Although there are numerous optical spectroscopy techniques and methods that have been used to extract the fundamental bandgap of a semiconductor,most of them belong to one of these three approaches:(1)the excitonic a...Although there are numerous optical spectroscopy techniques and methods that have been used to extract the fundamental bandgap of a semiconductor,most of them belong to one of these three approaches:(1)the excitonic absorption,(2)modulation spectroscopy,and(3)the most widely used Tauc-plot.The excitonic absorption is based on a many-particle theory,which is physically the most correct approach,but requires more stringent crystalline quality and appropriate sample preparation and experimental implementation.The Tauc-plot is based on a single-particle theo⁃ry that neglects the many-electron effects.Modulation spectroscopy analyzes the spectroscopy features in the derivative spectrum,typically,of the reflectance and transmission under an external perturbation.Empirically,the bandgap ener⁃gy derived from the three approaches follow the order of E_(ex)>E_(MS)>E_(TP),where three transition energies are from exci⁃tonic absorption,modulation spectroscopy,and Tauc-plot,respectively.In principle,defining E_(g) as the single-elec⁃tron bandgap,we expect E_(g)>E_(ex),thus,E_(g)>E_(TP).In the literature,E_(TP) is often interpreted as E_(g),which is conceptual⁃ly problematic.However,in many cases,because the excitonic peaks are not readily identifiable,the inconsistency be⁃tween E_(g) and E_(TP) becomes invisible.In this brief review,real world examples are used(1)to illustrate how excitonic absorption features depend sensitively on the sample and measurement conditions;(2)to demonstrate the differences between E_(ex),E_(MS),and E_(TP) when they can be extracted simultaneously for one sample;and(3)to show how the popular⁃ly adopted Tauc-plot could lead to misleading results.Finally,it is pointed out that if the excitonic absorption is not ob⁃servable,the modulation spectroscopy can often yield a more useful and reasonable bandgap than Tauc-plot.展开更多
Conjugated microporous polymers(CMPs) with tunable bandgaps have attracted increasing attention for photocatalytic hydrogen evolution. However, the synthesis of CMPs usually needs expensive metal-based catalysts. Here...Conjugated microporous polymers(CMPs) with tunable bandgaps have attracted increasing attention for photocatalytic hydrogen evolution. However, the synthesis of CMPs usually needs expensive metal-based catalysts. Herein, we report a metal-free synthetic route to fabricate pyridyl conjugated microporous polymers(PCMPs) via a condensed polymerization between aldehyde and aryl ketone monomers. The PCMPs show widely tunable specific surface areas(347–418 m^(2)/g), which were controlled via changing the used monomers. The PCMPs synthesized using monomers of dialdehyde and diacetylbenzene(diacetylpyridine) in the presence of pyridine exhibited the highest visible-light driven hydrogen evolution rate(9.56 μmol/h). These novel designed PCMPs provide wide adaptability to current materials designed for high-performance photocatalysts in different applications.展开更多
The concept of local resonance phononic crystals proposed in recent years provides a new chance for theoretical and technical breakthroughs in the structural vibration reduction.In this paper,a novel sandwich-like pla...The concept of local resonance phononic crystals proposed in recent years provides a new chance for theoretical and technical breakthroughs in the structural vibration reduction.In this paper,a novel sandwich-like plate model with local resonator to acquire specific low-frequency bandgaps is proposed.The core layer of the present local resonator is composed by the simply supported overhanging beam,linear spring and mass block,and well connected with the upper and lower surface panels.The simply supported overhanging beam is free at right end,and an additional linear spring is added at the left end.The wave equation is established based on the Hamilton principle,and the bending wave bandgap is further obtained.The theoretical results are verified by the COMSOL finite element software.The bandgaps and vibration characteristics of the local resonance sandwich-like plate are studied in detail.The factors which could have effects on the bandgap characteristics,such as the structural damping,mass of vibrator,position of vibrator,bending stiffness of the beam,and the boundary conditions of the sandwich-like plates,are analyzed.The result shows that the stopband is determined by the natural frequency of the resonator,the mass ratio of the resonator,and the surface panel.It shows that the width of bandgap is greatly affected by the damping ratio of the resonator.Finally,it can also be found that the boundary conditions can affect the isolation efficiency.展开更多
Many ionocovalent oxide materials are either semiconducting or insulating in nature.One of the most im- portant quantities characterising these materials,therefore,is the bandgap energy.The thermodynamic ap- proaches ...Many ionocovalent oxide materials are either semiconducting or insulating in nature.One of the most im- portant quantities characterising these materials,therefore,is the bandgap energy.The thermodynamic ap- proaches to the bandgaps of oxides are briefly described and some interracial phenomena with oxides are pres- ented.The standard electrode potentials of oxide electrodes and the heterogeneous catalytic behaviours of the oxides as well as the wetting and adhesion in liquid metal/oxide systems can be closely related to the bandgap energies of the oxides.The interfacial phenomena involving the ionocovalent oxides are associated with the electronic processes.展开更多
The narrow attenuation bands of traditional marine structures have long been a challenge in mitigating water waves.In this paper,a metastructure(MS)composed of floating periodic pontoons is proposed for broadband wate...The narrow attenuation bands of traditional marine structures have long been a challenge in mitigating water waves.In this paper,a metastructure(MS)composed of floating periodic pontoons is proposed for broadband water wave attenuation.The interaction of surface gravity waves with the MS is investigated using linear wave theory.The potential solutions of water waves by the MS with a finite array are developed by using the eigenfunction expansion matching method(EEMM),and the band structure of the MS is calculated by the transfer matrix method(TMM),in which the evanescent modes of waves are considered.The solution is verified against the existing numerical result for a special case.Based on the present solution,the association between Bragg resonance reflection and Bloch bandgaps is examined,the effects of pontoon geometry are analyzed,and the comparison between floating MS and bottom-mounted periodic structures is conducted.A computational fluid dynamics(CFD)model is further developed to assess the structures in practical fluid environments,and the floating MS presents excellent wave attenuation performance.The study presented here may provide a promising solution for protecting the coast and offshore structures.展开更多
