Eu Mossbauer spectra of BaFBr:Eu phosphor are reported for the first time.The results show that f(Eu(2+) )<f(Eu(3+)) or <x2>Eu(2+)><x2>Eu(3+),which indicates that the attraction between phonons and E...Eu Mossbauer spectra of BaFBr:Eu phosphor are reported for the first time.The results show that f(Eu(2+) )<f(Eu(3+)) or <x2>Eu(2+)><x2>Eu(3+),which indicates that the attraction between phonons and Eu(2+) is stronger than that between phonons and Eu(3+),this may cause a faster increase of f(Eu=(2+)vs f(Eu(3+)) when temperature decreases as observed in the experiments.It is also found from Mossbauer investigation that when temperature decreases,the relative content of Eu(2+) decreases, while that of Eu(3+) increases.The temperature dependent Mossbauer spectra provide evidence for electron exchange or hopping between Eu(2+) or Eu(3+) sites in BaFBr lattice. The Mossbauer results are discussed and compared with the results of XPS and Photoluminescence studies.展开更多
Thermal stimulated luminescence (TSL) and photostimulated luminescence (PSL) were used to investigate the luminescent performance of Al 3+ doped BaFBr∶Eu 2+ in different synthetic conditions. Theory analys...Thermal stimulated luminescence (TSL) and photostimulated luminescence (PSL) were used to investigate the luminescent performance of Al 3+ doped BaFBr∶Eu 2+ in different synthetic conditions. Theory analysis shows that the decay of TSL spectra is different from that of PSL spectra. Theoretical calculation was used to investigate the effects of energy state in Al 3+ doped BaFBr∶Eu 2+ by different synthetic conditions. The relationship of color center’s energy and different synthetic conditions is discussed.展开更多
In Ref.[1] we reported the V centers and hole-photostimulated luminescence(HPSL) of BaFCl crystal. The result shows that the V centers play an equal role asthe F centers in the X-ray storage and photostimulated lumine...In Ref.[1] we reported the V centers and hole-photostimulated luminescence(HPSL) of BaFCl crystal. The result shows that the V centers play an equal role asthe F centers in the X-ray storage and photostimulated luminescence (PSL) processes.Previous research work paid much attention to the F centers but neglected the Vcenters. So the X-ray storage and PSL processes have not been revealed completelyyet. Our research work is significant as a complement to the previous documents.展开更多
In ref.[1] we reported the high temperature （from room temperature to 773K）thermostimulated luminescence （TSL） of BaFC1: Eu<sup>2+</sup> crystals. Three new glow peaks werefound and assigned to be caus...In ref.[1] we reported the high temperature （from room temperature to 773K）thermostimulated luminescence （TSL） of BaFC1: Eu<sup>2+</sup> crystals. Three new glow peaks werefound and assigned to be caused, respectively, by F<sub>2</sub>, F<sub>3</sub> and F<sub>4</sub> centers which were theaggregates of F centers. Meanwhile, the high temperature TSL of BaFBr:Eu<sup>2+</sup> crystals展开更多
文摘Eu Mossbauer spectra of BaFBr:Eu phosphor are reported for the first time.The results show that f(Eu(2+) )<f(Eu(3+)) or <x2>Eu(2+)><x2>Eu(3+),which indicates that the attraction between phonons and Eu(2+) is stronger than that between phonons and Eu(3+),this may cause a faster increase of f(Eu=(2+)vs f(Eu(3+)) when temperature decreases as observed in the experiments.It is also found from Mossbauer investigation that when temperature decreases,the relative content of Eu(2+) decreases, while that of Eu(3+) increases.The temperature dependent Mossbauer spectra provide evidence for electron exchange or hopping between Eu(2+) or Eu(3+) sites in BaFBr lattice. The Mossbauer results are discussed and compared with the results of XPS and Photoluminescence studies.
文摘Thermal stimulated luminescence (TSL) and photostimulated luminescence (PSL) were used to investigate the luminescent performance of Al 3+ doped BaFBr∶Eu 2+ in different synthetic conditions. Theory analysis shows that the decay of TSL spectra is different from that of PSL spectra. Theoretical calculation was used to investigate the effects of energy state in Al 3+ doped BaFBr∶Eu 2+ by different synthetic conditions. The relationship of color center’s energy and different synthetic conditions is discussed.
基金Project supported by the National Natural Science Foundation of China.
文摘In Ref.[1] we reported the V centers and hole-photostimulated luminescence(HPSL) of BaFCl crystal. The result shows that the V centers play an equal role asthe F centers in the X-ray storage and photostimulated luminescence (PSL) processes.Previous research work paid much attention to the F centers but neglected the Vcenters. So the X-ray storage and PSL processes have not been revealed completelyyet. Our research work is significant as a complement to the previous documents.
基金Project supported by the National Natural Science Foundation of China.
文摘In ref.[1] we reported the high temperature （from room temperature to 773K）thermostimulated luminescence （TSL） of BaFC1: Eu<sup>2+</sup> crystals. Three new glow peaks werefound and assigned to be caused, respectively, by F<sub>2</sub>, F<sub>3</sub> and F<sub>4</sub> centers which were theaggregates of F centers. Meanwhile, the high temperature TSL of BaFBr:Eu<sup>2+</sup> crystals
