The Bozhong19-6(BZ19-6)condensate gas reservoirs,located in the southwestern Bozhong sub-basin,Bohai Bay Basin,China,were paleo-oil reservoirs in the geological past and have undergone at least three successive hydroc...The Bozhong19-6(BZ19-6)condensate gas reservoirs,located in the southwestern Bozhong sub-basin,Bohai Bay Basin,China,were paleo-oil reservoirs in the geological past and have undergone at least three successive hydrocarbon charging events.The hydrocarbon migration and accumulation process of“early oil and late gas”has occurred in the current reservoirs.At the end of the sedimentation of the Guantao Formation(N_(1)g,∼12 Ma),the reservoirs began to fill with first stage low-moderate mature crude oil.At the late stage of the Lower Minghuazhen Formation(N_(1)ml)(∼6.7 Ma),the reservoirs were largely charged with second stage high mature crude oil.Since the deposition of the upper Minghuazhen Formation(N_(2)m^(u),∼5.1 Ma),the paleo-oil reservoirs were transformed into shallow Neogene reservoirs due to the reactivation of basement faults.From the late stage of the N_(2)m^(u)to the present day(∼2.8–0 Ma),the reservoirs were rapidly filled by natural gas within a short period.In addition,analysis of the formation of the reservoir bitumen and the conspicuous loss of the lower molecular weight n-alkanes in the crude oil reveal that the injection of a large amount of gas in the late stage caused gas flushing of the early charged oil.展开更多
The BZ19-6 deep buried-hill structural belt in the southwest of Bozhong Sag,Bohai Bay Basin,is a newly discovered super-giant oil and gas bearing area.The study on its reservoirs is still in the early stage,and the ch...The BZ19-6 deep buried-hill structural belt in the southwest of Bozhong Sag,Bohai Bay Basin,is a newly discovered super-giant oil and gas bearing area.The study on its reservoirs is still in the early stage,and the characteristics and control factors of reservoir development are not understood deeply.In this paper,cores,sidewall cores,rock sections were analyzed and described.Then,based on regional structural setting,mud logging and logging data,the buried-hill reservoirs in this area were analyzed from the aspects of petrological characteristics,reservoir space types and physical properties,the inherent factors influencing the development of the reservoirs were discussed,and distribution laws of the reservoirs were investigated.And the following research results were obtained.First,the deep buried-hill reservoirs of this belt are a pan-buried hill reservoir system composed of the Palaeocene-Eocene Kongdian Fm glutenite in the upper part and the Archean buried-hill metamorphic granite in the lower part.A multi-layer reservoir structure of glutenite pore zone,weathering crust dissolution fracture zone and inner fracture zone is formed.These reservoirs are complex in genesis and diverse in type.Second,the Archean buried-hill metamorphic granite reservoir can be vertically divided into weathering crust,inner fracture zone and tight zone,and it presents the dual characteristics of porous and fractured media.Third,the buried-hill weathering crust is mainly affected by strong dissolution and leaching superimposed with fracturing,forming fractured-porous reservoir space.The reservoir of inner fracture zone is mainly controlled by the superimposition of three-phrase fractures,which forms the main development period of buried-hill fractures since the Yanshanian.Fourth,the glutenite of Kongdian Fm is a typical sieve deposit and it is mainly controlled by the late dissolution.Fifth,migmatization and supercritical fluid cryptoexplosion play a constructive role in the development of the reservoirs.In conclusion,the understanding of buried-hill glutenite and metamorphic reservoir system developed in this belt is conductive to determining the target and direction of next oil and gas exploration in this area.展开更多
Cp;ZrCl（S;CNBz;） is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549（1）A; Zr-C 2.489-2.533; Zr-S 2.667（1）, 2.734（1）; Zr-Cl-S1 137.6（1）;; Zr-Cl-S2 73....Cp;ZrCl（S;CNBz;） is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549（1）A; Zr-C 2.489-2.533; Zr-S 2.667（1）, 2.734（1）; Zr-Cl-S1 137.6（1）;; Zr-Cl-S2 73.3（1）;).展开更多