A gradient metamaterial with varying-stiffness local resonators is proposed to open the multiple bandgaps and further form a broad fusion bandgap.First,three local resonators with linearly increasing stiffness are per...A gradient metamaterial with varying-stiffness local resonators is proposed to open the multiple bandgaps and further form a broad fusion bandgap.First,three local resonators with linearly increasing stiffness are periodically attached to the spring-mass chain to construct the gradient metamaterial.The dispersion relation is then derived based on Bloch's theorem to reveal the fusion bandgap theoretically.The dynamic characteristic of the finite spring-mass chain is investigated to validate the fusion of multiple bandgaps.Finally,the effects of the design parameters on multiple bandgaps are discussed.The results show that the metamaterial with a non-uniform stiffness gradient pattern is capable of opening a broad fusion bandgap and effectively attenuating the longitudinal waves within a broad frequency region.展开更多
One-dimensional photonic crystals (1D PhCs) have a unique ability to control the propagation of light waves, however certain classes of 1D oxides remain relatively unexplored for use as PhCs. Specifically, there has n...One-dimensional photonic crystals (1D PhCs) have a unique ability to control the propagation of light waves, however certain classes of 1D oxides remain relatively unexplored for use as PhCs. Specifically, there has not been a comparative study of the three different 1D PhC structures to compare the influence of layer thickness, number, and refractive index on the ability of the PhCs to control light transmission. Herein, we use the transfer matrix method (TMM) to theoretically examine the transmission of 1D PhCs composed of layers of TiO<sub>2</sub>/SiO<sub>2</sub>, TiO<sub>2</sub>/SnO<sub>2</sub>, SiO<sub>2</sub>/SnO<sub>2</sub>, and combinations of the three with various top and bottom layer thicknesses to cover a substantial region of the electromagnetic spectrum (UV to NIR). With increasing layer numbers for TiO<sub>2</sub>/SiO<sub>2</sub> and SiO<sub>2</sub>/SnO<sub>2</sub>, the edges became sharper and wider and the photonic bandgap width increased. Moreover, we demonstrated that PhCs with significantly thick TiO<sub>2</sub>/SiO<sub>2</sub> layers had a high transmittance for a wide bandgap, allowing for wide-band optical filter applications. These different PhC architectures could enable a variety of applications, depending on the properties needed.展开更多
Several types of acoustic metamaterial(AM)plates have been developed to achieve low-frequency and wide bandgaps,which are adjusted by their geometric configurations and material properties.This paper combines the clas...Several types of acoustic metamaterial(AM)plates have been developed to achieve low-frequency and wide bandgaps,which are adjusted by their geometric configurations and material properties.This paper combines the classical plate theory and the characteristics of piezoelectric materials,and uses the plane wave expansion method(PWEM)to derive the bandgap theoretical model of plate-type metastructures.The dispersion curves of the structures composed of elastic materials,piezoelectric materials,and functionally graded(FG)materials are compared and studied,and verified with the finite element simulation results.Then,the effects of temperatures,piezoelectric parameters,scatterer shapes,scatterer distributions,scatterer tapers,rubber layers,and spiral groove configurations on the bandgap of plate-type metastructures are discussed,and the material and geometric parameters are optimized with the genetic algorithm(GA).This study provides a reference for the design of low-frequency broadband structures.展开更多
Two novel hexagonal tungsten oxide materials,A(GaF_(2))_(3)(SeO_(3))_(2)(A=K and NH_(4)),designed by a chemical substitution-oriented method have been successfully synthesized via hydrothermal reactions.
Applying distinctive designs to mechanical metamaterials is an effective way to achieve bandgap generation,widening and movement.In this paper,the bandgaps of metamaterials are tailored through the unique design of be...Applying distinctive designs to mechanical metamaterials is an effective way to achieve bandgap generation,widening and movement.In this paper,the bandgaps of metamaterials are tailored through the unique design of bending,folding,and twisting units and applied to the vibration-damping design of a marine water pump base.It is found that the bending operation generates a new complete bandgap and significantly enlarges the directional bandgap in the low-frequency region;the folding operation expands the directional bandgap in the high-frequency region;and the twisting operation generates and broadens the directional bandgap in the mid-frequency region.The application of the negative Poisson’s ratio star-shaped metamaterial(NPRSM)cell,with a 60°bending angle,to vibration damping in a meta-material ship pump base is presented.The new base achieved vibration attenuation of 43.435 dB and 60.282 dB over the bandgap ranges of 517.95 Hz-668.36 Hz and 916.98 Hz-965.03 Hz,respectively.In addition,the weight of the new base was reduced by 36.19% compared to the conventional pump base,which is merely capable of bearing loads.This study provides an innovative design method for broadband vibration isolation and demonstrates the promising future of mechanical metamaterials in practical engineering applications.展开更多
