In this paper,the Ni/Al_(2)O_(3) monolithic catalyst with 15%Ni content was prepared using cordierite as a matrix,and the catalyst was modified with 10%NaOH to study the methanation performance of biomass gasification...In this paper,the Ni/Al_(2)O_(3) monolithic catalyst with 15%Ni content was prepared using cordierite as a matrix,and the catalyst was modified with 10%NaOH to study the methanation performance of biomass gasification simulated gas based on alkali-modified Ni/Al_(2)O_(3) monolithic catalyst.BET,TEM,H_(2)-TPR,XRD,CO_(2)-TPD and TG were used to characterize the physicochemical properties of the catalyst before and after modification.The results indicated that the CO conversion rate trends of unmodified and modified Ni/Al_(2)O_(3) monolithic catalysts over 2 h were fundamentally consistent.However,the Ni/Al_(2)O_(3) catalysts modified for 2 h demonstrated significantly enhanced performance compared to those modified for 1 h.Regarding CH4 selectivity,the modified Ni/Al_(2)O_(3) catalyst exhibited markedly better performance than the unmodified Ni/Al_(2)O_(3) catalyst,confirming the enhanced methane performance of the alkali-modified Ni/Al_(2)O_(3) monolithic catalyst.Under optimized conditions(H_(2)/CO volume ratio of 3∶1,space velocity of 10000 mL/(g·h),and temperature of 400℃),the methanation performance of the Ni/Al_(2)O_(3) monolithic catalyst modified for 2 h reached its peak,achieving a CO conversion rate of 97%with 100%CH4 selectivity.展开更多
Biomass-based hydrocarbon fuels,as one of the alternatives to traditional fossil fuels,have attracted considerable attention in the energy field due to their renewability and environmental benefits.This article provid...Biomass-based hydrocarbon fuels,as one of the alternatives to traditional fossil fuels,have attracted considerable attention in the energy field due to their renewability and environmental benefits.This article provides a systematic review of recent research progress in the chemical synthesis of biomass-based hydrocarbon fuels.It outlines the conversion pathways using feedstocks such as lipids,terpenoids,cellulose/hemicellulose,and lignin.Depending on the feedstock,various products with distinct structural characteristics can be prepared through reactions such as cyclization,condensation,and catalytic hydrogenation.Throughout the synthesis process,three key factors play a critical role:efficient catalyst development,production process optimization,and computational-chemistry-based molecular design.Finally,the article discusses future perspectives for biomass-based hydrocarbon fuel synthesis research.展开更多
Converting biomass to syngas(CO+H_(2))is an accessible way to incorporate renewable carbon into the sustainable chemical industry.However,due to insufficient C–C bond breaking even at high temperature,biomass reformi...Converting biomass to syngas(CO+H_(2))is an accessible way to incorporate renewable carbon into the sustainable chemical industry.However,due to insufficient C–C bond breaking even at high temperature,biomass reforming produces syngas with a reduced yield accompanied by the formation of tar,char,and complex side-products.Herein,irradiation of perovskite La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.75)Ru_(0.05)O_(3-δ)(LSCFR)by concentrated sunlight activates thermodynamically stable lattice oxygen,thereby increasing the fraction of activated lattice oxygen from 12%to 43%.This enhanced oxidation ability enables biomass conversion to CO_x in 96%yield alongside H_(2) production.Sunlight irradiation also facilitates lattice oxygen replenishment via CO_(2) reduction,allowing dry photoreforming of biomass over LSCFR.In a flow apparatus,the dry photoreforming affords CO and H_(2) in 80%and 41%yields,respectively,producing 0.15 and 0.06 m~3 of CO and H_(2) in 20 h.This work reveals the light-responsive oxidation ability of oxides for the sustainable refining of native biomass.展开更多
Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of...Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field.展开更多
Optically pure chiral chemicals are important building blocks with widespread applications across mul-tiple scientific and industrial do-mains such as in pharmaceuticals,agrochemicals,and food,especially acting as pre...Optically pure chiral chemicals are important building blocks with widespread applications across mul-tiple scientific and industrial do-mains such as in pharmaceuticals,agrochemicals,and food,especially acting as precursors to synthesize biodegradable polymers.As an al-ternative to fossil resources,renew-able lignocellulosic biomass has been used to access chiral chemicals,due to the versatile inherent stere-ostructures and multiple functional groups,such as hydroxyl,carbonyl,and phenyl ether groups.Typically,as the two main units of(hemi)cel-lulose components in lignocellulosic biomass,D-xylose and D-glucose bear multiple chiral centers(e.g.,2R-3S-4R for D-xylose and 2R-3S-4R-5R for D-glucose).Lignin bearsβ-O-4 linkages,exhibiting(R,S/S,R)or(R,R/S,S)stereocenters at the side-chainαandβcarbon atoms.The valorization of biomass into optical-ly pure chiral chemicals is vital for developing a more sustainable future.This review discuss-es the production of typical chiral chemicals derived from biomass through chemocatalysis,including lactones(e.g.,R/S-valerolactone),carboxylic acids(e.g.,D/L-glyceric acid,D/L-lactic acid),polyols(e.g.,tetrose),furans,oligosaccharides,and others.Two strategies are generally employed.One approach involves first producing achiral platform chemicals from biomass,followed by the introduction of asymmetric catalysts to reconstruct stereocenters.The second relates to selectively preserving one or more inherent stereocenters in the natural biomass structure during complex cascade reactions in which biomass feedstock acts as a“chi-ral pool",thus eliminating the establishment of stereocenter.The feedstock,methods em-ployed,and enantioselectivity and applications of the target chiral chemicals are discussed.Despite these advances,the synthesis of optically pure chemicals from biomass is still in its in-fancy.The coming decade presents both extraordinary challenges and opportunities in biomass-derived chiral chemistry.Future research should be focused on:(1)integrating well-established asymmetric catalysis techniques and methods with biomass’s inherent chiral pools,presenting an unprecedented opportunity to expand the chemical space of sustainable chiral compounds;(2)mastering polyfunctional complexity of chiral chemicals through holis-tic utilization of biomass’multichiral centers;(3)unlocking lignin’s stereochemical treasury that represents the next frontier in biomass valorization.展开更多
The increasing scarcity of freshwater resources has driven the rapid emergence of solar-driven interfacial evaporators(SDIEs)as a sustainable approach to harvest fresh water by utilizing solar energy.Lignocellulosic b...The increasing scarcity of freshwater resources has driven the rapid emergence of solar-driven interfacial evaporators(SDIEs)as a sustainable approach to harvest fresh water by utilizing solar energy.Lignocellulosic biomass,featuring natural abundance,excellent renewability,unique natural structures,and superior biodegradability compared to the synthetic polymers,is highly attractive for constructing solar steam generators.This review aims to offer an innovative and in-depth insight into designing and optimizing highperformance integrated solar interfacial evaporators derived from renewable lignocellulosic biomass.First,the structural characteristics of lignocellulosic biomass are briefly introduced,serving as photothermal layer or supporting substrates in SDIEs.Secondly,the fabrication methods and processing technologies of lignocellulosic biomass-based evaporators are summarized from the perspective of photothermal layer and supporting substrates.Next,the most recent advances of regulation and optimization strategies are proposed to improve evaporation efficiency.Subsequently,this review summarizes the diverse functionalities of SDIEs,including desalination,power generation,wastewater treatment and antimicrobial,atmospheric water harvesting,and photocatalytic hydrogen production.Finally,the challenges in this field and outlook on the future development are discussed,which are anticipated to provide new opportunities for the advancement of lignocellulosic biomass-based SDIEs.展开更多
