Reaction of phenols and activated aromatics with 1-butyl-3-methylimidazolium tribromide [（Bmim）Br3] under solvent-free conditions gave selectively the corresponding monobromination products in excellent yields.
Self-powered and flexible ultrabroadband photodetectors(PDs)are desirable in a wide range of applications.The current PDs based on the photothermoelectric(PTE)effect have realized broadband photodetection.However,most...Self-powered and flexible ultrabroadband photodetectors(PDs)are desirable in a wide range of applications.The current PDs based on the photothermoelectric(PTE)effect have realized broadband photodetection.However,most of them express low photoresponse and lack of flexibility.In this work,high-performance,self-powered,and flexible PTE PDs based on laser-scribed reduced graphene oxide(LSG)∕CsPbBr3 are developed.The comparison experiment with LSG PD and fundamental electric properties show that the LSG∕CsPbBr3 device exhibits enhanced ultrabroadband photodetection performance covering ultraviolet to terahertz range with high photoresponsivity of 100 mA/W for 405 nm and 10 mA/W for 118μm at zero bias voltage,respectively.A response time of 18 ms and flexible experiment are also acquired at room temperature.Moreover,the PTE effect is fully discussed in the LSG∕CsPbBr3 device.This work demonstrates that LSG∕CsPbBr3 is a promising candidate for the construction of high-performance,flexible,and self-powered ultrabroadband PDs at room temperature.展开更多
Lead halide perovskites attracted a lot of attention in the last several years,with a focus gradually shifting from the record power conversion efficiencies reported for photovoltaic devices based on thin perovskite f...Lead halide perovskites attracted a lot of attention in the last several years,with a focus gradually shifting from the record power conversion efficiencies reported for photovoltaic devices based on thin perovskite films[1]towards superior展开更多
基金Project supported by the Science Foundation of Jiangxi Province （No. 0520001） and the Science and Technology Foundation of the Education Department of Jiangxi Province.
文摘Reaction of phenols and activated aromatics with 1-butyl-3-methylimidazolium tribromide [（Bmim）Br3] under solvent-free conditions gave selectively the corresponding monobromination products in excellent yields.
基金National Natural Science Foundation of China(61605141,61675147,61735010,91838301)National Key Research and Development Program of China(2017YFA0700202)+1 种基金Basic Research Program of Shenzhen(JCYJ20170412154447469)Beiyang Young Junior faculties of Tianjin University(2019XRG-0056).
文摘Self-powered and flexible ultrabroadband photodetectors(PDs)are desirable in a wide range of applications.The current PDs based on the photothermoelectric(PTE)effect have realized broadband photodetection.However,most of them express low photoresponse and lack of flexibility.In this work,high-performance,self-powered,and flexible PTE PDs based on laser-scribed reduced graphene oxide(LSG)∕CsPbBr3 are developed.The comparison experiment with LSG PD and fundamental electric properties show that the LSG∕CsPbBr3 device exhibits enhanced ultrabroadband photodetection performance covering ultraviolet to terahertz range with high photoresponsivity of 100 mA/W for 405 nm and 10 mA/W for 118μm at zero bias voltage,respectively.A response time of 18 ms and flexible experiment are also acquired at room temperature.Moreover,the PTE effect is fully discussed in the LSG∕CsPbBr3 device.This work demonstrates that LSG∕CsPbBr3 is a promising candidate for the construction of high-performance,flexible,and self-powered ultrabroadband PDs at room temperature.
文摘Lead halide perovskites attracted a lot of attention in the last several years,with a focus gradually shifting from the record power conversion efficiencies reported for photovoltaic devices based on thin perovskite films[1]towards superior