Construction of electron donor-acceptor(D-A)conjugated system is an established strategy for achieving reverse saturable absorption(RSA)and broadband optical limiting(OL).Nevertheless,organic materials exhibit OL abil...Construction of electron donor-acceptor(D-A)conjugated system is an established strategy for achieving reverse saturable absorption(RSA)and broadband optical limiting(OL).Nevertheless,organic materials exhibit OL ability across the visible to near-infrared-II spectra range remain scarce.Herein,a series of D-A typeπ-conjugated copolymers with ultra-narrow bandgaps(0.62-0.76 e V)and strong ICT absorption were synthesized by coupling electron-withdrawing block[1,2,5]thiadiazolo[3,4-g]quinoxaline(TQ)with various electron-donating groups(thiophene,selenophene,bithiophene,di(thiophen-2-yl)ethene,and thienothiophene for P1-P5,respectively).Z-scan experiments reveal that all copolymers exhibit RSA behaviours at both 532 and 1064 nm,while P1,P3 and P4 maintain RSA performance extending to 1600 nm.Among all copolymers,P5 exhibits the strongest RSA performance upon both 532 and 1064 nm laser pulses,with the highest nonlinear absorption coefficient(β_(eff))of 51.5 and 49.4 cm·GW^(-1),respectively,and the lowest OL onset fluence(Fon)of 0.31 and 0.38 J·cm^(-2),respectively.In contrast,P4 shows optimal RSA property at 1600 nm laser pulse,withβeff of 13.1 cm·GW^(-1)and Fon of 1.43 J·cm^(-2),respectively.Combining the results of Z-scan and UV-Vis-NIR experiments,it can be speculated that moderate ground-state absorption,rather than excessively strong absorption,favors superior RSA properties.This work offers valuable insights for designing copolymers with excellent RSA behavior,as well as presents a class of candidate material systems for ultrabroadband optical limiting.展开更多
A design idea for single-component metamaterial plates is proposed to achieve the thermal stability of flexural wave bandgap by the perforated and pre-curved patterns.The band structure analysis suggests that perforat...A design idea for single-component metamaterial plates is proposed to achieve the thermal stability of flexural wave bandgap by the perforated and pre-curved patterns.The band structure analysis suggests that perforation can release part of the in-plane thermal expansion to weaken the softening effect of thermal stress.Introducing precurved components to the perforated structure will stop the decrement of the bandgap frequency in thermal environment,and even make the frequency higher with appropriate structural parameters.The bending stiffness of the heated plate is enhanced by the thermal deflection induced stiffening effect of the pre-curved components.The segmented pre-curved component presents a strong ability to resist the thermal influence on the flexural wave bandgap.A simplified model is established for the local structure of the precurved component.The theoretical calculations explain the thermally induced frequency increment of the bandgap and the discrepancy in the thermal response between the two pre-curved models.The transmittance of flexural wave validates the effectiveness of the proposed design.展开更多
Local resonant acoustic metamaterials have broad applications in sound insulation,yet their single-configuration designs often exhibit limited and discontinuous bandgap widths,hindering full-frequency noise attenuatio...Local resonant acoustic metamaterials have broad applications in sound insulation,yet their single-configuration designs often exhibit limited and discontinuous bandgap widths,hindering full-frequency noise attenuation across the human auditory range.This study presents a double-phase fidget-spinner-shaped acoustic metamaterial(DFAM),specifically designed to achieve an ultra-broad,low-frequency continuous bandgap by means of synergistic structural optimization,enabling effective and robust control of audible noise.Based on Bloch's theorem and the finite element method,the dispersion relation of the DFAM structure is calculated and verified by the transmission loss curves.The propagation characteristics of sound waves within the structure are further analyzed for noise frequencies that fall within the passband.The influence of the geometric and physical parameters on the bandgap is investigated,and the corresponding transmission loss in the propagation direction is further calculated.A hybrid collaborative design strategy,leveraging multi-parameter optimization and bandgap complementarity,is developed to construct a metastructure with continuous bandgap coverage from 20 Hz to 1000 Hz.The resulting metastructure demonstrates exceptional broadband noise attenuation,achieving a total bandgap width of 876.3 Hz(87.63% of the target range)with the transmission loss up to-762.78 d B in a three-periodic arrangement.The simulation and experimental results for the transmission loss of the DFAM metastructure show strong agreement in the low-frequency range.This work provides a novel framework for designing ultra-wide low-frequency continuous bandgap metastructures,offering significant potential for noise mitigation in complex environments.展开更多
β-Ga_(2)O_(3) MOS inverter should play a crucial role in β-Ga_(2)O_(3) electronic circuits. Enhancement-mode(E-mode) MOSFET was fabricated based on β-Ga_(2)O_(3) film grown by atomic layer deposition technology, an...β-Ga_(2)O_(3) MOS inverter should play a crucial role in β-Ga_(2)O_(3) electronic circuits. Enhancement-mode(E-mode) MOSFET was fabricated based on β-Ga_(2)O_(3) film grown by atomic layer deposition technology, and the β-Ga_(2)O_(3) inverter was further monolithically integrated on this basis. The β-Ga_(2)O_(3) n MOSFET exhibits excellent electrical characteristics with an on/off current ratio reaching 10^(5). The logic inverter shows outstanding voltage inversion characteristics under low-frequency from 1 to 400 Hz operation. As the frequency continues to increase to 10 K, the reverse characteristic becomes worse due to parasitic capacitance induced by processes, and the difference between the highest and lowest values of VOUT has an exponential decay relationship with the frequency. This paper provides the practice for the development of β-Ga_(2)O_(3)-based circuits.展开更多
