A kind of azo-containing resin(Azo-R)was synthesized by a simple way through the coupling reaction of 2-nitro-N-methyldiphenylamine-4-diazoresin(NDR)with phenol,and a new covalentely attached multilayer film from Azo-...A kind of azo-containing resin(Azo-R)was synthesized by a simple way through the coupling reaction of 2-nitro-N-methyldiphenylamine-4-diazoresin(NDR)with phenol,and a new covalentely attached multilayer film from Azo-R asH-donor and photosensitive diazoresin,diphenylamine-4-diazoresin(DR)as H-acceptor via H-bonding attraction by self-assembly technique has been fabricated.Following the decomposition of diazonium group of DR under exposure to UVlight,the H-bonds between the layers of the film convert to covalent bonds and the film becomes very stable toward polarsolvents or electrolyte aqueous solutions.Thus the UV-irradiated azo-containing films can be used to measure photocurrentin a conventional three-electrode photoelectrochemical cell using KCl as supporting electrolyte.It was confirmed that theazo-containing multilayer film is responsible for the photocurrent generation.展开更多
Photoisomerization of a new polymer: monoesters of polymaleic acid containing naphthalene-azo-anthraquinone groups in side chains at the air-water interface of a Langmuir trough wan detected by recording the developme...Photoisomerization of a new polymer: monoesters of polymaleic acid containing naphthalene-azo-anthraquinone groups in side chains at the air-water interface of a Langmuir trough wan detected by recording the development of surface pressure with time. This process wan found to be a first-order reaction and complete within several minutes.展开更多
An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesis and characterized by IR, NMR, GPC, viscosity and elemental measurements. The macroinitiator was further use to polymerize acrylamid...An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesis and characterized by IR, NMR, GPC, viscosity and elemental measurements. The macroinitiator was further use to polymerize acrylamide (AAm) in benzene to form polybutadiene/polyacrylamide (PBD/PAAm) block copolymers. High conversion of AAm was obtained over a wide range of monomer/macroinitiator ratios. The PBD/PAAm block copolymers were found to have excellent solvent resistance.展开更多
基金This work is financially supported by NSFC(No.2027400250173002).
文摘A kind of azo-containing resin(Azo-R)was synthesized by a simple way through the coupling reaction of 2-nitro-N-methyldiphenylamine-4-diazoresin(NDR)with phenol,and a new covalentely attached multilayer film from Azo-R asH-donor and photosensitive diazoresin,diphenylamine-4-diazoresin(DR)as H-acceptor via H-bonding attraction by self-assembly technique has been fabricated.Following the decomposition of diazonium group of DR under exposure to UVlight,the H-bonds between the layers of the film convert to covalent bonds and the film becomes very stable toward polarsolvents or electrolyte aqueous solutions.Thus the UV-irradiated azo-containing films can be used to measure photocurrentin a conventional three-electrode photoelectrochemical cell using KCl as supporting electrolyte.It was confirmed that theazo-containing multilayer film is responsible for the photocurrent generation.
文摘Photoisomerization of a new polymer: monoesters of polymaleic acid containing naphthalene-azo-anthraquinone groups in side chains at the air-water interface of a Langmuir trough wan detected by recording the development of surface pressure with time. This process wan found to be a first-order reaction and complete within several minutes.
基金This work was supported by the National Natural Science Foundation of China(Grant 2907200)
文摘An azo-group containing polybutadiene macroinitiator was prepared by Pinner synthesis and characterized by IR, NMR, GPC, viscosity and elemental measurements. The macroinitiator was further use to polymerize acrylamide (AAm) in benzene to form polybutadiene/polyacrylamide (PBD/PAAm) block copolymers. High conversion of AAm was obtained over a wide range of monomer/macroinitiator ratios. The PBD/PAAm block copolymers were found to have excellent solvent resistance.
