The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-bas...The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-based observations remain insufficient to clearly reflect the characteristics of the region’s lithospheric magnetism.In this study,we evaluate the lithospheric magnetism of the Tibetan Plateau by using a 3D surface spline model based on observations from>200 newly constructed repeat stations(portable stations)to determine the spatial distribution of plateau geomagnetism,as well as its correlation with the tectonic features of the region.We analyze the relationships between M≥5 earthquakes and lithospheric magnetic field variations on the Tibetan Plateau and identify regions susceptible to strong earthquakes.We compare the geomagnetic results with those from an enhanced magnetic model(EMM2015)developed by the NGDC and provide insights into improving lithospheric magnetic field calculations in the Tibetan Plateau region.Further research reveals that these magnetic anomalies exhibit distinct differences from the magnetic-seismic correlation mechanisms observed in other tectonic settings;here,they are governed primarily by the combined effects of compressional magnetism,thermal magnetism,and deep thermal stress.This study provides new evidence of geomagnetic anomalies on the Tibetan Plateau,interprets them physically,and demonstrates their potential for identifying seismic hazard zones on the Plateau.展开更多
AIM:To assess the possibility of using different large language models(LLMs)in ocular surface diseases by selecting five different LLMS to test their accuracy in answering specialized questions related to ocular surfa...AIM:To assess the possibility of using different large language models(LLMs)in ocular surface diseases by selecting five different LLMS to test their accuracy in answering specialized questions related to ocular surface diseases:ChatGPT-4,ChatGPT-3.5,Claude 2,PaLM2,and SenseNova.METHODS:A group of experienced ophthalmology professors were asked to develop a 100-question singlechoice question on ocular surface diseases designed to assess the performance of LLMs and human participants in answering ophthalmology specialty exam questions.The exam includes questions on the following topics:keratitis disease(20 questions),keratoconus,keratomalaciac,corneal dystrophy,corneal degeneration,erosive corneal ulcers,and corneal lesions associated with systemic diseases(20 questions),conjunctivitis disease(20 questions),trachoma,pterygoid and conjunctival tumor diseases(20 questions),and dry eye disease(20 questions).Then the total score of each LLMs and compared their mean score,mean correlation,variance,and confidence were calculated.RESULTS:GPT-4 exhibited the highest performance in terms of LLMs.Comparing the average scores of the LLMs group with the four human groups,chief physician,attending physician,regular trainee,and graduate student,it was found that except for ChatGPT-4,the total score of the rest of the LLMs is lower than that of the graduate student group,which had the lowest score in the human group.Both ChatGPT-4 and PaLM2 were more likely to give exact and correct answers,giving very little chance of an incorrect answer.ChatGPT-4 showed higher credibility when answering questions,with a success rate of 59%,but gave the wrong answer to the question 28% of the time.CONCLUSION:GPT-4 model exhibits excellent performance in both answer relevance and confidence.PaLM2 shows a positive correlation(up to 0.8)in terms of answer accuracy during the exam.In terms of answer confidence,PaLM2 is second only to GPT4 and surpasses Claude 2,SenseNova,and GPT-3.5.Despite the fact that ocular surface disease is a highly specialized discipline,GPT-4 still exhibits superior performance,suggesting that its potential and ability to be applied in this field is enormous,perhaps with the potential to be a valuable resource for medical students and clinicians in the future.展开更多
In Earth system modeling,the land surface is coupled with the atmosphere through surface turbulent fluxes.These fluxes are computed using mean meteorological variables between the surface and a reference height in the...In Earth system modeling,the land surface is coupled with the atmosphere through surface turbulent fluxes.These fluxes are computed using mean meteorological variables between the surface and a reference height in the atmosphere.However,the dependence of flux computation on the reference height,which is usually set as the lowest level in the atmosphere in Earth system models,has not received much attention.Based on high-resolution large-eddy simulation(LES)data under unstable conditions,we find the setting of reference height is not trivial within the framework of current surface layer theory.With a reasonable prescription of aerodynamic roughness length(following the setting in LESs),reference heights near the top of the surface layer tend to provide the best estimate of surface fluxes,especially for the momentum flux.Furthermore,this conclusion for the sensible heat flux is insensitive to the ratio of roughness length for momentum versus heat.These results are robust,whether using the classical or revised surface layer theory.They provide a potential guide for setting the proper reference heights for Earth system modeling and can be further tested in the near future using observational data from land–atmosphere feedback observatories.展开更多
Workpiece rotational grinding is widely used in the ultra-precision machining of hard and brittle semiconductor materials,including single-crystal silicon,silicon carbide,and gallium arsenide.Surface roughness and sub...Workpiece rotational grinding is widely used in the ultra-precision machining of hard and brittle semiconductor materials,including single-crystal silicon,silicon carbide,and gallium arsenide.Surface roughness and subsurface damage depth(SDD)are crucial indicators for evaluating the surface quality of these materials after grinding.Existing prediction models lack general applicability and do not accurately account for the complex material behavior under grinding conditions.This paper introduces novel models for predicting both surface roughness and SDD in hard and brittle semiconductor materials.The surface roughness model uniquely incorporates the material’s elastic recovery properties,revealing the significant impact of these properties on prediction accuracy.The SDD model is distinguished by its analysis of the interactions between abrasive grits and the workpiece,as well as the mechanisms governing stress-induced damage evolution.The surface roughness model and SDD model both establish a stable relationship with the grit depth of cut(GDC).Additionally,we have developed an analytical relationship between the GDC and grinding process parameters.This,in turn,enables the establishment of an analytical framework for predicting surface roughness and SDD based on grinding process parameters,which cannot be achieved by previous models.The models were validated through systematic experiments on three different semiconductor materials,demonstrating excellent agreement with experimental data,with prediction errors of 6.3%for surface roughness and6.9%for SDD.Additionally,this study identifies variations in elastic recovery and material plasticity as critical factors influencing surface roughness and SDD across different materials.These findings significantly advance the accuracy of predictive models and broaden their applicability for grinding hard and brittle semiconductor materials.展开更多
In this paper,a physical model of RIS of bistatic polarized radar cross section is derived starting from the Stratton-Chu equations under the assumptions of physical optics,PEC,far field and rectangular RIS element.In...In this paper,a physical model of RIS of bistatic polarized radar cross section is derived starting from the Stratton-Chu equations under the assumptions of physical optics,PEC,far field and rectangular RIS element.In the context of important physical characteristics of the backscattering polarization of RIS,the modeling of the RIS wireless channel requires a tradeoff between complexity and accuracy,as well as usability and simplicity.For channel modeling of RIS systems,RIS is modelled as multi-equivalent virtual base stations(BSs)induced by multi polarized electromagnetic waves from different incident directions.The comparison between test and simulation results demonstrates that the proposed algorithm effectively captures the key characteristics of the general RIS element polarization physical model and provides accurate results.展开更多