Subtropical evergreen sub-montane forests in Punjab,Pakistan,are vital for carbon sequestration and play an essential role in supporting local communities.While the global importance of tree species diversity in enhan...Subtropical evergreen sub-montane forests in Punjab,Pakistan,are vital for carbon sequestration and play an essential role in supporting local communities.While the global importance of tree species diversity in enhancing aboveground carbon(AGC)storage is well established,there remains limited empirical evidence from Pakistan’s forest ecosystems.This study investigated how taxonomic and functional diversity,alongside topographical variables,influence AGC across four districts in Punjab.Taxonomic metrics such as the Importance Value Index(IVI)and genus richness were computed,along with functional diversity indices including functional richness(FRic),functional dispersion(FDis),functional divergence(FDiv),and functional evenness(FEve).AGC was estimated using species-specific allometric equations,and linear mixed-effects models were applied to identify the most influential predictors.Acacia modesta and A.nilotica emerged as the dominant species in the studied sites.While species richness and biomass increased with elevation,Shannon diversity showed a negative relationship with elevation.AGC values ranged from 100 to 350 Mg ha⁻¹across the study sites.Among diversity metrics,FRic(0.042)and FDis(0.342)were significantly associated with higher AGC,whereas taxonomic diversity measures showed weaker correlations.Although elevation was a strong predictor of diversity patterns,it did not have a significant direct effect on carbon storage.These findings underscore the importance of incorporating functional trait diversity and topographic variability into forest management strategies to enhance carbon sequestration,strengthen ecosystem resilience and support sustainable rural livelihoods.展开更多
Many adsorbents have been developed for uranium recovery to ensure global energy and environmental security.However,most reported adsorbents involve complex preparation process and rely heavily on petrochemical feedst...Many adsorbents have been developed for uranium recovery to ensure global energy and environmental security.However,most reported adsorbents involve complex preparation process and rely heavily on petrochemical feedstocks,which undoubtedly increases carbon emissions from production in the nuclear industry.Here,a biomass aerogel(CS-BT)is prepared by the facile cross-linking of chitosan and bayberry tannins with glutaraldehyde.U(Ⅵ)can be adsorbed by hydroxyl groups on CS-BT aerogel via chelation,and the maximum adsorption capacity of the obtained aerogel to U(Ⅵ)is 140 mg·g^(-1)and the removal rate reaches up to 99%(at 298.15 K,pH=5.0).The pseudo-second-order kinetics model and Freundlich model can better match the adsorption process of CS-BT aerogel,implying that its adsorption is a chemical adsorption process dominated by multilayer adsorption.The thermodynamic results show that the adsorption process of U(Ⅵ)by CS-BT aerogel is spontaneous and exothermic.Hence,our biomass aerogel can effectively extract uranium from water,contributing to the sustainable development of the nuclear industry.展开更多
The root-to-shoot(R/S)ratio is a critical indicator of the balance between root biomass and shoot biomass,representing the ecological strategies and adaptive responses of plants to environmental conditions.However,the...The root-to-shoot(R/S)ratio is a critical indicator of the balance between root biomass and shoot biomass,representing the ecological strategies and adaptive responses of plants to environmental conditions.However,the patterns of change in community R/S ratios during forest succession and their response to moisture levels across broad geographic gradients remains unclear.Based on forest biomass data from a national field inventory of 5,825 plots conducted across China between 2011 and 2015,this study looked into allocating biomass shoots and roots at the early,middle,and late stages of growth in plantations and succession in natural forests,and evaluated how moisture availability influences this allocation.The results revealed a significant decline in R/S ratios from early to late stages for both plantations and natural forests.Shoot and root biomass in plantations grew isometrically during the early and middle succession stages but shifted to allometric growth in the late stage,with the slope of the log-transformed shoot-root biomass relationship differing significantly across growth stages.Natural forests,in contrast,maintained isometric growth across successional stages,showing no significant variation in the slope of the log-transformed shoot-root biomass relationship.Environmental factors,particularly moisture levels,strongly influenced R/S ratios.Moisture levels significantly affected size-corrected R/S ratios,particularly in the middle stage of plantations and the early and middle stages of natural forests,supporting the hypothesis of optimal allocation.These findings suggest that in water-limited regions,forest management should prioritize drought-tolerant,deep-rooted native species,encourage mixed-species planting in the early stage,and reduce logging intensity in mature plantations.Conserving natural forests to maintain successional dynamics is essential for long-term ecological resilience.These findings emphasize the importance of balancing productivity with ecological sustainability by adapting practices to specific environments and forest types under climate change.展开更多
Lignocellulosic biomass is the most abundant re-newable resource on Earth,boasting advan-tages such as wide avail-ability and negative car-bon emissions.Especial-ly,efficient separation of lignocellulose into cellu-lo...Lignocellulosic biomass is the most abundant re-newable resource on Earth,boasting advan-tages such as wide avail-ability and negative car-bon emissions.Especial-ly,efficient separation of lignocellulose into cellu-lose,hemicellulose and lignin,and realizing val-orization of these compo-nents are more responsive to the development needs of biomass refinery and the green chem-istry era.This review outlines the main components of lignocellulose and briefly summerizes their utilization in chemical raw materials and energy production.It mainly focused on cur-rent advances in component separation methods of lignocellulose by organic solvents,ionic liquids and deep eutectic solvents.The design of separation methods,understanding of sepa-ration mechanisms,and optimization of reaction systems in each method are highlighted in detail.Furthermore,the ongoing challenges and future directions based on mechanism and in-dustrialization are critically discussed.Our goal is to elucidate the separation mechanisms and principles of method design,providing guidance for the development of highly efficient com-ponent separation methods of lignocellulose.展开更多