Owing to superior breakdown voltage and excellent robustness,the betagallium oxide(β-Ga_(2)O_(3))power device has emerged as a pivotal research frontier in power electronics.Although advanced packaging strategies,inc...Owing to superior breakdown voltage and excellent robustness,the betagallium oxide(β-Ga_(2)O_(3))power device has emerged as a pivotal research frontier in power electronics.Although advanced packaging strategies,including nanosilver paste sintering,alumina direct bond copper(DBC)substrates,and flipchip structures,have been adopted to mitigate the intrinsic low thermal conductivity ofβ-Ga_(2)O_(3).However,a further reduction in the thermal resistance while maintaining high reliability remains a challenge.This study introduces a novel packaging methodology that synergistically integrates nano-silver films with aluminum nitride active metal brazing(AMB-AlN)substrates,achieving an ultra-low junction-to-case thermal resistance.By comprehensive reliability assessments onβ-Ga_(2)O_(3) Schottky barrier diodes(SBDs)and hetero-junction diodes(HJDs),the results demonstrate that the SBDs and HJDs exhibit surge current densities of 0.876 kA/cm^(2) and 0.778 kA/cm^(2),respectively,which represents a significant advancement in device performance benchmarks.These advancements provide critical insights into packaging design for highreliability ultrawide bandgap semiconductor systems.展开更多
The application potential of tuning two-dimensional materials(2DMs)characteristics through strain engineering for wearable and flexible devices has been widely recognized.However,the challenges lie in achieving accura...The application potential of tuning two-dimensional materials(2DMs)characteristics through strain engineering for wearable and flexible devices has been widely recognized.However,the challenges lie in achieving accurate deterministic positioning,spatial modulation,controllable magnitude,and permanent nanostrains.Herein,motivated by the skin swelling caused by mosquito bites,a technique utilizing the heated nanotip in atomic force microscopy for thermomechanical nanoindentation is demonstrated.This method enables precise positioning of localized nanostrain and regulation of bandgap in tungsten diselenide(WSe_(2))/molybdenum disulfide(MoS_(2))heterobilayer transferred onto a flexible polymethyl methacrylate film.The magnitude of strain in the WSe_(2)/MoS_(2) heterobilayer can be controlled by adjusting the parameters of nanoindentation,leading to a spatially modulated average strain of up to 2.5%on the ring-shaped expansion structure(RES).The local bandgap of the WSe_(2)/MoS_(2) heterobilayer is spatially regulated through three distinct regions.In particular,the RES exhibits the largest extent of bandgap modulation,accompanied by a significant change of~12 meV.The nanostrain significantly enhances the photoresponse speed of the photodetector device.For instance,under illumination from a 405 nm wavelength-laser,the rise time and fall time are reduced by 75%and 87.52%,respectively,compared to the device without strain.Similarly,under illumination from a 532 nm wavelength-laser,the rise time and fall time are reduced by 66.67%and 80.60%,respectively.These findings demonstrate that the proposed method serves as a versatile way for improving the photoresponse of optoelectronic devices based on 2DMs.展开更多
Since opening sizable bandgaps in bilayer graphene （BLG） was proven possible, BLG has attracted considerable attention as a promising high-mobility candidate material for many electronic and optoelectronic applicati...Since opening sizable bandgaps in bilayer graphene （BLG） was proven possible, BLG has attracted considerable attention as a promising high-mobility candidate material for many electronic and optoelectronic applications. However, the bandgaps observed in the transport experiments reported in the literature are far smaller than both the theoretical predictions and the bandgaps extracted from optical measurements. In this study, we investigate the factors preventing the formation of large bandgaps and demonstrate that a -200-meV transport bandgap can be opened in BLG by scaling the gate dielectric and employing a ribbon channel to suppress the percolative transport. This is the largest transport bandgap that has been achieved in BLG to date.展开更多
This paper studies the bandgap characteristics of a locally resonant metamaterial beam with time delays.The dispersion relations are addressed based on transfer matrix method.The governing equations of motion of the b...This paper studies the bandgap characteristics of a locally resonant metamaterial beam with time delays.The dispersion relations are addressed based on transfer matrix method.The governing equations of motion of the beam in the frequency domain are given according to spectral element method.The amplitude-frequency responses of the forced beam are determined by solving linear algebraic equations.The obtained results show that the time-delayed feedback control has great relationships with the location,width and number of the bandgaps.It is interesting that the time delay can change the direction of the movement of the bandgap and give rise to the generation of multiple bandgaps.The influences of different combinations of control parameters on the bandgap properties are shown,such as broadening effects.展开更多
To address the increasing demand for massive data storage and processing,brain-inspired neuromorphic comput-ing systems based on artificial synaptic devices have been actively developed in recent years.Among the vario...To address the increasing demand for massive data storage and processing,brain-inspired neuromorphic comput-ing systems based on artificial synaptic devices have been actively developed in recent years.Among the various materials inves-tigated for the fabrication of synaptic devices,silicon carbide(SiC)has emerged as a preferred choices due to its high electron mobility,superior thermal conductivity,and excellent thermal stability,which exhibits promising potential for neuromorphic applications in harsh environments.In this review,the recent progress in SiC-based synaptic devices is summarized.Firstly,an in-depth discussion is conducted regarding the categories,working mechanisms,and structural designs of these devices.Subse-quently,several application scenarios for SiC-based synaptic devices are presented.Finally,a few perspectives and directions for their future development are outlined.展开更多