Global deforestation has been recognized as an important factor influencing climate change over the past century.However, uncertainties remain regarding its biophysical impacts on temperature across China. Utilizing m...Global deforestation has been recognized as an important factor influencing climate change over the past century.However, uncertainties remain regarding its biophysical impacts on temperature across China. Utilizing monthly data from eight global climate models of the Land Use Model Intercomparison Project, a multimodel comparison was conducted to quantitatively analyze the biophysical impacts of global deforestation on near-surface air temperature in China, using a surface energy balance decomposition method. Results show a 38%(29% to 45%) reduction in forest cover in China(ensemble mean and range across eight models) relative to pre-industrial levels, and an annual cooling of 0.6 K(0.05 to1.4 K) accompanied by global deforestation. Notably, surface albedo causes a cooling effect of 0.6 K(0.2 to 2.0 K), while surface latent and sensible heat fluxes partially offset this cooling by 0.2 K(-0.2 to 0.5 K) and 0.2 K(-0.04 to 0.6 K),respectively. These effects are more pronounced in winter and spring in deforested regions. Furthermore, the separation of atmospheric feedbacks under clear-sky and cloudy conditions show that the cloud radiative effect only accounts for 0.1 K(-0.1 to 0.4 K), while the clear-sky surface downward radiation is a significant cooling factor, contributing up to-0.5 K(-1.2 to 0.004 K), particularly in summer. However, the consistency of these models in simulating the impact of surface latent heat flux and albedo on surface temperature in China in response to deforestation is somewhat poor, highlighting the need to improve these related processes.展开更多
In this paper,an incremental contact model is developed for the elastic self-affine fractal rough surfaces under plane strain condition.The contact between a rough surface and a rigid plane is simplified by the accumu...In this paper,an incremental contact model is developed for the elastic self-affine fractal rough surfaces under plane strain condition.The contact between a rough surface and a rigid plane is simplified by the accumulation of identical line contacts with half-width given by the truncated area divided by the contact patch number at varying heights.Based on the contact stiffness of two-dimensional flat punch,the total stiffness of rough surface is estimated,and then the normal load is calculated by an incremental method.For various rough surfaces,the approximately linear load-area relationships predicted by the proposed model agree well with the results of finite element simulations.It is found that the real average contact pressure depends significantly on profile properties.展开更多
Recent studies have demonstrated a growing global interest in utilising agricultural waste to remediate wastewater.This stems from growing apprehensions about high levels of heavy metals,especially Pb^(2+)ions,in wast...Recent studies have demonstrated a growing global interest in utilising agricultural waste to remediate wastewater.This stems from growing apprehensions about high levels of heavy metals,especially Pb^(2+)ions,in wastewater produced by industrial processes such as mining,paint production,oil refining,smelting,and electroplating.This study examined apple pomace’s Pb^(2+)ions adsorption from wastewater.Response Surface Methodology(RSM)was employed,utilising the central composite face-centred design(CCFD)with three variables:initial concentration(1-50 mg/L),adsorbent dosage(0.1-1 g),and particle size(75-425μm)to formulate a mathematical model for the biosorption of Pb^(2+)ions on apple pomace.An artificial neural network(ANN)was developed using data generated from the RSM design.The CCFD and ANN models showed considerable efficacy in the adsorption process,exhibiting correlation coefficient values of 0.9921 and 0.9999,respectively.The isotherm and kinetic studies were performed,and the Freundlich Isotherm model best fitted the equilibrium data,with a correlation coefficient of 0.972 and a qe of 5.145 mg/g.Additionally,the pseudo-second-order model proved to be the most appropriate for the kinetic data,with an R^(2)of 0.9996.These results confirm that apple pomace functions as an effective,low-cost,and environmentally and sustainably biosorbent for the removal of Pb^(2+)ions from wastewater.Both RSM and ANN models exhibited high predictive capability for the biosorption process.While ANN provides more flexibility in modelling complex non-linear relationships,it is prone to overfitting,particularly with limited datasets,and this was addressed through a 5-fold cross-validation technique.展开更多
A response surface method was utilized for the finite element model updating of a cable-stayed bridge in this paper to establish a baseline finite element model(FEM)that accurately reflects the characteristics of the ...A response surface method was utilized for the finite element model updating of a cable-stayed bridge in this paper to establish a baseline finite element model(FEM)that accurately reflects the characteristics of the actual bridge structure.Firstly,an initial FEM was established by the large-scale finite element software ANSYS,and the modal analysis was carried out on the dynamic response measured by the actual bridge structural health monitoring system.The initial error was obtained by comparing the dynamic characteristics of the measured data with those of the initial finite element model.Then,the second-order complete polynomial was selected to construct the response surface model;the corrected parameters were chosen using the sensitivity method.The response surface model(RSM)was fitted under the test cases designed using the central composite design method.After constructing the objective function,the RSMwas optimized and iterated by the sequential quadratic programmingmethod to obtain the corrected FEM.Finally,the dynamic characteristics of the modified FEM were compared with those of the actual bridge to get the final error.The results show that the modified FEM simulates the dynamic characteristics of the actual cable-stayed bridges more accurately.展开更多
BACKGROUND Chronic hepatitis B(CHB)patients rarely achieve functional cure with initial pegylated interferon alpha-2b(Peg-IFNα-2b)therapy.Validated tools to guide retreatment candidates are lacking.We hypothesized th...BACKGROUND Chronic hepatitis B(CHB)patients rarely achieve functional cure with initial pegylated interferon alpha-2b(Peg-IFNα-2b)therapy.Validated tools to guide retreatment candidates are lacking.We hypothesized that clinical indicators predict hepatitis B surface antigen(HBsAg)clearance during retreatment.AIM To develop a prediction model for HBsAg clearance in Peg-IFNα-2b retreatment.METHODS In this retrospective cohort study,we enrolled 135 CHB/compensated cirrhosis patients receiving Peg-IFNα-2b retreatment after initial non-clearance at Tianjin University Central Hospital(2017-2025).Predictors were identified through univariate Cox,least absolute shrinkage and selection operator,and multivariate Cox regression.Model performance was assessed via receiver operating characteristic analysis and Harrell’s C-index,with risk stratification by X-tile optimization.RESULTS HBsAg clearance rate was 20.74%(28/135).Independent predictors included:Combination nucleos(t)ide analogue(NA)therapy during initial treatment[hazard ratio(HR)=0.276,95%confidence interval(CI):0.092-0.833],baseline HBsAg at retreatment(HR=0.571,95%CI:0.410-0.795),HBsAg decline after initial treatment(HR=2.050,95%CI:1.108-3.793),and treatment interval(HR=1.013/week,95%CI:1.008-1.018).The retreatment HBsAg clearance prediction score(RHCP-S)demonstrated area under the curve of 0.920(95%CI:0.863-0.946),sensitivity of 92.3%,specificity of 79.3%.Clearance rates differed significantly:RHCP-S challenge group(≤74 points):3.45%,RHCP-S probable group(74-110 points):29.63%,RHCP-S dominant group(≥110 points):80.95%(P<0.001).CONCLUSION The overall HBsAg clearance rate with Peg-IFNα-2b retreatment was 20.74%(28/135).The RHCP-S model identifies optimal retreatment candidates(≥110 points)with 80.95%clearance probability,associated with the absence of combination NA therapy during initial treatment,greater initial HBsAg decline,longer intervals,and lower retreatment HBsAg.展开更多