This study investigated biomass allocation in young stands of European beech(Fagus sylvatica L.)and Norway spruce(Picea abies(L.)Karst.)across 31 forest sites in the Western Carpathians,Slovakia.A total of 541 trees a...This study investigated biomass allocation in young stands of European beech(Fagus sylvatica L.)and Norway spruce(Picea abies(L.)Karst.)across 31 forest sites in the Western Carpathians,Slovakia.A total of 541 trees aged 2–10 years,originating from natural regeneration and planting,were destructively sampled to quantify biomass in four components:foliage,branches,stems,and roots.Generalized non-linear least squares(GNLS)models with a weighing variance function outperformed log-transformed seemingly unrelated regression(SUR)models in terms of accuracy and robustness,especially for foliage and branch biomass.When using height as the predictor,SUR models tended to underestimate biomass in planted beech,leading to notable underprediction of aboveground and total biomass.Biomass allocation patterns varied significantly by species and regeneration origin.Using a non-linear system of equations and component ratio modelling,we found out that planted spruce displayed low variability and a consistent dominance of needle biomass,while naturally regenerated beech showed greater variability and a higher proportion of stem biomass,reflecting stronger competition-driven vertical growth.Interspecific differences in total biomass were more pronounced when using tree height,with spruce generally exhibiting greater biomass than beech at equivalent heights.Overall,stem base diameter marginally outperformed tree height as a predictor of biomass.However,tree height-based models showed strong performance and are particularly suitable for integration with remote sensing applications.These findings can directly support forest managers and modellers in comparing regeneration methods and biomass estimation approaches for early-stage stand development,carbon accounting,and remote sensing calibration.展开更多
1.Introduction The non-renewable fossil fuels have triggered severe energy crisis and global climate change,necessitating the development of sustainable solutions for the growing population.It is estimated that the gl...1.Introduction The non-renewable fossil fuels have triggered severe energy crisis and global climate change,necessitating the development of sustainable solutions for the growing population.It is estimated that the global annual production of biomass exceeds 180 billion tons[1].Due to its broad availability,renewability,and tunable molecular functionality,biomass is considered as a versatile and sustainable substitute to fossil fuels for the production of fuels and chemicals[2,3].展开更多
Understanding the patterns and drivers of biomass allocation among organs at a broad scale is crucial for predicting the responses of plant growth and carbon sequestration to environmental change.However,the extent to...Understanding the patterns and drivers of biomass allocation among organs at a broad scale is crucial for predicting the responses of plant growth and carbon sequestration to environmental change.However,the extent to which the general rules govern these patterns and the key factors affecting biomass allocation remain poorly understood.Using a global dataset of 239 tree species,we tested the two prevailing theories(i.e.,the allometric partitioning theory(APT)and the optimal partitioning theory(OPT))by investigating the scaling relationships between plant organs and how environmental factors and phylogeny shape the patterns of biomass allocation.Our results generally support APT at the global scale,with variations in biomass allocation patterns explained by OPT.As plant size increased,a significant shift in biomass allocation from leaves to roots and stems,as well as from roots to stems,was observed.Specific environmental factors(including temperature,precipitation variables,and soil properties)significantly influenced biomass allocation with distinct patterns in the angiosperms and gymnosperms,even when the allometric effects were taken into account.We conclude that tree biomass allocation among organs(i.e.,the ratios of leaf to stem,leaf to root,stem to root,and aboveground to belowground)is governed by allometry but modulated by optimization at the global scale.Our findings highlight the importance of considering both the ontogenetic and environmental effects in predicting the responses of biomass sequestration to phylogenetic and environmental factors.展开更多
Carbon dioxide(CO_(2))is the main greenhouse gas(GHG)released by human activities.The substitution of fossil resources by biomass as a bio-renewable resource,has significant potential to reduce GHG emissions.The appro...Carbon dioxide(CO_(2))is the main greenhouse gas(GHG)released by human activities.The substitution of fossil resources by biomass as a bio-renewable resource,has significant potential to reduce GHG emissions.The approach to biomass,as the only true full-scale alternative to fossil resources,is progressing rapidly.Converting biomass into furanic compounds,as versatile platform chemicals for synthesizing a wide range of bio-based products is the cornerstone of sustainable technologies.The extensive body of this review combines the biomass valorization to furanic compounds by CO_(2)utilization and furanic compounds conversion by CO_(2)fixation.These processes can be strategically applied through both‘thermochemical’and‘electrochemical’pathways,by utilizing CO_(2)from the atmosphere or industrial emission point and returning it to the natural carbon cycle.In the thermochemical pathway CO_(2)acts as a carbon source(carboxylation and polymerization)or active reaction assistant in the biomass conversion(CO_(2)-assisted conversion),without altering its oxidation state,facilitating the synthesis of valuable products and polymers.Conversely,in the electrochemical pathway,CO_(2)can be used as a carbon source(electrocarboxylation)to give the corresponding carboxylic acid,or it can undergo reduction,yielding methanol,carbon monoxide(CO),formic acid,and analogous compounds,while on the other side,furanic compounds undergo oxidation yielding high-value-added chemicals.Finally,potential future research directions are suggested to promote CO_(2)utilization and fixation in the valorization of biomass-derived furanic compounds,and challenges facing further research are highlighted.展开更多
In the current era of renewable energy prominence,the wide operational capacity of coal-fired boilers has emerged as crucial for ensuring the sustainability of power plants.However,attaining ultra-low nitrogen oxides(...In the current era of renewable energy prominence,the wide operational capacity of coal-fired boilers has emerged as crucial for ensuring the sustainability of power plants.However,attaining ultra-low nitrogen oxides(NO_x)emissions during periods of low-load operations presents a significant and persistent challenge for coal power enterprises.While techniques such as biomass re-burning and advanced re-burning have shown promise in enhancing NO reduction effciency above 800℃,their elevated levels of chlorine(Cl)and alkali metals pose potential risks to boiler equipment integrity.Therefore,this study proposes the utilization of biomass char derived from pyrolysis as a dual-purpose solution to enhance NO reduction efficiency while safeguarding boiler integrity during low-load operations.Findings indicate that pyrolysis treatment effectively reduces the Cl and alkali metal content of biomass.Specifically,it was determined that biomass char produced through deeply pyrolysis at 300℃achieves the highest NO reduction efficiency while minimizing the presence of harmful components.At a reduction temperature of 700℃,both re-burning and advanced re-burning techniques exhibit NO reduction efficiencies of 55.90%and 62.22%,which is already an ideal deficiency at low temperatures.The addition of water vapor at 700-800℃obviously avoids the oxidation of ammonia to NO in advanced reburning.Upon further analysis,denitrification efficiency in biomass char re-burning and advanced reburning is influenced not only by volatile content but also by physicochemical properties such as porosity and surface functional group distribution under certain reaction conditions.This study provides a theoretical framework for the industrial implementation of biomass char for NO control in coal-fired power plants,offering insights into optimizing NO reduction efficiency while mitigating potential risks to boiler equipment.展开更多
