With the rapid development of science and technology,the high-security-level anti-counterfeiting technique is essential for ensuring property or information security.In this work,we prepared micron NaYTiO_(4):Bi/Er(NY...With the rapid development of science and technology,the high-security-level anti-counterfeiting technique is essential for ensuring property or information security.In this work,we prepared micron NaYTiO_(4):Bi/Er(NYT:Bi/Er) phosphors with integrating up-conversion(UC) photoluminescence,downshifting(DS) emission,phosphorescence and photochromism(PC) performances for advanced multiple anti-counterfeiting application.Owing to the abundant energy levels of Er^(3+)ions,the UC and DS luminescence behaviors are anticipated.Specifically,the yellow-green emission of Er^(3+)ions can be observed upon 980 nm excitation,and the bright green emission is demonstrated under 281 or 254 nm excitation due to the energy transitions of Er^(3+)ions and the energy transfer process from Bi^(3+)to Er^(3+)ions.Besides,the introduction of Bi^(3+)ions generates defect levels in the matrix and thus leads to phosphorescence.Furthermore,the repeatable PC performance could be triggered by the 365 nm irradiation and vanished with 450 nm illumination or thermal stimulation.To verify the practical usability of NYT:Bi/Er phosphors on anti-counterfeiting applications,some experiments are designed and successfully executed.It is believed that the NYT:Bi/Er phosphors can be a promising candidate for high-security-level multiple anti-counterfeiting.展开更多
Targeting the huge unused bandwidth（BW）of modem telecommunication networks,Bi/Er co-doped silica optical fibers（BEDFs）have been proposed and developed for ultra-broadband,high-gain optical amplifiers covering the ...Targeting the huge unused bandwidth（BW）of modem telecommunication networks,Bi/Er co-doped silica optical fibers（BEDFs）have been proposed and developed for ultra-broadband,high-gain optical amplifiers covering the 1150-1700 nm wavelength range.Ultrabroadband luminescence has been demonstrated in both BEDFs and bismuth/erbium/ytterbium co-doped optical fibers（BEYDFs）fabricated with the modified chemical vapor deposition（MCVD）and in situ doping techniques.Several novel and sophisticated techniques have been developed for the fabrication and characterization of the new active fibers.For controlling the performance of the active fibers,post-treatment processes using high temperature,γ-radiation,and laser light have been introduced.Although many fundamental scientific and technological issues and challenges still remain,several photonic applications,such as fiber sensing,fiber gratings,fiber amplification,fiber lasers,etc.,have already been demonstrated.展开更多
We fabricate a high-performance Bi/Er/La co-doped silica fiber with a fluorescence intensity of-33.8 dBm and a gain coefficient of 1.9 dB/m.With the utilization of the fiber as a gain medium,a linear-cavity fiber lase...We fabricate a high-performance Bi/Er/La co-doped silica fiber with a fluorescence intensity of-33.8 dBm and a gain coefficient of 1.9 dB/m.With the utilization of the fiber as a gain medium,a linear-cavity fiber laser has been constructed,which exhibits a signal-to-noise ratio of 74.9 dB at 1596 nm.It has been demonstrated that the fiber laser has a maximum output power of 107.4 mW,a slope efficiency of up to 17.0%,and a linewidth of less than 0.02 nm.Moreover,an all-fiber single-stage optical amplifier is built up for laser amplification,by which the amplified laser power is up to 410.0 mW with pump efficiency of 33.8%.The results indicate that the laser is capable of high signal-to-noise ratio and narrow linewidth,with potential applications for optical fiber sensing,biomedicine,precision measurement,and the pump source of the mid-infrared fiber lasers.展开更多
We demonstrate a white light fiber source based on Bismuth and Erbium co-doped fiber and a single 830nm laser diode pump. The light spectral intensity from 1100 to 1570nm is over -45dBm, which provide ~40dB dynamic ra...We demonstrate a white light fiber source based on Bismuth and Erbium co-doped fiber and a single 830nm laser diode pump. The light spectral intensity from 1100 to 1570nm is over -45dBm, which provide ~40dB dynamic range for an OSA based spectral measurement.展开更多