To achieve the track following and collision avoidance of underactuated unmanned surface vehicle(USV),autonomous navigation model based on model predictive control is established by including the track offset,speed va...To achieve the track following and collision avoidance of underactuated unmanned surface vehicle(USV),autonomous navigation model based on model predictive control is established by including the track offset,speed variation and rule compliance as the evaluation functions and including the ship domain of dynamic/static navigation obstacles and the mechanical characteristics limitation as constraints.The effectiveness of the model for autonomous navigation of USV in the situation of multi-ship encounters and in the complex waters with both dynamic and static obstructions is verified by several groups of simulation work.The simulation results show that the proposed model can realize the autonomous navigation of the underactuated USV under the complex waters.展开更多
This paper addresses the parallel control of autonomous surface vehicles subject to external disturbances,state constraints,and input constraints in complex ocean environments with multiple obstacles.A safety-certifie...This paper addresses the parallel control of autonomous surface vehicles subject to external disturbances,state constraints,and input constraints in complex ocean environments with multiple obstacles.A safety-certified parallel model predictive control scheme with collision-avoiding capability is proposed for autonomous surface vehicles in the framework of parallel control.Specifically,an extended state observer is designed by leveraging historical and real-time data for concurrent learning to map the motion of autonomous surface vehicles from its physical system to its artificial counterpart.A parallel model predictive control law is developed on the basis of the artificial system for both physical and artificial autonomous surface vehicles to realize virtual-physical tracking control of vehicles subject to state and input constraints.To ensure safety,highorder discrete control barrier functions are encoded in the parallel model predictive control law as safety constraints such that collision avoidance with obstacles can be achieved.A recedinghorizon constrained optimization problem is constructed with the safety constraints encoded by control barrier functions for parallel model predictive control of autonomous surface vehicles and solved via neurodynamic optimization with projection neural networks.The effectiveness and characteristics of the proposed method are demonstrated via simulations for the safe trajectory tracking and automatic berthing of autonomous surface vehicles.展开更多
Typhoon Chaba was the most intense typhoon to strike western Guangdong since Typhoon Mujigae in 2015.According to the National Disaster Reduction Center of China,in the morning of July 7,2022,over 1.5 million people i...Typhoon Chaba was the most intense typhoon to strike western Guangdong since Typhoon Mujigae in 2015.According to the National Disaster Reduction Center of China,in the morning of July 7,2022,over 1.5 million people in Guangdong,Guangxi,and Hainan were affected by Typhoon Chaba.The typhoon also caused the“Fukui 001”ship to be in distress in the waters near Yangjiang,Guangdong,on July 2,resulting in big casualties.Studies have indicated that wind field forecast for Typhoon Chaba was not accurate.To better simulate typhoon events and assess their impacts,we proposed the use of a model wind field(Fujita-Takahashi)integrated with the Copernicus Marine and Environmental Monitoring Service(CMEMS)data to reconstruct effectively the overall wind field of Typhoon Chaba.The simulation result aligns well with the observations,particularly at the Dashu Island Station,showing consistent trends in wind speed changes.However,certain limitations were noted.The model shows that the attenuation of wind speed is slower when typhoon neared land than that observed,indicating that the model has a high simulation accuracy for the ocean wind field,but may have deviations near coastal areas.The result is accurate for open sea but deviated for near land due to the land friction effect.Therefore,we recommend to adjust the model to improve the accuracy for near coasts.展开更多
Global warming induced by increased CO_(2) has caused marked changes in the ocean.Previous estimates of ocean salinity change in response to global warming have considerable ambiguity,largely attributable to the diver...Global warming induced by increased CO_(2) has caused marked changes in the ocean.Previous estimates of ocean salinity change in response to global warming have considerable ambiguity,largely attributable to the diverse sensitivities of surface fluxes.This study utilizes data from the Flux-Anomaly-Forced Model Intercomparison Project to investigate how ocean salinity responds to perturbations of surface fluxes.The findings indicate the emergence of a sea surface salinity(SSS)dipole pattern predominantly in the North Atlantic and Pacific fresh pools,driven by surface flux perturbations.This results in an intensification of the“salty gets saltier and fresh gets fresher”SSS pattern across the global ocean.The spatial pattern amplification(PA)of SSS under global warming is estimated to be approximately 11.5%,with surface water flux perturbations being the most significant contributor to salinity PA,accounting for 8.1% of the change after 70 years in experiments since pre-industrial control(piControl).Notably,the zonal-depth distribution of salinity in the upper ocean exhibits lighter seawater above the denser water,with bowed isopycnals in the upper 400 m.This stable stratification inhibits vertical mixing of salinity and temperature.In response to the flux perturbations,there is a strong positive feedback due to consequent freshening.It is hypothesized that under global warming,an SSS amplification of 7.2%/℃ and a mixed-layer depth amplification of 12.5%/℃ will occur in the global ocean.It suggests that the salinity effect can exert a more stable ocean to hinder the downward transfer of heat,which provides positive feedback to future global warming.展开更多
The high-order deformation effects in even-even^(246,248)No are investigated by means of pairing self-consistent WoodsSaxon-Strutinsky calculations using the potential-energy-surface(PES)approach in an extended deform...The high-order deformation effects in even-even^(246,248)No are investigated by means of pairing self-consistent WoodsSaxon-Strutinsky calculations using the potential-energy-surface(PES)approach in an extended deformation space(β_(2),β_(3),β_(4),β_(5),β_(6),β_(7),β_(8)).Based on the calculated two-dimensional projected energy maps and different potential energy curves,we found that the highly even-order deformations have an important impact on both the fission trajectory and energy minima,while the odd-order deformations,accompanying the even-order ones,primarily affect the fission path beyond the second barrier.Relative to the light actinide nuclei,the nuclear ground state changes to the superdeformed configuration,but the normally deformed minimum,as the low-energy shape isomer,may still be primarily responsible for enhancing nuclear stability and ensuring experimental accessibility in^(246,248)No.Our present investigation indicates the nonnegligible impact of high-order deformation effects along the fission valley and will be helpful for deepening the understanding of different deformation effects and deformation couplings in nuclei,especially in this neutron-deficient heavy-mass region.展开更多