While numerous allometric models exist for estimating biomass in trees with single stems,models for multi-stemmed species are scarce.This study presents models for predicting aboveground biomass(AGB)in European hazel(...While numerous allometric models exist for estimating biomass in trees with single stems,models for multi-stemmed species are scarce.This study presents models for predicting aboveground biomass(AGB)in European hazel(Corylus avellana L.),growing in multi-stemmed shrub form.We measured the size and harvested the biomass of 30 European hazel shrubs,drying and weighing their woody parts and leaves separately.AGB(dry mass)and leaf area models were established using a range of predictors,such as the upper height of the shrub,number of shoots per shrub,canopy projection area,stem base diameter of the thickest stem,and the sum of cross-sectional areas of all stems at the stem base.The latter was the best predictor of AGB,but the most practically useful variables,defined as relatively easy to measure by terrestrial or aerial approaches,were the upper height of the shrub and the canopy projection area.The leaf biomass to AGB ratio decreased with the shrub's height.Specific leaf area of shaded leaves increases with shrub height,but that of leaves at the top of the canopy does not change significantly.Given that the upper shrub height and crown projection of European hazel can be estimated using remote sensing approaches,especially UAV and LIDAR,these two variables appear the most promising for effective measurement of AGB in hazel.展开更多
Understanding how dominant plants respond to nitrogen(N)addition is critical for accurately predicting the potential effects of N deposition on ecosystem structure and functionality.Biomass partitioning serves as a va...Understanding how dominant plants respond to nitrogen(N)addition is critical for accurately predicting the potential effects of N deposition on ecosystem structure and functionality.Biomass partitioning serves as a valuable indicator for assessing plant responses to environmental changes.However,considerable uncertainty remains regarding how biomass partitioning shifts with increasing N inputs in sandy ecosystems.To address this gap,we conducted a greenhouse N fertilization experiment in April 2024,using seeds from 20 dominant plant species in the Horqin Sandy Land of China representing 5 life forms:annual grasses,annual forbs,perennial grasses,perennial forbs,and shrubs.Six levels of N addition(0.0,3.5,7.0,14.0,21.0,and 49.0 g N/(m2•a),referred to as N0,N1,N2,N3,N4,and N5,respectively)were applied to investigate the effects of N inputs on biomass partitioning.Results showed that for all 20 dominant plant species,the root biomass:shoot biomass(R:S)consistently declined across all N addition treatments(P<0.050).Concurrently,N addition led to a 23.60%reduction in root biomass fraction,coupled with a 12.38%increase in shoot biomass fraction(P<0.050).Allometric partitioning analysis further indicated that N addition had no significant effect on the slopes of the allometric relationships(leaf biomass versus root biomass,stem biomass versus root biomass,and shoot biomass versus root biomass).This suggests that plants can adjust resource investment—such as allocating more resources to shoots—to optimize growth under favorable conditions without disrupting functional trade-offs between organs.Among different life forms,annual grasses,perennial grasses,and annual forbs exhibited increased allocation to aboveground biomass,enhancing productivity and potentially altering community composition and competitive hierarchies.In contrast,perennial forbs and shrubs maintained stable biomass partitioning across all N addition levels,reflecting conservative resource allocation strategies that support long-term ecosystem resilience in nutrient-poor environments.Taken together,these findings deepen our understanding of how nutrient enrichment influences biomass allocation and ecosystem dynamics across different plant life forms,offering practical implications for the management and restoration of degraded sandy ecosystems.展开更多
Land-use systems are a key factor influencing the biomass and carbon sequestration potential of a given plant species.This study aimed to estimate the above-and belowground biomass and carbon sequestration potential o...Land-use systems are a key factor influencing the biomass and carbon sequestration potential of a given plant species.This study aimed to estimate the above-and belowground biomass and carbon sequestration potential of the Bauhinia thonningii tree across different land-use types in northern Ethiopia.Vegetation and soil data were collected from 72 sampling plots(100 m×50 m)in cultivated and grazing land-use types in the Tselemti district,Tigray region,Ethiopia.Soil organic carbon stocks were calculated from measured carbon contents between 0–15 and 15–30 cm soil depths and bulk density values for cultivated and grazing land-use types.B.thonningii dendrometric parameters showed significant variation among the land-use types.The highest aboveground biomass(16.57±3.64 Mg ha^(-1)),aboveground carbon(8.28±1.82 Mg C ha^(-1)),total carbon stock(65.58±3.92 Mg C ha^(-1)),and CO_(2)sequestration(237.52±14.37 Mg C ha^(-1))were observed in grazing lands compared to cultivated lands.Dendrometric parameters,above-and belowground biomass,and carbon sequestration were significantly higher in grazing lands than in cultivated lands.Soil organic carbon was higher in the upper surface layer(0–15 cm)than in the sub-surface layer(15–30 cm)for both land-use types.Basal area,aboveground biomass,belowground biomass,above-and belowground carbon stocks,total carbon stock,CO_(2),and total biomass carbon stocks exhibited a perfect to moderate range of positive correlation with each other,while showing a low positive correlation with land-use types(p<0.05).Grazing land with B.thonningii trees possesses a higher carbon stock than cultivated land,showing the potential for increasing biomass and carbon stock in grazing land systems by scaling up similar practices.Improved tree-based farming systems can contribute to mitigate global warming,support carbon financing initiatives,and serve as a benchmark for comparing future changes in biomass and carbon stocks.展开更多
The quest for sustainable energy solutions has intensified the search for alternative feedstocks that can supplement or replace fossil fuels. Obtaining fuels or chemicals through the conversion of renewable biomass is...The quest for sustainable energy solutions has intensified the search for alternative feedstocks that can supplement or replace fossil fuels. Obtaining fuels or chemicals through the conversion of renewable biomass is a promising candidate [1,2]. Some noblemetal-based (e.g., Pt, Pd and Rh) catalysts exhibit significant catalytic activity to the conversion reaction of these biomass.展开更多
基金Supported by the National Natural Science Foundation of China(52506188,52476215)Natural Science Foundation of Liaoning Province(2024-MS-139,2024JH3/10200047)Scientific Research Program of Department of Education of Liaoning Province(310125042,LJ212410143033)。
文摘In this paper,the Ni/Al_(2)O_(3) monolithic catalyst with 15%Ni content was prepared using cordierite as a matrix,and the catalyst was modified with 10%NaOH to study the methanation performance of biomass gasification simulated gas based on alkali-modified Ni/Al_(2)O_(3) monolithic catalyst.BET,TEM,H_(2)-TPR,XRD,CO_(2)-TPD and TG were used to characterize the physicochemical properties of the catalyst before and after modification.The results indicated that the CO conversion rate trends of unmodified and modified Ni/Al_(2)O_(3) monolithic catalysts over 2 h were fundamentally consistent.However,the Ni/Al_(2)O_(3) catalysts modified for 2 h demonstrated significantly enhanced performance compared to those modified for 1 h.Regarding CH4 selectivity,the modified Ni/Al_(2)O_(3) catalyst exhibited markedly better performance than the unmodified Ni/Al_(2)O_(3) catalyst,confirming the enhanced methane performance of the alkali-modified Ni/Al_(2)O_(3) monolithic catalyst.Under optimized conditions(H_(2)/CO volume ratio of 3∶1,space velocity of 10000 mL/(g·h),and temperature of 400℃),the methanation performance of the Ni/Al_(2)O_(3) monolithic catalyst modified for 2 h reached its peak,achieving a CO conversion rate of 97%with 100%CH4 selectivity.
