A zinc oxide ZnO field emitter-based backlight unit for liquid crystal display with a gated structure is fabricated by screen-printing processes.The measured anode field emission current density reaches 0.62 mA/cm2 wh...A zinc oxide ZnO field emitter-based backlight unit for liquid crystal display with a gated structure is fabricated by screen-printing processes.The measured anode field emission current density reaches 0.62 mA/cm2 when the applied gate voltage is 570 V.Part of the anode current is contributed by the secondary electron emission which is excited from the MgO layer inside the gate apertures on the gate plate. The average emission current density and luminance are 0.47 mA/cm2 and 1 250 cd/m2 respectively with a fluctuation of about 10% during the 1 000 min measurement.By a finite element method calculation the gated structure shows a good electron beam focusing property. The driving performance of the backlight unit is characterized by SPICE simulation tools and measured by the oscilloscope. Stable field emission line-by-line scanning and fast response characteristics of the backlight unit indicate its promising application in the liquid crystal displays.展开更多
Wide color gamut(WCG) backlight for liquid crystal display(LCD) utilizing white light-emitting diodes(LED) has attracted considerable attention for their high efficiency and color reduction.In this review,recent devel...Wide color gamut(WCG) backlight for liquid crystal display(LCD) utilizing white light-emitting diodes(LED) has attracted considerable attention for their high efficiency and color reduction.In this review,recent developments in crystal structure,luminescence and applications of phosphors for wide color gamut LED backlight are introduced.As novel red phosphors,Mn4+activate fluoride and aluminate phosphors are advanced in quantum efficiency,thermal quenching and color saturation for their characteristic spectrum with broad excitation band and linear emission.The crystal structure and fluorescence properties of Mn4+doped fluosilicate,fluorogermanate,fluotitanate,as well as Sr4 Al14O25,CaAl12O19 and BaMgAl10O17 phosphors are discussed in detail.A serial of narrow-band red-emitting Eu2+,Eu3+and Pr3+-doped nitride silicates and molybdate phosphors are also introduced.Rare-earth-doped oxynitride and silicate green-emitting phosphors have attracted more and more attention because of the wide excitation,narrow emission,high quenching temperature,high quantum efficiency,such as β-sialon:Eu2+,Ba3Si6O12N2:Eu2+,MSi2O2N2:Eu2+(M=Ca,Sr,Ba),y-AlON:Mn2+and Ca3Sc2Si3O12:Ce3+.All above phosphors demonstrate their adaptability in wide color gamut LCD display.Especially for Mn4+doped fluosilicate red phosphor and β-sialon:Eu2+green phosphor.To achieve an ultra-high color gamut in white LED backlight and against the OLED,innovative narrow-band-emission red and green phosphor materials with independent intellectual property rights are continuously pursed.展开更多
A switchable autostereoscopic 3-dimensional(3D) display device with wide color gamut is introduced in this paper. In conjunction with a novel directional quantum-dot(QD) backlight, the precise scanning control strateg...A switchable autostereoscopic 3-dimensional(3D) display device with wide color gamut is introduced in this paper. In conjunction with a novel directional quantum-dot(QD) backlight, the precise scanning control strategy, and the eye-tracking system, this spatial-sequential solution enables our autostereoscopic display to combine all the advantages of full resolution,wide color gamut, low crosstalk, and switchable 2D/3D. And also, we fabricated an autostereoscopic display prototype and demonstrated its performances effectively. The results indicate that our system can both break the limitation of viewing position and provide high-quality 3D images. We present two working modes in this system. In the spatial-sequential mode,the crosstalk is about 6%. In the time-multiplexed mode, the viewer should wear auxiliary and the crosstalk is about 1%,just next to that of a commercial 3D display(BENQ XL2707-B and View Sonic VX2268 WM). Additionally, our system is also completely compatible with active shutter glasses and its 3D resolution is same as its 2D resolution. Because of the excellent properties of the QD material, the color gamut can be widely extended to 77.98% according to the ITU-R recommendation BT.2020(Rec.2020).展开更多
Two 50-μm Mo wires in parallel used as a Z-pinch load are electrically exploded with a pulsed current rising to 275 kA in 125 ns and their explosion processes are backlighted using an X-pinch as an x-ray source. The ...Two 50-μm Mo wires in parallel used as a Z-pinch load are electrically exploded with a pulsed current rising to 275 kA in 125 ns and their explosion processes are backlighted using an X-pinch as an x-ray source. The backlighting images show clearly the processes similar to those occurring in the initial stages of a cylindrical wire-array Z-pinch, including the electric explosion of single wires characterised by the dense wire cores surrounded by a low-density coronal plasma, the expansion of the exploding wire, the sausage instability （m = 0） in the coronal plasma around each wire, the motion of the coronal plasma as well as the wire core toward the current centroid, the formation of the precursor plasma column with a twist structure something like that of higher mode instability, especially the kink instability （m = 1）.展开更多