(CH_3C_5H_4)Zr(S_2CNBz_2)_3, Mr=987.55, space group P1, a=13.002(4), b=13.659(3), c=29.685(8); α=100.72(2)~o,β=97.23(2)~o, γ=105.36(2)~o; V=4909(2)~3, Z=4, Dc=1.34gcm^(-3), Mo-K(λ=0.71073A) radiation, μ=5.0cm^(-1...(CH_3C_5H_4)Zr(S_2CNBz_2)_3, Mr=987.55, space group P1, a=13.002(4), b=13.659(3), c=29.685(8); α=100.72(2)~o,β=97.23(2)~o, γ=105.36(2)~o; V=4909(2)~3, Z=4, Dc=1.34gcm^(-3), Mo-K(λ=0.71073A) radiation, μ=5.0cm^(-1), R=0.069, Rw=0.078 for 6100 reflections. The title complex has pentagonal bipyramid configuration in which the zirconium atom is coordinated by one CH_3C_5H_4 group and three bidentate dibenzyldithiocarbamate ligands.展开更多
A large gas field with reserves of nearly 200 billion m^(3)dBZ19-6dwas discovered in the Bozhong Depression in the Bohai Bay Basin in 2018.There is a considerable difference between the amount of natural gas that woul...A large gas field with reserves of nearly 200 billion m^(3)dBZ19-6dwas discovered in the Bozhong Depression in the Bohai Bay Basin in 2018.There is a considerable difference between the amount of natural gas that would traditionally be expected to be generated by the thermal degradation of low-mature kerogens and the resources that have been confirmed by exploration.Therefore,the geochemical characteristics and the genesis of gas have become crucial aspects of investigating deep natural gas in the Bozhong Depression.The deep gas in the depression is predominantly methane.Its dry coefficient(C_(1)/C_(1-5))ranges from 0.73 to 0.94,which is generally characterized as wet gas.The main nonhydrocarbon gases are CO_(2)(1.26%-52.00%)and N_(2)(0.1%-0.74%),with traces of H_(2)S(10.44×10^(-6)-36.63×10^(-6) ppm).The natural gases are thermogenic oil-type gases from the Shahejie and Dongying Formations.The deep natural gas in the Bozhong Depression is mainly derived from kerogen degradation,with contributions from oil cracking gas in the BZ1/19 and BZ2/3 structures.Complex carbon isotopic reversals are caused by the filling and mixing of natural gas with different maturities from the same source,evaporative fractionation due to the filling of late-stage high-mature natural gas,and Rayleigh fractionation under deep exogenous temperatures in the presence of transition metals.Combining the analysis of the fluid properties of natural gas,the evaluation of the performance of the migration system,and the understanding of the accumulation background indicates a high possibility that the gas was supplied from multiple hydrocarbon sources over long distances in the late stage.Thus,advantageous traps with high temperatures,close proximity to source kitchens,and favorable migration conditions are the preferred targets for future natural gas exploration in the Bozhong Depression.展开更多
基金supported by the National Science&Technology Specific Project,China(No.2016ZX05024-003-008).
文摘The Bozhong19-6(BZ19-6)condensate gas reservoirs,located in the southwestern Bozhong sub-basin,Bohai Bay Basin,China,were paleo-oil reservoirs in the geological past and have undergone at least three successive hydrocarbon charging events.The hydrocarbon migration and accumulation process of“early oil and late gas”has occurred in the current reservoirs.At the end of the sedimentation of the Guantao Formation(N_(1)g,∼12 Ma),the reservoirs began to fill with first stage low-moderate mature crude oil.At the late stage of the Lower Minghuazhen Formation(N_(1)ml)(∼6.7 Ma),the reservoirs were largely charged with second stage high mature crude oil.Since the deposition of the upper Minghuazhen Formation(N_(2)m^(u),∼5.1 Ma),the paleo-oil reservoirs were transformed into shallow Neogene reservoirs due to the reactivation of basement faults.From the late stage of the N_(2)m^(u)to the present day(∼2.8–0 Ma),the reservoirs were rapidly filled by natural gas within a short period.In addition,analysis of the formation of the reservoir bitumen and the conspicuous loss of the lower molecular weight n-alkanes in the crude oil reveal that the injection of a large amount of gas in the late stage caused gas flushing of the early charged oil.
基金supported by the National Major Science and Technology Project“Comprehensive Study on Buried-Hill Reservoir-Forming in the Bohai Sea and Favorable Exploration Direction”(No.:2016ZX05024-003-010)the Scientific Research Project of CNOOC“Petroleum Geological Characteristics,Forming Mechanism of Typical Oil&Gas Reservoir and Prediction of Prospects of the Buried Hill in the Bohai Sea Area”(No.:CCL2014TJXZSS0870).
