放问题、缓解化石燃料短缺、维持自然界碳循环平衡的一种有希望的解决方案。催化体系的开发对提高电催化CO_(2)转化的效率和选择性具有重要意义。甲酸(HCOOH)是CO_(2)... 可持续地将CO_(2)转化为高附加值的化学品和燃料是解决CO_(2)过量排放问题、缓解化石燃料短缺、维持自然界碳循环平衡的一种有希望的解决方案。催化体系的开发对提高电催化CO_(2)转化的效率和选择性具有重要意义。甲酸(HCOOH)是CO_(2)电催化还原的重要产物之一,其化工和能源领域具有广泛的应用价值。Bi基材料因其低成本、环境友好等优势,在该领域展现出良好的催化潜力,但仍需克服诸多挑战。综述了常温常压水相体系中Bi基材料电催化CO_(2)还原制甲酸研究进展,从Bi金属、Bi单原子、Bi合金及Bi复合材料系统分析了各类催化剂的特性与优势,并对Bi基催化剂的未来发展方向进行了展望。 展开更多
关键词 电催化 CO_(2)还原 bi基催化剂 甲酸 电化学
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触变成形Mg-5Sn-3Bi-2Cu合金微观组织与力学性能研究
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作者 孟帅举 王孟璐 +6 位作者 杜慈威 归金琪 杨贵荣 余海存 毕广利 陈体军 曹驰 《材料导报》 北大核心 2026年第1期170-174,共5页
为探清触变加工Mg-Sn-Bi系合金显微组织与力学行为特点,综合采用OM、SEM、XRD、EPMA和室温拉伸试验,对比研究了Mg-5Sn-3Bi-2Cu(TBC532)合金在触变锻造前后的微观组织特征与力学性能变化。结果表明,触变锻造态样品中形成了由近球状粗晶... 为探清触变加工Mg-Sn-Bi系合金显微组织与力学行为特点,综合采用OM、SEM、XRD、EPMA和室温拉伸试验,对比研究了Mg-5Sn-3Bi-2Cu(TBC532)合金在触变锻造前后的微观组织特征与力学性能变化。结果表明,触变锻造态样品中形成了由近球状粗晶和细小二次凝固组织构成的双峰结构,显著区别于铸态TBC532合金的均匀树枝晶组织。触变锻造态TBC532合金中近球状粗晶体积分数约为60.8%,其平均尺寸及形状因子分别为98.5μm和1.26;二次凝固组织由平均晶粒尺寸约为4.6μm的细小等轴树枝晶和连续网状的化合物相(Mg_(3)Bi_(2)、Mg_(2)Sn、Mg_(2)Cu和BiSn)构成,主要均匀分布在球状组织之间,少量分布在近球状晶粒内部。触变锻造态TBC532合金的抗拉强度和延伸率比铸态试样更高,较铸态合金分别提升17.0%与36.1%,分别达到(292.3±5.2)MPa和(14.7±0.3)%,其断裂机制主要为穿晶韧性断裂,这主要归因于触变锻造态TBC532合金中细晶组织的细晶强化作用以及粗、细晶区之间的协同作用。 展开更多
关键词 Mg-Sn-bi合金 触变加工 混晶结构 强韧化机理
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Multi-scale modeling of the multi-phase flow in water electrolyzers for green hydrogen production
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作者 Lizhen Wu Qing Wang +2 位作者 Wenzhi Li Mingcong Tang Liang An 《Materials Reports(Energy)》 2025年第3期40-49,共10页
Water electrolyzers play a crucial role in green hydrogen production.However,their efficiency and scalability are often compromised by bubble dynamics across various scales,from nanoscale to macroscale components.This... Water electrolyzers play a crucial role in green hydrogen production.However,their efficiency and scalability are often compromised by bubble dynamics across various scales,from nanoscale to macroscale components.This review explores multi-scale modeling as a tool to visualize multi-phase flow and improve mass transport in water electrolyzers.At the nanoscale,molecular dynamics(MD)simulations reveal how electrode surface features and wettability influence nanobubble nucleation and stability.Moving to the mesoscale,models such as volume of fluid(VOF)and lattice Boltzmann method(LBM)shed light on bubble transport in porous transport layers(PTLs).These insights inform innovative designs,including gradient porosity and hydrophilic-hydrophobic patterning,aimed at minimizing gas saturation.At the macroscale,VOF simulations elucidate two-phase flow regimes within channels,showing how flow field geometry and wettability affect bubble discharging.Moreover,artificial intelligence(AI)-driven surrogate models expedite the optimization process,allowing for rapid exploration of structural parameters in channel-rib flow fields and porous flow field designs.By integrating these approaches,we can bridge theoretical insights with experimental validation,ultimately enhancing water electrolyzer performance,reducing costs,and advancing affordable,high-efficiency hydrogen production. 展开更多
关键词 Water electrolyzers Bubble dynamics MULTI-SCALE multi-phase MODELING
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A thermodynamically complete multi-phase equation of state for dense and porous metals at wide ranges of temperature and pressure
