BF3·OEte （Boron trifluoride etherate）, an inexpensive and commercially easily available Lewis acid stoichiometrically employed for Beckamann rearrangement in general, was now found to efficiently catalyze Beckm...BF3·OEte （Boron trifluoride etherate）, an inexpensive and commercially easily available Lewis acid stoichiometrically employed for Beckamann rearrangement in general, was now found to efficiently catalyze Beckmann rearrangement of ketoximes into their corresponding amides （up to 99% yield） in anhydrous acetonitrile under reflux temperature.展开更多
基金Project supported by the National Natural Science Foundation of China （No. 20602011）, New Century Excellent Talents in University, the Ministry of Education, China （No. NCET-07-0283）, and ‘111＇ Project （No. B07023）.
文摘BF3·OEte （Boron trifluoride etherate）, an inexpensive and commercially easily available Lewis acid stoichiometrically employed for Beckamann rearrangement in general, was now found to efficiently catalyze Beckmann rearrangement of ketoximes into their corresponding amides （up to 99% yield） in anhydrous acetonitrile under reflux temperature.