基金Support by National Natural Science Foundation of China(22127802,22573091)the HY Action(62402010305)。
文摘Biomass-based hydrocarbon fuels,as one of the alternatives to traditional fossil fuels,have attracted considerable attention in the energy field due to their renewability and environmental benefits.This article provides a systematic review of recent research progress in the chemical synthesis of biomass-based hydrocarbon fuels.It outlines the conversion pathways using feedstocks such as lipids,terpenoids,cellulose/hemicellulose,and lignin.Depending on the feedstock,various products with distinct structural characteristics can be prepared through reactions such as cyclization,condensation,and catalytic hydrogenation.Throughout the synthesis process,three key factors play a critical role:efficient catalyst development,production process optimization,and computational-chemistry-based molecular design.Finally,the article discusses future perspectives for biomass-based hydrocarbon fuel synthesis research.
基金financial support from the National Key R&D Program of China(2024YFB4206302)the National Natural Science Foundation of China(22025206,22172157)+3 种基金the Dalian Innovation Support Plan for High Level Talents(2022RG13)the Department of Science&Technology of Liaoning province(2024021100-JH3/102)DICP(DICP I202326)the Youth Innovation Promotion Association(YIPA)of the Chinese Academy of Sciences(2023192)。
文摘Converting biomass to syngas(CO+H_(2))is an accessible way to incorporate renewable carbon into the sustainable chemical industry.However,due to insufficient C–C bond breaking even at high temperature,biomass reforming produces syngas with a reduced yield accompanied by the formation of tar,char,and complex side-products.Herein,irradiation of perovskite La_(0.6)Sr_(0.4)Co_(0.2)Fe_(0.75)Ru_(0.05)O_(3-δ)(LSCFR)by concentrated sunlight activates thermodynamically stable lattice oxygen,thereby increasing the fraction of activated lattice oxygen from 12%to 43%.This enhanced oxidation ability enables biomass conversion to CO_x in 96%yield alongside H_(2) production.Sunlight irradiation also facilitates lattice oxygen replenishment via CO_(2) reduction,allowing dry photoreforming of biomass over LSCFR.In a flow apparatus,the dry photoreforming affords CO and H_(2) in 80%and 41%yields,respectively,producing 0.15 and 0.06 m~3 of CO and H_(2) in 20 h.This work reveals the light-responsive oxidation ability of oxides for the sustainable refining of native biomass.
基金supported by National Natural Science Foundation of China(22578155,22478147)the Natural Science Foundation of Huaian City(HAB2024051).
文摘Biomass is a resourcewhose organic carbon is formed from atmospheric carbon dioxide.It has numerous characteristics such as low carbon emissions,renewability,and environmental friendliness.The efficient utilization of biomass plays a significant role in promoting the development of clean energy,alleviating environmental pressures,and achieving carbon neutrality goals.Among the numerous processing technologies of biomass,hydrothermal carbonization(HTC)is a promising thermochemical process that can decompose and convert biomass into hydrochar under relatively mild conditions of approximately 180℃–300℃,thereby enabling its efficient resource utilization.In addition,HTC can directly process feedstocks with high moisture content without the need for high-temperature drying,resulting in lower energy consumption.Based on a systematic analysis of the critical articles mainly published in 2011-2025 related to biomass,HTC,and hydrochar applications,in this review,the category of biomass was first classified and the chemical compositions were summarized.Then,the main chemical reaction pathways involved in biomass decomposition and transformation during the HTC process were introduced.Meanwhile,the roles of key process parameters,including reaction temperature,residence time,pH,feedstock type,pressure,mass ratio of biomass to water,and the use of catalysts on HTC,were carefully discussed.Finally,the applications of hydrochar in energy utilization,environmental remediation,soil improvement,adsorbent,microbial fermentation,and phosphorus recovery fields were highlighted.The future directions of the HTC process were also provided,which would respond to climate change by promoting the development of the sustainable carbon materials field.
基金supported by the National Natural Sci-ence Foundation of China(Nos.22478263,22308230)Natural Science Foundation of Sichuan(No.2024NSF-SC1134)+2 种基金China Postdoctoral Science Foundation(No.2024T170612)111 center(B17030)the Fun-damental Research Funds for the Central Universities.
文摘Optically pure chiral chemicals are important building blocks with widespread applications across mul-tiple scientific and industrial do-mains such as in pharmaceuticals,agrochemicals,and food,especially acting as precursors to synthesize biodegradable polymers.As an al-ternative to fossil resources,renew-able lignocellulosic biomass has been used to access chiral chemicals,due to the versatile inherent stere-ostructures and multiple functional groups,such as hydroxyl,carbonyl,and phenyl ether groups.Typically,as the two main units of(hemi)cel-lulose components in lignocellulosic biomass,D-xylose and D-glucose bear multiple chiral centers(e.g.,2R-3S-4R for D-xylose and 2R-3S-4R-5R for D-glucose).Lignin bearsβ-O-4 linkages,exhibiting(R,S/S,R)or(R,R/S,S)stereocenters at the side-chainαandβcarbon atoms.The valorization of biomass into optical-ly pure chiral chemicals is vital for developing a more sustainable future.This review discuss-es the production of typical chiral chemicals derived from biomass through chemocatalysis,including lactones(e.g.,R/S-valerolactone),carboxylic acids(e.g.,D/L-glyceric acid,D/L-lactic acid),polyols(e.g.,tetrose),furans,oligosaccharides,and others.Two strategies are generally employed.One approach involves first producing achiral platform chemicals from biomass,followed by the introduction of asymmetric catalysts to reconstruct stereocenters.The second relates to selectively preserving one or more inherent stereocenters in the natural biomass structure during complex cascade reactions in which biomass feedstock acts as a“chi-ral pool",thus eliminating the establishment of stereocenter.The feedstock,methods em-ployed,and enantioselectivity and applications of the target chiral chemicals are discussed.Despite these advances,the synthesis of optically pure chemicals from biomass is still in its in-fancy.The coming decade presents both extraordinary challenges and opportunities in biomass-derived chiral chemistry.Future research should be focused on:(1)integrating well-established asymmetric catalysis techniques and methods with biomass’s inherent chiral pools,presenting an unprecedented opportunity to expand the chemical space of sustainable chiral compounds;(2)mastering polyfunctional complexity of chiral chemicals through holis-tic utilization of biomass’multichiral centers;(3)unlocking lignin’s stereochemical treasury that represents the next frontier in biomass valorization.