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作者 Yanhong Zhao Li-Fang Wang +6 位作者 Qili Zhang Le Zhang Hongzhou Song Xingyu Gao Bo Sun Haifeng Liu Haifeng Song 《Chinese Physics B》 2025年第3期499-504,共6页
A thermodynamically complete multi-phase equation of state(EOS)applicable to both dense and porous metals at wide ranges of temperature and pressure is constructed.A standard three-term decomposition of the Helmholtz ... A thermodynamically complete multi-phase equation of state(EOS)applicable to both dense and porous metals at wide ranges of temperature and pressure is constructed.A standard three-term decomposition of the Helmholtz free energy as a function of specific volume and temperature is presented,where the cold component models both compression and expansion states,the thermal ion component introduces the Debye approximation and melting entropy,and the thermal electron component employs the Thomas-Fermi-Kirzhnits(TFK)model.The porosity of materials is considered by introducing the dynamic porosity coefficientαand the constitutive P-αrelation,connecting the thermodynamic properties between dense and porous systems,allowing for an accurate description of the volume decrease caused by void collapse while maintaining the quasi-static thermodynamic properties of porous systems identical to the dense ones.These models enable the EOS applicable and robust at wide ranges of temperature,pressure and porosity.A systematic evaluation of the new EOS is conducted with aluminum(Al)as an example.300 K isotherm,shock Hugoniot,as well as melting curves of both dense and porous Al are calculated,which shows great agreements with experimental data and validates the effectiveness of the models and the accuracy of parameterizations.Notably,it is for the first time Hugoniot P-σcurves up to 10~6 GPa and shock melting behaviors of porous Al are derived from analytical EOS models,which predict much lower compression limit and shock melting temperatures than those of dense Al. 展开更多
关键词 equation of state multi-phase model porous metal
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Bi-2223超导带材力学性能增强研究进展
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作者 毕雁鸿 姜浪 +3 位作者 杨芳 张胜楠 闫果 张平祥 《中国材料进展》 北大核心 2026年第2期102-110,共9页
Bi_(2)Sr_(2)Ca_(2)Cu_(3)O_(x)(Bi-2223)超导材料具有高临界转变温度和高上临界场,由其制备的Bi-2223带材具有较高的载流性能,因而在电工领域的应用中具有明确的优势。然而,Bi-2223带材在超导电缆、磁体等使用过程中所受洛伦兹力和热... Bi_(2)Sr_(2)Ca_(2)Cu_(3)O_(x)(Bi-2223)超导材料具有高临界转变温度和高上临界场,由其制备的Bi-2223带材具有较高的载流性能,因而在电工领域的应用中具有明确的优势。然而,Bi-2223带材在超导电缆、磁体等使用过程中所受洛伦兹力和热应力会对超导芯丝造成损伤,使带材的载流性能降低。在实际应用中需要对Bi-2223带材进行力学性能增强,以保证Bi-2223带材的使用性能。简述了Bi-2223带材的常用力学性能增强方法,包括合金包套增强和层压增强,还介绍了常用的银合金包套和层压增强材料,阐述了银合金包套增强作用和层压增强中残余应变对Bi-2223带材增强的作用。 展开更多
关键词 bi-2223带材 临界电流密度 银合金包套 层压增强 残余应变
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Mg-Bi合金热变形行为研究
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作者 尤建伟 要玉宏 +2 位作者 刘江南 王欣雨 任梦飞 《稀有金属材料与工程》 北大核心 2026年第1期241-249,共9页
聚焦Mg-3Bi和Mg-6Bi 2种合金在400℃、应变速率0.001 s^(-1)条件下的挤压变形行为,并深入剖析挤压过程中合金的微观组织特征。研究发现,当Bi含量由3wt%增加到6wt%,合金塑性显著提升,断后伸长率由2.1%增加到5.6%,抗拉强度由188.2 MPa提高... 聚焦Mg-3Bi和Mg-6Bi 2种合金在400℃、应变速率0.001 s^(-1)条件下的挤压变形行为,并深入剖析挤压过程中合金的微观组织特征。研究发现,当Bi含量由3wt%增加到6wt%,合金塑性显著提升,断后伸长率由2.1%增加到5.6%,抗拉强度由188.2 MPa提高到209.2 MPa。高温挤压变形时,Mg-3Bi合金的软化机制主要是不连续动态再结晶,Mg-6Bi合金的是不连续动态再结晶和粒子诱导再结晶,其中前者的晶粒尺寸要大于后者。对Mg-Bi合金采用模具挤压时,模具边缘区域应变明显大于中心区域,形成类似于等通道转角挤压变形织构,当变形量累积到一定程度后,粒子诱导再结晶机制启动。合金挤压变形后,模具边缘区域和中心区域的晶粒均呈现高度再结晶状态,晶粒c轴垂直于挤压方向,形成典型挤压纤维织构。对Mg-Bi合金力学性能提升的贡献从高到低依次为晶粒细化、位错强化和纳米相强化机制。较Mg-3Bi合金,Mg-6Bi的韧窝密度更大,分散了应力集中,因此表现出更好的塑性。 展开更多
关键词 Mg-bi合金 挤压热变形 力学性能 动态再结晶