Marine forecasting is critical for navigation safety and disaster prevention.However,traditional ocean numerical forecasting models are often limited by substantial errors and inadequate capture of temporal-spatial fe...Marine forecasting is critical for navigation safety and disaster prevention.However,traditional ocean numerical forecasting models are often limited by substantial errors and inadequate capture of temporal-spatial features.To address the limitations,the paper proposes a TimeXer-based numerical forecast correction model optimized by an exogenous-variable attention mechanism.The model treats target forecast values as internal variables,and incorporates historical temporal-spatial data and seven-day numerical forecast results from traditional models as external variables based on the embedding strategy of TimeXer.Using a self-attention structure,the model captures correlations between exogenous variables and target sequences,explores intrinsic multi-dimensional relationships,and subsequently corrects endogenous variables with the mined exogenous features.The model’s performance is evaluated using metrics including MSE(Mean Squared Error),MAE(Mean Absolute Error),RMSE(Root Mean Square Error),MAPE(Mean Absolute Percentage Error),MSPE(Mean Square Percentage Error),and computational time,with TimeXer and PatchTST models serving as benchmarks.Experiment results show that the proposed model achieves lower errors and higher correction accuracy for both one-day and seven-day forecasts.展开更多
In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics...In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics.Given copper's extensive industrial applications,sustainable recovery from low-grade ores is critical.Five key parameters-acid concentration,leaching time,particle size,temperature,and solids percentage-were identified as major influences on copper recovery.The results revealed that leaching time and solids percentage,along with interactions between temperature-time and temperature-solids percentage,had the most significant effects.Optimal conditions for 80% copper recovery while minimizing iron recovery below 3% included an acid concentration of 1.21 mol L^(-1),a leaching time of 108 min,a particle size of 438μm,a temperature of 45℃,and a solids percentage of 18.2%.Leaching kinetics were analyzed using shrinking core models,with the Dickinson model best describing the process,showing an activation energy of 32.63 kJ mol^(-1),indicative of mixed diffusion and chemical reaction control.The final kinetic model effectively predicted the influence of key parameters.These findings highlight the importance of optimizing process variables and selecting suitable kinetic models to enhance extraction efficiency,reduce costs,and improve sustainability in copper recovery.展开更多
The mapping method is a forward-modeling method that transforms the irregular surface to horizontal by mapping the rectangular grid as curved; moreover, the wave field calculations move from the physical domain to the...The mapping method is a forward-modeling method that transforms the irregular surface to horizontal by mapping the rectangular grid as curved; moreover, the wave field calculations move from the physical domain to the calculation domain. The mapping method deals with the irregular surface and the low-velocity layer underneath it using a fine grid. For the deeper high-velocity layers, the use of a fine grid causes local oversampling. In addition, when the irregular surface is transformed to horizontal, the flattened interface below the surface is transformed to curved, which produces inaccurate modeling results because of the presence of ladder-like burrs in the simulated seismic wave. Thus, we propose the mapping method based on the dual-variable finite-difference staggered grid. The proposed method uses different size grid spacings in different regions and locally variable time steps to match the size variability of grid spacings. Numerical examples suggest that the proposed method requires less memory storage capacity and improves the computational efficiency compared with forward modeling methods based on the conventional grid.展开更多
The modeling ability of a stand-alone version of the Simple Biosphere Model 2（SiB2） was tested mainly through diagnosing the simulated latent heat（LE）,sensible heat（H）,CO2 flux,and air temperature at the Tongyu ...The modeling ability of a stand-alone version of the Simple Biosphere Model 2（SiB2） was tested mainly through diagnosing the simulated latent heat（LE）,sensible heat（H）,CO2 flux,and air temperature at the Tongyu field observation station（44°25＇N,122°52＇E,184 m elevation） of Coordinated Enhanced Observing Period（CEOP）,where the land cover is cropland and grassland.In the whole year of 2003,the canopy height and the leaf area index was variable.During non-growth period,the surface would become bare,while during the growth period,the canopy height could reach 2.0 m high over cropland and 0.8 m high over grassland,respectively,and max leaf area index could reach 4.2 and 2.4,respectively.The model was initialized with measurement and driven by half-hourly atmospheric observations.The simulation values for 2003 were compared against measurements.Results show that the model is of a good ability of simulating the hourly latent heat（LE）,sensible heat（H）,CO2 flux and temperature during the growth period.Moreover,the daily LE,H and CO2 flux simulated by SiB2 could reflect their yearly change reasonably.However,the model may overestimate the H generally.展开更多
We present a finite difference （FD） method for the simulation of seismic wave fields in fractured medium with an irregular （non-fiat） free surface which is beneficial for interpreting exploration data acquired in ...We present a finite difference （FD） method for the simulation of seismic wave fields in fractured medium with an irregular （non-fiat） free surface which is beneficial for interpreting exploration data acquired in mountainous regions. Fractures are introduced through the Coates-Schoenberg approach into the FD scheme which leads to local anisotropic properties of the media where fractures are embedded. To implement surface topography, we take advantage of the boundary-conforming grid and map a rectangular grid onto a curved one. We use a stable and explicit second-order accurate finite difference scheme to discretize the elastic wave equations （in a curvilinear coordinate system） in a 2D heterogeneous transversely isotropic medium with a horizontal axis of symmetry （HTI）. Efficiency tests performed by different numerical experiments clearly illustrate the influence of an irregular free surface on seismic wave propagation in fractured media which may be significant to mountain seismic exploration. The tests also illustrate that the scattered waves induced by the tips of the fracture are re-scattered by the features of the free surface topography. The scattered waves provoked by the topography are re-scattered by the fractures, especially Rayleigh wave scattering whose amplitudes are much larger than others and making it very difficult to identify effective information from the fractures.展开更多
基金supported by the CAS Pioneer Hundred Talents Program and Second Tibetan Plateau Scientific Expedition Research Program(2019QZKK0708)as well as the Basic Research Program of Qinghai Province:Lithospheric Geomagnetic Field of the Qinghai-Tibet Plateau and the Relationship with Strong Earthquakes(2021-ZJ-969Q).
文摘The National Geophysical Data Center(NGDC)of the United States has collected aeromagnetic data for input into a series of geomagnetic models to improve model resolution;however,in the Tibetan Plateau region,ground-based observations remain insufficient to clearly reflect the characteristics of the region’s lithospheric magnetism.In this study,we evaluate the lithospheric magnetism of the Tibetan Plateau by using a 3D surface spline model based on observations from>200 newly constructed repeat stations(portable stations)to determine the spatial distribution of plateau geomagnetism,as well as its correlation with the tectonic features of the region.We analyze the relationships between M≥5 earthquakes and lithospheric magnetic field variations on the Tibetan Plateau and identify regions susceptible to strong earthquakes.We compare the geomagnetic results with those from an enhanced magnetic model(EMM2015)developed by the NGDC and provide insights into improving lithospheric magnetic field calculations in the Tibetan Plateau region.Further research reveals that these magnetic anomalies exhibit distinct differences from the magnetic-seismic correlation mechanisms observed in other tectonic settings;here,they are governed primarily by the combined effects of compressional magnetism,thermal magnetism,and deep thermal stress.This study provides new evidence of geomagnetic anomalies on the Tibetan Plateau,interprets them physically,and demonstrates their potential for identifying seismic hazard zones on the Plateau.
