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白光LED用Ba_2LaF_7:Pr^(3+)微晶玻璃的发光性能研究 被引量:1
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作者 张志雄 欧阳绍业 +1 位作者 张约品 夏海平 《无机材料学报》 SCIE EI CAS CSCD 北大核心 2016年第10期1046-1050,共5页
采用高温熔制法制备得到50SiO_2-10AlF_3-5TiO_2-30BaF_2-4La F_3-Pr_2O_3(mol%)基质玻璃,玻璃样品分别经640℃、660℃和690℃热处理后,成功获得透明Ba_2LaF_7:Pr^(3+)微晶玻璃且维持着较高的透明度。用XRD和TEM分析热处理前后样品的相... 采用高温熔制法制备得到50SiO_2-10AlF_3-5TiO_2-30BaF_2-4La F_3-Pr_2O_3(mol%)基质玻璃,玻璃样品分别经640℃、660℃和690℃热处理后,成功获得透明Ba_2LaF_7:Pr^(3+)微晶玻璃且维持着较高的透明度。用XRD和TEM分析热处理前后样品的相变和结构变化,并研究了热处理前后样品的光谱特性。结果表明:玻璃经热处理后生成了Ba_2LaF_7微晶颗粒;热处理前后样品光谱特性的变化表明:热处理后掺杂的Pr^(3+)离子逐渐进入到Ba_2LaF_7晶格位;在波长443 nm的激发下,660℃热处理过的样品实现了白光输出,对应的三色坐标为(0.323,0.343)。 展开更多
关键词 ba2laf7:Pr^3+ 微晶玻璃 发光性能
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Near-white light-emitting Dy^(3+)-doped transparent glass ceramics containing Ba_2LaF_7 nanocrystals 被引量:3
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作者 欧阳绍业 张为欢 +2 位作者 张志雄 张约品 夏海平 《Chinese Optics Letters》 SCIE EI CAS CSCD 2015年第9期58-61,共4页
Glass ceramics Ba2LaFT:xDy3+ are obtained through the conventional melt-quenching technique, and their lu- minescent properties are investigated. Under 350 nm excitation, the emission spectra consists of a strong bl... Glass ceramics Ba2LaFT:xDy3+ are obtained through the conventional melt-quenching technique, and their lu- minescent properties are investigated. Under 350 nm excitation, the emission spectra consists of a strong blue- yellow band as well as a weak red emission centered at 660 nm, which are attributed to the 4F9/2 →6H15/2, 4F9/2→6H13/2 and 4F9/2 → 6Hll/2 transitions of the Dy3+ ion, respectively. The corresponding Commission Internationale de L'Eclairage (CIE) chromaticity coordinate for a sample of 2 mol.% Dy203 after being heat-treated at 690℃ is (0.313, 0.328). It is concluded that the formed materials may have the possibility of applications for white light-emitting diodes (LEDs). 展开更多
关键词 BA La Near-white light-emitting Dy doped transparent glass ceramics containing ba2laf7 nanocrystals LEDs
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