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熔盐净化和熔体急冷对Sn-Bi-Ag-Si系焊料合金组织和性能的影响
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作者 刘博文 刘亚 +4 位作者 郭志球 吴长军 陈军修 朱翔鹰 苏旭平 《特种铸造及有色合金》 北大核心 2026年第1期87-94,共8页
采用配比为(质量分数,下同)0~50%NaCl+30%~50%KCl+10%~20%Na3AlF6的熔融复合盐,在750~850℃范围内对Sn-Bi-Ag-Si系合金熔体进行净化处理后急冷,采用扫描电镜、能谱仪、差示扫描热量仪、电子万能试验机等研究了试验前后合金的组织与性能... 采用配比为(质量分数,下同)0~50%NaCl+30%~50%KCl+10%~20%Na3AlF6的熔融复合盐,在750~850℃范围内对Sn-Bi-Ag-Si系合金熔体进行净化处理后急冷,采用扫描电镜、能谱仪、差示扫描热量仪、电子万能试验机等研究了试验前后合金的组织与性能变化。结果表明,熔盐净化和急冷的协同作用会细化粗大的块状Bi相组织,同时使得合金抗拉强度提高了约10%,而在Cu基体表面的润湿性提高了约40%。 展开更多
关键词 低温无铅合金 Sn-bi系合金 熔盐净化 界面反应
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基于Bi-LSTM特征融合和FT-FSL的非侵入式负荷辨识
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作者 张竹露 李华强 +1 位作者 刘洋 许立雄 《广西师范大学学报(自然科学版)》 北大核心 2026年第1期33-44,共12页
通过非侵入式负荷监测(non-intrusive load monitoring,NILM)对负荷能耗进行实时监测和数据分析,能够实现能源合理配置和精细化管理。为了提高负荷标注数据不足情况下NILM的负荷识别效果,本文提出一种基于Bi-LSTM特征融合和微调小样本学... 通过非侵入式负荷监测(non-intrusive load monitoring,NILM)对负荷能耗进行实时监测和数据分析,能够实现能源合理配置和精细化管理。为了提高负荷标注数据不足情况下NILM的负荷识别效果,本文提出一种基于Bi-LSTM特征融合和微调小样本学习(fine-tuned few-shot learning,FT-FSL)的新方法应用于NILM。首先,通过Bi-LSTM将加权像素电压-电流(voltage-current,V-I)图像特征和多维时频序列特征进行融合;然后,通过FT-FSL使负荷分类模型能够基于少量标注数据进行训练;最后,在PLAID数据集上与4种主流FSL方法(包括匹配网络、原型网络、关系网络和MAML)进行对比实验。结果表明,本文方法的准确率达到92.46%,与对比模型相比,分别提高12.21个百分点、4.18个百分点、5.90个百分点和9.04个百分点,验证了本文方法能够有效识别标注数据不足的负荷类型。 展开更多
关键词 非侵入式负荷监测 负荷辨识 小样本学习 bi-LSTM 微调
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Interfacial charge redistribution at multi-phase boundaries for efficient electrocatalytic ammonia synthesis and high-power Zn-NO_(3)^(-)batteries
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作者 Xinyu Zhao Xiaoxiao Zou +4 位作者 Bohuai Pang Hang Ma Qing Liu Lilian Wang Hong Guo 《Journal of Energy Chemistry》 2025年第12期306-315,I0009,共11页
The nitrate reduction via electrochemical catalysis offers an environmentally friendly method for sustainable ammonia production and wastewater remediation.However,conventional Co-based catalysts suffer from a major l... The nitrate reduction via electrochemical catalysis offers an environmentally friendly method for sustainable ammonia production and wastewater remediation.However,conventional Co-based catalysts suffer from a major limitation:their nitrate(NO_(3)^(-))adsorption capacity remains weak.This drawback severely restricts their catalytic efficiency.To overcome this limitation,we synthesized a triphasic interface material(Cu/Co/CoO@C)via rapid joule heating and elucidated its performance-enhancing mechanisms.The exceptional catalytic performance originates from the phase interface-induced multiscale structural regulation.At the microscopic scale,electronic structure modulation through interfacial charge redistribution between Cu and Co/CoO significantly reduces intermediate adsorption energies.Co 3d and O 2p orbitals coupling generates a localized polarized electric field,enhancing NO_(3)^(-)activation.At the macroscopic scale,defect-rich structures improve mass transfer and expose abundant active sites.With the Cu/Co/CoO@C,the yield of NH_(3) is achieved to 2.03 mmol h^(-1)cm^(-2)(-0.4 V vs.RHE,Faradaic efficiency(FE)98.4%).The assembled Zn-NO_(3)^(-)battery delivered a maximum power density of 52.09 mW cm^(-2)and a NH_(3) production rate of 297.5μmol h^(-1)cm^(-2)(FE 95.4%).Based on these results,this work offers new insights into multiphase interface design. 展开更多
关键词 multi-phase interface Electronic modulation P-d orbital coupling Core-satellite structure Zn-NO_(3)^(-)battery