In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was establis...In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was established.Yanlieshan tunnel of Jiujing highway was taken as an example for the optimization.The optimal LDPs of the backlighting system of the tunnel interior zone were obtained by the POM,a comparison between the optimization results and those of Yanlieshan tunnel’s actual lighting system was performed,which showed that the optimized backlighting system with LED lamps installed according to the optimized LDPs could save energy remarkablely even under full capacity lighting condition.Illuminance and illuminance uniformity of the tunnel road surface still met the lighting demands even the LED lamp’s luminance decreased by 30%.A backlighting simulation experiment with the optimized backlighting LDPs for Yanlieshan tunnel was accomplished in the software Dialux.The simulation results basically agreed with the optimization calculated results from the POM which proved the correctness of the backlighting POM.展开更多
In the current situation of energy shortages,saving energy and reducing consumption are undoubtedly valid methods to relieve the pressure on resources.CsPbX_(3)(X=Cl,Br,and I)perovskites as star inorganic materials ha...In the current situation of energy shortages,saving energy and reducing consumption are undoubtedly valid methods to relieve the pressure on resources.CsPbX_(3)(X=Cl,Br,and I)perovskites as star inorganic materials have drawn growing attention owing to their unique properties,making them suitable for applications such as light-emitting diodes(LEDs),solar cells,photodetectors,or lasers.This work presents zinc oxide(ZnO)induced self-crystallized CsPb(Br/I)_(3) perovskite with a 26%photoluminescence quantum yield(PLQY)prepared by the traditional melt-quenching method.Furthermore,the full width at half maximum(FWHM)(34–44 nm)can be regulated by the ZnO content.In addition,as a downconverter,CsPb(Br/I)_(3) perovskite nanocrystals(NCs)realize a bright red backlight that covers≈94%Rec.2020 standards in the CIE 1931 color space and 126%of National Television System Committee(NTSC).This finding undoubtedly confirms an effective path for fabricating perovskite materials in a green,low-cost,and time-saving way,enriching the knowledge of glass crystallization mechanisms and promoting their applications in wide color gamut backlights.展开更多
An X-pinch axial backlighting system has been designed to quantitatively measure the density distribution of wirearray Z-pinch plasmas. End-on backlighting experiments were carried out on a 200 kA, 100 ns pulsed-power...An X-pinch axial backlighting system has been designed to quantitatively measure the density distribution of wirearray Z-pinch plasmas. End-on backlighting experiments were carried out on a 200 kA, 100 ns pulsed-power generator(PPG-1) at the Tsinghua University. Compared with side-on backlighting, end-on measurements provide an axial view of the evolution of Z-pinch plasmas. Early stages of 2-, 4-, and 8-wire Z-pinch plasmas were observed via point-projection backlighting radiography with a relatively high success rate. The density distribution of Z-pinch plasma on the r–θ plane was obtained directly from the images with the help of step wedges, and the inward radial velocity was calculated. The ablation rates obtained by X-pinch backlighting experiments are compared in detail with those calculated by the rocket model and the results show consistency.展开更多
We utilized "direct illumination-type" LED backlight project, made white-light LED array in rectangle, designed a sheet of reflective film, a sheet of diffuser and two sheets of brightness enhancement film, ...We utilized "direct illumination-type" LED backlight project, made white-light LED array in rectangle, designed a sheet of reflective film, a sheet of diffuser and two sheets of brightness enhancement film, then analyzed illuminance chart which was the result of simulation in several distance between reflective film and optical film. It showed the best matching between illuminance and uniformity while in 25mm distance. Finally, we discussed some problems with thermal dispersion.展开更多
This study proposes an innovative design method for functional optical film microstructures used in displays and applies this design to LCD backlighting to replace multi-layer optical film functional integration with ...This study proposes an innovative design method for functional optical film microstructures used in displays and applies this design to LCD backlighting to replace multi-layer optical film functional integration with composite optical film. We design a novel optical film microstructure based on light uniformity and wide-angle lumination distribution and determine the optimal optical microstructure parameters by combining the global optimization of a genetic algorithm with ray tracing. The purpose of this study is to develop substitutes for traditional multi-layer prism brightness enhancers and light-diffusing film stacks and to examine the structural changes during calculations and summarize the characteristics. In this study, we focus on determining the optimal light uniformity of new optical film microstructures. The seven-inch LED backlight module of the method proposed in this study achieved 94.59% uniformity and 168° lumination distribution while reducing thickness by 66% to 82% compared to a traditional multi-layer optical film stack.展开更多