基金supported by grants from National Natural Science Foundation of China(224708046,22508229,22278049)Young Elite Scientists Sponsorship Program by CAST(2022QNRC001)+1 种基金Xingliao Talent Program-Young Top Talent(XLYC2403126)Liaoning Provincial Basic Scientific Research Project for Higher Education(LJ212510152013)。
文摘The increasing scarcity of freshwater resources has driven the rapid emergence of solar-driven interfacial evaporators(SDIEs)as a sustainable approach to harvest fresh water by utilizing solar energy.Lignocellulosic biomass,featuring natural abundance,excellent renewability,unique natural structures,and superior biodegradability compared to the synthetic polymers,is highly attractive for constructing solar steam generators.This review aims to offer an innovative and in-depth insight into designing and optimizing highperformance integrated solar interfacial evaporators derived from renewable lignocellulosic biomass.First,the structural characteristics of lignocellulosic biomass are briefly introduced,serving as photothermal layer or supporting substrates in SDIEs.Secondly,the fabrication methods and processing technologies of lignocellulosic biomass-based evaporators are summarized from the perspective of photothermal layer and supporting substrates.Next,the most recent advances of regulation and optimization strategies are proposed to improve evaporation efficiency.Subsequently,this review summarizes the diverse functionalities of SDIEs,including desalination,power generation,wastewater treatment and antimicrobial,atmospheric water harvesting,and photocatalytic hydrogen production.Finally,the challenges in this field and outlook on the future development are discussed,which are anticipated to provide new opportunities for the advancement of lignocellulosic biomass-based SDIEs.
文摘Subtropical evergreen sub-montane forests in Punjab,Pakistan,are vital for carbon sequestration and play an essential role in supporting local communities.While the global importance of tree species diversity in enhancing aboveground carbon(AGC)storage is well established,there remains limited empirical evidence from Pakistan’s forest ecosystems.This study investigated how taxonomic and functional diversity,alongside topographical variables,influence AGC across four districts in Punjab.Taxonomic metrics such as the Importance Value Index(IVI)and genus richness were computed,along with functional diversity indices including functional richness(FRic),functional dispersion(FDis),functional divergence(FDiv),and functional evenness(FEve).AGC was estimated using species-specific allometric equations,and linear mixed-effects models were applied to identify the most influential predictors.Acacia modesta and A.nilotica emerged as the dominant species in the studied sites.While species richness and biomass increased with elevation,Shannon diversity showed a negative relationship with elevation.AGC values ranged from 100 to 350 Mg ha⁻¹across the study sites.Among diversity metrics,FRic(0.042)and FDis(0.342)were significantly associated with higher AGC,whereas taxonomic diversity measures showed weaker correlations.Although elevation was a strong predictor of diversity patterns,it did not have a significant direct effect on carbon storage.These findings underscore the importance of incorporating functional trait diversity and topographic variability into forest management strategies to enhance carbon sequestration,strengthen ecosystem resilience and support sustainable rural livelihoods.
基金supported by Doctoral Scientific Fund Project of Southwest University of Science and Technology(20zx7130)Seawater Uranium Extraction Innovation and Development Fund Project(China National Nuclear Corporation)(CNNCCXLM-202215)。
文摘Many adsorbents have been developed for uranium recovery to ensure global energy and environmental security.However,most reported adsorbents involve complex preparation process and rely heavily on petrochemical feedstocks,which undoubtedly increases carbon emissions from production in the nuclear industry.Here,a biomass aerogel(CS-BT)is prepared by the facile cross-linking of chitosan and bayberry tannins with glutaraldehyde.U(Ⅵ)can be adsorbed by hydroxyl groups on CS-BT aerogel via chelation,and the maximum adsorption capacity of the obtained aerogel to U(Ⅵ)is 140 mg·g^(-1)and the removal rate reaches up to 99%(at 298.15 K,pH=5.0).The pseudo-second-order kinetics model and Freundlich model can better match the adsorption process of CS-BT aerogel,implying that its adsorption is a chemical adsorption process dominated by multilayer adsorption.The thermodynamic results show that the adsorption process of U(Ⅵ)by CS-BT aerogel is spontaneous and exothermic.Hence,our biomass aerogel can effectively extract uranium from water,contributing to the sustainable development of the nuclear industry.
基金supported by the China National Science Foundation(No.42130506,42071031)the Special Technology Innovation Fund of Carbon Peak and Carbon Neutrality in Jiangsu Province(BK20231515)+1 种基金the Spanish Government grant PID2022-140808NB-I00 funded by MICIU/AEI/https://doi.org/10.13039/501100011033the Catalan Government grants SGR 2021-1333 and AGAUR2023 CLIMA 00118.
文摘The root-to-shoot(R/S)ratio is a critical indicator of the balance between root biomass and shoot biomass,representing the ecological strategies and adaptive responses of plants to environmental conditions.However,the patterns of change in community R/S ratios during forest succession and their response to moisture levels across broad geographic gradients remains unclear.Based on forest biomass data from a national field inventory of 5,825 plots conducted across China between 2011 and 2015,this study looked into allocating biomass shoots and roots at the early,middle,and late stages of growth in plantations and succession in natural forests,and evaluated how moisture availability influences this allocation.The results revealed a significant decline in R/S ratios from early to late stages for both plantations and natural forests.Shoot and root biomass in plantations grew isometrically during the early and middle succession stages but shifted to allometric growth in the late stage,with the slope of the log-transformed shoot-root biomass relationship differing significantly across growth stages.Natural forests,in contrast,maintained isometric growth across successional stages,showing no significant variation in the slope of the log-transformed shoot-root biomass relationship.Environmental factors,particularly moisture levels,strongly influenced R/S ratios.Moisture levels significantly affected size-corrected R/S ratios,particularly in the middle stage of plantations and the early and middle stages of natural forests,supporting the hypothesis of optimal allocation.These findings suggest that in water-limited regions,forest management should prioritize drought-tolerant,deep-rooted native species,encourage mixed-species planting in the early stage,and reduce logging intensity in mature plantations.Conserving natural forests to maintain successional dynamics is essential for long-term ecological resilience.These findings emphasize the importance of balancing productivity with ecological sustainability by adapting practices to specific environments and forest types under climate change.
基金supported by National Key Technolo-gy R&D Program of China(2023YFD1701505)De-velopment Projects in Anhui Province(2022107020013).
文摘Lignocellulosic biomass is the most abundant re-newable resource on Earth,boasting advan-tages such as wide avail-ability and negative car-bon emissions.Especial-ly,efficient separation of lignocellulose into cellu-lose,hemicellulose and lignin,and realizing val-orization of these compo-nents are more responsive to the development needs of biomass refinery and the green chem-istry era.This review outlines the main components of lignocellulose and briefly summerizes their utilization in chemical raw materials and energy production.It mainly focused on cur-rent advances in component separation methods of lignocellulose by organic solvents,ionic liquids and deep eutectic solvents.The design of separation methods,understanding of sepa-ration mechanisms,and optimization of reaction systems in each method are highlighted in detail.Furthermore,the ongoing challenges and future directions based on mechanism and in-dustrialization are critically discussed.Our goal is to elucidate the separation mechanisms and principles of method design,providing guidance for the development of highly efficient com-ponent separation methods of lignocellulose.