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Multi-Phase Degradation Modeling Based on Uncertain Random Process for Remaining Useful Life Prediction Under Triple Uncertainties
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作者 Xuerui Cao Kaixiang Peng Ruihua Jiao 《IEEE/CAA Journal of Automatica Sinica》 2025年第6期1129-1143,共15页
Due to abrupt changes in the intrinsic degradation mechanism or shock from external environmental pressure,degradations of some equipment are characterized by multi-phase and jumps.Meanwhile,equipment is subject to in... Due to abrupt changes in the intrinsic degradation mechanism or shock from external environmental pressure,degradations of some equipment are characterized by multi-phase and jumps.Meanwhile,equipment is subject to inherent fluctuations,limited data and imperfect measurements resulting in aleatory,epistemic and measurement uncertainties of the degradation process.This paper proposes a degradation model and remaining useful life(RUL)prediction method under triple uncertainties for a category of complex equipment with multi-phase degradation and jumps.First,a multi-phase degradation model with random jumps and measurement errors is constructed based on uncertain random processes.Afterward,the analytic expression of RUL prediction considering the heterogeneity is derived by modeling the uncertainty of degradation states at change points under the concept of first hitting time.A stochastic uncertain approach is utilized for the proposed multi-phase degradation model to identify model parameters based on historical data.Furthermore,the implied degradation features are adaptively updated in online stage using similarity-based weighted stochastic uncertain maximum likelihood estimation and Kalman filtering.Finally,the effectiveness of the method is verified by simulation example and practical case. 展开更多
关键词 Measurement errors multi-phase degradation model random jumps remaining useful life(RUL)prediction uncertain random process
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Atomic-scale characterization of epitaxial Bi(110)/VTe_(2)bilayer heterostructure
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作者 WANG Qiwei LI Shaochun 《物理学进展》 北大核心 2026年第1期13-21,共9页
Interplay between topology and magnetism can give rise to exotic properties in topological materials.Two-dimensional bismuth has been extensively studied owing to its topological states with a strong spin-orbit coupli... Interplay between topology and magnetism can give rise to exotic properties in topological materials.Two-dimensional bismuth has been extensively studied owing to its topological states with a strong spin-orbit coupling,and 1T-VTe_(2)monolayer theoretically predicted to host an intrinsic magnetism as experimentally suggested.In this work,we successfully constructed a vertical heterostructure composed of the two-dimensional Bi(110)monolayer and 1T-VTe_(2)monolayer by using molecular beam epitaxy(MBE).Scanning tunneling microscopy(STM)measurements revealed that the growth of Bi preferably occurs along the step edges of the VTe_(2)monolayer,forming a Bi(110)monolayer on top of the VTe_(2)monolayer next to a peripheral Bi bilayer.The Bi(100)/VTe_(2)heterostructure exhibits a specific lattice registry with a well-defined moiréperiodicity.Scanning tunneling spectroscopy(STS)measurements further unveiled an universal suppression in the local density-of-states at the boundary of the Bi(110)/VTe_(2)bilayer.By examining the atomic structures of Bi(110)boundaries,we found this effect does not originate from the previously proposed atomic reconstruction at the step edge of Bi(110),but is likely related to the magnetic properties of the VTe_(2)monolayer. 展开更多