A micro-projection dynamic backlight for multi-view three-dimensional(3D)display is proposed.The proposed backlight includes a light emitting diodes(LEDs)array,a lenticular lens array,and a scattering film.The LED arr...A micro-projection dynamic backlight for multi-view three-dimensional(3D)display is proposed.The proposed backlight includes a light emitting diodes(LEDs)array,a lenticular lens array,and a scattering film.The LED array,the lenticular lens,and the scattering film construct a micro-projection structure.In this structure,the LEDs in the array are divided into several groups.The light from each LED group can be projected to the scattering film by the lenticular lens and forms a series of bright stripes.The different LED groups have different horizontal positions,so these bright stripes corresponding to different LED groups also have different horizontal positions.Therefore,they can be used as a dynamic backlight.Because the distance between the LEDs array and the lenticular lens is much larger than the distance between the lenticular lens and the scattering films,the imaging progress will make the width of the bright stripes much smaller than that of the LEDs,and the pitch of the stripes is also decreased.According to the 3D display theory,the bright stripes with small width and pitch help to increase the number of views.Therefore,the proposed micro-projection dynamic backlight is very suitable for multi-view 3D display.An experimental prototype was developed,and the experimental results show that the micro-projection dynamic backlight can correctly complete the directional projection of the parallax images to form a 3D display.展开更多
We propose an automatic three-dimensionM （3D） pupil tracking backlight system for holographic 3D display system with large image size and full-parallax accommodation effect. The proposed tracking module is applied t...We propose an automatic three-dimensionM （3D） pupil tracking backlight system for holographic 3D display system with large image size and full-parallax accommodation effect. The proposed tracking module is applied to a holographic 3D display system with two sets of directional holographic imaging module composed of 2 × 2 large scale lens array and 22-inch high-resolution liquid crystal display 3D panel. System architecture is described and experimental results are presented.展开更多
High efficient lead halide perovskites with wide-color gamut properties have emerged as new candidates for backlight displays.However,the toxicity of lead and the instability of halide perovskites greatly limit their ...High efficient lead halide perovskites with wide-color gamut properties have emerged as new candidates for backlight displays.However,the toxicity of lead and the instability of halide perovskites greatly limit their practical applications.Herein,the luminescent powders of[(CH_(3))4N]2MnBr_(4)and[(CH_(3))4N]MnBr3 were synthesized via a simple yet robust solvent evaporation method.[(CH_(3))4N]2MnBr_(4)with tetrahedral coordination Mn^(2+)and[(CH_(3))4N]MnBr3 with octahedral coordination Mn^(2+)show green at 517 nm and red emission peaks at 620 nm,respectively,originating from the^(4)T1-^(6)A_(1)transition of Mn^(2+).To enhance optical of manganese halide via effective alloying,Zn^(2+)-doped[(CH_(3))4N]2MnBr_(4)was successfully prepared,and the quantum efficiency of[(CH_(3))_(4)N]_(2)Mn_(0.6)Zn_(0.4)Br_(4)was as high as 65%.Furthermore,[(CH_(3))4N]2Mn0.6Zn0.4Br_(4)exhibits better optical and thermal stability compared to[(CH_(3))4N]2MnBr_(4).[(CH_(3))_(4)N]_(2)Mn_(0.6)Zn_(0.4)Br_(4)@CsPbBr_(1.2)I_(1.8)light conversion films with different green-to-red ratios are placed in backlight display devices,and their color gamut exceeds 106%of the National Television Standards Committee(NTSC)1953 standard,which is superior to the currently reported Mn-based perovskite.This work broadly shows that the[(CH_(3))_(4)N]_(2)Mn_(0.6)Zn_(0.4)Br_(4)will provide effective route to fabricate stable and high-performance lead-free liquid crystal displays.展开更多
基金The National Basic Research Program of China(973 Program)(No.2013CB328803)the National Natural Science Foundation of China(No.51002031)+1 种基金the Ph.D.Programs Foundation of Ministry of Education of China(No.20100092120022)the National High Technology Research and Development Program of China(863 Program)(No.2012AA03A302,2013AA011004)
文摘A zinc oxide ZnO field emitter-based backlight unit for liquid crystal display with a gated structure is fabricated by screen-printing processes.The measured anode field emission current density reaches 0.62 mA/cm2 when the applied gate voltage is 570 V.Part of the anode current is contributed by the secondary electron emission which is excited from the MgO layer inside the gate apertures on the gate plate. The average emission current density and luminance are 0.47 mA/cm2 and 1 250 cd/m2 respectively with a fluctuation of about 10% during the 1 000 min measurement.By a finite element method calculation the gated structure shows a good electron beam focusing property. The driving performance of the backlight unit is characterized by SPICE simulation tools and measured by the oscilloscope. Stable field emission line-by-line scanning and fast response characteristics of the backlight unit indicate its promising application in the liquid crystal displays.
