In the present work, the sulfur doped bismuth-based catalysts were prepared by incipient wetness impregnation method and used for the hydrochlorination of acetylene to vinyl chloride monomer （VCM） in a fixed-bed rea...In the present work, the sulfur doped bismuth-based catalysts were prepared by incipient wetness impregnation method and used for the hydrochlorination of acetylene to vinyl chloride monomer （VCM） in a fixed-bed reactor. The effect of introduction of S was characterized by N2 adsorption-desorption, powder X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, temperature-programmed reduction and X-ray photoelectron spectroscopy. The characterization results indicated that the doping of S resulted in the increase of Brunauer-Emmett-Teller （BET） surface areas and decrease of active species particle size for the Bi-based catalysts, which led to more accessible active sites, and consequently boosted the catalytic hydrochlorination activity. The effect of H2SO4 concentration on the activity of this type catalyst was examined, and the results showed that there is an optimal loading of H2SO4 （S/Bi=0.5 mol/mol）, at which the conversion of C2H2 was enhanced to 81% under the reaction condition and coke deposition is a main reason for the deactivation of catalyst.展开更多
The direct reductive amination of 2,5-diformylfuran (DFF) with ammonia to 2,5-bis(aminomethyl)furan (BAF) was demonstrated, for the first time, over the commercial type Nickel-Raney and acid treated Nickel-Raney catal...The direct reductive amination of 2,5-diformylfuran (DFF) with ammonia to 2,5-bis(aminomethyl)furan (BAF) was demonstrated, for the first time, over the commercial type Nickel-Raney and acid treated Nickel-Raney catalysts. The effects of reaction parameters such as reaction medium, temperature and hydrogen pressure were described. The acid treated Nickel-Raney catalyst exhibited the highest BAF yield in the THF-water mixed reaction medium. The relatively higher Ni0 species composition and larger surface area of the acid treated Nickel-Raney catalyst with specific reaction conditions contributed greatly to the BAF formation. The oligomeric species, such as furanic imine trimers and tetramers confirmed by MALDI-MS analysis were presented as the intermediates of DFF reductive amination.展开更多
基金supported by the National Natural Science Foundation of China(Nos.U1403293,21263025)the Graduate Research and Innovation Program of Xinjiang(No.XJGRI2015010)
文摘In the present work, the sulfur doped bismuth-based catalysts were prepared by incipient wetness impregnation method and used for the hydrochlorination of acetylene to vinyl chloride monomer （VCM） in a fixed-bed reactor. The effect of introduction of S was characterized by N2 adsorption-desorption, powder X-ray diffraction, transmission electron microscopy, thermogravimetric analysis, temperature-programmed reduction and X-ray photoelectron spectroscopy. The characterization results indicated that the doping of S resulted in the increase of Brunauer-Emmett-Teller （BET） surface areas and decrease of active species particle size for the Bi-based catalysts, which led to more accessible active sites, and consequently boosted the catalytic hydrochlorination activity. The effect of H2SO4 concentration on the activity of this type catalyst was examined, and the results showed that there is an optimal loading of H2SO4 （S/Bi=0.5 mol/mol）, at which the conversion of C2H2 was enhanced to 81% under the reaction condition and coke deposition is a main reason for the deactivation of catalyst.
文摘The direct reductive amination of 2,5-diformylfuran (DFF) with ammonia to 2,5-bis(aminomethyl)furan (BAF) was demonstrated, for the first time, over the commercial type Nickel-Raney and acid treated Nickel-Raney catalysts. The effects of reaction parameters such as reaction medium, temperature and hydrogen pressure were described. The acid treated Nickel-Raney catalyst exhibited the highest BAF yield in the THF-water mixed reaction medium. The relatively higher Ni0 species composition and larger surface area of the acid treated Nickel-Raney catalyst with specific reaction conditions contributed greatly to the BAF formation. The oligomeric species, such as furanic imine trimers and tetramers confirmed by MALDI-MS analysis were presented as the intermediates of DFF reductive amination.