通过对角化364×364完全能量矩阵的理论方法,对掺杂在Bi_(4)Ge_(3)O_(12)晶体中的Er^(3+)的Stark能级和EPR参数进行了研究,同时,定量分析了高阶晶体场混合效应和J-J混合效应对EPR g因子的影响。研究结果表明:对Er^(3+)来说,最主要的...通过对角化364×364完全能量矩阵的理论方法,对掺杂在Bi_(4)Ge_(3)O_(12)晶体中的Er^(3+)的Stark能级和EPR参数进行了研究,同时,定量分析了高阶晶体场混合效应和J-J混合效应对EPR g因子的影响。研究结果表明:对Er^(3+)来说,最主要的J-J混合效应来源于多重态谱项2 K 15/2,其对EPR g因子的贡献约占2.5%,而最主要的高阶晶体场混合效应来源于第一激发多重态^(4)I_(13/2)和基态多重态^(4)I_(15/2)之间的晶体场混合,其对各向异性g因子中g⊥的贡献大致是g//的两倍(即g⊥约占0.21%,g//约占0.092%),其他更高阶的晶体场混合和J-J混合效应可以忽略不计。因此,对于Er^(3+)掺杂的络合物系统来说,只考虑基态多重态4 I 15/2对EPR g因子的贡献应该是一个很好的近似。展开更多
The （60 - x）Bi2O3 - xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated using the melting method. The thermal stability of the glasses was studied with ...The （60 - x）Bi2O3 - xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated using the melting method. The thermal stability of the glasses was studied with their DTA curves. The results show that the difference between the glass transition temperature and the crystallization onset temperature increases with the increase of GeO2 content, indicating that the thermal stability of the glass has become better. The absorption spectra were recorded and the stimulated emission cross sections were calculated using the McCumber theory. The Ω2, O4, and Ω6 parameters,the transition probability, the radiative lifetime, and the fluorescence branch ratio of Er^3＋ for optical transition were calculated from their absorption spectra in terms of reduced matrix U^（t）（λ = 2, 4, 6） character for optical transitions. The infrared emission of Er^3＋ was measured upon excitation with 970 nm light and the full width at half-maximum （FWHM） was estimated from the emission spectra. The pumping efficiency and the intensity of the emission at the 1.54 μm band of Er^3＋ were enhanced considerably by co-doping Yb^3＋ .展开更多
Cyclic electrodeposition was used to investigate the preparation of Er-Co-Bi alloy thin film in DMSO system. Experimental results indicate that Er-Co-Bi alloy thin film containing 14.83 %32.65 % Er is prepared from 0....Cyclic electrodeposition was used to investigate the preparation of Er-Co-Bi alloy thin film in DMSO system. Experimental results indicate that Er-Co-Bi alloy thin film containing 14.83 %32.65 % Er is prepared from 0.1 mol/L ErCl3+0.1 mol/L CoCl2+0.1 mol/L Bi（NO3）3+0.1 mol/L LiCl +DMSO system by cyclic electrodeposition on Cu substrate. The optimum cyclic potential of electrodeposition is that upper potential is within a potential range from -0.50 V to -1.00 V and lower potential is within a potential range from -2.00 V to )-2.60 V.) The surface of alloy thin film observed by scanning electron microscope is black, adhesive and has metallic luster. The film is amorphous proved by the X-ray diffractometry.展开更多
The （60 - x） Bi2O3-xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated by melting method. The thermal stability of the glasses was studied by their DTA ...The （60 - x） Bi2O3-xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated by melting method. The thermal stability of the glasses was studied by their DTA curves. The results indicate that the difference between the glass transition temperature and the crystallization onset temperature increase as increase of GeO2 content, indicating that the thermal stability of the glass becomes better. The absorption spectra were recorded. The stimulated emission cross sections were calculated by McCumber theory. The Ω2, Ω4, and Ω6 parameters, transition probability, radiative lifetime, fluorescence branch ratio of Er^3＋ for optical transition were calculated from their absorption spectra in terms of reduced matrix U^（1）（λ = 2, 4, 6） character for optical transitions. The infrared emission was measured by excitation with 970 nm light and the FWHM was estimated from their emission spectra. The pumping efficiency and the intensity of emission at the band of 1.54 μm are enhanced greatly by addition of Y2O3.展开更多
基金supported by the Introduced Innovative R&D Team Project of "The Pearl River Talent Recruitment Program"of Guangdong Province (No.2019ZT08C321)Guangdong Basic and Applied Basic Research Foundation (No.2019A1515110443)the National Natural Science Foundation of China (No.51872327)。