基金Project supported by National Key Research and Development Program(2017YFB0404301)
文摘Wide color gamut(WCG) backlight for liquid crystal display(LCD) utilizing white light-emitting diodes(LED) has attracted considerable attention for their high efficiency and color reduction.In this review,recent developments in crystal structure,luminescence and applications of phosphors for wide color gamut LED backlight are introduced.As novel red phosphors,Mn4+activate fluoride and aluminate phosphors are advanced in quantum efficiency,thermal quenching and color saturation for their characteristic spectrum with broad excitation band and linear emission.The crystal structure and fluorescence properties of Mn4+doped fluosilicate,fluorogermanate,fluotitanate,as well as Sr4 Al14O25,CaAl12O19 and BaMgAl10O17 phosphors are discussed in detail.A serial of narrow-band red-emitting Eu2+,Eu3+and Pr3+-doped nitride silicates and molybdate phosphors are also introduced.Rare-earth-doped oxynitride and silicate green-emitting phosphors have attracted more and more attention because of the wide excitation,narrow emission,high quenching temperature,high quantum efficiency,such as β-sialon:Eu2+,Ba3Si6O12N2:Eu2+,MSi2O2N2:Eu2+(M=Ca,Sr,Ba),y-AlON:Mn2+and Ca3Sc2Si3O12:Ce3+.All above phosphors demonstrate their adaptability in wide color gamut LCD display.Especially for Mn4+doped fluosilicate red phosphor and β-sialon:Eu2+green phosphor.To achieve an ultra-high color gamut in white LED backlight and against the OLED,innovative narrow-band-emission red and green phosphor materials with independent intellectual property rights are continuously pursed.
基金Project supported by the National Key R&D Program of China(Grant No.2016YFB0401503)the R&D Plan of Jiangsu Science and Technology Department,China(Grant No.BE2016173)
文摘A switchable autostereoscopic 3-dimensional(3D) display device with wide color gamut is introduced in this paper. In conjunction with a novel directional quantum-dot(QD) backlight, the precise scanning control strategy, and the eye-tracking system, this spatial-sequential solution enables our autostereoscopic display to combine all the advantages of full resolution,wide color gamut, low crosstalk, and switchable 2D/3D. And also, we fabricated an autostereoscopic display prototype and demonstrated its performances effectively. The results indicate that our system can both break the limitation of viewing position and provide high-quality 3D images. We present two working modes in this system. In the spatial-sequential mode,the crosstalk is about 6%. In the time-multiplexed mode, the viewer should wear auxiliary and the crosstalk is about 1%,just next to that of a commercial 3D display(BENQ XL2707-B and View Sonic VX2268 WM). Additionally, our system is also completely compatible with active shutter glasses and its 3D resolution is same as its 2D resolution. Because of the excellent properties of the QD material, the color gamut can be widely extended to 77.98% according to the ITU-R recommendation BT.2020(Rec.2020).
基金supported by the National Natural Science Foundation of China (Grant No. 10635050)the Foundation for the Author of National Excellent Doctoral Dissertation of China (Grant No. 200748)+2 种基金the International Atomic Energy Agency (Grant No. 14509)the Postdoctoral Science Foundation of China (Grant No. 20090450355)the Special Research Fund for the Doctoral Program of Higher Education,China (Grant No. 200800030037)
文摘Two 50-μm Mo wires in parallel used as a Z-pinch load are electrically exploded with a pulsed current rising to 275 kA in 125 ns and their explosion processes are backlighted using an X-pinch as an x-ray source. The backlighting images show clearly the processes similar to those occurring in the initial stages of a cylindrical wire-array Z-pinch, including the electric explosion of single wires characterised by the dense wire cores surrounded by a low-density coronal plasma, the expansion of the exploding wire, the sausage instability （m = 0） in the coronal plasma around each wire, the motion of the coronal plasma as well as the wire core toward the current centroid, the formation of the precursor plasma column with a twist structure something like that of higher mode instability, especially the kink instability （m = 1）.