关键词 bi/VTe_(2)heterostructure moirépattern edge state molecular beam epitaxy scanning tunneling microscopy
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Microstructure design and feasibility of hot stamping for new generation high strength multi-phase steels
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作者 JIN Xuejun 《Baosteel Technical Research》 CAS 2010年第S1期49-49,共1页
Optimization of microstructure for new generation advanced high strength steels(AHSS)for automobiles was briefly reviewed.Two different heat treatments(quenching partitioning austempering/QPA and quenching partitionin... Optimization of microstructure for new generation advanced high strength steels(AHSS)for automobiles was briefly reviewed.Two different heat treatments(quenching partitioning austempering/QPA and quenching partitioning tempering/QPT)have been investigated to obtain optimal microstructures,which are made up of martensite(hard phase),retained austenite(soft phase),and carbide or nano-bainite.Combination of hot stamping and newly developed heat treatments is discussed. 展开更多
关键词 high strength multi-phase steels hot stamping MARTENSITE retained austenite
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Development and Application of Multi-phase Nitrides Bonded Silicon Carbide Lintel Blocks for Dry Quenching Furnaces
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作者 CAO Huiyan FENG Yanbin +4 位作者 ZHANG Xinhua HUANG Zhigang LI Jie WANG Xinhui WU Jiguang 《China's Refractories》 CAS 2023年第2期7-11,共5页
Multi-phase nitrides bonded silicon carbide lintel blocks were prepared using industrial SiC(SiC≥98 mass%,3-0.5,≤0.5 and≤0.044 mm),Si powder(Si≥98 mass%,≤0.044 mm),and SiO2 micropowder(SiO2≥96 mass%,d50=0.15 pm)... Multi-phase nitrides bonded silicon carbide lintel blocks were prepared using industrial SiC(SiC≥98 mass%,3-0.5,≤0.5 and≤0.044 mm),Si powder(Si≥98 mass%,≤0.044 mm),and SiO2 micropowder(SiO2≥96 mass%,d50=0.15 pm)as raw materials,and calcium lignosulfonate as the additive,batching,mixing,and molding on a vibration pressure molding machine,drying and then firing at 1420℃for 10 h in high-purity N2.The apparent porosity,the bulk density,the cold modulus of rupture,the hot modulus of rupture,and the linear expansion coefficient of the samples were tested.The phase composition and the microstructure of the samples at different nitriding depths(50,100,and 150 mm)were analyzed by XRD and SEM.The field application effects of the blocks were studied.The results show that:(1)the multi-phase nitrides bonded silicon carbide refractories can dynamically adjust their own phase composition and minimize structural and thermal stresses,improving the service life of key parts of dry quenching furnaces;(2)calcium lignosulfonate can improve the nitriding micro-environment of multi-phase nitrides bonded silicon carbide lintel blocks,successfully increasing the effective nitriding thickness of the blocks to 300 mm;(3)Sinosteel LI RR provides a unique concept in the design of materials and block types as well as the stable and scientific overall structure,promoting the industrialization process of dry quenching furnaces with long service life in China. 展开更多
关键词 inclined channel area dry quenching furnaces silicon carbide multi-phase nitrides lintel blocks
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