It is found that the core-shell structured grains are easy to produce for fine grain doped BaTiO3 ceramics in the sintering process. We study the influence of the core-shell structure on the Curie-Weiss temperature an...It is found that the core-shell structured grains are easy to produce for fine grain doped BaTiO3 ceramics in the sintering process. We study the influence of the core-shell structure on the Curie-Weiss temperature and dielectric properties of BaTiO3 ceramics by using effective medium approximation (EMA). Considering the second approximation, the dielectric properties of fine grain doped BaTiO3 ceramics are consistent with experimental data.展开更多
BaTiO3/epoxy composites consisting of two three-dimensionally interpenetrating networks of BaTiO3 and epoxy phases were prepared using a new approach. The BaTiO3/epoxy composites exhibit a colossal dielectric constant...BaTiO3/epoxy composites consisting of two three-dimensionally interpenetrating networks of BaTiO3 and epoxy phases were prepared using a new approach. The BaTiO3/epoxy composites exhibit a colossal dielectric constant, low dielectric loss and high flexural strength. In the BaTiO3 networks, chemically bonded grain boundaries between neighboring BaTiO3 grains were established, and they are responsible for the colossal dielectric constant and high flexural strength of the BaTiO3/epoxy composites. Furthermore, unlike the conventional ceramic/polymer composites, this approach also makes high loadings of BaTiO3 contents possible for the BaTiO3/epoxy composites without compromising their high flexural strength.展开更多
基金supported by the Natural Science Foundation of Shanxi Province,China(Grant No.2012011028-2)
文摘It is found that the core-shell structured grains are easy to produce for fine grain doped BaTiO3 ceramics in the sintering process. We study the influence of the core-shell structure on the Curie-Weiss temperature and dielectric properties of BaTiO3 ceramics by using effective medium approximation (EMA). Considering the second approximation, the dielectric properties of fine grain doped BaTiO3 ceramics are consistent with experimental data.
基金Funded by the National Natural Science Foundation of China(Nos.21571095 and 51362020)the Jiangxi Provincial Department of Education(KJLD13008)
文摘BaTiO3/epoxy composites consisting of two three-dimensionally interpenetrating networks of BaTiO3 and epoxy phases were prepared using a new approach. The BaTiO3/epoxy composites exhibit a colossal dielectric constant, low dielectric loss and high flexural strength. In the BaTiO3 networks, chemically bonded grain boundaries between neighboring BaTiO3 grains were established, and they are responsible for the colossal dielectric constant and high flexural strength of the BaTiO3/epoxy composites. Furthermore, unlike the conventional ceramic/polymer composites, this approach also makes high loadings of BaTiO3 contents possible for the BaTiO3/epoxy composites without compromising their high flexural strength.