基金funded by the grant“EVA4.0”,No.Z.02.1.01/0.0/0.0/16_019/0000803 supported by OP RDE as well as by the projects APVV-19-0387,APVV-22-0056,and APVV-23-0293 from the Slovak Research and Development Agencyco-funded by the European Commission under the Horizon Europe Teaming for Excellence action+1 种基金project Ligno Silvagrant agreement No.101059552。
文摘This study investigated biomass allocation in young stands of European beech(Fagus sylvatica L.)and Norway spruce(Picea abies(L.)Karst.)across 31 forest sites in the Western Carpathians,Slovakia.A total of 541 trees aged 2–10 years,originating from natural regeneration and planting,were destructively sampled to quantify biomass in four components:foliage,branches,stems,and roots.Generalized non-linear least squares(GNLS)models with a weighing variance function outperformed log-transformed seemingly unrelated regression(SUR)models in terms of accuracy and robustness,especially for foliage and branch biomass.When using height as the predictor,SUR models tended to underestimate biomass in planted beech,leading to notable underprediction of aboveground and total biomass.Biomass allocation patterns varied significantly by species and regeneration origin.Using a non-linear system of equations and component ratio modelling,we found out that planted spruce displayed low variability and a consistent dominance of needle biomass,while naturally regenerated beech showed greater variability and a higher proportion of stem biomass,reflecting stronger competition-driven vertical growth.Interspecific differences in total biomass were more pronounced when using tree height,with spruce generally exhibiting greater biomass than beech at equivalent heights.Overall,stem base diameter marginally outperformed tree height as a predictor of biomass.However,tree height-based models showed strong performance and are particularly suitable for integration with remote sensing applications.These findings can directly support forest managers and modellers in comparing regeneration methods and biomass estimation approaches for early-stage stand development,carbon accounting,and remote sensing calibration.
基金supported by the Shanghai Pilot Program for Basic Research-Shanghai Jiao Tong University(21TQ1400211)the National Key Research and Development Program(YFB20234004900)+2 种基金the Shanghai Municipal Science and Technology Major Projectthe State Key Laboratory of Photoelectric Conversion and Utilization of Solar Energy(Innovation Fund Project SKLPCU24OP009)the National Science Foundation of China(No.22579110)。
文摘1.Introduction The non-renewable fossil fuels have triggered severe energy crisis and global climate change,necessitating the development of sustainable solutions for the growing population.It is estimated that the global annual production of biomass exceeds 180 billion tons[1].Due to its broad availability,renewability,and tunable molecular functionality,biomass is considered as a versatile and sustainable substitute to fossil fuels for the production of fuels and chemicals[2,3].
基金supported by the China Postdoctoral Science Foundation(2023M733712)the National Natural Science Foundation of China(31971491,32571862 and 32571830)the Strategic Priority Research Program of the Chinese Academy of Sciences(A)。
文摘Understanding the patterns and drivers of biomass allocation among organs at a broad scale is crucial for predicting the responses of plant growth and carbon sequestration to environmental change.However,the extent to which the general rules govern these patterns and the key factors affecting biomass allocation remain poorly understood.Using a global dataset of 239 tree species,we tested the two prevailing theories(i.e.,the allometric partitioning theory(APT)and the optimal partitioning theory(OPT))by investigating the scaling relationships between plant organs and how environmental factors and phylogeny shape the patterns of biomass allocation.Our results generally support APT at the global scale,with variations in biomass allocation patterns explained by OPT.As plant size increased,a significant shift in biomass allocation from leaves to roots and stems,as well as from roots to stems,was observed.Specific environmental factors(including temperature,precipitation variables,and soil properties)significantly influenced biomass allocation with distinct patterns in the angiosperms and gymnosperms,even when the allometric effects were taken into account.We conclude that tree biomass allocation among organs(i.e.,the ratios of leaf to stem,leaf to root,stem to root,and aboveground to belowground)is governed by allometry but modulated by optimization at the global scale.Our findings highlight the importance of considering both the ontogenetic and environmental effects in predicting the responses of biomass sequestration to phylogenetic and environmental factors.
基金the National Key R&D Program of China(No.2021YFC2101604)National Natural Science Foundation of China(Nos.U23A20123,22278339)+1 种基金Fujian Provincial Key Science and Technology Program of China(No.2022YZ037013)Xiamen University for the financial support.
文摘Carbon dioxide(CO_(2))is the main greenhouse gas(GHG)released by human activities.The substitution of fossil resources by biomass as a bio-renewable resource,has significant potential to reduce GHG emissions.The approach to biomass,as the only true full-scale alternative to fossil resources,is progressing rapidly.Converting biomass into furanic compounds,as versatile platform chemicals for synthesizing a wide range of bio-based products is the cornerstone of sustainable technologies.The extensive body of this review combines the biomass valorization to furanic compounds by CO_(2)utilization and furanic compounds conversion by CO_(2)fixation.These processes can be strategically applied through both‘thermochemical’and‘electrochemical’pathways,by utilizing CO_(2)from the atmosphere or industrial emission point and returning it to the natural carbon cycle.In the thermochemical pathway CO_(2)acts as a carbon source(carboxylation and polymerization)or active reaction assistant in the biomass conversion(CO_(2)-assisted conversion),without altering its oxidation state,facilitating the synthesis of valuable products and polymers.Conversely,in the electrochemical pathway,CO_(2)can be used as a carbon source(electrocarboxylation)to give the corresponding carboxylic acid,or it can undergo reduction,yielding methanol,carbon monoxide(CO),formic acid,and analogous compounds,while on the other side,furanic compounds undergo oxidation yielding high-value-added chemicals.Finally,potential future research directions are suggested to promote CO_(2)utilization and fixation in the valorization of biomass-derived furanic compounds,and challenges facing further research are highlighted.
基金supported by the Open Topics of State Key Laboratory of Clean and Efficient Coal-Fired Power Generation and Pollution Control(D2022FK103)National Natural Science Foundation of China(22278250)+1 种基金the Shanxi Province Science and Technology Cooperation and Exchange Special Program(202104041101014)the Shanxi Province Scholarship Council。
文摘In the current era of renewable energy prominence,the wide operational capacity of coal-fired boilers has emerged as crucial for ensuring the sustainability of power plants.However,attaining ultra-low nitrogen oxides(NO_x)emissions during periods of low-load operations presents a significant and persistent challenge for coal power enterprises.While techniques such as biomass re-burning and advanced re-burning have shown promise in enhancing NO reduction effciency above 800℃,their elevated levels of chlorine(Cl)and alkali metals pose potential risks to boiler equipment integrity.Therefore,this study proposes the utilization of biomass char derived from pyrolysis as a dual-purpose solution to enhance NO reduction efficiency while safeguarding boiler integrity during low-load operations.Findings indicate that pyrolysis treatment effectively reduces the Cl and alkali metal content of biomass.Specifically,it was determined that biomass char produced through deeply pyrolysis at 300℃achieves the highest NO reduction efficiency while minimizing the presence of harmful components.At a reduction temperature of 700℃,both re-burning and advanced re-burning techniques exhibit NO reduction efficiencies of 55.90%and 62.22%,which is already an ideal deficiency at low temperatures.The addition of water vapor at 700-800℃obviously avoids the oxidation of ammonia to NO in advanced reburning.Upon further analysis,denitrification efficiency in biomass char re-burning and advanced reburning is influenced not only by volatile content but also by physicochemical properties such as porosity and surface functional group distribution under certain reaction conditions.This study provides a theoretical framework for the industrial implementation of biomass char for NO control in coal-fired power plants,offering insights into optimizing NO reduction efficiency while mitigating potential risks to boiler equipment.