This paper introduces a high-precision bandgap reference(BGR)designed for battery management systems(BMS),fea-turing an ultra-low temperature coefficient(TC)and line sensitivity(LS).The BGR employs a current-mode sche...This paper introduces a high-precision bandgap reference(BGR)designed for battery management systems(BMS),fea-turing an ultra-low temperature coefficient(TC)and line sensitivity(LS).The BGR employs a current-mode scheme with chopped op-amps and internal clock generators to eliminate op-amp offset.A low dropout regulator(LDO)and a pre-regula-tor enhance output driving and LS,respectively.Curvature compensation enhances the TC by addressing higher-order nonlinear-ity.These approaches,effective near room temperature,employs trimming at both 20 and 60°C.When combined with fixed cur-vature correction currents,it achieves an ultra-low TC for each chip.Implemented in a CMOS 180 nm process,the BGR occu-pies 0.548 mm²and operates at 2.5 V with 84μA current draw from a 5 V supply.An average TC of 2.69 ppm/℃ with two-point trimming and 0.81 ppm/℃ with multi-point trimming are achieved over the temperature range of-40 to 125℃.It accommo-dates a load current of 1 mA and an LS of 42 ppm/V,making it suitable for precise BMS applications.展开更多
基金Supported by Bissell Distinguished Professor Endowment Fund at UNC-Charlotte。
文摘Although there are numerous optical spectroscopy techniques and methods that have been used to extract the fundamental bandgap of a semiconductor,most of them belong to one of these three approaches:(1)the excitonic absorption,(2)modulation spectroscopy,and(3)the most widely used Tauc-plot.The excitonic absorption is based on a many-particle theory,which is physically the most correct approach,but requires more stringent crystalline quality and appropriate sample preparation and experimental implementation.The Tauc-plot is based on a single-particle theo⁃ry that neglects the many-electron effects.Modulation spectroscopy analyzes the spectroscopy features in the derivative spectrum,typically,of the reflectance and transmission under an external perturbation.Empirically,the bandgap ener⁃gy derived from the three approaches follow the order of E_(ex)>E_(MS)>E_(TP),where three transition energies are from exci⁃tonic absorption,modulation spectroscopy,and Tauc-plot,respectively.In principle,defining E_(g) as the single-elec⁃tron bandgap,we expect E_(g)>E_(ex),thus,E_(g)>E_(TP).In the literature,E_(TP) is often interpreted as E_(g),which is conceptual⁃ly problematic.However,in many cases,because the excitonic peaks are not readily identifiable,the inconsistency be⁃tween E_(g) and E_(TP) becomes invisible.In this brief review,real world examples are used(1)to illustrate how excitonic absorption features depend sensitively on the sample and measurement conditions;(2)to demonstrate the differences between E_(ex),E_(MS),and E_(TP) when they can be extracted simultaneously for one sample;and(3)to show how the popular⁃ly adopted Tauc-plot could lead to misleading results.Finally,it is pointed out that if the excitonic absorption is not ob⁃servable,the modulation spectroscopy can often yield a more useful and reasonable bandgap than Tauc-plot.
基金supported by the National Natural Science Foundation of China (Nos. 52103024, 52073046, 51873036 and51673039)the Program of Shanghai Academic Research Leader(No. 21XD1420200)+5 种基金the Shanghai Shuguang Program (No. 19SG28)the Chang Jiang Scholar Program (No. Q2019152)the Shanghai Pujiang Talent Program (No. 20PJ1400600)the Shanghai Natural Science Foundation (Nos. 22ZR1401600 and 19ZR1470900)the Fundamental Research Funds for the Central Universities(No. 2232021D-01)the Fundamental Research Funds for the Central Universities and Graduate Student Innovation Fund of Donghua University (No. CUSF-DH-D-2019024)。
文摘Conjugated microporous polymers(CMPs) with tunable bandgaps have attracted increasing attention for photocatalytic hydrogen evolution. However, the synthesis of CMPs usually needs expensive metal-based catalysts. Herein, we report a metal-free synthetic route to fabricate pyridyl conjugated microporous polymers(PCMPs) via a condensed polymerization between aldehyde and aryl ketone monomers. The PCMPs show widely tunable specific surface areas(347–418 m^(2)/g), which were controlled via changing the used monomers. The PCMPs synthesized using monomers of dialdehyde and diacetylbenzene(diacetylpyridine) in the presence of pyridine exhibited the highest visible-light driven hydrogen evolution rate(9.56 μmol/h). These novel designed PCMPs provide wide adaptability to current materials designed for high-performance photocatalysts in different applications.
基金the National Natural Science Foundation of China(Nos.11872127,11832002,11732005)Qin Xin Talents Cultivation Program of Beijing Information Science and Technology University(No.QXTCP A201901)the Project High-Level Innovative Team Building Plan for Beijing Municipal Colleges and Universities(No.IDHT20180513)。
文摘The concept of local resonance phononic crystals proposed in recent years provides a new chance for theoretical and technical breakthroughs in the structural vibration reduction.In this paper,a novel sandwich-like plate model with local resonator to acquire specific low-frequency bandgaps is proposed.The core layer of the present local resonator is composed by the simply supported overhanging beam,linear spring and mass block,and well connected with the upper and lower surface panels.The simply supported overhanging beam is free at right end,and an additional linear spring is added at the left end.The wave equation is established based on the Hamilton principle,and the bending wave bandgap is further obtained.The theoretical results are verified by the COMSOL finite element software.The bandgaps and vibration characteristics of the local resonance sandwich-like plate are studied in detail.The factors which could have effects on the bandgap characteristics,such as the structural damping,mass of vibrator,position of vibrator,bending stiffness of the beam,and the boundary conditions of the sandwich-like plates,are analyzed.The result shows that the stopband is determined by the natural frequency of the resonator,the mass ratio of the resonator,and the surface panel.It shows that the width of bandgap is greatly affected by the damping ratio of the resonator.Finally,it can also be found that the boundary conditions can affect the isolation efficiency.
文摘Many ionocovalent oxide materials are either semiconducting or insulating in nature.One of the most im- portant quantities characterising these materials,therefore,is the bandgap energy.The thermodynamic ap- proaches to the bandgaps of oxides are briefly described and some interracial phenomena with oxides are pres- ented.The standard electrode potentials of oxide electrodes and the heterogeneous catalytic behaviours of the oxides as well as the wetting and adhesion in liquid metal/oxide systems can be closely related to the bandgap energies of the oxides.The interfacial phenomena involving the ionocovalent oxides are associated with the electronic processes.
