The temperature-dependent photoluminescence （PL） spectra of Baln204, prepared by coprecipitation, are measured and discussed. Aside from the reported 3.02-eV violet emission, the 1.81-eV yellow emission in- volved w...The temperature-dependent photoluminescence （PL） spectra of Baln204, prepared by coprecipitation, are measured and discussed. Aside from the reported 3.02-eV violet emission, the 1.81-eV yellow emission in- volved with oxygen vacancy is also observed at room temperature wherein the deep donor level is at 1.2 eV. With the temperature increasing, the peak energies for both emissions show a red shift. Moreover, the yel- low emission intensity decreases while the violet emission intensity increases. The temperature dependence of the yellow emission intensity fits very well into the one-step quenching process equation, indicating a fitted activation energy at 19.2 meV.展开更多
基金supported by the National "973" Program of China (No.2010CB933700)the National Natural Science Foundation of China (Nos.10804117 and 60221502)+1 种基金the Shanghai Natural Science Foundation(No.08ZR1421900)the Knowledge Innovation Program of the Chinese Academy of Sciences
文摘The temperature-dependent photoluminescence （PL） spectra of Baln204, prepared by coprecipitation, are measured and discussed. Aside from the reported 3.02-eV violet emission, the 1.81-eV yellow emission in- volved with oxygen vacancy is also observed at room temperature wherein the deep donor level is at 1.2 eV. With the temperature increasing, the peak energies for both emissions show a red shift. Moreover, the yel- low emission intensity decreases while the violet emission intensity increases. The temperature dependence of the yellow emission intensity fits very well into the one-step quenching process equation, indicating a fitted activation energy at 19.2 meV.