基金funded by grants EVA4.0 No.Z.02.1.01/0.0/0.0/16_019/0000803 and ITMS2014+313011W580s provided by EU OP RDEin CZ and SKprojects APVV-18-0086,APVV-19-0387,APVV-20-0168,APVV-20-0215 and APVV-22-0056 from the Slovak Research and Development Agencysupport from the European Research Executive Agency for ReForest,Grant Agreement Nr:101060635
文摘While numerous allometric models exist for estimating biomass in trees with single stems,models for multi-stemmed species are scarce.This study presents models for predicting aboveground biomass(AGB)in European hazel(Corylus avellana L.),growing in multi-stemmed shrub form.We measured the size and harvested the biomass of 30 European hazel shrubs,drying and weighing their woody parts and leaves separately.AGB(dry mass)and leaf area models were established using a range of predictors,such as the upper height of the shrub,number of shoots per shrub,canopy projection area,stem base diameter of the thickest stem,and the sum of cross-sectional areas of all stems at the stem base.The latter was the best predictor of AGB,but the most practically useful variables,defined as relatively easy to measure by terrestrial or aerial approaches,were the upper height of the shrub and the canopy projection area.The leaf biomass to AGB ratio decreased with the shrub's height.Specific leaf area of shaded leaves increases with shrub height,but that of leaves at the top of the canopy does not change significantly.Given that the upper shrub height and crown projection of European hazel can be estimated using remote sensing approaches,especially UAV and LIDAR,these two variables appear the most promising for effective measurement of AGB in hazel.
基金supported by the National Grassland Technology Innovation Centre(Preparation)Project(CCPTZX2023B02-2)the National Natural Science Foundation of China(32071845)the Key Science and Technology Project of Inner Mongolia Autonomous Region(2021ZD001505).
文摘Understanding how dominant plants respond to nitrogen(N)addition is critical for accurately predicting the potential effects of N deposition on ecosystem structure and functionality.Biomass partitioning serves as a valuable indicator for assessing plant responses to environmental changes.However,considerable uncertainty remains regarding how biomass partitioning shifts with increasing N inputs in sandy ecosystems.To address this gap,we conducted a greenhouse N fertilization experiment in April 2024,using seeds from 20 dominant plant species in the Horqin Sandy Land of China representing 5 life forms:annual grasses,annual forbs,perennial grasses,perennial forbs,and shrubs.Six levels of N addition(0.0,3.5,7.0,14.0,21.0,and 49.0 g N/(m2•a),referred to as N0,N1,N2,N3,N4,and N5,respectively)were applied to investigate the effects of N inputs on biomass partitioning.Results showed that for all 20 dominant plant species,the root biomass:shoot biomass(R:S)consistently declined across all N addition treatments(P<0.050).Concurrently,N addition led to a 23.60%reduction in root biomass fraction,coupled with a 12.38%increase in shoot biomass fraction(P<0.050).Allometric partitioning analysis further indicated that N addition had no significant effect on the slopes of the allometric relationships(leaf biomass versus root biomass,stem biomass versus root biomass,and shoot biomass versus root biomass).This suggests that plants can adjust resource investment—such as allocating more resources to shoots—to optimize growth under favorable conditions without disrupting functional trade-offs between organs.Among different life forms,annual grasses,perennial grasses,and annual forbs exhibited increased allocation to aboveground biomass,enhancing productivity and potentially altering community composition and competitive hierarchies.In contrast,perennial forbs and shrubs maintained stable biomass partitioning across all N addition levels,reflecting conservative resource allocation strategies that support long-term ecosystem resilience in nutrient-poor environments.Taken together,these findings deepen our understanding of how nutrient enrichment influences biomass allocation and ecosystem dynamics across different plant life forms,offering practical implications for the management and restoration of degraded sandy ecosystems.
基金financial support from Mekelle University and the MU-HU-NMBU institutional collaboration project。
文摘Land-use systems are a key factor influencing the biomass and carbon sequestration potential of a given plant species.This study aimed to estimate the above-and belowground biomass and carbon sequestration potential of the Bauhinia thonningii tree across different land-use types in northern Ethiopia.Vegetation and soil data were collected from 72 sampling plots(100 m×50 m)in cultivated and grazing land-use types in the Tselemti district,Tigray region,Ethiopia.Soil organic carbon stocks were calculated from measured carbon contents between 0–15 and 15–30 cm soil depths and bulk density values for cultivated and grazing land-use types.B.thonningii dendrometric parameters showed significant variation among the land-use types.The highest aboveground biomass(16.57±3.64 Mg ha^(-1)),aboveground carbon(8.28±1.82 Mg C ha^(-1)),total carbon stock(65.58±3.92 Mg C ha^(-1)),and CO_(2)sequestration(237.52±14.37 Mg C ha^(-1))were observed in grazing lands compared to cultivated lands.Dendrometric parameters,above-and belowground biomass,and carbon sequestration were significantly higher in grazing lands than in cultivated lands.Soil organic carbon was higher in the upper surface layer(0–15 cm)than in the sub-surface layer(15–30 cm)for both land-use types.Basal area,aboveground biomass,belowground biomass,above-and belowground carbon stocks,total carbon stock,CO_(2),and total biomass carbon stocks exhibited a perfect to moderate range of positive correlation with each other,while showing a low positive correlation with land-use types(p<0.05).Grazing land with B.thonningii trees possesses a higher carbon stock than cultivated land,showing the potential for increasing biomass and carbon stock in grazing land systems by scaling up similar practices.Improved tree-based farming systems can contribute to mitigate global warming,support carbon financing initiatives,and serve as a benchmark for comparing future changes in biomass and carbon stocks.
文摘The quest for sustainable energy solutions has intensified the search for alternative feedstocks that can supplement or replace fossil fuels. Obtaining fuels or chemicals through the conversion of renewable biomass is a promising candidate [1,2]. Some noblemetal-based (e.g., Pt, Pd and Rh) catalysts exhibit significant catalytic activity to the conversion reaction of these biomass.