基金Project supported by the National Natural Science Foundation of China(No.12272128)the Natural Science Foundation of Jiangsu Province of China(No.BK20243019)。
文摘The narrow attenuation bands of traditional marine structures have long been a challenge in mitigating water waves.In this paper,a metastructure(MS)composed of floating periodic pontoons is proposed for broadband water wave attenuation.The interaction of surface gravity waves with the MS is investigated using linear wave theory.The potential solutions of water waves by the MS with a finite array are developed by using the eigenfunction expansion matching method(EEMM),and the band structure of the MS is calculated by the transfer matrix method(TMM),in which the evanescent modes of waves are considered.The solution is verified against the existing numerical result for a special case.Based on the present solution,the association between Bragg resonance reflection and Bloch bandgaps is examined,the effects of pontoon geometry are analyzed,and the comparison between floating MS and bottom-mounted periodic structures is conducted.A computational fluid dynamics(CFD)model is further developed to assess the structures in practical fluid environments,and the floating MS presents excellent wave attenuation performance.The study presented here may provide a promising solution for protecting the coast and offshore structures.
基金supported by the National Natural Science Foundation of China(Nos.12122206,52175125,12272129,12304309,and 12302039)the Zhejiang Provincial Natural Science Foundation of China(No.LQ24A020006)+1 种基金the Hong Kong Scholars Program of China(No.XJ2022012)the Natural Science Foundation of Hunan Province of China(No.2024JJ4004)。
文摘A gradient metamaterial with varying-stiffness local resonators is proposed to open the multiple bandgaps and further form a broad fusion bandgap.First,three local resonators with linearly increasing stiffness are periodically attached to the spring-mass chain to construct the gradient metamaterial.The dispersion relation is then derived based on Bloch's theorem to reveal the fusion bandgap theoretically.The dynamic characteristic of the finite spring-mass chain is investigated to validate the fusion of multiple bandgaps.Finally,the effects of the design parameters on multiple bandgaps are discussed.The results show that the metamaterial with a non-uniform stiffness gradient pattern is capable of opening a broad fusion bandgap and effectively attenuating the longitudinal waves within a broad frequency region.
文摘One-dimensional photonic crystals (1D PhCs) have a unique ability to control the propagation of light waves, however certain classes of 1D oxides remain relatively unexplored for use as PhCs. Specifically, there has not been a comparative study of the three different 1D PhC structures to compare the influence of layer thickness, number, and refractive index on the ability of the PhCs to control light transmission. Herein, we use the transfer matrix method (TMM) to theoretically examine the transmission of 1D PhCs composed of layers of TiO<sub>2</sub>/SiO<sub>2</sub>, TiO<sub>2</sub>/SnO<sub>2</sub>, SiO<sub>2</sub>/SnO<sub>2</sub>, and combinations of the three with various top and bottom layer thicknesses to cover a substantial region of the electromagnetic spectrum (UV to NIR). With increasing layer numbers for TiO<sub>2</sub>/SiO<sub>2</sub> and SiO<sub>2</sub>/SnO<sub>2</sub>, the edges became sharper and wider and the photonic bandgap width increased. Moreover, we demonstrated that PhCs with significantly thick TiO<sub>2</sub>/SiO<sub>2</sub> layers had a high transmittance for a wide bandgap, allowing for wide-band optical filter applications. These different PhC architectures could enable a variety of applications, depending on the properties needed.
文摘Several types of acoustic metamaterial(AM)plates have been developed to achieve low-frequency and wide bandgaps,which are adjusted by their geometric configurations and material properties.This paper combines the classical plate theory and the characteristics of piezoelectric materials,and uses the plane wave expansion method(PWEM)to derive the bandgap theoretical model of plate-type metastructures.The dispersion curves of the structures composed of elastic materials,piezoelectric materials,and functionally graded(FG)materials are compared and studied,and verified with the finite element simulation results.Then,the effects of temperatures,piezoelectric parameters,scatterer shapes,scatterer distributions,scatterer tapers,rubber layers,and spiral groove configurations on the bandgap of plate-type metastructures are discussed,and the material and geometric parameters are optimized with the genetic algorithm(GA).This study provides a reference for the design of low-frequency broadband structures.
基金supported by the National Research Foundation of Korea(NRF)funded by the Ministry of Science and ICT(Grant No.2018R1A5A1025208 and 2019R1A2C3005530).
文摘Two novel hexagonal tungsten oxide materials,A(GaF_(2))_(3)(SeO_(3))_(2)(A=K and NH_(4)),designed by a chemical substitution-oriented method have been successfully synthesized via hydrothermal reactions.
文摘Applying distinctive designs to mechanical metamaterials is an effective way to achieve bandgap generation,widening and movement.In this paper,the bandgaps of metamaterials are tailored through the unique design of bending,folding,and twisting units and applied to the vibration-damping design of a marine water pump base.It is found that the bending operation generates a new complete bandgap and significantly enlarges the directional bandgap in the low-frequency region;the folding operation expands the directional bandgap in the high-frequency region;and the twisting operation generates and broadens the directional bandgap in the mid-frequency region.The application of the negative Poisson’s ratio star-shaped metamaterial(NPRSM)cell,with a 60°bending angle,to vibration damping in a meta-material ship pump base is presented.The new base achieved vibration attenuation of 43.435 dB and 60.282 dB over the bandgap ranges of 517.95 Hz-668.36 Hz and 916.98 Hz-965.03 Hz,respectively.In addition,the weight of the new base was reduced by 36.19% compared to the conventional pump base,which is merely capable of bearing loads.This study provides an innovative design method for broadband vibration isolation and demonstrates the promising future of mechanical metamaterials in practical engineering applications.