基金Supported by National Natural Science Foundation of China(No.82160195,No.82460203)Degree and Postgraduate Education Teaching Reform Project of Jiangxi Province(No.JXYJG-2020-026).
文摘AIM:To assess the possibility of using different large language models(LLMs)in ocular surface diseases by selecting five different LLMS to test their accuracy in answering specialized questions related to ocular surface diseases:ChatGPT-4,ChatGPT-3.5,Claude 2,PaLM2,and SenseNova.METHODS:A group of experienced ophthalmology professors were asked to develop a 100-question singlechoice question on ocular surface diseases designed to assess the performance of LLMs and human participants in answering ophthalmology specialty exam questions.The exam includes questions on the following topics:keratitis disease(20 questions),keratoconus,keratomalaciac,corneal dystrophy,corneal degeneration,erosive corneal ulcers,and corneal lesions associated with systemic diseases(20 questions),conjunctivitis disease(20 questions),trachoma,pterygoid and conjunctival tumor diseases(20 questions),and dry eye disease(20 questions).Then the total score of each LLMs and compared their mean score,mean correlation,variance,and confidence were calculated.RESULTS:GPT-4 exhibited the highest performance in terms of LLMs.Comparing the average scores of the LLMs group with the four human groups,chief physician,attending physician,regular trainee,and graduate student,it was found that except for ChatGPT-4,the total score of the rest of the LLMs is lower than that of the graduate student group,which had the lowest score in the human group.Both ChatGPT-4 and PaLM2 were more likely to give exact and correct answers,giving very little chance of an incorrect answer.ChatGPT-4 showed higher credibility when answering questions,with a success rate of 59%,but gave the wrong answer to the question 28% of the time.CONCLUSION:GPT-4 model exhibits excellent performance in both answer relevance and confidence.PaLM2 shows a positive correlation(up to 0.8)in terms of answer accuracy during the exam.In terms of answer confidence,PaLM2 is second only to GPT4 and surpasses Claude 2,SenseNova,and GPT-3.5.Despite the fact that ocular surface disease is a highly specialized discipline,GPT-4 still exhibits superior performance,suggesting that its potential and ability to be applied in this field is enormous,perhaps with the potential to be a valuable resource for medical students and clinicians in the future.
基金supported by the Natural Science Foundation of China(Grant Nos.42088101 and 42375163)the Guangdong Major Project of Basic and Applied Basic Research(Grant No.2021B0301030007)the specific research fund of The Innovation Platform for Academicians of Hainan Province(Grant No.YSPTZX202143)。
文摘In Earth system modeling,the land surface is coupled with the atmosphere through surface turbulent fluxes.These fluxes are computed using mean meteorological variables between the surface and a reference height in the atmosphere.However,the dependence of flux computation on the reference height,which is usually set as the lowest level in the atmosphere in Earth system models,has not received much attention.Based on high-resolution large-eddy simulation(LES)data under unstable conditions,we find the setting of reference height is not trivial within the framework of current surface layer theory.With a reasonable prescription of aerodynamic roughness length(following the setting in LESs),reference heights near the top of the surface layer tend to provide the best estimate of surface fluxes,especially for the momentum flux.Furthermore,this conclusion for the sensible heat flux is insensitive to the ratio of roughness length for momentum versus heat.These results are robust,whether using the classical or revised surface layer theory.They provide a potential guide for setting the proper reference heights for Earth system modeling and can be further tested in the near future using observational data from land–atmosphere feedback observatories.
基金supported by the National Key Research and Development Program of China(2022YFB3605902)the National Natural Science Foundation of China(52375411,52293402)。
文摘Workpiece rotational grinding is widely used in the ultra-precision machining of hard and brittle semiconductor materials,including single-crystal silicon,silicon carbide,and gallium arsenide.Surface roughness and subsurface damage depth(SDD)are crucial indicators for evaluating the surface quality of these materials after grinding.Existing prediction models lack general applicability and do not accurately account for the complex material behavior under grinding conditions.This paper introduces novel models for predicting both surface roughness and SDD in hard and brittle semiconductor materials.The surface roughness model uniquely incorporates the material’s elastic recovery properties,revealing the significant impact of these properties on prediction accuracy.The SDD model is distinguished by its analysis of the interactions between abrasive grits and the workpiece,as well as the mechanisms governing stress-induced damage evolution.The surface roughness model and SDD model both establish a stable relationship with the grit depth of cut(GDC).Additionally,we have developed an analytical relationship between the GDC and grinding process parameters.This,in turn,enables the establishment of an analytical framework for predicting surface roughness and SDD based on grinding process parameters,which cannot be achieved by previous models.The models were validated through systematic experiments on three different semiconductor materials,demonstrating excellent agreement with experimental data,with prediction errors of 6.3%for surface roughness and6.9%for SDD.Additionally,this study identifies variations in elastic recovery and material plasticity as critical factors influencing surface roughness and SDD across different materials.These findings significantly advance the accuracy of predictive models and broaden their applicability for grinding hard and brittle semiconductor materials.
基金supported by Ministry of Science and Technology of the People’s Republic of China(2020YFB1808101)the Project“5G evolution wireless air interface intelligent R&D and verification public platform project”supported by Ministry of Industry and Information Technology of the People’s Republic of China(TC220A04M).
文摘In this paper,a physical model of RIS of bistatic polarized radar cross section is derived starting from the Stratton-Chu equations under the assumptions of physical optics,PEC,far field and rectangular RIS element.In the context of important physical characteristics of the backscattering polarization of RIS,the modeling of the RIS wireless channel requires a tradeoff between complexity and accuracy,as well as usability and simplicity.For channel modeling of RIS systems,RIS is modelled as multi-equivalent virtual base stations(BSs)induced by multi polarized electromagnetic waves from different incident directions.The comparison between test and simulation results demonstrates that the proposed algorithm effectively captures the key characteristics of the general RIS element polarization physical model and provides accurate results.
