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马来酸酐接枝聚乙烯对竹粉/高密度聚乙烯复合材料性能的影响 被引量:6
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作者 何文 庄文皎 +1 位作者 蒋身学 张齐生 《林产工业》 北大核心 2014年第2期12-14,18,共4页
以废旧高密度聚乙烯(HDPE)、竹粉(BF)为原料,马来酸酐接枝聚乙烯(MAH-g-PE)作为偶联剂,通过混炼、平板热压成型制备BF/HDPE复合材料。研究通过改变偶联剂的添加量(0%,2%,5%,8%)来检测产品的吸湿、吸水性、力学强度等指标,结果显示:MAH-g... 以废旧高密度聚乙烯(HDPE)、竹粉(BF)为原料,马来酸酐接枝聚乙烯(MAH-g-PE)作为偶联剂,通过混炼、平板热压成型制备BF/HDPE复合材料。研究通过改变偶联剂的添加量(0%,2%,5%,8%)来检测产品的吸湿、吸水性、力学强度等指标,结果显示:MAH-g-PE能明显改善BF/HDPE复合材料的吸湿、吸水性能,以及提高产品的力学性能,当添加量为5%时,样品显示了最低的吸湿、吸水率,静曲强度与弹性模量分别提高60%和52%,拉伸强度与抗冲击强度分别增长48%和72%。红外光潜(VrIR)检测证实添加MAH-g-PE后,游离羟基与马来酸酐之间发生了酯化反应。 展开更多
关键词 竹粉 高密度聚乙烯复合材料 马来酸酐接枝聚乙烯 废旧高密度聚乙烯 吸湿性 傅里叶红外光谱
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Study of the Physical, Mechanical and Thermal Properties of Banana Fiber Reinforced HDPE Composites
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作者 Budrun Neher Rakib Hossain +3 位作者 Kaniz Fatima M. A. Gafur Md. Abul Hossain Farid Ahmed 《Materials Sciences and Applications》 2020年第4期245-262,共18页
Natural fiber reinforced composite materials are replacing the conventional materials, owing to their excellent physical, mechanical, electrical, and thermal properties. Also they increase biodegradability, reduce cos... Natural fiber reinforced composite materials are replacing the conventional materials, owing to their excellent physical, mechanical, electrical, and thermal properties. Also they increase biodegradability, reduce cost and decrease environmental pollution and hazards. In this study, obsolete high density polyethylene (HDPE) has used as polymer matrix and banana fiber as reinforcement material. Composites (5%, 10%, 15% and 20% of fiber contents) were made by hot press molding method by using Paul-Otto Weber Hydraulic press machine. The physical, mechanical and thermal properties of banana fiber-HDPE composites were studied and investigated the increment or decrement nature of different properties due to addition of banana fiber in BF-HDPE composites. The bulk density of composites increased with the increase wt. (%) of fiber content in composites. Water absorption ability of banana fiber and BF-HDPE composites also increased with the increase of wt. (%) of fiber content in composites and with socking time. Tensile strength of the BF-HDPE composites increased with the increase of fiber content in both cases (continuous aligned fiber orientation and continuous bidirectional fiber orientation). Moreover, the tensile strength of BF-HDPE composites with continuous aligned fiber orientation was greater than that of continuous bidirectional fiber orientation. At first, the flexural strength increased for 5% BF-HDPE composites then the value decreased for other higher compositions. The flexural strength of continuous aligned fiber orientation was slightly greater than that of continuous bidirectional fiber orientation and composite with 5% banana fiber showed better flexural properties than others. Leeb’s rebound hardness decreased with the increase of fiber addition. Different thermal properties like TG/DTG, DTA of the obsolete HDPE and BF-HDPE composites were studied using thermo gravimetric analyzer and it was found that composite with 20% fiber content was more thermally stable than three other compositions. 展开更多
关键词 bf-hdpe Water ABSORPTION TENSILE Strength HARDNESS TG-DTG
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玻璃纤维的偶联/接枝改性及其对HDPE/竹粉复合材料性能的影响 被引量:2
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作者 张炜鹏 KHANAL Santosh 徐世爱 《功能高分子学报》 CAS CSCD 北大核心 2019年第3期329-335,共7页
通过熔体共混制备了玻璃纤维(GF)增强的高密度聚乙烯(HDPE)/竹粉(BF)复合材料(HDPE/BF)。为了增强GF与基体之间的相互作用,先用γ-甲基丙烯酰氧基丙基三甲氧基硅烷对GF进行处理,在GF表面引入双建,然后在熔体共混过程中加入少量过氧化二... 通过熔体共混制备了玻璃纤维(GF)增强的高密度聚乙烯(HDPE)/竹粉(BF)复合材料(HDPE/BF)。为了增强GF与基体之间的相互作用,先用γ-甲基丙烯酰氧基丙基三甲氧基硅烷对GF进行处理,在GF表面引入双建,然后在熔体共混过程中加入少量过氧化二异丙苯,引发双建与基体之间的接枝反应,使GF与HDPE产生化学键合。通过弯曲和冲击实验测试了复合材料的力学性能,通过热失重和维卡软化点表征了复合材料的热性能,并用扫描电子显微镜观察了复合材料的形貌结构。结果表明,通过偶联/接枝的协同改性,GF与基体之间的界面相互作用增强,使HDPE/BF复合材料的力学性能和热性能得到大幅提高。 展开更多
关键词 HDPE/BF复合材料 玻璃纤维 KH570 偶联/接枝改性
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