基金National Natural Science Foundation of China(No.61463015)
文摘In order to acquire the most energy-saving luminairedistribution-parameters(LDPs)of highway tunnel interior zone backlighting,the parameters optimization model(POM)of backlighting for tunnel interior zone was established.Yanlieshan tunnel of Jiujing highway was taken as an example for the optimization.The optimal LDPs of the backlighting system of the tunnel interior zone were obtained by the POM,a comparison between the optimization results and those of Yanlieshan tunnel’s actual lighting system was performed,which showed that the optimized backlighting system with LED lamps installed according to the optimized LDPs could save energy remarkablely even under full capacity lighting condition.Illuminance and illuminance uniformity of the tunnel road surface still met the lighting demands even the LED lamp’s luminance decreased by 30%.A backlighting simulation experiment with the optimized backlighting LDPs for Yanlieshan tunnel was accomplished in the software Dialux.The simulation results basically agreed with the optimization calculated results from the POM which proved the correctness of the backlighting POM.
基金the National Natural Science Foundation of China(Nos.51872207 and 52072271)。
文摘In the current situation of energy shortages,saving energy and reducing consumption are undoubtedly valid methods to relieve the pressure on resources.CsPbX_(3)(X=Cl,Br,and I)perovskites as star inorganic materials have drawn growing attention owing to their unique properties,making them suitable for applications such as light-emitting diodes(LEDs),solar cells,photodetectors,or lasers.This work presents zinc oxide(ZnO)induced self-crystallized CsPb(Br/I)_(3) perovskite with a 26%photoluminescence quantum yield(PLQY)prepared by the traditional melt-quenching method.Furthermore,the full width at half maximum(FWHM)(34–44 nm)can be regulated by the ZnO content.In addition,as a downconverter,CsPb(Br/I)_(3) perovskite nanocrystals(NCs)realize a bright red backlight that covers≈94%Rec.2020 standards in the CIE 1931 color space and 126%of National Television System Committee(NTSC).This finding undoubtedly confirms an effective path for fabricating perovskite materials in a green,low-cost,and time-saving way,enriching the knowledge of glass crystallization mechanisms and promoting their applications in wide color gamut backlights.
基金supported by the National Natural Science Foundation of China(Grant Nos.11177086 and 51177086)Guangdong Innovative Research Team Program of China(Grant No.2011S013)+2 种基金the National Key Research and Develop Program of China(Grant No.2016YFC0105102)the National Basic Research Program of China(Grant Nos.2012AA02A604 and 2015AA043203)Beijing Center for Mathematics and Information Interdisciplinary Sciences,China
文摘An X-pinch axial backlighting system has been designed to quantitatively measure the density distribution of wirearray Z-pinch plasmas. End-on backlighting experiments were carried out on a 200 kA, 100 ns pulsed-power generator(PPG-1) at the Tsinghua University. Compared with side-on backlighting, end-on measurements provide an axial view of the evolution of Z-pinch plasmas. Early stages of 2-, 4-, and 8-wire Z-pinch plasmas were observed via point-projection backlighting radiography with a relatively high success rate. The density distribution of Z-pinch plasma on the r–θ plane was obtained directly from the images with the help of step wedges, and the inward radial velocity was calculated. The ablation rates obtained by X-pinch backlighting experiments are compared in detail with those calculated by the rocket model and the results show consistency.
文摘We utilized "direct illumination-type" LED backlight project, made white-light LED array in rectangle, designed a sheet of reflective film, a sheet of diffuser and two sheets of brightness enhancement film, then analyzed illuminance chart which was the result of simulation in several distance between reflective film and optical film. It showed the best matching between illuminance and uniformity while in 25mm distance. Finally, we discussed some problems with thermal dispersion.