基金supported by the National Natural Science Foundation of China (Grant No.42305041)the Natural Science Foundation of Hubei Province of China (Grant No.2020CFB331)supported by the National Key Scientific and Technological Infrastructure project “Earth System Numerical Simulation Facility” (Earth Lab)。
文摘Global deforestation has been recognized as an important factor influencing climate change over the past century.However, uncertainties remain regarding its biophysical impacts on temperature across China. Utilizing monthly data from eight global climate models of the Land Use Model Intercomparison Project, a multimodel comparison was conducted to quantitatively analyze the biophysical impacts of global deforestation on near-surface air temperature in China, using a surface energy balance decomposition method. Results show a 38%(29% to 45%) reduction in forest cover in China(ensemble mean and range across eight models) relative to pre-industrial levels, and an annual cooling of 0.6 K(0.05 to1.4 K) accompanied by global deforestation. Notably, surface albedo causes a cooling effect of 0.6 K(0.2 to 2.0 K), while surface latent and sensible heat fluxes partially offset this cooling by 0.2 K(-0.2 to 0.5 K) and 0.2 K(-0.04 to 0.6 K),respectively. These effects are more pronounced in winter and spring in deforested regions. Furthermore, the separation of atmospheric feedbacks under clear-sky and cloudy conditions show that the cloud radiative effect only accounts for 0.1 K(-0.1 to 0.4 K), while the clear-sky surface downward radiation is a significant cooling factor, contributing up to-0.5 K(-1.2 to 0.004 K), particularly in summer. However, the consistency of these models in simulating the impact of surface latent heat flux and albedo on surface temperature in China in response to deforestation is somewhat poor, highlighting the need to improve these related processes.
基金supported by the National Natural Science Foundation of China(Grant Nos.12372100,12302126,and 12302141)the China Postdoctoral Science Foundation(Grant No.2023M732799)+1 种基金the Fundamental Research Funds for the Central Universities(Grant No.xzy012024020)Sihe Wang also thanks the support from the China Scholarship Council(CSC).
文摘In this paper,an incremental contact model is developed for the elastic self-affine fractal rough surfaces under plane strain condition.The contact between a rough surface and a rigid plane is simplified by the accumulation of identical line contacts with half-width given by the truncated area divided by the contact patch number at varying heights.Based on the contact stiffness of two-dimensional flat punch,the total stiffness of rough surface is estimated,and then the normal load is calculated by an incremental method.For various rough surfaces,the approximately linear load-area relationships predicted by the proposed model agree well with the results of finite element simulations.It is found that the real average contact pressure depends significantly on profile properties.
基金funding from the National Research Foundation of South Africa[Grant No:PMDS240909267358]。
文摘Recent studies have demonstrated a growing global interest in utilising agricultural waste to remediate wastewater.This stems from growing apprehensions about high levels of heavy metals,especially Pb^(2+)ions,in wastewater produced by industrial processes such as mining,paint production,oil refining,smelting,and electroplating.This study examined apple pomace’s Pb^(2+)ions adsorption from wastewater.Response Surface Methodology(RSM)was employed,utilising the central composite face-centred design(CCFD)with three variables:initial concentration(1-50 mg/L),adsorbent dosage(0.1-1 g),and particle size(75-425μm)to formulate a mathematical model for the biosorption of Pb^(2+)ions on apple pomace.An artificial neural network(ANN)was developed using data generated from the RSM design.The CCFD and ANN models showed considerable efficacy in the adsorption process,exhibiting correlation coefficient values of 0.9921 and 0.9999,respectively.The isotherm and kinetic studies were performed,and the Freundlich Isotherm model best fitted the equilibrium data,with a correlation coefficient of 0.972 and a qe of 5.145 mg/g.Additionally,the pseudo-second-order model proved to be the most appropriate for the kinetic data,with an R^(2)of 0.9996.These results confirm that apple pomace functions as an effective,low-cost,and environmentally and sustainably biosorbent for the removal of Pb^(2+)ions from wastewater.Both RSM and ANN models exhibited high predictive capability for the biosorption process.While ANN provides more flexibility in modelling complex non-linear relationships,it is prone to overfitting,particularly with limited datasets,and this was addressed through a 5-fold cross-validation technique.
基金supported by the National Natural Science Foundation of China(NNSFC)(Grant no.12272148).
文摘A response surface method was utilized for the finite element model updating of a cable-stayed bridge in this paper to establish a baseline finite element model(FEM)that accurately reflects the characteristics of the actual bridge structure.Firstly,an initial FEM was established by the large-scale finite element software ANSYS,and the modal analysis was carried out on the dynamic response measured by the actual bridge structural health monitoring system.The initial error was obtained by comparing the dynamic characteristics of the measured data with those of the initial finite element model.Then,the second-order complete polynomial was selected to construct the response surface model;the corrected parameters were chosen using the sensitivity method.The response surface model(RSM)was fitted under the test cases designed using the central composite design method.After constructing the objective function,the RSMwas optimized and iterated by the sequential quadratic programmingmethod to obtain the corrected FEM.Finally,the dynamic characteristics of the modified FEM were compared with those of the actual bridge to get the final error.The results show that the modified FEM simulates the dynamic characteristics of the actual cable-stayed bridges more accurately.
基金Supported by the Tianjin Health Research Project(Key Project),No.TJWJ2024ZD004Tianjin Key Medical Discipline(Specialty)Construction Project,No.TJYXZDXK-034A.
文摘BACKGROUND Chronic hepatitis B(CHB)patients rarely achieve functional cure with initial pegylated interferon alpha-2b(Peg-IFNα-2b)therapy.Validated tools to guide retreatment candidates are lacking.We hypothesized that clinical indicators predict hepatitis B surface antigen(HBsAg)clearance during retreatment.AIM To develop a prediction model for HBsAg clearance in Peg-IFNα-2b retreatment.METHODS In this retrospective cohort study,we enrolled 135 CHB/compensated cirrhosis patients receiving Peg-IFNα-2b retreatment after initial non-clearance at Tianjin University Central Hospital(2017-2025).Predictors were identified through univariate Cox,least absolute shrinkage and selection operator,and multivariate Cox regression.Model performance was assessed via receiver operating characteristic analysis and Harrell’s C-index,with risk stratification by X-tile optimization.RESULTS HBsAg clearance rate was 20.74%(28/135).Independent predictors included:Combination nucleos(t)ide analogue(NA)therapy during initial treatment[hazard ratio(HR)=0.276,95%confidence interval(CI):0.092-0.833],baseline HBsAg at retreatment(HR=0.571,95%CI:0.410-0.795),HBsAg decline after initial treatment(HR=2.050,95%CI:1.108-3.793),and treatment interval(HR=1.013/week,95%CI:1.008-1.018).The retreatment HBsAg clearance prediction score(RHCP-S)demonstrated area under the curve of 0.920(95%CI:0.863-0.946),sensitivity of 92.3%,specificity of 79.3%.Clearance rates differed significantly:RHCP-S challenge group(≤74 points):3.45%,RHCP-S probable group(74-110 points):29.63%,RHCP-S dominant group(≥110 points):80.95%(P<0.001).CONCLUSION The overall HBsAg clearance rate with Peg-IFNα-2b retreatment was 20.74%(28/135).The RHCP-S model identifies optimal retreatment candidates(≥110 points)with 80.95%clearance probability,associated with the absence of combination NA therapy during initial treatment,greater initial HBsAg decline,longer intervals,and lower retreatment HBsAg.