基金supported by the National Natural Science Foundation of China(No.52102013)。
文摘Construction of electron donor-acceptor(D-A)conjugated system is an established strategy for achieving reverse saturable absorption(RSA)and broadband optical limiting(OL).Nevertheless,organic materials exhibit OL ability across the visible to near-infrared-II spectra range remain scarce.Herein,a series of D-A typeπ-conjugated copolymers with ultra-narrow bandgaps(0.62-0.76 e V)and strong ICT absorption were synthesized by coupling electron-withdrawing block[1,2,5]thiadiazolo[3,4-g]quinoxaline(TQ)with various electron-donating groups(thiophene,selenophene,bithiophene,di(thiophen-2-yl)ethene,and thienothiophene for P1-P5,respectively).Z-scan experiments reveal that all copolymers exhibit RSA behaviours at both 532 and 1064 nm,while P1,P3 and P4 maintain RSA performance extending to 1600 nm.Among all copolymers,P5 exhibits the strongest RSA performance upon both 532 and 1064 nm laser pulses,with the highest nonlinear absorption coefficient(β_(eff))of 51.5 and 49.4 cm·GW^(-1),respectively,and the lowest OL onset fluence(Fon)of 0.31 and 0.38 J·cm^(-2),respectively.In contrast,P4 shows optimal RSA property at 1600 nm laser pulse,withβeff of 13.1 cm·GW^(-1)and Fon of 1.43 J·cm^(-2),respectively.Combining the results of Z-scan and UV-Vis-NIR experiments,it can be speculated that moderate ground-state absorption,rather than excessively strong absorption,favors superior RSA properties.This work offers valuable insights for designing copolymers with excellent RSA behavior,as well as presents a class of candidate material systems for ultrabroadband optical limiting.
基金Project supported by the National Natural Science Foundation of China(Nos.12102321 and 52192633)the Natural Science Basic Research Plan in Shaanxi Province of China(No.2025JCYBMS-050)。
文摘A design idea for single-component metamaterial plates is proposed to achieve the thermal stability of flexural wave bandgap by the perforated and pre-curved patterns.The band structure analysis suggests that perforation can release part of the in-plane thermal expansion to weaken the softening effect of thermal stress.Introducing precurved components to the perforated structure will stop the decrement of the bandgap frequency in thermal environment,and even make the frequency higher with appropriate structural parameters.The bending stiffness of the heated plate is enhanced by the thermal deflection induced stiffening effect of the pre-curved components.The segmented pre-curved component presents a strong ability to resist the thermal influence on the flexural wave bandgap.A simplified model is established for the local structure of the precurved component.The theoretical calculations explain the thermally induced frequency increment of the bandgap and the discrepancy in the thermal response between the two pre-curved models.The transmittance of flexural wave validates the effectiveness of the proposed design.
基金Project supported by the National Natural Science Foundation of China(No.12572020)the Key Project of Natural Science Foundation of Hebei Province of China(No.A2023210064)。
文摘Local resonant acoustic metamaterials have broad applications in sound insulation,yet their single-configuration designs often exhibit limited and discontinuous bandgap widths,hindering full-frequency noise attenuation across the human auditory range.This study presents a double-phase fidget-spinner-shaped acoustic metamaterial(DFAM),specifically designed to achieve an ultra-broad,low-frequency continuous bandgap by means of synergistic structural optimization,enabling effective and robust control of audible noise.Based on Bloch's theorem and the finite element method,the dispersion relation of the DFAM structure is calculated and verified by the transmission loss curves.The propagation characteristics of sound waves within the structure are further analyzed for noise frequencies that fall within the passband.The influence of the geometric and physical parameters on the bandgap is investigated,and the corresponding transmission loss in the propagation direction is further calculated.A hybrid collaborative design strategy,leveraging multi-parameter optimization and bandgap complementarity,is developed to construct a metastructure with continuous bandgap coverage from 20 Hz to 1000 Hz.The resulting metastructure demonstrates exceptional broadband noise attenuation,achieving a total bandgap width of 876.3 Hz(87.63% of the target range)with the transmission loss up to-762.78 d B in a three-periodic arrangement.The simulation and experimental results for the transmission loss of the DFAM metastructure show strong agreement in the low-frequency range.This work provides a novel framework for designing ultra-wide low-frequency continuous bandgap metastructures,offering significant potential for noise mitigation in complex environments.
基金supported by Natural Science Basic Research Program of Shaanxi Province of China (No. 2023-JC-YB-574)National Natural Science Foundation of China (No. 62304178)。
文摘β-Ga_(2)O_(3) MOS inverter should play a crucial role in β-Ga_(2)O_(3) electronic circuits. Enhancement-mode(E-mode) MOSFET was fabricated based on β-Ga_(2)O_(3) film grown by atomic layer deposition technology, and the β-Ga_(2)O_(3) inverter was further monolithically integrated on this basis. The β-Ga_(2)O_(3) n MOSFET exhibits excellent electrical characteristics with an on/off current ratio reaching 10^(5). The logic inverter shows outstanding voltage inversion characteristics under low-frequency from 1 to 400 Hz operation. As the frequency continues to increase to 10 K, the reverse characteristic becomes worse due to parasitic capacitance induced by processes, and the difference between the highest and lowest values of VOUT has an exponential decay relationship with the frequency. This paper provides the practice for the development of β-Ga_(2)O_(3)-based circuits.