文摘The BZ19-6 deep buried-hill structural belt in the southwest of Bozhong Sag,Bohai Bay Basin,is a newly discovered super-giant oil and gas bearing area.The study on its reservoirs is still in the early stage,and the characteristics and control factors of reservoir development are not understood deeply.In this paper,cores,sidewall cores,rock sections were analyzed and described.Then,based on regional structural setting,mud logging and logging data,the buried-hill reservoirs in this area were analyzed from the aspects of petrological characteristics,reservoir space types and physical properties,the inherent factors influencing the development of the reservoirs were discussed,and distribution laws of the reservoirs were investigated.And the following research results were obtained.First,the deep buried-hill reservoirs of this belt are a pan-buried hill reservoir system composed of the Palaeocene-Eocene Kongdian Fm glutenite in the upper part and the Archean buried-hill metamorphic granite in the lower part.A multi-layer reservoir structure of glutenite pore zone,weathering crust dissolution fracture zone and inner fracture zone is formed.These reservoirs are complex in genesis and diverse in type.Second,the Archean buried-hill metamorphic granite reservoir can be vertically divided into weathering crust,inner fracture zone and tight zone,and it presents the dual characteristics of porous and fractured media.Third,the buried-hill weathering crust is mainly affected by strong dissolution and leaching superimposed with fracturing,forming fractured-porous reservoir space.The reservoir of inner fracture zone is mainly controlled by the superimposition of three-phrase fractures,which forms the main development period of buried-hill fractures since the Yanshanian.Fourth,the glutenite of Kongdian Fm is a typical sieve deposit and it is mainly controlled by the late dissolution.Fifth,migmatization and supercritical fluid cryptoexplosion play a constructive role in the development of the reservoirs.In conclusion,the understanding of buried-hill glutenite and metamorphic reservoir system developed in this belt is conductive to determining the target and direction of next oil and gas exploration in this area.
文摘Cp;ZrCl（S;CNBz;） is a five-coordinate bent zirconocene in which the dibenzyldithiocarbamate is a bidentate ligand (Zr-Cl 2.549（1）A; Zr-C 2.489-2.533; Zr-S 2.667（1）, 2.734（1）; Zr-Cl-S1 137.6（1）;; Zr-Cl-S2 73.3（1）;).
文摘(CH_3C_5H_4)Zr(S_2CNBz_2)_3, Mr=987.55, space group P1, a=13.002(4), b=13.659(3), c=29.685(8); α=100.72(2)~o,β=97.23(2)~o, γ=105.36(2)~o; V=4909(2)~3, Z=4, Dc=1.34gcm^(-3), Mo-K(λ=0.71073A) radiation, μ=5.0cm^(-1), R=0.069, Rw=0.078 for 6100 reflections. The title complex has pentagonal bipyramid configuration in which the zirconium atom is coordinated by one CH_3C_5H_4 group and three bidentate dibenzyldithiocarbamate ligands.
文摘A large gas field with reserves of nearly 200 billion m^(3)dBZ19-6dwas discovered in the Bozhong Depression in the Bohai Bay Basin in 2018.There is a considerable difference between the amount of natural gas that would traditionally be expected to be generated by the thermal degradation of low-mature kerogens and the resources that have been confirmed by exploration.Therefore,the geochemical characteristics and the genesis of gas have become crucial aspects of investigating deep natural gas in the Bozhong Depression.The deep gas in the depression is predominantly methane.Its dry coefficient(C_(1)/C_(1-5))ranges from 0.73 to 0.94,which is generally characterized as wet gas.The main nonhydrocarbon gases are CO_(2)(1.26%-52.00%)and N_(2)(0.1%-0.74%),with traces of H_(2)S(10.44×10^(-6)-36.63×10^(-6) ppm).The natural gases are thermogenic oil-type gases from the Shahejie and Dongying Formations.The deep natural gas in the Bozhong Depression is mainly derived from kerogen degradation,with contributions from oil cracking gas in the BZ1/19 and BZ2/3 structures.Complex carbon isotopic reversals are caused by the filling and mixing of natural gas with different maturities from the same source,evaporative fractionation due to the filling of late-stage high-mature natural gas,and Rayleigh fractionation under deep exogenous temperatures in the presence of transition metals.Combining the analysis of the fluid properties of natural gas,the evaluation of the performance of the migration system,and the understanding of the accumulation background indicates a high possibility that the gas was supplied from multiple hydrocarbon sources over long distances in the late stage.Thus,advantageous traps with high temperatures,close proximity to source kitchens,and favorable migration conditions are the preferred targets for future natural gas exploration in the Bozhong Depression.