基金the National Natural Science Foundation of China(No.51879119)the Key Projects of National Key Research and Development Program(No.2021YFB390150)+1 种基金the Natural Science Project of Fujian Province(Nos.2022J01323,2021J01822 and 2020J01660)the Fuzhou-Xiamen-Quanzhou Independent Innovation Region Cooperated Special Foundation(No.3502ZCQXT2021007)。
文摘To achieve the track following and collision avoidance of underactuated unmanned surface vehicle(USV),autonomous navigation model based on model predictive control is established by including the track offset,speed variation and rule compliance as the evaluation functions and including the ship domain of dynamic/static navigation obstacles and the mechanical characteristics limitation as constraints.The effectiveness of the model for autonomous navigation of USV in the situation of multi-ship encounters and in the complex waters with both dynamic and static obstructions is verified by several groups of simulation work.The simulation results show that the proposed model can realize the autonomous navigation of the underactuated USV under the complex waters.
基金supported in part by the National Science and Technology Major Project(2022ZD0119902)the National Natural Science Foundation of China(52471372,623B2018,62203015,62233001)+4 种基金the Liaoning Revitalization Leading Talents Program(XLYC2402054)the Key Basic Research of Dalian(2023JJ11CG008)the Fundamental Research Funds for the Central Universities(3132023508)the Collaborative Research Fund of Hong Kong Research Grants Council(C1013-24G)the Cultivation Program for the Excellent Doctoral Dissertation of Dalian Maritime University(2023YBPY005).
文摘This paper addresses the parallel control of autonomous surface vehicles subject to external disturbances,state constraints,and input constraints in complex ocean environments with multiple obstacles.A safety-certified parallel model predictive control scheme with collision-avoiding capability is proposed for autonomous surface vehicles in the framework of parallel control.Specifically,an extended state observer is designed by leveraging historical and real-time data for concurrent learning to map the motion of autonomous surface vehicles from its physical system to its artificial counterpart.A parallel model predictive control law is developed on the basis of the artificial system for both physical and artificial autonomous surface vehicles to realize virtual-physical tracking control of vehicles subject to state and input constraints.To ensure safety,highorder discrete control barrier functions are encoded in the parallel model predictive control law as safety constraints such that collision avoidance with obstacles can be achieved.A recedinghorizon constrained optimization problem is constructed with the safety constraints encoded by control barrier functions for parallel model predictive control of autonomous surface vehicles and solved via neurodynamic optimization with projection neural networks.The effectiveness and characteristics of the proposed method are demonstrated via simulations for the safe trajectory tracking and automatic berthing of autonomous surface vehicles.
基金Supported by the National Key Research and Development Program of China(Nos.2021YFC3101801,2023YFC3008200)the National Natural Science Foundation of China(Nos.42476219,41976200)+6 种基金the National Foreign Experts Program(No.S20240134)the Innovative Team Plan of the Department of Education of Guangdong Province(No.2023KCXTD015)the Tropical Ocean Environment in Western Coastal Waters Observation and Research Station of Guangdong Province(No.2024B1212040008)the Independent Research Project of the Southern Ocean Laboratory(No.SML2022SP301)the Shandong Innovation and Development Research Institute Think Tank Projectthe Guangdong Ocean University Scientific Research Program(No.060302032106)the Start-up Fund for Ph D Researchers(No.060302032104)。
文摘Typhoon Chaba was the most intense typhoon to strike western Guangdong since Typhoon Mujigae in 2015.According to the National Disaster Reduction Center of China,in the morning of July 7,2022,over 1.5 million people in Guangdong,Guangxi,and Hainan were affected by Typhoon Chaba.The typhoon also caused the“Fukui 001”ship to be in distress in the waters near Yangjiang,Guangdong,on July 2,resulting in big casualties.Studies have indicated that wind field forecast for Typhoon Chaba was not accurate.To better simulate typhoon events and assess their impacts,we proposed the use of a model wind field(Fujita-Takahashi)integrated with the Copernicus Marine and Environmental Monitoring Service(CMEMS)data to reconstruct effectively the overall wind field of Typhoon Chaba.The simulation result aligns well with the observations,particularly at the Dashu Island Station,showing consistent trends in wind speed changes.However,certain limitations were noted.The model shows that the attenuation of wind speed is slower when typhoon neared land than that observed,indicating that the model has a high simulation accuracy for the ocean wind field,but may have deviations near coastal areas.The result is accurate for open sea but deviated for near land due to the land friction effect.Therefore,we recommend to adjust the model to improve the accuracy for near coasts.
基金supported by the Laoshan Laboratory[grant number LSKJ202202403]the National Natural Science Foundation of China[grant number 42030410]+1 种基金additionally supported by the Startup Foundation for Introducing Talent of NUISTJiangsu Innovation Research Group[grant number JSSCTD202346]。
文摘Global warming induced by increased CO_(2) has caused marked changes in the ocean.Previous estimates of ocean salinity change in response to global warming have considerable ambiguity,largely attributable to the diverse sensitivities of surface fluxes.This study utilizes data from the Flux-Anomaly-Forced Model Intercomparison Project to investigate how ocean salinity responds to perturbations of surface fluxes.The findings indicate the emergence of a sea surface salinity(SSS)dipole pattern predominantly in the North Atlantic and Pacific fresh pools,driven by surface flux perturbations.This results in an intensification of the“salty gets saltier and fresh gets fresher”SSS pattern across the global ocean.The spatial pattern amplification(PA)of SSS under global warming is estimated to be approximately 11.5%,with surface water flux perturbations being the most significant contributor to salinity PA,accounting for 8.1% of the change after 70 years in experiments since pre-industrial control(piControl).Notably,the zonal-depth distribution of salinity in the upper ocean exhibits lighter seawater above the denser water,with bowed isopycnals in the upper 400 m.This stable stratification inhibits vertical mixing of salinity and temperature.In response to the flux perturbations,there is a strong positive feedback due to consequent freshening.It is hypothesized that under global warming,an SSS amplification of 7.2%/℃ and a mixed-layer depth amplification of 12.5%/℃ will occur in the global ocean.It suggests that the salinity effect can exert a more stable ocean to hinder the downward transfer of heat,which provides positive feedback to future global warming.