文摘This study proposes an innovative design method for functional optical film microstructures used in displays and applies this design to LCD backlighting to replace multi-layer optical film functional integration with composite optical film. We design a novel optical film microstructure based on light uniformity and wide-angle lumination distribution and determine the optimal optical microstructure parameters by combining the global optimization of a genetic algorithm with ray tracing. The purpose of this study is to develop substitutes for traditional multi-layer prism brightness enhancers and light-diffusing film stacks and to examine the structural changes during calculations and summarize the characteristics. In this study, we focus on determining the optimal light uniformity of new optical film microstructures. The seven-inch LED backlight module of the method proposed in this study achieved 94.59% uniformity and 168° lumination distribution while reducing thickness by 66% to 82% compared to a traditional multi-layer optical film stack.
基金supported by the National Natural Science Foundation of China (NSFC) (No. 61705022)Research Programs of Science and Technology Department of Sichuan Province (Nos. 2019JDRC0075 and 2019YJ0377)+2 种基金Sichuan Academic Achievement Analysis and Application Research Center Project (No. w16216284)Enterprise Research Project of Chengdu Technological University (No. 2020QY005)Seed Fund Project of Intelligent Air Vehicle Research Center (No. 2020ZZ002)
文摘A micro-projection dynamic backlight for multi-view three-dimensional(3D)display is proposed.The proposed backlight includes a light emitting diodes(LEDs)array,a lenticular lens array,and a scattering film.The LED array,the lenticular lens,and the scattering film construct a micro-projection structure.In this structure,the LEDs in the array are divided into several groups.The light from each LED group can be projected to the scattering film by the lenticular lens and forms a series of bright stripes.The different LED groups have different horizontal positions,so these bright stripes corresponding to different LED groups also have different horizontal positions.Therefore,they can be used as a dynamic backlight.Because the distance between the LEDs array and the lenticular lens is much larger than the distance between the lenticular lens and the scattering films,the imaging progress will make the width of the bright stripes much smaller than that of the LEDs,and the pitch of the stripes is also decreased.According to the 3D display theory,the bright stripes with small width and pitch help to increase the number of views.Therefore,the proposed micro-projection dynamic backlight is very suitable for multi-view 3D display.An experimental prototype was developed,and the experimental results show that the micro-projection dynamic backlight can correctly complete the directional projection of the parallax images to form a 3D display.
基金supported by Giga KOREA project(GK13D0100,Development of Telecommunications Terminal with Digital Holographic Table-top Display)
文摘We propose an automatic three-dimensionM （3D） pupil tracking backlight system for holographic 3D display system with large image size and full-parallax accommodation effect. The proposed tracking module is applied to a holographic 3D display system with two sets of directional holographic imaging module composed of 2 × 2 large scale lens array and 22-inch high-resolution liquid crystal display 3D panel. System architecture is described and experimental results are presented.
基金supported by the National Natural Science Foundation of China(Nos.51872207 and 52072271).
文摘High efficient lead halide perovskites with wide-color gamut properties have emerged as new candidates for backlight displays.However,the toxicity of lead and the instability of halide perovskites greatly limit their practical applications.Herein,the luminescent powders of[(CH_(3))4N]2MnBr_(4)and[(CH_(3))4N]MnBr3 were synthesized via a simple yet robust solvent evaporation method.[(CH_(3))4N]2MnBr_(4)with tetrahedral coordination Mn^(2+)and[(CH_(3))4N]MnBr3 with octahedral coordination Mn^(2+)show green at 517 nm and red emission peaks at 620 nm,respectively,originating from the^(4)T1-^(6)A_(1)transition of Mn^(2+).To enhance optical of manganese halide via effective alloying,Zn^(2+)-doped[(CH_(3))4N]2MnBr_(4)was successfully prepared,and the quantum efficiency of[(CH_(3))_(4)N]_(2)Mn_(0.6)Zn_(0.4)Br_(4)was as high as 65%.Furthermore,[(CH_(3))4N]2Mn0.6Zn0.4Br_(4)exhibits better optical and thermal stability compared to[(CH_(3))4N]2MnBr_(4).[(CH_(3))_(4)N]_(2)Mn_(0.6)Zn_(0.4)Br_(4)@CsPbBr_(1.2)I_(1.8)light conversion films with different green-to-red ratios are placed in backlight display devices,and their color gamut exceeds 106%of the National Television Standards Committee(NTSC)1953 standard,which is superior to the currently reported Mn-based perovskite.This work broadly shows that the[(CH_(3))_(4)N]_(2)Mn_(0.6)Zn_(0.4)Br_(4)will provide effective route to fabricate stable and high-performance lead-free liquid crystal displays.