文摘With the rapid development of science and technology,the high-security-level anti-counterfeiting technique is essential for ensuring property or information security.In this work,we prepared micron NaYTiO_(4):Bi/Er(NYT:Bi/Er) phosphors with integrating up-conversion(UC) photoluminescence,downshifting(DS) emission,phosphorescence and photochromism(PC) performances for advanced multiple anti-counterfeiting application.Owing to the abundant energy levels of Er^(3+)ions,the UC and DS luminescence behaviors are anticipated.Specifically,the yellow-green emission of Er^(3+)ions can be observed upon 980 nm excitation,and the bright green emission is demonstrated under 281 or 254 nm excitation due to the energy transitions of Er^(3+)ions and the energy transfer process from Bi^(3+)to Er^(3+)ions.Besides,the introduction of Bi^(3+)ions generates defect levels in the matrix and thus leads to phosphorescence.Furthermore,the repeatable PC performance could be triggered by the 365 nm irradiation and vanished with 450 nm illumination or thermal stimulation.To verify the practical usability of NYT:Bi/Er phosphors on anti-counterfeiting applications,some experiments are designed and successfully executed.It is believed that the NYT:Bi/Er phosphors can be a promising candidate for high-security-level multiple anti-counterfeiting.
基金Authors are thankful for the support of National Natural Science Foundation of China （Grant Nos. 61520106014, 61405014 and 61377096）, Key Laboratory of In-fiber Integrated Optics, Ministry Education of China, State Key Laboratory of Information Photonics and Optical Communications （Beijing University of Posts and Telecommunica- tions） （No. IPOC2016ZT07）, Key Laboratory of Optical Fiber Sensing ＆ Communications （Education Ministry of China）, Key Laboratory of Optoelectronic Devices and Systems of Ministry of Education and Guangdong Province （No. GD201702） and Science and Technology Commission of Shanghai Municipality, China （Nos. SKLSFO2015-01 and 15220721500）. We also wishes to express our thanks to all members of Photonics ＆ Optical Communications at UNSW, Prof. John Canning and Dr. Kevin Cook at University of Sydney, Prof. Graham Town at Macquarie University, and Prof. Tingyun Wang at Shanghai University for their assistance and contributions.
文摘Targeting the huge unused bandwidth（BW）of modem telecommunication networks,Bi/Er co-doped silica optical fibers（BEDFs）have been proposed and developed for ultra-broadband,high-gain optical amplifiers covering the 1150-1700 nm wavelength range.Ultrabroadband luminescence has been demonstrated in both BEDFs and bismuth/erbium/ytterbium co-doped optical fibers（BEYDFs）fabricated with the modified chemical vapor deposition（MCVD）and in situ doping techniques.Several novel and sophisticated techniques have been developed for the fabrication and characterization of the new active fibers.For controlling the performance of the active fibers,post-treatment processes using high temperature,γ-radiation,and laser light have been introduced.Although many fundamental scientific and technological issues and challenges still remain,several photonic applications,such as fiber sensing,fiber gratings,fiber amplification,fiber lasers,etc.,have already been demonstrated.
基金This work was supported by the National Key Research and Development Program of China(No.2020YFB1805800)National Natural Science Foundation of China(Nos.61975113,61935002,61735009,and 61705126),Project(No.D20031)Shanghai Professional Technical Public Service Platform of Advanced Optical Waveguide Intelligent Manufacturing and Testing(No.19DZ2294000).
文摘We fabricate a high-performance Bi/Er/La co-doped silica fiber with a fluorescence intensity of-33.8 dBm and a gain coefficient of 1.9 dB/m.With the utilization of the fiber as a gain medium,a linear-cavity fiber laser has been constructed,which exhibits a signal-to-noise ratio of 74.9 dB at 1596 nm.It has been demonstrated that the fiber laser has a maximum output power of 107.4 mW,a slope efficiency of up to 17.0%,and a linewidth of less than 0.02 nm.Moreover,an all-fiber single-stage optical amplifier is built up for laser amplification,by which the amplified laser power is up to 410.0 mW with pump efficiency of 33.8%.The results indicate that the laser is capable of high signal-to-noise ratio and narrow linewidth,with potential applications for optical fiber sensing,biomedicine,precision measurement,and the pump source of the mid-infrared fiber lasers.