文摘Owing to superior breakdown voltage and excellent robustness,the betagallium oxide(β-Ga_(2)O_(3))power device has emerged as a pivotal research frontier in power electronics.Although advanced packaging strategies,including nanosilver paste sintering,alumina direct bond copper(DBC)substrates,and flipchip structures,have been adopted to mitigate the intrinsic low thermal conductivity ofβ-Ga_(2)O_(3).However,a further reduction in the thermal resistance while maintaining high reliability remains a challenge.This study introduces a novel packaging methodology that synergistically integrates nano-silver films with aluminum nitride active metal brazing(AMB-AlN)substrates,achieving an ultra-low junction-to-case thermal resistance.By comprehensive reliability assessments onβ-Ga_(2)O_(3) Schottky barrier diodes(SBDs)and hetero-junction diodes(HJDs),the results demonstrate that the SBDs and HJDs exhibit surge current densities of 0.876 kA/cm^(2) and 0.778 kA/cm^(2),respectively,which represents a significant advancement in device performance benchmarks.These advancements provide critical insights into packaging design for highreliability ultrawide bandgap semiconductor systems.
基金financial supports of the National Natural Science Foundation of China(52222512)。
文摘The application potential of tuning two-dimensional materials(2DMs)characteristics through strain engineering for wearable and flexible devices has been widely recognized.However,the challenges lie in achieving accurate deterministic positioning,spatial modulation,controllable magnitude,and permanent nanostrains.Herein,motivated by the skin swelling caused by mosquito bites,a technique utilizing the heated nanotip in atomic force microscopy for thermomechanical nanoindentation is demonstrated.This method enables precise positioning of localized nanostrain and regulation of bandgap in tungsten diselenide(WSe_(2))/molybdenum disulfide(MoS_(2))heterobilayer transferred onto a flexible polymethyl methacrylate film.The magnitude of strain in the WSe_(2)/MoS_(2) heterobilayer can be controlled by adjusting the parameters of nanoindentation,leading to a spatially modulated average strain of up to 2.5%on the ring-shaped expansion structure(RES).The local bandgap of the WSe_(2)/MoS_(2) heterobilayer is spatially regulated through three distinct regions.In particular,the RES exhibits the largest extent of bandgap modulation,accompanied by a significant change of~12 meV.The nanostrain significantly enhances the photoresponse speed of the photodetector device.For instance,under illumination from a 405 nm wavelength-laser,the rise time and fall time are reduced by 75%and 87.52%,respectively,compared to the device without strain.Similarly,under illumination from a 532 nm wavelength-laser,the rise time and fall time are reduced by 66.67%and 80.60%,respectively.These findings demonstrate that the proposed method serves as a versatile way for improving the photoresponse of optoelectronic devices based on 2DMs.
文摘Since opening sizable bandgaps in bilayer graphene （BLG） was proven possible, BLG has attracted considerable attention as a promising high-mobility candidate material for many electronic and optoelectronic applications. However, the bandgaps observed in the transport experiments reported in the literature are far smaller than both the theoretical predictions and the bandgaps extracted from optical measurements. In this study, we investigate the factors preventing the formation of large bandgaps and demonstrate that a -200-meV transport bandgap can be opened in BLG by scaling the gate dielectric and employing a ribbon channel to suppress the percolative transport. This is the largest transport bandgap that has been achieved in BLG to date.
文摘This paper studies the bandgap characteristics of a locally resonant metamaterial beam with time delays.The dispersion relations are addressed based on transfer matrix method.The governing equations of motion of the beam in the frequency domain are given according to spectral element method.The amplitude-frequency responses of the forced beam are determined by solving linear algebraic equations.The obtained results show that the time-delayed feedback control has great relationships with the location,width and number of the bandgaps.It is interesting that the time delay can change the direction of the movement of the bandgap and give rise to the generation of multiple bandgaps.The influences of different combinations of control parameters on the bandgap properties are shown,such as broadening effects.
基金supported by the Natural Science Foundation of Zhejiang Province(Grant No.LQ24F040007)the National Natural Science Foundation of China(Grant No.U22A2075)the Opening Project of State Key Laboratory of Polymer Materials Engineering(Sichuan University)(Grant No.sklpme2024-1-21).
文摘To address the increasing demand for massive data storage and processing,brain-inspired neuromorphic comput-ing systems based on artificial synaptic devices have been actively developed in recent years.Among the various materials inves-tigated for the fabrication of synaptic devices,silicon carbide(SiC)has emerged as a preferred choices due to its high electron mobility,superior thermal conductivity,and excellent thermal stability,which exhibits promising potential for neuromorphic applications in harsh environments.In this review,the recent progress in SiC-based synaptic devices is summarized.Firstly,an in-depth discussion is conducted regarding the categories,working mechanisms,and structural designs of these devices.Subse-quently,several application scenarios for SiC-based synaptic devices are presented.Finally,a few perspectives and directions for their future development are outlined.
基金supported by the National Natural Science Foundation of China(NSFC)under grant No.62204235。
文摘This paper introduces a high-precision bandgap reference(BGR)designed for battery management systems(BMS),fea-turing an ultra-low temperature coefficient(TC)and line sensitivity(LS).The BGR employs a current-mode scheme with chopped op-amps and internal clock generators to eliminate op-amp offset.A low dropout regulator(LDO)and a pre-regula-tor enhance output driving and LS,respectively.Curvature compensation enhances the TC by addressing higher-order nonlinear-ity.These approaches,effective near room temperature,employs trimming at both 20 and 60°C.When combined with fixed cur-vature correction currents,it achieves an ultra-low TC for each chip.Implemented in a CMOS 180 nm process,the BGR occu-pies 0.548 mm²and operates at 2.5 V with 84μA current draw from a 5 V supply.An average TC of 2.69 ppm/℃ with two-point trimming and 0.81 ppm/℃ with multi-point trimming are achieved over the temperature range of-40 to 125℃.It accommo-dates a load current of 1 mA and an LS of 42 ppm/V,making it suitable for precise BMS applications.