基金supported by the Natural Science Foundation of Henan Province(No.252300421478)the National Natural Science Foundation of China(Nos.11975209,U2032211,12075287)。
文摘The high-order deformation effects in even-even^(246,248)No are investigated by means of pairing self-consistent WoodsSaxon-Strutinsky calculations using the potential-energy-surface(PES)approach in an extended deformation space(β_(2),β_(3),β_(4),β_(5),β_(6),β_(7),β_(8)).Based on the calculated two-dimensional projected energy maps and different potential energy curves,we found that the highly even-order deformations have an important impact on both the fission trajectory and energy minima,while the odd-order deformations,accompanying the even-order ones,primarily affect the fission path beyond the second barrier.Relative to the light actinide nuclei,the nuclear ground state changes to the superdeformed configuration,but the normally deformed minimum,as the low-energy shape isomer,may still be primarily responsible for enhancing nuclear stability and ensuring experimental accessibility in^(246,248)No.Our present investigation indicates the nonnegligible impact of high-order deformation effects along the fission valley and will be helpful for deepening the understanding of different deformation effects and deformation couplings in nuclei,especially in this neutron-deficient heavy-mass region.
基金supported by the National Key Research and Development Program Project(2023YFC3107804)Planning Fund Project of Humanities and Social Sciences Research of the Ministry of Education(24YJA880097)the Graduate Education Reform Project in North China University of Technology(217051360025XN095-17)。
文摘Marine forecasting is critical for navigation safety and disaster prevention.However,traditional ocean numerical forecasting models are often limited by substantial errors and inadequate capture of temporal-spatial features.To address the limitations,the paper proposes a TimeXer-based numerical forecast correction model optimized by an exogenous-variable attention mechanism.The model treats target forecast values as internal variables,and incorporates historical temporal-spatial data and seven-day numerical forecast results from traditional models as external variables based on the embedding strategy of TimeXer.Using a self-attention structure,the model captures correlations between exogenous variables and target sequences,explores intrinsic multi-dimensional relationships,and subsequently corrects endogenous variables with the mined exogenous features.The model’s performance is evaluated using metrics including MSE(Mean Squared Error),MAE(Mean Absolute Error),RMSE(Root Mean Square Error),MAPE(Mean Absolute Percentage Error),MSPE(Mean Square Percentage Error),and computational time,with TimeXer and PatchTST models serving as benchmarks.Experiment results show that the proposed model achieves lower errors and higher correction accuracy for both one-day and seven-day forecasts.
基金Open Access funding enabled and organized by Projekt DEAL.
文摘In this study,copper extraction from low-grade oxide-sulfide ores was investigated using a leaching method combined with response surface methodology(RSM)to optimize operational conditions and assess leaching kinetics.Given copper's extensive industrial applications,sustainable recovery from low-grade ores is critical.Five key parameters-acid concentration,leaching time,particle size,temperature,and solids percentage-were identified as major influences on copper recovery.The results revealed that leaching time and solids percentage,along with interactions between temperature-time and temperature-solids percentage,had the most significant effects.Optimal conditions for 80% copper recovery while minimizing iron recovery below 3% included an acid concentration of 1.21 mol L^(-1),a leaching time of 108 min,a particle size of 438μm,a temperature of 45℃,and a solids percentage of 18.2%.Leaching kinetics were analyzed using shrinking core models,with the Dickinson model best describing the process,showing an activation energy of 32.63 kJ mol^(-1),indicative of mixed diffusion and chemical reaction control.The final kinetic model effectively predicted the influence of key parameters.These findings highlight the importance of optimizing process variables and selecting suitable kinetic models to enhance extraction efficiency,reduce costs,and improve sustainability in copper recovery.
基金financially supported by the National Natural Science Foundation of China(Nos.41104069 and 41274124)the National 973 Project(Nos.2014CB239006 and 2011CB202402)+1 种基金the Shandong Natural Science Foundation of China(No.ZR2011DQ016)Fundamental Research Funds for Central Universities(No.R1401005A)
文摘The mapping method is a forward-modeling method that transforms the irregular surface to horizontal by mapping the rectangular grid as curved; moreover, the wave field calculations move from the physical domain to the calculation domain. The mapping method deals with the irregular surface and the low-velocity layer underneath it using a fine grid. For the deeper high-velocity layers, the use of a fine grid causes local oversampling. In addition, when the irregular surface is transformed to horizontal, the flattened interface below the surface is transformed to curved, which produces inaccurate modeling results because of the presence of ladder-like burrs in the simulated seismic wave. Thus, we propose the mapping method based on the dual-variable finite-difference staggered grid. The proposed method uses different size grid spacings in different regions and locally variable time steps to match the size variability of grid spacings. Numerical examples suggest that the proposed method requires less memory storage capacity and improves the computational efficiency compared with forward modeling methods based on the conventional grid.
基金supported by the National Basic Research Program of China (2006CB400506)
文摘The modeling ability of a stand-alone version of the Simple Biosphere Model 2（SiB2） was tested mainly through diagnosing the simulated latent heat（LE）,sensible heat（H）,CO2 flux,and air temperature at the Tongyu field observation station（44°25＇N,122°52＇E,184 m elevation） of Coordinated Enhanced Observing Period（CEOP）,where the land cover is cropland and grassland.In the whole year of 2003,the canopy height and the leaf area index was variable.During non-growth period,the surface would become bare,while during the growth period,the canopy height could reach 2.0 m high over cropland and 0.8 m high over grassland,respectively,and max leaf area index could reach 4.2 and 2.4,respectively.The model was initialized with measurement and driven by half-hourly atmospheric observations.The simulation values for 2003 were compared against measurements.Results show that the model is of a good ability of simulating the hourly latent heat（LE）,sensible heat（H）,CO2 flux and temperature during the growth period.Moreover,the daily LE,H and CO2 flux simulated by SiB2 could reflect their yearly change reasonably.However,the model may overestimate the H generally.
基金sponsored by the Knowledge Innovation Program of the Chinese Academy of Sciences No.KZCX2-YW-132)the Important National Science and Technology Specific Projects(No.2008ZX05008-006)the National Natural Science Foundation of China Nos.41074033,40721003,40830315,and 40874041)
文摘We present a finite difference （FD） method for the simulation of seismic wave fields in fractured medium with an irregular （non-fiat） free surface which is beneficial for interpreting exploration data acquired in mountainous regions. Fractures are introduced through the Coates-Schoenberg approach into the FD scheme which leads to local anisotropic properties of the media where fractures are embedded. To implement surface topography, we take advantage of the boundary-conforming grid and map a rectangular grid onto a curved one. We use a stable and explicit second-order accurate finite difference scheme to discretize the elastic wave equations （in a curvilinear coordinate system） in a 2D heterogeneous transversely isotropic medium with a horizontal axis of symmetry （HTI）. Efficiency tests performed by different numerical experiments clearly illustrate the influence of an irregular free surface on seismic wave propagation in fractured media which may be significant to mountain seismic exploration. The tests also illustrate that the scattered waves induced by the tips of the fracture are re-scattered by the features of the free surface topography. The scattered waves provoked by the topography are re-scattered by the fractures, especially Rayleigh wave scattering whose amplitudes are much larger than others and making it very difficult to identify effective information from the fractures.