文摘We demonstrate a white light fiber source based on Bismuth and Erbium co-doped fiber and a single 830nm laser diode pump. The light spectral intensity from 1100 to 1570nm is over -45dBm, which provide ~40dB dynamic range for an OSA based spectral measurement.
文摘通过对角化364×364完全能量矩阵的理论方法,对掺杂在Bi_(4)Ge_(3)O_(12)晶体中的Er^(3+)的Stark能级和EPR参数进行了研究,同时,定量分析了高阶晶体场混合效应和J-J混合效应对EPR g因子的影响。研究结果表明:对Er^(3+)来说,最主要的J-J混合效应来源于多重态谱项2 K 15/2,其对EPR g因子的贡献约占2.5%,而最主要的高阶晶体场混合效应来源于第一激发多重态^(4)I_(13/2)和基态多重态^(4)I_(15/2)之间的晶体场混合,其对各向异性g因子中g⊥的贡献大致是g//的两倍(即g⊥约占0.21%,g//约占0.092%),其他更高阶的晶体场混合和J-J混合效应可以忽略不计。因此,对于Er^(3+)掺杂的络合物系统来说,只考虑基态多重态4 I 15/2对EPR g因子的贡献应该是一个很好的近似。
文摘The （60 - x）Bi2O3 - xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated using the melting method. The thermal stability of the glasses was studied with their DTA curves. The results show that the difference between the glass transition temperature and the crystallization onset temperature increases with the increase of GeO2 content, indicating that the thermal stability of the glass has become better. The absorption spectra were recorded and the stimulated emission cross sections were calculated using the McCumber theory. The Ω2, O4, and Ω6 parameters,the transition probability, the radiative lifetime, and the fluorescence branch ratio of Er^3＋ for optical transition were calculated from their absorption spectra in terms of reduced matrix U^（t）（λ = 2, 4, 6） character for optical transitions. The infrared emission of Er^3＋ was measured upon excitation with 970 nm light and the full width at half-maximum （FWHM） was estimated from the emission spectra. The pumping efficiency and the intensity of the emission at the 1.54 μm band of Er^3＋ were enhanced considerably by co-doping Yb^3＋ .
文摘Cyclic electrodeposition was used to investigate the preparation of Er-Co-Bi alloy thin film in DMSO system. Experimental results indicate that Er-Co-Bi alloy thin film containing 14.83 %32.65 % Er is prepared from 0.1 mol/L ErCl3+0.1 mol/L CoCl2+0.1 mol/L Bi（NO3）3+0.1 mol/L LiCl +DMSO system by cyclic electrodeposition on Cu substrate. The optimum cyclic potential of electrodeposition is that upper potential is within a potential range from -0.50 V to -1.00 V and lower potential is within a potential range from -2.00 V to )-2.60 V.) The surface of alloy thin film observed by scanning electron microscope is black, adhesive and has metallic luster. The film is amorphous proved by the X-ray diffractometry.
文摘The （60 - x） Bi2O3-xGeO2-30B2O3-10ZnO （x = 5, 10, 20, 30 molar percent） glasses doped with Er^3＋ and Er^3＋/Yb^3＋ were fabricated by melting method. The thermal stability of the glasses was studied by their DTA curves. The results indicate that the difference between the glass transition temperature and the crystallization onset temperature increase as increase of GeO2 content, indicating that the thermal stability of the glass becomes better. The absorption spectra were recorded. The stimulated emission cross sections were calculated by McCumber theory. The Ω2, Ω4, and Ω6 parameters, transition probability, radiative lifetime, fluorescence branch ratio of Er^3＋ for optical transition were calculated from their absorption spectra in terms of reduced matrix U^（1）（λ = 2, 4, 6） character for optical transitions. The infrared emission was measured by excitation with 970 nm light and the FWHM was estimated from their emission spectra. The pumping efficiency and the intensity of emission at the band of 1.54 μm are enhanced greatly by addition of Y2O3.
